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Science
Iron 1 3
Hydrogen 2 2
Oxygen 1 4
Balance the atom which is maximum in number on either side of a chemical equation.
In this equation, the number of oxygen atom is the maximum on the RHS.
To balance the oxygen, one needs to multiply the oxygen on the LHS by 4, so that, the number of
oxygen atoms becomes equal on both sides.
Fe + 4 × H2O → Fe3O4 + H2
Now, the number of hydrogen atoms becomes 8 on the LHS, which is more than that on the RHS. To
balance it, one needs to multiply the hydrogen on the RHS by 4.
Fe + 4 × H2O → Fe3O4 + 4 × H2
After that, the number of oxygen and hydrogen atoms becomes equal on both sides. The number of iron
is one on the LHS, while it is three on the RHS. To balance it, multiply the iron on the LHS by 3.
3 × Fe + 4 × H2O → Fe3O4 + 4 × H2
Now the number of atoms of each element becomes equal on both sides. Thus, this equation becomes a
balanced equation.
After balancing, the above equation can be written as follows:
Name of atom No. of atoms in the reactant No No. of atoms in the product
Iron 3 3
Hydrogen 8 8
Oxygen 4 4
3Fe + 4H2O → Fe3O4 + 4H2.
To Make Equations More Informative:
Writing the symbols of physical states of substances in a chemical equation:
By writing the physical states of substances, a chemical equation becomes more informative.
• Gaseous state is represented by symbol (g).
• Liquid state is represented by symbol (l).
• Solid state is written by symbol (s).
• Aqueous solution is written by symbol (aq).
• Writing the condition in which reaction takes place: The condition is generally written above and/or
below the arrow of a chemical equation.
Thus, by writing the symbols of the physical state of substances and condition under which reaction
takes place, a chemical equation can be made more informative.
What are the types of a chemical reaction?
Types of Chemical Reactions: Combination Reaction, Decomposition Reaction, Displacement
Reaction, Double Displacement Reaction, Neutralization Reactions, Exothermic – Endothermic
Reactions and Oxidation-Reduction Reactions.
Types of Chemical Reactions:
Chemical reactions can be classified in following types:
(i) Combination Reaction: Reactions in which two or more reactants combine to form one product are
called Combination Reactions.
A general combination reaction can be represented by the chemical equation given here:
A + B → AB
Examples:
When magnesium is burnt in the air (oxygen), magnesium oxide is formed. In this reaction, magnesium
is combined with oxygen.
Mg(s) + O2(g) → 2MgO(s)
Magnesium + Oxygen → Magnesium Oxide
When carbon is burnt in oxygen (air), carbon dioxide is formed. In this reaction, carbon is combined
with oxygen.
C (s) + O2(g) → CO2(g)
Carbon + Oxygen → Carbon dioxide
(ii) Decomposition Reaction: Reactions in which one compound decomposes in two or more
compounds or elements are known as Decomposition Reaction. A decomposition reaction is just the
opposite of combination reaction.
A general decomposition reaction can be represented as follows :
AB → A + B
Examples:
When calcium carbonate is heated, it decomposes into calcium oxide and carbon dioxide.
CaCO3(s) heat−→− CaO(s) + CO2(g)
Calcium carbonate → Calcium oxide + Carbon dioxide
When ferric hydroxide is heated, it decomposes into ferric oxide and water
2Fe(OH)3(s) △→ Fe2O3(s) + 3H2O(l)
Thermal Decomposition: The decomposition of a substance on heating is known as Thermal
Decomposition.
Example: 2Pb(NO3)2(s) heat−→− 2PbO(s) + 4NO2(g) + O2(g)
Electrolytic Decomposition: Reactions in which compounds decompose into simpler compounds
because of passing of electricity, are known as Electrolytic Decomposition. This is also known as
Electrolysis.
Example: When electricity is passed in water, it decomposes into hydrogen and oxygen.
2H2O(l) ________ 2H2(g) + O2(g)
Photolysis or Photo Decomposition Reaction: Reactions in which a compound decomposes because of
sunlight are known as Photolysis or Photo Decomposition Reaction.
Example: When silver chloride is put in sunlight, it decomposes into silver metal and chlorine gas.
2AgCl(s) (white) Sunlight−→−−−−− 2Ag(s) (grey) + Cl2(g)
Photographic paper has a coat of silver chloride, which turns into grey when exposed to sunlight. It
happens because silver chloride is colourless while silver is a grey metal.
(iii) Displacement Reaction: The chemical reactions in which a more reactive element displaces a less
reactive element from a compound is known as Displacement Reactions. Displacement reactions are
also known as Substitution Reaction or Single Displacement/ replacement reactions.
A general displacement reaction can be represented by using a chemical equation as follows :
A + BC → AC + B
Displacement reaction takes place only when ‘A’ is more reactive than B. If ‘B’ is more reactive than
‘A’, then ‘A’ will not displace ‘C’ from ‘BC’ and reaction will not be taking place.
Examples:
When zinc reacts with hydrochloric acid, it gives hydrogen gas and zinc chloride.
Zn(s) + 2HCl(aq) → ZnCl2(aq) + H2(g)
When zinc reacts with copper sulphate, it forms zinc sulphate and copper metal.
Zn(s) + CuSO4(aq) → ZnSO4(aq) + Cu(s)
(iv) Double Displacement Reaction: Reactions in which ions are exchanged between two reactants
forming new compounds are called Double Displacement Reactions.
AB + CD → AC + BD
Examples:
When the solution of barium chloride reacts with the solution of sodium sulphate, white precipitate of
barium sulphate is formed along with sodium chloride.
BaCl2(aq) + Na2SO4(aq) → BaSO4(s) (Precipitate) + 2NaCl(aq)
When sodium hydroxide (a base) reacts with hydrochloric acid, sodium chloride and water are formed.
NaOH(aq) + HCl(aq) → NaCl(aq) + H2O(l)
Note: Double Displacement Reaction, in which precipitate is formed, is also known as precipitation
reaction. Neutralisation reactions are also examples of double displacement reaction.
Precipitation Reaction: The reaction in which precipitate is formed by the mixing of the aqueous
solution of two salts is called Precipitation Reaction.
Example:
Neutralization Reaction: The reaction in which an acid reacts with a base to form salt and water by an
exchange of ions is called Neutralization Reaction.
Example:
Endothermic Reaction: A chemical reaction in which heat energy is absorbed is called Endothermic
Reaction.
Example: Decomposition of calcium carbonate.
Corrosion of Silver Metal: The surface of silver metal gets tarnished (becomes dull) on exposure to air,
due to the formation of a coating of black silver sulphide(Ag2S) on its surface by the action of H2S gas
present in the air.
Rancidity: The taste and odour of food materials containing fat and oil changes when they are left
exposed to air for a long time. This is called Rancidity. It is caused due to the oxidation of fat and oil
present in food materials.
Methods to prevent rancidity:
• By adding anti-oxidant.
• Vacuum packing.
• Replacing air by nitrogen.
• Refrigeration of foodstuff.
1. Chemical Reaction: During chemical reactions, the chemical composition of substances changes or
new substances are formed.
2. Chemical Equation: Chemical reactions can be written in chemical equation form which should
always be balanced.
3. Types of Chemical Reactions:
Combination reaction: A single product is formed from two or more reactants.
2Mg + O2 → 2MgO
Decomposition reaction: A single reactant breaks down to yield two or more products.
• Thermal decomposition: 2Pb(NO2)2 → 2PbO + 4NO2 + O2
• Electrolysis: 2H20 → 2H2 + O2
• Photochemical reaction: 2AgBr → 2Ag + Br2
Displacement reaction: One element is displaced by another element.
Zn + CuSO4 → ZnSO4 + Cu
Double displacement reaction: Exchange of ions between reactants.
AgNO3 + NaCl → AgCl + NaNO3
Redox reaction: Both oxidation and reduction take place simultaneously.
CuO + H2 → Cu + H2O
Exothermic reaction: A chemical reaction in which heat energy is evolved.
C + O2 → CO2 (g) + heat
Endothermic reaction: A chemical reaction in which heat energy is absorbed.
ZnCO3 + Heat → ZnO + CO2
Redox reaction: Chemical reaction in which both oxidation and reduction take place simultaneously.
4. Oxidation: Reaction that involves the gain of oxygen or loss of hydrogen.
5. Reduction: Reaction that shows the loss of oxygen or gain of hydrogen.
ZnO + C → Zn + CO
ZnO is reduced to Zn—reduction. C is oxidized to CO—Oxidation.
6. Effects of Oxidation Reactions in Our Daily Life:
• Corrosion: It is an undesirable change that occurs in metals when they are attacked by moisture, air,
acids and bases.
Example, Corrosion (rusting) of Iron: Fe2O3. nH2O (Hydrated iron oxide)
• Rancidity: Undesirable change that takes place in oil containing food items due to the oxidation of fatty
acids.
Preventive methods of rancidity: Adding antioxidants to the food materials, storing food in the airtight
container, flushing out air with nitrogen gas and refrigeration.
•
3. What happens when dilute hydrochloric acid is added to iron filings? Tick the correct answer :
(a) Hydrogen gas and iron chloride are produced.
(b) Chlorine gas and iron hydroxide are produced.
(c) No reaction takes place.
(d) Iron salt and water are produced.
Answer: (a) Hydrogen gas and iron chloride are produced - The Chlorine from Hydrogen chloride is
displaced by the Iron fillings to undergo the following reaction.
2HCl + Fe → FeCl2 + H2
5. Translate the following statements into chemical equations and then balance them.
(a) Hydrogen gas combines with nitrogen to form ammonia.
(b) Hydrogen sulphide gas burns in air to give water and sulphur dioxide.
(c) Barium chloride reacts with aluminium sulphate to give aluminium chloride and a precipitate
of barium sulphate.
(d) Potassium metal reacts with water to give potassium hydroxide and hydrogen gas.
Answer: (a) Unbalanced: H2 + N2 → NH3
Balanced: 3H2 + N2 → 2NH3
(b) Unbalanced: H2S + O2 → H2O + SO2
Balanced: 2H2S + 3O2 → 2H2O + 2SO2
(c) Unbalanced:
BaCl2 + Al2(SO4)3 → AlCl3 + BaSO4
Balanced: 3BaCl2 + Al2(SO4)3 → 2AlCl3 + 3BaSO4
(d) Unbalanced: K + H2O → KOH + H2
Balanced: 2K + 2H2O → 2KOH + H2
8. Write the balanced chemical equation for the following and identify the type of reaction in each
case :
(a) Potassium bromide (aq) + Barium iodide (aq) → Potassium iodide (aq) + Barium
(b) Zinc carbonate(s) → Zinc oxide (s) + Carbon dioxide (g) bromide(s)
(c) Hydrogen (g) + Chloride (g) → Hydrogen chloride (g)
(d) Magnesium (s) + Hydrochloric acid (aq) → Magnesium chloride (aq) + Hydrogen (g)
Answer:
(a) 2KBr (aq) + Bal2(aq) → 2Kl(aq) + BaBr2(s)
Type : Double displacement reaction
(b) ZnCO3 (s) → ZnO (s) + CO2 (g)
Type: Decomposition reaction
(c) H2 (g) + Cl2 (g) → 2HCl(g)
Type: Combination reaction
(d) Mg (s) + 2HCl (aq) → MgCl2 (aq) + H2 (g)
Type : Displacement reaction
11. Why are decomposition reactions called the opposite of combination reactions? Write
equations for these reactions.
Answer:
In a decomposition reaction, a single compound breaks down to produce two or more simpler
substances.
For example:
While, in a combination reaction, two or more substances simply combine to form a new substance.
For example:
12. Write one equation each for the decomposition reactions where energy is supplied in the form
of heat, light or electricity.
OR
Decomposition reactions require energy either in the form of heat or light or electricity for
breaking down the reactants. Write one equation each for decomposition reactions where energy
is supplied in the form of heat, light and electricity. [CBSE 2015 (Delhi)]
Answer:
13. What is the difference between displacement and double displacement reactions? Write
equations for these reactions.
Answer:
In displacement reactions, a more reactive metal displaces a less reactive metal from its solution. For
example,
Fe(s) + CuSO4(aq) → Cu(s) + FeSO4(aq)
This is a displacement reaction where iron displaces copper from its solution.
In double displacement reactions, two reactants in solution exchange their ions. For example,
AgNO3(aq) + NaCl (aq) → AgCl(s) + NaNO3 (aq)
This is a double displacement reaction where silver nitrate and sodium chloride exchange Cl– and
NO3– ions between them.
14. In the refining of silver, the recovery of silver from silver nitrate solution involved
displacement by copper metal. Write down the reaction involved.
Answer:
16. Explain the following in terms of gain or loss of oxygen with two examples each:
(a) Oxidation and
(b) Reduction.
Answer:
(a) Oxidation : The addition of oxygen to a substance is called oxidation.
Example:
(i) S(s) + O2(g) → SO2(g) (Addition of oxygen to sulphur)
(ii) 2Mg(s) + O2 (g) → 2MgO(s) (Addition of oxygen to magnesium)
(b) Reduction : The removal of oxygen from a substance is called reduction.
Example: (i) CuO + H2 \(\under right arrow { Heat }\) Cu + H2O
Here, copper oxide is being reduced to copper because oxygen gets removed from copper oxide.
(ii) ZnO + C → Zn + CO
Here, zinc oxide is being reduced to zinc because oxygen gets removed from zinc oxide.
17. A shiny brown coloured element ‘X’ on heating in air becomes black in colour. Name the
element ‘X’ and the black coloured compound formed.
Answer:
Element ‘X’ is copper (Cu).
The black coloured compound is copper oxide (CuO). The reaction involved is
19. Oil and fat containing food items are flushed with nitrogen. Why ?
Answer:
To keep food items fresh and save from getting oxidised, food items are flushed with nitrogen.
20. Explain the following terms with one example each (a) Corrosion, (b) Rancidity.
Answer:
(a) Corrosion : It is the process in which metals are eaten up gradually by the action of air, moisture or a
chemical (such as an acid) on their surface.
Example: When iron is exposed to moist air for a long period of time, its surface acquires a coating of a
brown, flaky substance called rust. Rust is mainly hydrated iron (III) oxide [Fe2O3.xH20].
(b) Rancidity: The condition produced by aerial oxidation of fats and oils in foods marked by unpleasant
smell and taste is called rancidity.
Rancidity spoils the food materials prepared in fats and oils which have been kept for a considerable
time and makes them unfit for eating.
Rancidity can be prevented by adding anti-oxidants to foods containing fats and oils. It can also be
prevented by flushing fat and oil containing foods with nitrogen before sealing.
22. Write the balanced equation for the following chemical reactions.
(i) Hydrogen + Chlorine → Hydrogen chloride
(ii) Barium chloride + Aluminium sulphate → Barium sulphate + Aluminium chloride
(iii) Sodium + Water → Sodium hydroxide + Hydrogen
Answer:
(i) H2 + Cl2 → 2HCl
(ii) 3 BaCl2 + Al2(SO4)3 → BaSO4 + 2 AlCl3
(iii) 2Na + 2H2O → 2NaOH + H2↑
23. Write a balanced chemical equation with state symbols for the following reactions :
(i) Solutions of barium chloride and sodium sulphate in water react to give insoluble barium
sulphate and the solution of sodium chloride.
(ii) Sodium hydroxide solution (in water) reacts with hydrochloric acid solution (in water) to
produce sodium chloride solution and water.
Answer:
(i) BaCl2 (aq) + Na2SO4 (aq) → BaSO4(s) + 2NaCl (aq)
(ii) NaOH (aq) + HCl(aq) → NaCl(aq) + H2O(l)
25. Why is the amount of gas collected in one of the test tubes in text book Activity 1.7 (i.e.,
electrolysis of water) double of the amount collected in the other? Name this gas. [CBSE 2015
(Delhi)]
Answer:
In Activity 1.7, water is electrolysed to give H2 gas at one electrode and O2 gas at the other electrode.
2H2O(l) → 2H2(g) + O2(g)
Thus two molecules of water on electrolysis give two molecules of hydrogen gas and one molecule of
oxygen gas or in other words the amount of hydrogen gas collected would be double than that of oxygen
gas.
26. Why does the colour of copper sulphate solution change when an iron nail is dipped in it?
OR
An iron nail is dipped in the solution of copper sulphate for about 30 minutes. State the change in
colour observed. Give reason for the change. [CBSE 2015 (Delhi)]
Answer:
When an iron nail is dipped in copper sulphate solution, the displacement reaction takes place. The
colour of copper sulphate solution fades due to the formation of light green solution of iron sulphate.
27. Give an example of a double displacement reaction other than the one given in Activity 1.10
(NCERT Text Book).
Answer:
Sodium hydroxide and hydrochloric acid react to form sodium chloride and water.
28. Identify the substances that are oxidised and the substances which are reduced in the following
reactions.
(i) 4Na(s) + O2 (g) → 2Na2O(s)
(ii) CuO (s) + H2(g) → Cu (s) + H2O(l)
Answer:
(i) Substances oxidized is Na as it gains oxygen and oxygen is reduced.
(ii) Substances reduced is Cu as hydrogen is oxidised as it gains oxygen.
3. Which of the following statements about the given reaction are correct?
3Fe (s) + 4H2O (g) → Fe3O4 (s) + 4 H2 (g)
(i) Iron metal is getting oxidized
(ii) Water is getting reduced
(iii) Water is acting as reducing agent
(iv) Water is acting as oxidizing agent
(a) (i), (zi) and (iii)
(b) (in) and (iv)
(c) (i), (ii) and (iv)
(d) (ii) and (iv)
8. Give the ratio in which hydrogen and oxygen are present in water by volume.
(a) 1:2
(b) 1:1
(c) 2:1
(d) 1:8
11. A substance ‘X’ is used in white-washing and is obtained by heating limestone in the absence of air.
Identify ‘X’.
(a) CaOCl2
(b) Ca (OH)2
(c) CaO
(d) CaCO3
14. In the double displacement reaction between aqueous potassium iodide and aqueous lead nitrate, a
yellow precipitate of lead iodide is formed. While performing the activity if lead nitrate is not available,
which of the following can be used in place of lead nitrate?
(a) Lead sulphate (insoluble)
(b) Lead acetate
(c) Ammonium nitrate
(d) Potassium sulphate
15. What type of chemical reactions take place when electricity is passed through water?
(a) Displacement
(b) Combination
(c) Decomposition
(d) Double displacement
Explaination:
18. The condition produced by aerial oxidation of fats and oils in foods marked by unpleasant smell and
taste is called:
(a) antioxidation
(b) reduction
(c) rancidity
(d) corrosion
19. Electrolysis of water is a decomposition reaction. The mole ratio of hydrogen and oxygen gases
liberated during electrolysis of water is:
(a) 1 : 1
(b) 2:1
(c) 4:1
(d) 1:2
20. When S02 gas is passed through saturated solution of H2S, which of the following reaction occurs?
(a) SO2 + 2H2S → 2H20 + 3S
(b) SO2 + 2H2S → H20 + 3S
(c)SO2 + H2S → H2O + S
(d) SO2 + H2O → SO3 + H2
ANSWERS:
1. Reduction
2.Combination
3.skeletal
4.Exothermic
5.Endothermic
6.Displacement
7.Double displacement
8.Insoluble
9.Loss
10.Decomposition reaction
11.Oxidation
12.CaO(s) and CO2 (g)