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Revision Test 1 Aldehydes and Chemical Kinetics

The document is an examination paper for Chemistry for Class XII at Chinmaya Vidyalaya, Vaduthala, consisting of multiple-choice questions, short answer questions, and longer problem-solving questions. It covers various topics including reaction rates, properties of carboxylic acids, catalytic effects, and isomer identification. The paper is structured into three sections with varying marks allocated to each question.

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11 views2 pages

Revision Test 1 Aldehydes and Chemical Kinetics

The document is an examination paper for Chemistry for Class XII at Chinmaya Vidyalaya, Vaduthala, consisting of multiple-choice questions, short answer questions, and longer problem-solving questions. It covers various topics including reaction rates, properties of carboxylic acids, catalytic effects, and isomer identification. The paper is structured into three sections with varying marks allocated to each question.

Uploaded by

fathimasakeer13
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
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STD XII CHINMAYA VIDYALAYA, VADUTHALA Maxmark-25

CHEMISTRY Time-1 hour


SECTION-A (One mark each)

1. The rate constant of a first order reaction depends on the


(a) concentration of the reactant (b) time of reaction
(c) temperature (d) extent of reaction occurred

2. The correct statement from the following is


(a) The boiling points of carboxylic acids are lower than those of alcohols of comparable molecular mass
(b) The pKa value of chloroacetic acid is higher than that of acetic acid
(c) Ethanoic acid when heated with soda lime gives ethane
(d) Carboxylic acids liberate H2 when treated with sodium

3. Which of the following reagents can convert CH2 = CH – CH2 – CH2OH to CH2 = CH – CH2 – CHO
(a) HNO3 (b) H2 / Pd-BaSO4 (c) B2H6 / THF (d) PCC / CH2Cl2

4. Which of the following is true for a positive catalyst?


(i) It decreases activation energy
(ii) It alters reaction mechanism
(iii) It shortens the time to attain equilibrium
(iv) It increases equilibrium concentration of the products
(a) (i) and (ii) (b) (i) and (iii) (c) (iii) and (iv) (d) (i), (ii), and (iii)

5. The product obtained when benzoic acid is treated with chlorine in presence of FeCl 3 is
(a) 2-Chlorobenzoicacid (b) 3-Chlorobenzoicacid (c) Chloro benzene (d) Benzoyl chloride

SECTION-B (Two marks each)


6. Explain the following reactions: (a) Clemmensen reduction (b) Stephen reaction

7. Arrange the following in the increasing order of their property indicated:


(a) Ethanal, Propanone, Propanal, Butanone (reactivity towards nucleophilic addition)
(b) 4-Nitrobenzoic acid, benzoic acid, 3,4-Dinitrobenzoic acid, 4-Methoxy benzoic acid (Acid strength)

8. For a chemical reaction R → P, the variation in the concentration, ln [R] vs. time (s) plot is given as

(i) Predict the order of the reaction.


(ii) What is the slope of the curve?
(iii) Write the unit of rate constant for this reaction.

9. For a first order reaction, show that time required for 3/4th completion of the initial concentration of the reactant
is twice the time required for the half life?

SECTION-C (Three marks each)

10. How will you convert the following?


(i) Nitrobenzene into aniline
(ii) Ethanoic acid into methanamine
(iii) Aniline into N−phenylethanamide
11. (A), (B) and (C) are three non-cyclic functional isomers of a carbonyl compound with molecular formula C 4H8O.
Isomers (A) and (C) give positive Tollens' test whereas isomer (B) does not give Tollens' test but gives positive
Iodoform test. Isomers (A) and (B) on reduction with Zn(Hg)/conc. HCl give the same product (D)?

12. The following data were obtained during the first-order thermal decomposition of SO2Cl2 at a constant volume:
SO2Cl2 → SO2 + Cl2

Expt Time in Total


no sec pressure/atm
1 0 0.4
2 100 0.7

13. (a) What is the effect of catalyst on:


(i) Gibbs energy (∆G) and (ii) activation energy of a reaction?
(b) A first order reaction takes 20 minutes for 25% decomposition. Calculate the time when 75% of the reaction will
be completed. (Given: log = 2 = 0·3010, log 3 = 0·4771, log 4 = 0·6021)

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