VIDYA BHARATI GHINMAYA VIDYALAYA

F.tl'4TA'J <?' | ''5

PREBOARDEMMINATION-2U5 fcHE
SET-2

Maximum Marks:7O
Time allowed: 3 hours
General Instructions:
a) All the questions are compulsory'
b) There are 26 questions in total'
questions and carry one mark each'
c) Questions 1 to 5 are very short answer type
d) Questions 6 to 10 carry tvvo marks each'
e) Questions 11 to 22 carry three marks each'
Questions 23 is value based
question carying four marks'
fl
g) Ouestions 24to26carryfive markseach' nre one
-L^:-^ L--
--_, choice
internal been provided in one question c)f two marks,
has r,.aan
h) There is no overall choice. However, an only one of the choices in
each. You have to attempt
question of three marks and all three questions in five marks

(a) Sucrose (b) Lactose?

1. What is the hydrolysis product of
2. Give 1UPAC name of CH ICOCH zCOCH s'
used to concentrate
3. An ore sample of galena is contaminated
with zinc blende' Name the chemical which can be
galena selectively by forth floatation method'

4.Thedecompositionreactionofammoniagasonp|atinumsurfacehasarateconstantk=2.5x10-4mo|L/S'
What is the order of the reaction?

5. What arcL2-16 and 13 * 15 compounds? Give examples'

5. What type of linkage holds together the

monomers of D'N'A?

effect of catalyst on the rate of reaction'

7. a) Define threshold energy of a reaction. b) Give the

8. Which is a stronger acid phenol or cresol? Explain'

9.a)HowisDacronobtained?b)Givetwoexamp|esofbiodegradablepo|ymer.

Or {a) Give the difference between Buna-N

and Buna-S'
PVC' Polythene'
polymer and condensation polYmer Terylene' Bakelite'
{b) classify the following as addition
(b) Pure zinc oxide
10. Give reasons for the following (a) Frenkel
defect does not change the density of Agcl crystal'
is white solid but turns yellow on heating
)lcu
ff:Ftn1nhE-GiEESEnergy cnange or rne rorrewr
E Ocr 3+ lCr = -0.75 V and E OCu 2+ lCu =
+0'34 V

12.a)Low|evelnor.adrena|ineisthecauseofdepression.Whattypeofdrugsisneededtocurethisproblem?G|ve
two examPles.

b) What are fillers and builders in soaps?

13. a) Write down the equations for hydrolysis of X F+ and

XeFo'

Give reasons'
b) Which of these to reactions is a Redox reaction?
 14.

:,H:[,"ffi:3:il:illilJ-i:ilil;#;r to wash crothes with water containins

dissorved carcium hydrogen

ii. Give an advantage ofsoaps

over synthetic detergents.

Or

i. What are anti_fertility drugs? Give

two examples.
ii. why ranitidine better antacids
than sodium bicarbonate or magnesium
hydroxide?

treated with H za/H zso4 gives

c+Hroo which cannot be resorved
'f,i:#,|:n:ilL:ljj,.,ilt:il3,iltJ::#hen
16' ' why o-hydroxybenzaldehyde
is a tiquid at room temperature
solid? whire p-hydroxybenzardehyde is
a high merting

1.7. Distinguish between with appropriate

tests of:
a) Propanoyl chloride and propanoic
acid.
b) Acetophenone and benzophenone.

c) Phenol and benzoic acid.

d) Benzoicacid and ethyl benzoate.

18' A metal ion M 0+ having d

4 valence electronic configuration
complex compound. Assuming combines with three didentate ligands
A 0 r p, to form a

(i) Draw the diagram showing

d orbitar spritting during this comptex
formation.
(ii) write the electronic
configuration of the valence erectrons
of the metar M n+ ion in terrns of t2g and e g.
(iii) What type of hybridization
will M n+ ion have?
(iv) Name the type of isomerism
exhibited by this complex.
f 9' calculate the amount of KCI which
must be added to 1 kg of water
so that the freezing point is depressed
by (

20. Explain each of the following

a' The bond angres (o

- N- o) are not of the same varue in 2 No
- and 2 NO +
b. The stability of +5 6;;6.1ion
state decrease down the group 15.

c. Nitrogen is much less reactive than

phosphorus

21' The Rate of a particular reaction

triples when temperature change
activation energy of the reaction.fGiven from 50 0 c to 100 0 c. calcurate
rog3=0.4771: R = g.314 JK -i mot _r] the

or neutrar. How does this happen?

:i,ffl:lr||'i:il:'":::?::Hliile what are essentiar and non-essentiar
 ,ttill',..o.,#{:i:qH*";;lf[1;l1;:iff;TiiJ:l:;r"r**e,ivingtheresincelastnveyears when
or shobha after coming r'o'n
'.r'ooi.o,r,ed
his Mothe' il;;;ii.:J;T,TfljlT:f|fl::r,ffi?}],flr"H;:"
:ffi:Iili:1ffi:i:tT::ru1,t#mXmi;lt..ii,i",,o*,h orphvtop,air,,on Mrs shobha
and her
Read the above passage
and answer the following question
a. What values are expressed
by Ravi and His mother?
b' why phytoprankton grow
excessivery while they were
using detergents?
24. The compounds A
and B dehydrobrominates
compounds by the addition to give the same c which can resenerate both
of Hgr in presenc.e and ibsence these
and B gives o",.,,lXlil1X*:::]i:d': "l oi r,vorggqn
&:il::;?T;-"'n""" peroxide respeitively. on hydrorysiS
1,1-diphenyre,nr""f Sl,liinl',il1ff"'ffff: .::,ffiffi*
J
"i "i,r'
u"n,un" in p;;. A
or hydrogen ions yierds

E with reactions.

OR

An organic compound ?' (c

aHo) reacts with ditute
forming compounds 'c' and H zsoa and Hgso giving .B'
'o'':o; uoon'reaclion *itt .ooa iim"?o4 which reacts with NaoH and
|2
acetyl chloride in presence s hydrocarbon ,E, which
of anhyorous atminum .hrorioe on reaction with
equation. eiueJ;'. ra"niirv e,e,c,i *o'a and write
the reaction
25' a) Derive the refationship
between relative lowering
liquid. of vapour pressure and rnore
fraction of the voratire

in benzene. what wir be thevapour pressure

- --o vL' '&s' 'e wrrclt rne vapour pressure of pure benzene
iiili::iT,:1T?TiiT:lt:il"#ff ora sorution containing6lg
6606 torr? at the tempeiature of experiment is
ii) what woufd have been
the vapour pressure in the
mole fractions and vapour pressure absence of dimerization?
iii) Derive a rerationship between
ofa component of an idear
sorution in the tiquid phase
and vapour phase.
Or

a) which aqueous solution

has higher concentration -r.
molar or I moraf sorution of
the same sorute? Give reason.

JJ':"'fi[: [n1;ffii:?,.'l?-#ffiil5,',::':';];l:'",,, ar 20 0c, rreeze at-0.24 0c, carcu,ate the

26' ' A translucent white waxy
solid (A) on heating.in an inert
Allotrope (A) on reaction with atmosphere is converted
very air"i".q"""us KoH riberates to its alrotropic form (B).
smett' with excess of chrorine
ro'r ; ;i!t
poisonous gas (c) having
rJirijJhvdrorvses;;;;;#d (E). rdentify compounds rotten fish
(A) to (r) .
Or

Explain the following properties

of transition elemen$:
a) Enthalpy of atomization.

b) Variable oxidation state.

c) Coloured complex formation.