TS EAMCET Solved Paper 03 May 2019 Shift 2
TS EAMCET Solved Paper 03 May 2019 Shift 2
Session 2
(3:00 PM to 6:00 PM)
Mathematics
1. If [ x ] denotes the greatest integer £ x, then é 1 2 0 -1ù é 1 4 -1ù
(c) ê 3 4 1 2 ú (d) ê2 3 0 ú
4 - x2 ê ú ê ú
the domain of the function f (x) = is ë -2 3 2 5 û ë0 1 2 û
[ x] + 2
(a) (-¥, - 2 ] È [-1, 2 ) (b) (-¥, - 2 ) È [-1, 2 ] 6. Consider the following system of equations
(c) (- ¥, - 2 ) È (-1, 2 ) (d) (-¥, - 1] È [1, 2 ] in matrix form
2 æ1ö æ xö
2. Let f (x) = (x + 1) - 1, x ³ -1. Then ç ÷ ç ÷
{ x : f (x) = f -1 (x)} = ç 2 ÷ (1 2 l ) ç y ÷ = O
çl÷ çz÷
ì -3 + i 3 -3 - i 3 ü
è ø è ø
(a) {0, 1, - 1} (b) í-1, , ý
îï 2 2 þ Then which one of the following statements
(c) {0,–1} (d) f is ture?
(a) " l Î(-¥, ¥), the given system has non trivial
3. For all n Î N , if 12 + 22 + 32 +...+ n2 > x, then solution
x= (b) " l Î(- ¥, ¥), the given system has only trivial
n3 n3 n4 solution
(a) (b) (c) n3 (d) (c) For l ¹ 0, the given system does not have any
3 2 4
solution
4. If the determinant of the matrix (d) For l = 0, the given system is inconsistent
é0 a bù p
ê ú 7. If the amplitude of (z - 1 - 2i) is , then the
A = ê-a 0 b ú is zero for all a , b then 3
êë - b a 0 úû locus of z is
a +b = (a) y = 3 x + (2 - 3 ) (b) y = 3x - 3
(a) 0 (b) 1 (c) x = 3 y + (2 - 3 ) (d) y = 3x + 2
(c) -1 (d) 2 æ k -1 k - 2 ö
8. If the point ç , ÷ lies on the locus of z
5. Suppose n > 1 and A is a n ´ n non singular è k k ø
matrix such that |Adj A|= |Adj (Adj A)|. Then z + 3i
the matrix whose rank is n, is satisfying the inequality < 1, then the
3z + i
é 1 2 3ù é2 2 2 ù interval in which k lies is
(a) ê 4 5 6ú (b) ê2 2 2 ú
ê ú ê ú (a) (-¥, 2 ) È (3, ¥) (b) [2, 3]
ë 6 7 8û ë2 2 2 û (c) [1, 5] (d) (-¥, 1) È (5, ¥)
48 TS EAMCET (Engineering) Online Solved Paper 2019
9. If the complex cube roots of (-i) are a , b , g , III. Number of ways of placing ‘n’ objects in k
2 2 2 bins such that atleast one bin is non-empty is
then a + b + g = ( n-1)
C k -1 .
(a) 1 (b) -1 (c) -i (d) 0
IV. nC k - n -1
Ck = ( n-1)
C k -1
10. Imaginary part of ( 3 - i)2016 + (- 3 - i)2019 is
(a) 2 2016 (b) -2 2016 (c) -2 2019 (d) 2 2019
Then which of the above statements are true?
(a) All the four statements (b) (iii) and (iv) only
11. If a and b are the roots of the equation (c) All except (iii) (d) All except (i)
x 2 - 2 x + 4 = 0 , then a 12 + b12 = 4
18. For | x| < , the approximate value of
(a) 212 (b) 210 (c) 213 (d) –213 3
1
12. The solution set of the inequation 1
is
3 x + 31 - x - 4 < 0 , is (4 - 3 x) 2
(a) (0, 1) (b) (0, 2 ) (c) (1, 2 ) (d) (1, 3)
1 2 x 12 x2 3 x 15 2
(a) - + (b) 1 - - x
13. One of the real roots of the equation 4 3 39 16 256
x 3 - 6 x 2 + 6 x - 2 = 0 is 1 3 x 27 x2 1 3 x 15 2
(c) + + (d) - + x
1 1 2 16 256 2 16 256
23 23 2x + 7
(a) -1 (b) 2 (c) 1
(d) 1 19. If
23 -1 23 +1 (x + 4) (x 2 + 9) (x 2 + 16)
2
24. If a and b are the roots of the quadratic 30. If OA = $i + 2$j + 3k$ and OB = 4 $i + k$ are the
equation 3 x 2 - 16 x + 5 = 0 , then position vectors of the points A and B, then
æa +b ö the position vector of a point on the line
tan -1 a + tan -1 b - tan -1 ç ÷= passing through B and parallel to the vector
è1 - ab ø
OA ´OB which is at a distance of 189 units
p
(a) 0 (b) p (c) (d) -p from B is
2
(a) 6$i + 11$j - 7k$ (b) 4$i + 11$j - 8 k$
25. sinh [log (2 + 5)] + cosh [log (2 + 3)] = (c) 2 $i - 11$j + 8 k$ (d) -2 $i - 11$j + 8 k$
(a) 4 (b) 3
(c) 2 (d) 1 31. A vector a of length 2 units is making an
angle 60º with each of the X -axis and Y -axis.
26. p1 , p 2 , p 3 are the altitudes of a triangle ABC If another vector b of length 2 units is
drawn from the vertices A , B and C making an angle 45º with each of the Y -axis
respectively. If D is the area of the triangle and Z-axis, then a ´ b =
and 2s is the sum of its sides a , b and c, then (a) (1 - 2 )$i - $j + k$ (b) $i - 2 $j + k$
1 1 1
+ - = (c) 2 $i - $j + 2k$ (d) i - 2 $j + (1 - 2 )k$
p1 p 2 p 3
s-a s-b 32. Let a be a non zero vector. If
(a) (b)
D D x = $i ´ (a ´ $i), y = $j ´ (a ´ $j) - a and
s -c s
(c) (d) z = k$ ´ (a ´ k$ ) - a , then [ x y z] =
D D
(a)|a| (b) 2|a| (c) 0 (d) 1
27. If in triangle ABC ,
C C 33. If r = $i + $j + t (2$i - $j + k$ ) and r = 2$i + $j - k$ + s
a 2 + 2 bc - (b2 + c 2) = absin cos , then (3 $i - 5 $j + 2 k$ ) are the vector equations of two
2 2
cot(B + C) = lines L1 and L 2 , then the shortest distance
8 1 between them is
(a) – (b)
15 4 9 10 11
(a) (b) (c) (d) 0
15 59 59 59
(c) - (d) 4
8
34. If r is a unit vector satisfying r ´ a = b, |a|= 2
28. If p1 , p 2 , p 3 are the altitudes of a triangle ABC and |b|= 3, then one such r =
from the vertices A , B, C respectively, then 1 1
1 1 1 1 (a) [2 a + (b ´ a )] (b) [a - (2b ´ a )]
with the usual notation, 2 + 2 + 2 + 2 = 4 4
r1 r2 r3 r 1 1
(c) [a - (b ´ a )] (d) [a - (b ´ a )]
a2 b 2c 2 3 4
(a) p1 p2 p3 (b)
4D2 35. The variance of the data 2, 3, 5, 11, 13, 17, 19
2 2 2 æ 1
a bc 1 1ö is nearly
(c) (d) 4 ç 2 + 2 + 2 ÷
D2 è p1 p2 p3 ø (a) 6.258 (b) 24.25
(c) 4.95 (d) 39.71
29. Vectors a , b , c , d are such that
(a ´ b) ´ (c ´ d) = O , P1 and P2 are two planes 36. The approximate value of the mean deviation
determined by vectors a , b and c , d about the mean for the following data is
respectively. Then the angle between the Class Interval 0-2 2-4 4-6 6-8 8-10
planes P1 and P2 is
p Frequency 1 2 3 2 1
(a) 0 (b)
4 (a) 3.56 (b) 4.61
p p
(c) (d) (c) 2.19 (d) 1.78
3 2
50 TS EAMCET (Engineering) Online Solved Paper 2019
42. The locus of all points that are at a distance 48. The ratio in which the line x + y - 1 = 0
of atleast 2 units from (-3 , 0) is divides the line segment joining the origin
2 2
(a) {( x, y)| x + y + 6 x + 7 > 0} and the point of intersection of the lines
represented by
(b) {( x, y)| x2 + y2 + 6 x + 5 ³ 0}
2 x 2 - 13 xy - 7 y 2 + x + 23 y - 6 = 0 is
(c) {( x + y)| x2 + y2 - 6 x + 5 > 0}
(d) {( x, y)| x2 + y2 - 6 x + 5 £ 0} (a) 15 : 11 (b) -11 : 15
(c) 7 : 3 (d) 7 : 19
43. If q 1 , q 2 , q 3 are respectively the angles by 49. The lines represented by 5 x 2 - xy - 5 x + y = 0
which the coordinate axes are to be rotated are normals to a circle S = 0. If this circle
to eliminate the xy term from the following touches the circle
equations, then the descending order of these
S¢ º x 2 + y 2 - 2 x + 2 y - 7 = 0 externally, then
angles is
TS EAMCET (Engineering) Solved Papers 51
the equation of the chord of contact of centre 55. Consider the curves C1: y 2 = 4 x and
of S¢ = 0 with respect to S = 0 is
C 2 : x 2 + y2 - 6 x +1 = 0
(a) 2 y - 7 = 0 (b) x - 1 = 0
(c) 3 x + 4 y - 7 = 0 (d) x + y = 5 Assertion (A) The common tangents to the
curves C1 and C 2 are othogonal.
50. The equation of the circle that touches the
Y -axis at a distance of 4 units from the origin Reason (R) x - y + 1 = 0 and x + y + 1 = 0 are
and cuts off an intercept of 6 units on the the common tangents to the curves C1 and C 2
X -axis is The correct answer is
(a) x2 + y2 ± 5 x - 8 y + 16 = 0 (a) (A) is true, (R) is true and (R) is the correct
(b) x2 + y2 ± 2 x - 4 y = 0 explanation of (A).
(c) x2 + y2 ± 3 x - 2 y - 8 = 0 (b) (A) is true, (R) is true but (R) is not a correct
(d) x2 + y2 ± 10 x - 8 y + 16 = 0 explanation of (A).
(c) (A) is true but (R) is false.
51. The condition for the circles (d) (A) is false but (R) is true.
x 2 + y 2 + ax + 4 = 0 and x 2 + y 2 + by + 4 = 0 56. If OT is the semi-minor axis of an ellipse, A
to touch each other is and B are its foci and ÐATB is a right angle,
1 11 then the eccentricity of that ellipse is
(a) - = (b) a2 + b 2 = 16
a2 b 2 16 1
1 1 1 1 1 (a) 1 (b)
(c) 2 + 2 = (d) + =4 3
a b 16 a2 b2 1 1
(c) (d)
2 2
52. If the equation of the circle which passes
through the point (1, 1) and cuts both the 57. The locus of the mid-points of the portion of
circles x 2 + y 2 - 4 x - 6 y + 4 = 0 and x 2 y2
2 2 the tangents of the ellipse + =1
x + y + 6 x - 4 y + 15 = 0 orthogonally is 2 1
x 2 + y 2 + 2 gx + 2 fy + c = 0 , then 5 g + 2 f + c = intercepted between the coordinate axes is
1 1
(a) 0 (b) 1 (a) + =1 (b) 2 x2 + y2 = 4
4 x2 2 y2
(c) 3 (d) 2
1 1
(c) + =1 (d) x2 + 2 y2 = 4
53. If the line x + y + 1 = 0 intersects the circle 2 x2 4 y2
x 2 + y 2 + x + 3 y = 0 at two points A and B,
58. The distance between the tangents to the
then the centre of the circle which passes x 2 3 y2
through the points A , B and the point of hyperbola - = 1 which are parallel to
intersection of the tangents drawn at A and B 20 4
to the given circle is the line x + 3 y = 7 is
4
5 5 (a) 4 5 (b)
(a) æç , ö÷ (b) (1, - 1) 5
è 8 8ø
2
3 1 (c) (d) 2 5
(c) æç , - ö÷ (d) (3, - 4) 5
è 4 4ø
59. The length of the projection of the line
54. The vertex of the parabola (y - 1)2 = 8(x - 1) is
segment joining the points (3, 4, 5) and
at the centre of a circle and the parabola cuts (4, 6, 3) on the line joining the points
that circle at the ends of its latusrectum. (-1, 2 , 4 ) and (1, 0 , 5) is
Then the equation of that cicle is 4 5
(a) (b)
(a) x2 + y2 - 2 x - 2 y - 18 = 0 3 4
(b)x2 + y2 - 2 x - 2 y + 18 = 0 2
(c) (d) 1
(c) x2 + y2 + 2 x + 2 y - 16 = 0 3
(d) x2 + y2 - 2 x - 2 y + 16 = 0
52 TS EAMCET (Engineering) Online Solved Paper 2019
1
60. If A(3, 2, 3), B (1, 4 , 6 ) and C(7 , 4 , 5) are the -
65. Suppose f (x) = e - x
+e x2. If
three vertices of a parallelogram ABCD, then
1
the angle between its diagonal through D and -
2
the side DC is e- x æ 1 ö e x æ 2 ö
f ¢¢ (x) = a ç1 + ÷ + b 4 ç3 - 2 ÷,
16 ö 5 ö x è x ø x è x ø
(a) cos -1 æç ÷ (b) cos -1 æç ÷
è 357 ø è 126 ø then (a , b) =
5 ö 2 ö 1 1 1 1
(c) cos -1 æç ÷ (d) cos -1 æç ÷ (a) æç , 2 ö÷ (b) æç , - 2 ö÷ (c) æç - , 2 ö÷ (d) æç - , - 2 ö÷
è 21 ø è 357 ø è4 ø è4 ø è 4 ø è 4 ø
61. p1 is a plane passing through the point 66. The derivative of cos h -1 x with respect to log
(1,2,3) and perpendicular to the planes x at x = 5 is
x + 2 y + 3 z - 6 = 0, x + 2 y + 2 z - 5 = 0. If 5 1
(a) (b)
(-1, 2 , - 3) is the foot of the perpendicular 26 26
drawn from the point (1, 3 , 2) on to a plane 1 5
(c) (d)
p 2 , then the angle between the planes p1 and 2 6 2 6
p 2 is
9 ö p
(a) cos -1 æç ÷ (b) 67. A right solid circular cylinder of given volume
è 255 ø 4 will have the least total surface area when
æ 6ö p
(c) cos -1 ç ÷ (d) (a) its height is equal to its radius
è 10 ø 2 (b) its height is equal to its diameter
(c) its height is independent of its radius
62. If [ x ] is the greatest integer function, then 3
(d) its height is times of its radius
æ[ x ]3 é x ù 3 ö 4
lim ç -ê ú ÷ =
x ®2 + ç
è 3 ë 3 û ÷ø 68. The smaller side of the rectangle with the
largest area, that can be inscribed inside a
64
(a) 0 (b) semi-circle of radius 2 units is of length
27 1 1
8 7 (a) (b) 3 (c) (d) 2
(c) (d) 2 3
3 3
kinetic energy, K of the particle varies with 92. A particle of mass 0.1 kg is executing simple
the distance as K = bx c , where b and c are harmonic motion of amplitude 0.1 m. When
constants. The values of b and c are the particle passes through the mean position,
(a) b =
ma
;c = 3 (b) b =
ma
;c = 4 its kinetic energy is 8 ´ 10 -3 J. If the initial
3 4 phase is 45º, the equation of its motion is
ma ma (Assume, x ()t as the position of the particle at
(c) b = ;c = 4 (d) b = ;c = 3
2 2 time t.)
88. A mass of 2 kg initially at a height of 1.2 m p
. sinæç 4t + ö÷
(a) x(t ) = 01
above an uncompressed spring with spring è 4ø
constant 2 ´ 10 4 N/m, is released from rest to p
. sinçæ16t + ÷ö
(b) x(t ) = 01
è 4ø
fall on the spring. Taking the acceleration
æ æ p öö
due to gravity as 10 m/s 2 and neglecting the (c) x(t ) = 01
. sinç2 çt + ÷ ÷
è è 4 øø
air resistance, the compression of the spring
æ pö
in mm is (d) x(t ) = 01
. sin ç2t + ÷
è 4ø
(a) 20 (b) 40 (c) 50 (d) 60
89. A bullet of mass 1 kg fired with a speed 93. If a satellite has to orbit the earth in a
-1 circular path every 6 hrs, at what distance
2 ms from x = 0 passes through a block of
from the surface of the earth should be
wood whose centre is kept at a distance of
satellite placed (radius of earth, Re = 6400
10 m from the origin as shown in the figure. GM
The retarding force Fr on the bullet within km) (Assume, = 8 .0 ´ 10 12 N/m 2 /kg,
the wooden block is - 0 .5 / x. The minimum 4 p2
length of the block (upto one decimal digit) where, G and M are gravitational constant
required to completely stop the bullet is and mass of earth and 10 1/ 3 = 2.1.
(Assume, e 4 = 55) (a) 15100 km (b) 8720 km
(c) 20600 km (d) 5560 km
x=0 x=10
94. A copper wire of cross-sectional area 0.01
cm 2 is under a tension of 22 N. Find the
(a) 10.1 m (b) 9.2 m (c) 9.7 m (d) 19.3 m
percentage change in the cross-sectional area.
90. A solid spherical ball rolls on a horizontal (Young’s modulus of copper = 1.1 ´ 10 11 N/m 2
surface at 10 m/s and continues to roll up on and Poisson’s ratio = 0 .32)
an inclined surface as shown in the figure. If (a) 12.6 ´ 10-3 (b) 8.6 ´ 10-3
the mass of the ball is 11 kg and frictional (c) 6.4 ´ 10-3 (d) 2.8 ´ 10-3
losses are negligible, the value of h where the
95. A cylindrical tank with a large diameter is
ball stop and starts rolling down the
filled with water. Water drains out through a
inclination is (Assume, g = 10 m/s 2 ) hole at a bottom of the tank. If the
cross-sectional area of the hole is 6 cm 2 then
the drainge rate (in m 3 /s) when the depth of
h the water is 0.2 m, is
30°
. ´ 10-3
(a) 10 (b) 8.2 ´ 10-2
(a) 8 m (b) 6 m (c) 7 m (d) 10 m (c) 2.2 ´ 10-3
(d) 1.2 ´ 10-3
91. A long cylinderical rod is welded to a thin 96. The surface tension of the soap water
circular disc of diameter 0.5 m at a point on 1
its circumference. The rod is in the same solution is N/m. The free energy of the
10 p
plane as that of the disc and forms a tangent
surface layer of a soap bubble of diameter
to the disc. The radius of gyration of the disc
5 mm will be
about the rod (in m) is
(a) 2.5 ´ 10-6 J (b) 1 ´ 10-7 J
1 5 1
(a) (b) (c) (d) 2 2 (c) 8 ´ 106 J (d) 5 ´ 10-6 J
4 8 2
56 TS EAMCET (Engineering) Online Solved Paper 2019
97. Statement A Convection involves flow of The speed of the vehicle is (Assume the
matter within a fluid due to unequal velocity of sound is 333 m/s.)
temperatures of its parts. (a) 6 m/s (b) 5 m/s
Statement B A hot bar placed under a (c) 3 m/s (d) 1 m/s
running tap water loses heat due to effect of 103. Three lenses of focal lengths +10 cm, -10 cm
convection with in water. and +30 cm are placed at distance of 30 cm,
Statement C Heat transfer always involves 35 cm and 45 cm, respectively from an object.
temperature different between two systems. The distance between the object and the
Identify the correct option. image formed is
(a) A, B, C are true (a) 100 cm (b) 75 cm
(b) Only A and C are true (c) 30 cm (d) 45 cm
(c) Only A and B are true
(d) Only B and C are true 104. In a Young’s double slit experiment, a thin
sheet of refractive index 1.6 is used to cover
98. A body cools from 70ºC to 40ºC in one slit while a thin the sheet of refractive
5 min. Calculate the time it takes to cool index 1.3 is used to cover the second slit. The
from 60º C to 30º C. The temperature of the thickness of both the sheets are same and the
surroundings is 20º C. wavelength of light used is 600 nm. If the
(a) 1 min (b) 7 min (c) 6 min (d) 15 min central point on the screen is now occupied
by what had been the 10th bright fringe
99. One mole of ideal gas goes through a process
(m = 10), then the thickness of covering
pV 3 = constant, where p and V are pressure sheets is
and volume, respectively. Let W be the work (a) 50 mm (b) 8 mm
done by the gas as its temperature is (c) 20 mm (d) 40 mm
increased by DT. The value of |W| is (R is the
universal gas constant.) 105. An infinite line of charge with uniform line
1 R charge density of 1 C/m is palced along the
(a) RDT (b) RDT (c) R 3 DT (d) DT
3 2 y-axis. A charge of 1C is placed on the x-axis
at a distance of d = 3 m from the origin. At
100. An ideal gas is placed in a tank at 27ºC. The what distance r from the origin on the
pressure is initially 600 kPa. One fourth of x-axis, the total electric field is zero.
the gas is then released from the tank and (Assume, 0 < r < d)
thermal equilibrium is established. What will (a) 1 m (b) 2 m
be the pressure if the temperature is 327º C? (c) 2.5 m (d) 1.75 m
(a) 900 kPa (b) 1000 kPa
(c) 1050 kPa (d) 1250 kPa 106. A capacitor of capacitance 4 mF is charged to
101. Which of the following equation represents a a potential difference of 6 V with a battery.
simple harmonic motion? (w is the angular The battery is removed and in its place
frequency, A is amplitude of oscillation and another capacitor of capacitance is 8 mF
introduced and the circuit is closed. The
i = -1
potential difference attained by each of the
dx d 2 x2 capacitors in V is
(a) = iw x 2 - A 2 (b) = w2 x
dt dt 2 (a) 2 (b) 4 (c) 6 (d) 8
d2x d2x
(c) 2 = iw x2 - A 2 (d) = wx 2
dt dt 2 107. Estimate the magnitude of current that
passes through a wire, if 0.1 mol of electrons
102. A musician on a moving vehicle plays a tone flow through it in 40 min. (Assume,
at 880 Hz note. When the vehicle was Avagadro’s number = 6 .0 ´ 10 23 )
approaching a listener, he receives it as
888 Hz tone. (a) 4 A (b) 9 A (c) 12 A (d) 14 A
TS EAMCET (Engineering) Solved Papers 57
108. Find the potential difference between a and 113. A sinusoidal voltage with a frequency of
b, as shown in the below circuit, 50 Hz is applied to a series LCR circuit with a
a resistance of 5W, inductance of 20 mH and a
capacitance of 500 mF. The magnitude of
impedance of the circuit is closed to
15 W 5W 45 V (a) 19.2 W (b) 14.4 W
(c) 9.6 W (d) 5 W
24 W 12 W 8W 114. The concept of displacement current solves
an ambiguity in
b (a) Gauss’s law (b) Faraday’s law
10 W (c) Ampere’s law (d) Coulomb’s law
(a) 165 V (b) 198 V (c) 213 V (d) 224 V 115. A photodiode sensor is used to measure the
109. A metal disc of radius, a = 10 cm rotates with output of a 300 W lamp kept 10 m away. The
a constant angular speed of w = 200 rad/s sensor has an opening of 2 cm in diameter.
about its axis. The potential difference How many photons enter the sensor if the
between the centre and the rim of the disc wavelength of the light is 660 nm and the
under a uniform magnetic field, B = 5 mT exposure time is 100 ms. (Assume that all
directed perpendicular to the disc, is the energy of the lamp is given off as light
(a) 2 mV (b) 5 mV (c) 10 mV (d) 15 mV and h = 6 .6 ´ 10 -34 Js)
(a) 3.6 ´ 1013 (b) 2.8 ´ 1013
110. A proton accelerated by a potential (c) 2.5 ´ 1013 . ´ 1013
(d) 18
difference 500 kV flies through a uniform
transverse magnetic field 0.1 T. The field is 116. To excite the spectral line of wavelength
spread on a region of 1.0 cm thickness. The 4960 Å of an atom, an excitation energy of
angle through which the proton gets deviated 7.7 eV is required. The ground state energy of
from its original direction is : (mass of proton the atom is 10.5 eV. The energies of two
. ´ 10 -27 kg and charge of proton
= 16 levels involved in the emission of 4960 Å line
. ´ 10 19 C)
= 16 are : (Assume hc = 1240 eV-nm, where h is
(a) 0.01 rad (b) 0.1 rad (c) 0.05 rad (d) 0.08 rad
planck’s constant and c is speed of light.)
(a) 14.2 eV, 16.1 eV
111. A toroid has an iron core with an internal (b) 12.2 eV, 18.2 eV
magnetic field of 10 p mT, when the current (c) 15.7 eV, 20.5 eV
in the winding of 1500 turns per meter is (d) 15.7 eV, 18.2 eV
10 A. Determine the field due to
117. In one average life-time of a radioactive
magnetisation (m 0 = 4 p ´ 10 -7 Hm -1)
nuclei,
8 p
(a) (4p ) mT (b) (10p ) mT (c) æç ö÷ mT (d) æç ö÷ mT (a) more than half the active nuclei decay.
èpø è 4ø
(b) half the active nuclei decay.
112. A conducting wire bent but in the shape of (c) less than half the active nuclei decay .
semicircle has length L and moves in its (d) all the nuclei decay.
plane with constant velocity v. A uniform 118. The truth table for the given logic circuit is
magnetic field B exists in the direction
perpendicular to the plane of the wire. The A
velocity makes an angles 45º to diameter B
joining free ends and the emf induced
between the ends of the wire is F = a ( BvL). Y
The value of constant a is
2 1 2
(a) 2 (b) (c) (d)
p 2 p
58 TS EAMCET (Engineering) Online Solved Paper 2019
(a) (d)
A B Y A B Y
0 0 0 0 0 1
0 1 1 0 1 0
1 0 1 1 0 0
1 1 0 1 1 0
Chemistry
121. The radius of the 2nd orbit of B 4+ ion is 124. The correct increasing order of basic
(a) 4.23 Å (b) 0.2340 Å character of Ce(OH)3, Gd(OH)3 and
(c) 0.4232 Å (d) 0.3241 Å Nd(OH)3 is
(a) Ce(OH)3 < Nd(OH)3 < Gd(OH)3
122. The product of uncertainty in the position (b) Gd(OH)3 < Ce(OH)3 < Nd(OH)3
and uncertainty in velocity of a particle is (c) Gd(OH)3 < Nd(OH)3 < Ce(OH)3
5.79 ´ 10 -5 m 2 s -1 . If uncertainty in the (d) Ce(OH)3 < Gd(OH)3 < Nd(OH)3
position is 1 nm, what is the uncertainty in
the measurement of its velocity in m s -1 ? 125. How many ions of the following have bond
(a) 579
. ´ 10 7
(b) 579
. ´ 105 order of 2.5?
. ´ 10-5
(c) 579 . ´ 104
(d) 579 N –2 , NO - , C-2 , N+2 , C22 - , CN+
(a) 4 (b) 3
123. Among the isoelectronic ions (c) 2 (d) 5
(O 2- , N 3– , Mg 2+ , Na+), the ions with least and
126. Which of the following ions has tetrahedral
highest ionic radius are respectively
2+ 3- geometry and sp 3 -hybridisation for its central
(a) Mg , N
2+ 2- atom?
(b) Mg , O
(a) BH-4 (b) NH-2
(c) Na + , N3-
(d) Na + , O 2- (c) CO 2-
3 (d) H3O +
TS EAMCET (Engineering) Solved Papers 59
127. Diffusion of CH 4(g) and O 2(g) occurs under The correct answer is
similar conditions, then the ratio of their A B C D
rates of diffusion is (a) I V II III
(b) V III IV II
(a) 1.414 (b) 0.707 (c) 2.312 (d) 1.732
(c) IV II I III
128. The variation of compressibility factor (Z) (d) IV V II III
with pressure (p in bar) for some gases are 133. A solution of 0.1 mole of CH 3NH 2
shown in the figure below. Identify the gases
(K b = 5 ´ 10 -4 ) and 0.08 mole of HCl is
(A), (B) and (C) respectively
diluted to one litre, then the pOH of the
(B) solution is (log 125. = 0 .1)
(a) 10.1 (b) 3.9
(C)
(c) 4.9 (d) 9.9
Z (A) 134. What are two types of crystal structures
shown by ice at different pressures?
(a) Hexagonal and monoclinic
(b) Cubic and monoclinic
p (c) Hexagonal and tetragonal
(a) real gas, N2 , CO 2 (b) ideal gas, H2 ,CO 2 (d) Cubic and hexagonal
(c) ideal gas, CO 2 , H2 (d) real gas, H2 , CO 2 135. Identify X and Y respectively in the following
129. What is the equivalent weight of methanol, if reactions
Air
one mole of CH 3OH is combusted to form CO Mg(s) D
MgO+B
and H 2O? H2 O H2 O
131 . Which of the following does not follow first 136. Which one among the following statements
law of thermodynamics? (W = work; q = heat; is correct about a solution of borax in water?
DU = change in internal energy) (a) It is acidic because it contains H3BO 3 and NaOH
(b) It dissociates into NaBO 2 and B 2O 3
(a) W > 0; q > 0;DU < 0 (b) W = 0; q = 0; DU = 0
(c) It is neutral because it contains NaOH and H3BO 3
(c) W > 0; q = 0; DU > 0 (d) W < 0; q < 0;DU < 0
(d) It is alkaline because it contains NaOH and H3BO 3
132. Match the following :
137. Identify the correct statements from the
List I (Reaction) List II ( K p ) following:
A. 2SO 2( g ) + O 2( g ) - 2SO 3( g ) I. 0.98 I. Quartz is a piezoelectric material.
at 298 K II. All group 14 tetrachlorides except CCl 4
are easily hydrolysed by water
B. 2SO 2( g ) + O 2( g ) - 2SO 3( g ) II. 3.0 ´ 10 4
at 700 K III. The C ¾ C bond distance within the layer
of graphite is 154 pm.
C. N 2O 4 ( g ) - 2NO 2( g ) at 298 K III. 1700
IV. SiO 2 is soluble in aqueous HCl solution.
D. N 2O 4 ( g ) - 2NO 2( g ) at 500 K IV. 4.0 ´ 10 24 (a) I, III (b) I, II
(c) III, IV (d) II, IV
V 6.8 ´ 10 -5
60 TS EAMCET (Engineering) Online Solved Paper 2019
138. Match the following : 142. NaCl is a fcc lattice, where Na + ions are at
corner and face centre position. Chloride ions
List I List II are at edge centres and body centre positions.
A. SO 2 (i) Photochemical smog How many NaCl formula units will be in an
unit cell?
B. PAN (ii) Acid rain
(a) 2 (b) 4 (c) 3 (d) 1
C. Smoke (iii) Stratospheric pollutant
143. How many grams of glucose are required to
D. CF2Cl 2 (iv) Particulate prepare an aqueous solution of glucose
having a vapour pressure of 23.324 mm Hg at
The correct answer is 25ºC in 100 g of water? The vapour pressure
A B C D A B C D of pure water at 25ºC is 23.8 mm Hg.
(a) IV III I II (b) III I IV II (Molar mass of glucose = 180 g mol -1 )
(c) IV I III II (d) II I IV III
(a) 20.4 (b) 10.3 (c) 5.4 (d) 7.4
139. Find the suitable IUPAC name of the 144. If 0.1 M solution of NaCl is isotonic with
compound given below :
1.1 w% urea solution, the degree of ionisation
CH 2 ¾ CH 2 ¾ C ¾ CH 2 ¾ CH 2 ¾ CH ¾ CO 2H of NaCl is (molar masses of urea and NaCl are
½ ½½ ½ 60 and 58.5 g mol -1 respectively)
OH O Br (a) 2 (b) 0.83 (c) 1 (d) 1.83
145. An electrolyte of a polymer-salt complex of
(a) 2-bromo-7- hydroxy-5-oxo heptanoic acid poly (ethylene oxide) LiCF3 SO 3 is shaped
(b) 1-hydroxy-3-keto-6-bromo heptanoic acid into a free standing circular film of 20 mm
(c) 2-bromo-5-keto-7-hydroxy heptanoic acid diameter and a thickness of 20 mm. When it
(d) 5-oxo-7-hydroxy-2-bromo heptanoic acid is sandwiched between 2 stainless steel
140. The boiling point (in K) of cis but-2-ene and circular electrodes of the same diameter, this
314
dipole moment (in D) of trans but-2-ene are cell exhibits a conductance of S. What is
respectively 5
the specific conductivity of the electrolyte?
(a) 274,0.00 (b) 277,0.00
(c) 277, 0.33 (d) 274,0.33 (a) 4 m S cm -1 (b) 0.4 S cm -1
(c) 40 m S cm -1 (d) 0.004 S cm -1
141. The major product formed in the following
reaction sequence is 146. The following results have been obtained
NH2 during the kinetic studies of reaction :
(i) (CH3CO)2O/Pyridine
2NO + 2H 2 ¾¾® N 2 + 2H 2O
(ii) Conc. HNO3/Conc.H2SO4
Expt -d [NO ] [ NO] [ H2 ]
(iii) H3O/HBr mol L-1 s -1
dt mol L -1 mol L -1
NH2 NHCOCH3 1. 4.8 ´ 10 -5 1 ´ 10 -2 1 ´ 10 -3
NO2 2. 432
. ´ 10 –5
3 ´ 10 -2
1 ´ 10 -3
(a) (b) 3. 86.4 ´ 10 -5 3 ´ 10 -2 2 ´ 10 -3
147. The mass of haemoglobin in mg required to 153. Which one of the following is a
protect from coagulation of 50 mL of a gold biodegradable polymer?
sol on adding 5 mL of 10% NaCl solution is H H O O
(gold number of haemoglobin = 0 .03)
(a) 0.03 (b) 0.75 (a) [ N (CH2)6 N C (CH2)4 C ]n
(c) 0.30 (d) 0.15 O H
157. Find the correct order of acid strengths of the 159. Which of the below reactions produce
following compounds : carboxylic acids?
OH OH MnO 2
(A) (B) I. HC ºº C ¾ CH == C ¾ CH 2OH ¾¾¾®
CH 3COCH 3
½
OH OH CH 3
(C) (D)
O ( i ) aq.NaOH
MeO II. Ph ¾ CCl 3 ¾¾¾¾®
Å
( ii ) H 2O/ H
CH3
OH ( i ) Mg
III. C2H 5Br ¾¾¾¾®
OH (ii) CO 2
( iii ) H 2O/ H Å
(E) (F)
K 2Cr 2O 7 / H 2SO 2
IV. CH 3CH == CHCH 3 ¾¾¾¾¾®
NO2 D
NO2
(a) I, II, III, (b) II, III, IV
(a) F > D > E > B > C > A
(c) I, III, IV (d) I, II, IV
(b) D > F > E > C > B > A
(c) D > E > F > B > C > A 160. Find the suitable method from the following
(d) F > E > D >B > C > A to prepare primary amines without the loss
158. The compound that does not undergo of carbons.
haloform reaction is (a) Gabriel method
(b) Alkylation method
(a) CH3CHO (b) CH3CH2OH
(c) Hoffmann Bromamide method
(c) CH3COCH3 (d) C 2H5COCH2CH3
(d) Stephen method
Answers
Mathematics
1. (b) 2. (c) 3. (a) 4. (a) 5. (a) 6. (a) 7. (a) 8. (d) 9. (d) 10. (c)
11. (c) 12. (a) 13. (c) 14. (a) 15. (d) 16. (a) 17. (c) 18. (c) 19. (d) 20. (d)
21. (c) 22. (c) 23. (d) 24. (b) 25. (a) 26. (d) 27. (c) 28. (d) 29. (a) 30. (a)
31. (a) 32. (c) 33. (b) 34. (d) 35. (d) 36. (d) 37. (c) 38. (b) 39. (a) 40. (b)
41. (a) 42. (b) 43. (b) 44. (d) 45. (*) 46. (d) 47. (c) 48. (a) 49. (a) 50. (d)
51. (c) 52. (d) 53. (c) 54. (a) 55. (a) 56. (c) 57. (c) 58. (b) 59. (a) 60. (a)
61. (c) 62. (c) 63. (c) 64. (c) 65. (b) 66. (d) 67. (b) 68. (d) 69. (b) 70. (c)
71. (d) 72. (d) 73. (a) 74. (d) 75. (b) 76. (c) 77. (b) 78. (c) 79. (d) 80. (c)
Physics
81. (d) 82. (d) 83. (a) 84. (b) 85. (b) 86. (a) 87. (a) 88. (c) 89. (*) 90. (c)
91. (b) 92. (a) 93. (b) 94. (a) 95. (d) 96. (d) 97. (b) 98. (b) 99. (d) 100. (a)
101. (a) 102. (c) 103. (b) 104. (c) 105. (b) 106. (a) 107. (a) 108. (c) 109. (b) 110. (a)
111. (a) 112. (d) 113. (d) 114. (c) 115. (c) 116. (d) 117. (a) 118. (a) 119. (a) 120. (c)
Chemistry
121. (c) 122. (d) 123. (a) 124. (c) 125. (b) 126. (a) 127. (a) 128. (b) 129. (a) 130. (b)
131. (a) 132. (c) 133. (b) 134. (d) 135. (d) 136. (d) 137. (b) 138. (d) 139. (a) 140. (b)
141. (c) 142. (b) 143. (a) 144. (b) 145. (c) 146. (a) 147. (d) 148. (a) 149. (b) 150. (d)
151. (c) 152. (c) 153. (c) 154. (b) 155. (b) 156. (c) 157. (a) 158. (d) 159. (b) 160. (a)
Note (*) None of the option is correct.
Answer with Solutions
Mathematics
1. (b) We have, 5. (a) Given,
4- x 2 |adj A|=|adj (adj A)|
f (x) = 2
[x] + 2 |A|n -1 =|A|( n -1)
f (x) is defined if Þ n - 1 = (n - 1)2
4 - x2 x2 - 4 Þ n - 1 = 1 Þ n = 2 {Q n>1}
³0 Þ £0
[x] + 2 [x] + 2 The matrix
(x 2 - 4)([x] + 2) é1 2 3ù
Þ £0 ê ú
([x] + 2)2 ê 4 5 6ú has rank = 2
ê 6 7 8ú
Þ (x + 2) (x - 2) ([x] + 2) £ 0 ë û
By wavy curve method 6. (a) We have,
– + – + é1 ù é xù
ê ú ê ú
–2 –1 2 ê ú[
2 1 2 l] ê yú = 0
ê lú êzú
\ x Î (-¥ , - 2) È [-1, 2] ë û ë û
2. (c) We have, é1 2 l ù é x ù
ê úê ú
f (x) = (x + 1)2 - 1 ê 2 4 2lú ê y ú = 0
ê l 2l l2 ú ê z ú
Given f (x) = f -1 (x) ë ûë û
é1 2 l ù
Q f ( f (x)) = x ê ú
Let A = ê 2 4 2lú
( f (x) + 1)2 - 1 = x
ê l 2l l2 ú
ë û
Þ ( f (x) + 1)2 = x + 1
|A|= 1(4l - 4l ) - 2(2l - 2l2) + l(4l - 4l)
2 2 2
Þ (x + 1)4 = x + 1
|A|= 0, " l Î R
Þ (x + 1) [(x + 1)3 - 1] = 0 \The given system has non trivial solution.
Þ x = -1, x = 0 7. (a) Let, z = x + iy
x = {0, - 1}
\z - 1 - 2i = x + iy - 1 - 2i = (x - 1) + (y - 2)i
3. (a) Given, y - 2ö p
arg (z - 1 - 2i) = tan-1 æç ÷=
12 + 22 + 32 +…… + n2 > x è x -1 ø 3
n(n + 1) (2n + 1) y-2 p
Þ >x = tan = 3 Þ 3(x - 1) = y - 2
6 x -1 3
n(n + 1) (2n + 1) n(n)(2n) 3x - y + 2 - 3 = 0
Q >
6 6 Þ y = 3x + (2 - 3)
2n3 n3
\ x= Þx= 8. (d) Given,
6 3
z + 3i
4. (a) We have, <1
3z + i
é 0 a bù
ê ú x + (y + 3)i
A = ê-a 0 bú <1 [Let z = x + iy]
ê - b a 0ú 3(x + iy) + i
ë û
|x + (y + 3)i|<|3x + (3y + 1)i|
|A|= 0 for all a, b
Þ x 2 + (y + 3)2 < 9 x 2 + (3y + 1)2
\ A is skew symmetric matrix.
Hence, a = -b Þ a + b = 0 Þ x 2 + y2 + 6 y + 9 < 9 x 2 + 9 y2 + 6 y + 1
64 TS EAMCET (Engineering) Online Solved Paper 2019
( 3 - i)2016 + (- 3 - i)2019 23 -1
1 - tan2 x 1 1 1 1 1 1
Þ - 2tan x + 2 = 0 \ + - = + -
1 + tan2 x p1 p2 p3 c sin B a sin C b sin A
Þ (1 - tan2 x) - 2(tan x - 1)(1 + tan2 x) = 0 a b c 1 2(s - c) (s - c)
= + - = (a + b - c) = =
Þ (1 - tan x)(1 + tan x + 2 + 2tan2 x) = 0 2D 2D 2D 2D 2D D
1 1 1 s
Þ (1 - tan x) (2tan2 x + tan x + 3) = 0 \ + - =
p1 p2 p3 D
p p
Þ tan x = 1 Þ tan x = tan Þ x = np +
4 4 27. (c) Given,
C C
24. (b) a , b are roots of equation 3x 2 - 16 x + 5 = 0. a 2 + 2bc - (b 2 + c 2) = ab sin cos
2 2
16 5 1
\ a+b = , ab = Þ 2 2 2
a + 2bc - (b + c ) = ab sin C
3 3 2
Now,
æ a+b ö 1
tan-1 a + tan-1 b - tan-1 ç ÷ Þ a 2 - (b 2 + c 2 - 2bc) = ab sin C
è 1 - ab ø 2
æ a+b ö æ a+b ö 1
= p + tan-1 ç ÷ - tan-1 ç ÷ [Q ab >1] Þ a 2 - (b - c)2 = ab sin C
è 1 - ab ø è 1 - ab ø 2
=p 1
Þ (a - b + c) (a + b - c) = ab sin C
2
25. (a) We have, 4(s - b) (s - c) = D
sinh[log (2 + 5)] + cosh [log (2 + 3)]
s(s - a) (s - b) (s - c)
e log( 2+ 5)
-e - log ( 2+ 5)
e log( 2+ 3)
+ e - log( 2+ 3) Þ 4=
+ (s - b) (s - c)
2 2
s(s - a) A
1 1 Þ 4= Þ cot = 4
(2 + 5) - (2 + 3) + (s - b) (s - c) 2
= 2+ 5 + 2+ 3
2 2 A 1
Þ tan =
(2 + 5) - ( 5 - 2) + (2 + 3) + (2 - 3) 8 2 4
= = =4
2 2 A
2tan
Q tan A = 2
26. (d) Given, A
BC = a, AC = b 1 - tan2
2
AB = c, AD = p1 1
BE = p2, CF = p3 2 æç ö÷
è 4ø 8 15
In DABC, Þ tan A = = Þ cot A =
1 15 8
p1 1 1 1-
sin B = Þ = 16
c p1 c sin B 15 15
Þ cot[p - (B + C)] = Þ cot(B + C) = -
1 1 8 8
Similarly, =
p2 a sin C 28. (d) We have,
1 1 p1 , p2 , p3 are the altitudes of a triangle ABC from
and =
p3 b sin A the vertices A, B, C respectively.
TS EAMCET (Engineering) Solved Papers 67
1 1 1 Similarly, b = $)
2 (cos a$i + cos 45º $j + cos 45º k
\ D= ap1 = bp2 = cp3
2 2 2
cos a + cos 45º + cos2 45º = 1
2 2
D D D D
r1 = , r2 = , r3 = ,r = 1 1
s-a s-b s-c s cos2 a = 1 - æç + ö÷ = 0
è 2 2ø
1 1 1 1
\ 2 + 2+ 2+ 2 æ 1 $ 1 $ö $ $
r1 r2 r3 r \ b= 2ç j+ k÷ = j + k
(s - a)2 (s - b)2 (s - c)2 s 2 è 2 2 ø
= + + + 2 $i $j k$
D2 D2 D2 D
1 a ´b = 1 1 $
2 = (1 - 2)$i - $j + k
= 2 [4s 2 - 2s(a + b + c) + (a 2 + b 2 + c 2)]
D 0 1 1
1 a2 + b2 + c 2
= 2 (4s 2 - 4s 2 + a 2 + b 2 + c 2) = 32. (c) Let a = a1 $i + a2$j + a3 k$
D D2
$
\ x = $i ´ (a ´ $i ) = a - a1$i = a2 $j + a3 k
4D2 æ 1 1 1 ö æ1 1 1 ö
= 2 çç 2 + 2 + 2 ÷÷ = 4 çç 2 + 2 + 2 ÷÷
D è p1 p2 p3 ø è p1 p2 p3 ø y = $j ´ (a ´ $j) - a = a - a $j - a = - a $j
2 2
$ ´ (a ´ k
z=k $) - a = a - a k
$ $
29. (a) Given, 3 - a = - a 3k
(a ´ b) ´ (c ´ d) = 0 é 0 a2 a3 ù
|a ´ b||c ´ d|sin q = 0 [x y z] = ê 0 - a 2 0 ú
ê ú
Þ q = 0º êë 0 0 - a 3 úû
\Angle between plane P1 and P2 determined by [x y z] = 0
vector a , b and c, d respectively
q = 0º 33. (b) We have,
$)
r = $i + $j + t(2$i - $j + k
30. (a) We have,
r = 2$i + $j - k $ + s (3$i - 5$j + 2k
$)
OA = $i + 2$j + 3k$ and OB = 4$i + k
$
$i $j k$ Here,
$ a1 = $i + $j
Q OA ´ OB = 1 2 3 = 2$i + 11$j - 8k $
b1 = 2$i - $j + k
4 0 1
a = 2$i + $j - k$
2
Equation of line passing through B and parallel to $
OA ´ OB is b2 = 3$i - 5j$ + 2k
$ + l( 2$i + 11$j - 8k)
r = 4$i + k $ $
a 2 - a 1 = $i - k
$ $
r = (4 + 2l) i + 11l j+ (1 - 8l)k $ $i $j k $
Distance from B to line is 189. $
b1 ´ b2 = 2 -1 1 = 3$i - $j - 7k
2 2 2 3 -5 2
\ 189 = (4 + 2l - 4) + (11l) + (1 - 8l - 1)
2 2 2
189 = 4l + 121l + 64l |b1 ´ b2|= 9 + 1 + 49 = 59
189 = 189l2 (a - a 1) × (b1 ´ b2)
Shortest Distance = 2
l = ±1 |b1 ´ b2|
\Position vector lie on line B $ $)
(i - k) × (3$i - $j - 7k 10
$
r = 6$i + 11$j - 7k = =
59 59
31. (a) We have,
$) 34. (d) We have ,
a = 2(cos 60º $i + cos 60º $j + cos gk
r ´a = b
cos2 60º + cos2 60º + cos2 g = 1 |r ´ a|= |b|
1 1 1 1
cos2 g = 1 - æç + ö÷ = cos g = |r||a|sin q =|b|
è 4 4ø 2 2 |b| 3
æ1 $ 1 $ 1 $ö $ $ $ sin q = = [Q|r| = 1,|a| = 2,|b| = 3]
\a = 2 ç i + j + k ÷ = i + j + 2k |a| 2
è2 2 2 ø
\ q = 60°
68 TS EAMCET (Engineering) Online Solved Paper 2019
(r ´ a) ´ a = b ´ a \ Required probability
(r.a)a - |a |2 r = b ´ a R
P(II) ´ P æç ö÷
1 æ II ö è II ø
r = 2 [(a × r) a - b ´ a ] Pç ÷ =
|a| è R ø P(I) ´ P(R / I) + P(II) + P æ R ö
ç ÷
è II ø
1
r = ((|a||r|cos q) a - b ´ a) 1 5
4 ´
2 11 35
1 = =
Þ r = (a - (b ´ a)) 1 3 1 5 68
4 ´ + ´
2 7 2 11
35. (d) We have, 39. (a) Consider the events
2, 3, 5, 11, 13, 17, 19 A = Sum of number in two dice be greater than 9
2 + 3 + 5 + 11 + 13 + 17 + 19 70 B = Number of dice B is 5
x= = = 10
7 7 6
\ P(A) =
S(x i - x)2 64 + 49 + 25 + 1 + 9 + 49 + 81 36
s2 = =
7 7 6
P(B) =
2 278 36
s = = 39.71
7 2
P(A Ç B) =
36. (d) 36
A P(A Ç B) 2 1
Class- mid- frequency x i fi ( x i - x ) = di fi di Required probability = P æç ö÷ = = =
èBø P(B) 6 3
interval value ( x i ) ( fi )
0-2 1 1 1 4 4 40. (b) Here,
2-4 3 2 6 2 4 1
n = 5, P = 20% = ,
4-6 5 3 15 0 0 5
1 4
6-8 7 2 14 2 4 q =1- p =1- =
5 5
8-10 9 1 9 4 4
Required probability
Sfi = 9 Sfi xi = 45 Sfid i = 16
P(r ³ 2) = P(r = 2) + P(r = 3) + P(r = 4) + P(r = 5)
Sfi x i 45
x= = =5 1 2 æ 4ö
3
Sfi 9 P(r ³ 2) = 5C2 æç ö÷ ç ÷
è 5ø è 5ø
Sfi di 16
Mean deviation = = = 1.78 1 3 4 2 1 4 4 1 5
Sfi 9 + 5C3 æç ö÷ æç ö÷ + 5C4 æç ö÷ æç ö÷ + æç ö÷
è 5ø è 5 ø è 5ø è 5 ø è 5ø
37. (c) We have, 1
= (10 ´ 64 + 10 ´16 + 5 ´ 4 + 1)
P(A) = 0.3, P(B) = 0.4 and P(A Ç B) = 0.5 55
\ P(A) = 0.7, P(B) = 0.6 640 + 160 + 20 + 1 821
= =
P(A È B) = P(A) + P(B) - P(A Ç B) 3125 3125
= 0.7 + 0.6 - 0.5 = 0.8 41. (a) Here,
B ö P(B Ç (A È B)) P(A Ç B)
Q P æç ÷= = n = 500, p = 2%, q = 98%
è AÈBø P(A È B) P(A È B) Required probability
P(A) - P(A Ç B) 0.7 - 0.5 P(X £ 1) = P(X = 0) + P(X = 1)
= = = 0.25
P(A È B) 0.8 l° e - l le - l
= +
38. (b) Bag I contains 3 Red and 4 Black balls 0! 1!
Bag II contains 5 Red and 6 Black balls P(X £ 1) = e -l (1 + l)
1 1 2
P(I) = , P(II) = = e -10 (1 + 10) [Q l = np = 500 ´ = 10]
2 2 100
æ Rö 3 æ R ö 5 11
Pç ÷ = , Pç ÷ = =
I
è ø 7 II
è ø 11 e10
TS EAMCET (Engineering) Solved Papers 69
x y
42. (b) Let the point A(x , y) and B(-3, 0). Also, - =1
-4 4 / 3
Given AB ³ 2
\ a = -4, b = -4 / 3
AB2 ³ 4
Hence, 3pbp - 3aa
(x + 3) + y 2 ³ 4
2
æ -4 ö 4p
x 2 + y2 + 6 x + 5 ³ 0 = 3p ç ÷ (2) - 3(-4) = 8p
è 3ø 3
\Locus of point A is
45. (*) We have,
{(x , y) |x 2 + y 2 + 6 x + 5 ³ 0}
A(1, 2), B(3,-1), C(4, 0)
43. (b) We have, Centroid of DABC is
A1 = 3x 2 + 5xy + 3y 2 + 2x + 3y + 4 = 0 A(1, 2)
Since, axes are rotated through an angle q1
\ x = x1 cos q1 - y1 sin q1 , y = x1 sin q1 + y1 cos q1
Putting the value of x and y in A1 ,
3(x1 cos q1 - y1 sin q1)2 + 5(x1 cos q1 - y1 sin q1) O(h, k)
(x1 sin q1 + y1 cos q1) + 3(x1 sin q1 + y1 cos q1)2
+2(x1 cos q1 - y1 sin q1) + 3(x1 sin q1 + y1 cos q1) + 4 = 0 B(3, –1) C(4, 0)
Eliminating x1 y1 , we get æ1 + 3 + 4 , 2 - 1 + 0 ö = æ 8 , 1 ö
\Coefficient of x1 y1 is zero ç ÷ ç ÷
è 3 3 ø è 3 3ø
\ -6 sin q1 cos q1 + 5(cos q12 - sin q12) + 6 sin q1 cos q1 = 0 Let (h, k) be circumcentre of DABC
Þ + 5cos 2 q1 = 0 \ OA = OB = OC, OA = OB
Þ cos 2q1 = 0 Þ 2q1 = 90° Þ q1 = 45° (h - 1)2 + (k - 2)2 = (h - 3)2 + (k + 1)2
Similarly, for A2 = 5x 2 + 2 3xy + 3y 2 + 6 = 0
Þh2 - 2h + 1 + k2 - 4k + 4 = h2 - 6h + 9 + k2 + 2k + 1
5(x1 cos q2 - y1 sin q2)2 + 2 3(x1 cos q2 - y1 sin q2) Þ 4h - 6k = 5 …(i)
(x1 sin q2 + y1 cos q2) + 3(x1 sin q2 + y1 cos q2)2 + 6 = 0 Similarly, OA = OC
Eliminating x , y, we get Q (h - 1)2 + (k - 2)2 = (h - 4)2 + k2
–10sin q2 cos q2 + 2 3(cos2 q2 - sin2 q2) + 6sin q2 cos q2 = 0 Þ 6h - 4k = 11 …(ii)
2 3 Solving Eqs. (i) and (ii), we get
–2sin 2 q2 + 2 3 cos 2 q2 = 0 Þ tan 2 q2 =
2 23 7
h= , k=
tan 2 q2 = 3 Þ 2 q2 = 60° Þ q2 = 30° 10 10
For A3 = 4 x 2 + 3xy + 5y 2 - 4 = 0 Distance between circumcentre and centroid of
DABC is
After putting the value of x and y and on
2 2
elimination x , y, term, we get æ 23 - 8 ö + æ 7 - 1 ö = 11 2
ç ÷ ç ÷
-8sin q3 cos q3 + 3(cos2 q3 - sin2 q3) è 10 3 ø è 10 3 ø 30
+10sin q3 cos q3 = 0 46. (d) Equation of given lines are
- 3 x + 2y + 1 = 0 …(i)
Þ tan 2 q3 = Þ 2q3 = 120° Þ q3 = 60°
9 and x + 2y - 1 = 0 …(ii)
\ 60° > 45° > 30° 1+1 2
Distance between parallel lines = =
\ q3 > q1 > q2 1+ 4 5
44. (d) We have, A line passes through the (-5, 4) and intercept of
2
x cos a + y sin a = p is normal form of equation length is perpendicular of the given line.
5
x + 3y + 4 = 0 \Equation of line
-1 3 2x - y + l = 0
\ cos a = , sin a = - , p = 2
2 2 Since, its passes through (-5, 4)
æ p ö 4p \ l = 14
a = çp + ÷ =
è 3ø 3 Required line is 2x - y + 14 = 0.
70 TS EAMCET (Engineering) Online Solved Paper 2019
-b ö b2 5
Centre = æç 0, Putting (2, 1), we get l = -
÷ , r2 = -4 2
è 2 ø 4
Centre of circle
Circle are touch each other
æ -1 æ 5 ö -1 æ 5ö ö æ 3 1 ö
a2 b2 a2 b2 ç ç1 - ÷ , ç 3 - ÷ ÷ = ç ,- ÷
\ + = -4+ -4 è 2 è 2ø 2 è 2ø ø è 4 4 ø
4 4 4 4
54. (a) We have,
a2 b2 a2 b2 æ a2 ö æ b2 ö
+ = - 4+ - 4 + 2 çç - 4 ÷÷ çç - 4 ÷÷ (y - 1)2 = 8(x - 1)
4 4 4 4 è 4 øè 4 ø
Vertex = (1, 1)
æ a2 ö æ b2 ö Focus = (3, 1)
4= çç - 4 ÷÷ çç - 4 ÷÷
è 4 øè 4 ø End of latusrectum = (3, 5) and (3, - 3)
a 2b 2 æ a2 b2 ö Equation of circle whose centre (1, 1) and passes
16 = - 4çç + ÷ + 16 through (3, 5) and (3, -3) is
16 è 4 4 ÷ø
(x - 1)2 + (y - 1)2 = (3 - 1)2 + (5 - 1)2
a2 b2
a2 + b2 = x 2 + y 2 - 2x - 2y + 2 = 4 + 16
16
1 1 1 x 2 + y 2 - 2x - 2y - 18 = 0
Þ + =
a 2 b 2 16 55. (a) We have,
52. (d) Equation of given circles are y 2 = 4 x and x 2 + y 2 - 6 x + 1 = 0
2 2 1
x + y - 4x - 6y + 4 = 0 …(i) Tangent to parabola is y = mx +
and 2 2
x + y + 6 x - 4 y + 15 = 0 …(ii) m
1
The circle x 2 + y 2 + 2gx + 2 fy + c = 0 cuts the given y = mx + is also tangent of circle (x - 3)2 + y 2 = 8
m
circle (i) and (ii) orthogonally.
1
\ -4 g - 6 f = c + 4 …(iii) 3m +
\ 2 2= m
and 6 g - 4 f = c + 15 …(iv)
1 + m2
Also, circle is passes through (1, 1).
\ 1 + 1 + 2g + 2 f + c = 0 1
Þ ( + m2) = 9m2 +
81 +6
2g + 2 f + c = -2 …(v) m2
Solving Eqs. (iii), (iv) and (v), we get Þ (8 + 8m2)m2 = 9m4 + 1 + 6m2
3g = 4 Þ m4 - 2m2 + 1 = 0
\ 5g + 2 f + c = 3g + (2g + 2 f + c) Þ (m2 - 1)2 = 0
= 4- 2= 2
\ m = ±1
53. (c) Equation of circle passing through intersection \Common tangent of curves cuts of orthogonal
of line x + y + 1 = 0 and circle x 2 + y 2 + x + 3y = 0 is Equation of common tangents are
x 2 + y 2 + x + 3y + l(x + y + 1) = 0 y = x + 1 and y = - x -1
x 2 + y 2 + (1 + l) x + (3 + l) y + l = 0 Þ x - y + 1 = 0 and x + y + 1 = 0
x + y + 1 = 0 is chord of contact of circle \Both statements are true and (R) is correct
x 2 + y 2 + x + 3y = 0 explanation of (A).
Let (h, k) is intersection point of tangents at A and B. 56. (c) Given,
x + h 3y + 3k OT = b
\ xh + yk + + =0
2 2 AB = 2ae
(2h + 1) x + (2k + 3) y + h + 3k = 0 ÐATB = 90º
and x + y + 1 = 0 are identical \ AB2 = AT 2 + BT 2
2h + 1 2k + 3 h + 3k
\ = = (2ae)2 = 2AT 2 [Q AT = BT]
1 1 1
Solving, we get h = 2, k = 1 (2, 1)lie on circle (2ae)2 = 2(b 2 + a 2e 2)
x 2 + y 2 + (1 + l) x + (3 + l) y + l = 0 Þ 4a 2e 2 = 2b 2 + 2a 2e 2
72 TS EAMCET (Engineering) Online Solved Paper 2019
b2 59. (a) Let OA = (3$i + 4$j + 5k$ ) and OB = (4$i + 6$j + 3k$ )
Þ a 2e 2 = b 2 Þ e 2 =
a2 $
AB = $i + 2$j - 2k
T $ and OD = (i + 5k
OC = (- $i + 2$j + 4k) $)
CD = 2$i - 2$j + k$
Projection of AB on CD is
A O B AB × CD |($i + 2$j - 2k $ ) × (2$i - 2$j + k
$ )|
=
|CD| 4+ 4+1
|2 - 4 + 2|
= = 4/ 3
3
b2 60. (a) A(3, 2, 3), B(1, 4, 6) and C(7, 4, 5) are the three
Þ 1 - e2 = 1 -
a2 vertices of parallelogram ABCD
2 2 é 2 b2 ù Let M is mid-point of AC
Þ 1- e = e êQ e = 1 - 2 ú
ë a û
1 1 \ Point M = (5, 3, 4)
Þ e2 = Þe=
2 2 D C
q
x 2 y2
57. (c) Equation of tangents of ellipse + = 1 is
2 1
x M
cos q + y sin q = 1
2
The x-intercept and y-intercept are ( 2sec q, 0) and A B
(0, cos es q) respectively Direction ratio of DC is equal to direction ratio of
Let (h, k) mid-point of intercept AB and direction ratio of DB is equal to direction
2secq cosec q ratio of MB.
\ h= ,k= \ d.r of DC = (-2, 2, 3)
2 2
1 and d.r of DB = (-4, 1, 2)
Þ cos q =
2h Angle between DC and DB is
1 8 + 2+ 6
and sin q = q = cos-1
2k 4 + 4 + 9 16 + 1 + 4
Squaring and adding, we get 16
q = cos-1
1 1 17 21
+ =1
2h2 4k2 q = cos-1
16
1 1 357
Locus be + =1
2x 2 4 y 2 61. (c) Direction ratio of plane p1
x 2 3y 2 $i $
$j k
58. (b) Equation of tangent to hyperbola - =1
20 4
1 2 3 = -2$i + $j
parallel to x + 3y = 7 is
1 2 2
-1 20 4
y= x± - $)
3 9 3 Direction ratio of plane p 2 = ($i + 3$j + 2k
3y = - x ± 2 2 $ $ $ $
-(- i + 2 j - 3k) = 2$i + $j + 5k
x + 3y = 2 2 Angle between plane p1 and p 2 is
and x + 3y = -2 2 $)
(-2$i + $j) × (2$i + $j + 5k æ -4 + 1 ö
q = cos-1 = cos-1 ç ÷
Distance between parallel tangent is 4+1 4 + 1 + 25 è 5 30 ø
2 2+ 2 2 4 2 4 3 æ 6ö
d= = = q = cos-1 = Þ q = cos-1 çç ÷÷
1+ 3 2 10 5 150 è 10 ø
TS EAMCET (Engineering) Solved Papers 73
68. (d) Let the length and width of rectangle be 2 x Þ I = ò 2aq tan qsec2 qdq
and y respectively. é dq ù
Þ I = 2a ê qò tan q sec2 qdq - ò tan q sec 2 qdq. dqú + c
ë dq ò û
B
é q tan2 q tan2 q ù
Þ I = 2a ê -ò dqú + c
r
y ë 2 2 û
Þ I = a[q tan2 q - ò (sec2 q - 1)dq + c]
O x A
In DOAB Þ I = aq tan2 q - a tan q + aq + c
r 2 = x 2 + y2 Þ x 2 = 4 - y2 [Q r = 2] Þ I = q(a tan2 q + a) - a tan q + c
0 1
x etan y
= ò 1 + y2 dy
é x2 x4 ù é x2 x4 ù
= ê - ú + ê -
4 úû 0 1
-1 -1
ë 2 4 û -1 ë 2 xetan y
= e 2tan y + c ¢
2
1 1 1 1 1 1
= æç - ö÷ + æç - ö÷ = 2 ´ =
-1 -1
2xetan y
- e 2tan y
= c [where, C = 2C ¢]
è 2 4ø è 2 4ø 4 2
Physics
81. (d) There are four types of fundamental forces in 84. (b) A relative motion between rain and boy is
nature namely, (i) Gravitational force (ii) shown in the figure below,
Electromagnetic force (iii) Strong nuclear force Boy Boy
and (iv) Weak nuclear forces. W E
w = angular frequency 104. (c) Given, refractive index of first sheet m 1 = 1.6
differentiating equation w.r.t, t we get refractive index of second sheet m 2 = 1.3 and
dx wavelength of light, l = 600 nm = 600 ´10-9 m
= = Aw cos(wt + f)
dt
A Young’s double slit experiment is shown below,
= Aw[1 - sin2(wt + f)]1 / 2 (Q cos q = 1 - sin2 q) in which two thin sheets are covered the slits.
1/ 2
é x2 ù So, the path difference introduced in slit 1.
= Aw ê1 - 2 ú = w A2 - x 2
ë A û Dx1 = (m 1 - 1)t = (1.6 - 1)t = 0.6t
15W 5W Req = 15×5 = 15 W Here first, we have to find the radius of circular
45V 1 15+5 4 path, (shown in figure) which is given by relation,
2 m(KE)
R=
qB
12W
Energy emitted by lamp in exposure time, 118. (a) The given logic circuit can be redrawn as,
E 0 = Power of lamp (p) ×exposure time (t)
A A.B
E 0 = 300 ´100 ´10-3 = 3 J B
B
So, the number of photons entering to sensor is
given by
E A¢ Y=A.B+A. B
N= 0 ´ s A A.B
E A0
30 p ´10-4 So, from the above expression (boolean
= -19
´
3 ´10 4p ´102 expression)of Y the truth table is shown below,
13
Þ N = 2. 5 ´ 10
A B A B A.B A.B Y
So, the correct option is (c).
0 0 1 1 0 0 0
116. (d) Given, ground state energy of an atom,
0 1 1 0 0 1 1
E g = 10.5 eV
1 0 0 1 1 0 1
excitation energy = 7.7 eV and wavelength of
spectral line, l = 4960 Å 1 1 0 0 0 0 0
As, it is given that the excitation of 7.7 eV So, the table of A, B and Y is matches with option (a).
required to limit electromagnetic wave(EMW) of
wavelength 4960 Å, then the energy of excited 119. (a) As, change in the collector current,
state is DI c = 8.9 mA and change in emitter currert,
E1 = E g + 7.7eV = 10.5 + 7.7 DI E = 9mA
E1 = 18.2 eV So, the current amplification factor,
DI DI C
Now, the energy of photon of wavelength, 4960 Å b= C =
is DI B DI E - DI C
hc 12400 (Q DI E = DI C + DI B )
E= = = 2. 5 eV
l 4960 8.9 8.9
Þ b= = = 89
So, the next possible spectral line emitting state (9 - 8.9) 01.
energy,
Hence, the correct option is (a).
E 2 = E1 - 2. 5 eV = 18.2 - 2. 5 = 157
. eV
So, the energy of two states is 15.7eV and 18.2 eV 120. (c) Key Idea The maximum line of right distance dm
Hence, the correct option is (d). between two transmitting antenna of height hT and
receiving antenna of height hR above the earth is given
117. (a) Key Idea The mean life of a radioactive element is by,
equal to the ratio of the sum of life-time of all the active dm = 2RhT + 2RhR
atom to the total numbers of active atom. It can be
expressed as, As, given that,height of transmitting antenna ,
1 hT = 45 ´10-3 km, distance between receiving and
Mean life, (t) =
decay constant (l) transmitting antenna, dm = 40 km and radius of
eath, R = 6400 km
Since, as we know that the half-life of radioactive
nuclei is given as, Let height of receiving antenna, hR = x
0.693 By putting the values in above expression,
T1 / 2 =
l 40 = 2 ´ 6400 ´ 45 ´10-3 + 2 ´ 6400 ´ x ´10-3
So, from above expression, 40 = 24 + 2 ´ 6.4 ´ x
T1 / 2 = 0.693 t (40 - 24)2
x= = 20 m
As, 0.693 is less than 1, so the average life time is 2 ´ 6.4
more than the half life of atom. Hence, the correct option is (c).
Hence, the correct option is (a).
Chemistry
n2 Therefore, the basic character of hydroxides
121. (c) Radius of the nth orbit (rn) = 0.529 ´ Å decreases from La(OH)3 to Lu(OH)3. Hence, the
Z
correct order of basic character will be
For B 4 + ion, (Z) = 5, second orbit (n) = 2
Gd(OH)3 <Nd(OH)3 <Ce(OH)3.
0.529 ´ (2)2 0.529 ´ 4
r2 (B 4 + ) = Å= Å 125. (b) Bond order
5 5
r2 (B 4 + ) = 0.4232 Å Number of bonding electrons – Number
of anti - bonding electrons
122. (d) According to Heisenberg’s uncertainty principle: =
2
h – (10 - 5) 6
Dx. Dv ³ Bond order of N 2 is = = 2.5
4pm 2 2
where, Dx = uncertainty in position - (10 - 6) 4
Bond order of NO is = =2
Dv = uncertainty in velocity 2 2
h = Planck’s constant – 1 5
Bond order of C2 is (9 - 4) = = 2. 5
2 2
Given, the product of uncertainty in the position
+ (9 - 4) 5
and uncertainty in velocity of a particle is Bond order of N 2 is = = 2. 5
. ´10-5 m 2 s -1 . It means Dx. Dv = 579
579 . ´10-5 2 2
2 -1 2- (10 – 4) 6
m s . Also, uncertainty in the position is 1 nm. Bond order of C2 is = = 3.
2 2
\ 10-9m ´ Dv = 579
. ´10-5 m 2s -1 (Q1 nm = 10-9 m) (8 - 4)
+
Bond order of CN is =2
. ´10-5 m2s-1
579 2
or, Dv = . ´104 ms -1
= 579
10-9 m
126. (a) Boron-hydride ion (BH -4) has sp 3-hybridisation.
123. (a) If the ions derived from different atoms are Therefore, it is tetrahedral geometry.
isoelectronic, that means they all have same –
number of electrons in their electronic shells. H
Also, they will have get same electronic
configuration but their nuclear charge will differ B
because of their difference in number of protons
H H
in the nucleus. With increase in number of H
protons in the nucleus the electrons are more Tetrahedral
attracted towards nucleus thereby causing the
(b) In NH -2molecule, the number of sigma bond is
decrease in ionic radius.
2 and the number of lone pairs is 2, i.e.
The given ions are:
sp 3-hybridisation. Due to presence of 2 lone
Mg 2+ — number of protons = 12 and number of
pairs, NH -2 molecule will be bent shape similar
electrons = 10
Na + — number of protons = 11 and number of to water. –
electrons = 10
O 2- — number of protons = 8 and number of N
electrons = 10
N 3– — number of protons = 7 and number of H H
electrons = 10 Bent shape
Hence, the correct order of ionic radius of given
ions will be (c) The carbonate ion, CO 2-
3 has a trigonal planar
147. (d) Gold number is the number of milligram of 153. (c) Biodegradable polymers are a special class of
the protective colloid which prevents the polymer that can be broken into small segments
coagulation of 10 mL of red gold solution. When 1 by enzyme-catalysed reactions, using enzymes
mL of a 10 percent solution of sodium chloride is produced by microorganism. From the given
added to it. Here, gold number of Hb= 0.03 . option (c) is a biodegradable polymer.
So, mass of Hb require for 10 mL of gold is 0.03mg. It is a nylon-2-nylon-6 or nylon-2, 6 polymer. It is
So, weight (mass)require for 50 mL of gold an alternating polyamide copolymer of glycine and
solution is 0.15 mg. amino caproic acid and is biodegradable.
148. (a) Chlorine can be manufactured by electrolysis H O H O
of a sodium chloride solution (brine). The
production of chlorine results in the co-products N CH2 C C (CH2)5 C
n
of caustic soda (sodium hydroxide, NaOH) and Polyamide linkage (Nylon-6, 6)
hydrogen gas (H 2).
At cathode 2H + (aq) + 2 e - ¾® H 2(g)
154. (b) Trypsin is responsible for breakdown of
proteins into amino acid. It is a human pancreatic
1
At anode Cl – (aq) ¾® Cl 2(aq) + e - enzyme which breakdown proteins into amino
2 acids along with several other enzymes like,
or 2Cl - (aq) ¾® Cl 2(g) + 2e - carboxy peptidase and dipeptidase.
TS EAMCET (Engineering) Solved Papers 89
155. (b) Analgesic These are the drugs which are In case (D) para hydroxy acetophenone ¾ COCH 3
used for relieving pain. Codeine is an important group shows less (-R) effect than ¾NO 2 group.
analgesic. So, it will be less acidic than para nitrophenol.
Tranquilizer The drugs which act on the central In case (E), m-nitrophenol will show less acidic
nervous system and help in reducing anxiety are character than D because in this case only -I effect
called tranquilizers. Phenalzine is a tranquilizer. is present.
In case (C) ¾ OMe is a electron releasing group
Antibiotic Antibiotics are defined as chemical
which decrease the stability of phenoxide ion by
substances produced by microorganisms that can
increasing electron density so it will be less acidic
inhibit the growth or even destroy other
than (B) and in case of (A) resonance is not
micro-organisms. Protonsil is an antibiotic.
present, Hence, it will be less acidic than C.
Antihistamine These drugs are also called as Hence, the correct order of acidic strengths of acid
anti-allergic drug and are used to treat allergy. is
Terfenadine is an antihistamine. Hence, correct
F >D >E >B >C > A
match is
A-III, B-I, C-IV, D-II. 158. (d) The Haloform reaction is given by aldehydes
and ketones containing three a-H atoms and
156. (c) æ ö
ç ÷
CH3 ç ÷
(CH3)3 CO–K+, (CH3)3COH alcohols containing ç CH 3 ¾ CH ¾ ÷ group.
CH3CH2 C CH3 ç ÷
½
çç OH ÷÷
Br H3 C CH3 H2C CH3 è ø
C C + C CH2 In other words all the methyl ketones
H3 C CH3 H3C æ ö
ç ÷
27% 73% ç ÷
ç CH 3 ¾ C ¾ ÷ and only acetaldehyde (ethanal)
(Internal alkene) (Terminal alkene) ç || ÷
ç O ÷
è ø
So, in this reaction potassium tert-butoxide in
(CH 3CHO) can give this test.
tert-butyl alcohol [(CH 3)3CO -K + in(CH 3)3COH] is
NaOH + I 2 M NaOH
used to obtain the maximum percentage of CH 3 ¾ CHO ¾¾¾¾®I 3C ¾ CHO ¾¾®
terminal alkene by dehydrohalogenation of or NaOH M
CH 3CH 2C(CH 3)2 Br. HCOO – + CHI 3
Note When a more hindered base is used, more of O
the thermodynamically less favoured terminal alkene || NaOH + I 2
is generated. CH 3 ¾ C ¾ CH 3 ¾¾¾¾®CH 3COO – + CHI 3
NaOH+I
2
If we will use other base then the reaction takes CH 3CH 2OH ¾¾¾¾® CHI 3 + HCOO -
place as follows:
NaOH + I 2
CH3
C2H 5COCH 2CH 3 ¾¾¾¾® does not give Haloform
CH2 CH3 H test.
CH3CH2O–Na+
CH3CH2 C CH3 C C +
CH3CH2OH
CH3
159. (b)
H
Br 51% 2 MnO
I. HC ºº C ¾ CH == C ¾ CH 2OH ¾¾¾¾®
½ CH3COCH3
CH2 CH3 CH 3
CH3
5 4 3 2 1
C C + CH3 CH2 CH2 CH CH2 HC ºº C ¾ CH == C ¾ CHO
H H 31% ½
18% CH 3
2-methyl pent-2-ene, 4-yne-1-al
157. (a) In case (F) para nitrophenol -R effect of (i)aq. NaOH
(¾NO 2) group at para position of benzene ring II. Ph ¾ CCl 3 ¾¾¾¾®PhC(OH)3
increase its acidity by electron withdrawing effect
2 (i)H O/ H+
of ¾NO 2 group. ¾¾¾¾® PhCOOH
Benzoic acid
90 TS EAMCET (Engineering) Online Solved Paper 2019
(i)Mg O
III. C2H 5 Br ¾¾®C2H 5MgBr
– + COOH C H
O MgBr OH D H
N H
+ –H2O
O –H2O
(ii) CO2 (iii) H2O / H
C — C 2H5 C — C2H5 COOH C
O O Phthalic
Propanoic acid acid O
Phthalic O
K 2 Cr2 O 7 / H 2SO 4 anhydride
IV. CH 3CH == CHCH 3 ¾¾¾¾¾® 2CH 3COOH
D (Acetic acid
or ethanoic acid) NH
In reaction (II),(III),(IV) acids are formed. But in
reaction (I) aldehyde is formed. O
Phthalimide
160. (a) Gabriel method is the suitable method for the
preparation of primary amines without the loss of O O
r s
carbons. This reaction is used for the preparation Alc. K O H
of 1º aliphatic amine and 1º aromatic amine RX sr
N R NK
(containing electron withdrawing group at o-and –KX
p- position e.g. NO 2 group).
N-alkyl
Phthalimide on treatment with ethanolic KOH phthalide O O
forms potassium salt of phthalimide which on Potassium phthalimide
heating with RX followed by either alkaline COOH
hydrolysis or hydrazinolysis with hydrazine H+/H2O
(H 2N.NH 2) produces the corresponding 1º amine. s + RNH2
OH H2O 1° amine
COOH
Phthalic acid