INTEGER TYPE

44. What should be the ratio of the velocities of CH4 and O2 molecules so that they are associated with de Broglie
waves of equal wavelengths?
CH4 O2
[JC06 (D)]
Ans. (2)
Sol. According to de Broglie equation
For methane (CH4),
h
 CH 4 
m CH 4  CH 4
For oxygen (O2),
h
O2 
m O 2  O 2
Since the wavelength of CH4 and O2 should be equal,
 CH4   O2

h h
or 
m CH 4  CH 4 m O 2  O 2

m CH 4  CH 4  m O 2  O 2

CH 4 m O2 32
or   2
O 2 m CH 4 16

36 In a hydrogen like sample, ions are in a particular excited state, if electrons make transition upto 1st excited state,
then it produces maximum 15 different types of spectral lines. If electron make transition from given excited
state to ground state then calculate total number spectral line present in visible region.
1st
15
(visible region)
[JC06 (M)]
Ans. (5)
n  n  1
Sol. = 15
2
 n = 5
 n–2=5
 n=7
no.ofspectral linesin visibleregion is
7  2, 6  2, 5  2, 4  2, 3  2

40. Wave number of a spectral line for a given transition is x cm–1 for He+, then its value for Be3+ (isoelectronic of
He+) for same transition is a × x cm–1 then what is the value of a ? :
He+ x cm–1 Be3+ (He+
) a × x cm–1 a ?
[JC06 (E)]
Ans. (4)
Sol. (Theoratical)
37. The wave function of the atomic orbital of an H–like species is given as
1
 2s  Z1 / 2 (2  Zr)e  Zr / 2
4 2
The radius for nodal surface for He+ ion in Å is
[JC06 (M)]
Ans. (1)
Sol. At nodal surface, 2 value must be equal to zero. By equating 2 = 0 we will get the expression as (2 – Zr) = 0.
2 2
r   1Å
Z 2

64. Orbital angular momentum of 3s orbitals will be .......

[JC06 (E)]
Ans. (0)

65. How many Balmer lines in the spectrum will be observed when electrons return from 7th shell to 2nd shell ?
[JC06 (E)]
Ans. (5)

66. Principal quantum number of the shell to which the g–subshell first arise is .......
[JC06 (E)]
Ans. (5)

31. The electrons in a sample of gaseous Li2+ ions which are initially present in a particular excited state makes
a transition to a lower level. The emitted photons are absorbed by a sample of H-atoms which are present
in their ground state. This sample of H-atoms on de excitation gives maximum 6 different types of spectral
lines. Find the quantum number of initial excited state of Li2+ ions.
Fill your answer as sum of digits (excluding decimal places) till you get the single digit answer.
[JC06 (D)]
Ans. (3)

34. Ionization energy of H-atom is 13.6 eV. If H-atom are in the ground state is excited by monochromatic light
of energy 12.1 eV then the total number of different spectral lines emitted according to Bohr's theory will be.
H- 13.6 eV H- 12.1 eV

[JC06 (D)]
Ans. (3)
Sol. By absorbing 12.1 eV, electrons will be excited to n = 3
On returning maximum 3 lines can be obtained.

41. No. of visible lines when an electron returns from 5th orbit to ground state in H spectrum :
[JC06 (M)]
Ans. 3
Sol. Visible lines  Balmer series (52, 42, 32). So, 3 lines.

15. Photon having energy equivalent to the binding energy of 4th state of He+ ion is used to eject an electron from
 the metal with K.E. 2eV. If electron is further accelerated through the potential difference of 4V then the
minimum value of de–Broglie wavelength associated with the electron is :
(h = 6.6 x 10–34 J-s, me = 9.1 x 10–31 kg, 1 eV = 1.6 x 10–19J)
He+
2eV 4V

(h = 6.6 x 10–34 J-s, me = 9.1 x 10–31 kg, 1 eV = 1.6 x 10–19J)

[JC06 (M)]
Ans. (5)
Sol. Final kinetic energy of electron, KEf = 2 + 4 = 6 eV.

150 150
 = = = 5 Å.
KE 6

59. Very large number of H–atoms exist in 3rd excited state. Find out maximum number of spectral lines obtained
when they return back to ground state.
[JC06 (E)]
Ans. (6)
(n i  n f  1)(n i  n f )
Sol. N
2
63. The velocity of electron in a certain Bohr’s orbit of hydrogen atom bears in the ratio 1 : 275 to the velocity of
light. The quantum number (n) of the orbit is
[JC06 (E)]
Ans. (2)
2.188  10 6 3  10 8
Sol. Velocity of e– = 
n 275
n=2

64. In a single hydrogen atom, the electron is excited to its 6th orbit. The maximum no. of distinct lines possible,
when it comes to the ground state is .............
[JC06 (E)]
Ans. (5)
Sol. No. of spectral lines = 5.

66. The visible spectral lines for transition of hydrogen electron in a sample of hydrogen atoms from 5th excited
state to ground state will be–
[JC06 (E)]

Ans. (4)
Sol. Visible or Balmer line = n2 – 2
=6–2=4

68. The radius of the orbit in hydrogen atom is 0.8464 nm. The velocity of electron in this orbit is 547×10x m/sec.
The value of ‘x’ will be
[JC06 (E)]
Ans. (3)
Sol. Radius of orbit rn = 0.529 × n2 = 0.8464 × 10
n=4
2.188  10 6
Velocity of e– = m / s = 547×103 m/sec  x = 3
n
40. A transition metal complex shows a magnetic moment of 5.9 B.M. at room temperature. The number of
unpaired electrons on the metal is:
[JC06 (E)]
Ans. (5)
Sol. Magnetic moment = n(n  2)B.M.

17. The wave function  of 2s – orbital is given by

1/2
1  1   r   r / 2a 0
 2s    2   e
2 2  a 0   a0 
At r = r0, radial node is formed. Calculate the value of (r0/ a0)
[JC06 (M)]
Ans. (2)
2
Sol. At r = r0  2s  0
r
It is possible only when 2  0
a0
 r0 = 2a0

39. Difference between nth and (n + 1)th Bohrs radius of H atom is equal to its (n - 1)th Bohrs radius. The value of
nis:
[JC06 (E)]
Ans. (4)

33. Calculate the wavelength of a rested electron (in Å) after it absorbs a photon of wavelength 9 nm.
[Given h = 6 × 10–34 J-sec , m = 9 × 10–31 kg].
[JC06 (E)]
Ans. (1)
hc
Sol. E =

h h
= 
2m.KE 2mC
6 10 3  9  10 9
= 31 8
 1010  1Å
2  9 10  3 10
42. A compound of vanadium has a magentic moment 1.73 BM. Give number of unpaired electrons in vanadium
ion.
[JC06 (E)]
Ans. (1)
Sol. Number of unpiared electron are given by
Magnetic moment = [n(n  2)] B.M.
where n is number of unpaired electrons
or 1.73 = [n(n  2)] or 1.73 × 1.73 = n2 + 2n
 n=1
Now Vanadium atom must have one unpaired electron and thus its configuration is
4+ 2 2 6 2 6 1
23V : 1s , 2s 2p , 3s 3p 3d

43. The number of unpaired electrons in carbon atom is -

[JC06 (E)]
Ans. (2)
Sol. 1s22s22p2

44. Give total spin for d6 configuration.

[JC06 (E)]
Ans. (2)
1
Sol. 4 2
2

33. The ionisation potential of a hydrogen like species is 36 volt. What is the value of excitation energy from
ground state to 1st excited state. (in eV)
[JC06 (E)]
Ans. (5)
(I.P.)
Sol. E = –
n2
 1 8
E = I.P.  1   = I.P. × = 32 eV
 9 9

38. A certain metal when illuminated alternatively by light of 1 = 155 nm and 2 = 310 nm emit photoelectrons of
maximum kinetic energies in the ratio 5 : 1. The work function of the metal in eV is
[Take hc = 1240 eV nm]
[JC06 (E)]
Ans. (3)
1240
Sol.    (Kmax )1
155
1240
   (Kmax )2
310
We know
Kmax1
5
Kmax 2
 = 3 eV.

65. The number of revolution of an electron in the second bond orbit of H–atom in one second is 8.18 × 102x.
Find x.
[JC06 (D)]
Ans. (7)
V2
Sol. Revolution per sec. = 2 r
2

2.19  10 8 m / sec
= 2  8.18  10 14
2
2  3.14  0.53  2

38. How many of the following elements has / have fully filled penultimate shell in their ground state
Na, Pd, He, Ar, Cu, Kr, F
[JC06 (M)]
Ans. (5)

36. Wavelength of radio waves is 124 nm. Total number of photons per second produced by a source that consumes
energy at the rate of 16W is x × 1019. The value of x is -
 [ J C 0 6
(M)]
Ans. (1)

38. How many elements are possible for the I period of periodic table if azimuthal quantum number can have
integral values from 0 to (n + 1). [n = shell number & other rules are remaning same to form periodic table.
[JC06 (M)]
Ans. (8)

39. Consider Bohr's theory for hydrogen atom. The magnitude of angular momentum, orbit radius and veloc-
ity of the electron in nth energy state in a hydrogen atom are  , r & v respectively. Find out the value of '
x', if (vr) is directly proportional to nx.
[JC06 (E)]
Ans. (2)

65. If the diameter of two different nuclei are in the ratio 2:1 then their mass number are in the ratio :
[JC06 (M)]
Ans. (8)
Sol. Radius of nucleus is given by
r = r0 (A)1/3
where A is the mass number.
15 2–
66. Calculate the number of neutrons in 8
O

[JC06 (E)]
Ans. (7)
Sol. number of neutrons = mass no. – atomic no.
= 15 – 8
= 7

58. The number of correct statement(s) among. The given statements is–

2 1 1
(i) Wave number ( ) for first line transition in Lymen series = RH Z  2  2 
1 2

(ii) Ionization energy of H-like species = 13.6 ev × Z2 .

(iii) Energy required for first excitation = 10.2 evZ2 of H–like species
(iv) Bohr explained the dual nature of electron.
(v) de-broglie wave length is also called threshold wavelength
9
(vi) 4 Be and 59 B are mirror isobars to each other.
235 231
(vii) 92 U and 90 Th are isodiaphers
th
(viii) H-atoms in 5 excited state. The number of spectral lines belonging to Balmer series of emission spectrum
is4
(ix) Circumference of spherical path of electron (2r) = n where n = No. photons.
[JC06 (M)]
Ans. (6)
Sol. 2r = n (where n = No of wave = No. of shell)
de Broglie explain the dual nature of electron
threshold wave length is related with photocathode metal while.

60. In a hydrogen like sample an electron make transition from n = 6 to 3rd excited state then find total number of
emitted photons.
[JC06 (M)]
Ans. (3)
 n(n  1) 2
Sol.  (2  1)  3
2 2
33. In a single hydrogen atom, the electron is excited to its 6th orbit. The maximum no. of distinct lines possible,
when it comes to the ground state is .............
[JC06 (M)]
Ans. (5)
Sol. No. of spectral lines = 5

36. The visible spectral lines for transition of hydrogen electron in a sample of hydrogen atoms from 6th excited
state to ground state will be–
Ans. (5)
[JC06 (E)]
Sol. Visible or Balmer line = n2 – 2
=7–2=5
38. The radius of the orbit in hydrogen atom is 0.8464 nm. The velocity of electron in this orbit is 547×10x m/sec.
The value of ‘x’ will be
[JC06 (M)]
Ans. (3)
Sol. Radius of orbit rn = 0.529 × n2 = 0.8464 × 10
n=4
2.188  10 6
Velocity of e– = m /s
n
= 547×103 m/sec  x = 3

40. In a sample of hydrogen atom in ground state electrons make transition from ground state to a particular excited
state where path length is five times de-broglie wavelength, electrons make back transition to the ground state
producing all possible photons. If photon having 3rd highest energy of this sample can be used to excite the
electron in a particular excited state of Li2+ atom then find the final excited state of Li2+ atom.

Li2+ Li2+

[JC06 (M)]
Ans. (9)
Sol. Since electron goes the state where the path length is 5 times de-broglie wavelength.
 2r = 5
2r
also =  n = 5
n
Hence electron goes to the 5th state.
3rd highest energy line will be 3  1
If this photon is used for Li+2 then

 1  1 1 
 
13.6  1   = 13.6 × Z2  n2 n2 
32   1 2 
 39
Hence final excited state = 9.

35. A hydrogen like species with atomic number 'Z' is in an excited state and emits photons of energy
25.7 and 8.7 eV when makes a transition to 1st and 2nd excited state respectively. Calculate value
of'Z':
'Z' 1st 2nd
25.7 8.7 eV 'Z' :
[JC06 (M)]
Ans. (3)

36. No. of visible lines when an electron returns from 5th orbit to ground state in H spectrum :

JC06 (E)
Ans. (3)
Sol. Visible lines  Balmer series (5  2, 4  2, 3  2). So, 3 lines.

37. In a sample of H-atom electrons make transition from 5th excited state to ground state, producing all possible
types of photons, then number of lines in infrared region are
H- 5th

JC06 (E)
Ans. (6)
6(6 – 1)
Sol. infrared lines = total lines – visible lines – UV lines = – 4 – 5 = 15 – 9 = 6.
2
(visible lines = 4 62, 52, 42, 32) (UV lines = 5 61, 51, 41, 31, 21)

12. An orbital having double dumpbell shape of an unielectronic specie is represented as

)
3/2 
1  1  
 (r)    .2 (  1)(  2)(  6)e 2

16 4  a 0 
2r
where   and a0 represents Bohr’s radius. Calculate sum of angular & spherical nodes.
a0

2r
 , a0
a0
[JC06 (M)]
Ans. (5)
Sol. From (r) 3 radial nodes 7 also the orbital is d ( 2)
 Total nodes = n –  – 1 +  = n – 1 = 5
 = 2 & n –  – 1  n = 6.

14. Calculate maximum number of different spectral lines which can be observed if a sample of H atom containing
3 H atoms consists of electrons in 4th excited state.

[JC06 (M)]
Ans. (7)

Sol.

4 lines 2 lines 1 line

Maximum 7 lines can be obtained by any other combination also.

34. Standing wave in a string 35 cm long has a total of six nodes including ends. Hence wavelength is
35 cm
 2 4 6 [Standing wave]
1 3 5

[Give your answer as sum of digits and fill OMR sheet]

[JC06 (M)]
Ans. (5)
Sol. Number of waves
35
2.5 

  14 cm

35. An electron of He+ is excited to fourth excited state from ground state. Assuming two He+ in the sample. What
will be maximum number of different spectral lines when it returns to ground state.
He+ He+

[JC06 (D)]
Ans. (6)

5
1 5
4
2
Sol. 3
3 6
2
4
1
2nd He+
First He+

31. Number of visible lines when an electron returns from 5th orbit to ground state in H–spectrum is.......
[JC06 (E)]
Ans. (3)

32. The number de Broglie waves made by a Bohr electron in an orbit of maximum magnetic quantum number 3
is........
[JC06 (M)]
Ans. (4)

36. The de Broglie wavelength of an electron in a certain orbit of hydrogen atom is 13.3 Å. So the number of waves
presentinanorbitis .............
[JC06 (M)]
Ans. (4)
Sol. If  is de Broglie’s wavelength and n is principal quantum number,
n   2 rn  2   0.529  n 2
  = 2 × 0.529 × n
 n=4

37. In a single isolated hydrogen atom, the electron is excited to its 6th orbit. The maximum no. of distinct lines
possible, when it comes to the ground state is .............
[JC06 (E)]
Ans. (5)
Sol. No. of spectral lines = 5.

39. Ionisation potential of hydrogen atom is 13.6 eV. Hydrogen atom in the ground state are excited by
monochromatic light of energy 12.1 eV. The spectral lines emitted by hydrogen according to Bohr’s theory will
be:
Sol. The electron in H–atom is excited to III shell after absorbing 12.1 eV; because
13.6
E 3  E1   13.6  12.1
9
Thus, possible transitions are (3–1) = 2 = 2+ 1 = 3

40. The amount of energy required to remove the electron from a Li2+ ion in its ground state is how many times
greater than the amount of energy required to remove the electron from an H–atom in its ground state ?
[JC06 (E)]
Ans. (9)

19. A H-like species emitted a photon corresponding to the limiting line of Lyman series. The photon liberated a
photoelectron from He+ in ground state. The kinetic energy of the emitted electron is 68 ev. The atomic number
of H-likespecie is.
JC06 (E)
Ans. (3)
Sol. 13.6×4 + 68 = 13.6 ×9

16. Photons of equal energy were allowed to strike on two different gas samples. H-atoms in one sample is in some
excited state with a principal quantum number ‘n’ and H-atoms in other sample is in ground state. The photonic
beams totally ionise the H-atoms in both samples. If the difference in the kinetic energy of the ejected electrons
in the two different cases is 10.2 eV. Then the principal quantum number ‘n’ of the excited state is
JC06 (D)
Ans. (2)
Sol. The energy difference between two principal energy levels will be equal to the difference between kinetic energies
of the ejected electrons. E1 – E2 = 10.2ev.

13. A single electron system has Ionisation energy 11808 KJ mol–1. Find the number of protons in the nucleus of the
system.
11808 KJ mol–1
JC06 (D)
Ans. (3)
Sol. IE = 1312  Z2 kJ / mol
11808  1312  Z2 kJ / mol
Z=3

15. Ionisation potential of hydrogen atom is 13.6 eV. Hydrogen atom in the ground state are excited by
monochromatic light of energy 12.1 eV. The maximum number of spectral lines emitted by hydrogen according
to Bohr’s theory will be:
13.6 eV H 12.1 eV

JC06 (D)
Ans. (3)
Sol. The electron in H–atom is excited to III shell after absorbing 12.1 eV ; because,
13.6
E 3  E1   13.6  12.1
9
Thus, possible transitions are (3 – 1) : 2 = 2 + 1 = 3.

17. The velocity of an electrons in a certain Bohr’s orbit of H-atom bears the ratio 1 : 275 to the velocity of light.
Then find the quantum number (n) of the orbit.
H- 1 : 275 (n)

JC06 (M)
Ans. (2)
C 3  10 10
Sol. ve =  = 1.09 × 108 cm/s.
275 275
 2 e 2
Now, vn =
nh

2 e 2 2  3.14  (4.803  10 10 )2

n=  =2
vnh 1.09  10 8  6.625  10 27

35 A current of 3.7A is passed for 6hrs. between Ni electrodes in 0.5L of 2M solution of Ni(NO3)2.
What will be the molarity of solution at the end of electrolysis?
JC26 (E)
Ans. (2)
Sol. With Ni electrode, cathode reaction, Ni2+ + 2e–  Ni, Anode reaction, Ni  Ni2+ + 2e
No. Change in molarity of solution.

36. The reduction potential of hydrogen electrode when placed in a buffer solution is found to be – 0.413V. The pH of
thebufferis-
JC26 (M)
Ans. (7)
1 0.414
Sol. – 0.413 = 0 – 0 .059 log 
or = – log H+ = pH or pH = 7
[H ] 0.059

36. An electron of He+ is excited to fourth excited state from ground state. Assuming two He+ in the sample. What
will be maximum number of spectral lines when it returns to ground state.
He+ He+

[JC06 (M)]
Ans. (6)

5
1 5
4
2
Sol. 3
3 6
2
4
1
2nd He+
First He+

18. Find out the number of waves made by Bohr electron in one complete revolution in its 3rd orbit.
[JC06 (E)]
Ans. (3)

64. The radius of electron in 2nd excited state for hydrogen like species is equal to the first Bohr radius of hydrogen.
Find atomic number of hydrogen like species :
[JC06 (M)]
Ans. (9)

32
Sol. 0.529 Å   0.529 Å
z
z=9

65. When 4f level is completely filled with electrons, the next electron will enter into a subshell whose (n + l) is equal
to.....
 [JC06 (E)]
Ans. (7)
Sol. The next electron will enter into 5d subshell whose (n + l) will be equal to 7 (seven).

69. If there are three atom of hydrogen in the sample. Find the maximum number of spectral line when electron de-
excited from second excited state to ground state.
3

[JC06 (M)]
Ans. (3)
Sol. Consider maximum lines for each atom. Then two atoms gives maximum times and more than 2 atomic gives
same no. of times.
37. When a metal is exposed with light of wavelength , the maximum kinetic energy of electron
produced was found to be 2 eV. When the same metal was exposed with light of wavelength /2,
the maximum kinetic energy of elelctron produced was 6 eV. What is the value of work function
of metal in eV.
[JC06 (M)]
Ans. 2
hc
Sol. 2 =  ........(i)

2hc
6=  ........(ii)

Solving :  = 2eV Ans.

13.6  48 eV
31. By a sample of ground state atomic hydrogen, UV light of energy is absorbed. How many
49 quanta
different wavelengths will be observed in Balmer region of hydrogen spectrum ?
[JC06 (M)]
Ans. (5)

7
6
5
4
Sol.
3
2 Balmer
1

38. ' particle' of 3.6 MeV are fired towards nucleus ZA X, at point of closest separation distance between ' particle'
and 'X' is 1.6 × 10–14m. Calculate atomic number of 'X'
[Given : 1/4 = 9 × 109 in S.I. units]
Fill your answer as sum of digits (excluding decimal places) till you get the single digit answer.
[JC06 (M)]
Ans. (2)

(9  109 )(z)(2)(1.6 1019 ) 2

Sol. 3.6 × 1.6 × 10–13 =
1.6 1014
 Z = 20

39. For a hypothetical atom find out the total number of electrons that are filled in between 9s and 9p subshells
 1 1
if spin quantum numbers have   , 0,   , three values.
 2 2
Fill your answer as sum of digits (excluding decimal places) till you get the single digit answer.
[JC06 (M)]
Ans. (9)
Sol. 9s 6g, 7f, 8d, 9p
Total number of orbitals filled = 5 + 7 + 9 = 21
Total number of electrons filled = 21 × 3 = 63
Ans. 6 + 3 = 9
33. An electron having initial kinetic energy 2 eV is placed in an electric field of potential 4V. Calculate
de-Broglie wavelength of electron in Å.
[JC06 (E)]
Ans. 5

K.E.final = K.E.inital + K.E.due to field

= 2eV + 4eV = 6eV

So effective potential = 6V

150 150
 =  =5Å
v 6

36. Find the total number of electrons in ground state configuration of Zn which have any
 = any positive integral value
m = any non zero value
1
s=+ only
2
[JC06 (E)]
Ans. 8
36. How many of the following species are hydrogenic species which is valid for Bohr’s atomic model ?
(i) Li2+ (ii)He (iii)Be+ (iv) Be3+
(v) B 4+ (vi) B+ (vii) B3+ (viii) C4+
(ix) He + (x) Na +10

[JC06 (E)]
Ans. (5)
Sol. Li2+, Be3+, B4+, He+, Na+10 are single electron species.

67. Electrons in a sample of H  atoms make transitions from state n = x. to some lower excited state. The
emmission spectrum from the sample is found to contain only the lines belonging to a particular series. If one of
3
the photons had an energy of 0.6375 eV. Then find the value of ×. [Take 0.6375 eV = × 0.85eV]
4
 [JC06 (E)]
Ans. (8)
Sol. We have
3
E   0.85eV
4
As energy = 0.6375 the photon will belong to bracket series (as for bracket 0.31  E  0.85)
 1  1 1
0.85 ×  1    13.6  2  2 
4 4 n

1  13.6   4  
2

0.85  1    1 
   
4 16   n  

4 1
  n8
n 2
Hence x = 8.
rd
58. Find out the number of waves made by a Bohr electron in one complete revolution in its 3 orbit.
[JC06 (E)]
Ans. (3)
hr hr
Sol. From Bohr model mvr  mv 
2 2 r

h h 2 r
De broglie wavelength    
mv nh n

2 r 2  r
 number of waves made in one revolution = 
2 r
= n = Orbit number = 3.

n

60. Two bulbs A and B are emitting monochromatic light of wavelength such that A can just ionise H atoms & B
+
can just ionise He ions. If the power of A & B are 30 W & 40 W repsectively. Calculate the ratio of number of
photons emitted per second by bulb A to bulb B ?
[Give your answer as sum of digits and fill OMR sheet]
[JC06 (E)]
Ans. (3)
Sol. A  30 W EA (photon) = 13.6 eV
2
B  40 W EB (photon) = 13.6 0 × 2 = 4 × 13.6 eV
–19
For A (13.6 × 1.6 × 10 ) × nA = 30
–19
For B (4 × 13.6 × 1.6 × 10 ) × nB = 40
nA 3

nB 4 × 4

nA 3
 
nB 1

h
36. The orbital angular momentum of an electron in 4f orbital is k 2  3 . 2 , value of k is ………. :
[JC06 (E)]
Ans. (2)
eh
Sol. For f orbital  value is 3 and orbital angular momentum is = (  1). .
4 mc

38. Maximum number of spectral lines possible when an electron jumps from 5th excited state to ground state in
a sample containing only one hydrogen atom will be–
 [JC06 (E)]

Ans. (5)

th
Sol. 6 —5 Excited state
5
4
3
2
1 — Ground state

k
39. Number of lines formed in a hydrogen spectra when an electron jumps from n = 6 to n = 2 is k. Then is:
5
[JC06 (E)]
Ans. (2)
(n 2  n 1 )(n 2  n 1  1)
Sol. Number of lines = .
2

21. The velocity of an electrons in a certain Bohr’s orbit of H-atom bears the ratio 1 : 275 to the velocity of light.
Then find the quantum number (n) of the orbit.
[JC06 (E)]
Ans. (2)
C 3  10 10
Sol. ve =  = 1.09 × 108 cm/s.
275 275
2 e 2
Now, vn =
nh
2 e 2 2  3.14  (4.803  10 10 )2
n=  =2
vnh 1.09  10 8  6.625  10 27

25. When an electron jumps from 4th energy level to ground state in a hydrogen like atom, six different photons can
be observed. What is the minimum number of hydrogen atoms a sample should have to obtain all the 6 different
types of photons in its emission spectrum ?
[JC06 (E)]
Ans. (4)
n= 4
Sol. n= 3
n= 2
n= 1
No. of atoms required = 4

27. Maximum number of different spectral lines which will be obtained in visible region when a sample containing
large number of H atoms have atoms in 2nd, 3rd & 5th excited state only.
[JC06 (E)]
Ans. (4)
Sol. 5th excited state means 6
Possibletransitioninvisible regions
=6–2
 = 5–2
= 4–2
= 3–2
= 4

33. Calculate change in potential energy (in eV) when an electron move from ground state to third excited state in
He+.
Fill your answer as sum of digits (excluding decimal places) till you get the single digit answer.
[JC06 (E)]
Ans. (3)

15. The total number of nodes of an orbital with n = 4, l = 1, m = 0 is 9/x what is the value of x …………. :
[JC06 (E)]
Ans. (3)
Sol. 4p orbital has two radial and one angular node.

66. When 4f level is completely filled with electrons, the next electron will enter into a subshell whose (n + l) is equal
to.....
[JC06 (M)]
Ans. (7)
Sol. The next electron will enter into 5d subshell whose (n + l) will be equal to 7 (seven).