Class XI Session 2024-25 Subject - Chemistry Sample Question Paper - 2 Time Allowed: 3 hours General Instructions: 1. There are 33 questions in this question paper with intemal choice. 2, SECTION A consists of 16 multiple-choice questions carrying 1 mark each. 3, SECTION B consists of 5 very short answer questions carrying 2 marks each. 4, SECTION C consists of 7 short answer questions carrying 3 marks each. 5, SECTION D consists of 2 case-based questions carrying 4 marks each, 6, SECTION E consists of 3 long answer questions carrying 5 marks each, 7. All questions are compulsory. 8, The use of log tables and calculators is not allowed Section A 1. The number of moles of solute present in 1 kg of a solvent is called t a) Molarity (M) ») ppm ©) Normality( N ) 4) Molality (m) 2. Photoelectric effect established that light ir} a) behaves like particles ») behaves like magnetic fields ©) behaves like waves @) behaves like rays 3. Calculate the enthalpy change on freezing of 1.0 mol of water at 10.0°C to the ice at -10.0°C. AjsH=6.03k) [1 mol "at 0°C. a. CplH)0()] = 75.3 Jmol"! b. CplH0(6)] = 36.8 Jmol ®) AH = -5.231 Kimo! >) AH =-7.151 kJ molt ©) AH=-6.114kImol" ©) AH=-7.415k) mol 4, Find the energy of the photons which correspond to light of frequency 3 x 10'S Hz (Hint: h = Planck’s constant [1 = 6.626 x 10% Js)? @) 2.988 x 10185 >) 0.988 x 10785 ©) 1.308 x 10°18) ) 1,988 x 1078) 5. What will be the value of logarithm of equilibrium constant Ky if the standard free energy change of a reaction is [1] Page 1 of 14uy, 12, 13. AG? = -115 ki at 298 K will be a) 13.83 ») 2015, 9) 20:5 4) 2.303, Lines in the hydrogen spectrum which appear in the infrared region of the electromagnetic Spectrum, then they are called as a) Balmer series ) Hydrogen line series ©) Hydrogen series 4) Paschen series Dalda is prepared from oils by. a) hydrolysis, ») reduction ©) distillation ¢) oxidation Which solution is used for the separation of a mixture of phenol and aromatic carboxylic acid? a) NagCO3 b) NaHCOs ©) NaOH ) CaO An aqeous solution of compound A gives ethane on electrolysis. The compound A i a) Sodium propionate ) Sodium acetate ©) Sodium ethoxide 4) Ethyl acetate ‘The elements charecterised by the filling of 4 forbitals, are: a) Alkali metals ») Alkaline earth metals ©) Lanthanoids 4) Transition elements Given No(g) + 3H2(g) + NH3(g); A,-H® = -92.4 kJ mol", What is the standard enthalpy of formation of NH3 Bas? a) -41.3 kJ mol! ) -46.2 kJ mol! ©) -56.5 kJ mol ) -36.9 kJ molt In the following sequence of reactions, the alkene is converted to compound B Oy , 0.20 CHsCH = CHCH; 3A" B ‘The compound B- is? a) CHsCH,CHO b) CHyCHO ©) CHyCOCH 6) CHyCH,COCH, Assertion (A): Components of a mixture of red and blue inks can be separated by distributing the components between stationary and mobile phases in paper chromatography. Reason (R): The coloured components of inks migrate at different rates because paper selectively retains different components according to the difference in their partition between the two phases. a) Both A and R are true and R is the correct. —_b) Both A and R are true but R is not the explanation of A. correct explanation of A. ©) Ais true but R is false. 4) Ais false but R is true. Page 2 of 14 i a uy uy tu) a i a15. 16. 18, 19, 20. 21 22. 23, Assertion (A): Trans-2-butene on reaction with Bra gives a meso-2,3-dibromobutane. ry Reason (R): The reaction involves the syn-addition of bromine. a) Both A and R are true and Ris the correct —_b) Both A and R are true but R is not the explanation of A. correct explanation of A. ©) Ais true but R is false. 6) Ais false but R is true. Assertion (A): In the dissociation of PCs at constantp ressure and temperature, addition of helium at WW equilibrium increases the dissociation of PCs, Reason (R): Helium reacts with Clz and hence shifts the equilibrium in forward direction, a) Both A and R are true and R is the correct b) Both A and R are true but R is not the explanation of A. correct explanation of A. ©) Ais tue but R is false, 4) Ais false but R is true. Assertion (A): In 285em there are 3 Reason (R): Zero preceding to first non-zero digit are not significant. nificant figures. WW a) Both A and R are true and Ris the comect. —_b) Both A and R are true but R is not the explanation of A. correct explanation of A, ©) Ais tue but Ris false. @) Ais false but R is true. Section B Classify the following species into Lewis acids and Lewis bases and show how these act as Lewis acid/base: [21 OH bE cH 4. BCh; How does the reactivity of non-metals changes in a period and group? RI Calculate: Mass of 2.5 gram atoms of magnesium, RI Complete the following reactions: RI ske.KOH HBr i. Isopropyl bromide ———> A. ——+ cond itso, POP KE ii, n-Propyl alcohol > A ——> B aK Hest OR Define resonance energy. What is resonance energy of benzene? ‘The uncertainty in the position of a moving bullet of mass 10 g is Ax mAw= 2. Calculate the uncertainty in its [2] velocity? Section Explain the structure of the CO» molecule. 131 ‘Answer: BI (a) At298 K, Ky for the reaction NoO4(g) = 2NO2(g) is 0.98. Predict whether the reaction is itt spontaneous or not. © a Page 3 of 1424, 25. 26. 27. 28. 29. 30. (©) State Hess's law. ty) Give the relationship between AU and AH for gases. BI Justify that the following reactions are redox reactions: BI i, CuO + Ho(g) —+ Cu(s) + H20(g) ii, Fe03(s) + 3CO(g) —+ 2Fe(s) + 3CO2(g) |. 4BCla(g) + 3LIAIH4(s) —+ 2ByHe(g) + 3LICK(s) + 3 AICI(s) A photon of wavelength 4 x 10-7 m strikes on the metal surface, the work function of metal being 2.13 eV. (3) Calculate i. the energy of the photon (eV), ii, the kinetic energy of emission, iii. the velocity of the photoelectron. (1 eV = 1.6020 x 10°!9 J). How would you explain the fact that the first ionization enthalpy of sodium is lower than that of magnesium but [3] its second ionization enthalpy is higher than that of magnesium? Describe what you need to do in the laboratory to test, re ithe law of conservation of mass, i. the law of definite proportion il, the law of multiple proportions. Section D Read the following text carefully and answer the questions that follow: (4) Once an organic compound is extracted from a natural source or synthesised in the laboratory, iti essential to purify it. Various methods used for the purification of organic compounds are based on the nature of the compound and the impurity present in it. Finally, the purity of a compound is ascertained by determining its ‘melting or boiling point. This is one of the most commonly used techniques for the purification of solid organic compounds. In crystallisation Impurities, which impart colour to the solution are removed by adsorbing over activated charcoal. In distillation Liquids having different boiling points vaporise at different temperatures. The vapours are cooled and the liquids so formed are collected separately. Steam Distillation is applied to separate substances which are steam volatile and are immiscible with water. Distill jon under reduced pressure: This method is used to purify liquids having very high boiling points. 4. Which method can be used to separate two compounds with different solubilities in a solvent? ii, Distillation method is used to separate which type of substance? ine from aniline water mixture? iii, Which technique is used to separate or Why chloroform and aniline are easily separated by the technique of distillation? Read the following text carefully and answer the questions that follow: 14) Covalent molecules formed by heteroatoms bound to have some ionic character. The ionic characteris due to shifting ofthe electron pair towards A or B in the molecule AB. Hence, atoms acquire small and equal charge but opposite in sign. Such a bond which has some ionic characteris described as a polar covalent bond. Polar covalent molecules can exhibit a dipole moment. The dipole moment is equal to the product of charge separation, q and the bond length, d for the bond. The unit of dipole moment is Debye. One Debye is equal to 10° esu em, ‘The dipole moment is a vector quantity. It has both magnitude and direction. Hence, the dipole moment of Page 4 of 14ai. 32. molecules depends upon the relative orientation of the bond dipole, but not the polarity of bonds alone. The symmetrical structure shows a zero dipole moment. Thus, a dipole moment help to predict the geometry of the molecules. Dipole moment values can be used to distinguish between cis- and trans-isomers; ortho-, meta- and para-forms of a substance, etc. The percentage of ionic character of a bond can be calculated by the application of the following formula: Experimental value dipole moment ‘Theoretical value of dipole moment vont Qn Qs omni man a cr cl ii. A diatomic molecule has a dipole moment of 1.2D. If the bond length is 1.0 x 10cm, what fraction of % ionic character = x 100 charge does exist on each atom? (1) il, The dipole moment of NF3 is very much less that of NH3. Why? (2) OR A covalent molecule, x-y, is found to have a dipole moment of 1.5 x 1029 cm and a bond length 150 pm. ‘What will be the percentage of ionic character of the bond? (2) Section E Attempt any five of the following: 51 (a) What is hydrogenation? tl (b)__ Why do the C—C bonds rather than C—H bonds break during cracking of alkanes? tu (©) Which conformation of ethane is more stable? ir (@ What happens when 2-bromobutane is being treated with KOH (alcoholic)? tl (e) Identify the structure of A and B; tl KOH Kolbe's electroysis CH, — CH,COOH —+ A———"$. B Kor Kobe's electrolysis CHs ~ CH,COOH —+ CH;CH,COO-K* > CHyCH,CH2CHy » B (How will you separate propene from propyne? fy (g) Why is t-butyl bromide more reactive towards Sy reaction as compared to n-butyl bromide? 1 On the basis of Le Chatelier principle explain how temperature and pressure can be adjusted to increase the yield [5] of ammonia in the following reaction: N2(g) + 3H2(g) =2NH3() AH =-92.38 kimol" What will be the effect of the addition of argon to the above reaction mixture at constant volume? OR Determine the degree of ionization and pH of a 0.05M of ammonia solution. The fonization constant of ammonia can be taken from table given below. Base Kp Dimethylamine, (CH3))NH 5.4 x 104 Triethylamine, (C2H5)3N 645 x 10° Ammonia, NH3 or NH,OH 1.77 x 105 Page 5 of 14Quinine, (A plant product) 110 x 10° Pyridine, CsHsN 177 x 109 Aniline, CgHsNHy 4.27 x 10-710 Urea, CO (NH2)2 13 x 10-4 Also, calculate the ionization constant of the conjugate acid of ammonia. 33. Answer: ts} (@) i, An organic liquid decomposes below its boiling point. How will you purify it? Rs] [Name three types of chromatography? [251 OR i. Whats the relationship between the members of following pairs of structures? Arethey [2.5] structural or geometrical isomers or resonance contributors? ae eee? Oe Np ae ili, H- C -OH H- ct -OH ii, A sample of 0.50 g of an organic compound was treated according to Kjeldahl's method. The [2.5] ammonia evolved was absorbed in 50 mL of 0.5 M HSOq, The residual acid required 60 mL of 0.5 M solution of NaOH for neutralisation. Find the percentage composition of nitrogen in the compound, Page 6 of 14