SAFETY DATA SHEET

OXONIA ACTIVE 150

Section: 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : OXONIA ACTIVE 150

Other means of identification : Not applicable.

Recommended use : Sanitizer - Food contact surface

Product dilution information : 0.05 % - 1.0 %

Company : Ecolab New Zealand

2 Daniel Place
Te Rapa, Hamilton New Zealand
+64 7 958 2319

Emergency telephone : 0800 243 622 (0800 CHEMCALL)

number

Issuing date : 10.04.2017

Section: 2. HAZARDS IDENTIFICATION

HSNO Hazard classification

Product AS SOLD
Organic Peroxides : 5.2 F
Corrosive to Metals : 8.1 A
Acute toxicity (Oral) : 6.1 D
Acute toxicity (Inhalation) : 6.1 D
Acute toxicity (Dermal) : 6.1 E
Skin corrosion : 8.2 B
Serious eye damage : 8.3 A
Specific Target Organ : 6.9 A
Systemic Toxicity (Single
Exposure or Repeated
Exposure) (Inhalation)
Specific Target Organ : 6.9 B
Systemic Toxicity (Single
Exposure or Repeated
Exposure) (Oral)
Aquatic toxicity (Acute or : 9.1 B
Chronic)
Ecotoxic to terrestrial : 9.3 B
vertebrates

Product AT USE DILUTION

Not a hazardous substance or mixture.

GHS Label element

Product AS SOLD
Hazard pictograms :

Signal Word : Danger

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Hazard Statements : Heating may cause a fire.

May be corrosive to metals.
Harmful if swallowed.
May be harmful in contact with skin.
Causes severe skin burns and eye damage.
Harmful if inhaled.
Causes damage to organs if inhaled.
May cause damage to organs if swallowed.
Toxic to aquatic life with long lasting effects.
Toxic to terrestrial vertebrates.

Precautionary Statements : Prevention:

Keep away from heat, hot surfaces, sparks, open flames and other
ignition sources. No smoking. Keep only in original container. Keep
cool. Keep/Store away from clothing and other combustible materials.
Ground and bond container and receiving equipment. Wear protective
gloves/ protective clothing/ eye protection/ face protection. Take any
precaution to avoid mixing with combustibles. Do not breathe
dust/fume/gas/mist/vapours/spray. Wash skin thoroughly after
handling. Do not eat, drink or smoke when using this product. Use
only outdoors or in a well-ventilated area. Avoid release to the
environment.
Response:
In case of fire: Use dry sand, dry chemical or alcohol-resistant foam
for extinction. IF SWALLOWED: Rinse mouth. Do NOT induce
vomiting. IF ON SKIN (or hair): Remove/ Take off immediately all
contaminated clothing. Rinse skin with water/ shower. IF INHALED:
Remove victim to fresh air and keep at rest in a position comfortable
for breathing. IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. IF exposed or if you feel unwell: Call a POISON CENTER or
doctor/ physician. Specific treatment (see supplemental first aid
instructions on this label). Wash contaminated clothing before reuse.
Absorb spillage to prevent material damage. Collect spillage.
Storage:
Store in a well-ventilated place. Keep container tightly closed. Store
locked up. Store in corrosive resistant container with a resistant inner
liner. Store away from other materials. Protect from sunlight. Do not
expose to temperatures exceeding 50 °C/ 122 °F.
Disposal:
Dispose of contents/ container to an approved waste disposal plant.

Product AT USE DILUTION

Precautionary Statements : Prevention:
Wash hands thoroughly after handling.
Response:
Get medical advice/ attention if you feel unwell.
Storage:
Store in accordance with local regulations.

Product AS SOLD
Other hazards : Do not mix with bleach or other chlorinated products – will cause
chlorine gas.

Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS

Product AS SOLD
Pure substance/mixture : Mixture

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Chemical Name CAS-No. Concentration: (%)

Acetic acid 64-19-7 30 - 60
Peroxyacetic acid 79-21-0 10 - 30
Hydrogen peroxide 7722-84-1 10 - 30

Product AT USE DILUTION

No hazardous ingredients

Section: 4. FIRST AID MEASURES

Product AS SOLD
In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at
least 15 minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. Get medical attention immediately.

In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Use
a mild soap if available. Wash clothing before reuse. Thoroughly clean
shoes before reuse. Get medical attention immediately.

If swallowed : Rinse mouth with water. Do NOT induce vomiting. Never give
anything by mouth to an unconscious person. Get medical attention
immediately.

If inhaled : Remove to fresh air. Treat symptomatically. Get medical attention

immediately.

Protection of first-aiders : If potential for exposure exists refer to Section 8 for specific personal
protective equipment.

Notes to physician : Treat symptomatically.

Most important symptoms : See Section 11 for more detailed information on health effects and
and effects, both acute and symptoms.
delayed

Product AT USE DILUTION

In case of eye contact : Rinse with plenty of water.

In case of skin contact : Rinse with plenty of water.

If swallowed : Rinse mouth. Get medical attention if symptoms occur.

If inhaled : Get medical attention if symptoms occur.

Section: 5. FIREFIGHTING MEASURES

Product AS SOLD
Suitable extinguishing media : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.

Unsuitable extinguishing : None known.

media

Specific hazards during : Special protective equipment for firefighters

firefighting Oxidizer. Contact with other material may cause fire.
Oxidizer; material is an oxidizer which may readily react with other

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materials, especially upon heating.

Exposure to decomposition products may be a hazard to health.

Hazardous combustion : Decomposition products may include the following materials:

products Carbon oxides

Special protective equipment : In case of fire, wear a full face positive-pressure self contained
for firefighters breathing apparatus and protective suit.

Specific extinguishing : Collect contaminated fire extinguishing water separately. This must
methods not be discharged into drains. Fire residues and contaminated fire
extinguishing water must be disposed of in accordance with local
regulations. In the event of fire and/or explosion do not breathe fumes.

Hazchem Code : 2W

Section: 6. ACCIDENTAL RELEASE MEASURES

Product AS SOLD
Personal precautions, : Ensure adequate ventilation. Keep people away from and upwind of
protective equipment and spill/leak. Avoid inhalation, ingestion and contact with skin and eyes.
emergency procedures When workers are facing concentrations above the exposure limit they
must use appropriate certified respirators. Ensure clean-up is
conducted by trained personnel only. Refer to protective measures
listed in sections 7 and 8.

Environmental precautions : Do not allow contact with soil, surface or ground water.

Methods and materials for : Stop leak if safe to do so. Never soak up spilled or leaked acids and
containment and cleaning up bases with sawdust, wood chips or similar materials. Isolate the waste
do not allow it to come into contact with incompatible materials. For
small spills contain with sand or vermiculite and dilute the contained
product at least 10 times with water. Transfer to an open topped
container and remove to a safe place for neutralization* / disposal. For
large spills contain spill and evacuate the area, leave until the reaction
subsides, then collect up for disposal. Obtain consent from the local
water company / authority if considering discharge to sewer.
*NEUTRALIZATION : once diluted, neutralize with a suitable alkali
such as sodium bicarbonate.

Product AT USE DILUTION

Personal precautions, : Refer to protective measures listed in sections 7 and 8.
protective equipment and
emergency procedures

Environmental precautions : No special environmental precautions required.

Methods and materials for : Stop leak if safe to do so. Contain spillage, and then collect with non-
containment and cleaning up combustible absorbent material, (e.g. sand, earth, diatomaceous
earth, vermiculite) and place in container for disposal according to
local / national regulations (see section 13). Flush away traces with
water. For large spills, dike spilled material or otherwise contain
material to ensure runoff does not reach a waterway.

Product AS SOLD
Emergency Management Trigger Levels

The following triger level applies:

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Emergency Plan : 100 L

Signage : 10 L

Section: 7. HANDLING AND STORAGE

Product AS SOLD
Advice on safe handling : Do not ingest. Do not breathe dust/fume/gas/mist/vapours/spray. Use
only with adequate ventilation. Wash hands thoroughly after handling.
Do not get in eyes, on skin, or on clothing. Do not mix with bleach or
other chlorinated products – will cause chlorine gas.

Conditions for safe storage : Keep in a cool, well-ventilated place. Keep away from reducing
agents. Keep away from strong bases. Keep away from combustible
material. Keep out of reach of children. Keep container tightly closed.
Store in suitable labeled containers. Pressure bursts may occur due to
gas evolution if the container is not adequately vented.

Storage temperature : -10 °C to 50 °C

Product AT USE DILUTION

Advice on safe handling : Wash hands after handling. For personal protection see section 8.

Conditions for safe storage : Keep out of reach of children. Keep container tightly closed. Store in
suitable labeled containers.

Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Product AS SOLD
Components with workplace control parameters

Components CAS-No. Form of Permissible Basis

exposure concentration
Acetic acid 64-19-7 WES-TWA 10 ppm NZ OEL
25 mg/m3
WES-STEL 15 ppm NZ OEL
37 mg/m3
Hydrogen peroxide 7722-84-1 WES-TWA 1 ppm NZ OEL
1.4 mg/m3

Engineering measures : Effective exhaust ventilation system. Maintain air concentrations

below occupational exposure standards.

Personal protective equipment

Eye protection : Safety goggles

Face-shield

Hand protection : Wear the following personal protective equipment:

Laminate film
Nitrile
Unsupported neoprene
PVC
Natural rubber
Neoprene/natural rubber blend
Gloves should be discarded and replaced if there is any indication of
degradation or chemical breakthrough.

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Skin protection : Personal protective equipment comprising: suitable protective gloves,

safety goggles and protective clothing

Respiratory protection : When workers are facing concentrations above the exposure limit they
must use appropriate certified respirators.

Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice. Remove and wash contaminated clothing before re-use.
Wash face, hands and any exposed skin thoroughly after handling.
Provide suitable facilities for quick drenching or flushing of the eyes
and body in case of contact or splash hazard.

Product AT USE DILUTION

Engineering measures : Good general ventilation should be sufficient to control worker
exposure to airborne contaminants.

Personal protective equipment

Eye protection : No special protective equipment required.

Hand protection : No special protective equipment required.

Skin protection : No special protective equipment required.

Respiratory protection : No personal respiratory protective equipment normally required.

Section: 9. PHYSICAL AND CHEMICAL PROPERTIES

Product AS SOLD Product AT USE DILUTION

Appearance : liquid liquid
Colour : colourless colourless
Odour : pungent vinegar-like
pH : 1.0 - 2.0, 100 % 4.0 - 6.0
Flash point : 96 °C closed cup, Does not sustain combustion.
Odour Threshold : no data available
Melting point/freezing point : no data available
Initial boiling point and : > 100 °C
boiling range
Evaporation rate : no data available
Flammability (solid, gas) : no data available
Upper explosion limit : no data available
Lower explosion limit : no data available
Vapour pressure : no data available
Relative vapour density : no data available
Relative density : 1.06 - 1.18
Water solubility : soluble
Solubility in other solvents : no data available
Partition coefficient: n- : no data available
octanol/water

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Auto-ignition temperature : no data available

Thermal decomposition : no data available
Viscosity, kinematic : no data available
Explosive properties : no data available
Oxidizing properties : no data available
Molecular weight : no data available
VOC : no data available

Section: 10. STABILITY AND REACTIVITY

Product AS SOLD
Chemical stability : Stable under normal conditions.

pressure build-up

Possibility of hazardous : Do not mix with bleach or other chlorinated products – will cause
reactions chlorine gas.

Conditions to avoid : Direct sources of heat.

Exposure to sunlight.

Incompatible materials : Metals

Bases
Organic materials

Hazardous decomposition : Decomposition products may include the following materials:

products Carbon oxides

Section: 11. TOXICOLOGICAL INFORMATION

Information on likely routes of : Inhalation, Eye contact, Skin contact

exposure

Potential Health Effects

Product AS SOLD
Eyes : Causes serious eye damage.

Skin : May be harmful in contact with skin. Causes severe skin burns.

Ingestion : Harmful if swallowed. Causes digestive tract burns.

Inhalation : Harmful if inhaled. May cause nose, throat, and lung irritation.

Chronic Exposure : May cause damage to organs. May cause damage to organs through
prolonged or repeated exposure.

Product AT USE DILUTION

Eyes : Health injuries are not known or expected under normal use.

Skin : Health injuries are not known or expected under normal use.

Ingestion : Health injuries are not known or expected under normal use.

Inhalation : Health injuries are not known or expected under normal use.

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Chronic Exposure : Health injuries are not known or expected under normal use.

Experience with human exposure

Product AS SOLD
Eye contact : Redness, Pain, Corrosion

Skin contact : Redness, Pain, Corrosion

Ingestion : Corrosion, Abdominal pain

Inhalation : Respiratory irritation, Cough

Product AT USE DILUTION

Eye contact : No symptoms known or expected.

Skin contact : No symptoms known or expected.

Ingestion : No symptoms known or expected.

Inhalation : No symptoms known or expected.

Toxicity

Product AS SOLD
Product
Acute oral toxicity : Acute toxicity estimate : 31.99 mg/kg
Acute inhalation toxicity : 4 h Acute toxicity estimate : 0.31 mg/l
Acute dermal toxicity : Acute toxicity estimate : 3,376 mg/kg
Skin corrosion/irritation : no data available
Serious eye damage/eye : no data available
irritation
Respiratory or skin : Does not cause respiratory sensitisation.
sensitization
Carcinogenicity : no data available
Reproductive effects : no data available
Germ cell mutagenicity : no data available
Teratogenicity : no data available
STOT - single exposure : no data available
STOT - repeated exposure : no data available
Aspiration toxicity : no data available

Section: 12. ECOLOGICAL INFORMATION

Product AS SOLD
Ecotoxicity
Environmental Effects : Toxic to aquatic life with long lasting effects.

Product
Toxicity to fish : no data available

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Toxicity to daphnia and other : no data available

aquatic invertebrates
Toxicity to algae : no data available
Components
Toxicity to fish : Acetic acid
96 h LC50 Oncorhynchus mykiss (rainbow trout): 1,000 mg/l

Peroxyacetic acid
96 h LC50: 0.8 mg/l

Components
Toxicity to daphnia and other : Acetic acid
aquatic invertebrates 48 h EC50 Daphnia magna (Water flea): 39.6 mg/l

Peroxyacetic acid
48 h EC50: 0.73 mg/l

Components
Toxicity to algae : Acetic acid
72 h EC50 Skeletonema costatum (marine diatom): 1,000 mg/l

Peroxyacetic acid
72 h EC50: 0.7 mg/l

Hydrogen peroxide
72 h EC50: 1.38 mg/l

Persistence and degradability

Product AS SOLD
Readily biodegradable.

Bioaccumulative potential
no data available

Mobility in soil
no data available

Other adverse effects

no data available

Section: 13. DISPOSAL CONSIDERATIONS

Product AS SOLD
Disposal methods : Where possible recycling is preferred to disposal or incineration. If
recycling is not practicable, dispose of in compliance with local
regulations. Dispose of wastes in an approved waste disposal facility.

The product should not be allowed to enter drains, water courses or

the soil.

Disposal considerations : Dispose of as unused product. Empty containers should be taken to

an approved waste handling site for recycling or disposal. Do not re-
use empty containers. Dispose of in accordance with local, state, and
federal regulations.

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Product AT USE DILUTION

Disposal methods : Diluted product can be flushed to sanitary sewer.

Disposal considerations : Dispose of in accordance with local, state, and federal regulations.

Section: 14. TRANSPORT INFORMATION

Product AS SOLD

The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are
in compliance with the selected mode of transport.

Land transport (NZ_DG)

UN number : 3109
Description of the goods : ORGANIC PEROXIDE TYPE F, LIQUID
(Peroxyacetic acid)
Class : 5.2 (8)
Hazchem Code : 2W
Environmentally hazardous : No

Sea transport (IMDG/IMO)

UN number : 3109
Description of the goods : ORGANIC PEROXIDE TYPE F, LIQUID
(Peroxyacetic acid)
Class : 5.2 (8)
Marine pollutant : No

Special precautions for user : None

Section: 15. REGULATORY INFORMATION

Product AS SOLD
HSNO Approval Number : HSR002630

HSNO Group Standard : Organic Peroxides, Corrosive Group Standard 2006.

The components of this product are reported in the following inventories:

United States TSCA Inventory :

On TSCA Inventory

Canadian Domestic Substances List (DSL) :

All components of this product are on the Canadian DSL.

Australia. Industrial Chemical (Notification and Assessment) Act :

On the inventory, or in compliance with the inventory

New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand :

On the inventory, or in compliance with the inventory

Japan. ENCS - Existing and New Chemical Substances Inventory :

On the inventory, or in compliance with the inventory

Korea. Korean Existing Chemicals Inventory (KECI) :

On the inventory, or in compliance with the inventory

Philippines Inventory of Chemicals and Chemical Substances (PICCS) :

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OXONIA ACTIVE 150

On the inventory, or in compliance with the inventory

China Inventory of Existing Chemical Substances :

On the inventory, or in compliance with the inventory

Taiwan Chemical Substance Inventory :

On the inventory, or in compliance with the inventory

Section: 16. OTHER INFORMATION

Issuing date : 10.04.2017

Version : 1.3
Prepared by : Regulatory Affairs

REVISED INFORMATION: Significant changes to regulatory or health information for this revision is
indicated by a bar in the left-hand margin of the SDS.

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information
and belief at the date of its publication. The information given is designed only as a guidance for safe
handling, use, processing, storage, transportation, disposal and release and is not to be considered a
warranty or quality specification. The information relates only to the specific material designated and
may not be valid for such material used in combination with any other materials or in any process,
unless specified in the text.

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