UTTHAN BATCH

JEE (Main + Adv.) Division

Chemistry
CPS - 2
MOLE CONCEPT

Motion Education, 394 - Rajeev Gandhi Nagar, Kota-5 (Raj.)

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 UTTHAN BATCH - CPS
[ JEE ADVANCED ]

[STRAIGHT OBJECTIVE TYPE]

Q.1 to Q.4 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct
1. A rock contains 1.02% Al2O3 and 1.80% SiO2 (by mass). Apart from free SiO2, some SiO2 in the
rock is present as kaolin (Al2O3.2SiO2). All Al2O3 in the rock is present as Kaolin. The mass
percentage of free SiO2 in the rock is (Al = 27, Si=28)
(A) 1.2% (B) 0.6% (C) 1.8% (D) 0.8%

2. Copper reacts with HNO3 to produce Cu(NO3)2, N2O(g) and H2O. In what volume of 0.45 M-HNO3 solution,
sufficient copper should be added to produce 73.89 ml N2O (g) at 27°C and 114 cm Hg ? Assume no any
other reaction occurring.
(A) 100 ml (B) 80 ml (C) 125 ml (D) 200 ml

3. The odour of skunk is caused by chemical compounds called thiols(C4H10S). These can be deodorized
by reaction with household bleach (NaOCl) according to following unbalanced reaction:
C4H10S + NaOCl (aq)  C8H18S2 + NaCl(aq) + H2O(aq)
How many gram of thiol can be deodorized by 74.5 gm of NaOCl.
(A) 90 gm (B) 45 gm (C) 180 gm (D) 22.5 gm

4. 9 gm aluminum is added in 100 ml of HCl solution of density 1.1 gm/ml, by which a gas of
density 0.1 gm/litre is evolved. If after sufficient time, the mass of solution left is 118 gm, then
the volume of gas evolved is :
(A) 1 litre (B) 10 litre (C) 0.1 litre (D) 10 ml

[MULTIPLE OBJECTIVE TYPE]

Q.5 to Q.8 has four choices (A), (B), (C), (D) out of which ONE OR MORE THAN ONE is correct.
5. 400 ml of a sample of coal gas containing 40% H2(g), 35% CH4(g), 15% CO(g) and 10% C2H2(g)
was mixed with 2500 ml of air containing 20% oxygen by volume and exploded and resulting
solution is cooled. Then after explosion -
(A) Volume of final mixture is 2290 mL (B) Volume of CH4(g) is 160 mL
(C) Volume of H2(g) is 140 mL (D) Volume of O2(g) left is10 mL

6. 100 gm of oleum sample (labelled as 109%) is mixed with 200 gm of oleum sample (labelled as
104.5%). Select the correct statement(s) for new oleum sample :
(A) Oleum labelling is 106%.
(B) mass of SO3 in final mixture is 80 gm.
(C) mole of NaOH required for complete neutralisation of new mixture is 2/3.
(D) (A) and (B) both

7. A 200 ml mixture of CO & CO2 is passed through excess of red hot charcoal causing the following
reaction.
CO2(g) + C(s)  2CO(g).
After passing the gas through charcoal, volume increased to 270 ml. Select the correct
statement(s).
(A) Volume percentage of CO in the original mixture is 65%.
(B) If original mixture was passed through KOH solution volume would have reduced to 70 ml.
(C) Mole fraction of CO2 in the original mixture will be 0.35.
(D) Minimum moles of red hot charcoal required for complete conversion of CO2 should be 70
millimoles.

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 UTTHAN BATCH - CPS
8. Which of the following molarity of KMnO4 solution can produce atleast 1 gm each of CO2 and
water when 2 litre of KMnO4 reacts with excess of oxalic acid.
2KMnO4 + 5H2C2O4 + 3H2SO4  2MnSO4 + K2SO4+ 10 CO2 + 8 H2O

1 1 1 1
(A) M (B) M (C) M (D) M
18 160 80 96

[COMPREHENSION TYPE]
Q.9 to Q.14 are based upon a paragraph. Each questions has four choice (A), (B), (C), (D) out of which
ONLY ONE is correct
Paragraph for question nos. 9 to 11

50 litre of a gaseous mixture having mass ratio 1 : 2 : 2 of C2H4, CO & N2 gas respectively is
taken in an eudiometer tube. This mixture is exploded with 60 litre O2 and after explosion
resulting gaseous mixture cooled to initial conditions of temperature & pressure.

9. Volume contraction will be

(A) 20 litre (B) 30 litre (C) 25 litre (D) 10 litre

10. Total volume of final gaseous mixture after passing the above obtained resulting gaseous mixture
through KOH solution is
(A) 30 litre (B) 10 litre (C) 15 litre (D) 40 litre

11. Average molecular mass of original gaseous mixture is

(A) 16 (B) 24 (C) 28 (D) None of these

Paragraph for question nos. 12 to 14

Two different formulaes are used in order to represent composition of any molecule, Empirical
formula & molecular formula. While the former gives an idea of relative ratio of number of atoms,
latter gives the exact number of atoms in the molecule. Based on this info answer the questions
that follows.

12. 4.6 gm of an organic compound on complete combustion gave 8.8 gm of CO2(g) & 5.4 gm of H2O(g)
only & no other products . What will be the empirical formula of the organic compound?
(A) CH3 (B) C2H2O (C) CH2O (D) CH2

13. An organic compound contains C, H, N & O. The number of oxygen atom is same as that of
nitrogen atom which is one third of number of carbon atoms & number of hydrogen atoms is
approximately 2.33 times of carbon atoms. If vapour density of the compound is 73 then molecular
formula of the compound will be
(A) C3H7NO (B) C2H5NO (C) C6H14N2O2 (D) C5H12N3O2

14. A 62 gm sample of a substance consist of 2 gm hydrogen, 28 gm nitrogen & remaining oxygen.

What will be its empirical formula?
(A) HNO2 (B) HNO (C) HNO3 (D) HNO4

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 UTTHAN BATCH - CPS

[ MATCH THE COLUMN TYPE ]

Q.15 to Q.17 has matching list. The codes of list have choices (A), (B), (C) & (D) out of which Only one
is correct

15. 10 ml sample of H2SO4 solution (sp. gr. of solution = 1.47) is treated with 10 gm impure KI
solution. The final mixture is neutralised by 20ml of 8 % (w/v) NaOH solution for left H2SO4.
The liberated I2 is divided into two parts

Evolved I2

Part - I Part - II

Passed through 20 ml Na2S2O3 solution Passed through excess KCl

yielded 0.3 g NaI Gives 0.497 g of Cl2

Reactions :
8KI + 5H2SO4  4K2SO4 + 4I2 + H2S + 4H2O
H2SO4 + 2NaOH  Na2SO4 + 2H2O
I2 + 2Na2S2O3  2NaI + Na2S4O6
I2 + 2KCl  2KI + Cl2

Column I Column II

(A) M Na 2S2O3 (P) 26.56

(B) % (w/W) of H2SO4 (Q) 0.1

(C) % purity of KI (R) 0.008

(D) Total moles of I2 evolved (S) 20

Select the correct option
(A) (A)Q, (B) S, (C) P, (D) R (B) (A)P, (B) Q, (C) P, (D) R
(C) (A)Q, (B) P, (C) R, (D) S (D) (A)Q, (B) R, (C) S, (D) R

16. Match the column:

Column I Column II

wt. of H 2SO 4 finally 3

(A) 50 gm of “109 % oleum” (P)  or 4
wt. of SO 3 finally 2
(B) 100 gm of “109 % oleum” + 4.5 gm H2O (Q) 20 gm SO3 in the final solution

(C) 25 gm of “118 % oleum” (R) Final % labelling 104.5%

(D) 200 gm of “104.5% oleum” (S) 80 gm H2SO4 per 100 gm

oleum solution finally
Select the correct option
(A) (A) P, Q (B) R, (C) R, (D) P, S (B) (A) P, R, S (B) S, (C) S, (D) R, S
(C) (A) P, Q (B) Q, (C) Q, (D) P, R, S (D) (A) P, Q, R (B) P, (C) P, (D) R, S

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 UTTHAN BATCH - CPS
17. Column I ColumnII
(A) "33.6 V" H2O2 solution (P) % w/W = 50
(dsolution = 0.21 gm / ml)

(B) Solution prepared by adding (Q) Mole fraction of solute = 0.33

116 gm H2O to 80 gm
"122.5 %" oleum sample

(C) 9.8 w/v % aqueous solution (R) 10.2 m

of H3PO4
(dsolution = 0.196 gm/ml)
(S) 1000 gm solution contains
5.1 moles of solute
Select the correct option
(A) (A) P (B) P,Q,S (C) P,R,S (B) (A) S (B) P,R,Q,S (C) R,S
(C) (A) R (B) P,Q,S (C) P,S (D) (A) Q (B) P,R,S (C) P,R,S

[NUMERICAL VALUE TYPE]

Q.18 to Q.25 are NUMERICAL VALUE Questions. (whose answer may be Single digit, Multiple digit & decimal
number)
18. Calculate the volume of a 20% (w/w) HCl solution of density 2.5 gm/ml required to prepare 363
gm of AsCl3 according to the following equations.
2KMnO4 + 16 HCl  2KCl + 2MnCl2 + 5Cl2 + 8H2O
2As + 3Cl2  2AsCl3
Given that the yield of Ist and IInd reaction are 60% and 80% respectively and sufficient amount
of "As" and KMnO4 is present. [As = 75, Cl = 35.5]

19. A mixture containing N2 and H2 in 1 : 3 by mole is partially converted into NH3. The NH3 formed
is completely neutralized by 200 ml of 2.5 M H3PO4. Calculate the vapour density of first mixture
(containing N2, H2 and NH3) if NH3 is not consumed in II reaction.

20. The vapours of organic compound was burnt in oxygen. Equal volume of both gaseous substance
were taken at same pressure and temperature. After the reaction, the system was returned to
the original condition and it turn out that its volume has not changed. The product of combustion
contain 50% CO2 (g) and 50% H2O (g) by volume and no other gas. Find the molecular weight of
organic compound (in gram/mol) in question.

21. The aluminium in a 0.4 gm impure sample was precipitated with 8-hydroxyquinoline and the ppt.

was filtered and dissolved in acid. To this solution 50.00 ml of 0.05 M BrO3 and 2.38 gm of KBr
(which produces Br2) was added. After reaction of Br2 with 8-hydroxyquinoline, excess of I¯ was
added to the resultant solution, which reacts with unreacted Br2 and the liberated I2 reacts
completely with 50 ml of 0.1 M Na2S2O3. Calculate the % of Al2O3 in the sample if all Al is present
in Al2O3 form.
The relevent balanced reactions are :

(HOQL) = 8-hydroxyquinoline

Al3+ +  Al(HOQL)3 + 3H+ ....(1)

Ppt.


Al(HOQL)3 H Al3  3HOQL ....(2)
ppt

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 UTTHAN BATCH - CPS

BrO 3  5Br   6 H   3Br2  3H 2O ....(3)

....(4)

Br2  2I –  2Br   I 2 ....(5)

I 2  2 Na 2S2O3  Na 2S4O6  2 NaI ....(6)

22. A 3.92 gm sample of fertilizer contained nitrogen as (NH4)2SO4. It was analysed for nitrogen by
heating with NaOH. The ammonia was collected in 100 ml of 0.4 M HCl. The excess HCl required
40 ml of 0.3 M NaOH for complete neutralisation. What is the percentage of nitrogen in the
fertilizer ?

23. Two element X and Y form compounds X2Y3 and XY2O3 (when combined with O2). If 0.15 mole of
X2Y3 weighs 15.9 gm and 0.15 mole of XY2O3 weighs 16.5 gm find the atomic weights of X & Y.
Represents your answer as abcd, where "ab" represent atomic weight of X and "cd" represent
atomic weight of Y. Suppose your answer is 24 & 9 then the same must be filled in OMR sheet as
2409.00

24. Once Tom & Jerry entered a chemistry lab where a chemist was preparing 3 l H2SO4 solution. He
labelled the solution as 10 m (dsolution = 3.3 gm/ml). As the chemist left the lab, a mischief
came in Tom's mind. He tried to throw the solution on Jerry but failed. In doing so some of the
H2SO4 solution fell on the floor, so he added water to make it again to 3 l. The chemist returned
back & got astonished when he saw the result of analysis, that were d = 1.5 gm/ml and % w/
w = 98. Find out the moles of H2SO4 which fell down on the floor.

25. A mixture of sodium chloride (NaCl) and anhydrous sodium carbonate (Na2CO3) has a mole ratio
2 : 1. It is dissolved in water and treated with BaCl2 solution. The mass of BaCO3 precipitated is
98.5 gm. Calculate the mass (in gm) of NaCl in the mixture.

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