CHEMISTRY ' 2024

Af•t/.,_ &10,h1 ;'11

11.., All•ll'l'd: n,,,, """"
IC"""",u"" .,, olt.,...,, odddlo••I n 111l n•ln /Pt ot1lt ,,,.J/nt f/,, 1'"1"'·
~ -·••I Nor,,.,, "'""'t J.,,., 1h11 '""'·'
111;. ,,.,_., r, '"'"'' ,~," fi11o, ..., l~•n• - A, II, C •nd U
An~..,. •II 1p1o1..,_._
Sn.11°" -A"'""''',,,°"",.,.,,.,,, 11.!vl•r ,.,._,...,,,.,_-a"""·
6'cllo11 - n'"""•h ,1,,,, ,..,,1m,o Lf """ """" rack.
S,,1ton - C ....,,;,,, af ,n,,,, 8P'11"111• If llrrrr l!Wltt r«h, 1114
Strtlo,, - D '""'"''of,.,"1"""""•• uJ flw m.ub """·
°"' '1""'11""
,.,,,,,,., <lioict1 ·•~ i,,..,, l'fWUtd I• r,orll I• s,,111111 B,
StotUon - C81!J Sttlio. - ll M "'
llldtllling "111~J, 11\~k. ,1,o,,14 lot Jent on I/rt~,.. 11"'1 ,u, in.I ~ I III I/rt ml fl/ I •13 • •
TIii' inln11/rd .,.,b J,rr ~,.,,1.,,,_ ar part, I'/ ~im<l•lrU .,, gnnr In ~,.,~, I /,
tl/~•lu1n1 ,,.,,., /1, Kh~n ""'"'""' pr,,sib(t ,nd diilg,01111 ~-ltm lluy ,,,., lrdpfr,1.
Whrn $0/t'hfi 11•mm't.i/ prol'l,nu, Ill r!Mmlwl 1r,,rbn~ mu,1 !Jr •Mrim.
In -Un& Ill/I 11r,tbltm~ Mil Iii, fol!awuig J.i~ 1
OIIJ/""/ R• I .911 Cill dtg-1 111<>1, I • 8.JJ'I< /K·' ,_-1 • 0.0821 drnl •I•• 1,~1,,,.,-
11 •1•1 • l ,1,.,, """. JOJ.J I. J far""'1y. 96.SOO .-i,ulombs,
_ 1\""Sudro·, ~llmb,, • 6.02.J • JIJl.l,
0UES'fiONS
SECJlON /\ -14 MAltKS
Qu,.IIIG-1, IRl Dry ccll ca,,/., d,otgtd ca;ily,
ISi Grni•lrit; rod acls llS a c;,lluxlt in dr•y ,rd/.
WFUI hi tlrt l>IQnb by droosir,g tlr, n1111ta11rlott
(1\ 011/y <Pl awl CR) (cl Only rr) am! /SI
-"'"t,o,,, tlro11t giva, hdoto ;,, llit brnck,rs: M•lJ
/1114 . poir,oning. ..-,o, ph~sgr11r, dq1<11dc1111 cnna:r, (b) Only CQI ar.d /RI ldl Orlly (QI and (S)
1114tpt,rdm~ diellryT ctlrrr, firs/, el/tyl cqrbo,wtt, tlllt'l>t.1 Ii I) T/r, nrrM complt'.r Ion 1/u,t is pnr~m•sntlit L•:
Ill f o r • ~ ra1rlia11, IJ00-rultt;oJ t11IH011sla111 is (Alcmir """''"" ef Fe~ 26, C:i ~ 29, Cu• 27 and Ni= ZS>
0.05 Jte1• Tl1t rmc1ia11 is of_ordrr and wfll be M /fr(CN)4/Z· M INifCN4)P-
of 1h, i11iliul ro11cmlrarkm. (bl fCo(N/iJ)if• ldl /CufNHJJ+fl•
OD £DTAis ~d·irr /Ire lrealma,1 of___ u•lrilrCis (iii) 1v,r,... KM1104is ltt~kd mil/r acidified ora!ic ariil, gu,
p/Alln u11Std in 11,t trtalmmt of. • btrbbfrs ar, eooltoed. TTrcst gos bulM~-s arf ~'rlliYd due
011J 1'Tltaddilion ofsma,11 q11a11/ityofcllnmol lodtlorofi,rm to tlrc forma1ia11 of:
p,rmits I~ formalio,r of ___ a11d co1111t•rts ii (al S02 lei 503
into lilt hannf.rss CUln/N/Ulld _ __ Cbl C.::O2 (di 01
(ltl TIit dthydralion of tl/ryl altol,o/ w/l/1 t'011C. HzS04 (iv) TTie reaCl/011 of t.1/ian•mide n•ilh a/rulrvlic sodium
fJ Jf09C moiuly yields,___ u,11/lt al 170'€ /Ire /1ydroxitlc and l•rom/nt sli\'S;
moin product fom1''11 is._ __ (al rrliylnmlrw. (cl prop~l•min,.
111 Stl«t allll writt the amrct a/ttninlivt fra111 tire (b) 111t•lhyla111int. (d) a11ilille.
"-gi11t11 wltiw. 17"1] lv) Arr tq11l111olar S<il11/im1 of 11011-t,ulalilt S<IIUlts ii n11d
Ill Which ant of /lit folluu•ing slallrmc11/s is come/ 8 sltir.t,s adq>rtss/urr i·11 freai11g /1<1fol /11 /lit ••lio of
rrgardb,g Utt dry er/I? 2 : t. /f A rrm1ai1,s /11 ils 11orm,d ;tatol /n 1111 -~111111011 •
(P) Zinc w11l11i11l'r 11c/s ,rs an a11odc In dry c;/1, /lie slalt of B 111 1/;i, so/111/011 ~•ill be:
CQ) Zinc co1tlat11er 1oµcl1e$ 1/rr paste of MrrOz arid la) rrormal. lei '15.(()~rote,I.
C11rbo11. (b) lrydrol!Jsei/, (d) di;,<ccr.11,J.
 ..
" tit#,;
±ll
i:klfl• .,.........,. . . . .,...,o,,.,,,~-- •
.filf«-.
::ii. . . . . .
..
to .1 ;; ltlrW..,.._lt..,.,_
· • · - - pl;' Ill, /ltA -
. . ,1 .... .,..,..,._,,,,,.,_
-ti/IC; -(Qfl•.lllr1rlH11f I
Q::sntfws..
,,_.,,,,,..,,,,,.,...,. • • 5 .,
Ill '
fwlt 41 M Alll•J11a'4J/.-a,,t.rw..1N..._dtt CQ Bm.:w 1ow,i1ttia,r
I I fiiw lwl ..,,,.,,....,..,,,..,. & (II) lciolofoiiN .....,,._
ft em ~ II/ .a,r ""1Jda ,_,_ Qaatlan7. ~
MO I.MfJ.._Ollly. Olklllalt lltt mabam ,_a,,, d«frlal lllOl't dlialCIIJI lie
ea, Bollt AM»lfoN a4 RM!oH m lnlt _, ~ " obfa1Nti1Jn,,,, • phwn/e «JI llllliff itli""14 -dJl/o,i, ti
if dtt ""1'ld nq,/a,lilM fo, Nlllrlion. 298 IC.
lb) Boll, .4saorflm lfflll Rttson m 11W b111 ~ Zn 1z,,Z• IIAg' IAg
111 no111ttamm~Jor AJsmion. ,..,, ,-,,
(d AaaliClil io trw '"" Rmtin u ft,1#. Groen r!'rz,,>•,z,,1 • - fJ.76V; to('-¥" /Af)- • fl.BO V
(d) "-tion is fol# b i d ~ u tru~: Question 8.
(0 R~4 tire,.,_. p,n ~law •u .._ tlrr Cl) Givi:a m1B011/ortlldi o{llrfol/Dwmg.
121
,pntl- lbl falltnD. IS-11 W f.l/raxy rtJumr does /IOI mid u,id, sod/11111. 6u1
Whm rrro ""1111/ans ore srp,nltd '1y • ~mi-pmnt"'1/e tl/UUIOI don.
- ~ tht ,.,,nm,
maltc11lt11 - fmm • so/11l/mt of (bl [lhoxy tlluiiw wit/1 a,111:. HI at 37JK giV<S
roncniltalion to a solution of hightr ,,ro/;lr
lc,aw mo1,n c1R50M tnid CH,f /n,t-nol CH30H alrd C1Hy.
_...,,,,_,lo,,
lhrottfh - I s . OR
(l) Sama, 1tn10..wl /Ju, 01,ttr luml slrdl of 11W diffem,t Iii) An organic compound /Al l~ng 1nolen,l11r ftml'u/1
,.,,,.. whiJt cwl/in• at ho,r1t, Ht /J11t11 plawl ont ~.'KIi in fi ,ul {Bl with .rwltadar
•...,. ., ,., c,HwO onns a co~ Co ii -•
pun, uw/er and tht o!lttr tgg in Slduraltrl i:ol111JOt1 •1 farmula C H,O oxidation. mpc1un
011 181 gim
suai,se. Whal chan,gt is l1r likely In obs<!r:vc irt 11,r eggs a po•ilivt iodofont1 ltsL Tl,, reaction of mmpou11d
aftD frw l1ounl [IJ] ;,,it/, CIIJMgBr foJlov.Y!d by hydrolysis gil'l'S
(ii) Which solution, /1y/ltrto11/c or hypolaliic, luzs II hig/tfl compound (CJ will, mulerular formula C5H110,
amount ofsolute in !'<Jn., quantity ofsalulian? Identify 1,.,, n.,mpaunds ( Al, /Bl 1111d (CJ. Wrilt
(ill) A 5% 111jut()11s :;.,/uli11n ofglucose (molar mnss :--iso Ifie reaction for 11"' C'Mtmo11 of aimpound /Al to
g moJ-') ;5 isotonic u,it/1 1.66% aqurou~ solulum of conipout1J 181.
ura1. Calcu1a/c //le m11lar ma.-. of, urta. Question • 121
9
SECTION B -20 MARKS If lOO t!tl,J of 011 a,1,_11s sofulio11 of p prottfo c:u~rai11s
Question 2. 1.21 1-26g of /lrutci11, Ilk! osmolk pmsurr of tlit solub1111 at
(i) Wrllt u cTtanioal ltSI lo dl$ting11islr /lt•r.ot>'II ellumol 300K is fe u11d lo be 2.57 x lo-3 qlm.
and pl1c11oJ. . . Calculal, 11,, molar 11,n,s of prott'tll.
(ii) G~ a d11!111ical rillldio11 t<J amum nc<'-laldc),yde 11110 (R =0.0821 L aim K-1 mur-1)
sa:o1ulflTY propy/ !llcvliol. Qurstion 10. 121
121
Question 3. . (i) Bet1uildclryde is /1'$5 ,e,1ctfue 1/11111 propionalddrydt.
Givtt a rcastm for each of tlrt followwg: W1,yl
11 'der•d as d-block • ., • I
n Zit1c rad111ium a11d mercury are co sr ' (ii) 1,, tlw />rtparalillll ofctlumal by t/1t,md11t10'.10 ct,111,w,
1
i tdm,;•,1ts /Jul 1101 regarded ns lran~ilio11 da11t11/s. rtl,m,at should be ,a11on:·d immdiatdy as ,1 is fom1td.
(ii) Tro11silion me/a/s possess a gro/11 lr11de11cy lo fann WJ,y?
amrpltr a11111"'unds. I Question 11. (21
2
Que5hon• .._• 1 (I) WIiy is Mt1 •2 /011 more stoble tiia11 Fc' 2 ion ·1
C,,11vert lltt folluwitig /Jy giuiug d1c111ical rqun//011s for (Atomic n,unbcr of M11 = 25 a11d Fe-26)
t11clt.
 IS•ila - •
II
~
••••/if ,. S C

w CIIP'.!S!l.+tlJ~Jf",+/&
.,. GffpH~IIJ~l•I
IOI -tlCl
~'/JD•
--:~-Jrit~-,-'";~-~!l~.6!.,!•~l~ct"~ OR
~--t--ji'~---,.~~-+.JM~,!•_!!llt~l:.J (Ill GiR- • Ja;•iclll lttl ta '1ttinpi,li b,laWII ,,_
J 0.l! O.JO 1,92 • Jct-I fol""'1/ng ,-nofn,mpounb..
4 0.30 D.lO 7,611 • to-I (I) El1wlllol ..,,1 l/ltlhllno/
• -..,,,, dllJoll-i"I: lb) Slh,nol _, Elhitlull
~-,. r,,,(lf'tffil aN,rof/'hr ~ k) P,op,m-2-<JI •nd 2-11111/fJIp,of11111•2-ol
• f) f111_,_,,,...11on QQeaHon JI. 131
'8 11'1 r,/1/w ofr11t n111sl11J1t Ill TIit r& t:OMlanl ofII rtdcl,.,,, al SOOK anJ 700K 11tt
~ U. o.oz lltC"' an,/ (),01 __ , ~ - c:.la<Wt the
U---, U.""lt I~ follou.na 1n1t1..,,,. by Ill ...,,,,_.,, Er (,rcliwl/On ~trr,y)
I ,,.JW1tr1ttmtp/t j,r md, ........ g11,1,,, Ollt ' " ' A nidloactl11r suht~ whkh nnib idpllll p,uticlr
Ill em,pling rr•ctfon f:J//oQ jil'61 oriln rt«lion. '11le lu,lf-lifr pcriad of
jl,J ,4atyl111itm tftJlrylmrrint l1ti$ radioo.~ subsllllltt is 30 hours. c.Jadalt lhL
.n ,tn,li~ ;/ttCS nol glt,t Frj,d,I _ C,..,.s __ • . /nztlian in /!fflYJJI (%1 of tire radillflr.tlw sub,,to11a:
,..
•,_n.
......i1o111',
.,,. · -1·on. C.wc TP/lit'I: mruri•!~ r1f'tr!IQl1mtrfi.
SECTlO!lfD-1SMARKS
U--:: .. · ·• ,,,,. · · 131 Qur.ilion19 (51
,1 ,Ir~" IIISUS a p..3$tCIIIII 11$ sl,e Is st,fferi fro (i) •
9' ..,,.,..,. 1U1d JO. int •lnin 'Wltid fi t ng "' )In •r-ia cc>mpo11nd / ,'\}, h01>ino II cn.,-i"c smi'/1
, - - • pl ' , r• . . ' • -soIublt uita111in • -·· " -r·'"~"
,,_,.1,1 /nr iys1an1111rescnbe la her? . forms tuu campou1:dJ; IBJ and IC! by rtllCling will,
/ii s,,,,,eshp11tfawdropso/vincgnri!1 niillr.. W/ral .1 couc. ~,id/11111 hydruxuJ;,. Tiu, 11roltcUl11r formula of
_, yo11 1/ii11k /u, "'1scrvr.d in Utt milk:nfttr ~ ; 1•~ "-""l'•u11d (BJ is C7Hp. u,llidr forms campouttd /Al
\\11111 is I/ti~ phe11crme,10t1 lo,,,u,,, as? •me· agai,, on oxidation. Cmr,po,md lCl farms bmuru, 011
•1 I if I d I
_, htaling will: sodlt lime
liD /iJ4!II( .,tl pmullCO '!I ro '!,'$is of s11crosc; Is it a
«during s11gnr or a IUln•reducing sugar? Writt lht stn,1·111,,s·of compo1111ds /A). 181 and (C}.
Also, Write ,,,, rt:ld/0115 im~..:d.
~da11 t 5. • . . IJJ (II) ld1'ltli/y ti~ rnmpoumis IAl 1111d IBJ in ll1e read ions
~ 115 $Dl11/1011 C(t11l11111mg 12.50 g of /iqrium clr/urid,/ gii•ert btlow:
1
~~ gofuwltr boils nl 373.0834 K. Colculole 1/,e degtcr
;~lion of bari11111 cltloride. (a) C6B6 AIC~~;~y.J , /.Al Krc,)~'. R,SO, (BJ
.. r.
·~
...,
far H20 • 0.52
I
K kg mot'1; molern/ar ma$s ,l 1 lb) ,..,., /0/
i1:•2D8.34gmuJ- . Lr,rCHOH-CH3 Ki{?rO, +lli SO (Al
~• rn ~ }81
~ rrz,nic rompou11d C2H40 gives red prt,dpilate wlsm Qucslion 10. (SI
'iJld:.;/h Fehling so/111io11. (i) A coorcli,1Mio11 cumpou!ld h11s aformula CoC/J_4N/13.
iiio undergoes oldol cot1dl'llsafim1 i,1 the pn-srure of It 11rcci1•itptcs silt\'r iorts lis AgC1 and its molar
E'ml:~OH. co111iucta11ce mrrcspowls lo a to/a/ of two ions.
I /Jtntify lite orgn11ic compo1111d aud write its IUPAC Dased oit t/Jis /t1ftm11utfo11, a11SWL-r the fullowi11g
IWl'.t. q111JS1io11s.
i 1\7iich aompo1111d will be fomwd who11 I/sis organic la) Di!duce slruc/urnl fimnula of tlr£ complex
.mt1p11u11d m,cts wit/, hydroxy/amine? qJIIIJ)(IU/u/,

L
 •.., , •. ' ;:;,;
.. ·-.;~.;; .;;...;,·--;·;;·· .. -- .....sr
·•--·~-m ......r_...,.....,......_so......,...
"ttoalli...-:,~,;,;
•
....."'
Id Di 9 • J

Ql, r & ,kw.1c.i W

_, ICl l(N HJ l~ 1C1 a..
4
ftric,.t .._ ,, a/ * _, ,ir .
ht..., lltrtl ICofNH3l,C,ISO,
lllodwl.,,, __ ,,_
011
oa
Cal A 0.05 M NH40H IIOIMIIDII o/fin 11w ,_ _.
fl( J0.8 o/111111 lo • allld11dil>i
Qu" " " 2,1 . ly CIII 11 291&:
If 11v orfl ain,1.t11I ;. 11.143 cw,-
151 1 ....i _,
Ill lal s,"'1, ,,., Ji.g,.,m ~•' "' Mo w llwll
Cw ,¼ ,....,,,,,.itrmm1I r:ril
,.,,,,.,..If
,md •11.4Wl'F lht
('Olfduclollet of NH 40H 01
ill}bdl# . . . _
f7J .4 S cm2 mot· 1, colclllilk llw
qw ,,_ """ ,.,, ,_ ./blloluj-a:
( 1) Sp.cijit arruluc,.ncr
(2.) Mol,ir amductan,,
(3) Drg r« ef di.-"Ultion
(b) In flit diagnr,11 of tl~
tltt lro lyh c rd! f
l,daw, AB ond Care e,onnttltd
msnits
rkctro/~lei; of 7.nSO., AgNOJ
o"d CuS(j
rtllp«l111tly.
II Mtady aum nl of 1.5 A WUS
fl"m d until 1.4
g ofAg ttVS dq,ositl:d al lht ailh
odt of cdl B.

c~ ,, C.~c.'"te••-O.J37V; E0ug'iA,J
J • 0.799V
(I) Wn tc th, a,/1 renclio11 for I/rt
abovt cdl ,
(2) Calc111Dtr thr ~tqndard rnifaf
tht a ll.
(3) If the conc.·ntrntio11 of (C,il'J
is 0.l M
011d E,.,.11 is 0.422 V. at 25"C, calc
ulrrtt the
co11t,t11lralion of/ Ag ' J. 1"1
lCI
(4) 0,/c u/a lr AC for /lo, all (l\loruic ,,,.,,,. ofl\g = 108, L
. u •63.S, Zit •6S
Cb) Calculutt ,.~ for BaCl and
2 A/2'SO4)3 /rom II~ AIIS1M' tire followi ng qutslions.
f Pllnwmg dnla.
(1) How /011g did the cur rttr
For ,.om Br' : 127 2 5 , ,,,2 111ol 1 l Jlou•?
• ,.o
• "r AJ3• • 189 (2) W/i11l uir1ghl of Cu 1111d 211
Scnil mor1 tms ~rtt
cat/rode?
AN SW ER S
SECTION- A
Answer 1. !,Ourccs. 1lencc, I.he cell canno
t be reUSl!d
re ch a~ .
(Al (i) 6rst, depcndcnL
Ill) (di !Cu(NI J ) t1-
(ill lead poisoning, cancer 34
Expluation: Th e substance
(ijj ) phosgene, ethyl carbon s which h
ate unpaired electrons are called
(iv) diethyl eth er, etbene param,g111
while diamagnetic su~ ian
(8) 0) (c) Only (P) and ces have all ~
(S) electrons paired
Expl~n~tion: A dry cell contain [Fe(C'S) Jl-
s a container 4
made or rinc acting a5 I.he negativ 1. Assume IC is the oxidoh
e terminal i.e. on number or F,
anode and a carbon (graphite) given complex, the n
rod with a metal
cap acting as I.he positive term
inal i.e. cathode. IC+ 'i(-1) •- 2, IC- 4 • -2 , IC
A mixture or carbon particles •- 2 +~ • •
and ammonium Electronic configuration of Fe -
chloride ,s p~ nt between the (/\r ) 3d6-u2
positive and Fc+2 " lArl 3d6
negative 1erminals. Once the che
or the cell are exhausted , It stomic al con tents
ps producing
All electrons are paired, hence,
It is diamagr
electricity. These oontents are in nature lCo(NI l:i) ~;.
not regenerated
when electricity is supplied 2. Assume IC is the oxidation
from external number of C
given complex, then IC+ 6(0) • +
3, :x • + 3
 CHEMISTRY 2023
SEC TIO N A - 14 MARKS lcl """°"Ion,/ IO ,_ ..._ _. ,,,.,. ., lilr
0- ,..... 1. n111itf
crmcrnlnlllon
w rm"' ,., W. .lt i,, tbotfllr lk ,,.,.,.,,,ri,rr Cd) lndq,nlllnrl r,f the il1IIW l'IIIIMllfllllD
wolUW ,,_ ,,, _ git w In dit .,_.,,. n
, 11•11 ICI M,etc• lllt followlllfl 14-11
1,1"'1/r. '"'''· a/ulrJ,ilt. w.,,.,,,1,.6. 4. ,,,..,111. c ,-•, Ill p ~ Co) ~ + ,.,, ,_
2. l . ,.,,rm\)tli.· •"HI.l11glr. im,>t1nt , Rbt,r"mund
'd
(W EOTA !bl Globular /1'Dltfo
01 l'ht ,,, _, """"°''
ur .....,y oridistd {m l mlo
Olll /,lmholwllmr le) ktJJ lye
_ _ _ a,,J llitn '"to _ _ _
tiil Th< ,n/,.,.,,,tdlalr aflitwltd complrx
IM
1D)
l11s11 //11 (rJ) Huodaute u,-
in a dlnnlarl U1
rnl( I""' is h:,11hty _ _ _ due
lo _ _ _ ml'1',<zy,
.usmion: lf • solwlhm amlmns both W 12,,JI
ions, t/1t H' imll ut mlllCtfl jirsl ol ~ Ne•
ff'4
(Iii) n.,. """J/norimt ""mf,rr and oxidation slal t '-'f Iha Rr,is°": Cnlions u>/111 11/glwr c:• i,al~
mmrla: KJ l"rlCN )/ nrt _ _ _ and arr t"'-a,i
6 _ __ fi,-;1 . , n,t/tadt.
re,,..-rlln'1'y.
(a) Balli /\s.<trtion and R11H11t1
li•l ""1pom,,,,,.o. rr11r rim1u-/rh unccam an /rut 11111 "- '•
lllg•min pr<'$C11« l• I/it comet apl1111at/011 fa, .Am-rliow.
of ronc. 110 gim ___ a,wl 1/ie
reaction is (b) 80111 t\SStrlion a11d Rt4SIIII o,r
b1Pwn as _ _ _ m/u rlia11. lnrt, Ind R,,aso"
is 1101lht rorr« I apW1U1tian far AIMtion
IBJ ~lt rt 111td 1uri lt the cor rrc/ altr .
mnlivt fro" ' tJ,e (c) As.<nlio11 Is lrut bul Rz.w11
dio irn glr n lie/ow. i$ f:d,,t.
(d) A11SCrlion is felSt but Rcn.0:011
m The rtorthm of• pri"u,ry • mint with chlorofo 14•11 I.iii M Sl'rtion: Nldili,111 of bromlnt uiatt
is tr~.
rm m,d r lo l-ln,1,,.
,1/,01101/c KO H is c1ilk d: gft..s two Ofllical i.somm.
(a) a.,tiylamin t m irlio11 Rt uson: 11,~1110011clf11T11r,d con taiiis twoo
tsymlllthit
lb) Ko/br's mulion carf,on atoms.
Id Rt·imrr•Ticmann n•lldJon (a) &1/r A~i,r/ian anti r= n o,~ hilt , ,mil RL.1son
(di W11,t-Filli11.11 r,~ctlcm is I/re cam el expla11atio11 f,,,- As>i'rlion.
Iii) IVl,icli rnr. "f 1/ie fo//w.,irig sta11·111wts Is (bl Bolh ASStTl/011 mul Rntso11 arc /rue, but
1RUE for RtrlSOn
1hr G/1/mnic er/I? is 1101lht con td aplanalian far i\s;<
ction.
(c) Assi•rtion ls lrut bu t~ is fol$t.
~) Eledrons fJTJJ from copper rlcc
lrndc to zinc (d) Assetlion is fnl~c but R,•aso11 is trut.
d1,·/rodt
lb) C111rrrrt flows from : /11c drrtrod SECTION B - 20 MARKS
e to CV/'Jltl'
Questi on 2.
cltelri>dr 121
Cnlrulalc tire mass of •s,wbic acid (nrO
le) C.lions mot..- rir,nuds OO/'P'" rfa-lrod U'Clllar mass = lio
c g!mol) I/mt slro11l1f !,., dissolllt'd irr 155
(d) Ca1io11s mow luuvmts :inc tlrctrod g of autic 11tt l lo
t CaUSi a drpri!$.<ion offrrning poirrl by 1
(ljj) "7riclr 011eof tl,c f~llou•ing compou ,uls ·15 K. Assume //ul
asc~rbic acid do,s 1101 dissocia te or as,,,cia/
is dia111ug11cllc
and cv!o11rl.-ss? t In rite sol,,Ji• .
(K;Jor nc'Nic ncirl • 3·9 Kkg/11101)
la) K2Cr20 7 Id KA-1110 Qu nti on3.
4 [21
lbl z,,504 (d ) Cri /S0 / Git-.! a reason for 11:L fo/l0111irrg:
(i ~) 1 1
~or a fir,I ordu reaction, 1/r, lwlf-lift
l""'iod (f ) (i) cu• snits are 1,nrama$11rlic u,ltilt C11' ~ Is m
t<! 112 dirrmagudic.
(ii) Mn• 2ru111pou11dsart morcs/u
(a) praportio11al to tlrr imlinl
co11m1lratim 1
Qu rsli on 4.
r,·
lrlc t/rarr 1,~1111,w•und;.
lb) im-lyr,mporli.1nal lo tl,e itrilirr/ co11r 121
nrtra1/,111
Giv.•rlwmital cqualious for .-.:ch of lhc folw
~i ng:
 ........., ...t
.........
· - - - • • bAllJt-,
_____ .,.__
_,.

~
121
""'of""Jolloa,iar, sa:u~c-nMAN i,-il!
,_,,.,,,,111ntrr..,_.,,,_,,.,1,
if.~-
.....,.
Q...._u,
- of•J(nl-,,, _,,. ,. ~
,11aii lllrlliyl lllat/iol ,,_ llllldt Hmr 111111 flit 60%""""" , . ,, """""'
ht,...,. Ill

~ ,,./'f11,tfall-,wi,1g cr/111 298 k,

' C.la,i.,, I/le "'1µ/J,,,,,., tli,i'Jl1r
12) Q11fttion13.
11t,.,,,,.,.,,.
1.11
fl II AS' ro-oowl / Ag Wntt 1hr bolimml drtmkol .,UO. for lht ,,,_,,.,
,. ..dll
,,_ • o-34 V. £"A,•1.., • 0·80 V llllllt lrlllllion,; .
•~.tcf:.f.'rt111 C,nlltl Ill Son41/teytr'• m,cllan
~ ,,,,.,. 11ll Wurl.: l'fllalion
•._,. lht fellowing dirmical r N41li • 11) (Ill) l'lnkd,lrin mid/on
r ..,,J ._,,ct q ans. Qlle.tlon 14. 131
~ • +iizSO, +Kl - ~ - + - - U1 Give an mmplt e,ich of frlluclion 511F tlll4 non-
I t --
•---;--,+HtSO,+HzS--+ ___+ rtd11cing sugar,
J{JI + - - Ill) Whal l,i dtnalllfll//On ofpn,lrins7
' ,.,,..-- - - - IUO Give on •%11"'1'/t m/1 of 11w1tr sofuli~ lli/llJIIUI IIIUIfal
_.... I, (2) ~lllublt 11/lllmin.
r:~ J'in 11it fl'llnwi11g ltt obtained? (Gittt dtrmiral Queation ts. 13)
1,-.i· I II
~ rd Whw 2 g of ltemoic arid is d/s:;o111til ~ 25 g of bmunr.
Ill [I~ from Grigiui 's roige,il, sllOUIS adq,r155io11 in frtt:.i11g pciinl ~11111 to 1-62 K. Mol.ill
.i Ditlhy/ tllitr from 5lldium rllroxldc. dqlmsiM rotrstant (Kj of bt1iu11t is 4-9 K kg l!lfll"1 tmd
OR mol«u/11r l«lght ofbtiWJic rod• 122 glmol. Wlult IDl11 bt
a,p~ic coni~und [A} C2H;;(J, 011 heallrsg wfllc lht />crrtnlngt astllKialion of I~ benzoic ~?
f ~ HiS04 al 413 Kgit'eS a rrn,tral rompou 11d /BJ (/kr,u,/c add form; d&Mr 111/101 Jis.<alutil in brnwrt.)
CJ4,J), Compo1mJ IBl on ln-alr11en1 with PC/5 Question 16. 131
pH prod11tl, which 011 subt<f,/Uent lrealmrrrl will, Accniml far tire follouoing:
rtN yidh campound IC/ CiH,N. Cnmpol/J,a IC/ m Phenol is a strongu acid il"l!l afipltiltic alcohols.
111 hyllralysis gii't-s 011 pcid IDI C,1160 2• ldc11lify lire (ii) lillratrnl gi1¥s fodofatm rnrctio, whn-tJIS me/Mlwl
1
111111p,unds /Al, /BJ, [Cl and (D}. di,es uol·,iiut iudofi1rn1 ~ct ion.
jlllloa 9. 121 (iii) EJhm sfwr,ld nut lie distilled lodry11&.
~ ,._ pm;surt of blood at p"C is 8,21 aim. lloa, Question 17. (31
r , j ~ i• groms slio11/d ~c used per /fire uf aq11J!(lus (i) ldallify I/rt oomporuuls /AJ, (BJ and ICI In /ht
.,. fur an inlrairJrous i11jection so that ii is iS!Jlonfc fi>llau,;,, ,eact/ous:
.tllaN? /Moltrular wl. ofgl11cD1e • 180 glmol) 8
~nlO. Ill ta) CH,1COOH ~l IA/ a,,• KOH [Bl
~lJlllllic carltorylic acid IA/ wlrid, readily sublimes 011 CIICIJ • N~OH,-.i {Cl
l!ir, pmduces wmpo1111d /Bl on lrtnlrr1<·rtt wit/, 1'05, ,wu l!!'.O
-:.;wi..418/, wltcn reduced ill llieprcswcro[Pd catalyst ,:., J1 [Cl
lb) Cll,", Br~ (Al~ IBI u•.
• BaS01 poiso1,ed by sulpliur hi xylt11e so/1.r/011 sive.s OR
~ fCl. W/1e11 compound /Cl is cor,dc,ised ill the Iii) flow will flu following be co,rvr.rttd7 {Git\- dJoriall
~ofalcholic KCN, ii gives c,nnpormd lD/ (Mal,cu//JI' cqu41/o,i)
0
~• f C11mpou11d /Olis C14H1P2) (ai f,f/1yl bromidt 1ocllryl i,«y,r,tidt
~ lht C11mpou11ds (Al, IBJ, (Cl urrd IDJ. (b) Aul/in, to m, u11t d/,Jwni•m cllloriik

~
11
~ 1 11. 111 (c) Btrr:err, ditmmium drlDriik lo pJrmol
1toso" for eacl, of l/1e f0Uouri11g:
 ---- -
_,_______ .,__________ ··••10
·- ____ ·-··1·-·· -··• -•·· ··•• •·•· ••• • '"i:
--·•1h2
IIC ·-··
···· Q.a ...., 13 -,.- .
m40 _,,, ,. d (I) ~ ,r«l /k ~ tf ~5 • _. If ~
Qt,11111Dft II.
-A f""I _., _., .. "sow. ,_,.,,,.., «id It 5·25 • Jo-5 olmr ~ · ~ l a"""6c
,_., ..,., ,.
;
JIIO K ntl 11120111ht11tn d 320 IC. c.,.-.,m a,flll udio lly _, .,,. ,,,. ,__ ,_
.....
rnns y tf tlw- .:IM r.
GiWff A",,r1 • 30-5 ola,r"l CJIIZ IIIOl'"l 111111
S~CTION D -15 MARKS 1
151 A•mcoo-i • 5CJ-!, ahn.- mi' mo,-1
0-l loa lt.
tqu•tiona IO ilJus lNlt llv CU) Cak ui.tt the IDM ,. . lo lkpasit J·Z7 ,.,a,,.,
IVrilt llw d1nnkol d ~I
a,lho d, u,hm II a,m nl of 2 llfflf'• fs J'Gll
(II
jolhla,ug nntt ,_.,;.,u;
C•I Conni:um·• mk'lion thuolution of CuSO◄· &"
(b) uvz m,di m, (Awmic rmgl rt of Cu • 63·5 gmo1-I>
(d Aide/ n111drn."11ion OR
1111/J llw Jollmuing 1w "°'" '"'d1 tGm t chnlliall «Cl
CII) Hmv (l) The rcsislana of a amduclwity ctll Tllilh 0-1 M
rquall,111)
solution is 200 ohm. WIim lht lllmt c:eU {a fillef
(•) A«lald1o/rydt IO Kno M f
with 0·02 M NaQ solution, 1/w lfflll111«
(b) Fnrmaldthydr lo urolroplM
1100 ohm. If the cond uctivity of 0-1 M ~
(SJ ceQ
Qul'!lllon 20. sohil ion is 0·0129 ohm- I cm·l, c11/c11l11t lllt
N•1m: /lit ~ o/ismllMSln ahib ilhl by lht
jollCNJing udiv ity of 0-02 M NeQ
Cl) consl1111I and mou,r corld
puirs "Ic,,,,,,,.,.,,,45: solution.
Ca) {Ca<NH3Js[ONOJJC11 tmd {Co(NH3'5'N02
JJCJz v,
0 /a.2H zO (II) T11ec111/ (E",.11! of tht folluwing tl'llction if 0-89
Cb) {O<H1OJsCJX:,1HzOand /CrlHzOJ4 2 4 2 + 2c,1+
JSn • + 2C r-. JS11 •
(c) {Pt(NH3J4Cl2/Br 2 1111d /Pt(NH3)◄ 8r1 /02
Calculate tlw value of t.G for the rcaclion. Prr4itl
0

Wr(/c tlu- JUPAC Mm~ of lhL followi11g

complrxcs:
(HI
wl1rtl,er tire abm,e rcaclio11 will bt sponlanro~
s a,
(,1) J01(N H3J/ll2011/C13
1101.
(bl K2/Ni(CN4)/
ANS WE R S
tc
SECTION- A have unpa ired ell'Clrons and is not attracted
mag netic field . It is also colo urles s.
An• wer 1 .
(iv) (d) Inde pend ent of initia l concentration
alde hyde , carboxylic acid ot
Expl .anil ion: lntegTated rate law for a lirst
(A) (i)
(ii) unsl.ible, high reaction is
(ill) 6, + 2 2.30 a
Uv) prop ane, Clemmen..'l4!n's Redu ction k • - 1o g -
1 a- x
(8) Ci) (a) Carb ylam ine reac tion
e
Explination: The reaction of a prim ary amin For h all-life, t - 1112, :c • !!.
KOH 2
with chlo rofo rm (CHCl 3) and elha nolic
is
(pot assiu m hyd roxi de disso lved In etha
nol)
On subs titut ing the valu es,
caJJed the Carb ylam lne reac tion. k = 2.303 log ~
C6HsN111 + CH 03 +3KO H ➔ 1112 a- !!.
<;,ffsNC + 3KO + 3H20 2
elec trod e
Iii) (c) Cati on mov es towa rds copp er
k= 2.303 log 2. ~
E,cpl.uution: In a Galv anic celJ, elec tron s flow 1112
) to the '112
from the anod e (zinc elec trod e in this case
curr ent flow s 0.693
cath ode (cop per elec trod e), and
ode to or tl/2 • -k -
in the oppo site direction, fro m the cath
the anod e. Cations mov e tow ards the cath ode
(copper electrode) where reduction occurs.
(ill) (b) Zn.SO.
llxplualioa: 1.inc sulphate (UISOt) is
t#emlllMdc ~ mean1ng it c1oes not
Thus, half-life peri od (t1n) of a tint order
does not depend upon t h e ~
a (0 w. ... ..

61) EDTA
C<) Am d,-
(41) Ha oI 1 '
l
 , +JKCT+3Hz0
Ci, Comrlrfc ll~-r-t11dl11,r gillfn A~tit.
(b) Nwtit 01"' tr~clio.is glli'l•n Rlottt.
Q•Hlion 7,
AilSlDi:r J/,r fellu-..&,g ~•rstio11S." 121
0) N11.mr Ut~ cl1&'micnf cc,,,p,·,,md wJddr ca,, bt! 1~ ;rs
tJII rmH:.tpHc 4$ :r,JI ,:s a dl~1rfii,ttml,
~\.?ltJI ilti ,rrtifiC'i11l STb0!lt ,1ing i1gt?lll 1 Gic!i! OtJc!
example
Question 8,
Aft~t ordtr rraction L,; SO':,;, nwr;ilde i,r 30 mim,ta .112.rc
nmi tlti:. 1M211re rtalHon i5 nsni,1 SOo/v romJJ,1dr fo 1tJ urirrn:Cs
nJ ,17r.c_ C;,lcnlcrc tl:i: adltr~Ho,i tJJtt,~:{ uj lht rc4clfnn
fR=B.J 14 /K"1 111ur11. 121
•.:Act ts no! Rl\·cn due to chi:inQt: l.n lh~ pruem o·Jlnbus.
 ··a· ............................. --
--
- Cl
- • • •■ -- - - - -- ---- ---
- - - - - -.,_ - - • --•• ••••
I -,- -..._
(2) : : : : ; ; . , . : ..... 1vr ~ - ~ -•

..,....._....,..,.,..,,,,_1, rfllw_follo,rmg. la! 0--'DCI u.

1k siu ef IlletrivGknl Cllllo,u in llir ........
"
., ~ -.,__.. .,, (0
CID tllrylammr•rtltyl .,_.., «riff . - sttadlly as 1~ 8biiir -~~
Qu""41ft 10. j- I m Whal is IJm ,...,IGiiW:- ..i. 7 '
Gftlf - Nrflitwl Inf to nfi'1P-" ,.,,_,, t«1t af 11w (II) W7Iy •re 1/tc compound• of ~ Iii
Jtrl'-'~ ,,_. of <Ylfff1""'" ; 8 l2I colouml 7 " ' f~
(II '""""'dnnfdr •"' e'ffllddtlfdt Qaead- 13. u1
~
«td II /FdCNJJ' iu coardin11hon compla 1o,i;
(a) Is the comp/a ion d1'inuigttttic or p,,r~lf4 ~
IIII flnt:,,Jddft,dr •"' e-rl~
SECTION C • U MARkS t
QuntiOft 11. (b) WhJJt is the hybri41,at/on stalt of tht 1
(II .1n•mrr th~ fallnwm,~ 'l"!Sllons 131 mt/al ntom ? Cl!!l!,j ul
(a) A first nrdr, rrarlrm, talt'!I 100 mmul~ far (U) Namt lht lypt of lsomtrlsm shown by Ille foll..,_ ~
r,•mrlrl,nn <I/ b()% of lht rrocllon. Find lhe pairofc:oordi11atian compounds: ··-""\I
11ml' fr'l/ll1ttd 1rl~n 90"4 ef the mtel111n u!llJ ~ [Co(NHJJ5SO,.JBr and /Co(NH;y5BrJS04 Ill
n•mpldN Qa. a don 14.
(b) /11 n rrnct1n11. mA + 118 - Prod11cts, wlum tht
,.....,,on An~r
l/1tfallowi11g questions.•• IM \ ,..1
ro11u71trnl,n11 r,/ A ;, do11l1/rtl, tl,r rntt o1, 1 _,.,.
i~ a/<() d1111hlrd Wl,m thr amcr11tralion of 8 1s (I) Which aq11cc11s so/11t /011 of co11ctnlralion O.OJ Mlol!i I
,11111/t/rd tht' ratr <>/ ~"'" lrrt'llmes four times. i.L KC/, MgCJ1 imd AICJ3 10011/d flt most tffetn1>11,,
foul tl,r oPtTall ordtr ofrtttel1on a,agulating a 11egotivdy cl,nrgcd co/lo/do/ sclwtioncf
OR As2S1l
Ui) A11br,...,. tl,e fa/1011•111,~ •111rstums
(a) Mrntio1101111 two factors thnt i1if111cnct ll1erat~ofa Ill) Blttdi11g coused by Orsic.kfrom n rn.or4uringslunli1t1
,.,,,.,,11cn/ rrnrlloll can be stopped by mhbi11g afom. Gim reason,
(b) In a first ordrr n-od1on, 20% of a rtJJdant rs (iii) Muddy water can be purified by adding potaJh a,,
am•umrd 111 30 n111111/ts. Calculate tht fallowing : to ii. Gi11t rtoSOII.
(1) 77,c /10/f-hfr fk!rlod of tht ,mc/1011.

ANSWERS

SECTION-A reaction, two benzaldehyde units combine in !ht

.nswcr I . presence of M alcoholic solution of KCN to givu
) Rrst, independent coupled product. The reaction can be rep~ted
i) coloured, unpaired as:
UJ eltctrophllic, meta
nswer 2.
, (.al 6 and 3
Explanation: The coordination number is the
OO
H H

number of ligands or donor atoms attached to the I--::: +

/2
I Alcoholic KCN
A
cen tral metal ion in a complex. ln this complex, (6'n1.oill)
' E' 1s coordinated to four ammonia (NH]) ligands
and two chloride (Cl1 ions. (ijj) (bl Ethyl alcohol ..
So, the coordination number (CN) Is 4 + 2 ~ 6. Expl.mation: When ethyl amine_ reacts Wl;
The charge on the coordination sphere is + I, nitrous acid (HN0i), then ethyl d1azoniU111 1
ammine is a neutral ligand, and two chlorine
is formed, which is quite unstable, and hen~
atoms carry- I charge each. Therefore, oxidation
stale of the metal is ca lcuJa led as: easily breaks into ethyl alcohol ~d ~l~b
x-2 =+ 1orx=+3 The nitrous acid is a highly reactive u,te till
(b) C6H5CH(OH)COC6fis so it is prepared at the time of reaction by treacti
NaN02 with HO. Hence, the complete rea
Explanation: The mentioned reaction is known
is given as:
as the benzoin condensation reaction. In this
r-r la not given due 10 cb&nae In the prueot syllabus.
~~ tlw b/•n.b lly chOOllrig ~ -,,p. •lirl
-,) ..,,.,,,.,,.,, lhosegn,r,, ir, fht, ••ldon, :"' • ~
1
~ w/um,, ,,,_, h~rm. gn,,,. -•'--I
( .,-...... c«t,ylamine. -.l,8 u ..,_.., tnt.
a--,•···· "I'" , mgh, twz, d1rp1
,.,.... gram 111olt. aubon IIIOltozide) '
ti} Equiwlml antd11dltljfy fs flit Clll1lfllktl
,-,wer "fall th, ion, [urnuhftj by Olla . "Ir '"'
CaJ XDio,t
n-tyrw.,
of- , ,· , ~
an •~ctnilylo PP'<Snlt ;,. • <hfiriih ---rf ,: •mkorafMtton
so/UltOfl. ,.,.tion..
(10 Bltaching ~l!J', 011 treai-nt Willi •U..,no/ ffvl DiJlorll'IIII ottw-(,IJ f"'!"-,, fr,£10r
or attlone ~Ol.'S - - - TIiis iJ "" e:tUlplt al drill slr11ct1,rc
___ l'Ncl1on. '7
Cd) A•- llit foUdlolng 411/!Sliotu: ~" 21
(till Or1ttr orl,itnl onmple:r.,. /nvo/11<' (I) Wltat is Ille a,mmon. nmnc,. of Ille polymrr
/1ybridiz,i/io11 and nre spi11 complexe,. ol>tiri,1..! l,y the pofy,ncrlsallan o/, ~ 1
(Iv} Zfoc ori~ is rrduceA by _ _ at 1673,C r,, b ii addition 11C1fym,,r .,,. <:1Jt1M""11ion
form ti11c and _ _ _•• polynra?-
(ll) Why zn2• Iona /ITC ,.,,-.,..,.1,ss ~ N;l• ioll5
n,} Srloct tl1t correct allernot/10, from lhe choias ;,,,,,, :
8 a.rt gr,,,n 111,d Cu2' iOll5 tttc blue l11 calawrl
14• ll tllil TI1e molar cond11clivify of /'laCI, CH5COON•
(II n,c pacJ.ing ,fficir,1cy of•implt o,blc slrw:hlrt, a,u/ HCJ at info,ltr ililulionis 126..fS, 91-0 •""
body er>1trred cubic structure a'n4 f•c• cent,nd 426·16 .,11.,-1 anl n10:-I ,,..pc,rlwrly. Cakul,al,
qubic structure res,,.cfit-ely is:••
tlrr molar corullldwily (~) for eHJCOOR •
(1) 52-4%, 74-%, 68''1. infir1ilr dil11tlm1.
(2) 74%, 68%, 52.4•,:,
6v) Trknlify theromrounds A, B. C ,111d 0.
(3) 52·4%, 68%, 74%
(4) 68"/o, 7~%, 52•4.%
C • H5COOH socr, 1 A Nf1 3 1 B
ll•~IJCOH
(ii) When 11aloru, is trtatcd wim Grignord's C 0
reagc111, folluwed by l(ydto/ysis, !he prod11cl Q11.,stion 2.
fomuul is:
(a) J\n tlemrnl l11u lllomtc u..-iglrl 93g mor1 a,ul dm,
(1) Secondary alcoliol
ll·S g 011- 1 • If llw eilg" lcensl/1 "fits u11il c,/1 is .
(2) Tertiary a/cnliol pm, 1daUij\J tlu, typr 11/ 1111iJ ct/I.••
(3) Primary alrol1ol (1','A = 6•023 ~ J()2l mo[·I)
(4) Aldellydc ea
(iii) l'>'hic/1 of tl1e following tlectro/ylts is le1151 (b) Otfculale 11,,_ radi11s of fQPp,!1' 111,>111. Tht Id.
effective i11 ca11sing floce11/atlo11 of positively wtighl of copper is 63·55 g mcil"1• II crysta,
charged ftJrric l1ydro:cidt sol? .. in ftV:e Ctrilr.trtd cubic_ lallico and hm ,wirsil
(1) KJ /F,(CNhl (2) K2Cro. 8·93 g cm- 3 al 298K. ••
(3) K• LFnCNJ 6I (4) KBr (NJ\= 6·023 >< 1()2-l ,no/·1)
(iv) 011 heati11g a11 alipl,atic. primary oml11r with Question 3.
c/dorofonn 011d alcolrolic pota.,;siu111 l1ydro:cide,
Comp!ct,, and l>alamr lllt follawing dimrhi1 a,u,,tiim.s:..
tlie organic compou11d formed is a,, :
""•·-Aru,_.w_c_r_ls_no
_1""&1,-
ven due 10 cb1n1e 1n the pttacn1 sylla.bu.
 .. .. .. .. .. .. .. . ~· -~...:'. (fJ f!fl
0
~
-•-
•
- -., + •
• '
II: I
• M ir •
,.,,,,., ............
I I 1 f Pf I -1 1..:ts iilli

OU W ril rll tt_ .,, io ll .,,

.,..,. rf;p t, .
Dl
o1 ur
til lll fl lw N t~ .l. ..e .1 •~
m A ., _ cf liJltf II ,. .. ,
.. .. . •
.
Q■ ,,: s. ,ollllfon.
Ill Hot," a,;,.ptic, '# rfn,,,, 4i,htf«la O l)A iid «t ric Pl ffl lll il,
Ill N. w t 1s r• l2J ... , . . . . . ~
t t _, .. 111111 m i k
• ml t1S a 41,in.frdl,,tl." IO d • 111 •ff srp llc ..,..,.. .- . l
j
(ill) Ai lda is..,,., (l,JCl~ • .W . ID
Qo11Rf .. . • ~
121 sofllfiltol of,n mi all l Slllpidu
An ,llo y ofgoU CAio) and (AszS~.
clld11!111111 (C,1) crysfllllltn 11111h Qn rf: ::t1 tJ .
e n,i,i< .tr wf ldf ' 111 Nicfl
gr,14 lllOms oavpy I/tr CDrllt c■) How will you IXl>IIOI
,m J caJmi11111 ai -s fol n 1M Jolhlrnn1:.(Cit~
lnlo lltr foa cra trn . W1ial is llw OjWlii,,,I)
Jor-Y af lltiulloy?..
(II Btnzoy1 dlluri/Jt lO
Qaes111111 7. brnzalMhydc.
Oil Mttlsyl clsloriilt 1t1 Pl ic
(a) Statt , _ .fer lltt d .
foUmru,g: (Ill) ,\! 'die acid to trldlsaM.
(I) Ellryfilmint is JOlu!t
121
lt in nl tr 'lffllttJlS 1111iliJtt OR
is inso/Mblt in Ul lla. (b) ,\ ttlo nt ,\ (C H,
4 01 whidl ~ blDfo,.
(ii) Afiphalic amiNS rt«lion Ji- a,mpou
m stronger ~ I/tan
ll70fflftlic "11hlll'S. on htalill& ?l'ilh cone. std B 1111 reDCtion. I
H2SO4 al 443 K git-t
a ~p oi md C dt idr
OR jamd o-..lllliik D. D o
(t,) Comp/tit mi l Nl111 hydrolysis witl1 Zn d11st givc
1a 11~ fdlcrwing OfW11iot1s: :5 only E. ldt111ify IJ,
Ill C.flsNH +CHJCOC/ Clltllp0Ult d5 A '" [. Wr
ire tltt kJ .I »• ,-, ;., , iril
2 -4 _ .. _
Uil Cz'lsNHz + HNO
Qu eU on 8.
2 - _ + _+ _ rornpor,nd A.
Qu tsl lon 14 .
{21 A first on kr reaction is ll
Om o lht stn lch trt of rni 50% complttrd in 30 min
on lrlr~fh "'r ib molttule. •te; ,
/hi' hybridisi, tion of tht cm Sta lt JOO Kand in 10 nri1111trs GI
lrlll atom ond llit gtomdry 320 I<. Calc'!hil<lht- «tnll
tht molm,/e. • • of t1i cgy oflhc ruction. CR 1 lic
= 8·.314 /K· I mol" .)
Question 9. Qu Ht ion 15.
c■1 Oa/adiik 1hr emfand l31 frplai11 tlu= following: t
AG for tlit gimr ct/1 at 25'C:
Crw I Cr '' (0-1 M) II Ft-·,. UI Tmnsition ntdiJls and
(0-01 M // Ft1, Ih m rontp011nds 8ffl"l'ill
1 al1il>it G pammagnctic bdsaui
Gm-n: i:;_.,.,,, •-0 -7-1 V. E;,2.,r, s- 0-44 V (ii) TI1m is an iltertG
o11r.
St in dmsity of dcne
ius frc
IIF s 96500 C. R • 8·314 /K:' 1 liln11iunr 12 c 22) lo copper
mol· 1) (Z • 29) in ll1r .
Sfri<s of tra11j,ifio11 CU'ffltll ts.
OR liii) K2Cr z07 acts as a 1101
(b) Cakulirlt tht dr g= tYrf11I oxidising agrnl
of diSS O(iGtio11 (a} of acetir lldd. acidic meJiu11L
if its molar cvudu ctit,ity (~
is 3!M5 S cm2 mo r1• Question 16.
!Cit...,, ).' 11t • 349·6 S mi2 nzo 1 (;a) (i) Th
1 t- a11d >..',atJCC)O"I = t M' Gt Qt in ooili11g poi
40-93 S a,il ,IIOl" 1J nt um 0-30
of acme Gcid is disS<>l ved in
Question 10. 100 8 of /,,.'11:t
is 0-0633°C. Ullcwdt lhe
131 moltelWIT irri&hl
"-4mt an important im of silocr. l'fuw Grelir add frum lliis data. Wh
at co11rlt,s/o,r,
is sil va ntr o;, ltd
from lrs s11lpli idt ore? Git1t
balo,1crd chtmica/ equations
you draw about lht mo lmd,,r
stott of IM soil
inr olm l in !ht atrlldion of in lht sol ution?
p11rt siln-r. ~-
Question U. (Git'tll _Kb for bm :tn t s 2·5
3 K kg mar'. al. ;
13} o{C • 12, H • l . O a 16)
·• AAs:""u ts not gl\'t:n dur (ill 0.,1mn!11t list osmoli
to change m the prtR:nt 5l1 c pl'l'SSllrt of a S<llul
1•bus.
prq,aml by dissolving 0-0
25 g of Kz5 0 1
,••---~·2 ~ ~""'"
...
~
------------------
., 25-C,, ..
Jla,ocildf4. -.._·-·-----------
" '1" 1 u., «a&o. O,)•o,·•;,;_;;.,._;ji, : •••--a:Ji Rrtr,
11
tit • 0-0!21 Ul-altn ,C-1 lllal .....,.:1 .-,il&wli,z,.,..,wa J 11""!=_.,.. -..,,.;-
I( so,• t74 IC mot-1)
• OR
• • 11lf. 01 mr~•t~--.,,
QHO(HpJ.C,~ J o»t,P -
.. ,rn
(CtCflP>.-
(1) -"" ...,.,...,us solu/ion r,J l!Otl-aoi.tfl a,.H:P _ _,,.,.._, J
1 t,I
II
Jtr'"',L"S "' 272·4 K. wlrile rure '11.'llff Jrt''"'- ClHCo<NH.,), J /Cr(CN), I "!'4 (l.ll•u•yt
· /Co(c;N)6 J · ' .
273•0 K. Otlcrmint th, follawin •
,ciut•" ", - 1•86 K ks ..,u1-1. :·. 0_
mo/· ' u,ri1 VIII"'"' press 11rr of w!,1
51 2
:,q at

K "8
uo IJriffg ,,_ 1>.,,,,CC "°"" qprCN!"'-Le:~
""""'' Jiy!,rid&attO" ait4 lltllpdla - ~ - - '
23·i56 nurr of H8J - _ tr al 298 K • [NICCOJ, 1- (at. '"'· ofNI- 28)
(11 TI,c 1110/lllity of S(Jfulio,r Q,a•llon 11. , l51
(2) Boilirrg ,x,u,1 ofsolulion (al tll Giw 1,ar.ru:ed cJ1twdoil equatJons for 1M
(31 Tire lou....ring of u,pour pn!$S ,r follmDin8 r~lonS: •
298 K urr o, uwlt'I' al lll Pltotol 15 t-kd ,vit;ft itt cold aJbltne
(ii) ~ S<>l11tion co11l11i11i11g 1·23g of cnlrium nUra!e 110l1tlion oJbcmZ'ffl~ dinOfflM'!f chJc,rlb.
11110g of water, bolls al I00•97S•C at 760 mm (2) ouilhyl elhn ;s frtllltd with p1tc1,p1ioro1&11
Hg. Cakulale /Ir;, vrm'I Hoff factor for the 1
al llus corrceutratio11.
11
~f pcntru:hlori4L ,
(3) Ethyl alcohol Js b"rlJled with tl,ionyl cfdoride.
(K;, for n~ter = 0,52 K kg mo1-1, mol. wt. of (ID Gluc 011e dtenri.:al rnt ~ todiftlnguish befu,mt
cl!lcrtmr mtratc -1 &l g mor' ). '""fo!klwing ~~ ofto1npowtda:
~ o n 17. (SI (1) Et!taltOI 1111d dinitlllyl dNr
l•I (ii Write 11,e IUPAC names of !ht following (l) Propan-1-ol And propcm,-2-ol
ccmrplex<>s:
(1) [Cu(NR ) /SO OR.
(2J /Co(eu)zC/3 4J 4 (b) (\) Wrllr drmtiail t'l"alions lo ill1tStr11te II
(3) K /.Al{C o2 J J follor.oiug nAnre reactions:
3 2 4 3
(iii Witlr reference to tht coordination canrple.x ion (1) Williamson's synthtsis
[Fe(H 0 ) /2" arlSWl'T tire fol/awing: (al, 110. of 1.2) Est1.1riJication reac.tion
2
Fe c 26) 6 (3) Rcfnu.•r-Tiem1111n rtru!tion
(1) Give lire CUPAC name of tire compla l011. (U) Identify the compo1mds A and B i:n the g;
(2) Vv/101 is tlze oxidation mmrber of !/Je cerrlrol rcaclicms :
111dal atom? .ta.N.OH • B
(tlCif150H
(3) Hott! mllllY impaired ckclrorrs are lllere in
tire complex ionl
(4.) State tire type of l1yl,1idisalio11 of !he
complex ion.
OR

AN SWERS

OH
I
°"'3-C-O
I
tone is tcealed with CH-3
(T~;ak..t
alcohol is obtained.
(ci) (ii)lodofem\_ test - (a) Aceta\dehyde
e represented as;
oe (iii) Anhenius equation-{d) frequency

• I
CH3-C-CH3
I
CHa
I
(iv) Distorted octahedral stnlelure-{1:
hexa(luoride
(d) (li) Zinc: iOllll have a completely
orbital. This means that tt-
 ISTRV

Queedoal, Motdi I~following:

c.1 r,u in ,,., ll""1ls 1,y """"'"' 11ua .,.,,,.,.,"''~ word/ w D/caf/iJpt/m,
avr,lt fro,,, tint givnl i11 lltt lmwh-ls: lJI•• CH) Cryslllll• Sflld••
lrnort t/r,r/i, P""'"'V• Clll/to«, LMtm l'ellgffll, ltoo,
feu,, Im thlln, Grignlll'd's rtagrt1I, ltrt/flry, onudt,
um, ft/1111 111, llnt} (iii) Phenol (cl 0/phn,yJ
C11 77ie d,:n,tam of b011ing point of 0-5 M l<zSO• (Iv) Fillig rtaction {di l\nllln,,
is
$d11ll.,11 thlll ofO-S M lln'4 so/wlion. (di A1tsw1,r 1114followtn~ 'l"':'lians : It • 2l
Tht rli't'fll!on of /Joili,1g point of 0•5 M KCI
S<t/ulMln is _ _ lhal ofO-S M K,S0 solulio,,, CU Ill Which lrivaknl ion htu "l.01'lmlbJl si:L ;,
1 1l1t lllnllrrnllid sn-ks i,t., l.a11tl1a1ru., ; ;
1111 A n1i~ llm of COIIC. HC/ ond 011hydro14 ZnCl 0
,~ ral/i'd ~--u.~rith shows m,iximum
1 (I..a:'') tn Lutaiiu,n ion (l..u"J ? <Al, no.~
rtllCtif!ity tr/Ill ___ a/,·ttl,o/, lartlluJnum= 57 a11d lutetium = n1 ·
Uiil Ill t/1-rlrolytir rifining the impure mtlal is made (2) Erplai11 uo/Jy Cir' i5 llRra""'gncllc h•
- -~u."iilta 11,;,, w,•1 ofp11ren1ttalis u,;cd cu· i!l Ji.mag,,.tic. <At. No. a/Cu= zgJ
as --- '"
(lvl Wl!t!11 1/ir co11m1/rlliio1l of a rtillllan/ of first
(ii) Wl,m 11 <wrdinotion t»ntpound GJ0)'6NH
is mixer/ wit/1 /lgN03, llrrtt! mah$ of l\gC/ ar
,>rd,r rcartion is do11bled, 11,r ralt of 1:t'<lctio11 prtripitald /'l'r ,,,o1,. of ""' 1'11mpound, Wrft
bt,•on,,s ___ lfmes, but fer a ___order tire strucfural formula a11J. fUPAC tta•tt of th
wu-tion, lire mfr 1,f r,,.ctio11 rmiuJns the same, coorrli1111tfo11 co111pound.
(bl !Meet ti,; rorn•ct altmralfoc from 1/tt iholas liii) Culorlure 11,. lroilj11g point of """' sul11/i0
si11t11; I4 • 11 rclre11 6 g of 11rc11 is dis.'ill/ool in ~00 gof 1tu/o.
(ii 7711· eel/ t""~lio11 is ~11011la,ieo11s or feasible wlrm
t.mJ. t>f II,~ ct/I is: (Kb for w111,, • 0·52 K kg mot-', builing /"'ti
01 11tgatil!e ofp11rnwlrr • 37,1 K. 11,oJ. wl ~f 1lrca =61
(iv)
(21 ,,o,;itit~ lde11tify I/re cnmpo1111d$ A, 8. C mid D in j,
131 Zero given nachou:
(41 dLl1er1,,silive or ,u,gativ,
1 HC £ C/L H,('~~,SO, , A ~ 101
(ii) ,Wr/r/1, /Wrong ll1t Jol/uwirrg polymer.;, is a :.0.-• IJ~sn,
pt~yester?"'
(I) A,felnmi11, (2) Bak/ii,
Question 2.
(31 7l·ryleni: HJ l'olyl/1e11e
(ill) 77r,: correct prder ofi11crcasfog adrlic str~ngll, of (al For l/1e rmctio11 A + B ➔ C + V, tire initial r,
tire ax011rids of clr/ori11e is:~ fer diffcrerrt reacU011s attd irrit/a/ cimcenttalion
reacla11ts arc, sn,·11 l1dow:
11) /IC/OJ < HC/O4 < 11001 < HC/O
12) HC/O < HCJO1 < RC/O < HC/O, 5; J11ilial Co11c.
3 No, Initial rate
(3J HC/O1 < HC/O < HCIO, < HCJO (Al molt L- 1 fll.l moleL· 1 (molt L· 1 Stc1J
3
14) /:IC/O3 <HCJO, </KIO< HC/O I. 1·0
(iv) A ratalyst is rr subslam-e wlric/1 :
1 l·O 2 • 70·J
2. 2·0
(11 c/11111ges the (i/11ilibri11111 co11sta11t of tire 1·0 l • w·J
rnactim1. 3. 4·0 1·0 8•10.,J
(2) i11rreas.r; tlte rq11ilibri11111 co11sta11t of llrt
r,•act/011, 4. l·0 2·0 2 • 10-J
(3) " 'f'Plies " "11J,'Y to the rrnctio11. 5. l·O 4·0 2 • w•J
(4) slr//rlms tire time lo react, equilibrium.
:::-:-:'.'::::-7:"---:--;--
•• A.MWf.r is not Sl\'l'Q due lO t h.ilnge In Iha pre.s,nt Syllabus.
(I) M,at rs tire oi,ern/1 order of reacllo11 ?
(ii) Wrile tlrt rate law 1,quatio,1,
 ••········--·-···-
oa -~,•••••~4••~·-~~~~---•-,9•..lt
, , , - ,,,., t 1,. •11111
~ lllt ,,_,_ i1r .....,1.,
A, Qr . . . . .
All ~ I n Ii
,.
,.,., .,'°" ICPijo/dfoM,
JO
,,,, ""
....
II; ~ H i.
Clllarlrl, . . . . . . . . ,,.• . , .
/Jr# ryrt er/ dn;g llllrltlr " ' - u,, ,::_ CN,,•Haot111')H
,..,,_,,,,,.,,UJ 11/slf/ftwcrmdlllot,... .
- , QusSk:,, U,
~-,,, f!#ll'l"ili:m , Gm! - ~ II{ DMlbtllMroltb/Ullfallowh,ai"
·,,•f'}""''•• • W Cry,,1111 In llw at,lcl#/11 If,,,,,,.,.,,.._ frr#'
,..
f'"\\'rdl
~•
!;:.,.,.,.,..., rlil'!lllcal tlpl.ll/ian for Nclr of il1t
121 Pl/~"'""'*
WI NIICN Pl 1111 gt,,,clJn of.
. ,IIJ,,fr,,.,,,, 1 ,a,,,,r
II tfi:;:,;~ 1;::;::O,;thn~ll•o,,w iii l(ia pmmcr Cllll ~ bl //ltatrodlon ~Iron.from 1i.o,ri4,s.(:,J
L
I ~'"t.rldt
cfl/oriiJ• 1rc111td ,.,;11r tlcol,oQuatlaa 12.
CiJ Wrltt lhdUPA.C ,,.,_ ofllltJoll-lng :
lie por,_...,
~•"s. . (1) K,IFdCp,JJ (2) /CD<NHJ,01S0
4

~ tht ,n,1110111.rr alld lhc type ,f pol 121 till ,r«CN>JI- u GcaordlnGliDPI com,lla Ion-. 1M
I ~ 1aklS pince 1olw11 Pn/J Is~- .. l"'~!lon Ctl Clllc11Wt llrt ~ nrm,brr / ;nm in
0

~ ' 1/,t mono•lm of nylo11 6, 6. ., n,,npla. . . tlicl

I ' 6, (21 /s th_e r:m11ph:t "'" d1afflJlgndill""Pf',mn,,g,,
011 IIA» u'lllr.t 1Ul/11bk t~lantlns ,a
~,nrt • 121 C3) IVhal u I~ lry&ridisaJ/arl sla/r of tire a,rlt•1
O
. -by lh~ir d,ficit.1tcy h, tlot , 1 1/,e disti1."'f n11!111l al11m 7
,,iiO"_' clitlof"" iiuli11id1J11L H) IVriJt 1~ JIJ PAC llllnul ofIM CJJMpla /ml.
~
7
H•"' will you oblain 11,, follottibig 1 (G' 121 Question 13, Ill
~ ,11t1f1it>II cq11•tion~): ,11r !u/i,nc,il ta) u,,wir why:
Ii) 8t112£11t from plir,wl (ii 'Trrir,sit•m t/cmtn~ fomr a1loys.
(iii /oJoftmn fr<>m dho11ul (iii z,.i• ,.,/t< "" ,u/dl~ ._,,_ CiiJ• salJs tnT
OR colo•rrd.
•1 How will ya11 a'1la/t1 1/u, fol/uu,in• , ., cc· (Ill) Transiti"" ,netols and t/lclr ~ 5 •ti 11S
• chtrmrn • >:
. I tqttallHn!
. • , "" 1>w•mml calalyst.
OR
(i) Solfr:yl•ldelry~from phrnol
lb> Co1111•lt1t a11d 1,ula11e< the followirtlf cltnrtlca
(iii l'rop,m-2-ol from C,ignnrd's ""Rm'
C/IIW,OllS;
Quislion 8: • Ill (I) KMnO,+R2SO,+H1C10, ➔_ + _
ShbW tllol for• p,st or,/,rn,adian llu: 11111, r,qufr,d 10
to111plcr, 75% of rtaclion i., •bout 2 limts more 11,uir
t/lJII r,q11irnl to t'ilmp/,r; 50% af th• r,aclion.
QllllliOn 9. (JJ +_+_
Ill W/lt'11 0·4 g of oxalic ueid is dis$tl/utd in .W JI uf Oiil K,Cr,O, + H2SO,-+ frS04 ➔ _ +_
"'"'"""', tlie fren.ing,,.,u,t •f ,,,. t'<Jl•lion is lou.,:n,d +
by 0-45 K. Colc11latc Iii, a,g,.,,
of=dntion of QQJtic [31
adJI. Acdic arid forms J;,,,..,
w/:011 dls,;o/ved ; 11 Qu.,.lion 1.4.
l11mu11t. Gire bolanc<tl CIJlrnlians far tl,cJolfuwing:
(Ki for be112,:11e • 5•12 K kg mo)•'• al. wt. C • 12, m A11ili11c Is lrmr,,/ with brom/11, wat,r,
n~ 1, 0 ~ I6) Oil Etl1ylam/J1t ls /i,at;d u,ilh clllorofann Olld a1colwlic
siilutlan ofpomssi11111 hydn>xi1I,.
OR
~) A so/11tio11 is pr;-pnrtd by dissolvins 9·25 g of (Iii) 'Be11Zf11, diazc11i11111 c/1laridc is trc,:,ltd 111W, iu cold
no11-votatile so/,.t,• in 450 ml 1,f 1<Y1l<T, .It l111s 1111 s.1lulio11 ofanili11c i,, aciiiic ,ri,d/urrr.
osmotic prtssurr of350 '""' of Hs oJ:li•C. Ass11111fns (:)uestiun 15. IJJ
the solute is 110,r.--clt.Y:lrcilylr-, detenn~ttt its mol~tulnr O.Jin• "" following tm11s uiiU, suilablt·aarr,pla:"
mass. (R cO•OS)I /ii nh/1 K- 1 1110/ -l) (~>. P,'l'liznlion Iii) /!J•-ctmpJ,o.rtsis
hlil Dialysis
 ....
. . . :Cl
.,,,,,
. ••••••••••••••••••
,,1.. ,,.,.,
, "'
_,.,,
SE _ _ ,,,._ I;

""""" tf AtHO,fi' Ill,...

_,,,,
••••••
.
M ,,.,,,,,,,,,
fJ
•• Ill..,,
••••••

-
•••••• ...,••• _,• I•..-a;"~v
_ ...,. .._- --..- .-.., .,..,
--- -r; ;;;S T ....
............
for"',..,.,,, hf
1111111•

J 6

tN.d. f{Af•I OI. f f•'6,!0 IJCJ c-,,ltlf•ullwncrlMfollotDlnl,_-.,.~...,..,-:••

00
• Ot1t,M1, ,,,,,,,,./. al dG/11' llrtctll ,_., ,, 11) P4 +ff,SO. _. -♦ - • -
lllK: 121 Ag+HN01 ➔-•-•-
ltlllMld
Aft,.,IMt'° ,.1,d!Cr ',-»./C •,,1
Qaestf an 11. , bf
G,m L"'.,. • 1•11 V
I r • !¥~ C c,1 II) GiR' IN,Jimtttl cquarlon, for I/rt fo&wlnr
OR rr«linnt:
(II Acrttdddiyu rrtld, with 1rydrugrn L')Wlridt.
ca,1 cu 04iM IMftt/mff11 l1'fff11:
CJ1 S,,,..--ijit ro,ui,u unrt (:zJ AaJo11t rcadJ u1il/1 phtny/ l1ydrazint.
(2) Mltl -" 's la,
(31 A«tk t1eid is ltttltnl u,i/lt tlhlino/ QI/ 1

(Ill Tht mi..<11n.-r of, L'Ornludivily 1"111/ ronlalning

drop ef cone. Hz504.
0-001 M KO ,o/ufa,,,-, 298 K is lSOOo/mt. \Viral (UI Gillt ont clitm/ca/ lest taclr lo disllnguiJ/t
IM ml ron,t,.,nl and
1.1 "'olar
rondJldirtity of btluml 1hrfallmrvrg p«irs of ~IUII U :
(11 Actlnnt ond btn:o/Jd,yth.
MIOI M KQ solution, if ll1r rortdMcl/t,ity of I/ti,
~ulion is 0-146 • 1Cr
1 oltnr1 ""'' al 298 K ? (2) l'henol 1111d bmzuir Rrid.
151 OR
Quntlo n 17.
Cal Cl) E:.iplairr why:•• (b) (II Wrilt c/Jt'nlicnl tqu111/1ms to illustm t /hi
(1) F/r,;,,irrr /u,s lbuw l'kclron lljfinity thtm
follorring name rtllllions:
drlorint. (1) Aldo/ co11dmsalion
(2) Rr,d p~phorus is kss rcactiUt: 1111111 wlrilt (11 Ca1111/zznro's reaction
pltMplrorus. 0) 8r11:Di11 cundarsotion
(3) 0-..onc ndS "5 11 ponrf11/ oxidising agmt. (ii} ldmlify tlrt compou11ds A 11nd B in IM giMt
reacl/011s:
(iii DrlllD lb£ slr11cturl!S of llit following:"
(2) If, ~ Cll1CI • jOJ 8
(I) XtF,
OR
(1) V • H,S, I
dJCI,(...~) I.. l(,C'lO,
&n~ir
Iii £1'71/ain v•lry:"
(b)
(l) lnJcrhAlogc11 rompoumls = morr: mldme 121 c11,cocu,
1/JIVI Ille r; l11lrd dr111r.11ta/ halagcm.

ANSW ERS

.a.nswerl U the ooU polential (E0111) is wro, it means that the

ccU is al equilibrium. ;ind the react.Ion is neither
:.J Ci) more than. less than spontancuus in the fonv.ud nor !ht! reverse direction.
(ii) Lucas reagent. 1.ertiary
(iv) two, zero (iv) (4) Shortens the lime to readt equilibrium
'bl Iii (2) P01,i1h-e Exphnallon: A Coltalyst provides an alrerrui ti"e
Expl•n•tion: The spontancily or feasibility of a niaction p.1thway with a lower activation energy,
cell reaction is determined by the sign of the cell which allows the reaction to proceed faster and
potcnti•I (EcelJ) or electromotive fol'a! (e.m.f.) of readting equilibrium more quickly. Hence, .o
the cell. If the cell po1enti11I (E<tll) is positive, ii catalyst shortens the time to reach equilibrium.
indicates that the cell reaction is spontaneous or ◄cl (I) (d) Aniline
feasible.
(Ui) (b) Reimer-Tiemann re.1ction
Uthe cell polenlinl (E.,.ul is negativl', it indicates
wt the cell rcaclion is not spontaneous or feasible (iv) (c) Diphcnyl
under the given conditi ons. (d) Cl) (1) In the lanthanoid series (lanthanlde
series), as you move from Lanthanum (4
• An••tr ii not 11vcn due 10 th.ange In the pre.sen1 syllab1,u;.