XI_IIT-IC/IR Date: 03-02-2025

Time: 3:00 hrs. CTA – 05 Max. Marks:180

JEE-ADVANCE 2022 P-2 MODEL

KEY SHEET

PHYSICS
1 2 3 4 5 6 7 8 9
4 8 8 2 8 2 2 4 ABCD
10 11 12 13 14 15 16 17 18

ABC BC AD BC ABCD B B A B

CHEMISTRY
19 20 21 22 23 24 25 26 27
3 5 5 1 3 4 5 1 CD
28 29 30 31 32 33 34 35 36

AD BD AC AC ACD B B A A

MATHEMATICS
37 38 39 40 41 42 43 44 45
1 7 4 6 6 4 4 7 ABD
46 47 48 49 50 51 52 53 54

BC AB ACD AD ABCD B C A B
Narayana IIT/NEET Academy CTA-05 XI_IIT_IC/IR_Adv_2022_P2_03-02-2025
SOLUTIONS
PHYSICS
1. (4)

Immediately after release

Consider the half rod BC, Its COM has a downward acceleration

FShear = Shear force applied by part AV on the part BC.

2. (8)

3. (8)
Initial pressure in both chambers = atmospheric pressure (P0)
Let initial volume of the left and right chambers be V1 and V2 respectively, and the area of cross
section of the cylinder be A.
For left chamber using PV = constant we get
P(V1 + 4A) = P0V1 ...(i)
4A is change in volume of the compartment.
Similarly for right chamber P(V2 + 6A) = P0V2 ...(ii)
Where P = final common pressure of the two chambers after the outer piston has been moved by
10 cm
(i) ÷ (ii) gives
V1  4 A V1 V 2
  4V2  6V1  1 
V2  6 A V2 V2 3
20
 If original distance of inner piston from the closed end is x1 then x1 =  2  8cm
5
After the outer piston is removed, the inner piston will come to equilibrium at its original location
only, because pressure will become equal to atmospheric pressure.
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Hence answer is 8 cm.

4. (2)
Let P1= initial pressure of the gas inside the tube
P0 = P1 + gh1 [h1 height of Hg column]
gho = P1 + gh1
P1 = g (h0 – h1)
Temperature of the gas is given by
PV  g  h0  h1  A  h0  h1 
T1  1 1   A  area of cross sec tion 
nR R
2

T1
h  h 
 0 1
 ga
R
After increasing the temperature, let the height of Hg column be h2
2

T2
h  h 
 0 2
 gA
R
 gA  2 2
T  T2  T1   h0  h2    h0  h1   ...(i )
R  
Let's calculate the work done by the gas in pushing the Hg column.
h2
W   PdV     h  h0  h  Adh
h1
 ve sign as dh is negative 
h2
  h0  h  2 
  gA  
 2  h 1

 gA  2 2 RT
  h0  h2    h0  h1     Using(i) 
2   2
First law of thermodynamics
Q  nCV T  W
3 RT
 RT   2 R T
2 2
5. (8)
The state of m1 = 1 g of ice is changed from solid to liquid. The heat absorbed in the melting
process is
Q2 = m1L.
The heat supplied is Q = 420 J. By energy conservation, Q = Q1 + Q2. Substitute Q1 and Q2 from
equations (1) and (2) to get
Q  m1 L 420  10  3.36  10 
3 5

m 
S T  2100  5
 8 103 kg  8 g
6. (2)
In a thermodynamics process, the heat supplied to the system, the increase in internal energy of
the system, and the work done by the system are related by the first law of thermodynamics,

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Q = AU + W.
The first law of thermodynamics for the process iaf gives
Qiaf = Uiaf + Wiaf = (Uf – Ui) + (Wia + Waf). (1)
Substitute Qiaf = 500 J, Ui = 100 J, Wia = 0 (constant volume), and Waf = 200 J in equation (1) to
get Up = 400 J.
In the process ib,
Qib = Uib + Wib = (Ub – Ui) + Wib- (2)
Substitute Ub = 200 J, Ui = 100 J, and Wib = 50 J in equation (2) to get Qib = 150 J.
In the process bf,
Qbf = Ubf + Wbf = (Uf - Ub) + Wbf. (3)
Substitute Uf = 400 J, Ub = 200 J and Wbf = 100 J in equation (3) to get Qb = 300 J. Thus,
Qbf/Qib= 300/150 = 2.
7. (2)
The acceleration due to gravity at the surface of a spherical planet of radius R and mass M is
given by 9o = GM/R2, where G is the universal gravitational constant. Let h be the maximum
height attained by the bullet of mass m when fired vertically upwards with a velocity v. The
acceleration due to gravity at a height h above the surface of the planet is given by g = GM/(R+
h)2.
Given, g = g0/4 i.e.,
GM/(R+ h)2 = ¼(GM/R2).
Solve to get h = R. At the maximum height, kinetic energy of the bullet becomes zero. Apply
conservation of energy between the initial and the final (maximum height) positions of the bullet
to get
-GMm/R+ ½mv2 = - GMm/(R+ h) + 0.
Substitute h = R and solve to get v? = GM/R. The escape velocity from the planet is given by
vesc = 2  GM / R   2v 2 v 2
8. (4)
Differentiate the expression E(t) = A2e-t at to get
dE = 2Ae-t dA – A2e-t dt. (1)
Divide equation (1) by E(t) and simplify to get
dE dA dA dt
2   dt  2  t  2
E A A t
The error in measurement of a parameter r is generally defined by
xactual  ameasured  x
where x is a small positive number representing measurement error. Let A and t be the
measurement errors (both positives) in A and t. From equation (2).
dE is maximum when dA = A and dt = -t. Thus,
the percentage relative error in E(t) is given by
E A t
2  t
E A t
2 1.25%    0.2  51.5%   4%
We encourage you to derive equation (2) by taking logarithm on both sides of E(t) = A2e-t and
then differentiating it.
9. (A, B, C, D)
Equilibrium of piston gives.
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kx0
PS  kx0 or P
S

PS kx0

Since, the chamber is thermally insulated Q = 0

 Elastic potential energy of spring = work done by gas
1
or work done by gas = kx 02
2
This work is done in the expense of internal energy of the gas.
1
Therefore, internal energy of the gas is decreased by kx 02 .
2
Internal energy of an ideal gas depends on its temperature only. Internal energy of the gas is
decreasing. Therefore, temperature of the gas will decrease.
10. (A, B, C)
V3
 constant,
T2
2V 2 RT
dV  dT , P  , W   PdV  400 R
3T V
U  nCV T  900R ,
Q  nC T and Q  U  W  1300R
Q 13
C  R
nT 6
11. (B, C)
Heat required to raise the temperature of ice from 00C to 1000C
= 10  80 + 10  1  100 = 1800 cal
heat given by steam when it converts into water at 1000C = 5  540 = 2700 cal
temperature of mixture is 1000C at thermal equilibrium
1800
amount of steam converted into water at 1000C by 1800 cal =  3.33 gms
540
12. (A, D)
900
H  rate of heat flow  …(1)
li l0

Ki A K 0 A
Hli
Now, 1000    …(2)
Ki A
 
 900  l 900
or   1000    i  1000 
l l
 i  0  Ki A l K
1 0 i
 K i A K 0 A  K 0 li
Now, we can see that  can be decreased by increasing thermal conductivity of outer layer ( K0 )
and thickness of inner layer li  .

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13. (B, C)
F.B.D. of ball in frame of container
4Vg
Y
Va 4Va
X
Vg
4Vg  Vg
ay   3g
V
L 1
 3gt 2
2 2
L
t 
3g
4Va  Va
ax =  3a
V
1
L  3at 2
2
2L
t 
3a
2L L
Ball to collide at point Q, t   a = 2g
3a 3g
14. (A, B, C, D)

l ml 2
J  
4 12
3J J
  , Vcm 
ml m
l l J
V A  Vcm    0 , Vupper  Vcm   
3 2 2m
l 5 J
Vlower  Vcm   
2 2m
15. (B)
FL FL
Y 2  l 2
r l r
l1  F1  L1  r22   F   L   4r 2 
     =     =1:1
l 2  F2  L2  r12   2 F   2 L   r 2 
or l1 = l2
RT
C
16. (B) M
V1 V2
For isobaric process, 
T1 T2

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V0 4V0
Hence   T2  4T1
T1 T2
C1 T C T0
From  1  0   C2  2C0
C2 T2 C2 4T0
17. (A) Q  W AB  WBC  WCA  U , ( U  0 for the complete cycle)
 10  103  1  WBC  0
 WBC  10 J
18. (B) If there is no heat current means temperature at both end of rod are equal and temperature at a
distance 60 cm from hot end of the rod is 500C

CHEMISTRY
19. (3)
20. (5)
21. (5)
22. (1)
23. (3)
24. (4)
25. (5)
26. (1)
27. (CD)
Steric inhibition to resonance of 0 – NO2 group lowers the acid strength. Introduction of three
nitro groups on the phenyl ring increases acidity of phenol greatly and it become even stronger
acid than benzoic acid.
28. (AD)
Unsymmetrical alkane like (A) and (D) cannot be obtained as sole product in Wurtz coupling
reaction.
29. (BD)
(A) NaBH4 cannot reduce a primary halide to alkane.
(B) LiAlH4 can reduce a primary alkyl halide to alkane.
(C) Tertiary alkyl halide on treatment with LiAlH4 gives alkene.
(D) Triphenyl tin hydride reduces all three types of alkyl halides (10, 20, and 30) to corresponding
alkane.
30. (AC)
Electron donating resonance effect of – OH and – OMe from para position increases basic
strength.
31. (AC)
Both are capable of showing geometrical isomerism through the methyl substituents in the
cyclopropyl ring. Simultaneously they are also chiral. “a” is chiral but does not show geometrical
isomerism.
32. (ACD)
 Geometrical isomers are stereoisomers.
 Butane – 2, 3 – diol has a meso form and a pair of enantiomers.
 Geometrical isomers are simultaneously diastereomer.

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33. (B)
Ester group has the highest priority hence ethyl benzoate. Chloro and ethyl are numbered
alphabetically because they are equidistant.
34. (B)
They are cis-trans isomers, therefore diastereomers.
35. (A)
Biphenyl with AB – AB substitution at ortho positions are chiral provided A and B are bulky
groups that sends the two phenyl rings in perpendicular planes.
36. (A)
Only cis and trans isomers at C – 2, 3 carbon.

MATHEMATICS
37. (1)
1 1 1 1
  
an 1 an ( an  1) an an  1
1 1 1
  
an  1 an an 1
1 1 1
S    2 also a101> 1
a1 a101 a101
 [S] = 1
38. (7)

39. (4)

40. 6

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41. 6

42. 4

43. 4

44. (7)

or n1 = 1, n2 = 2, n3 = 4, n4 = 5

n1 = 1, n2 = 2, n3 = 4, n4 = 6

45. (A, B, D)

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46. (B, C)

47. (A, B)

48. (A, C, D)

49. (A, D)

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50. (A, B, C, D)

51. (B)

52. (C)

53. (A)

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54. (B)

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