PROGRAM OVERVIEW

HAZARD COMMUNICATION SAFETY PROGRAM

REGULATORY STANDARD: OSHA - 29 CFR 1910.1200

INTRODUCTION
The Hazard Communication Standard requires employers to inform employees of the hazards
and identities of workplace chemicals to which they are exposed. This program specifies the
requirements for evaluation of chemical hazards in the workplace and establishes means for
communicating hazard information to all affected workers including chemical Safety Data Sheets
(SDS), labeling, a Written Hazard Communication Program, employee training and
communication requirements for contractors and vendors.

TRAINING
 Employees and contractors must be made aware of the hazards they may encounter and
the precautions they must take to protect themselves from these hazards.
 Employees or contractors must be trained on initial assignment and whenever any new
physical, chemical or health hazards are introduced, when non-routine tasks or procedures
are required, or when employees are working with or near unlabeled piping systems that
contain hazardous chemicals.

ACTIVITIES
 Determine if hazardous chemicals are present in the workplace
 Ensure the availability of a SDS for each hazardous chemical or mixture in the workplace
 Ensure a Hazardous Chemical List is maintained
 Evaluate the hazards for each chemical or mixture used and/or stored in the workplace
 Ensure proper labeling of chemical containers in accordance with Globally Harmonized
System (GHS) requirements.
 Complete the Written Hazard Communication Program
 Employees trained
 Process to evaluate and document any new hazards or changes

FORMS
 Hazardous Chemical List
 Training Attendance Roster
 Written Hazard Communication Program
 As needed:
 Michigan Specific Information
 Minnesota Specific Information
 Rhode Island Specific Information

Table of Contents
1. Purpose
2. Scope
3. Responsibilities
4. Procedure
5. Safety Information
6. Training Information & Requirements
7. Definitions

Hazard Communication Safety Program 1 Rev. [01/19]

 HAZARD COMMUNICATION PROGRAM

1. Purpose. To provide an effective, written hazard communication program in compliance with

company, State and Federal regulatory requirements. Hazard Communication applies to all
chemicals and mixtures purchased, manufactured, used, and/or stored by the company to
which employees, contractors, tenants or visitors may be exposed. (Laboratories, as defined
by OSHA regulations, are not covered under this program.)

2. Scope. This program applies to all operations at company facilities and job-sites. This
program does not apply to articles, food or beverage items. Consumer products are exempt
if they are used at the same frequency, duration, and concentration as home use.

3. Responsibilities.

3.1 Management must:

3.1.1 Perform a hazard determination. The company is required to determine the

hazards of any products or chemicals they manufacture and/or sell.

3.1.2 Ensure a Hazardous Chemical List is maintained either for the company as a
whole, or for each department or work area.

3.1.3 Evaluate the hazards for each chemical or mixture used or stored in the
workplace.

3.1.4 Maintain a Written Hazard Communication Program.

3.1.5 Assure labels and other forms of warning are affixed to chemical containers, as
appropriate, meeting Globally Harmonized System (GHS) label requirements.

3.1.6 Train and inform employees on initial assignment and whenever a new physical,
chemical or health hazard is introduced into the workplace, or when non-routine
tasks or procedures are required.

3.1.7 Develop and implement a method of communication between any contractors

and the company which describes and outlines.

3.1.8 Some State OSHA Programs have additional requirements (including Michigan,
Minnesota, Rhode Island, etc.).

3.2 Employees must:

3.2.1 Attend Hazard Communication Training upon initial assignment, and when
changes to the workplace hazards occur (through process changes or a change
of work assignment).

3.2.2 Re-label any containers into which hazardous chemicals or mixtures are
transferred.

Hazard Communication Safety Program 2 Rev. [01/19]

 3.2.3 Inform management of any changes to chemicals or chemical uses.

4. Procedure.

4.1 Determine if hazardous chemicals are present in the workplace.

4.2 Written Hazard Communication Program (See the included form for the Written
Hazard Communication Program.) This program must contain or describe:

4.2.1 A list of hazardous chemicals

4.2.2 Criteria and Label information

4.2.3 Safety Data Sheets (SDS)

4.2.4 Employee information and training

4.2.5 Procedures for evaluating the hazards of any non-routine tasks (e.g. one-time
chemical uses) and for evaluating any unlabeled pipes in the work area that
contain hazardous chemicals.

4.2.6 Multi-employer workplaces (Provisions for contractors)

4.3 Hazardous Chemical List (See the included Form for a Hazardous Chemical List)

Create a list of all hazardous chemicals used in the workplace. If necessary, use the
chemical SDSs to determine whether or not a chemical is a hazardous chemical.

4.4 Chemical Labeling

4.4.1 Manufacturer/GHS Compliant labeling: All containers must be labeled with the
product identifier, signal work, hazard statement, pictogram(s), precautionary
statement, and manufacturer name, address, and phone number. Such labels
may not be defaced or covered.

4.4.2 Workplace labeling: May be used for process materials and must contain the
chemical identity and appropriate hazard warnings.

4.4.3 Portable Container labels: should be on all containers at all times. However,
labels are not required for portable containers provided they are immediately
used by the employee on that work-shift and remain in the direct control of the
employee at all times.

4.4.4 All labels must be in legible English. Other languages may be used, provided a
label in English is also provided.

Hazard Communication Safety Program 3 Rev. [01/19]

 4.4.5 Pipes or piping systems that contain a hazardous chemical shall be identified to
employees by at least one (1) readily accessible label, sign, placard, written
operating instructions, process sheet, batch ticket or substance identification
system.

4.5 Safety Data Sheets

4.5.1 Ensure the availability of a SDS for each hazardous chemical or mixture in the
workplace and are:

4.5.1.1 Readily accessible and available by employees on each work shift

4.5.1.2 Written in English

4.5.1.3 Obtained from the manufacturer or supplier of the chemical or

material before it is used at the workplace, if one did not accompany
the shipment

4.5.1.4 Kept for the duration of its use or storage, at a minimum, and for 30
years after discontinuing chemical use.

4.5.2 SDSs are prepared by the chemical manufacturer following the GHS
requirements.

4.6 Multi-employer workplaces (Provisions for contractors) must be informed about:

4.6.1.1 Onsite access to and maintenance of a current SDS

4.6.1.2 Labeling procedures

4.6.1.3 Protective and precautionary measures

4.7 Maintain a process to evaluate and document any new hazards or changes to the
workplace that would affect the above requirements, including any non-routine tasks or
procedures, or unlabeled piping systems that contain hazardous chemicals.

5. Safety Information

Trade Secret Information - Trade Secrets are products which, when the chemical identity of
the product is revealed, would jeopardize the manufacturer’s competitive advantage. Trade
secret materials (and requests to reveal trade secret information) must comply with the
requirements of OSHA 1910.1200(i) and Appendix D.

6. Training and Information

6.1 Employees must be trained on initial assignment and whenever any new physical,
chemical or health hazards are introduced, when non-routine tasks or procedures are
required, or when employees are working with or near unlabeled piping systems that
contain hazardous chemicals.

Hazard Communication Safety Program 4 Rev. [01/19]

 6.2 Training includes (Annual training required in some states):

6.2.1 Identification of the work areas where hazardous chemicals are used.

6.2.2 The location and availability of the written program, hazardous chemical list,
and SDSs.

6.2.3 Information on the methods and observations used to detect the presence or
release of chemicals (monitors, alarm systems, odors, visual appearance, etc.)
including any “non-routine” tasks that employees may be asked to periodically
perform which are beyond their regularly assigned duties.

6.2.4 The physical, health, simple asphyxiation, combustible dust, and pyrophoric
gas hazard information of the chemicals present

6.2.5 The measures employees can take to protect themselves from identified
chemical hazards (procedures, personal protective equipment, etc.)

6.2.6 The labeling system used in the workplace

6.2.7 The details of the Written Hazard Communication Program

7. Definitions

 Hazard Statement - statement assigned to a hazard class and category that describes
the nature of the hazard(s) of a chemical, including, where appropriate, the degree of
hazard.

 Laboratory - A facility where relatively small quantities of hazardous chemicals are used
on a non-production basis. The following conditions must be met:
 Chemical manipulations are carried out on a "laboratory scale”
 Multiple chemical procedures or chemicals are used
 The procedures involved are not part of a production process, nor in any way
simulate a production process
 "Protective laboratory practices and equipment" are available and in common use
to minimize the potential for employee exposure to hazardous chemicals

 Pictogram - a composition that may include a symbol plus other graphic elements, such
as a border, background pattern, or color, that is intended to convey specific information
about the hazards of a chemical. Eight pictograms are designated under this standard
for application to a hazard category.

 Precautionary statement- a phrase that describes recommended measures that should

be taken to minimize or prevent adverse effects resulting from exposure to a hazardous
chemical, or improper storage or handling.

 Process Materials - Chemicals that are routinely used in a chemical process or as part
of a mixture for a chemical process.

Hazard Communication Safety Program 5 Rev. [01/19]

  Product Identifier - the name or number used for a hazardous chemical on a label or in
the SDS. It provides a unique means by which the user can identify the chemical.

 Safety Data Sheets (SDS) - reference documents that outline the product information,
hazards and other required elements for hazardous chemicals or materials. These
documents are produced by the manufacturer of the chemical or material and must be
maintained at any workplace where they are used or stored.

 Signal Word – a word used to indicate the relative level of severity of hazard and alert
the reader to a potential hazard on the label. The signal words used in this section are
"danger" and "warning." "Danger" is used for the more severe hazards, while "warning"
is used for the less severe.

Hazard Communication Safety Program 6 Rev. [01/19]

 HAZARDOUS CHEMICAL LIST

Manufacturer
Common Name Manufacturer
Name of Chemical Emergency
(what this company calls the or
(as it appears on the SDS or Chemical Contact
material – if different than the Supplier
Label) Information Or
SDS) Name
Phone Number

053AF GERM X HAND SANITIZER WITH VITAMIN E AND ALOE

HAND SANITIZER VI-JON INC. CHEMTREC: 1-800-424-9300

ACETYLENE AIRGAS USA, LLC 1-866-734-3438

ANSUL ABC MULTIPURPOSE DRY CHEMICAL AGENT - STORED PRESSURE ABC FIRE EXTINGISHER POWDER TYCO FIRE PROTECTION PRODUCTS CHEMTREC: 1-800-424-9300

BLUE MONSTER PTFE THREAD SEAL TAPE

THREAD TAPE MILL-ROSE 440-974-6730
-- -- -- --
CLEAR MARKING PAINT RUST-OLEUM CORPORATION 1-847-367-7700

DIESEL FUEL GLOBAL COMPANIES LLC CHEMTREC: 1-800-424-9300

EXCALIBUR 7018 MR WELDING RODS THE LINCOLN ELECTRIC COMPANY

1-888-609-1762

FLEETWELD 5P+ WELDING RODS THE LINCOLN ELECTRIC COMPANY

1-888-609-1762
HERCULES BLUE BLOCK THREAD DOPE HCC HOLDINGS, INC 1-877-740-5015
HERCULES DUCK BUTTER DUCK BUTTER HCC HOLDINGS, INC 1-877-740-5015
INDUSTRIAL ENAMAL PAINT ROLL/BRUSH ON PAINT THE SHERWIN-WILLIAMS COMPANY
1-800-424-9300
IRWIN CHALK - RED, PERMANENT CHALK BOX CHALK IRWIN TOOLS 1-800-464-7946
KWIK SEAL TUB & TILE ADHESIVE CAULK - ALL COLORS DAP PRODUCTS INC 1-800-222-1222

LOCTITE LB 8023 ANTI-SEIZE HENKEL CORPORATION 1-877-671-4608

MAPP GAS AIRGAS USA, LLC AND ITS AFFILIATES

1-866-734-3438
MARATHON PETROLEUM PREMIUM AW II HYDRULIC OIL
HYDRAULIC OIL MARATHON PETROLEUM COMPANY LP
1-877-627-5463
OATEY 95/5 LEAD FREE PLUMBING SOLDER
OATEY CO. 1-800-424-9300
OATEY CPVC FLOWGUARD GOLD UVI ONE-STEP YELLOW CEMENT CPVC CEMENT - YELLOW OATEY CO. 1-877-740-5015

Completed by: Wade Robinson Date: 4/12/2021

Hazardous Chemical List Form 7 Rev. [01/19]

 HAZARDOUS CHEMICAL LIST

Manufacturer
Common Name Manufacturer
Name of Chemical Emergency
(what this company calls the or
(as it appears on the SDS or Chemical Contact
material – if different than the Supplier
Label) Information Or
SDS) Name
Phone Number

OATEY NO. 5 PASTE FLUX PASTE FLUX OATEY CO. 1-877-740-5015

OATEY PLUMBER'S PUTTY OATEY CO. 1-800-424-9300
OATEY PURPLE PRIMER LARGE DIAMETER PIPE
OATEY CO. 1-877-740-5015
OATEY PVC HEAVY DUTY CLEAR OR GRAY CEMENT
OATEY CO. 1-877-740-5015
PRO LSPR 6PK MARK FLUORESCENT ORANGE GROUND MARKER PAINT RUST-OLEUM CORPORATION 1-847-367-7700

OXYGEN AIRGAS USA, LLC AND ITS AFFILIATES

1-866-734-3438

PROPANE AIRGAS USA, LLC AND ITS AFFILITAES

1-866-734-3438

RED GREASE CRD INDUSTRIES, INC. 800-424-9300

RIDGID NU-CLEAR THREAD CUTTING OIL (UNITED STATES) THREAD CUTTING OIL RIDGID TOOL COMPANY 9-1-1
BP UNLEADED GAS BP PRODUCTS NORTH AMERICA INC
1-800-447-8735
VICTAULIC LUBRICANT JTM PRODUCTS, INC 610-559-3300

Completed by: Wade Robinson Date: 4/12/2021

Hazardous Chemical List Form 7 Rev. [01/19]

 TRAINING ATTENDANCE ROSTER
HAZARD COMMUNICATION
Hazard Communication Training Includes:
General Requirements and Right To Know/Understand
Types and Format of Chemical Labels including GHS format
Chemical Hazard Categories and Hazards
SDS overview TRAINING TO BE COMPLETED PRIOR TO
COMING ON SITE AND REVIEWED WHILE ON
Chemical Spill Response
SITE. WITH ANY SITE-SPECIFIC CHEMICAL
Exposure Incident Reporting RULES.
INSTRUCTOR: DATE: LOCATION:

NAME (Please Print)

FIRST - MI - LAST SIGNATURE
By signing below, I attest that I have attended the safety training for the topic indicated, and will abide by
the safety information, procedures, rules, regulations and/or company policy as presented and instructed

Name of Interpreter, if utilized:

Training Attendance Roster Hazard Communication Form 8 Rev. [01/19]

 WRITTEN HAZARD COMMUNICATION PROGRAM
The purpose of this written program is to document how the Hazard Communication requirements are met.

General:
Project Manager and Superintendent
is responsible for the initial and ongoing activities to keep this Hazard
Communication Program current.
The location of the written program is: Mullin's Site Office Trailer
The location of the list of hazardous chemicals is: SDS binder
The location of the Safety Data Sheets (SDSs) is: Mullin's Site Office Trailer
The list of hazardous chemicals, the written program, and the SDSs are required to be accessible to
employees at all times. If electronic access is provided, describe the process for accessing this information:
.
If an SDS is not received at the time of purchase or shipment, an SDS will be obtained either through the
manufacturer’s website, by calling the manufacturer or supplier, or by writing the company. If the SDS is
not available, OSHA may be contacted or notified.
Project Manger and Superintendent is responsible for ensuring that SDSs are received.

Hazard Warning Labels:

Original manufacturer’s labels are general used to ensure updated information on chemical hazards is
made available.
Project Manger and Superintendent
is responsible for ensuring that all hazardous chemicals in the workplace
have appropriate labels (original manufacturer’s labels, or written/printed labels (such as HMIS, NFPA or
NAFTA code labels) affixed by our company. If alternative systems to the hazard warning statements are
used, describe the system used: .

Warehouse Manager is responsible for ensuring any containers shipped or taken off our company
premises have appropriate labels, which include the identity of the chemical, appropriate hazard warning
statements, and the name and address of manufacturer or responsible party.

SDS for Company Made or Manufactured Chemicals: N/A

is responsible for ensuring that SDSs are created and written for every
hazardous chemical that the company makes, mixes or manufactures.

is responsible for ensuring that any SDSs are shipped to another company
who purchases or is provided with our company-specific chemicals or mixtures.

Written Hazard Communication Program FORM 9 [Rev.01/19]

 Non-Routine Tasks and Unlabeled Pipes:
PROJECT MANAGER AND SUPERINTENDENT is responsible for ensuring that any new or non-routine tasks are

identified and training is appropriately provided. SDSs and chemical label reviews are used as part of this
hazard evaluation and identification.
The methods used to inform employees of the hazards of non-routine tasks, and the hazards associated
with chemicals contained in unlabeled pipes in their work areas are as follows:

Contractors:
PROJECT MANAGER AND SUPERINTENDENT is responsible for supplying an SDS, upon request. Contractors working at

our sites or locations will be provided with an SDS for any chemical used or stored at the facility, upon
request. Describe the methods used to provide on-site access to SDS:
MULLINS SDS MANUAL WILL BE LOCATED IN THE SITE OFFICE TRAILER

Describe how you communicate information about your labeling system, if different than that used by
contractors or subcontractors for types of labeling: N/A
Methods used to inform any precautionary measures that need to be taken to protect employees during the
workplace’s normal operating conditions and in foreseeable emergencies:

Off-Site Work: N/A

Employees working at other sites may request an SDS for any chemical they may be exposed to. During
training or orientation, our employees are informed of how to request information on the elements of that
location’s written hazard communication program, including Safety Data Sheet information, labeling, non-
routine work hazards and unlabeled pipes.
is responsible for ensuring that this occurs, as needed.

Information and Training:

SAFETY MANAGER is responsible for identifying employees who need training.

SAFETY MANAGER is responsible for conducting training upon initial assignment.

The hazard communication training must cover the following items, at a minimum:
 Information on the operations where hazardous chemicals are present
 The location and availability of this written program, list of hazardous chemicals, and SDS
 How to detect releases of hazardous chemicals (monitoring equipment, visual determination, odor,
equipment sensors, etc).
 The physical and health hazards of chemicals in the work area, including any unlabeled chemical
pipes.
 The measures that employees can take to protect themselves from these hazards.
The details of the Hazard Communication Program, including the explanation of the labeling system and
SDS.
SAFETY MANAGER is responsible for ensuring that these elements are covered in the training
program.

Completed by: Wade Robinson Date: 4/12/2021

Written Hazard Communication Program FORM 10 Rev.01/19

 BRIEF
Hazard Communication Standard: Safety Data Sheets
The Hazard Communication Standard (HCS) Sections 1 through 8 contain general
(29 CFR 1910.1200(g)), revised in 2012, requires information about the chemical, identification,
that the chemical manufacturer, distributor, hazards, composition, safe handling practices,
or importer provide Safety Data Sheets and emergency control measures (e.g., fire
(SDSs) (formerly MSDSs or Material Safety fighting). This information should be helpful to
Data Sheets) for each hazardous chemical those that need to get the information quickly.
to downstream users to communicate Sections 9 through 11 and 16 contain other
information on these hazards. The information technical and scientific information, such as
contained in the SDS is largely the same as physical and chemical properties, stability
the MSDS, except now the SDSs are required and reactivity information, toxicological
to be presented in a consistent user-friendly, information, exposure control information,
16-section format. This brief provides guidance and other information including the date of
to help workers who handle hazardous preparation or last revision. The SDS must
chemicals to become familiar with the format also state that no applicable information was
and understand the contents of the SDSs. found when the preparer does not find relevant
information for any required element.
The SDS includes information such as the
properties of each chemical; the physical, The SDS must also contain Sections 12
health, and environmental health hazards; through 15, to be consistent with the UN
protective measures; and safety precautions Globally Harmonized System of Classification
for handling, storing, and transporting the and Labeling of Chemicals (GHS), but OSHA
chemical. The information contained in the SDS will not enforce the content of these sections
must be in English (although it may be in other because they concern matters handled by other
languages as well). In addition, OSHA requires agencies.
that SDS preparers provide specific minimum
information as detailed in Appendix D of A description of all 16 sections of the SDS,
29 CFR 1910.1200. The SDS preparers may along with their contents, is presented below:
also include additional information in various
section(s).

Section 1: Identification
This section identifies the chemical on the SDS as well as the recommended uses. It also provides
the essential contact information of the supplier. The required information consists of:
• Product identifier used on the label and any other common names or synonyms by which the
substance is known.
• Name, address, phone number of the manufacturer, importer, or other responsible party, and
emergency phone number.
• Recommended use of the chemical (e.g., a brief description of what it actually does, such
as flame retardant) and any restrictions on use (including recommendations given by the
supplier).

1
 Section 2: Hazard(s) Identification
This section identifies the hazards of the chemical presented on the SDS and the appropriate
warning information associated with those hazards. The required information consists of:
• The hazard classification of the chemical (e.g., flammable liquid, category1).
• Signal word.
• Hazard statement(s).
• Pictograms (the pictograms or hazard symbols may be presented as graphical reproductions
of the symbols in black and white or be a description of the name of the symbol (e.g., skull
and crossbones, flame).
• Precautionary statement(s).
• Description of any hazards not otherwise classified.
• For a mixture that contains an ingredient(s) with unknown toxicity, a statement describing how
much (percentage) of the mixture consists of ingredient(s) with unknown acute toxicity. Please
note that this is a total percentage of the mixture and not tied to the individual ingredient(s).

Section 3: Composition/Information on Ingredients

This section identifies the ingredient(s) contained in the product indicated on the SDS, including
impurities and stabilizing additives. This section includes information on substances, mixtures,
and all chemicals where a trade secret is claimed. The required information consists of:
Substances
• Chemical name.
• Common name and synonyms.
• Chemical Abstracts Service (CAS) number and other unique identifiers.
• Impurities and stabilizing additives, which are themselves classified and which contribute to
the classification of the chemical.
Mixtures
• Same information required for substances.
• The chemical name and concentration (i.e., exact percentage) of all ingredients which are
classified as health hazards and are:
° Present above their cut-off/concentration limits or
° Present a health risk below the cut-off/concentration limits.
• The concentration (exact percentages) of each ingredient must be specified except
concentration ranges may be used in the following situations:
° A trade secret claim is made,
° There is batch-to-batch variation, or
° The SDS is used for a group of substantially similar mixtures.
Chemicals where a trade secret is claimed
• A statement that the specific chemical identity and/or exact percentage (concentration) of
composition has been withheld as a trade secret is required.

1
Chemical, as defined in the HCS, is any substance, or mixture of substances.

2
 Section 4: First-Aid Measures
This section describes the initial care that should be given by untrained responders to an
individual who has been exposed to the chemical. The required information consists of:
• Necessary first-aid instructions by relevant routes of exposure (inhalation, skin and eye contact,
and ingestion).
• Description of the most important symptoms or effects, and any symptoms that are acute or
delayed.
• Recommendations for immediate medical care and special treatment needed, when necessary.

Section 5: Fire-Fighting Measures

This section provides recommendations for fighting a fire caused by the chemical. The required
information consists of:
• Recommendations of suitable extinguishing equipment, and information about extinguishing
equipment that is not appropriate for a particular situation.
• Advice on specific hazards that develop from the chemical during the fire, such as any
hazardous combustion products created when the chemical burns.
• Recommendations on special protective equipment or precautions for firefighters.

Section 6: Accidental Release Measures

This section provides recommendations on the appropriate response to spills, leaks, or releases,
including containment and cleanup practices to prevent or minimize exposure to people,
properties, or the environment. It may also include recommendations distinguishing between
responses for large and small spills where the spill volume has a significant impact on the
hazard. The required information may consist of recommendations for:
• Use of personal precautions (such as removal of ignition sources or providing sufficient
ventilation) and protective equipment to prevent the contamination of skin, eyes, and clothing.
• Emergency procedures, including instructions for evacuations, consulting experts when
needed, and appropriate protective clothing.
• Methods and materials used for containment (e.g., covering the drains and capping
procedures).
• Cleanup procedures (e.g., appropriate techniques for neutralization, decontamination, cleaning
or vacuuming; adsorbent materials; and/or equipment required for containment/clean up).

Section 7: Handling and Storage

This section provides guidance on the safe handling practices and conditions for safe storage
of chemicals. The required information consists of:
• Precautions for safe handling, including recommendations for handling incompatible
chemicals, minimizing the release of the chemical into the environment, and providing advice
on general hygiene practices (e.g., eating, drinking, and smoking in work areas is prohibited).
• Recommendations on the conditions for safe storage, including any incompatibilities. Provide
advice on specific storage requirements (e.g., ventilation requirements).

3
 Section 8: Exposure Controls/Personal Protection
This section indicates the exposure limits, engineering controls, and personal protective
measures that can be used to minimize worker exposure. The required information consists of:
• OSHA Permissible Exposure Limits (PELs), American Conference of Governmental Industrial
Hygienists (ACGIH) Threshold Limit Values (TLVs), and any other exposure limit used or
recommended by the chemical manufacturer, importer, or employer preparing the safety data
sheet, where available.
• Appropriate engineering controls (e.g., use local exhaust ventilation, or use only in an enclosed
system).
• Recommendations for personal protective measures to prevent illness or injury from exposure
to chemicals, such as personal protective equipment (PPE) (e.g., appropriate types of eye, face,
skin or respiratory protection needed based on hazards and potential exposure).
• Any special requirements for PPE, protective clothing or respirators (e.g., type of glove material,
such as PVC or nitrile rubber gloves; and breakthrough time of the glove material).

Section 9: Physical and Chemical Properties

This section identifies physical and chemical properties associated with the substance or mixture.
The minimum required information consists of:
• Appearance (physical state, color, etc.); • Upper/lower flammability or explosive limits;
• Odor; • Vapor pressure;
• Odor threshold; • Vapor density;
• pH; • Relative density;
• Melting point/freezing point; • Solubility(ies);
• Initial boiling point and boiling range; • Partition coefficient: n-octanol/water;
• Flash point; • Auto-ignition temperature;
• Evaporation rate; • Decomposition temperature; and
• Flammability (solid, gas); • Viscosity.
The SDS may not contain every item on the above list because information may not be relevant
or is not available. When this occurs, a notation to that effect must be made for that chemical
property. Manufacturers may also add other relevant properties, such as the dust deflagration
index (Kst) for combustible dust, used to evaluate a dust’s explosive potential.

4
 Section 10: Stability and Reactivity
This section describes the reactivity hazards of the chemical and the chemical stability
information. This section is broken into three parts: reactivity, chemical stability, and other.
The required information consists of:
Reactivity
• Description of the specific test data for the chemical(s). This data can be for a class or family
of the chemical if such data adequately represent the anticipated hazard of the chemical(s),
where available.
Chemical stability
• Indication of whether the chemical is stable or unstable under normal ambient temperature
and conditions while in storage and being handled.
• Description of any stabilizers that may be needed to maintain chemical stability.
• Indication of any safety issues that may arise should the product change in physical
appearance.
Other
• Indication of the possibility of hazardous reactions, including a statement whether the chemical
will react or polymerize, which could release excess pressure or heat, or create other hazardous
conditions. Also, a description of the conditions under which hazardous reactions may occur.
• List of all conditions that should be avoided (e.g., static discharge, shock, vibrations, or
environmental conditions that may lead to hazardous conditions).
• List of all classes of incompatible materials (e.g., classes of chemicals or specific substances)
with which the chemical could react to produce a hazardous situation.
• List of any known or anticipated hazardous decomposition products that could be produced
because of use, storage, or heating. (Hazardous combustion products should also be included
in Section 5 (Fire-Fighting Measures) of the SDS.)

Section 11: Toxicological Information

This section identifies toxicological and health effects information or indicates that such data
are not available. The required information consists of:
• Information on the likely routes of exposure (inhalation, ingestion, skin and eye contact).
The SDS should indicate if the information is unknown.
• Description of the delayed, immediate, or chronic effects from short- and long-term exposure.
• The numerical measures of toxicity (e.g., acute toxicity estimates such as the LD50 (median
lethal dose)) - the estimated amount [of a substance] expected to kill 50% of test animals in a
single dose.
• Description of the symptoms. This description includes the symptoms associated with
exposure to the chemical including symptoms from the lowest to the most severe exposure.
• Indication of whether the chemical is listed in the National Toxicology Program (NTP)
Report on Carcinogens (latest edition) or has been found to be a potential carcinogen in the
International Agency for Research on Cancer (IARC) Monographs (latest editions) or found
to be a potential carcinogen by OSHA.

5
 Section 12: Ecological Information (non-mandatory)
This section provides information to evaluate the environmental impact of the chemical(s) if it
were released to the environment. The information may include:
• Data from toxicity tests performed on aquatic and/or terrestrial organisms, where available
(e.g., acute or chronic aquatic toxicity data for fish, algae, crustaceans, and other plants; toxicity
data on birds, bees, plants).
• Whether there is a potential for the chemical to persist and degrade in the environment either
through biodegradation or other processes, such as oxidation or hydrolysis.
• Results of tests of bioaccumulation potential, making reference to the octanol-water partition
coefficient (Kow) and the bioconcentration factor (BCF), where available.
• The potential for a substance to move from the soil to the groundwater (indicate results from
adsorption studies or leaching studies).
• Other adverse effects (e.g., environmental fate, ozone layer depletion potential, photochemical
ozone creation potential, endocrine disrupting potential, and/or global warming potential).

Section 13: Disposal Considerations (non-mandatory)

This section provides guidance on proper disposal practices, recycling or reclamation of the
chemical(s) or its container, and safe handling practices. To minimize exposure, this section
should also refer the reader to Section 8 (Exposure Controls/Personal Protection) of the SDS.
The information may include:
• Description of appropriate disposal containers to use.
• Recommendations of appropriate disposal methods to employ.
• Description of the physical and chemical properties that may affect disposal activities.
• Language discouraging sewage disposal.
• Any special precautions for landfills or incineration activities.

Section 14: Transport Information (non-mandatory)

This section provides guidance on classification information for shipping and transporting of
hazardous chemical(s) by road, air, rail, or sea. The information may include:
• UN number (i.e., four-figure identification number of the substance)2.
• UN proper shipping name2.
• Transport hazard class(es)2.
• Packing group number, if applicable, based on the degree of hazard2.
• Environmental hazards (e.g., identify if it is a marine pollutant according to the International
Maritime Dangerous Goods Code (IMDG Code)).
• Guidance on transport in bulk (according to Annex II of MARPOL 73/783 and the International
Code for the Construction and Equipment of Ships Carrying Dangerous Chemicals in Bulk
(International Bulk Chemical Code (IBC Code)).
• Any special precautions which an employee should be aware of or needs to comply with, in
connection with transport or conveyance either within or outside their premises (indicate
when information is not available).

2
Found in the most recent edition of the United Nations Recommendations on the Transport of
Dangerous Goods.
3
MARPOL 73/78 means the International Convention for the Prevention of Pollution from Ships,
1973, as modified by the Protocol of 1978 relating thereto, as amended.
6
 Section 15: Regulatory Information (non-mandatory)
This section identifies the safety, health, and environmental regulations specific for the product
that is not indicated anywhere else on the SDS. The information may include:
• Any national and/or regional regulatory information of the chemical or mixtures (including any
OSHA, Department of Transportation, Environmental Protection Agency, or Consumer Product
Safety Commission regulations).

Section 16: Other Information

This section indicates when the SDS was prepared or when the last known revision was made.
The SDS may also state where the changes have been made to the previous version. You may
wish to contact the supplier for an explanation of the changes. Other useful information also may
be included here.

Employer Responsibilities Standard can be found on OSHA’s Hazard

Employers must ensure that the SDSs Communication Safety and Health Topics
are readily accessible to employees for all page, located at:
hazardous chemicals in their workplace. This http://www.osha.gov/dsg/hazcom/index.html.
may be done in many ways. For example,
employers may keep the SDSs in a binder or
on computers as long as the employees have Disclaimer: This brief provides a general
immediate access to the information without overview of the safety data sheet
leaving their work area when needed and a requirements in the Hazard Communication
back-up is available for rapid access to the Standard (see 29 CFR 1910.1200(g) and
SDS in the case of a power outage or other Appendix D of 29 CFR 1910.1200). It does not
emergency. Furthermore, employers may alter or determine compliance responsibilities
want to designate a person(s) responsible for in the standard or the Occupational Safety
obtaining and maintaining the SDSs. If the and Health Act of 1970. Since interpretations
employer does not have an SDS, the employer and enforcement policy may change over
or designated person(s) should contact the time, the reader should consult current
manufacturer to obtain one. OSHA interpretations and decisions by the
Occupational Safety and Health Review
References Commission and the courts for additional
OSHA, 29 CFR 1910.1200(g) and Appendix D. guidance on OSHA compliance requirements.
Please note that states with OSHA-approved
United Nations Globally Harmonized System of state plans may have additional requirements
Classification and Labelling of Chemicals (GHS), for chemical safety data sheets, outside of
third revised edition, United Nations, 2009. those outlined above. For more information
These references and other information on those standards, please visit:
related to the revised Hazard Communication http://www.osha.gov/dcsp/osp/statestandards.html.

This is one in a series of informational briefs highlighting OSHA programs, policies or standards. It does
not impose any new compliance requirements. For a comprehensive list of compliance requirements
of OSHA standards or regulations, refer to Title 29 of the Code of Federal Regulations. This information
will be made available to sensory-impaired individuals upon request. The voice phone is (202) 693-1999;
teletypewriter (TTY) number: (877) 889-5627.

www.osha.gov • (800) 321 OSHA (6742)

DSG BR-3514 2/2012

Product Number: 053AF Product Name: Germ-X Hand Sanitizer with Vitamin E and Aloe
Issuing Date: May 11, 2015 Revision Date: None Revision Number: 0

_____________________________________________________________________________________________
Safety Data Sheet
The supplier identified below generated this SDS using the UL SDS template. UL did not test, certify, or approve the substance described in this SDS,
and all information in this SDS was provided by the supplier or was reproduced from publically available regulatory data sources. UL makes no
representations or warranties regarding the completeness or accuracy of the information in this SDS and disclaims all liability in connection with the use of
this information or the substance described in this SDS. The layout, appearance and format of this SDS is © 2014 UL LLC. All rights reserved.
_____________________________________________________________________________________________

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE

COMPANY/UNDERTAKING
Product identifier
Product Name 053AF Germ-X Hand Sanitizer with Vitamin E and Aloe
Other means of identification
Synonyms None
Recommended use of the chemical and restrictions on use
Recommended Use Hand Sanitizer
Uses advised against Use only as directed
Details of the supplier of the safety data sheet
Supplier Name Vi-Jon Inc.
Supplier Address Vi-Jon Inc.
8800 Page Avenue
Saint Louis
MO
63114
US
Supplier Phone Number Phone: 314-427-1000 (M-F 8am-4pm CST)
Fax:3144271010
Supplier Email [email protected]
Emergency telephone number Chemtrec: 1-800-424-9300 (24-Hour)

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Product Number: 053AF Product Name: Germ-X Hand Sanitizer with Vitamin E and Aloe
Issuing Date: May 11, 2015 Revision Date: None Revision Number: 0
_____________________________________________________________________________________________

2. HAZARDS IDENTIFICATION
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Flammable liquids Category 3
GHS Label elements, including precautionary statements
Emergency Overview
Signal word Warning

Flammable liquid and vapor

Appearance: Clear to Slightly Hazy, Physical State: Slightly Viscous Liquid Odor: Floral, Alcohol
Pale Green, Slightly Viscous Liquid
Precautionary Statements - Prevention
Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Keep container tightly closed
Ground/bond container and receiving equipment
Use explosion-proof electrical/ ventilating/ lighting/ equipment
Use only non-sparking tools
Take precautionary measures against static discharge
Precautionary Statements - Response
Skin
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
Fire
In case of fire: Use CO2, dry chemical, or foam for extinction
Precautionary Statements - Storage
Store in a well-ventilated place. Keep cool
Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Not applicable
Unknown Toxicity
0.259927% of the mixture consists of ingredient(s) of unknown toxicity
Other information
Toxic to aquatic life
PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION
May cause slight eye irritation
Interactions with Other Chemicals
None known.

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Product Number: 053AF Product Name: Germ-X Hand Sanitizer with Vitamin E and Aloe
Issuing Date: May 11, 2015 Revision Date: None Revision Number: 0
_____________________________________________________________________________________________

3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No Weight-% Trade Secret
Ethyl Alcohol 62% v/v 64-17-5 50 - 100 *
Aloe Barbadensis Leaf Gel 85507-69-3 0 - 10 *
Carbomer Proprietary 0 – 10 *
FD&C Blue No. 1 3844-45-9 0 – 10 *
FD&C Yellow No. 5 1934-21-0 0 – 10 *
Fragrance Proprietary 0 – 10 *
Glycerin 56-81-5 0 – 10 *
Isopropyl Alcohol 67-63-0 0 – 10 *
Isopropyl Myristate 110-27-0 0 – 10 *
Propylene Glycol 57-55-6 0 – 10 *
Tocopheryl Acetate 7695-91-2 0 - 10 *
Water 7732-18-5 10 - 50 *
*The exact percentage (concentration) of composition has been withheld as a trade secret

4. FIRST AID MEASURES

First aid measures
Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Keep eye wide open while rinsing. Do not rub affected area. Remove
contact lenses, if present and easy to do. Continue rinsing.
Skin Contact In the case of skin irritation or allergic reactions, see a physician.
Inhalation Move to fresh air. Get medical attention immediately if symptoms occur. May
cause allergic respiratory reaction. If breathing has stopped, contact emergency
medical services immediately and give artificial respiration.
Ingestion Do NOT induce vomiting. Rinse mouth immediately and drink plenty of water.
Never give anything by mouth to an unconscious person.
Self-protection of the first aider Ensure that medical personnel are aware of the material(s) involved, take
precautions to protect themselves and prevent spread of contamination.
Most important symptoms and effects, both acute and delayed
Most Important Symptoms and No information available.
Effects
Indication of any immediate medical attention and special treatment needed
Notes to Physician Treat symptomatically.

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Product Number: 053AF Product Name: Germ-X Hand Sanitizer with Vitamin E and Aloe
Issuing Date: May 11, 2015 Revision Date: None Revision Number: 0
_____________________________________________________________________________________________

5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Dry chemical. Carbon dioxide (CO2). Water spray. Alcohol resistant foam.
Unsuitable extinguishing media
CAUTION: All these products have a very low flash point. Use of water spray when fighting fire may be inefficient.
Specific Hazards Arising from the Chemical
Vapors can form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than
air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard
indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard.
Uniform Fire Code Flammable Liquid: I-C
Hazardous Combustion Products
Carbon oxides.
Explosion Data
Sensitivity to Mechanical Impact No.
Sensitivity to Static Discharge Yes.
Protective equipment and precautions for firefighters
Move containers from fire area if you can do it without risk.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Personal Precautions ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
All equipment used when handling the product must be grounded. Do not touch or walk
through spilled material. Stop leak if you can do it without risk.
Other Information Water spray may reduce vapor; but may not prevent ignition in closed spaces.
Environmental Precautions
Environmental Precautions Prevent entry into waterways, sewers, basements or confined areas.
Methods and material for containment and cleaning up
Methods for Containment A vapor suppressing foam may be used to reduce vapors. Absorb or cover with dry earth,
sand or other non-combustible material and transfer to containers.
Methods for cleaning up Use clean non-sparking tools to collect absorbed material. Dike far ahead of liquid spill for
later disposal. Soak up with inert absorbent material. Pick up and transfer to properly
labeled containers.

7. HANDLING AND STORAGE

Precautions for safe handling
Handling Handle in accordance with good industrial hygiene and safety practice. Use personal
protection equipment. Avoid contact with skin and eyes. Avoid breathing vapors or mists.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use grounding and
bonding connection when transferring this material to prevent static discharge, fire or
explosion. Use with local exhaust ventilation. Use spark-proof tools and explosion-proof
equipment. Keep in an area equipped with sprinklers. Use according to package label
instructions.
Conditions for safe storage, including any incompatibilities
Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from
heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static
electricity). Keep in properly labeled containers. Do not store near combustible materials.
Keep in an area equipped with sprinklers. Store in accordance with the particular national
regulations. Store in accordance with local regulations.
Incompatible Products None known based on information supplied.

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Product Number: 053AF Product Name: Germ-X Hand Sanitizer with Vitamin E and Aloe
Issuing Date: May 11, 2015 Revision Date: None Revision Number: 0
_____________________________________________________________________________________________

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters
Exposure Guidelines There is no exposure data pertaining to the Product. This section reflects exposure
data pertaining to individual ingredients.
Chemical Name ACGIH TLV
OSHA PEL NIOSH IDLH
Ethyl Alcohol 62% v/v STEL: 1000 ppm
TWA: 1000 ppm IDLH: 3300 ppm 10% LEL
64-17-5 TWA: 1900 mg/m3 TWA: 1000 ppm
(vacated) TWA: 1000 ppm TWA: 1900 mg/m3
3
(vacated) TWA: 1900 mg/m
Glycerin TWA: 10 mg/m3 mist TWA: 15 mg/m3 mist, total
56-81-5 particulate
TWA: 5 mg/m3 mist, respirable
fraction
(vacated) TWA: 10 mg/m3 mist,
total particulate
(vacated) TWA: 5 mg/m3 mist,
respirable fraction
ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value OSHA PEL: Occupational Safety and Health
Administration - Permissible Exposure Limits Immediately Dangerous to Life or Health
Other Exposure Guidelines Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d
962 (11th Cir., 1992) See section 15 for national exposure control parameters
Appropriate engineering controls
Engineering Measures Showers
Eyewash stations
Ventilation systems
Individual protection measures, such as personal protective equipment
Eye/Face Protection Tight sealing safety goggles.
Skin and Body Protection Wear protective gloves and protective clothing. Long sleeved clothing. Chemical resistant
apron. Impervious gloves. Antistatic boots.
Respiratory Protection No protective equipment is needed under normal use conditions. If exposure limits are
exceeded or irritation is experienced, ventilation and evacuation may be required.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink or
smoke when using this product. Contaminated work clothing should not be allowed out of
the workplace. Regular cleaning of equipment, work area and clothing is recommended.
Wash hands before breaks and immediately after handling the product.

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Product Number: 053AF Product Name: Germ-X Hand Sanitizer with Vitamin E and Aloe
Issuing Date: May 11, 2015 Revision Date: None Revision Number: 0
_____________________________________________________________________________________________

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical and Chemical Properties
Physical State Slightly Viscous Liquid
Appearance Clear to Slightly Hazy, Pale Green, Odor Floral, Alcohol
Slightly Viscous Liquid
Color Pale Green Odor Threshold No information available
Property Values Remarks Method
pH 7.0 None known
Melting / freezing point No data available None known
Boiling point / boiling range No data available None known
Flash Point 23 C / 73 F None known
Evaporation Rate No data available None known
Flammability (solid, gas) No data available None known
Flammability Limit in Air
Upper flammability limit No data available
Lower flammability limit No data available
Vapor pressure No data available None known
Vapor density No data available None known
Specific Gravity 0.90 None known
Water Solubility Miscible in water None known
Solubility in other solvents No data available None known
Partition coefficient: n-octanol/water No data available None known
Autoignition temperature No data available None known
Decomposition temperature No data available None known
Kinematic viscosity No data available None known
Dynamic viscosity No data available None known
Explosive properties No data available
Oxidizing Properties No data available
Other Information
Softening Point No data available
VOC Content (%) No data available
Particle Size No data available
Particle Size Distribution No data available

10. STABILITY AND REACTIVITY

Reactivity
No data available.
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing.
When used in accordance with the directions.
Hazardous Polymerization
Hazardous polymerization does not occur.
Conditions to avoid
Heat, flames and sparks.
Incompatible materials
None known based on information supplied.
Hazardous Decomposition Products
Carbon oxides.

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Product Number: 053AF Product Name: Germ-X Hand Sanitizer with Vitamin E and Aloe
Issuing Date: May 11, 2015 Revision Date: None Revision Number: 0
_____________________________________________________________________________________________

11. TOXICOLOGICAL INFORMATION

There is no data for this product. The information included in this section describes the potential hazards of the
individual ingredients.
Information on likely routes of exposure
Product Information
Inhalation Specific test data for the substance or mixture is not available.
Eye Contact Specific test data for the substance or mixture is not available.
Skin Contact Specific test data for the substance or mixture is not available.
Ingestion Specific test data for the substance or mixture is not available.
Component Information
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
Ethyl Alcohol 62% v/v - - = 124.7 mg/L ( Rat ) 4 h
64-17-5
Glycerin - > 10 g/kg ( Rabbit ) -
56-81-5
Isopropyl Myristate > 10000 mg/kg ( Rat ) = 5 g/kg ( Rabbit ) > 41 mg/L ( Rat )
110-27-0
Water > 90 mL/kg ( Rat ) - -
7732-18-5
Information on toxicological effects
Symptoms No information available.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization No information available.
Mutagenic Effects No information available.
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
Chemical Name ACGIH IARC NTP OSHA
Ethyl Alcohol 62% v/v A3 Group 1 Known X
64-17-5
FD&C Blue No. 1 Group 3
3844-45-9
ACGIH (American Conference of Governmental Industrial Hygienists)
A3 - Animal Carcinogen
IARC (International Agency for Research on Cancer)
Group 1 - Carcinogenic to Humans
Group 3 - Not Classifiable as to Carcinogenicity in Humans
NTP (National Toxicology Program)
Known - Known Carcinogen
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X - Present
Reproductive Toxicity No information available.
STOT - single exposure No information available.
STOT - repeated exposure No information available.
Chronic Toxicity No known effect based on information supplied. Ethanol has been shown to be a
reproductive toxin only when consumed as an alcoholic beverage. Ethanol has been shown
to be carcinogenic in long-term studies only when consumed as alcoholic beverage.
Target Organ Effects Blood. Central Nervous System (CNS). Eyes. Liver. Reproductive System. Respiratory
system. Skin.
Aspiration Hazard No information available.
Numerical measures of toxicity Product Information
The following values are calculated based on chapter 3.1 of the GHS document
ATEmix (inhalation-dust/mist)
228.70 mg/l

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Product Number: 053AF Product Name: Germ-X Hand Sanitizer with Vitamin E and Aloe
Issuing Date: May 11, 2015 Revision Date: None Revision Number: 0
_____________________________________________________________________________________________

12. ECOLOGICAL INFORMATION

There is no ecological data on the Product. The Product ingredients are expected to be safe for the environment at
concentrations predicted under normal use and accidental spill scenarios. Packaging components are compatible with
the conventional solid waste management practices.
Ecotoxicity
No information available.
Persistence and Degradability
No information available.
Bioaccumulation
No information available.
Other adverse effects
No information available.

13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Disposal methods This material, as supplied, is a hazardous waste according to federal regulations (40 CFR
261).
Contaminated Packaging Do not reuse empty containers.
US EPA Waste Number D001
California Hazardous Waste Codes 331

14. TRANSPORT INFORMATION

DOT
Proper Shipping Name CONSUMER COMMODITY
Hazard Class ORM-D
Description CONSUMER COMMODITY, ORM-D
Emergency Response Guide 127
Number
TDG
UN-No. UN1170
Proper Shipping Name ETHANOL
Hazard Class 3
Packing Group III
Description UN1170, ETHANOL, 3, III
MEX
UN-No. UN1170
Proper Shipping Name ETHANOL
Hazard Class 3
Packing Group III
Description UN1170, ETHANOL, 3, III
ICAO
UN-No. UN1170
Proper Shipping Name ETHANOL SOLUTION
Hazard Class 3
Packing Group III
Description UN1170, ETHANOL SOLUTION, 3, III
IATA
UN-No. UN1170
Proper Shipping Name ETHANOL SOLUTION
Hazard Class 3
Packing Group III
Description UN1170, ETHANOL SOLUTION, 3, III

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Product Number: 053AF Product Name: Germ-X Hand Sanitizer with Vitamin E and Aloe
Issuing Date: May 11, 2015 Revision Date: None Revision Number: 0
_____________________________________________________________________________________________

IMDG/IMO
UN-No. UN1170
Proper Shipping Name ETHANOL
Hazard Class 3
Packing Group III
EmS-No. F-E, S-D
Description UN1170, ETHANOL, 3, III
RID
UN-No. UN1170
Proper Shipping Name ETHANOL SOLUTION
Hazard Class 3
Packing Group III
Classification code F1
Description UN1170, ETHANOL SOLUTION, 3, III
ADR
UN-No. UN1170
Proper Shipping Name ETHANOL SOLUTION
Hazard Class 3
Packing Group III
Classification code F1
Tunnel restriction code (D/E)
Description UN1170, ETHANOL SOLUTION, 3, III
ADN
UN-No. UN1170
Proper Shipping Name ETHANOL SOLUTION
Hazard Class 3
Packing Group III
Classification code F1
Special Provisions 144, 601
Description UN1170, ETHANOL SOLUTION, 3, III
Hazard Labels 3
Limited Quantity 5L
Ventilation VE01

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Product Number: 053AF Product Name: Germ-X Hand Sanitizer with Vitamin E and Aloe
Issuing Date: May 11, 2015 Revision Date: None Revision Number: 0
_____________________________________________________________________________________________

15. REGULATORY INFORMATION

International Inventories
TSCA Complies
DSL All components are listed either on the DSL or NDSL.
IECSC -
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations,
Part 372.
SARA 311/312 Hazard Categories
Acute Health Hazard No
Chronic Health Hazard No
Fire Hazard Yes
Sudden release of pressure hazard No
Reactive Hazard No
CWA (Clean Water Act)
This product does not contain any substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and
40 CFR 122.42).
CERCLA
This material, as supplied, does not contain any substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
US State Regulations
California Proposition 65 - NONE
This product does not contain any Proposition 65 chemicals.
U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania Rhode Island Illinois
Ethyl Alcohol 62% v/v X
64-17-5
Carbomer X
9003-01-4
Glycerin X X X X
56-81-5

International Regulations
Mexico
National occupational exposure limits
Component Carcinogen Status Exposure Limits
Ethyl Alcohol 62% v/v Mexico: TWA 1000 ppm
64-17-5 ( 50 - 100 ) Mexico: TWA 1900 mg/m3
Mexico - Occupational Exposure Limits - Carcinogens
Canada
WHMIS Hazard Class
B2
D2A

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Product Number: 053AF Product Name: Germ-X Hand Sanitizer with Vitamin E and Aloe
Issuing Date: May 11, 2015 Revision Date: None Revision Number: 0
_____________________________________________________________________________________________

16. OTHER INFORMATION

NFPA Health Hazards 1 Flammability 3 Instability 0 Physical and
Chemical Hazards -
NONE
HMIS Health Hazards 1 Flammability 3 Physical Hazard 0 Personal Protection
X

Prepared By WERCS Professional Services, LLC

23 British American Blvd.
Latham, NY 12110
1-800-572-6501
Issuing Date May 11, 2015
Revision Date None
Revision Note None
General Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its
publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and
release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated
and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

Approved and Updated by Vi-Jon, Inc.

Disclaimer:
The information and recommendations contained in the Safety Data Sheet (SDS) are supplied pursuant to 29 CFR 1910.1200 of the
Occupational Safety and Health Standards Hazard Communication Rule. The information and recommendations set forth herein are
presented in good faith and believed to be correct as of this date hereof.

Vi-Jon, however, makes no representation as to the completeness or accuracy thereof, and information is supplied upon the express
condition that the persons receiving the information will be required to make their own determination as to its suitability for their
purposes prior to use. In no event will Vi-Jon be responsible for any damages of any nature whatsoever resulting from the use of,
reliance upon, or the misuse of this information.

No representations or warranties, either expressed or implied, of merchantability, fitness for a particular purpose, or of any other nature,
are made hereunder with respect to information or the product to which the information refers. The information as supplied herein is
simply to be informative and intended solely to alert the user of the substance which is the subject matter of this SDS. The ultimate
compliance with federal, state or local regulations concerning the use of this compound, or compliance with respect to product liability,
rests solely upon the purchaser thereof.
End of Safety Data Sheet

_____________________________________________________________________________________________

Page 11 / 11
 SAFETY DATA SHEET
Acetylene

Section 1. Identification
GHS product identifier : Acetylene
Chemical name : acetylene
Other means of : Ethyne; Ethine; Narcylen; C2H2; Acetylen; UN 1001; Vinylene
identification
Product type : Gas.
Product use : Synthetic/Analytical chemistry.
Synonym : Ethyne; Ethine; Narcylen; C2H2; Acetylen; UN 1001; Vinylene

SDS # : 001001
Supplier's details : Airgas USA, LLC and its affiliates
259 North Radnor-Chester Road
Suite 100
Radnor, PA 19087-5283
1-610-687-5253

24-hour telephone : 1-866-734-3438

Section 2. Hazards identification

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : FLAMMABLE GASES - Category 1
substance or mixture GASES UNDER PRESSURE - Compressed gas

GHS label elements

Hazard pictograms :

Signal word : Danger

Hazard statements : Extremely flammable gas.
Contains gas under pressure; may explode if heated.
May displace oxygen and cause rapid suffocation.
May form explosive mixtures with air.
Precautionary statements
General : Read and follow all Safety Data Sheets (SDS’S) before use. Read label before use.
Keep out of reach of children. If medical advice is needed, have product container or
label at hand. Close valve after each use and when empty. Use equipment rated for
cylinder pressure. Do not open valve until connected to equipment prepared for use.
Fusible plugs in top, bottom, or valve melt at 98°C to 107°C (208°F to 224°F). Do not
discharge at pressures above 15psig (103kpa). Use a back flow preventative device in
the piping. Use only equipment of compatible materials of construction. Approach
suspected leak area with caution.
Prevention : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
Response : Leaking gas fire: Do not extinguish, unless leak can be stopped safely. In case of
leakage, eliminate all ignition sources.
Storage : Protect from sunlight. Store in a well-ventilated place.
Disposal : Not applicable.
Hazards not otherwise : In addition to any other important health or physical hazards, this product may displace
classified oxygen and cause rapid suffocation.

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Acetylene

Section 3. Composition/information on ingredients

Substance/mixture : Substance
Chemical name : acetylene
Other means of : Ethyne; Ethine; Narcylen; C2H2; Acetylen; UN 1001; Vinylene
identification
Product code : 001001

CAS number/other identifiers

CAS number : 74-86-2
Ingredient name % CAS number
Acetylene 100 74-86-2
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention if irritation occurs.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects
persist or are severe. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. To avoid the risk of static discharges and gas ignition, soak contaminated
clothing thoroughly with water before removing it. Get medical attention if symptoms
occur. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Ingestion : As this product is a gas, refer to the inhalation section.

Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : Contact with rapidly expanding gas may cause burns or frostbite.
Inhalation : No known significant effects or critical hazards.
Skin contact : Contact with rapidly expanding gas may cause burns or frostbite.
Frostbite : Try to warm up the frozen tissues and seek medical attention.
Ingestion : As this product is a gas, refer to the inhalation section.
Over-exposure signs/symptoms
Eye contact : No specific data.
Inhalation : No specific data.
Skin contact : No specific data.
Ingestion : No specific data.

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.

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Acetylene

Section 4. First aid measures

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media
Unsuitable extinguishing : None known.
media

Specific hazards arising : Contains gas under pressure. Extremely flammable gas. In a fire or if heated, a
from the chemical pressure increase will occur and the container may burst, with the risk of a subsequent
explosion.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Contact supplier immediately for specialist advice. Move containers from fire
area if this can be done without risk. Use water spray to keep fire-exposed containers
cool. If involved in fire, shut off flow immediately if it can be done without risk. If this is
impossible, withdraw from area and allow fire to burn. Fight fire from protected location
or maximum possible distance. Eliminate all ignition sources if safe to do so.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : Accidental releases pose a serious fire or explosion hazard. No action shall be taken
personnel involving any personal risk or without suitable training. Evacuate surrounding areas.
Keep unnecessary and unprotected personnel from entering. Shut off all ignition
sources. No flares, smoking or flames in hazard area. Avoid breathing gas. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

Environmental precautions : Ensure emergency procedures to deal with accidental gas releases are in place to avoid
contamination of the environment. Inform the relevant authorities if the product has
caused environmental pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up

Small spill : Immediately contact emergency personnel. Stop leak if without risk. Use spark-proof
tools and explosion-proof equipment.
Large spill : Immediately contact emergency personnel. Stop leak if without risk. Use spark-proof
tools and explosion-proof equipment. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.

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Acetylene

Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Contains gas under
pressure. Avoid breathing gas. Use only with adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Do not enter storage areas and confined
spaces unless adequately ventilated. Do not puncture or incinerate container. Use
equipment rated for cylinder pressure. Close valve after each use and when empty.
Protect cylinders from physical damage; do not drag, roll, slide, or drop. Use a suitable
hand truck for cylinder movement.
Use only non-sparking tools. Avoid contact with eyes, skin and clothing. Empty
containers retain product residue and can be hazardous. Store and use away from heat,
sparks, open flame or any other ignition source. Use explosion-proof electrical
(ventilating, lighting and material handling) equipment.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved area.
including any Store away from direct sunlight in a dry, cool and well-ventilated area, away from
incompatibilities incompatible materials (see Section 10). Eliminate all ignition sources. Cylinders
should be stored upright, with valve protection cap in place, and firmly secured to
prevent falling or being knocked over. Cylinder temperatures should not exceed 52 °C
(125 °F). Keep container tightly closed and sealed until ready for use. See Section 10
for incompatible materials before handling or use.

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
Ingredient name Exposure limits
Acetylene NIOSH REL (United States, 10/2016).
CEIL: 2662 mg/m³
CEIL: 2500 ppm
ACGIH TLV (United States, 3/2019). Oxygen
Depletion [Asphyxiant]. Explosive potential.

California PEL for Chemical Contaminants (

Table AC-1) (United States). Oxygen
Depletion [Asphyxiant].

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.

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Acetylene

Section 8. Exposure controls/personal protection

Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: safety glasses with side-
shields.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use. Respirator selection must be based on known or anticipated exposure
levels, the hazards of the product and the safe working limits of the selected respirator.

Section 9. Physical and chemical properties

Appearance
Physical state : Gas.
Color : Colorless.
Odor : Mild. Ethereal.
Odor threshold : Not available.
pH : Not available.
Melting point : -81°C (-113.8°F)
Boiling point : Not available.
Critical temperature : 35.25°C (95.5°F)
Flash point : Closed cup: -18.15°C (-0.67°F)
Evaporation rate : Not available.
Flammability (solid, gas) : Extremely flammable in the presence of the following materials or conditions: open
flames, sparks and static discharge and oxidizing materials.
Highly flammable in the presence of the following materials or conditions: heat.
Lower and upper explosive : Lower: 2.5%
(flammable) limits Upper: 100%
Vapor pressure : 635 (psig)
Vapor density : 0.907 (Air = 1)
Specific Volume (ft 3/lb) : 14.7058
Gas Density (lb/ft ) 3
: 0.0691
Relative density : Not applicable.
Solubility : Not available.
Solubility in water : 1.2 g/l
Partition coefficient: n- : 0.37
octanol/water
Auto-ignition temperature : 305°C (581°F)

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Acetylene

Section 9. Physical and chemical properties

Decomposition temperature : Not available.
Viscosity : Not applicable.
Flow time (ISO 2431) : Not available.
Molecular weight : 26.04 g/mole
Aerosol product
Heat of combustion : -48257522 J/kg

Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.

Incompatible materials : Oxidizers

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.

Hazardous polymerization : Under normal conditions of storage and use, hazardous polymerization will not occur.

Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Not available.
Irritation/Corrosion
Not available.
Sensitization
Not available.
Mutagenicity
Not available.
Carcinogenicity
Not available.
Reproductive toxicity
Not available.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Not available.
Specific target organ toxicity (repeated exposure)
Not available.
Aspiration hazard
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Acetylene

Section 11. Toxicological information

Not available.

Information on the likely : Not available.

routes of exposure
Potential acute health effects
Eye contact : Contact with rapidly expanding gas may cause burns or frostbite.
Inhalation : No known significant effects or critical hazards.
Skin contact : Contact with rapidly expanding gas may cause burns or frostbite.
Ingestion : As this product is a gas, refer to the inhalation section.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : No specific data.
Inhalation : No specific data.
Skin contact : No specific data.
Ingestion : No specific data.

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.
General : No known significant effects or critical hazards.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates
Not available.

Section 12. Ecological information

Toxicity
Not available.

Persistence and degradability

Not available.

Bioaccumulative potential

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Acetylene

Section 12. Ecological information

Product/ingredient name LogPow BCF Potential
Acetylene 0.37 - low

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations

Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Empty Airgas-owned pressure vessels should be returned to Airgas. Waste packaging
should be recycled. Incineration or landfill should only be considered when recycling is
not feasible. This material and its container must be disposed of in a safe way. Empty
containers or liners may retain some product residues. Do not puncture or incinerate
container.

Section 14. Transport information

DOT TDG Mexico IMDG IATA
UN number UN1001 UN1001 UN1001 UN1001 UN1001

UN proper ACETYLENE, ACETYLENE, ACETYLENE, ACETYLENE, ACETYLENE,

shipping name DISSOLVED DISSOLVED DISSOLVED DISSOLVED DISSOLVED
Transport 2.1 2.1 2.1 2.1 2.1
hazard class(es)

Packing group - - - - -
Environmental No. No. No. No. No.
hazards
“Refer to CFR 49 (or authority having jurisdiction) to determine the information required for shipment of the
product.”

Additional information
DOT Classification : Limited quantity Yes.
Quantity limitation Passenger aircraft/rail: Forbidden. Cargo aircraft: 15 kg.
TDG Classification : Product classified as per the following sections of the Transportation of Dangerous
Goods Regulations: 2.13-2.17 (Class 2).

Explosive Limit and Limited Quantity Index

0

Passenger Carrying Vessel Index

75

Passenger Carrying Road or Rail Index

Forbidden

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Acetylene

Section 14. Transport information

Special provisions
38
IATA : Quantity limitation Passenger and Cargo Aircraft: Forbidden. Cargo Aircraft Only: 15
kg.

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.

Transport in bulk according : Not available.

to IMO instruments

Section 15. Regulatory information

U.S. Federal regulations : TSCA 8(a) CDR Exempt/Partial exemption: Not determined
Clean Air Act (CAA) 112 regulated flammable substances: acetylene
Clean Air Act Section 112 : Not listed
(b) Hazardous Air
Pollutants (HAPs)
Clean Air Act Section 602 : Not listed
Class I Substances
Clean Air Act Section 602 : Not listed
Class II Substances
DEA List I Chemicals : Not listed
(Precursor Chemicals)
DEA List II Chemicals : Not listed
(Essential Chemicals)
SARA 302/304
Composition/information on ingredients
No products were found.
SARA 304 RQ : Not applicable.
SARA 311/312
Classification : Refer to Section 2: Hazards Identification of this SDS for classification of substance.

State regulations
Massachusetts : This material is listed.
New York : This material is not listed.
New Jersey : This material is listed.
Pennsylvania : This material is listed.
California Prop. 65
This product does not require a Safe Harbor warning under California Prop. 65.
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
Montreal Protocol
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.

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Acetylene

Section 15. Regulatory information

UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
Inventory list
Australia : This material is listed or exempted.
Canada : This material is listed or exempted.
China : This material is listed or exempted.
Europe : This material is listed or exempted.
Japan : Japan inventory (ENCS): This material is listed or exempted.
Japan inventory (ISHL): Not determined.
New Zealand : This material is listed or exempted.
Philippines : This material is listed or exempted.
Republic of Korea : This material is listed or exempted.
Taiwan : This material is listed or exempted.
Thailand : Not determined.
Turkey : This material is listed or exempted.
United States : This material is active or exempted.
Viet Nam : This material is listed or exempted.

Section 16. Other information

Hazardous Material Information System (U.S.A.)
Health / 0

Flammability 4
Physical hazards 3

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS®
ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
National Fire Protection Association (U.S.A.)

4 Flammability
Health 0 0 Instability/Reactivity
Note: The instability hazard rating for acetylene, dissolved (stabilized acetylene) is 2.
Special

Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Procedure used to derive the classification
Classification Justification
FLAMMABLE GASES - Category 1 Expert judgment
GASES UNDER PRESSURE - Compressed gas According to package

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Acetylene

Section 16. Other information

History
Date of printing : 11/11/2020
Date of issue/Date of : 11/11/2020
revision
Date of previous issue : 3/6/2020
Version : 2.01
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
References : Not available.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.

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 Safety Data Sheet
This safety data sheet complies with the requirements of: 2012 OSHA Hazard Communication Standard ( 29CFR 1910.1200)

Product name ANSUL ABC Multipurpose Dry Chemical Agent - Stored Pressure System

1. Identification
1.1. Product Identifier
Product name ANSUL ABC Multipurpose Dry Chemical Agent - Stored Pressure System

1.2. Other means of identification

Product code 435028
UN/ID no UN1044
Synonyms None
Chemical Family No information available

1.3. Recommended use of the chemical and restrictions on use

Recommended use No information available.
Uses advised against Consumer use.

1.4. Details of the Supplier of the Safety Data Sheet

Company Name Tyco Fire Protection Products
One Stanton Street
Marinette, WI 54143-2542
Telephone: 715-735-7411
Contact point Product Stewardship at 1-715-735-7411
E-mail address [email protected]

1.5. Emergency Telephone Number

Emergency telephone CHEMTREC 001-800-424-9300 or 001-703-527-3887

2. Hazards Identification
Classification

This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Simple asphyxiants
Gases Under Pressure - Compressed Gas

2.2. Label Elements

Signal Word
WARNING

Hazard Statements

May displace oxygen and cause rapid suffocation

Contains gas under pressure; may explode if heated

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Product name ANSUL ABC / PAGE 2 / 9
Multipurpose Dry Chemical Agent -
Stored Pressure System
_____________________________________________________________________________________________

Precautionary Statements

Storage
Protect from sunlight. Store in a well-ventilated place.

2.3. Hazards Not Otherwise Classified (HNOC)

Not Applicable.

2.4. Other Information

3. Composition/information on Ingredients
3.1. Mixture
The following component(s) in this product are considered hazardous under applicable OSHA(USA)

Chemical name CAS No. weight-%

Attapulgite 12174-11-7 1-5
Calcium carbonate 471-34-1 1-5

4. First aid measures

4.1. Description of first aid measures
General Advice Call 911 or emergency medical service. Remove and isolate contaminated clothing and
shoes.

Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If
eye irritation persists: Get medical advice/attention.

Skin contact In case of contact with liquefied gas, thaw frosted parts with lukewarm water.

Inhalation Move victim to fresh air. If breathing is irregular or stopped, administer artificial respiration.
Administer oxygen if breathing is difficult.

Ingestion If swallowed: Call a POISON CENTER or doctor/physician if you feel unwell.

Self-Protection of the First Aider Ensure that medical personnel are aware of the material(s) involved and take precautions to
protect themselves.

4.2. Most Important Symptoms and Effects, Both Acute and Delayed
Symptoms None known.

4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed
Note to physicians Keep victim warm and quiet.

5. Fire-fighting measures
5.1. Suitable Extinguishing Media
Use extinguishing agent suitable for type of surrounding fire. Dry chemical or CO2. Water spray, fog or regular foam.

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Product name ANSUL ABC / PAGE 3 / 9
Multipurpose Dry Chemical Agent -
Stored Pressure System
_____________________________________________________________________________________________

5.2. Unsuitable Extinguishing Media

None.

5.3. Specific Hazards Arising from the Chemical

Ruptured cylinders may rocket. Some may burn but none ignite readily.

5.4. Explosion Data

Sensitivity to Mechanical Impact None.
Sensitivity to Static Discharge None.

5.5. Protective Equipment and Precautions for Firefighters

Move containers from fire area if you can do it without risk. Damaged cylinders should be handled only by specialists.

6. Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal Precautions Do not touch or walk through spilled material. Stop leak if you can do it without risk.

OTHER INFORMATION Ventilate the area.

For emergency responders Use personal protection recommended in Section 8.

6.2. Environmental Precautions

Environmental Precautions Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to
contact spilled material. Prevent entry into waterways, sewers, basements or confined
areas. See Section 12 for additional Ecological Information.

6.3. Methods and material for containment and cleaning up

Methods for Containment If possible, turn leaking containers so that gas escapes rather than liquid. Allow substance
to evaporate.

Methods for Cleaning Up Use personal protective equipment as required. Cover powder spill with plastic sheet or tarp
to minimize spreading and keep powder dry. Take up mechanically, placing in appropriate
containers for disposal. Avoid creating dust. Clean contaminated surface thoroughly.

7. Handling and Storage

7.1. Precautions for Safe Handling

Advice on safe handling Avoid generation of dust. Do not breathe dust/fume/gas/mist/vapors/spray. Use with local
exhaust ventilation. Use personal protective equipment as required. Wash thoroughly after
handling.

7.2. Conditions for safe storage, including any incompatibilities

Storage Conditions Store in a well-ventilated place. Keep cool. Keep container tightly closed. Guard against
dust accumulation of material. Use care in handling/storage. Pressurized extinguishers
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Product name ANSUL ABC / PAGE 4 / 9
Multipurpose Dry Chemical Agent -
Stored Pressure System
_____________________________________________________________________________________________

should be properly stored and secured to prevent falling or being knocked over.

Incompatible Materials Strong acids.

8. Exposure Controls/Personal Protection

8.1. Control Parameters

Exposure guidelines
Chemical name ACGIH TLV OSHA PEL NIOSH IDLH Mexico OEL
Attapulgite TWA: 1 mg/m3 respirable - - -
12174-11-7 particulate matter
Calcium carbonate - - TWA: 10 mg/m3 total dust -
471-34-1 TWA: 5 mg/m3 respirable
dust
ACGIH (American Conference of Governmental Industrial Hygienists) OSHA (Occupational Safety and Health Administration of the
US Department of Labor): NIOSH IDLH Immediately Dangerous to Life or Health

8.2. Appropriate Engineering Controls

Engineering controls Ensure adequate ventilation, especially in confined areas.

8.3. Individual protection measures, such as personal protective equipment

Eye/Face Protection Avoid contact with eyes. Tight sealing safety goggles.

Skin and Body Protection No special precautions are needed in handling this material.

Respiratory Protection In case of insufficient ventilation, wear suitable respiratory equipment.

Ventilation Use local exhaust or general dilution ventilation to control exposure with applicable limits

8.4. General hygiene considerations

Do not eat, drink or smoke when using this product. Handle in accordance with good industrial hygiene and safety practice.

9. Physical and Chemical Properties

9.1. Information on basic physical and chemical properties

Physical State powder

Odor odorless Color Yellow
Odor Threshold No data available

Property Values Remar

ks •Met
hod
pH No data available
Melting point/freezing point No data available
Boiling point / boiling range No data available
Flash Point No data available
Evaporation Rate No data available
Flammability (solid, gas) No data available
Flammability limit in air
Upper flammability limit: No data available
Lower flammability limit: No data available
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Product name ANSUL ABC / PAGE 5 / 9
Multipurpose Dry Chemical Agent -
Stored Pressure System
_____________________________________________________________________________________________

Vapor Pressure No data available

Vapor Density No data available
Specific gravity No data available
Water Solubility No data available
Solubility in Other Solvents No data available
Partition coefficient No data available
Autoignition Temperature No data available
Decomposition Temperature No data available
Kinematic viscosity No data available

10. Stability and Reactivity

10.1. Chemical Stability

Stable under recommended storage conditions.

10.2. Reactivity
No data available

10.3. Possibility of hazardous reactions

Hazardous polymerization does not occur.

Hazardous Polymerization Hazardous polymerization does not occur.

10.4. Conditions to Avoid

None known based on information supplied.

10.5. Incompatible Materials

Strong acids.

10.6. Hazardous decomposition products

Carbon oxides. Nitrogen oxides (NOx).

11. Toxicological Information

11.1. Information on Likely Routes of Exposure

Product information

Inhalation May cause irritation of respiratory tract.

Eye Contact May cause irritation.

Skin contact May cause irritation.

Ingestion Ingestion may cause irritation to mucous membranes.

Component Information
Acute Toxicity

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Product name ANSUL ABC / PAGE 6 / 9
Multipurpose Dry Chemical Agent -
Stored Pressure System
_____________________________________________________________________________________________

Chemical name Oral LD50 Dermal LD50 Inhalation LC50

Calcium carbonate = 6450 mg/kg ( Rat ) - -
471-34-1

11.2. Information on Toxicological Effects

Symptoms No information available.

11.3. Delayed and immediate effects as well as chronic effects from short and long-term exposure
Carcinogenicity Attapulgite (palygorskite fibers) is a hydrated magnesium aluminum silicate. Long
palygorskite (attapulgite) fibers (>5 micrometers) are possibly carcinogenic to humans
(Group 2B). Short palygorskite (attapulgite) fibers (<5 micrometers) cannot be classified as
to their carcinogenicity to humans (Group 3). The attapulgite present in this product
contains fibers 0.5-2.5 um range, so would be considered by IARC as Group 3. This
product contains crystalline silica (quartz) in a non-respirable form. Inhalation of crystalline
silica is unlikely to occur from exposure to this product.
Chemical name ACGIH IARC NTP OSHA
Attapulgite - Group 3 - X
12174-11-7
IARC (International Agency for Research on Cancer)
Group 3 - Not Classifiable as to Carcinogenicity in Humans
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X - Present
Reproductive Toxicity No information available.
STOT - Single Exposure No information available.
STOT - Repeated Exposure No information available.
Target organ effects Eyes, Respiratory System, Skin.
Aspiration Hazard No information available.

11.4. Numerical Measures of Toxicity - Product information

The following values are calculated based on chapter 3.1 of the GHS document
ATEmix (dermal) 8156 mg/kg

12. Ecological Information

12.1. Ecotoxicity

Not classified.

Chemical name Algae/aquatic plants Fish Crustacea

Ammonium sulfate, technical - LC50 96 h 460 - 1000 mg/L LC50 48 h = 14 mg/L Daphnia
7783-20-2 Leuciscus idus static; LC50 96 h magna; EC50 24 h = 423 mg/L
123 - 128 mg/L Poecilia reticulata Daphnia magna
semi-static; LC50 96 h = 126 mg/L
Poecilia reticulata; LC50 96 h > 100
mg/L Pimephales promelas; LC50
96 h 32.2 - 41.9 mg/L
Oncorhynchus mykiss flow-through;
LC50 96 h 5.2 - 8.2 mg/L
Oncorhynchus mykiss static; LC50
96 h = 18 mg/L Cyprinus carpio;
LC50 96 h = 480 mg/L Brachydanio
rerio flow-through; LC50 96 h = 420
mg/L Brachydanio rerio semi-static;
LC50 96 h = 250 mg/L Brachydanio
rerio
Silicic Acid/silica gel, Amorphous EC50 (72h) = 440 mg/L LC50 (96h) static = 5000 mg/L EC50 (48h) = 7600 mg/L
_____________________________________________________________________________________________

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Product name ANSUL ABC / PAGE 7 / 9
Multipurpose Dry Chemical Agent -
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_____________________________________________________________________________________________

7631-86-9 Pseudokirchneriella subcapitata Brachydanio rerio Ceriodaphnia dubia

12.2. Persistence and Degradability

No information available.

12.3. Bioaccumulation
No information available.

12.4. Other Adverse Effects

No information available

13. Disposal Considerations

13.1. Waste Treatment Methods

Disposal of wastes This material, as supplied, is not a hazardous waste according to Federal regulations (40
CFR 261). This material could become a hazardous waste if it is mixed with or otherwise
comes in contact with a hazardous waste, if chemical additions are made to this material, or
if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether
the altered material is a hazardous waste. Consult the appropriate state, regional, or local
regulations for additional requirements.

Contaminated Packaging Do not reuse container. Pressurized container: Do not pierce or burn, even after use.

14. Transport Information

DOT
UN/ID no UN1044
Proper Shipping Name Fire extinguishers
Description UN1044, Fire extinguishers, 2.2
Hazard class 2.2
Special Provisions 18, 110
Emergency Response Guide 126
Number

TDG
UN/ID no UN1044
Description UN1044, Fire extinguishers, 2.2
Proper Shipping Name Fire extinguishers
Hazard class 2.2

MEX
UN/ID no UN1044
Description UN1044, Fire extinguishers, 2.2
Proper Shipping Name Fire extinguishers
Hazard class 2.2

ICAO (air)
UN/ID no UN1044
Description UN1044, Fire extinguishers, 2.2
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Product name ANSUL ABC / PAGE 8 / 9
Multipurpose Dry Chemical Agent -
Stored Pressure System
_____________________________________________________________________________________________

Proper Shipping Name Fire extinguishers

Hazard class 2.2
Special Provisions A19

IATA
UN/ID no UN1044
Description UN1044, Fire extinguishers, 2.2
Proper Shipping Name Fire extinguishers
Hazard class 2.2
ERG Code 2L
Special Provisions A19

IMDG
UN/ID no UN1044
Description UN1044, Fire extinguishers, 2.2
Proper Shipping Name Fire extinguishers
Hazard class 2.2
EmS-No F-C, S-V
Special Provisions 225

15. Regulatory Information

15.1. International Inventories
TSCA Complies
DSL/NDSL Complies
ENCS Does not comply
IECSC Complies
KECL Does not comply
PICCS Complies
AICS Complies

Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances

15.2. US Federal Regulations

SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical
or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

Chemical name SARA 313 - Threshold Values %

Ammonium dihydrogen phosphate - 7722-76-1 1.0
Ammonium sulfate, technical - 7783-20-2 1.0
SARA 311/312 Hazard Categories
Acute Health Hazard No
Chronic health hazard No
Fire Hazard No
Sudden Release of Pressure Hazard Yes
Reactive Hazard No

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_____________________________________________________________________________________________

CWA (Clean Water Act)

This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)

CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material

15.3. US State Regulations

California Proposition 65
This product contains the following Proposition 65 chemicals

Chemical name California Proposition 65

Attapulgite - 12174-11-7 Carcinogen

U.S. State Right-to-Know Regulations

Chemical name New Jersey Massachusetts Pennsylvania

Silicic Acid/silica gel, Amorphous - X X
7631-86-9
Magnesium carbonate X X -
546-93-0

16. Other information, including date of preparation of the last revision

NFPA Health Hazards 0 Flammability 0 Instability 0 Physical and chemical
properties -
HMIS Health Hazards 0 Flammability 0 Physical Hazards 3 Personal Protection X

Revision date 13-Feb-2019

Revision note No information available.
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.

End of Safety Data Sheet

_____________________________________________________________________________________________

Revision date 13-Feb-2019 Version 36

 Safety Data Sheet CS: 1. 9 . 22

Page: 1 of 5

IInfosafe No™ LQ3HB Issue Date October 2019 ISSUED by MILL-R OSE

Product Name Blue Monster PTFE Thread Seal Tape

1. Identification
GHS Product Blue Monster PTFE Thread Seal Tape
Identifier
Company Name Mill-Rose
Address 7310 Corporate Blvd
Mentor,
Ohio 44060
USA
Telephone/Fax Tel: (440)9746730
Number Fax: (440)2551072
Recommended use of Industrial tape.
the chemical and
restrictions on use
2. Hazard Identification
Classification of the Not classified as Hazardous according to the Globally Harmonised System
substance or mixture of Classification and labelling of Chemicals (GHS) including Work, Health
and Safety regulations , Australia.
Not classified as Dangerous Goods according to the Australian Code for
the Transport of Dangerous Goods by Road and Rail. (7th edition)
3. Composition/information on ingredients
Information on This product contains the following
Composition ingredients: -Polytetrafluoroethylene
-Distillates (petroleum ), hydrotreated
light -Pigment
Ingredients Name CAS Proportion

Ingredients determined 100%

not to be hazardous
4. First-aid measures
Inhalation Not considered a potential route of exposure. However, if inhaled, remove
affected person from contaminated area. Keep at rest until recovered. If
symptoms develop and/or persist seek medical attention .
Ingestion Unlikely due to form of product. However, if ingested, do not induce vomiting.
Wash out mouth thoroughly with water. If symptoms develop seek medical
attention.
Skin Wash affected area thoroughly with soap and water. If symptoms develop seek
medical attention.
Eye contact Not considered a potential route of exposure. However if in eyes, hold eyelids
apart and flush the eyes continuously with running water. Continue flushing
for several minutes until all contaminants are washed out completely. If
symptoms develop and persist seek medical attention.
First Aid Facilities Eyewash and normal washroom facilities.
Advice to Doctor Treat symptomatically.
Other Information For advice in an emergency, contact a Poisons Information Centre (Phone:
Australia 131 126) or a doctor.
5. Fire-fighting measures
Suitable Use carbon dioxide, dry chemical or foam.
extinguishing
media Hazards Under fire conditions this product may emit toxic and/or irritating fumes,
from Combustion smoke and gases including carbon monoxide, carbon dioxide, hydrogen
Products fluoride and oxides of nitrogen .
Specific hazards Combustible. This product will readily burn under fire conditions.
arising from the
chemical
Decomposition Not available
Temp.
Precautions in Fire fighters should wear Self-Contained Breathing Apparatus (SCBA) operated
connection with Fire in positive pressure mode and full protective clothing to prevent exposure
to vapours or fumes. Water spray may be used to cool down heat-exposed
 Safety Data Sheet CS: 1. 9 . 22

Page: 2 of 5

Infosafe No™ LQ3HB Issue Date October 2019 ISSUED by MILL-ROSE

Product Name Blue Monster PTFE Thread Seal Tape

containers . Fight fire from safe location. This product should be

prevented from entering drains and watercourses.
6. Accidental release measures
Personal precautions, Wear appropriate personal protective equipment and clothing to prevent
protective equipment exposure. Collect the material and place into a suitable labelled container.
and emergency Dispose of waste according to the applicable local and national regulations. If
procedures contamination of sewers or waterways occurs inform the local water and waste
management authorities in accordance with local regulations.
7. Handling and storage
Precautions for Avoid exposure. Use only in a well ventilated area. Keep containers
Safe Handling tightly closed. Prevent the build up of dusts, mists or vapours in the
work atmosphere. Maintain high standards of personal hygiene i.e. Washing
hands prior to eating, drinking, smoking or using toilet facilities.
Conditions for safe Store in a cool, dry, well-ventilated area, out of direct sunlight. Ensure that
storage, including any storage conditions comply with applicable local and national regulations.
incom patabilities
Handling Recommended operating temperatures: -260°C to
Temperatures Storage
Temperatures +260°C Store below 260°C.

8. Exposure controls/personal protection

Occupational No exposure value assigned for this material by Safe Work, Australia. However ,
exposure limit values the available exposure limits for decomposition products are given below:

Safe Work, Australia Exposure Standards:

Substance TWA STEL NOTICES
ppm mg/m 3 ppm mg/m3
Hydrogen fluoride 3 2.6 Peak Limitation
TWA (Time Weighted Average) The average airborne concentration of a
particular substance when calculated over a normal eight-hour working day,
for a five-day week.
STEL (Short Term Exposure Limit): The average airborne concentration over a
15 minute period which should not be exceeded at any time during a normal
eight-hour workday.
Peak Limitation: A ceiling concentration which should not be exceeded over
a measurement period which should be as short as possible but not exceeding
15 minutes.
Biological No biological limits allocated.
Limit Values
Appropriate Use with good general ventilation.
engineering controls
Respiratory None required, when used as intended.
Protection Eye
Protection None required, when used as intended.
Hand Protection None required, when used as intended.
Body Protection Suitable protective work wear, e.g. cotton overalls buttoned at neck and
wrist is recommended.
9. Physical and chemical properties
Appearance Solid polymeric film
Colour Blue
Odour Odourless
Decomposition Not available
Temperature

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 Safety Data Sheet CS: 1. 9 . 22

Page: 3 of 5

IInfosafe No™ LQ3HB Issue Date October 2019 ISSUED by MILL-ROSE

Product Name Blue Monster PTFE Thread Seal Tape

Melting Point Not available

Boiling Point Not available
Solubility in Water Insoluble
Specific Gravity 2.1
pH Not applicable
Vapour Pressure Not applicable
Vapour Density Not available
(Air=l)
Evaporation Rate Not available
Odour Threshold Not available
Viscosity Not applicable
Partition Coefficient: Not available
n-octanol/water
Flash Point Not applicable
Flammability Not flammable
Auto-Ignition Not self igniting
Temperature
Explosion Limit • Not applicable
Upper
Explosion Limit • Not applicable
Lower
10. Stability and reactivity
Reactivity Reacts with incompatible materials.
Chemical Stability Stable under normal conditions of storage and handling.
Conditions to Avoid Heat and sources of ignition. Temperatures >260°C without
adequate ventilation.
Incompatible Strong oxidising agents. Alkali metals, extremely potent oxidisers e.g.
Materials fluorine , chlorine tri-fluoride, 80% NaOH or KOH, metal hydrides such as
boranes (e.g. B2H6) aluminium chloride, ammonia, certain amines (R-NH2)
imines (RH-NH) and 70% nitric acid at temperatures near 260°C. Do not use on
oxygen lines.
Hazardous Thermal decomposition may result in the release of toxic and/or
Decomposition irritating fumes including carbon monoxide, hydrogen fluoride and carbon
Products dioxide. Carbonyl fluoride is the main decomposition product formed when
PTFE is subjected to extended exposure at normal sintering temperatures
(400°C). Carbonyl fluoride is immediately converted to highly corrosive
hydrogen fluoride in the presence of moist air.
Possibility of Reacts with incompatible materials.
hazardous reactions
11. Toxicological Information
Toxicology No toxicology data available for this product.
Information
No toxicity was observed in male/female rats fed PTFE (up to 25%) for 90 days.
Local sarcomas were induced in mice and rats implanted subcutaneously or
intraperitoneally with PTFE. However, this is not considered relevant to
normal industrial usage.
Ingestion Ingestion unlikely due to form of product. Ingestion of this product may
irritate the gastric tract causing nausea and vomiting .
Inhalation No adverse effects expected. The material is not normally an inhalation hazard
at temperatures below 260°C as it remains an inert solid. However, exposure to
thermal degradation products at temperatures above 260°C or fumes from tobacco
contaminated with particles of the product may result in polymer fume fever or
influenza-like symtoms (chills, headaches, difficulty in breathing and fever)
Symptoms may appear several hours after exposure but will disappear within

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 Safety Data Sheet CS: 1. 9 . 22

Page: 4 of 5

Infosafe No™ LQ3HB Issue Date October 2019 ISSUED by MILL-ROSE

Product Name Blue Monster PTFE Thread Seal Tape

24-48 hours . There are exposure standards for decomposition products.

Skin May be irritating to skin. The symptoms may include redness, itching
and swelling.
Eye Eye contact may cause mechanical irritation . May result in mild abrasion.
Respiratory Not expected to be a respiratory sensitiser .
sensitisation Skin
Sensitisation Not expected to be a skin sensitiser.

Germ cell Not considered to be a mutagenic hazard .

mutagenicity
Carcinogenicity Polytetrafluoroethylene is listed as a Group 3: Not classifiable as to
carcinogenicity to humans according to International Agency for Research
on Cancer (IARC ).
Reproductive Not considered to be toxic to reprod uction.
Toxicity STOT·
single exposure Not expected to cause toxicity to a specific target organ.
STOT-repeated
Not expected to cause toxicity to a specific target organ.
exposure
Aspiration Hazard Not considered to be an aspiration hazard.

12. Ecological information

Ecotoxicity No ecological data are available for this material.
Persistence and Not available
degradability
Mobility Not available
Bioaccumulative Not available
Potential
Other Adverse Not available
Effects
Environmental Prevent this material entering waterways, drains and sewers.
Protection

13. Disposal considerations

Disposal The disposal of the spilled or waste material must be done in accorda nce with
Considerations applicable local and national regulations.
14. Transport information
Transport Road and Rail Transport
Information Not classified as Dangerous Goods according to the Australian Code for the
Transport of Dangerous Goods by Road and Rail (ADG Code) (7th edition).
Marine Transport (IMO/IMDG):
Not classified as Dangerous Goods by the criteria of the International
Maritime Dangerous Goods Code (IMDG Code) for transport by sea.
Air Transport (ICAO/IATA):
Not classified as Dangerous Goods by the criteria of the International Air
Transport Association (IATA) Dangerous Goods Regulations for transport by
IMDG Marine air. No
pollutant
15. Regulatory information
Regulatory Not classified as Hazardous according to the Globally Harmonised System
Information of Classification and labelling of Chemicals (GHS) including Work, Health
and Safety regulations, Australia.
Not classified as a Scheduled Poison accord ing to the Standard for the
Uniform Scheduling of Medicines and Poisons (SUSMP).
Poisons Schedule Not Scheduled

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 Safety Data Sheet CS: 1. 9 . 22

Page: 5 of 5

Infosafe No™ LQ3HB Issue Date October 2019 ISSUED by MILL-ROSE

Product Name Blue Monster PTFE Thread Seal Tape

16. Other Information

Date of SDS Created: October 2019
preparation or last
revision of SDS
Literature Preparation of Safety Data Sheets for Hazardous Chemicals Code of
References Practice. Standard for the Uniform Scheduling of Medicines and Poisons.
Australian Code for the Transport of Dangerous Goods by Road & Rail.
Model Work Health and Safety Regulations, Schedule 10: Prohibited
carcinogens , restricted carcinogens and restricted hazardous chemicals.
Workplace exposure standards for airborne contaminants, Safe work
Australia. American Conference of Industrial Hygienists (ACGIH).
Globally Harmonised System of classification and labelling of chemicals.
...End Of MSDS...

Print Dat e : 1 0 / 17/2019 CS : 1 . 9 . 22

Date Printed: 5/1/2015 Page 1 / 9

Safety Data Sheet

* T rusted Quality Sinc e 1921 *
www.rustoleum.c om

1. Identification
Pro d u ct N a m e : PRO LSPR 6PK MARK CLEAR MARKING R e vi si o n D a te : 5/1/2015
SPRAY

Pro d u ct Id e n ti fi e r: 2596838 Su p e rce d e s D a te : New SDS

Pro d u ct U se /Cl a ss: Marking Paint/Aerosol

Su p p l i e r: Rust-Oleum Corporation M a n u fa ctu re r: Rust-Oleum Corporation

11 Hawthorn Parkway 11 Hawthorn Parkway
Vernon Hills, IL 60061 Vernon Hills, IL 60061
USA USA

Pre p a re r: Regulatory Department

Em e rg e n cy Te l e p h o n e : 24 Hour Hotline: 847-367-7700

2. Hazard Identification
EM ER GEN CY OVER VIEW: Extremely flammable liquid and vapor. Vapors may cause flash fire or explosion. Harmful if
inhaled. May affect the brain or nervous system causing dizziness, headache or nausea. Contents Under Pressure. May cause
eye, skin, or respiratory tract irritation. KEEP OUT OF REACH OF CHILDREN. Harmful if inhaled. Harmful if swallowed. Causes
eye irritation. Use ventilation necessary to keep exposures below recommended exposure limits, if any. Vapor Harmful. Causes
Eye, Skin, Nose, and Throat Irritation.

Cl a ssi fi ca ti o n
Sym b o l (s) o f Pro d u ct

Si g n a l Wo rd
Danger

Po ssi b l e H a za rd s
62% of the mixture consists of ingredient(s) of unknown acute toxicity

GH S H AZAR D STATEM EN TS
Flammable Aerosol, category 1 H222 Extremely flammable aerosol.
Flammable Liquid, category 1 H224 Extremely flammable liquid and vapor.
Acute Toxicity, Oral, category 5 H303 May be harmful if swallowed.
Acute Toxicity, Dermal, category 5 H313 May be harmful in contact with skin.
Skin Irritation, category 2 H315 Causes skin irritation.
Eye Irritation, category 2 H319 Causes serious eye irritation.
Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled.
STOT, single exposure, category 3, RTI H335 May cause respiratory irritation.
STOT, single exposure, category 3, NE H336 May cause drowsiness or dizziness.
Aspiration Hazard, category 2 H305 May be harmful if swallowed and enters airways.
Eye Irritation, category 2B H320 Causes eye irritation.
Date Printed: 5/1/2015 Page 2 / 9
Flammable Aerosol, category 1 H280 Contains gas under pressure; may explode if heated.
Germ Cell Mutagenicity, category 1B H340 May cause genetic defects. Classified as mutagenic Category 1 if one
ingredient is present at or above 0.1%. Applies to liquids, solids (w/w units)
and gases (v/v). The substance may also have its own exposure limit.
Routes of exposure are dependent on ingredient form.
Carcinogenicity, category 1B H350 May cause cancer. Classified as carcinogenic Category 1 on the basis of
epidemiological and/or animal data. Mixtures are classified as carcinogenic
when at least 1 ingredient has been classified as carcinogenic and is present
at 0.1% or above Routes of exposure are dependant on ingredient form.
STOT, repeated exposure, category 2 H373 May cause damage to organs <or state all organs affected, if known> through
prolonged or repeated exposure <state route of exposure if it is conclusively
proven that no other routes of exposure cause the hazard>.
GH S PR ECAU TION AR Y STATEM EN TS
P211 Do not spray on an open flame or other ignition source.
P220 Keep/Store away from clothing/…/combustible materials.
P235 Keep cool.
P251 Pressurized container: Do not pierce or burn, even after use.
P375 Fight fire remotely due to the risk of explosion.
P102 Keep out of reach of children.
P103 Read label before use.
P202 Do not handle until all safety precautions have been read and understood.
P234 Keep only in original container.
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P281 Use personal protective equipment as required.
P285 In case of inadequate ventilation wear respiratory protection.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P351 Rinse cautiously with water for several minutes.
P374 Fight fire with normal precautions from a reasonable distance.
P402 Store in a dry place.
P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50°C / 122°F.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/…/ equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin
with water/shower.
P370+P378 In case of fire: Use … for extinction.
P403+P235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents/container to …
P321 Specific treatment (see … on this label).
P352 Wash with plenty of soap and water.
P362 Take off contaminated clothing and wash before reuse.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing.
Date Printed: 5/1/2015 Page 3 / 9
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P201 Obtain special instructions before use.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P314 Get medical advice/attention if you feel unwell.
P302+P350 IF ON SKIN: Gently wash with plenty of soap and water.

3. Composition/Information On Ingredients

H AZAR D OU S SU BSTAN CES

Ch e m i ca l N a m e CAS-N o . Wt.% GH S Sym b o l s GH S Sta te m e n ts
Range

Acetone 67-64-1 25-50 GHS02-GHS07 H225-336-319

Propane 74-98-6 10-25
n-Butane 106-97-8 2.5-10
Naphtha, Petroleum, Hydrotreated Light 64742-49-0 2.5-10 GHS08 H340-350
Xylene (mixed isomers) 1330-20-7 2.5-10 GHS02-GHS07 H226-312-332-315
Mineral Spirits 64742-88-7 2.5-10 GHS06-GHS08 H331-372
n-Butyl Acetate 123-86-4 2.5-10 GHS02-GHS07 H225-336
Barium Sulfate 7727-43-7 2.5-10
Ethylbenzene 100-41-4 1.0-2.5 GHS02-GHS07 H225-332

The text for GHS Hazard Statements shown above (if any) is given in the "16. Other Information" section.

4. First-aid Measures
FIR ST AID - EYE CON TACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get
medical attention. Do NOT allow rubbing of eyes or keeping eyes closed.
FIR ST AID - SKIN CON TACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation
develops or persists.
FIR ST AID - IN H AL ATION : Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the
area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.
FIR ST AID - IN GESTION : Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter
the lungs and cause severe lung damage. Get immediate medical attention. If swallowed, get medical attention.

5. Fire-fighting Measures
EXTIN GU ISH IN G M ED IA: Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Water Fog

U N U SU AL FIR E AN D EXPL OSION H AZAR D S: FLASH POINT IS LESS THAN 20°F. EXTREMELY FLAMMABLE LIQUID AND
VAPOR!Water spray may be ineffective. Closed containers may explode when exposed to extreme heat due to buildup of steam.
Closed containers may explode when exposed to extreme heat. Vapors may form explosive mixtures with air. Vapors can travel to
a source of ignition and flash back. Isolate from heat, electrical equipment, sparks and open flame. Perforation of the pressurized
container may cause bursting of the can. No unusual fire or explosion hazards noted. Keep containers tightly closed.
SPECIAL FIR EFIGH TIN G PR OCED U R ES: Full protective equipment including self-contained breathing apparatus should be
used. Evacuate area and fight fire from a safe distance. Water may be used to cool closed containers to prevent pressure buildup
and possible autoignition or explosion. Use water spray to keep fire-exposed containers cool. Containers may explode when
heated.

6. Accidental Release Measures

Date Printed: 5/1/2015 Page 4 / 9
STEPS TO BE TAKEN IF M ATER IAL IS R EL EASED OR SPIL L ED : Contain spilled liquid with sand or earth. DO NOT use
combustible materials such as sawdust. Isolate the hazard area and deny entry to unnecessary and unprotected personnel.
Remove all sources of ignition, ventilate area and remove with inert absorbent and non-sparking tools. Dispose of according to
local, state (provincial) and federal regulations. Do not incinerate closed containers. Ventilate area, isolate spilled material, and
remove with inert absorbent. Dispose of contaminated absorbent, container, and unused contents in accordance with local, state,
and federal regulations.

7. Handling and Storage

H AN D L IN G: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder before
reuse. Use only with adequate ventilation. Follow all MSDS/label precautions even after container is emptied because it may retain
product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing.
STOR AGE: Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Contents under
pressure. Do not store above 120 ° F. Store large quantities in buildings designed and protected for storage of NFPA Class I
flammable liquids. Product should be stored in tightly sealed containers and protected from heat, moisture, and foreign materials.
Store in a dry, well ventilated place. Keep container tightly closed when not in use. Keep away from heat, sparks, flame and sources
of ignition. Avoid excess heat.

8. Exposure Controls/Personal Protection

W eight % ACGIH T LV- ACGIH T LV- OSHA PEL- OSHA PEL-

Ch e m i ca l N a m e CAS-N o . Less T han TWA ST EL TWA CEILING
Acetone 67-64-1 30.0 500 ppm 750 ppm 1000 ppm N.E.
Propane 74-98-6 20.0 1000 ppm N.E. 1000 ppm N.E.
n-Butane 106-97-8 10.0 1000 ppm 1000 ppm N.E. N.E.
Naphtha, Petroleum,
64742-49-0 10.0 200 mg/ m3 N.E. N.E. N.E.
Hydrotreated Light
Xylene (mixed isomers) 1330-20-7 10.0 100 ppm 150 ppm 100 ppm N.E.
Mineral Spirits 64742-88-7 10.0 100 ppm N.E. 100 ppm N.E.
n-Butyl Acetate 123-86-4 10.0 150 ppm 200 ppm 150 ppm N.E.
5 mg/ m3
(Inhlalable
15 mg/ m3 [Total
Barium Sulfate 7727-43-7 5.0 fraction w/ o N.E. N.E.
Dust]
asbestos and
<1% cryst.silica)
Ethylbenzene 100-41-4 5.0 20 ppm 125 ppm 100 ppm N.E.

PER SON AL PR OTECTION

EN GIN EER IN G CON TR OL S: Use explosion-proof ventilation equipment. Provide general dilution of local exhaust ventilation in
volume and pattern to keep TLV of hazardous ingredients below acceptable limits. Prevent build-up of vapors by opening all doors
and windows to achieve cross-ventilation. Use process enclosures, local exhaust ventilation, or other engineering controls to
control airborne levels below recommended exposure limits.
R ESPIR ATOR Y PR OTECTION : A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must
be followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with
organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to
exceed exposure limits.
SKIN PR OTECTION : Use gloves to prevent prolonged skin contact. Nitrile or Neoprene gloves may afford adequate skin
protection.
EYE PR OTECTION : Use safety eyewear designed to protect against splash of liquids.
OTH ER PR OTECTIVE EQU IPM EN T: Refer to safety supervisor or industrial hygienist for further guidance regarding types of
personal protective equipment and their applications.
H YGIEN IC PR ACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated
clothing immediately and launder before reuse.
Date Printed: 5/1/2015 Page 5 / 9

9. Physical and Chemical Properties

Ap p e a ra n ce : Aerosolized Mist Ph ysi ca l Sta te : Liquid
Od o r: Solvent Like Od o r Th re sh o l d : N.E.
R e l a ti ve D e n si ty: 0.748 pH: N.A.
Fre e ze Po i n t, ° C: N.D. Vi sco si ty: N.D.
So l u b i l i ty i n Wa te r: Slight Pa rti ti o n Co e ffi ci e n t, n -
No Information
D e co m p o sti o n Te m p ., ° C: No Information o cta n o l /w a te r:
Bo i l i n g R a n g e , ° C: -11 - 415 Exp l o si ve L i m i ts, vo l % : 0.7 - 13.0
Fl a m m a b i l i ty: Does not Support Combustion Fl a sh Po i n t, ° C: >93
Eva p o ra ti o n R a te : Faster than Ether Au to -i g n i ti o n Te m p ., ° C: No Information
Va p o r D e n si ty: Heavier than Air Va p o r Pre ssu re : N.D.

(See "Other information" Section for abbreviation legend)

10. Stability and Reactivity

CON D ITION S TO AVOID : Avoid temperatures above 120 ° F. Avoid contact with strong acid and strong bases. Avoid all possible
sources of ignition.
IN COM PATIBIL ITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies.
H AZAR D OU S D ECOM POSITION : By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it
emits acrid smoke and irritating fumes. Contains solvents which may form carbon monoxide, carbon dioxide, and formaldehyde.
H AZAR D OU S POL YM ER IZATION : Will not occur under normal conditions.
STABIL ITY: This product is stable under normal storage conditions.

11. Toxicological information

EFFECTS OF OVER EXPOSU R E - EYE CON TACT: Causes Serious Eye Irritation
EFFECTS OF OVER EXPOSU R E - SKIN CON TACT: May cause skin irritation. Allergic reactions are possible.
EFFECTS OF OVER EXPOSU R E - IN H AL ATION : High gas, vapor, mist or dust concentrations may be harmful if inhaled. High
vapor concentrations are irritating to the eyes, nose, throat and lungs. Harmful if inhaled. Avoid breathing fumes, spray, vapors, or
mist. Prolonged or excessive inhalation may cause respiratory tract irritation.
EFFECTS OF OVER EXPOSU R E - IN GESTION : Harmful if swallowed.
EFFECTS OF OVER EXPOSU R E - CH R ON IC H AZAR D S: IARC lists Ethylbenzene as a possible human carcinogen (group
2B). Overexposure to xylene in laboratory animals has been associated with liver abnormalities, kidney, lung, spleen, eye and
blood damage as well as reproductive disorders. Effects in humans, due to chronic overexposure, have included liver, cardiac
abnormalities and nervous system damage. May cause central nervous system disorder (e.g., narcosis involving a loss of
coordination, weakness, fatigue, mental confusion, and blurred vision) and/or damage. Reports have associated repeated and
prolonged occupational overexposure to solvents with permanent brain and nervous system damage. High concentrations may
lead to central nervous system effects (drowsiness, dizziness, nausea, headaches, paralysis, and blurred vision) and/or damage.
PR IM AR Y R OU TE(S) OF EN TR Y: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact

ACU TE TOXICITY VAL U ES

Th e a cu te e ffe cts o f th i s p ro d u ct h a ve n o t b e e n te ste d . D a ta o n i n d i vi d u a l co m p o n e n ts a re ta b u l a te d b e l o w :
CAS-N o . Ch e m i ca l N a m e Ora l L D 5 0 D e rm a l L D 5 0 Va p o r L C5 0
74-98-6 Propane N.I. N.I. 658 mg/L Rat
64742-49-0 Naphtha, Petroleum, Hydrotreated Light >5000 mg/kg Rat >3160 mg/kg Rabbit N.I.
1330-20-7 Xylene (mixed isomers) 4300 mg/kg Rat N.I. 47635 mg/L Rat
64742-88-7 Mineral Spirits >5000 mg/kg Rat 3000 mg/kg Rabbit >5.28 mg/L Rat
123-86-4 n-Butyl Acetate N.I. >17600 mg/kg Rabbit N.I.
100-41-4 Ethylbenzene 3500 mg/kg Rat 15354 mg/kg Rabbit 17.2 mg/L Rat

N.I. - No Information

12. Ecological Information

ECOL OGICAL IN FOR M ATION : Product is a mixture of listed components.
 Date Printed: 5/1/2015 Page 6 / 9

13. Disposal Information

D ISPOSAL IN FOR M ATION : Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not
allow to enter waterways, wastewater, soil, storm drains or sewer systems.

14. Transport Information

D o m e sti c (U SD OT) In te rn a ti o n a l (IM D G) Ai r (IATA) TD G (Ca n a d a )
U N N u m b e r: N.A. 1950 1950 N.A.

Paint Products in Paint Products in

Pro p e r Sh i p p i n g N a m e : Aerosols Aerosols
Limited Quantities Limited Quantities

H a za rd Cl a ss: N.A. 2.1 2.1 N.A.

Pa cki n g Gro u p : N.A. N.A. N.A. N.A.
L i m i te d Qu a n ti ty: Yes Yes Yes Yes

15. Regulatory Information

U.S. Federal Regulations:
CE R CLA - S A R A H a za rd Ca te g o ry
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:

Fire Hazard, Pressure Hazard, Acute Health Hazard, Chronic Health Hazard

S a ra S e c tio n 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:

Che mic a l N a me CA S -N o .
Xylene (mixed isomers) 1330-20-7
Ethylbenzene 100-41-4

T o xic S ub s ta nc e s Co ntro l A c t:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(b) if exported
from the United States:

No TSCA 12(b) components exist in this product.

CA LIFOR N IA P R OP OS IT ION 65:

Che mic a l N a me CA S -N o .
Ethylbenzene 100-41-4

CA LIFOR N IA P R OP OS IT ION 65 R E P R OD U CT IV E T OXIN S

No Proposition 65 Reproductive Toxins exist in this product.

International Regulations:
CA N A D IA N W H MIS :

This SDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.
Date Printed: 5/1/2015 Page 7 / 9

16. Other Information

H MIS R A T IN GS
H e a l th : 2* Fl a m m a b i l i ty: 4 Ph ysi ca l H a za rd : 0 Pe rso n a l Pro te cti o n : X

CA N A D IA N W H MIS CLA S S : AB5 D2A D2B

N FP A R A T IN GS
H e a l th : 2 Fl a m m a b i l i ty: 4 In sta b i l i ty 0

VOL ATIL E OR GAN IC COM POU N D S, g /L : 546

M SD S R EVISION D ATE: 5/1/2015

R EASON FOR R EVISION : No Information

Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined

T e xt fo r GH S H a za rd S ta te me nts s ho wn in S e c tio n 3 d e s c rib ing e a c h

ing re d ie nt:
H225 Highly flammable liquid and vapor.
H226 Flammable liquid and vapor.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H332 Harmful if inhaled.
H336 May cause drowsiness or dizziness.
H340 May cause genetic defects <state route of exposure if it is conclusively proven that no other routes of
exposure cause the hazard>.
H350 May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure
cause the hazard>.
H372 Causes damage to organs <or state all organs affected, if known> through prolonged or repeated
exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the
hazard>.

Ic o ns fo r GH S P ic to g ra ms s ho wn in S e c tio n 3 d e s c rib ing e a c h ing re d ie nt:

GH S0 2

GH S0 6

GH S0 7

GH S0 8
Date Printed: 5/1/2015 Page 8 / 9

Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be
accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of
these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred
by the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or
reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with
caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and
examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all
applicable international, federal, state, and local laws and regulations.
Date Printed: 5/1/2015 Page 9 / 9
 SAFETY DATA SHEET
Diesel Fuel

1. IDENTIFICATION
Product Identifier Diesel Fuel

Synonyms: Diesel Fuel, Motor Vehicle Diesel Fuel, Dyed Diesel, * DieselOne®, * DieselOne® w/Platinum Plus DFX,
Low Sulfur Diesel (LSD), Ultra Low Sulfur Diesel (ULSD)
Intended use of the Fuel
product:
Contact: Global Companies LLC
Water Mill Center
800 South St.
Waltham, MA 02454-9161
www.globalp.com

Contact Information: EMERGENCY TELEPHONE NUMBER (24 hrs): CHEMTREC (800) 424-9300
COMPANY CONTACT (business hours): 800-542-0778

2. HAZARD IDENTIFICATION
According to OSHA 29 CFR 1910.1200 HCS

Classification of the Substance or Mixture

Classification (GHS-US):
Flam. Liquid Category 3 H226
Skin Corrosion/Irritation Category 2 H315
Aspiration Hazard Category 1 H304
STOT SE Category 3 H336
Carcinogenicity Category 2 H350
Aquatic Chronic Category 2 H411
Serious Eye Damage/ Category 2B H319
Irritation

Labeling Elements

Signal Word (GHS-US): Danger

Hazard Statements (GHS-US): H226 – Flammable liquid and vapor.
H315 – Causes Skin irritation.
H304 – May be fatal if swallowed and enters airways.
H336 – May cause drowsiness or dizziness.
H350 – May cause cancer.
H411 – Toxic to aquatic life with long lasting effects.
H319 – May cause eye damage/irritation.

Precautionary Statements (GHS-US): P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233 - Keep container tightly closed.
P240 – Ground/bond container and receiving equipment.

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 SAFETY DATA SHEET
Diesel Fuel

P241 – Use explosion-proof electrical/ventilating/lighting equipment pursuant

to applicable electrical code.
P242 – Use only non-sparking tools.
P243 – Take precautionary measures against static discharge.
P261 – Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 – Wash skin thoroughly after handling.
P271 – Use only outdoors or in a well-ventilated area.
P273 – Avoid release to the environment.
P280 - Wear protective gloves/protective clothing/eye protection/face
protection.
P303+361+353 - If on skin (or hair): Take off immediately all contaminated
clothing. Rinse with water/shower.
P308+311 - If exposed or concerned: Get medical advice/attention.
P301+310 - If swallowed: Immediately call a poison center/doctor/…
P331 - Do NOT induce vomiting.
P370+P378 – In case of fire use firefighting foam or other appropriate media for
Class B fires to extinguish.
P403+235 - Store in a well-ventilated place. Keep cool.
P405 - Store locked up.
P501 – Dispose of contents/container in accordance with
local/regional/national/international regulation.

Other information:
NFPA 704
Health: 1
Fire: 2
Reactivity: 0

3. COMPOSITION / INFORMATION ON INGREDIENTS

Chemical Composition Information
Mixture
Name Product Identifier (CAS#) % (w/w) Classification
Diesel Fuel 68476-34-6 100 Flam Liq. 3, H226; Skin Irrit. 2, H315;
Aspiration 1, H304; STOT SE 3, H336;
Carc.2. H350; Aquatic chronic 2, H411
Naphthalene 91-20-3 <0.1 Carc. 2, H351; Acute Tox. 4, H302;
Aquatic Acute 1, H400; Aquatic Chronic 1,
H410
Additional Formulation Information:
Diesel Fuel consists of C9+ hydrocarbons resulting from distillation of crude oil.
Low Sulfur Diesel Fuel typically contains less than 500 ppm of sulfur
Ultra Low Sulfur Diesel Fuel typically contains less than 15 ppm of sulfur

4. FIRST AID MEASURES

Route Measures
Inhalation Remove person to fresh air. If person is not breathing, ensure an open airway and provide artificial respiration.
If necessary, provide additional oxygen once breathing is restored if trained to do so. Seek medical attention
immediately.

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 SAFETY DATA SHEET
Diesel Fuel

Route Measures
Ingestion Aspiration Hazard: DO NOT INDUCE VOMITING. Do not give liquids. Obtain immediate medical attention. If
spontaneous vomiting occurs, lean victim forward to reduce the risk of aspiration. Ingestion may cause
gastrointestinal disturbances including irritation, nausea, vomiting, and diarrhea, and central nervous system
(brain) effects similar to alcohol intoxication. In severe cases, tremors, convulsions, loss of consciousness,
coma, respiratory failure, and death.
Eye Contact In case of contact with eyes, immediately flush with clean, low-pressure water for at least 15 min. Hold eyelids
open to ensure adequate flushing. Seek medical attention. In case of contact lenses, remove immediately.
Skin Contact Remove contaminated clothing and shoes. Wash contaminated areas thoroughly with soap and water or
waterless hand cleanser. Obtain medical attention if irritation or redness develops. Thermal burns require
immediate medical attention depending on the severity and of the area of the body burned.

Most Important Symptoms

Contact with eyes and face may cause irritation. Long-term exposure may cause dermatitis (itching, irritation, pain and
swelling).
Inhalation may cause irritation and significant or long term exposure could cause respiratory insufficiency and pulmonary
edema.
Ingestion may cause aspiration, gastrointestinal disturbance, and CNS effects.
Immediate Medical Attention and Special Treatment
For contact with skin or eyes, immediately wash or flush contaminated eyes with gently flowing water. If possible, irrigate each
eye continuously with 0.9% saline (NS). If ingested, rinse mouth. Do NOT induce vomiting, as this may cause chemical
pneumonia (fluid in the lungs).
If inhaled, administer oxygen or establish a patent airway if breathing is labored. Suction if necessary. Monitor closely,
anticipate seizures. Consider orotracheal or nostracheal intubation of airway control if patient is unconscious or is in severe
respiratory distress.
Discard any clothing or shoes contaminated as they may be flammable.

5. FIRE-FIGHTING MEASURES
Extinguishing Media
Foam, carbon dioxide, dry chemical are most suitable
SMALL FIRES: Any extinguisher suitable for Class B fires, dry chemical, C02, water spray, firefighting foam, or Halon. Small fires
in the incipient (beginning) stage may typically be extinguished using handheld portable fire extinguishers and other firefighting
equipment.
LARGE FIRES: Foam, carbon dioxide, dry chemical. Water may be ineffective for fighting the fire, but may be used to cool fire-
exposed containers.
Specific Hazards / Products of Combustion
Moderate fire hazard when exposed to heat or flame with a very low flash point. Product is flammable and easily ignited when
exposed to heat, spark, open flame or other source of ignition. Flowing product may be ignited by self-generated static
electricity. When mixed with air and exposed to an ignition source, flammable vapors can burn in the open or explode in
confined spaces. Being heavier than air, vapors may travel long distances to an ignition source and flash back. Runoff to sewer
may cause fire or explosion hazard.
Combustion may produce smoke, carbon monoxide and other products of incomplete combustion.
Special Precautions and Protective Equipment for Firefighters
Isolate area around container involved in fire. Cool tanks, shells, and containers exposed to fire and excessive heat with water.
For massive fires the use of unmanned hose holders or monitor nozzles may be advantageous to further minimize personnel
exposure. Major fires may require withdrawal, allowing the tank to burn. Large storage tank fires typically require specially
trained personnel and equipment to extinguish the fire, often including the need for properly applied firefighting foam.

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 SAFETY DATA SHEET
Diesel Fuel

Fighting Equipment/Instructions
Firefighting activities that may result in potential exposure to high heat, smoke or toxic by-products of combustion should
require NIOSH- approved pressure-demand self-contained breathing apparatus with full face piece and protective clothing.

Refer to Section 9 for fire properties of this chemical including flash point, auto ignition temperature, and explosive limits.

6. ACCIDENTAL RELEASE MEASURES

ACTIVATE FACILITY SPCC, SPILL CONTINGENCY or EMERGENCY PLAN.
Personal Precautions
Due to high vapor density, flammable / toxic vapors may be present in low lying areas, dikes, pits, drains, or trenches. Vapors
may accumulate in low lying areas and reach ignitable concentrations. Ventilate the area. Use of non-sparking tools and
intrinsically safe equipment is recommended. Potential for flammable atmosphere should be monitored using a combustible
gas indicator positioned downwind of the spill area. Refer to Sections 2 and 7 for further hazard warnings and handling
instructions.
Use appropriate personal protective equipment to prevent eye/skin contact and absorption. Use NIOSH approved respiratory
protection, if warranted, to prevent exposures above permissible limits. Refer to Section 8. Contaminated clothing should not
be near sources of ignition.
Emergency Measures
As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. Consider
wind direction. Secure all ignition sources (flame, spark, hot work, hot metal, etc.) from area. Evaluate the direction of
product travel, diking sewers, etc. to confirm spill areas. Do not touch or walk-through spilled material. For large spills, isolate
initial action distance downwind 1,000 ft. (300 m).
Environmental Precautions
Stop the spill to prevent environmental release if it can be done safely. Product is toxic to aquatic life. Take action to isolate
environmental receptors including drains, storm sewers and natural water bodies. Keep on impervious surface if at all possible.
Use water sparingly to prevent product from spreading. Foam and absorbents may be used to reduce / prevent airborne
release.
Spills may infiltrate subsurface soil and groundwater; professional assistance may be necessary to determine the extent of
subsurface impact.
Follow federal, state or local requirements for reporting environmental release where necessary. Refer to Section 15 for
further information.
Containment and Clean-Up Methods
Carefully contain and stop the source of the spill, if safe to do so. Protect bodies of water by diking absorbents, or absorbent
boom, if possible. Do not flush down sewer or drainage systems, unless system is designed and permitted to handle such
material. The use of firefighting foam may be useful in certain situations to reduce vapors. The proper use of water spray may
effectively disperse product vapors or the liquid itself, preventing contact with ignition sources or areas/equipment that require
protection.
Take up with dry earth, sand or other non-combustible, inert oil absorbing materials. Carefully shovel, scoop or sweep up into a
waste container with clean, non-sparking tools for reclamation or disposal. Response and cleanup crews must be properly
trained and must utilize proper protective equipment. Refer to Section 8 for appropriate protective equipment.

7. HANDLING AND STORAGE

USE ONLY AS A FUEL.
DO NOT SIPHON BY MOUTH.
Handling Precautions
Handle as a flammable liquid. Keep away from heat, sparks, and open flame. No smoking. Electrical equipment should be
approved for classified area. Bond and ground containers during product transfer pursuant to NFPA 70 and API RP 2003 to
reduce the possibility of static-initiated fire or explosion. Follow precautions to prevent static initiated fire.
Use good personal hygiene practices. Use only with protective equipment specified in Section 8. Avoid repeated and/or
prolonged skin exposure. Use only outdoors or in well ventilated areas. Wash hands before eating, drinking, smoking, or using
toilet facilities. Do not use as a cleaning solvent on the skin. Do not use solvents or harsh abrasive skin cleaners for washing this

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 SAFETY DATA SHEET
Diesel Fuel

product from exposed skin areas. Waterless hand cleaners are effective. Promptly remove contaminated clothing and launder
before reuse. Use care when laundering to prevent the formation of flammable vapors which could ignite via washer or dryer.
Consider the need to discard contaminated leather shoes and gloves. Emergency eye wash capability should be available in the
near proximity to operations presenting a potential splash exposure.
Special slow load procedures for "switch loading" must be followed to avoid the static ignition hazard that can exist when
higher flash point material (such as fuel oil) is loaded into tanks previously containing low flash point products (such as this
product) - see API RP 2003, "Protection Against Ignitions Arising Out Of Static, Lightning and Stray Currents."
Storage
Large quantities of diesel fuel are stored in tanks or portable containers at an ambient storage temperature. Separate from
incompatible chemicals (Refer to Section 10) by distance or secondary containment. Keep away from flame, sparks, excessive
temperatures and open flame. Use approved vented containers that are clearly labeled. Label all secondary containers that
this material is transferred into with the chemical name and associated hazard(s). Empty product containers or vessels may
contain flammable vapors. Do not pressurize, cut, heat, weld or expose such containers to sources of ignition.
Storage tanks should have a venting system. If stored in small containers, the area should be well ventilated, away from
ignition sources and protected from potential damage or vehicular traffic. Post “No Smoking” signs in product storage areas.
This storage area should comply with NFPA 30 “Flammable and Combustible Liquid Code” or applicable building code. The
cleaning of tanks previously containing this product should follow API Recommended Practice (RP) 2013 “Cleaning Mobile Tanks
in Flammable and Combustible Liquid Service” and API RP 2015 “Safe Entry and Cleaning of Petroleum Storage Tanks”.
Incompatibles
Keep away from strong oxidizers, ignition sources and heat.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Occupational Exposure Limits
Component CAS # List Value
Diesel Fuel 68476-34-6 ACGIH TLV-TWA 100 mg/m3*

Naphthalene 91-20-3 ACGIH TLV-TWA 10 ppm

OSHA PEL 10 ppm
ACGIH STEL 15 ppm
*Critical effects; Skin; A3; CNS impairment.

Engineering Controls
Use adequate ventilation to keep vapor concentrations of this product below occupational exposure and flammability limits,
particularly in confined spaces. Intrinsically safe equipment and non-sparking tools shall be used in circumstances where
concentrations may exceed lower flammable limits. Grounding and bonding shall be used to prevent accumulation and
discharge of static electricity. Emergency shower and eyewash should be provided in proximity to handling areas in the event of
exposure to decontaminate.
Personal Protective Equipment
Exposure Equipment
Eye / Face Wear appropriate chemical protective glasses or goggles or face shields to prevent skin and eye contact
especially caused from splashing.
Skin Wear appropriate personal protective clothing to prevent skin contact. Gloves constructed of nitrile,
neoprene or PVC are recommended when handling this material. Chemical protective clothing such as of E.I.
DuPont TyChem®, Saranex® or equivalent recommended based on degree of exposure. Note: The resistance
of specific material may vary from product to product as well as with degree of exposure.

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 SAFETY DATA SHEET
Diesel Fuel

Exposure Equipment
Respiratory A NIOSH/MSHA-approved air-purifying respirator with organic vapor cartridges or canister may be
permissible under certain circumstances where airborne concentrations are or may be expected to exceed
exposure limits or for odor or irritation. Protection provided by air-purifying respirators is limited. Refer to
OSHA 29 CFR 1910.134, ANSI Z88.2-1992, NIOSH Respirator Decision Logic, and the manufacturer for
additional guidance on respiratory protection selection and limitations.
Use a positive pressure, air-supplied respirator if there is a potential for uncontrolled release, exposure levels
are not known, in oxygen-deficient atmospheres, or any other circumstance where an air-purifying respirator
may not provide adequate protection.
Thermal Product is stored at ambient temperature. No thermal protection is required except for emergency
operations involving actual or potential for fire. Use adequate ventilation to keep vapor concentrations of
this product below occupational exposure and flammability limits, particularly in confined spaces.

9. PHYSICAL AND CHEMICAL PROPERTIES

Property Value
Appearance Clear or straw-colored liquid. May be dyed red for distribution.
Odor Mild characteristic petroleum distillate odor.
Odor Threshold <1 ppm
pH Not available
Melting Point -22 to -0.4 ˚F (-30 to -18 ˚C)
Boiling Point Range 320 to 690 ˚F (160 to 366 ˚C)
Flash Point > 125.6 ˚F (52 ˚C) PMCC
Evaporation Rate Slow, varies with conditions
Flammability Flammable liquid (OSHA defined)
Flammable Limits 0.6 % - 6.5%
Vapor Pressure 0.009 psia @ 70 ˚F
Vapor Density >1 (air=1)
Specific Gravity 0.83-0.86 @ 60 ˚F (16 ˚C) (water=1)
Solubility Insoluble in water; miscible with other petroleum solvents.
Partition Coefficient (N- Log Kow range of 3.3 to >.6.0
octanol/water)

Autoignition Temperature 494 ˚F (257 ˚C)

Decomposition Temperature When heated it emits acrid smoke and irritating vapors.
Viscosity <3 cSt
Percent Volatiles 100

10. STABILITY AND REACTIVITY

Stability
This is a stable material that is flammable liquid (OSHA/GHS hazard category 3). Stable during transport.
Reactivity
Material is not self-reacting. Flammable concentrations may be present in air. Compound can react with oxidizing materials.

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 SAFETY DATA SHEET
Diesel Fuel

Possibility of Hazardous Reactions

Hazardous polymerization will not occur.
Incompatibility
Keep away from strong oxidizers such as nitric and sulfuric acids.
Conditions to Avoid
Avoid high temperatures, open flames, sparks, static electricity, welding, smoking and other ignition sources.
Hazardous Decomposition Products
Carbon monoxide, carbon dioxide and non-combusted hydrocarbons (smoke).

11. TOXICOLOGICAL INFORMATION

Acute Toxicity:
Acute Toxicity (Inhalation LC50)
Diesel Fuel (68476-34-6)
LC50 Inhalation Rat >6 mg/l/4h

Acute Toxicity (Dermal LD50)

Diesel Fuel (68476-34-6)
LD50 Dermal Rabbit >5000 mg/kg

Acute Toxicity (Oral LD50)

Diesel Fuel (68476-34-6)
LD50 Oral Rabbit >5000 mg/kg
Skin Corrosion/Irritation: Prolonged and repeated contact may cause skin irritation leading to dermatitis. Liquid may be
absorbed through the skin in toxic amounts if large areas of skin are exposed repeatedly.
Serious Eye Damage/Irritation: Causes serious eye irritation.
Respiratory or Skin Sensitization: Not classified
Germ Cell Mutagenicity: Not classified
Teratogenicity: Not available
Carcinogenicity: OSHA: NO, IARC: Group 3, NTP: NO, ACGIH: NOIC:A3, NIOSH: NO
IARC: Group 3 – Not classifiable as to their carcinogenicity to humans ACGIH: A3 – Confirmed animal carcinogen with unknown
relevance to humans
Studies have shown that similar products produce skin tumors in laboratory animals following repeated applications without
washing or removal. The significance of this finding to human exposure has not been determined. Other studies with active skin
carcinogens have shown that washing the animal’s skin with soap and water between applications reduced tumor formation.
IARC classifies whole diesel fuel exhaust particulates (byproduct of combustion of this material) carcinogenic to humans (Group
1) and NIOSH regards diesel fuel exhaust particulate as a potential occupational carcinogen.
Reproductive Toxicity: Not classified
Specific Target Organ Toxicity (Repeated Exposure): Not classified
Specific Target Organ Toxicity (Single Exposure): Inhalation exposure may cause drowsiness or dizziness by inhalation exposure.
Aspiration Hazard: The major health threat of ingestion occurs from the danger of aspiration (breathing) of liquid drops into the
lungs, particularly from vomiting. Aspiration may result in chemical pneumonia (fluid in the lungs), severe lung damage,
respiratory failure and even death.
Potential Health Effects: Vapor irritating to skin, eyes, nose, and throat. Ingestion may cause gastrointestinal disturbances,
including irritation, nausea, vomiting and diarrhea, and central nervous system (brain) effects similar to alcohol intoxication. In
severe cases, tremors, convulsions, loss of consciousness, coma, respiratory arrest, and death may occur.
WARNING: The burning of any hydrocarbon as a fuel in an area without adequate ventilation may result in hazardous levels of

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 SAFETY DATA SHEET
Diesel Fuel

combustion products, including carbon monoxide, and inadequate oxygen levels, which may cause unconsciousness,
suffocation, and death.

12. ECOLOGICAL INFORMATION

Toxicity:
This material is expected to be toxic to aquatic organisms and may cause long-term adverse effects in the aquatic environment.
Data for Component: Diesel Fuel (68476-34-6)
Material is toxic to aquatic organisms based on an acute basis (LC50/EC50 >1 but < 10 mg/L in the most sensitive species
tested).
Material is a long-term aquatic hazard based on a chronic basis (LC50/EC50 >1 but < 10 mg/L in the most sensitive species
tested).
Persistence and Degradation: This material is not expected to be readily biodegradable.
Bioaccumulative Potential: Not available
Mobility in Soil: Not available
Other Adverse Effects: None known
Other Information: Avoid release to the environment.

13. DISPOSAL CONSIDERATIONS

Consult federal, state and local waste regulations to determine appropriate disposal options. May be considered a hazardous
waste if disposed. Direct solid waste (landfill) or incineration at a solid waste facility is not permissible. Do not discharge to
sanitary or storm sewer. Personnel handling waste containers should follow precautions provided in this document.
Shipping containers must be DOT authorized packages. Follow licensure and regulations for transport of hazardous material
and hazardous waste as applicable.

14. TRANSPORT INFORMATION

US DOT
UN Identification Number NA 1993
Proper Shipping Name Diesel fuel
Hazard Class and Packing Group 3, PGIII
Shipping Label Flammable liquid
Placard / Bulk Package Flammable liquid, 1993
Emergency Response Guidebook Guide Number 128
This product may be re-classified as a “Combustible Liquid” meeting the definition in 49 CFR 173.120 unless transported
by vessel or aircraft.
Specific placard requirements must be met for shipments of this product as a Combustible Liquid by rail (See 49 CFR
172.332).
Non-bulk packages (<= 119 gal) of Combustible Liquids in package sizes less than the product reportable quantity are not
regulated as hazardous materials if the material does not meet any other hazard class.

IATA Information
UN Identification Number UN 1202
Proper Shipping Name Diesel fuel
Hazard Class and Packing Group 3, PGIII
ICAO Label 3
Packing Instructions Cargo 310
Max Quantity Per Package Cargo 220L
Packing Instructions Passenger 309Y
Max Quantity per Package Passenger 60L

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 SAFETY DATA SHEET
Diesel Fuel

ICAO
UN Identification Number UN 1202
Shipping Name / Description Diesel fuel
Hazard Class and Packing Group 3, PG III
IMDG Label 3
IMDG
UN Identification Number UN 1202
Shipping Name / Description Diesel fuel
Hazard Class and Packing Group 3, PGIII
IMDG Label 3
EmS Number F-E-S-E
Marine Pollutant Yes

15. REGULATORY INFORMATION

U.S. Federal, State, and Local Regulatory Information
Any spill or uncontrolled release of this product, including any substantial threat of release, may be subject to federal, state
and/or local reporting requirements. This product and/or its constituents may also be subject to other federal, state, or local
regulations; consult those regulations applicable to your facility/operation.
OSHA Hazard Communication Standard
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.

Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning And Community Right-to-Know Act of
1986) Sections 311 and 312
Immediate (Acute) Health Hazard Yes
Delayed (Chronic) Health Hazard Yes
Fire Hazard Yes
Reactive Hazard No
Sudden Release of Pressure Hazard No

Clean Water Act (Oil Spills)

Any spill or release of this product to “navigable waters” (Essentially any surface water, including certain wetlands) or adjoining
shorelines sufficient to cause a visible sheen or deposit of a sludge or emulsion must be reported immediately to the National
Response Center (1-800-424-8802) or, if not practical, the U.S. Coast Guard with follow up to the National Response Center, as
required by U.S. Federal Law. Also contact appropriate state and local regulatory agencies as required.
CERCLA Section 103 and SARA Section 304 (Release to the Environment)
The CERCLA definition of hazardous substances contains a “petroleum exclusion” clause which exempts this material. This
product does not contain any chemicals subject to the reporting requirements of CERCLA Section 103 or SARA 304.

SARA Section 313- Supplier Notification

This product does not contain any chemicals subject to the reporting requirements of Section 313 of the Emergency Planning
and Community Right-To-Know Act (EPCRA) of 1986 and of 40 CFR 372.
EPA Notification (Oil Spills)
If the there is a discharge of more than 1,000-gallons of oil into or upon navigable waters of the United States, or if it is the
second spill event of 42 gallons or more of oil into water within a twelve (12) month period, a written report must be submitted
to the Regional Administrator of the EPA within sixty days of the event.
Pennsylvania Right to Know Hazardous Substance list:
The following product components are cited in the Pennsylvania Special Hazardous Substance List, and are present at levels
which require reporting.
Component CAS Amount
Diesel Fuel 68476-34-6 100%

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Diesel Fuel

New Jersey Right to Know Hazardous Substance list:

The following product components are cited in the New Jersey Right to Know Hazardous Substance List, and are present at
levels which require reporting.
Component CAS Amount
Diesel Fuel 68476-34-6 100%
California Proposition 65 WARNING: This product contains chemicals known to the State of California to cause
Cancer or Reproductive Toxicity.
Component CAS Amount
Naphthalene 91-20-3 <0.1%

U.S. Toxic Substances Control Act

All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory requirements under 40 CFR
720.30.

CEPA - Domestic Substances List (DSL)

All substances contained in this product are listed on the Canadian Domestic Substances List (DSL) or are not required to be
listed.

Canadian Regulatory Information (WHMIS)

Class B3 – Combustible Liquid
Class D2A – Materials causing other toxic effects. (Very Toxic)

16. OTHER INFORMATION

Version 5
Issue Date June 26, 2019
Prior Issue Date May 20, 2016

Description of Revisions
Update viscosity information in Section 9. Update transportation information in Section 14 to clarify US DOT re-classification
option as a Combustible Liquid.

Abbreviations
mL Milliliter
˚F Degrees Fahrenheit (temperature) mm2 Square millimeters
< Less than mmHg Millimeters of mercury (pressure)
= Equal to N/A Not applicable
> Greater than N/D Not determined
AP Approximately ppm Parts per million
C Centigrade (temperature) sec Second
kg Kilogram ug Micrograms
L Liter
mg Milligrams

Acronyms
ACGIH American Conference of Governmental CERCLA Comprehensive Emergency Response,
Industrial Hygienists Compensation, and Liability Act
AIHA American Industrial Hygiene Association DOT U.S. Department of Transportation
AL Action Level EC50 Ecological concentration 50%
ANSI American National Standards Institute EPA U.S. Environmental Protection Agency
API American Petroleum Institute ERPG Emergency Response Planning Guideline
CAS Chemical Abstract Service GHS Global Harmonized System

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Diesel Fuel

HMIS Hazardous Materials Information System REL Recommended Exposure Limit (NIOSH)
IARC International Agency for Research On Cancer RVP Reid Vapor Pressure
IATA International Air Transport Association SARA Superfund Amendments and
IMDG International Maritime Dangerous Goods SCBA Self Contained Breathing Apparatus
Koc Soil Organic Carbon SPCC Spill Prevention, Control, and
LC50 Lethal concentration 50% Countermeasures
LD50 Lethal dose 50% STEL Short Term Exposure Limit (generally 15
MSHA Mine Safety and Health Administration minutes)
NFPA National Fire Protection Association TLV Threshold Limit Value (ACGIH)
NIOSH National Institute of Occupational Safety and TSCA Toxic Substances Control Act
Health TWA Time Weighted Average (8 hr.)
NOIC Notice of Intended Change UN United Nations
NTP National Toxicology Program UNECE United Nations Economic Commission for
OPA Oil Pollution Act of 1990 Europe
OSHA U.S. Occupational Safety & Health WEEL Workplace Environmental Exposure Level
Administration (AIHA)
PEL Permissible Exposure Limit (OSHA) WHMIS Canadian Workplace Hazardous Materials
RCRA Resource Conservation and Recovery Act Information System
Reauthorization Act of 1986 Title III

Disclaimer of Expressed and Implied Warranties

Information presented herein has been compiled from sources considered to be dependable, and is accurate and reliable to the
best of our knowledge and belief, but is not guaranteed to be so. Since conditions of use are beyond our control, we make no
warranties, expressed or implied, except those that may be contained in our written contract of sale or acknowledgment.
Vendor assumes no responsibility for injury to vendee or third persons proximately caused by the material if reasonable safety
procedures are not adhered to as stipulated in the data sheet. Additionally, vendor assumes no responsibility for injury to
vendee or third persons proximately caused by abnormal use of the material, even if reasonable safety procedures are
followed. Furthermore, vendee assumes the risk in their use of the material.

** End of Safety Data Sheet **

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 SAFETY DATA SHEET

1. Identification
Product identifier Hercules Blue Block
Other means of identification
Product code 7385E
Synonyms Part Numbers: 15703, 15707, 15711, 15716
Recommended use Pipe thread sealant.
Recommended restrictions None known.
Manufacturer/Importer/Supplier/Distributor information
Company Name HCC Holdings, Inc. an Oatey Affiliate
Address 4700 West 160th Street
Cleveland, OH 44135
Telephone 216-267-7100
E-mail [email protected]
Transport Emergency Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887)
Emergency First Aid 1-877-740-5015
Contact person MSDS Coordinator

2. Hazard(s) identification
Physical hazards Flammable liquids Category 4

Health hazards Serious eye damage/eye irritation Category 2A

Sensitization, skin Category 1
Environmental hazards Hazardous to the aquatic environment, acute Not applicable
hazard
Hazardous to the aquatic environment, Not applicable
long-term hazard
OSHA defined hazards Not classified.

Label elements

Signal word Warning

Hazard statement Combustible liquid. May cause an allergic skin reaction. Causes serious eye irritation.
Precautionary statement
Prevention Keep away from flames and hot surfaces-No smoking. Avoid breathing mist or vapor. Wash
thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace.
Wear protective gloves/eye protection/face protection.
Response If on skin: Wash with plenty of water. If in eyes: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation or rash
occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Wash
contaminated clothing before reuse. In case of fire: Use appropriate media to extinguish.
Storage Store in a well-ventilated place. Keep cool.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis.
classified (HNOC) Static accumulating flammable liquid can become electrostatically charged even in bonded and
grounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion.

3. Composition/information on ingredients
Mixtures

Hercules Blue Block SDS US

924569 Version #: 01 Revision date: - Issue date: 05-February-2015 1/9
 Chemical name CAS number %
Rosin 8050-09-7 15-25

Castor Oil 68187-84-8 10-20

Isopropyl alcohol 67-63-0 10-20

Talc 14807-96-6 10-15

Magnesium carbonate 546-93-0 5-15

Mica 12001-26-2 5-15

Titanium dioxide 13463-67-7 5-15

Silica, amorphous, fumed 112945-52-5 1-5

Crystalline silica (Quartz) 14808-60-7 <0.6

Other components below reportable levels 1.99
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.

4. First-aid measures
Inhalation Move to fresh air.
Skin contact Remove contaminated clothing immediately and wash skin with soap and water. In case of
eczema or other skin disorders: Seek medical attention and take along these instructions.
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Ingestion Get medical attention if symptoms occur.
Most important Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred
symptoms/effects, acute and vision. Irritation of nose and throat. May cause an allergic skin reaction. Dermatitis. Rash.
delayed
Indication of immediate Provide general supportive measures and treat symptomatically. Keep victim under observation.
medical attention and special Symptoms may be delayed.
treatment needed
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves. Wash contaminated clothing before reuse.

5. Fire-fighting measures
Suitable extinguishing media Alcohol resistant foam. Water fog. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide,
sand or earth may be used for small fires only.
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from The product is combustible, and heating may generate vapors which may form explosive vapor/air
the chemical mixtures. This product is a poor conductor of electricity and can become electrostatically charged.
If sufficient charge is accumulated, ignition of flammable mixtures can occur. To reduce potential
for static discharge, use proper bonding and grounding procedures. This liquid may accumulate
static electricity when filling properly grounded containers. Static electricity accumulation may be
significantly increased by the presence of small quantities of water or other contaminants. Material
will float and may ignite on surface of water. During fire, gases hazardous to health may be
formed.
Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
and precautions for firefighters
Fire fighting In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do
equipment/instructions so without risk.
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards Combustible liquid.

Hercules Blue Block SDS US

924569 Version #: 01 Revision date: - Issue date: 05-February-2015 2/9
6. Accidental release measures
Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Eliminate all
protective equipment and ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate
emergency procedures protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Do not touch
damaged containers or spilled material unless wearing appropriate protective clothing. Ensure
adequate ventilation. Use appropriate containment to avoid environmental contamination. Transfer
by mechanical means such as vacuum truck to a salvage tank or other suitable container for
recovery or safe disposal. Local authorities should be advised if significant spillages cannot be
contained. For personal protection, see section 8 of the SDS.
Methods and materials for Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep
containment and cleaning up combustibles (wood, paper, oil, etc.) away from spilled material.

Large Spills: Stop the flow of material, if this is without risk. Use water spray to reduce vapors or
divert vapor cloud drift. Dike the spilled material, where this is possible. Cover with plastic sheet to
prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the
product and place into a container for later disposal. Following product recovery, flush area with
water.

Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers
for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Environmental precautions Avoid discharge into drains, water courses or onto the ground. Use appropriate containment to
avoid environmental contamination.

7. Handling and storage

Precautions for safe handling Keep away from open flames, hot surfaces and sources of ignition. When using do not smoke.
Minimize fire risks from flammable and combustible materials (including combustible dust and
static accumulating liquids) or dangerous reactions with incompatible materials. Handling
operations that can promote accumulation of static charges include but are not limited to: mixing,
filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank and container
filling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations. Avoid breathing
mist or vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Provide
adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial
hygiene practices.

For additional information on equipment bonding and grounding, refer to the Canadian Electrical
Code in Canada, (CSA C22.1), or the American Petroleum Institute (API) Recommended Practice
2003, "Protection Against Ignitions Arising out of Static, Lightning, and Stray Currents" or National
Fire Protection Association (NFPA) 77, "Recommended Practice on Static Electricity" or National
Fire Protection Association (NFPA) 70, "National Electrical Code".

Conditions for safe storage, Keep away from heat, sparks and open flame. Eliminate sources of ignition. Avoid spark
including any incompatibilities promoters. Ground/bond container and equipment. These alone may be insufficient to remove
static electricity. Store in a cool, dry place out of direct sunlight. Store in original tightly closed
container. Store in a well-ventilated place. Keep in an area equipped with sprinklers. Store away
from incompatible materials (see Section 10 of the SDS).

8. Exposure controls/personal protection

Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

Components Type Value Form

Isopropyl alcohol (CAS PEL 980 mg/m3
67-63-0)
400 ppm
Magnesium carbonate PEL 5 mg/m3 Respirable fraction.
(CAS 546-93-0)
15 mg/m3 Total dust.
Titanium dioxide (CAS PEL 15 mg/m3 Total dust.
13463-67-7)

Hercules Blue Block SDS US

924569 Version #: 01 Revision date: - Issue date: 05-February-2015 3/9
 US. OSHA Table Z-3 (29 CFR 1910.1000)

Components Type Value Form

Crystalline silica (Quartz) TWA 0.3 mg/m3 Total dust.
(CAS 14808-60-7)
0.1 mg/m3 Respirable.
Mica (CAS 12001-26-2) TWA 20 mppcf
Silica, amorphous, fumed TWA 0.8 mg/m3
(CAS 112945-52-5)
20 mppcf
Talc (CAS 14807-96-6) TWA 0.3 mg/m3 Total dust.
0.1 mg/m3 Respirable.
20 mppcf
2.4 mppcf Respirable.
US. ACGIH Threshold Limit Values

Components Type Value Form

Crystalline silica (Quartz) TWA 0.025 mg/m3 Respirable fraction.
(CAS 14808-60-7)
Isopropyl alcohol (CAS STEL 400 ppm
67-63-0)
TWA 200 ppm
Mica (CAS 12001-26-2) TWA 3 mg/m3 Respirable fraction.
Talc (CAS 14807-96-6) TWA 2 mg/m3 Respirable fraction.
Titanium dioxide (CAS TWA 10 mg/m3
13463-67-7)
US. NIOSH: Pocket Guide to Chemical Hazards

Components Type Value Form

Crystalline silica (Quartz) TWA 0.05 mg/m3 Respirable dust.
(CAS 14808-60-7)
Isopropyl alcohol (CAS STEL 1225 mg/m3
67-63-0)
500 ppm
TWA 980 mg/m3
400 ppm
Magnesium carbonate TWA 5 mg/m3 Respirable.
(CAS 546-93-0)
10 mg/m3 Total
Mica (CAS 12001-26-2) TWA 3 mg/m3 Respirable.
Rosin (CAS 8050-09-7) TWA 0.1 mg/m3
Silica, amorphous, fumed TWA 6 mg/m3
(CAS 112945-52-5)
Talc (CAS 14807-96-6) TWA 2 mg/m3 Respirable.
Biological limit values
ACGIH Biological Exposure Indices

Components Value Determinant Specimen Sampling Time

Isopropyl alcohol (CAS 40 mg/l Acetone Urine *
67-63-0)
* - For sampling details, please see the source document.
Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level. Provide
eyewash station.
Individual protection measures, such as personal protective equipment
Eye/face protection Face shield is recommended. Wear safety glasses with side shields (or goggles).

Hercules Blue Block SDS US

924569 Version #: 01 Revision date: - Issue date: 05-February-2015 4/9
 Skin protection
Hand protection Wear appropriate chemical resistant gloves.
Other Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.
Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene When using do not smoke. Contaminated work clothing should not be allowed out of the
considerations workplace.

9. Physical and chemical properties

Appearance
Physical state Liquid.
Form Liquid paste.
Color Blue.
Odor Alcohol.
Odor threshold Not available.
pH Not available.
Melting point/freezing point Not available.
Initial boiling point and boiling Not available.
range
Flash point 170.0 °F (76.7 °C)
Evaporation rate Not available.
Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower Not available.
(%)
Flammability limit - upper Not available.
(%)
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure 33 mm Hg
Vapor density 2.07
Relative density 1.29
Solubility(ies)
Solubility (water) Slightly Soluble
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity 12000 cP
Other information
VOC (Weight %) 183 g/l

10. Stability and reactivity

Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous No dangerous reaction known under conditions of normal use.
reactions
Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the
flash point. Contact with incompatible materials.
Incompatible materials Acids. Strong oxidizing agents. Isocyanates. Chlorine.
Hazardous decomposition No hazardous decomposition products are known.
products
Hercules Blue Block SDS US
924569 Version #: 01 Revision date: - Issue date: 05-February-2015 5/9
11. Toxicological information
Information on likely routes of exposure
Inhalation Prolonged inhalation may be harmful.
Skin contact May cause an allergic skin reaction.
Eye contact Causes serious eye irritation.
Ingestion Expected to be a low ingestion hazard.
Symptoms related to the Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred
physical, chemical and vision. Irritation of nose and throat. May cause an allergic skin reaction. Dermatitis. Rash.
toxicological characteristics
Information on toxicological effects
Acute toxicity
Components Species Test Results
Isopropyl alcohol (CAS 67-63-0)
Acute
Dermal
LD50 Rabbit 12800 mg/kg
Oral
LD50 Rat 4.7 g/kg

* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation Prolonged skin contact may cause temporary irritation.
Serious eye damage/eye Causes serious eye irritation.
irritation
Respiratory or skin sensitization
Respiratory sensitization Not a respiratory sensitizer.
Skin sensitization May cause an allergic skin reaction.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity In 1997, IARC (the International Agency for Research on Cancer) concluded that crystalline silica
inhaled from occupational sources can cause lung cancer in humans. However in making the
overall evaluation, IARC noted that "carcinogenicity was not detected in all industrial
circumstances studied. Carcinogenicity may be dependent on inherent characteristics of the
crystalline silica or on external factors affecting its biological activity or distribution of its
polymorphs." (IARC Monographs on the evaluation of the carcinogenic risks of chemicals to
humans, Silica, silicates dust and organic fibres, 1997, Vol. 68, IARC, Lyon, France.) Risk of
cancer cannot be excluded with prolonged exposure.
IARC Monographs. Overall Evaluation of Carcinogenicity
Crystalline silica (Quartz) (CAS 14808-60-7) 1 Carcinogenic to humans.
Silica, amorphous, fumed (CAS 112945-52-5) 3 Not classifiable as to carcinogenicity to humans.
Titanium dioxide (CAS 13463-67-7) 2B Possibly carcinogenic to humans.
NTP Report on Carcinogens
Crystalline silica (Quartz) (CAS 14808-60-7) Known To Be Human Carcinogen.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity - Not classified.
single exposure
Specific target organ toxicity - Not classified.
repeated exposure
Aspiration hazard Not an aspiration hazard.
Chronic effects Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects.

12. Ecological information

Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.

Hercules Blue Block SDS US

924569 Version #: 01 Revision date: - Issue date: 05-February-2015 6/9
 Components Species Test Results
Isopropyl alcohol (CAS 67-63-0)
Aquatic
Fish LC50 Bluegill (Lepomis macrochirus) > 1400 mg/l, 96 hours
Rosin (CAS 8050-09-7)
Aquatic
Crustacea EC50 Daphnia 4.5 mg/l, 48 Hours

* Estimates for product may be based on additional component data not shown.
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)
Isopropyl alcohol (CAS 67-63-0) 0.05
Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations

Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of
contents/container in accordance with local/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some
products product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.

14. Transport information

DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
Transport in bulk according to Not established.
Annex II of MARPOL 73/78 and
the IBC Code
General information DOT: Not regulated as dangerous goods except when shipped in bulk. This material is not
regulated if in a container of 119 gallon (450 L) capacity or less.

15. Regulatory information

US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Isopropyl alcohol (CAS 67-63-0) LISTED
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - Yes
Pressure Hazard - No
Reactivity Hazard - No
Hercules Blue Block SDS US
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 SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous No
chemical
SARA 313 (TRI reporting)
Chemical name CAS number % by wt.
Isopropyl alcohol 67-63-0 10-20
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
US state regulations
US. Massachusetts RTK - Substance List
Crystalline silica (Quartz) (CAS 14808-60-7)
Isopropyl alcohol (CAS 67-63-0)
Magnesium carbonate (CAS 546-93-0)
Mica (CAS 12001-26-2)
Silica, amorphous, fumed (CAS 112945-52-5)
Talc (CAS 14807-96-6)
Titanium dioxide (CAS 13463-67-7)
US. New Jersey Worker and Community Right-to-Know Act
Crystalline silica (Quartz) (CAS 14808-60-7)
Isopropyl alcohol (CAS 67-63-0)
Magnesium carbonate (CAS 546-93-0)
Mica (CAS 12001-26-2)
Talc (CAS 14807-96-6)
Titanium dioxide (CAS 13463-67-7)
US. Pennsylvania Worker and Community Right-to-Know Law
Crystalline silica (Quartz) (CAS 14808-60-7)
Isopropyl alcohol (CAS 67-63-0)
Mica (CAS 12001-26-2)
Rosin (CAS 8050-09-7)
Silica, amorphous, fumed (CAS 112945-52-5)
Talc (CAS 14807-96-6)
Titanium dioxide (CAS 13463-67-7)
US. Rhode Island RTK
Isopropyl alcohol (CAS 67-63-0)
US. California Proposition 65
WARNING: This product contains a chemical known to the State of California to cause cancer.
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Crystalline silica (Quartz) (CAS 14808-60-7)
Titanium dioxide (CAS 13463-67-7)
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Canada Domestic Substances List (DSL) Yes
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

16. Other information, including date of preparation or last revision

Issue date 05-February-2015
Revision date -
Version # 01

Hercules Blue Block SDS US

924569 Version #: 01 Revision date: - Issue date: 05-February-2015 8/9
HMIS® ratings Health: 2
Flammability: 2
Physical hazard: 0
NFPA ratings
2
2 0

Disclaimer HCC Holdings Inc. an Oatey Affiliate cannot anticipate all conditions under which this information
and its product, or the products of other manufacturers in combination with its product, may be
used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of
the product, and to assume liability for loss, injury, damage or expense due to improper use. The
information in the sheet was written based on the best knowledge and experience currently
available.

Hercules Blue Block SDS US

924569 Version #: 01 Revision date: - Issue date: 05-February-2015 9/9
 SAFETY DATA SHEET

1. Identification
Product identifier Hercules Duck Butter
Other means of identification
Product code 7334E
Synonyms Part Numbers: 40501, 40506
Recommended use Lubricant for O-rings
Recommended restrictions Do not use on applications where product will be submerged under water.
Manufacturer/Importer/Supplier/Distributor information
Company Name HCC Holdings, Inc. an Oatey Affiliate
Address 4700 West 160th Street
Cleveland, OH 44135
Telephone 216-267-7100
E-mail [email protected]
Transport Emergency Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887)
Emergency First Aid 1-877-740-5015
Contact person MSDS Coordinator
2. Hazard(s) identification
Physical hazards Not Classified.
Health hazards Skin Irritant Cat 3
Eye Irritation Cat 2B
OSHA defined hazards This chemical is considered non-hazardous according to the OSHA Hazard Communication
Standard 2012 (29 CFR 1910.1200)
Label elements
Hazard symbol None.
Signal word Warning
Hazard statement Causes mild skin irritation. Causes eye irritation.
Precautionary statement
Prevention Wash skin thoroughly after handling.
Response If skin irritation occurs: Get medical advice/attention. IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye
irritation persists: Get medical advice/attention.
Storage Not applicable.
Disposal Not applicable.
Hazard(s) not otherwise None.
classified (HNOC)
3. Composition/information on ingredients
Mixtures
The product contains no substances which at their given concentration, are considered to be hazardous to health.
Chemical name CAS number %
Mixed sodium and potassium salts of tall oil (soap) 68606-06-4 15 - 25
4. First-aid measures
Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical
attention if symptoms occur.
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Skin contact Wash off immediately with soap and water. If skin irritation persists, call a physician.
Eye contact Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids.
Check for and remove any contact lenses. Get medical attention if irritation occurs.
Ingestion Do NOT induce vomiting. Drink plenty of water. Rinse mouth. Never give anything by mouth to
an unconscious person. Call a physician or poison control center immediately
Most important Direct contact with eyes may cause temporary irritation. Prolonged or repeated skin contact may
symptoms/effects, acute and cause irritation.
delayed
Indication of immediate medical Immediate medical attention is not required.
attention and special treatment
needed.
General information Note to physician, treat symptomatically.

5. Fire-fighting measures
Suitable extinguishing media Foam, water spray or fog. Dry chemical powder, carbon dioxide, sand or earth may be used for
small fires only.
Unsuitable extinguishing media Do not use water in a jet.
Specific hazards arising from No information available.
the chemical
Special protective equipment Fire-fighters should wear appropriate protective equipment and self-contained breathing
and precautions for firefighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Fire fighting Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a
equipment/instructions fire. No action shall be taken involving any personal risk or without suitable training. Use water
spray to keep fire-exposed containers cool. Fire water contaminated with this material must be
contained and prevented from being discharged to any waterway, sewer or drain.
Specific methods None
General fire hazards None

6. Accidental release measures

Personal precautions, Avoid contact with the skin and the eyes. Evacuate personnel to safe areas. Use
protective equipment and personal protective equipment. Keep people away from and upwind of spill/leak.
emergency procedures
Methods and materials for Dike to collect large liquid spills. Prevent leakage or spillage if safe to do so. Dam up. Soak up
containment and cleaning up with inert absorbent material Place the bulk of any spilled material into properly labeled
containers. Rinse any remaining material to sewage treatment facility. Clean up in accordance
with all applicable regulations.
Environmental precautions Prevent further leakage or spillage if safe to do so. Prevent product from entering
drains. Do not flush into surface water or sanitary sewer system. Prevent entry into
waterways, sewers, basements or confined areas. See Section 12 for additional
Ecological information

7. Handling and storage

Precautions for safe handling Wear personal protective equipment. Avoid contact with skin, eyes and clothing. Do not breathe
vapors or spray mist. Ensure adequate ventilation. Use only in area provided with appropriate
exhaust ventilation. Do not eat, drink or smoke when using this product. Wash thoroughly after
handling. Do not take internally.
Conditions for safe storage, Keep containers tightly closed in a dry, cool and well-ventilated place. Keep in properly labeled
including any incompatibilities containers. Keep out of the reach of children.

8. Exposure controls/personal protection

Occupational exposure limits
US. ACGIH Threshold Limit Values
Components Type Value

Biological limit values Data Not available.

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Appropriate engineering No special ventilation requirements. Good general ventilation should be sufficient to control
controls worker exposure to airborne contaminants. If this product contains ingredients with exposure
limits, use process enclosures, local exhaust ventilation or other engineering controls to keep
worker exposure below any recommended or statutory limits.
Individual protection measures, such as personal protective equipment
Eye/face protection Safety eyewear complying with an approved standard should be used when a risk assessment
indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts.
Skin protection
Hand Chemical-resistant, impervious gloves complying with an approved standard should be worn at
all times when handling chemical products if a risk assessment indicates this is necessary.
Other Appropriate footwear and any additional skin protection measures should be selected based on
the task being performed and the risks involved and should be approved by a specialist before
handling this product.
Respiratory protection Use a properly fitted, particulate filter respirator complying with an approved standard if a risk
assessment indicates this is necessary. Respirator selection must be based on known or
anticipated exposure levels, the hazards of the product and the safe working limits of the
selected respirator.
Thermal hazards None.
General hygiene Wash hands, forearms and face thoroughly after handling chemical products, before eating,
considerations smoking and using the lavatory and at the end of the working period. Appropriate techniques
should be used to remove potentially contaminated clothing. Contaminated work clothing should
not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that
eyewash stations and safety showers are close to the workstation location.
9. Physical and chemical properties
Appearance
Physical state Liquid
Form Paste
Color Off-White
Odor Slight
Odor threshold Not available.
pH 9 (5% Solution)
Melting point/freezing point No data available.
Initial boiling point and boiling Not determined
range
Flash point > 220 °F (> 104°C)
Upper/lower flammability or explosive limits
Flammability limit – lower (%) Not available
Flammability limit – upper (%) Not available
Explosive limit - lower (%) Not available
Explosive limit - upper (%) Not available
Vapor pressure Not applicable
Vapor density Not applicable
Relative density 1.2
Solubility(ies)
Solubility (water) Completely soluble.
Partition coefficient
(n-octanol/water) Not determined.
Auto-ignition temperature Not applicable
Decomposition temperature Not available
Viscosity, kinematic Not determined/
Other information
VOC (Weight %) < 1% by weight, < 12 g/L

10. Stability and reactivity

Reactivity Not reactive under normal conditions
Chemical stability The product is stable.
Possibility of hazardous Under normal conditions of storage and use, hazardous reactions will not occur.
reaction
Conditions to avoid Contact with incompatible materials.

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Incompatible materials Strong Oxidizing Agents.
Hazardous decomposition Carbon oxides.
products
11. Toxicological information
Information on likely routes of exposure
Inhalation Not a likely route
Skin contact May cause mild skin irritation.
Eye contact Causes Eye irritation
Ingestion No known significant effects or critical hazards.
Symptoms related to the Direct contact with eyes may cause temporary irritation. Prolonged or repeated
physical, chemical and contact may dry skin and cause irritation
toxicological characteristics
Information on likely routes of exposure
Acute Toxicity
Components Species Results

Skin corrosion/irritation Prolonged exposure may cause skin irritation.

Serious eye damage/eye Expected to be slightly irritating.
irritation
Respiratory or skin sensitization
Respiratory sensitization Inhalation of vapors or mists may cause irritation to the respiratory system.
Skin sensitization This product is not expected to cause skin irritation.
Germ cell mutagenicity Not considered a mutagenic hazard
Carcinogenicity No component of this product is identified as a probable, possible, or confirmed carcinogen by
IARC, NTP, Monographs, or OSHA.
Reproductive toxicity No known significant effects or critical hazards.
Specific target organ toxicity
Single exposure Not expected to be a hazard.
Repeated exposure Not expected to be a hazard.
Aspiration Hazard Not expected to be a hazard
Chronic effects Not Classified.
Further information None Provided.
12. Ecological information
Ecotoxicity
Product/ingredient name Results Species Exposure

Persistence and degradability Not Available.

Bio accumulative potential Not Available.
Mobility in soil Not determined.
Other adverse effects No known significant effects of critical hazards.

13. Disposal considerations

Disposal instructions The generation of waste should be avoided or minimized wherever possible. Disposal of this
product, solutions and any by-products should at all times comply with the requirements of
environmental protection and waste disposal legislation and any regional local authority
requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal
contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with
the requirements of all authorities with jurisdiction. Waste packaging should be recycled.
Incineration or landfill should only be considered when recycling is not feasible. This material
and its container must be disposed of in a safe way. Empty containers or liners may retain some
product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways,
drains and sewers.
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Local disposal regulations Not Applicable
Hazardous waste code Not Applicable
14. Transportation information
DOT Not Regulated
UN number
UN Proper Shipping Name
Transportation Hazard
classes
Packing group
IATA Not Regulated
UN number
UN Proper Shipping Name
Transportation Hazard
classes
Packing group
IMDG Not Regulated
UN number
UN Proper Shipping Name
Transportation Hazard
classes
Packing group
Environmental hazards
Marine polluntant

15. Regulatory information

U.S. Federal regulations TSCA 12(b) - Chemical export notification: None required.
TSCA 5(a)2 - Final significant new use rules: Not listed
TSCA 5(a)2 - Proposed significant new use rules: Not listed
TSCA 5(e) - Substances consent order: Not listed
US Federal Regulations
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.
SARA 311/312 Hazard Categories
Acute Health Hazard Yes
Chronic Health Hazard No
Fire Hazard No
Sudden Release of Pressure Hazard No
Reactive Hazard No
CWA (Clean Water Act)
This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42): None known
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302): None Known
US state regulations
California Prop 65 This product does not contain a chemical known to the State of California to cause cancer, birth
defects, or other reproductive harm.
International regulations
Country(s) or region Inventory Name On inventory list (yes/no)*

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 Canada DSL/NDSL Yes
United States & Puerto Rico Toxic Substances Control Act (TSCA 8b) Yes

16. Other information, including date of preparation or last revision

Issue Date 12-May-2015
Revision Date -

Version # 01
HMIS Rating Health: 1
Flammability: 1
Physical Hazards: 0
Disclaimer HCC Holdings Inc. an Oatey Affiliate cannot anticipate all conditions under which this information
and its product, or the products of other manufacturers in combination with its product, may be
used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of
the product, and to assume liability for loss, injury, damage or expense due to improper use. The
information in the sheet was written based on the best knowledge and experience currently
available.

Hercules Duck Butter SDS US

SDS #7334E Version #: 01 Revision date:11/16/2018 Issue date: 12-May-2015 Page 6 of 6
 SAFETY DATA SHEET
B54B11

Section 1. Identification
Product name : Industrial Enamel
Black
Product code : B54B11
Other means of : Not available.
identification
Product type : Liquid.
Relevant identified uses of the substance or mixture and uses advised against
Paint or paint related material.

Manufacturer : THE SHERWIN-WILLIAMS COMPANY

101 W. Prospect Avenue
Cleveland, OH 44115

Emergency telephone : US / Canada: (800) 424-9300

number of the company Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year

Product Information : US / Canada: (800) 524-5979

Telephone Number Mexico: Not Available

Regulatory Information : US / Canada: (216) 566-2902

Telephone Number Mexico: Not Available

Transportation Emergency : US / Canada: (800) 424-9300

Telephone Number Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year

Section 2. Hazards identification

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : FLAMMABLE LIQUIDS - Category 3
substance or mixture SKIN SENSITIZATION - Category 1
CARCINOGENICITY - Category 2
TOXIC TO REPRODUCTION - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -
Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1
Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 43.3%
(oral), 43.3% (dermal), 43.3% (inhalation)
GHS label elements
Hazard pictograms :

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Black
Section 2. Hazards identification
Signal word : Danger
Hazard statements : Flammable liquid and vapor.
May be fatal if swallowed and enters airways.
May cause an allergic skin reaction.
May cause respiratory irritation.
May cause drowsiness or dizziness.
Suspected of causing cancer.
Suspected of damaging fertility or the unborn child.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves, protective clothing and eye or face
protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment.
Use non-sparking tools. Take action to prevent static discharges. Use only outdoors or
in a well-ventilated area. Do not breathe vapor. Contaminated work clothing must not
be allowed out of the workplace.
Response : IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove
person to fresh air and keep comfortable for breathing. Call a POISON CENTER or
doctor if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or
doctor. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all
contaminated clothing. Rinse skin with water. Wash contaminated clothing before
reuse. IF ON SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get
medical advice or attention.
Storage : Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep
cool.
Disposal : Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which
elements can cause permanent brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:
This product contains chemicals known to the State of California to cause cancer and
birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY.
Please refer to the SDS for additional information. Keep out of reach of children. Do not
transfer contents to other containers for storage.
Hazards not otherwise : DANGER: Rags, steel wool, other waste soaked with this product, and sanding residue
classified may spontaneously catch fire if improperly discarded. Immediately place rags, steel
wool, other waste soaked with this product, and sanding residue in a sealed, water-filled,
metal container. Dispose of in accordance with local fire regulations.

Section 3. Composition/information on ingredients

Substance/mixture : Mixture
Other means of : Not available.
identification
CAS number/other identifiers
Ingredient name % by weight CAS number
Light Aliphatic Hydrocarbon ≥25 - ≤50 64742-47-8
Calcium Carbonate <10 1317-65-3
Carbon Black ≤3 1333-86-4
Xylene, mixed isomers <1 1330-20-7
Methyl Ethyl Ketoxime <1 96-29-7
Hydrotreated Heavy Petroleum Naphtha ≤0.3 64742-48-9
Zirconium 2-Ethylhexanoate ≤0.3 22464-99-9
Methyl Isobutyl Ketone ≤0.3 108-10-1
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Black
Section 3. Composition/information on ingredients
Ethylbenzene ≤0.3 100-41-4
Med. Aliphatic Hydrocarbon Solvent ≤0.3 64742-88-7
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health and hence require reporting in this section.

Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Skin contact : Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean
shoes thoroughly before reuse.
Ingestion : Get medical attention immediately. Call a poison center or physician. Wash out mouth
with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter
lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.

Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : No known significant effects or critical hazards.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness. May cause respiratory irritation.
Skin contact : May cause an allergic skin reaction.
Ingestion : Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways.
Over-exposure signs/symptoms
Eye contact : No specific data.

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Section 4. First aid measures
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Skin contact : Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Ingestion : Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam.
media
Unsuitable extinguishing : Do not use water jet.
media

Specific hazards arising : Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a
from the chemical fire or if heated, a pressure increase will occur and the container may burst, with the risk
of a subsequent explosion. The vapor/gas is heavier than air and will spread along the
ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
metal oxide/oxides

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Section 5. Fire-fighting measures
Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.

Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Avoid exposure - obtain special instructions before use. Avoid
exposure during pregnancy. Do not handle until all safety precautions have been read
and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist.
Do not swallow. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Do not enter storage areas and confined spaces unless
adequately ventilated. Keep in the original container or an approved alternative made
from a compatible material, kept tightly closed when not in use. Store and use away
from heat, sparks, open flame or any other ignition source. Use explosion-proof
electrical (ventilating, lighting and material handling) equipment. Use only non-sparking
tools. Take precautionary measures against electrostatic discharges. Empty containers
retain product residue and can be hazardous. Do not reuse container.

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Section 7. Handling and storage
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved area.
including any Store in original container protected from direct sunlight in a dry, cool and well-ventilated
incompatibilities area, away from incompatible materials (see Section 10) and food and drink. Store
locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination. See Section 10 for incompatible materials before handling or use.

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits (OSHA United States)
Ingredient name CAS # Exposure limits
Light Aliphatic Hydrocarbon 64742-47-8 ACGIH TLV (United States, 3/2020).
Absorbed through skin.
TWA: 200 mg/m³, (as total hydrocarbon
vapor) 8 hours.
Calcium Carbonate 1317-65-3 OSHA PEL (United States, 5/2018).
TWA: 5 mg/m³ 8 hours. Form: Respirable
fraction
TWA: 15 mg/m³ 8 hours. Form: Total dust
NIOSH REL (United States, 10/2016).
TWA: 5 mg/m³ 10 hours. Form: Respirable
fraction
TWA: 10 mg/m³ 10 hours. Form: Total
Carbon Black 1333-86-4 ACGIH TLV (United States, 3/2020).
TWA: 3 mg/m³ 8 hours. Form: Inhalable
fraction
NIOSH REL (United States, 10/2016).
TWA: 3.5 mg/m³ 10 hours.
TWA: 0.1 mg of PAHs/cm³ 10 hours.
OSHA PEL (United States, 5/2018).
TWA: 3.5 mg/m³ 8 hours.
Xylene, mixed isomers 1330-20-7 ACGIH TLV (United States, 3/2020).
TWA: 100 ppm 8 hours.
TWA: 434 mg/m³ 8 hours.
STEL: 150 ppm 15 minutes.
STEL: 651 mg/m³ 15 minutes.
OSHA PEL (United States, 5/2018).
TWA: 100 ppm 8 hours.
TWA: 435 mg/m³ 8 hours.
Methyl Ethyl Ketoxime 96-29-7 AIHA WEEL (United States, 7/2018). Skin
sensitizer.
TWA: 10 ppm 8 hours.
Hydrotreated Heavy Petroleum Naphtha 64742-48-9 None.
Zirconium 2-Ethylhexanoate 22464-99-9 ACGIH TLV (United States, 3/2020).
TWA: 5 mg/m³, (as Zr) 8 hours.
STEL: 10 mg/m³, (as Zr) 15 minutes.
NIOSH REL (United States, 10/2016).

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Section 8. Exposure controls/personal protection
TWA: 5 mg/m³, (as Zr) 10 hours.
STEL: 10 mg/m³, (as Zr) 15 minutes.
OSHA PEL (United States, 5/2018).
TWA: 5 mg/m³, (as Zr) 8 hours.
Methyl Isobutyl Ketone 108-10-1 ACGIH TLV (United States, 3/2020).
TWA: 20 ppm 8 hours.
STEL: 75 ppm 15 minutes.
NIOSH REL (United States, 10/2016).
TWA: 50 ppm 10 hours.
TWA: 205 mg/m³ 10 hours.
STEL: 75 ppm 15 minutes.
STEL: 300 mg/m³ 15 minutes.
OSHA PEL (United States, 5/2018).
TWA: 100 ppm 8 hours.
TWA: 410 mg/m³ 8 hours.
Ethylbenzene 100-41-4 ACGIH TLV (United States, 3/2020).
TWA: 20 ppm 8 hours.
NIOSH REL (United States, 10/2016).
TWA: 100 ppm 10 hours.
TWA: 435 mg/m³ 10 hours.
STEL: 125 ppm 15 minutes.
STEL: 545 mg/m³ 15 minutes.
OSHA PEL (United States, 5/2018).
TWA: 100 ppm 8 hours.
TWA: 435 mg/m³ 8 hours.
Med. Aliphatic Hydrocarbon Solvent 64742-88-7 OSHA PEL (United States, 5/2018).
TWA: 100 ppm 8 hours.
TWA: 400 mg/m³ 8 hours.
Occupational exposure limits (Canada)
Ingredient name CAS # Exposure limits
Petroleum refining, hydrotreated light distillate 64742-47-8 CA British Columbia Provincial (Canada,
1/2020). Absorbed through skin.
TWA: 200 mg/m³, (as total hydrocarbon
vapour) 8 hours.
CA Alberta Provincial (Canada, 6/2018).
Absorbed through skin.
8 hrs OEL: 200 mg/m³, (as total hydrocarbon
vapour) 8 hours.
CA Ontario Provincial (Canada, 6/2019).
Absorbed through skin.
TWA: 200 mg/m³, (as total hydrocarbon
vapour) 8 hours.
Carbon black 1333-86-4 CA British Columbia Provincial (Canada,
1/2020).
TWA: 3 mg/m³ 8 hours. Form: Inhalable
CA Ontario Provincial (Canada, 6/2019).
TWA: 3 mg/m³ 8 hours. Form: Inhalable
fraction.
CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 3.5 mg/m³ 8 hours.
CA Quebec Provincial (Canada, 7/2019).
TWAEV: 3.5 mg/m³ 8 hours.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 7 mg/m³ 15 minutes.

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Section 8. Exposure controls/personal protection
TWA: 3.5 mg/m³ 8 hours.
Xylene 1330-20-7 CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 100 ppm 8 hours.
15 min OEL: 651 mg/m³ 15 minutes.
15 min OEL: 150 ppm 15 minutes.
8 hrs OEL: 434 mg/m³ 8 hours.
CA British Columbia Provincial (Canada,
1/2020).
TWA: 100 ppm 8 hours.
STEL: 150 ppm 15 minutes.
CA Quebec Provincial (Canada, 7/2019).
TWAEV: 100 ppm 8 hours.
TWAEV: 434 mg/m³ 8 hours.
STEV: 150 ppm 15 minutes.
STEV: 651 mg/m³ 15 minutes.
CA Ontario Provincial (Canada, 6/2019).
STEL: 150 ppm 15 minutes.
TWA: 100 ppm 8 hours.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 150 ppm 15 minutes.
TWA: 100 ppm 8 hours.
Methyl Ethyl Ketoxime 96-29-7 AIHA WEEL (United States, 7/2018). Skin
sensitizer.
TWA: 10 ppm 8 hours.
Zirconium 2-Ethylhexanoate 22464-99-9 CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 5 mg/m³, (as Zr) 8 hours.
15 min OEL: 10 mg/m³, (as Zr) 15 minutes.
CA British Columbia Provincial (Canada,
1/2020).
TWA: 5 mg/m³, (as Zr) 8 hours.
STEL: 10 mg/m³, (as Zr) 15 minutes.
CA Quebec Provincial (Canada, 7/2019).
TWAEV: 5 mg/m³, (as Zr) 8 hours.
STEV: 10 mg/m³, (as Zr) 15 minutes.
CA Ontario Provincial (Canada, 6/2019).
STEL: 10 mg/m³, (as Zr) 15 minutes.
TWA: 5 mg/m³, (as Zr) 8 hours.
Methyl isobutyl ketone 108-10-1 CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 205 mg/m³ 8 hours.
8 hrs OEL: 50 ppm 8 hours.
15 min OEL: 75 ppm 15 minutes.
15 min OEL: 307 mg/m³ 15 minutes.
CA British Columbia Provincial (Canada,
1/2020).
TWA: 20 ppm 8 hours.
STEL: 75 ppm 15 minutes.
CA Ontario Provincial (Canada, 6/2019).
TWA: 20 ppm 8 hours.
STEL: 75 ppm 15 minutes.
CA Quebec Provincial (Canada, 7/2019).
TWAEV: 50 ppm 8 hours.
TWAEV: 205 mg/m³ 8 hours.
STEV: 75 ppm 15 minutes.
STEV: 307 mg/m³ 15 minutes.
CA Saskatchewan Provincial (Canada,
7/2013).

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Section 8. Exposure controls/personal protection
STEL: 75 ppm 15 minutes.
TWA: 50 ppm 8 hours.
Ethylbenzene 100-41-4 CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 100 ppm 8 hours.
8 hrs OEL: 434 mg/m³ 8 hours.
15 min OEL: 543 mg/m³ 15 minutes.
15 min OEL: 125 ppm 15 minutes.
CA British Columbia Provincial (Canada,
1/2020).
TWA: 20 ppm 8 hours.
CA Ontario Provincial (Canada, 6/2019).
TWA: 20 ppm 8 hours.
CA Quebec Provincial (Canada, 7/2019).
TWAEV: 100 ppm 8 hours.
TWAEV: 434 mg/m³ 8 hours.
STEV: 125 ppm 15 minutes.
STEV: 543 mg/m³ 15 minutes.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 125 ppm 15 minutes.
TWA: 100 ppm 8 hours.

Occupational exposure limits (Mexico)

CAS # Exposure limits
Light Aliphatic Hydrocarbon 64742-47-8 ACGIH TLV (United States, 3/2020).
Absorbed through skin.
TWA: 200 mg/m³, (as total hydrocarbon
vapor) 8 hours.
Zirconium 2-Ethylhexanoate 22464-99-9 NOM-010-STPS-2014 (Mexico, 4/2016).
TWA: 5 mg/m³, (as Zr) 8 hours.
STEL: 10 mg/m³, (as Zr) 15 minutes.
Ethylbenzene 100-41-4 NOM-010-STPS-2014 (Mexico, 4/2016).
TWA: 20 ppm 8 hours.

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Individual protection measures
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: safety glasses with side-
shields.

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Section 8. Exposure controls/personal protection
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.

Section 9. Physical and chemical properties

Appearance
Physical state : Liquid.
Color : Not available.
Odor : Not available.
Odor threshold : Not available.
pH : Not available.
Melting point/freezing point : Not available.
Boiling point/boiling range : 148°C (298.4°F)
Flash point : Closed cup: 38°C (100.4°F) [Tagliabue Closed Cup]
Evaporation rate : 0.13 (butyl acetate = 1)
Flammability (solid, gas) : Not available.
Lower and upper explosive : Lower: 1%
(flammable) limits Upper: 6%
Vapor pressure : 0.17 kPa (1.27 mm Hg) [at 20°C]
Vapor density : 5 [Air = 1]
Relative density : 0.97
Solubility : Not available.
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Kinematic (40°C (104°F)): <0.205 cm2/s (<20.5 cSt)
Molecular weight : Not applicable.
Aerosol product
Heat of combustion : 19.136 kJ/g

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Section 10. Stability and reactivity
Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.

Incompatible materials : Reactive or incompatible with the following materials:

oxidizing materials

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.

Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Carbon Black LD50 Oral Rat >15400 mg/kg -
Xylene, mixed isomers LC50 Inhalation Gas. Rat 6700 ppm 4 hours
LD50 Oral Rat 4300 mg/kg -
Methyl Ethyl Ketoxime LD50 Oral Rat 930 mg/kg -
Hydrotreated Heavy LC50 Inhalation Vapor Rat 8500 mg/m³ 4 hours
Petroleum Naphtha
LD50 Oral Rat >6 g/kg -
Zirconium 2-Ethylhexanoate LD50 Dermal Rabbit >5 g/kg -
LD50 Oral Rat >5 g/kg -
Methyl Isobutyl Ketone LD50 Oral Rat 2080 mg/kg -
Ethylbenzene LD50 Dermal Rabbit >5000 mg/kg -
LD50 Oral Rat 3500 mg/kg -
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
Xylene, mixed isomers Eyes - Mild irritant Rabbit - 87 mg -
Eyes - Severe irritant Rabbit - 24 hours 5 -
mg
Skin - Mild irritant Rat - 8 hours 60 Ul -
Skin - Moderate irritant Rabbit - 24 hours 500 -
mg
Skin - Moderate irritant Rabbit - 100 % -
Methyl Ethyl Ketoxime Eyes - Severe irritant Rabbit - 100 Ul -
Methyl Isobutyl Ketone Eyes - Moderate irritant Rabbit - 24 hours 100 -
Ul
Eyes - Severe irritant Rabbit - 40 mg -
Skin - Mild irritant Rabbit - 24 hours 500 -
mg
Ethylbenzene Eyes - Severe irritant Rabbit - 500 mg -
Skin - Mild irritant Rabbit - 24 hours 15 -
mg

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Section 11. Toxicological information
Sensitization
Not available.
Mutagenicity
Not available.
Carcinogenicity
Not available.
Classification
Product/ingredient name OSHA IARC NTP
Carbon Black - 2B -
Xylene, mixed isomers - 3 -
Methyl Isobutyl Ketone - 2B -
Ethylbenzene - 2B -
Reproductive toxicity
Not available.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Name Category Route of Target organs
exposure
Light Aliphatic Hydrocarbon Category 3 - Respiratory tract
irritation
Category 3 Narcotic effects
Calcium Carbonate Category 3 - Respiratory tract
irritation
Xylene, mixed isomers Category 3 - Respiratory tract
irritation
Hydrotreated Heavy Petroleum Naphtha Category 3 - Respiratory tract
irritation
Category 3 Narcotic effects
Methyl Isobutyl Ketone Category 3 - Respiratory tract
irritation
Category 3 Narcotic effects
Ethylbenzene Category 3 - Respiratory tract
irritation
Category 3 Narcotic effects
Med. Aliphatic Hydrocarbon Solvent Category 3 - Respiratory tract
irritation
Category 3 Narcotic effects
Specific target organ toxicity (repeated exposure)
Name Category Route of Target organs
exposure
Light Aliphatic Hydrocarbon Category 2 - -
Xylene, mixed isomers Category 2 - -
Hydrotreated Heavy Petroleum Naphtha Category 2 - -
Methyl Isobutyl Ketone Category 2 - -
Ethylbenzene Category 2 - -
Med. Aliphatic Hydrocarbon Solvent Category 1 - -
Aspiration hazard

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Section 11. Toxicological information
Name Result
Light Aliphatic Hydrocarbon ASPIRATION HAZARD - Category 1
Xylene, mixed isomers ASPIRATION HAZARD - Category 1
Hydrotreated Heavy Petroleum Naphtha ASPIRATION HAZARD - Category 1
Ethylbenzene ASPIRATION HAZARD - Category 1
Med. Aliphatic Hydrocarbon Solvent ASPIRATION HAZARD - Category 1

Information on the likely : Not available.

routes of exposure
Potential acute health effects
Eye contact : No known significant effects or critical hazards.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness. May cause respiratory irritation.
Skin contact : May cause an allergic skin reaction.
Ingestion : Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : No specific data.
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Skin contact : Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Ingestion : Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
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Section 11. Toxicological information
Not available.
General : May cause damage to organs through prolonged or repeated exposure. Once
sensitized, a severe allergic reaction may occur when subsequently exposed to very low
levels.
Carcinogenicity : Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : Suspected of damaging the unborn child.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates
Not available.

Section 12. Ecological information

Toxicity
Product/ingredient name Result Species Exposure
Light Aliphatic Hydrocarbon Acute LC50 2200 µg/l Fresh water Fish - Lepomis macrochirus 4 days
Xylene, mixed isomers Acute LC50 8500 µg/l Marine water Crustaceans - Palaemonetes 48 hours
pugio
Acute LC50 13400 µg/l Fresh water Fish - Pimephales promelas 96 hours
Methyl Ethyl Ketoxime Acute LC50 843000 µg/l Fresh water Fish - Pimephales promelas 96 hours
Methyl Isobutyl Ketone Acute LC50 505000 µg/l Fresh water Fish - Pimephales promelas 96 hours
Chronic NOEC 78 mg/l Fresh water Daphnia - Daphnia magna 21 days
Chronic NOEC 168 mg/l Fresh water Fish - Pimephales promelas - 33 days
Embryo
Ethylbenzene Acute EC50 4600 µg/l Fresh water Algae - Pseudokirchneriella 72 hours
subcapitata
Acute EC50 3600 µg/l Fresh water Algae - Pseudokirchneriella 96 hours
subcapitata
Acute EC50 6.53 mg/l Marine water Crustaceans - Artemia sp. - 48 hours
Nauplii
Acute EC50 2.93 mg/l Fresh water Daphnia - Daphnia magna - 48 hours
Neonate
Acute LC50 4200 µg/l Fresh water Fish - Oncorhynchus mykiss 96 hours

Persistence and degradability

Product/ingredient name Aquatic half-life Photolysis Biodegradability
Xylene, mixed isomers - - Readily
Methyl Isobutyl Ketone - - Readily
Ethylbenzene - - Readily

Bioaccumulative potential

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Section 12. Ecological information
Product/ingredient name LogPow BCF Potential
Xylene, mixed isomers - 8.1 to 25.9 low
Methyl Ethyl Ketoxime - 2.5 to 5.8 low
Hydrotreated Heavy - 10 to 2500 high
Petroleum Naphtha
Zirconium 2-Ethylhexanoate - 2.96 low

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations

Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.

Section 14. Transport information

DOT TDG Mexico IATA IMDG
Classification Classification Classification
UN number UN1263 UN1263 UN1263 UN1263 UN1263

UN proper PAINT PAINT PAINT PAINT PAINT. Marine

shipping name pollutant (Light
Aliphatic
Hydrocarbon)
Transport 3 3 3 3 3
hazard class(es)

Packing group III III III III III

Environmental No. No. No. Yes. The Yes.
hazards environmentally
hazardous
substance mark
is not required.

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Section 14. Transport information
Additional This product may Product classified - The The marine
information be re-classified as as per the environmentally pollutant mark is
"Combustible following sections hazardous not required when
Liquid," unless of the substance mark transported in
transported by Transportation of may appear if sizes of ≤5 L or ≤5
vessel or aircraft. Dangerous Goods required by other kg.
Non-bulk Regulations: transportation Emergency
packages (less 2.18-2.19 (Class regulations. schedules F-E, S-
than or equal to 3). E
119 gal) of
combustible
liquids are not
regulated as
hazardous
materials in
package sizes
less than the
product reportable
quantity.
ERG No. ERG No. ERG No.
128 128 128

Special precautions for user : Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability
prior to shipment, and compliance with the applicable regulations is the sole
responsibility of the person offering the product for transport. People loading and
unloading dangerous goods must be trained on all of the risks deriving from the
substances and on all actions in case of emergency situations.
Transport in bulk according : Not available.
to IMO instruments
Proper shipping name : Not available.

Section 15. Regulatory information

SARA 313
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
California Prop. 65
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
International regulations
International lists : Australia inventory (AICS): Not determined.
China inventory (IECSC): Not determined.
Japan inventory (ENCS): Not determined.
Japan inventory (ISHL): Not determined.
Korea inventory (KECI): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan Chemical Substances Inventory (TCSI): Not determined.

Date of issue/Date of revision : 10/15/2020 Date of previous issue : 11/28/2019 Version : 16 16/18
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Section 15. Regulatory information
Thailand inventory: Not determined.
Turkey inventory: Not determined.
Vietnam inventory: Not determined.

Section 16. Other information

Hazardous Material Information System (U.S.A.)
Health * 3

Flammability 2

Physical hazards 0

The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS®
ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service
mark of the American Coatings Association, Inc.
Procedure used to derive the classification
Classification Justification
FLAMMABLE LIQUIDS - Category 3 On basis of test data
SKIN SENSITIZATION - Category 1 Calculation method
CARCINOGENICITY - Category 2 Calculation method
TOXIC TO REPRODUCTION - Category 2 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract Calculation method
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Calculation method
Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Calculation method
ASPIRATION HAZARD - Category 1 Calculation method
History
Date of printing : 10/15/2020
Date of issue/Date of : 10/15/2020
revision
Date of previous issue : 11/28/2019
Version : 16
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
Indicates information that has changed from previously issued version.
Notice to reader

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Section 16. Other information
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer,
or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements
are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is
responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The
conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is
responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user
should not use the product for any purpose other than the purpose shown in the applicable section of this SDS
without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of
sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs
obtained from any other source.

Date of issue/Date of revision : 10/15/2020 Date of previous issue : 11/28/2019 Version : 16 18/18
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 SAFETY DATA SHEET
Telephone (704) 987-4555
8935 NorthPointe Executive Park Dr.
Huntersville, NC 28078
www.irwin.com

December 23, 2016

IRWIN Chalk – Red, Permanent
Revision 2

1. PRODUCT and COMPANY IDENTIFICATION

Commercial Product Name: IRWIN Chalk – Red, Permanent
Company: IRWIN Tools
Use of product: Snap line mark
Emergency contact: 1-800-464-7946 8:00am-5:00pm Monday-Friday

2. HAZARDS IDENTIFICATION
Hazards Identification: GHS Classification and Hazard Statement
Carcinogenicity – May cause cancer (lung) Category 1A, H350
Signal Word: DANGER
Precautionary Statements
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P280 Wear protective gloves and eye protection.
P308 and P313 If exposed or concerned, get medical advice/attention.
P405 Store locked up.
Hazards Not Otherwise Classified or Not Covered by GHS:
Eye: May cause irritation. Chalk dust is discomforting and abrasive to the eyes.
Skin: Prolonged skin contact may cause irritation. When the product is used as intended, it is
unlikely to cause discomfort.
Ingestion: Ingestion of large amounts may cause gastrointestinal irritation. Ingestion is
considered an unlikely route of entry in commercial or industrial environments.
Inhalation: May cause respiratory tract irritation. When the product is used as intended, it is
unlikely to cause discomfort.
Chronic: Repeated and prolonged inhalation exposure to crystalline silica dust above
exposure limits may cause delayed, chronic lung injury (silicosis). Prolonged inhalation of iron
oxide dust is known to produce a benign lung condition known as siderosis. When the project
is used as intended, dust levels should not exceed exposure limits. See Sections 8 and 11.

Hazard Ratings:
Hazardous Material Identification System (HMIS):
Health 2*, Flammability 0, Reactivity 0 *chronic effects
National Fire Protection Association (NFPA):
DANGER Health 2, Flammability 0, Reactivity 0

3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance name Value (%) CAS No. EC No.
Calcium carbonate 75 - 80 471-34-1 207-439-9
Red Iron Oxide 20 - 25 1309-37-1 215-168-2
Silica (crystalline quartz)1 0.1 - 1 14808-60-7 238-878-4
1
Calcium carbonate may contain crystalline silica at levels between 0.1 and 1.0 % and varies naturally.

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 SAFETY DATA SHEET
IRWIN Chalk – Red, Permanent

4. FIRST AID MEASURES

Inhalation: Remove from exposure and move to fresh air immediately.
Encourage the patient to blow nose to ensure clear breathing passages.
If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid if cough or other symptoms appear.

Skin contact: Wet clothing first to minimize dust generation, then; remove contaminated
clothing and shoes. Launder contaminated clothing before wearing again.
Wash affected area with water (and soap if available)
Get medical aid in the event of irritation.

Eye contact: Do not rub eyes, rubbing may cause abrasions. Flush eyes with plenty of water
for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Ingestion: If the victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical
aid immediately.

Additional advice: Show this safety data sheet to the doctor in attendance

5. FIRE-FIGHTING MEASURES
Suitable extinguishing media: Substance is noncombustible, however; the containers may
burn, releasing carbon monoxide, and carbon dioxide. Use appropriate extinguishing media for
the combustible material involved in a fire.

Explosion: No information found.

Specific hazards: If oxidation of this product should occur, heat will be liberated which could
cause surrounding combustibles to burn.

Special protective equipment for Firefighters: As in any fire, wear a self-contained

breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions: Wear appropriate personal protective equipment as specified in
Section 8.

Environmental precautions: Do not allow this material to be released to the environment

without proper governmental permits.

Methods for cleaning up: Recover the product whenever possible. Avoid generating dust
when sweeping/shoveling up. If required, wet the material with water to prevent creating dust.
Pick up and place in a suitable container for reclamation or disposal. Follow applicable OSHA
regulations (29 CFR 1910.120)

7. HANDLING AND STORAGE

Storage: Store this product in a tightly-closed container in a dry, well-ventilated area away
from incompatible substances.

Handling: Avoid creating, or breathing dust. Practice good personal hygiene, (hand washing,
etc.) after using this product. Avoid contact with skin and eyes.

Packaging material: No information found.

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 SAFETY DATA SHEET
IRWIN Chalk – Red, Permanent

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure Guidelines
Exposure Limit 8-Hour TWA1 (mg/m3)

% by OSHA PEL ACGIH NIOSH

Component CAS No. weight TLV REL

Calcium Carbonate 471-34-1; 70-75 152 53 102 102 53

(Limestone) (1317-65-3)
Red Iron Oxide 1309-37-1 25-30 10 53 5
Silica-Crystalline 14808-60-7 0.1-1.0 0.053 0.0253 0.053
Quartz4

1 TWA = Time-weighted average

2 Total dust.
3 Respirable dust.
4 Calcium carbonate may contain crystalline silica at levels between 0.1 and 1.0 % and
varies naturally.

Exposure and Engineering Controls: Facilities storing or utilizing this material should have
potable water available for washing eyes and skin. Use sufficient general area (or outdoor)
ventilation. Local exhaust ventilation should be used if airborne concentrations of dust exceed
limits cited in Section 8.

Personal protective equipment:

Hand protection: Wear protective gloves

Eye protection: Wear safety glasses, or chemical goggles in windy conditions or where eye
contact is possible.
Respiratory protection: When engineering controls are not sufficient to reduce exposure,
seek professional advice prior to respirator selection and use. Follow the OSHA respirator
regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or
European Standard EN 149 approved respirator when necessary.

Hygiene measures: Wash contaminated clothing before reuse.

Environmental exposure controls: No information found.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Powder
Color: Black
Odor: Odorless.
pH (at 10% solids): 8.5-9.5
Boiling point/range: No data available.
Melting point/range: Decomposes at 1,517 °F (825°C).
Flash point: No data available.
Evaporation rate: No data available.
Vapor density: No data available.
Solubility in water: <0.0002 (Trace)
Explosive properties: No data available.
Oxidizing properties: No data available.
Vapor pressure: No data available.
Relative density (H2O=1): 3.40-3.45
Viscosity: No data available.
Partition coefficient (n-octanol/water): No data available.

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 SAFETY DATA SHEET
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10. STABILITY AND REACTIVITY

Stability: Stable under normal temperatures and pressures.

Hazardous decomposition products: Carbon monoxide, carbon dioxide, calcium oxide.

Materials to avoid: Strong oxidizing agents, acids, aluminum, fluorine, magnesium, peroxides
hydrazine, calcium hypochlorite, performic acid, and bromine pentafluoride.

Conditions to avoid: Incompatible materials.

Hazardous Polymerization: Does not occur.

11. TOXICOLOGICAL INFORMATION

Note: Toxicological effects described in this section are those that would be expected based
on data from the components of this product.

Acute toxicity: Calcium carbonate (CAS# 471-34-1): Draize test, rabbit, eye: 750 ug/24H
Severe; Draize test, rabbit, skin: 500 mg/24H Moderate; Oral, rat: LD50 = 6,450mg/kg.

Inhalation: (Silica, crystalline quartz) Human: LCLo: 300 µg/m3/ intermittent exposure over a
10-year period produced pulmonary system effects.

Skin contact: (Calcium carbonate) Rabbit: 500mg administered for 24 hours produces
moderate skin irritation.

Eye contact: (Calcium carbonate) Rabbit: 0.750 mg administered for 24 hours produced
severe irritation.

Ingestion: (Calcium carbonate) Rat: LD50: 6,450 mg/kg.

(Iron Oxide) Rat: LD50: >5,000 mg/kg.

Chronic toxicity/Carcinogenicity: Repeated and prolonged inhalation exposure to

crystalline silica dust above exposure limits may cause delayed, chronic lung injury (silicosis).
When the product is used as intended, dust levels should not exceed exposure limits.

Quartz – crystalline silica:

The International Agency for Research on Cancer (IARC) has designated this substance
Group 1, “carcinogenic to humans”.
The National Toxicology Program (NTP) has designated this substance: Group K “known to be
a human carcinogen”
American Conference of Governmental Industrial Hygienists (ACGIH) has designated this
substance A2; suspected human carcinogen. The agent is carcinogenic in experimental
animals at dose levels, by route of administration, at sites of histologic type(s) or by
mechanism(s) considered relevant to worker exposure. Available epidemiologic studies are
conflicting or insufficient to confirm an increased risk of cancer in exposed humans.

12. ECOLOGICAL INFORMATION

Bioaccumulation: No information found.

Ecotoxicity effects: No information found.
Fish Toxicity: Golden Orfe (Leucisus idus) LC Lo: greater than 1,000 mg/l. Limestone (which is
primarily composed of calcium carbonate) is not classified as a “Toxic pollutant” or a
“hazardous substance under Section 307 and 311 of the United States Clean Water Act.

13. DISPOSAL CONSIDERATIONS

Waste from residues of this product is not a hazardous waste according to U.S. Environmental
Protection Agency (EPA) regulations. Disposal by landfill may be acceptable.
Consult an expert on the disposal of recovered material for compliance with state, provincial,
and/or local regulations.

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 SAFETY DATA SHEET
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14. TRANSPORT INFORMATION

U.S. DOT: Not regulated

ADR/RID: Not regulated

IMDG: Not regulated

ICAO/IATA: Not regulated

15. REGULATORY INFORMATION

U.S. Federal Regulations

OSHA: Ingredients are listed as air contaminants (29 CFR 1910.1000).
Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).

TSCA (Toxic Substance Control Act): All components of this product are listed on the TSCA
inventory.

CERCLA: Hazardous Substance, (40 CFR 302.4): Not Listed.

Extremely Hazardous Substance (40 CFR 355): Not Listed.

SARA Hazard Category: This product has been reviewed according to the EPA "Hazard
Categories" promulgated under Sections 311 and 312 of the Superfund Amendment and
Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following category:
"An immediate (acute) and chronic health hazard."

Chemicals subject to the reporting requirements of Section 313 or Title III of SARA and 40
CFR Part 372: None.

STATE REGULATIONS:
California's "Safe Drinking Water and Toxic Enforcement Act of 1986" (Proposition 65)

This product contains the following Proposition 65 regulated materials known to the State of
California to cause cancer or reproductive harm. The listed typical amounts are a result of their
natural presence in the raw materials from which this product is produced.
Silica-crystalline quartz equal to, or less than 1.0 percent

CANADA WHIMS: This product has been classified in accordance with the hazard criteria of
the Controlled Products Regulation (CPR), and the SDS contains all of the information
required by the CPR.

16. OTHER INFORMATION

The contents and format of this SDS are in accordance with the U.S. Hazard Communication
Standard 29 CFR 1910.1200; the Canadian CPR, and Workplace Hazardous Materials
Information System (WHMIS); and EEC Commission Directive 1999/45/EC, and EEC
Commission Regulation 1907/2006/EC (REACH) Annex II.

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 SAFETY DATA SHEET
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DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which
we believe are reliable. However, the information is provided without any warranty, express or
implied, regarding its correctness. The conditions or methods of handling, storage, use or
disposal of the product are beyond our control and may be beyond our knowledge. For this
and other reasons, we do not assume responsibility and expressly disclaim liability for loss,
damage or expense arising out of or in any way connected with the handling, storage, use or
disposal of the product. This SDS was prepared and is to be used only for this product.
If the product is used as a component in another product, this SDS information may not be
applicable.

End of document

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SDS Number: 00010009001 Revision Date: 10/23/2018

24 Hour Emergency Phone Numbers

Medical/Poison Control:
In U.S.: Call 1-800-222-1222

Outside U.S.: Call your local poison

control center
Transportation/National Response

Safety Data Sheet Center:

1-800-535-5053
1-352-323-3500
NOTE: The National ResponseCenter emergency
numbers to be used only in the event of chemical
emergencies involving a spill, leak, fire, exposure or
accident involving chemicals.

IMPORTANT: Provide this information to employees, customers, and users of this product. Read this SDS before handling or disposing of this
product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with
requirements of this standard. All abbreviated terms used in this SDS are further described in Section 16.

1. Identification

This Safety Data Sheet is available in American Spanish upon request.

Los Datos de Serguridad pueden obtenerse en Espanol si lo riquiere.

Product Name: Kwik Seal Tub & Tile Adhesive Caulk - All Revision Date: 10/23/2018
Colors

Product UPC Number: 070798180017, 070798180130, Supercedes Date: 10/2/2018

070798180024
Product Use/Class: Caulking Compound SDS No: 00010009001

Manufacturer: DAP Products Inc. Preparer: Regulatory and Environmental

2400 Boston Street Suite 200 Affairs
Baltimore, MD 21224-4723
888-327-8477 (non - emergency matters)

SDS Coordinator: [email protected]

Emergency Telephone:
Transportation: 1-800-535 -5053
1-352-323-3500
Poison Control: 1-800-222-1222

2. Hazards Identification

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SDS Number: 00010009001 Revision Date: 10/23/2018

GHS Classification
Not a hazardous substance or mixture.

Symbol(s) of Product
None
Signal Word
Not a hazardous substance or mixture.

Possible Hazards
4% of the mixture consists of ingredients of unknown acute toxicity

3. Composition/Information on Ingredients

Chemical Name CAS-No. Wt. % GHS Symbols GHS Statements

Limestone 1317-65-3 30-60 No Information No Information
Diethylene glycol dibenzoate 120-55-8 1-5 GHS07 H312
Lubricating petroleum oil 72623-86-0 1-5 GHS07 H332
Dipropylene glycol dibenzoate 27138-31-4 1-5 No Information No Information
Petroleum distillates 64741-88-4 1-5 GHS06 H331
Titanium dioxide 13463-67-7 0.1-1.0 No Information No Information
Quartz 14808-60-7 0.1-1.0 GHS07 H302
The text for GHS Hazard Statements shown above (if any) is given in the "Other information" Section.

4. First-aid Measures

FIRST AID - INHALATION: Material is not likely to present an inhalation hazard at ambient conditions. If you experience difficulty in
breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical attention immediately.
FIRST AID - SKIN CONTACT: In case of contact, wash skin immediately with soap and water.
FIRST AID - EYE CONTACT: In case of contact, immediately flush eyes with large quantities of water for at least 15 minutes until
irritation subsides. Get medical attention immediately.
FIRST AID - INGESTION: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately.
5. Fire-fighting Measures
UNUSUAL FIRE AND EXPLOSION HAZARDS: No Information
SPECIAL FIREFIGHTING PROCEDURES: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or
equivalent) and full protective gear. Use water spray to cool exposed surfaces.
EXTINGUISHING MEDIA: Alcohol Foam, Carbon Dioxide, Dry Chemical, Foam, Water Fog

6. Accidental Release Measures

ENVIRONMENTAL MEASURES: No Information
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Use personal protective equipment as necessary. In case of
spillage, absorb with inert material and dispose of in accordance with applicable regulations. Scrape up dried material and place into
containers.
7. Handling and Storage
HANDLING: KEEP OUT OF REACH OF CHILDREN!DO NOT TAKE INTERNALLY. Use only with adequate ventilation. Ensure fresh
air entry during application and drying. Wash thoroughly after handling.
STORAGE: Avoid excessive heat and freezing. Do not store at temperatures above 120 degrees F. Store away from caustics and
oxidizers.
8. Exposure Controls/Personal Protection

Ingredients with Occupational Exposure Limits

Chemical Name ACGIH TLV-TWA ACGIH-TLV STEL OSHA PEL-TWA OSHA PEL-CEILING

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SDS Number: 00010009001 Revision Date: 10/23/2018

Limestone N.E. N.E. 15 mg/m3 TWA N.E.

total dust, 5 mg/m3
TWA respirable
fraction
Diethylene glycol dibenzoate N.E. N.E. N.E. N.E.
Lubricating petroleum oil N.E. N.E. N.E. N.E.
Dipropylene glycol dibenzoate N.E. N.E. N.E. N.E.
Petroleum distillates N.E. N.E. N.E. N.E.
Titanium dioxide 10 mg/m3 TWA N.E. 15 mg/m3 TWA N.E.
total dust
Quartz 0.025 mg/m3 TWA N.E. 50 µg/m3 TWA N.E.
respirable
particulate matter
Further Advice: MEL = Maximum Exposure Limit OES = Occupational Exposure Standard SUP = Supplier's Recommendation
Sk = Skin Sensitizer N.E. = Not Established

Personal Protection

RESPIRATORY PROTECTION: No personal respiratory protective equipment normally required. National Institute for
Occupational Safety and Health (NIOSH) has recommended that the permissible exposure limit be changed to 50
micrograms respirable free silica per cubic meter of air (0.05 mg/m3) as determined by a full shift sample up to 10-hour
work shift.

SKIN PROTECTION: Rubber gloves.

EYE PROTECTION: Goggles or safety glasses with side shields.

OTHER PROTECTIVE EQUIPMENT: Not required under normal use.

HYGIENIC PRACTICES: Wash hands before breaks and at the end of workday. Remove and wash contaminated
clothing before re-use.

9. Physical and Chemical Properties

Appearance: Colored Physical State: Paste
Odor: Very Slight Ammonia Odor Threshold: Not Established
Density, g/cm3: 1.57 - 1.67 pH: Between 7.0 and 12.0
Freeze Point, °C: Not Established Viscosity (mPa.s): Not Established
Solubility in Water: No Information Partition Coeff., n-octanol/water: Not Established
Decomposition Temperature, °C: Not Established Explosive Limits, %: N.E. - N.E.
Boiling Range, °C: 100 - 100 Auto-Ignition Temperature, °C Not Established
Minimum Flash Point, °C: 100 Vapor Pressure, mmHg: Not Established
Evaporation Rate: Slower Than n-Butyl Acetate Flash Method: Seta Closed Cup
Vapor Density: Heavier Than Air Flammability, NFPA: Non-Flammable
Combustibility: Does not support combustion

(See "Other information" Section for abbreviation legend)

(If product is an aerosol, the flash point stated above is that of the propellant.)

10. Stability and Reactivity

STABILITY: Stable under recommended storage conditions.
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SDS Number: 00010009001 Revision Date: 10/23/2018

CONDITIONS TO AVOID: Excessive heat and freezing.

INCOMPATIBILITY: Incompatible with strong bases and oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS: Normal decomposition products, i.e., COx, NOx.

11. Toxicological Information

EFFECT OF OVEREXPOSURE - INHALATION: Under normal use conditions, this product is not expected to cause adverse health
effects. Inhalation of vapors in high concentration may cause mild irritation of respiratory system (nose, mouth, mucous membranes).
EFFECT OF OVEREXPOSURE - SKIN CONTACT: Under normal use conditions, this product is not expected to cause adverse
health effects. Prolonged or repeated contact with skin may cause mild irritation.
EFFECT OF OVEREXPOSURE - EYE CONTACT: Under normal use conditions, this product is not expected to cause adverse
health effects. Direct eye contact may cause irritation.
EFFECT OF OVEREXPOSURE - INGESTION: Under normal use conditions, this product is not expected to cause adverse health
effects. Single dose oral toxicity is very low. Amounts ingested incidental to industrial handling are not likely to cause injury; however,
ingestion of large amounts may cause injury.
CARCINOGENICITY: No Information
EFFECT OF OVEREXPOSURE - CHRONIC HAZARDS: Repeated or prolonged exposure may cause mild irritation of eyes and
skin. The International Agency for Research on Cancer (IARC) has determined that crystalline silica in the form of quartz or
cristobalite that is inhaled from occupational sources is carcinogenic to humans (Group 1- carcinogenic to humans). Refer to IARC
Monograph 68, Silica, Some Silicates and Organic Fibres (published in June 1997) in conjunction with the use of these materials. The
National Toxicology Program (NTP) classifies respirable crystalline silica as "known to be a human carcinogen". Refer to the 9th
Report on Carcinogens (2000). The American Conference of Governmental Industrial Hygienists (ACGIH) classifies crystalline silica,
quartz, as a suspected human carcinogen (Group A2). Breathing dust containing respirable crystalline silica may not cause
noticeable injury or illness even though permanent lung damage may be occurring. Inhalation of dust may have the following serious
chronic health effects: Excessive inhalation of respirable dust can cause pneumoconiosis, a respiratory disease, which can result in
delayed, progressive, disabling and sometimes fatal lung injury. Symptoms include cough, shortness of breath, wheezing, non-
specific chest illness and reduced pulmonary function. Smoking exacerbates this disease. Individuals with pneumoconiosis are
predisposed to develop tuberculosis. There is some evidence that breathing respirable crystalline silica or the disease silicosis is
associated with an increased incidence of significant disease endpoints such as scleroderma (an immune system disorder manifested
by fibrosis of the lungs, skin and other internal organs) and kidney disease.
PRIMARY ROUTE(S) OF ENTRY: Skin Contact, Inhalation

Acute Toxicity Values

The acute effects of this product have not been tested. Data on individual components are tabulated below

CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50

1317-65-3 Limestone 6450 mg/kg Rat >2000 mg/kg >20 mg/L

120-55-8 Diethylene glycol dibenzoate 2830 mg/kg Rat 2000 mg/kg Rabbit >200 mg/L Rat

72623-86-0 Lubricating petroleum oil >5000 mg/kg Rat >2000 mg/kg Rabbit N.I.

27138-31-4 Dipropylene glycol dibenzoate 5368 mg/kg Rat >2000 mg/kg Rabbit >200 mg/L Rat

64741-88-4 Petroleum distillates >5000 mg/kg Rat >2000 mg/kg Rabbit 2.18 mg/L Rat

13463-67-7 Titanium dioxide >10000 mg/kg Rat >5000 mg/kg Rabbit >20 mg/L

14808-60-7 Quartz 500 mg/kg Rat >2000 mg/kg >20 mg/L

N.I. = No Information

12. Ecological Information

ECOLOGICAL INFORMATION: Ecological injuries are not known or expected under normal use.

13. Disposal Information

DISPOSAL INFORMATION: This product does not meet the definition of a hazardous waste according to U.S. EPA Hazardous
Waste Management Regulation, 40 CFR Section 261. Dispose as hazardous waste according to all local, state, federal and provincial
regulations. State and Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper
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SDS Number: 00010009001 Revision Date: 10/23/2018

waste disposal is with the owner of the waste.

14. Transport Information

SPECIAL TRANSPORT PRECAUTIONS: No Information

DOT UN/NA Number: N.A.

DOT Proper Shipping Name: Not Regulated
DOT Technical Name: N.A.
DOT Hazard Class: N.A.
Hazard SubClass: N.A.
Packing Group: N.A.

15. Regulatory Information

SARA SECTION 313:

This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
No Sara 313 components exist in this product.
TOXIC SUBSTANCES CONTROL ACT:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:

No TSCA 12(b) components exist in this product.

16. Other Information

Revision Date: 10/23/2018 Supersedes Date: 10/2/2018
Reason for revision: Substance and/or Product Properties Changed in Section(s):
05 - Flammability Information
09 - Physical & Chemical Information
11 - Toxicological Information
16 - Other Information
Datasheet produced by: Regulatory Department
HMIS Ratings:
Health: Flammability: Reactivity: Personal Protection:

1 1 0 X

VOC Less Water Less Exempt Solvent, g/L: 27.7

VOC Material, g/L: 18
VOC as Defined by California Consumer Product Regulation, Wt/Wt%: 0.6
VOC Actual, Wt/Wt%: 1.2

Text for GHS Hazard Statements shown in Section 3 describing each ingredient:

H302 Harmful if swallowed.

H312 Harmful in contact with skin.
H331 Toxic if inhaled.
H332 Harmful if inhaled.
Icons for GHS Pictograms shown in Section 3 describing each ingredient:

Page 5 / 6
SDS Number: 00010009001 Revision Date: 10/23/2018

GHS06

GHS07

Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined

DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical
values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY
PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE
INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this
document is intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly
trained person, it is therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific
context of the intended use and (ii) determine if they are appropriate.

Page 6 / 6
 Safety Data Sheet

Revision Number: 003.0 Issue date: 03/11/2019

1. PRODUCT AND COMPANY IDENTIFICATION

Product name: LOCTITE LB 8023 IDH number: 299175
Product type/use: Lubricant Item number: 34395
Restriction of Use: None identified Region: United States
Company address: Contact information:
Henkel Corporation Telephone: +1 (860) 571-5100
One Henkel Way MEDICAL EMERGENCY Phone: Poison Control Center
Rocky Hill, Connecticut 06067 1-877-671-4608 (toll free) or 1-303-592-1711
TRANSPORT EMERGENCY Phone: CHEMTREC
1-800-424-9300 (toll free) or 1-703-527-3887
Internet: www.henkelna.com

2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
DANGER: CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE DAMAGE.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.

HAZARD CLASS HAZARD CATEGORY

SKIN IRRITATION 2
SERIOUS EYE DAMAGE 1
SKIN SENSITIZATION 1
REPRODUCTIVE TOXICITY 2

PICTOGRAM(S)

Precautionary Statements

Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been
read and understood. Avoid breathing vapors, mist, or spray. Wash affected area thoroughly
after handling. Contaminated work clothing should not be allowed out of the workplace. Wear
protective gloves, clothing, eye and face protection.
Response: IF ON SKIN: Wash with plenty of water. IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or
concerned: Get medical attention. If skin irritation or rash occurs: Get medical attention. Take
off contaminated clothing.
Storage: Store locked up.
Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local
governmental regulations.

2 % of the mixture consists of ingredient(s) of unknown acute toxicity.

Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the
United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS).

IDH number: 299175 Product name: LOCTITE LB 8023

Page 1 of 7
 See Section 11 for additional toxicological information.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Hazardous Component(s) CAS Number Percentage*
Residual oils (petroleum), solvent-refined,
64742-01-4 10 - 20
<3% DMSO
Calcium oxide 1305-78-8 10 - 20
Graphite 7782-42-5 10 - 20
Distillates (petroleum), solvent-refined
64741-88-4 10 - 20
heavy paraffinic
Petroleum distillates, hydrotreated, light
64742-53-6 5 - 10
naphthenic
Distillates (petroleum), hydrotreated
64742-52-5 5 - 10
heavy naphthenic
Calcium distearate 1592-23-0 5 - 10
Calcium dodecylbenzene sulfonate 26264-06-2 1-5
Calcium dihydroxide 1305-62-0 1-5
Sulfonic acids, petroleum, calcium salts 61789-86-4 1-5
Boron oxide (B2O3) 1303-86-2 0.1 - 1

* Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate protections.

4. FIRST AID MEASURES

Inhalation: Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give
artificial respiration. If symptoms develop and persist, get medical attention.

Skin contact: Wash with soap and water. Remove contaminated clothing and footwear. If
symptoms develop and persist, get medical attention. Wash clothing before
reuse.

Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Get medical attention.

Ingestion: Keep individual calm. Do not induce vomiting. Get medical attention.

Symptoms: See Section 11.

5. FIRE FIGHTING MEASURES

Extinguishing media: Carbon dioxide, foam, powder

Special firefighting procedures: Wear a self-contained breathing apparatus with a full face piece operated in
pressure-demand or other positive pressure mode.

Unusual fire or explosion hazards: In case of fire, keep containers cool with water spray.

Hazardous combustion products: Oxides of nitrogen. Oxides of carbon. Oxides of sulfur. Calcium oxide. Toxic
fumes.

6. ACCIDENTAL RELEASE MEASURES

Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected
personnel.

Environmental precautions: Do not allow product to enter sewer or waterways.

IDH number: 299175 Product name: LOCTITE LB 8023

Page 2 of 7
 Clean-up methods: Scrape up as much material as possible. Clean residue with soap and water.
Store in a partly filled, closed container until disposal. Refer to Section 8
"Exposure Controls / Personal Protection" prior to clean up.

7. HANDLING AND STORAGE

Handling: Use only with adequate ventilation. Prevent contact with eyes, skin and
clothing. Do not breathe vapor and mist. Wash thoroughly after handling.
Keep container closed.

Storage: Keep container closed. Keep in a cool, well ventilated area.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure
controls and protective equipment for each task performed.

Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER

Included in the
regulation but with no
data values. See
regulation for further
details
Residual oils (petroleum), solvent-refined, 5 mg/m3 TWA
None None None
<3% DMSO Inhalable fraction.
Exposure by all
routes should be
carefully controlled to
levels as low as
possible.
Calcium oxide 2 mg/m3 TWA 5 mg/m3 PEL None None
5 mg/m3 PEL
Respirable fraction.
2 mg/m3 TWA
Graphite 15 mg/m3 PEL Total None None
Respirable fraction.
dust.
15 MPPCF TWA
5 mg/m3 TWA 500 ppm (2,000
Distillates (petroleum), solvent-refined Inhalable fraction. mg/m3) PEL
None None
heavy paraffinic 5 mg/m3 TWA mist 5 mg/m3 PEL Mist.
10 mg/m3 STEL mist 5 mg/m3 TWA mist
500 ppm (2,000
Petroleum distillates, hydrotreated, light 5 mg/m3 TWA
mg/m3) PEL None None
naphthenic Inhalable fraction.
5 mg/m3 PEL Mist.
500 ppm (2,000
Distillates (petroleum), hydrotreated 5 mg/m3 TWA
mg/m3) PEL None None
heavy naphthenic Inhalable fraction.
5 mg/m3 PEL Mist.
3 mg/m3 TWA
Respirable fraction.
3 mg/m3 TWA
Calcium distearate None None None
Respirable fraction.
10 mg/m3 TWA
Inhalable fraction.
Calcium dodecylbenzene sulfonate None None None None
5 mg/m3 PEL
Respirable fraction.
Calcium dihydroxide 5 mg/m3 TWA None None
15 mg/m3 PEL Total
dust.
Sulfonic acids, petroleum, calcium salts None None None None
15 mg/m3 PEL Total
Boron oxide (B2O3) 10 mg/m3 TWA None None
dust.

Engineering controls: Provide adequate local exhaust ventilation to maintain worker exposure below
exposure limits.

IDH number: 299175 Product name: LOCTITE LB 8023

Page 3 of 7
 Respiratory protection: Observe OSHA regulations for respirator use (29 CFR 1910.134). Use NIOSH
approved respirator if there is potential to exceed exposure limit(s).

Eye/face protection: Safety goggles or safety glasses with side shields. Safety showers and eye
wash stations should be available.

Skin protection: Use impermeable gloves and protective clothing as necessary to prevent skin
contact.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Paste
Color: Black
Odor: Mild
Odor threshold: Not available.
pH: Not available.
Vapor pressure: Not available.
Boiling point/range: Not available.
Melting point/ range: Not available.
Specific gravity: 1.2648
Vapor density: Not available.
Flash point: Not applicable
Flammable/Explosive limits - lower: Not available.
Flammable/Explosive limits - upper: Not available.
Autoignition temperature: Not available.
Flammability: Not applicable
Evaporation rate: Not available.
Solubility in water: Insoluble
Partition coefficient (n-octanol/water): Not available.
VOC content: < 3 %; 38.4 g/l EPA Method 24
Viscosity: Not available.
Decomposition temperature: Not available.

10. STABILITY AND REACTIVITY

Stability: Stable under normal conditions of storage and use.

Hazardous reactions: None under normal processing.

Hazardous decomposition Oxides of carbon. Oxides of nitrogen. Oxides of sulfur. Calcium oxide. Toxic fumes.
products:

Incompatible materials: Strong acids and strong bases. Strong oxidizing agents. Strong reducing agents. Water.
Alkalis.

Reactivity: Not available.

Conditions to avoid: Keep away from heat, ignition sources and incompatible materials. Avoid dust formation.

11. TOXICOLOGICAL INFORMATION

Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion

IDH number: 299175 Product name: LOCTITE LB 8023

Page 4 of 7
 Potential Health Effects/Symptoms

Inhalation: May cause respiratory tract irritation.

Skin contact: Causes skin irritation. May cause an allergic skin reaction.
Eye contact: Causes serious eye damage.
Ingestion: Principal hazard of ingestion is aspiration into the lungs and subsequent pneumonitis.

Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects
Residual oils (petroleum), solvent-refined,
None Irritant
<3% DMSO
Calcium oxide None Irritant, Corrosive, Eyes
Graphite None Lung
Distillates (petroleum), solvent-refined
None Irritant
heavy paraffinic
Petroleum distillates, hydrotreated, light
None Irritant
naphthenic
Distillates (petroleum), hydrotreated
None Irritant
heavy naphthenic
Calcium distearate None No Target Organs
Calcium dodecylbenzene sulfonate None Eyes, Irritant
Calcium dihydroxide Oral LD50 (Rat) = 7,340 mg/kg Irritant, Corrosive
Sulfonic acids, petroleum, calcium salts None No Data
Blood, Central nervous system,
Boron oxide (B2O3) Oral LD50 (Mouse) = 3,163 mg/kg Gastrointestinal, Irritant, Kidney, Liver, Lung,
Metabolic, Nuisance dust, Skin, Vascular

OSHA Carcinogen
Hazardous Component(s) NTP Carcinogen IARC Carcinogen
(Specifically Regulated)
Residual oils (petroleum), solvent-refined, Known To Be Human
Group 1 No
<3% DMSO Carcinogen.
Calcium oxide No No No
Graphite No No No
Distillates (petroleum), solvent-refined
No No No
heavy paraffinic
Petroleum distillates, hydrotreated, light
No No No
naphthenic
Distillates (petroleum), hydrotreated
No No No
heavy naphthenic
Calcium distearate No No No
Calcium dodecylbenzene sulfonate No No No
Calcium dihydroxide No No No
Sulfonic acids, petroleum, calcium salts No No No
Boron oxide (B2O3) No No No

12. ECOLOGICAL INFORMATION

Ecological information: Not available.

IDH number: 299175 Product name: LOCTITE LB 8023

Page 5 of 7
 13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only.

Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal.

Hazardous waste number: Not a RCRA hazardous waste.

14. TRANSPORT INFORMATION

The transport information provided in this section only applies to the material/formulation itself, and is not specific to any
package/configuration.

U.S. Department of Transportation Ground (49 CFR)

Proper shipping name: Not regulated

Hazard class or division: None
Identification number: None
Packing group: None

International Air Transportation (ICAO/IATA)

Proper shipping name: Not regulated

Hazard class or division: None
Identification number: None
Packing group: None

Water Transportation (IMO/IMDG)

Proper shipping name: Not regulated

Hazard class or division: None
Identification number: None
Packing group: None

15. REGULATORY INFORMATION

United States Regulatory Information

TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act
Inventory.
TSCA 12 (b) Export Notification: None above reporting de minimis

CERCLA/SARA Section 302 EHS: None above reporting de minimis.

CERCLA/SARA Section 311/312: Immediate Health, Delayed Health
CERCLA/SARA Section 313: None above reporting de minimis.
CERCLA Reportable quantity: Calcium dodecylbenzene sulfonate (CAS# 26264-06-2) 1,000 lbs. (454 kg)

California Proposition 65: This product contains a chemical known in the State of California to cause cancer.

Canada Regulatory Information

CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic
Substances List.

16. OTHER INFORMATION

This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format.

IDH number: 299175 Product name: LOCTITE LB 8023

Page 6 of 7
 Prepared by: Product Safety and Regulatory Affairs

Issue date: 03/11/2019

DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel
Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods
Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods
mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and
persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing,
Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular
purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages
of any kind, including lost profits.

This Safety Data Sheet has been generated based on OSHA Hazard Communication Standard (29 CFR 1910.1200) and provides
information in accordance with U.S. federal law only. No warranty or representation of any kind is given with respect to the
substantive or export laws of any other jurisdiction or country. Please confirm that the information provided herein conforms to the
substantive export or other law of any other jurisdiction prior to export. Please contact Henkel Product Safety and Regulatory
Affairs for additional assistance.

IDH number: 299175 Product name: LOCTITE LB 8023

Page 7 of 7
 SAFETY DATA SHEET
MAPP GAS (Petroleum Gas, MAPD)

Section 1. Identification
GHS product identifier : MAPP GAS (Petroleum Gas, MAPD)
Other means of : MAP,MAPP,Methylacetylene-Propadiene, Mixture of Methylacetylene and Propadiene
identification
Product type : Liquefied gas
Product use : Synthetic/Analytical chemistry.
Synonym : MAP,MAPP,Methylacetylene-Propadiene, Mixture of Methylacetylene and Propadiene
SDS # : 002015
Supplier's details : Airgas USA, LLC and its affiliates
259 North Radnor-Chester Road
Suite 100
Radnor, PA 19087-5283
1-610-687-5253

24-hour telephone : 1-866-734-3438

Section 2. Hazards identification

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : FLAMMABLE GASES - Category 1
substance or mixture GASES UNDER PRESSURE - Liquefied gas

GHS label elements

Hazard pictograms :

Signal word : Danger

Hazard statements : Extremely flammable gas.
May form explosive mixtures with air.
Contains gas under pressure; may explode if heated.
May cause frostbite.
May displace oxygen and cause rapid suffocation.
Precautionary statements
General : Read and follow all Safety Data Sheets (SDS’S) before use. Read label before use.
Keep out of reach of children. If medical advice is needed, have product container or
label at hand. Close valve after each use and when empty. Use equipment rated for
cylinder pressure. Do not open valve until connected to equipment prepared for use.
Use a back flow preventative device in the piping. Use only equipment of compatible
materials of construction. Always keep container in upright position. Approach
suspected leak area with caution.
Prevention : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
Response : Leaking gas fire: Do not extinguish, unless leak can be stopped safely. Eliminate all
ignition sources if safe to do so.
Storage : Protect from sunlight. Store in a well-ventilated place.
Disposal : Not applicable.
Hazards not otherwise : Liquid can cause burns similar to frostbite.
classified

Date of issue/Date of revision : 10/22/2018 Date of previous issue : 2/6/2018 Version : 1.01 1/12
MAPP GAS (Petroleum Gas, MAPD)

Section 3. Composition/information on ingredients

Substance/mixture : Mixture
Other means of : MAP,MAPP,Methylacetylene-Propadiene, Mixture of Methylacetylene and Propadiene
identification
Product code : 002015

Ingredient name % CAS number

propylene 37 - 55 115-07-1
methyl acetylene 27 - 33 74-99-7
1,2-propadiene 13 - 15 463-49-0
isobutane 2-5 75-28-5
N-Butane 2-5 106-97-8
Propane 1-5 74-98-6
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention if irritation occurs.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects
persist or are severe. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. To avoid the risk of static discharges and gas ignition, soak contaminated
clothing thoroughly with water before removing it. Get medical attention if symptoms
occur. In case of contact with liquid, warm frozen tissues slowly with lukewarm water
and get medical attention. Do not rub affected area. Wash clothing before reuse.
Clean shoes thoroughly before reuse.
Ingestion : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get
medical attention if adverse health effects persist or are severe. Ingestion of liquid can
cause burns similar to frostbite. If frostbite occurs, get medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband. As this product rapidly becomes a gas when
released, refer to the inhalation section.

Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : Liquid can cause burns similar to frostbite.
Inhalation : No known significant effects or critical hazards.
Skin contact : Dermal contact with rapidly evaporating liquid could result in freezing of the tissues or
frostbite.
Frostbite : Try to warm up the frozen tissues and seek medical attention.
Ingestion : Ingestion of liquid can cause burns similar to frostbite.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:, frostbite
Inhalation : No specific data.
Date of issue/Date of revision : 10/22/2018 Date of previous issue : 2/6/2018 Version : 1.01 2/12
MAPP GAS (Petroleum Gas, MAPD)

Section 4. First aid measures

Skin contact : Adverse symptoms may include the following:, frostbite
Ingestion : Adverse symptoms may include the following:, frostbite

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media
Unsuitable extinguishing : None known.
media

Specific hazards arising : Contains gas under pressure. Extremely flammable gas. In a fire or if heated, a
from the chemical pressure increase will occur and the container may burst, with the risk of a subsequent
explosion.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Contact supplier immediately for specialist advice. Move containers from fire
area if this can be done without risk. Use water spray to keep fire-exposed containers
cool. If involved in fire, shut off flow immediately if it can be done without risk. If this is
impossible, withdraw from area and allow fire to burn. Fight fire from protected location
or maximum possible distance. Eliminate all ignition sources if safe to do so.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode. For
incidents involving large quantities, thermally insulated undergarments and thick textile
or leather gloves should be worn.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : Accidental releases pose a serious fire or explosion hazard. No action shall be taken
personnel involving any personal risk or without suitable training. Evacuate surrounding areas.
Keep unnecessary and unprotected personnel from entering. Do not touch or walk
through spilled material. Shut off all ignition sources. No flares, smoking or flames in
hazard area. Avoid breathing gas. Provide adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Put on appropriate personal protective
equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

Environmental precautions : Ensure emergency procedures to deal with accidental gas releases are in place to avoid
contamination of the environment. Avoid dispersal of spilled material and runoff and
contact with soil, waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil or air).

Date of issue/Date of revision : 10/22/2018 Date of previous issue : 2/6/2018 Version : 1.01 3/12
MAPP GAS (Petroleum Gas, MAPD)

Section 6. Accidental release measures

Methods and materials for containment and cleaning up
Small spill : Immediately contact emergency personnel. Stop leak if without risk. Use spark-proof
tools and explosion-proof equipment.
Large spill : Immediately contact emergency personnel. Stop leak if without risk. Use spark-proof
tools and explosion-proof equipment. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.

Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Contains gas under
pressure. Do not get in eyes or on skin or clothing. Avoid breathing gas. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do
not enter storage areas and confined spaces unless adequately ventilated. Do not
puncture or incinerate container. Use equipment rated for cylinder pressure. Close
valve after each use and when empty. Protect cylinders from physical damage; do not
drag, roll, slide, or drop. Use a suitable hand truck for cylinder movement.
Use only non-sparking tools. Empty containers retain product residue and can be
hazardous. Store and use away from heat, sparks, open flame or any other ignition
source. Use explosion-proof electrical (ventilating, lighting and material handling)
equipment.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved area.
including any Store away from direct sunlight in a dry, cool and well-ventilated area, away from
incompatibilities incompatible materials (see Section 10). Eliminate all ignition sources. Cylinders
should be stored upright, with valve protection cap in place, and firmly secured to
prevent falling or being knocked over. Cylinder temperatures should not exceed 52 °C
(125 °F). Keep container tightly closed and sealed until ready for use. See Section 10
for incompatible materials before handling or use.

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
Ingredient name Exposure limits
propylene ACGIH TLV (United States, 3/2017).
TWA: 500 ppm 8 hours.
ACGIH TLV (United States, 1/2005).
TWA: 500 ppm 8 hours. Form: All forms
methyl acetylene ACGIH TLV (United States, 3/2017).
TWA: 1640 mg/m³ 8 hours.
TWA: 1000 ppm 8 hours.
NIOSH REL (United States, 10/2016).
TWA: 1650 mg/m³ 10 hours.
TWA: 1000 ppm 10 hours.
OSHA PEL (United States, 6/2016).
TWA: 1650 mg/m³ 8 hours.
TWA: 1000 ppm 8 hours.
OSHA PEL 1989 (United States, 3/1989).
TWA: 1650 mg/m³ 8 hours.
TWA: 1000 ppm 8 hours.
1,2-propadiene None.
isobutane NIOSH REL (United States, 10/2016).
TWA: 1900 mg/m³ 10 hours.
TWA: 800 ppm 10 hours.

Date of issue/Date of revision : 10/22/2018 Date of previous issue : 2/6/2018 Version : 1.01 4/12
MAPP GAS (Petroleum Gas, MAPD)

Section 8. Exposure controls/personal protection

ACGIH TLV (United States, 3/2017).
STEL: 1000 ppm 15 minutes.
N-Butane NIOSH REL (United States, 10/2016).
TWA: 1900 mg/m³ 10 hours.
TWA: 800 ppm 10 hours.
OSHA PEL 1989 (United States, 3/1989).
TWA: 1900 mg/m³ 8 hours.
TWA: 800 ppm 8 hours.
ACGIH TLV (United States, 3/2017).
STEL: 1000 ppm 15 minutes.
Propane NIOSH REL (United States, 10/2016).
TWA: 1800 mg/m³ 10 hours.
TWA: 1000 ppm 10 hours.
OSHA PEL (United States, 6/2016).
TWA: 1800 mg/m³ 8 hours.
TWA: 1000 ppm 8 hours.
OSHA PEL 1989 (United States, 3/1989).
TWA: 1800 mg/m³ 8 hours.
TWA: 1000 ppm 8 hours.
ACGIH TLV (United States, 3/2017). Oxygen
Depletion [Asphyxiant].

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: safety glasses with side-
shields.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. If contact with the liquid is possible, insulated gloves suitable for low
temperatures should be worn. Considering the parameters specified by the glove
manufacturer, check during use that the gloves are still retaining their protective
properties. It should be noted that the time to breakthrough for any glove material may
be different for different glove manufacturers. In the case of mixtures, consisting of
several substances, the protection time of the gloves cannot be accurately estimated.
Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.

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MAPP GAS (Petroleum Gas, MAPD)

Section 8. Exposure controls/personal protection

Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Thermal hazards : If there is a risk of contact with the liquid, all protective equipment worn should be
suitable for use with extremely low temperature materials.

Section 9. Physical and chemical properties

Appearance
Physical state : Gas. [Liquefied gas]
Color : Not available.
Odor : Not available.
Odor threshold : Not available.
pH : Not available.
Melting point : -102.7°C (-152.9°F) This is based on data for the following ingredient: Methyl Acetylene.
Weighted average: -152.81°C (-243.1°F)
Boiling point : Not available.
Critical temperature : Lowest known value: 91.85°C (197.3°F) (Propylene).
Flash point : Not available.
Evaporation rate : Not available.
Flammability (solid, gas) : Not available.
Lower and upper explosive : Lower: 2%
(flammable) limits Upper: 13%
Vapor pressure : Not available.
Vapor density : Highest known value: 2.1 (Air = 1) (butane). Weighted average: 1.52 (Air = 1)
Gas Density (lb/ft 3) : Weighted average: 0.11
Relative density : Not applicable.
Solubility : Not available.
Solubility in water : Not available.
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Not applicable.
Flow time (ISO 2431) : Not available.
Molecular weight : 42 g/mol

Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Hazardous reactions or instability may occur under certain conditions of storage or use.
reactions

Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.

Incompatible materials : Oxidizers

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MAPP GAS (Petroleum Gas, MAPD)

Section 10. Stability and reactivity

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.

Hazardous polymerization : May Occur.

Conditions to Avoid: Elevated tempertures and pressures. Polymerization catalysts,

such as metal alkyls, can cause uncontrolled polymerization. Contamination with
oxygen can cause propadiene to form hazardous peroxides.

INHIBITORS/STABILIZERS

An ihibitor is added to the MAPD mixture to prevent potential unstable peroxide

formation. Butanes (iso and/or normal) are also added to the MAPD mixture to prevent
potential concentration of the methylacetylene and propadiene from reaching
concentration levels that would render the mixture unstable in case of weathering off
(evaporation of light components).

Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
isobutane LC50 Inhalation Vapor Rat 658000 mg/m³ 4 hours
N-Butane LC50 Inhalation Vapor Rat 658000 mg/m³ 4 hours
Irritation/Corrosion
Not available.
Sensitization
Not available.
Mutagenicity
Not available.
Carcinogenicity
Not available.
Classification
Product/ingredient name OSHA IARC NTP
propylene - 3 -
Reproductive toxicity
Not available.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Not available.
Specific target organ toxicity (repeated exposure)
Not available.
Aspiration hazard
Not available.

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MAPP GAS (Petroleum Gas, MAPD)

Section 11. Toxicological information

Information on the likely : Not available.
routes of exposure
Potential acute health effects
Eye contact : Liquid can cause burns similar to frostbite.
Inhalation : No known significant effects or critical hazards.
Skin contact : Dermal contact with rapidly evaporating liquid could result in freezing of the tissues or
frostbite.
Ingestion : Ingestion of liquid can cause burns similar to frostbite.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:, frostbite
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:, frostbite
Ingestion : Adverse symptoms may include the following:, frostbite

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.
General : No known significant effects or critical hazards.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates
Not available.

Section 12. Ecological information

Toxicity
Not available.

Persistence and degradability

Not available.

Bioaccumulative potential

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MAPP GAS (Petroleum Gas, MAPD)

Section 12. Ecological information

Product/ingredient name LogPow BCF Potential
propylene 1.77 - low
methyl acetylene 0.94 - low
1,2-propadiene 1.45 - low
isobutane 2.8 - low
N-Butane 2.89 - low
Propane 1.09 - low

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations

Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Empty Airgas-owned pressure vessels should be returned to Airgas. Waste packaging
should be recycled. Incineration or landfill should only be considered when recycling is
not feasible. This material and its container must be disposed of in a safe way. Empty
containers or liners may retain some product residues. Do not puncture or incinerate
container.

Section 14. Transport information

DOT TDG Mexico IMDG IATA
UN number UN1060 UN1060 UN1060 UN1060 UN1060

UN proper Methyl Acetylene Methyl Acetylene Methyl Acetylene Methyl Acetylene Methyl Acetylene
shipping name and and and and and
Propadiene Propadiene Propadiene Propadiene Propadiene
mixtures, mixtures, mixtures, mixtures, mixtures,
stabilized stabilized stabilized stabilized stabilized
Transport 2.1 2.1 2.1 2.1 2.1
hazard class(es)

Packing group - - - - -
Environmental No. No. No. No. No.
hazards
“Refer to CFR 49 (or authority having jurisdiction) to determine the information required for shipment of the
product.”

Additional information
TDG Classification : Product classified as per the following sections of the Transportation of Dangerous
Goods Regulations: 2.13-2.17 (Class 2).
Explosive Limit and Limited Quantity Index 0.125
ERAP Index 3000
Passenger Carrying Road or Rail Index Forbidden

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MAPP GAS (Petroleum Gas, MAPD)

Section 14. Transport information

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.

Transport in bulk according : Not available.

to Annex II of MARPOL and
the IBC Code

Section 15. Regulatory information

U.S. Federal regulations : TSCA 8(a) CDR Exempt/Partial exemption: Not determined
Clean Air Act (CAA) 112 regulated flammable substances: Propylene; Methyl
Acetylene; Propadiene; Isobutane; butane; propane
Clean Air Act Section 112 : Not listed
(b) Hazardous Air
Pollutants (HAPs)
Clean Air Act Section 602 : Not listed
Class I Substances
Clean Air Act Section 602 : Not listed
Class II Substances
DEA List I Chemicals : Not listed
(Precursor Chemicals)
DEA List II Chemicals : Not listed
(Essential Chemicals)
SARA 302/304
Composition/information on ingredients
No products were found.
SARA 304 RQ : Not applicable.
SARA 311/312
Classification : Refer to Section 2: Hazards Identification of this SDS for classification of substance.
SARA 313
Product name CAS number %
Form R - Reporting Propylene 115-07-1 37 - 55
requirements
Supplier notification Propylene 115-07-1 37 - 55

SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
State regulations
Massachusetts : The following components are listed: PROPYLENE; PROPENE; PROPYNE; METHYL
ACETYLENE; ISOBUTANE; BUTANE; PROPANE
New York : None of the components are listed.
New Jersey : The following components are listed: PROPYLENE; 1-PROPENE; METHYL
ACETYLENE; 1-PROPYNE; PROPADIENE; 1,2-PROPADIENE; Isobutane; PROPANE,
2-METHYL-; BUTANE; PROPANE
Pennsylvania : The following components are listed: 1-PROPENE; 1-PROPYNE; PROPANE,
2-METHYL-; BUTANE; PROPANE
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
Montreal Protocol (Annexes A, B, C, E)
Not listed.

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MAPP GAS (Petroleum Gas, MAPD)

Section 15. Regulatory information

Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
Inventory list
Australia : All components are listed or exempted.
Canada : All components are listed or exempted.
China : Not determined.
Europe : All components are listed or exempted.
Japan : Japan inventory (ENCS): Not determined.
Japan inventory (ISHL): Not determined.
Malaysia : Not determined.
New Zealand : All components are listed or exempted.
Philippines : All components are listed or exempted.
Republic of Korea : All components are listed or exempted.
Taiwan : All components are listed or exempted.
Thailand : Not determined.
Turkey : Not determined.
United States : All components are listed or exempted.
Viet Nam : Not determined.

Section 16. Other information

Hazardous Material Information System (U.S.A.)
Health / 1

Flammability 4
Physical hazards 3

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS®
ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
National Fire Protection Association (U.S.A.)

4 Flammability
Health 1 1 Instability/Reactivity
Special

Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.

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MAPP GAS (Petroleum Gas, MAPD)

Section 16. Other information

Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Procedure used to derive the classification
Classification Justification
FLAMMABLE GASES - Category 1 Expert judgment
GASES UNDER PRESSURE - Liquefied gas Expert judgment
History
Date of printing : 10/22/2018
Date of issue/Date of : 10/22/2018
revision
Date of previous issue : 2/6/2018
Version : 1.01
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
References : Not available.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.

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 SAFETY DATA SHEET
SDS ID NO.: 0298MAR019
Revision Date 05/22/2015

1. IDENTIFICATION
Product Name: Marathon Petroleum Premium AW II Hydraulic Oil
Synonym: Premium AW II ISO 32 Hydraulic Oil; Premium AW II ISO 46 Hydraulic Oil; Premium AW II
ISO 68 Hydraulic Oil; Premium AW II ISO 100 Hydraulic Oil; ISO 32 Premium AW II
Hydraulic Oil; ISO 46 Premium AW II Hydraulic Oil; ISO 68 Premium AW II Hydraulic Oil;
ISO 100 Premium AW II Hydraulic Oil
Product Code: 0298MAR019
Chemical Family: Hydrocarbon Mixture

Recommended Use: Hydraulic Fluid.

Restrictions on Use: All others.

Manufacturer, Importer, or Responsible Party Name and Address:

MARATHON PETROLEUM COMPANY LP
539 South Main Street
Findlay, OH 45840
SDS information: 1-419-421-3070

Emergency Telephone: 1-877-627-5463

2. HAZARD IDENTIFICATION
Classification

OSHA Regulatory Status

This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Acute aquatic toxicity Category 3

Chronic aquatic toxicity Category 3

Hazards Not Otherwise Classified (HNOC)

Not applicable.

Label elements
EMERGENCY OVERVIEW
Harmful to aquatic life with long lasting effects

Appearance Clear Liquid Physical State Liquid Odor Petroleum

Precautionary Statements - Prevention

Avoid release to the environment

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Precautionary Statements - Response

Not applicable.

Precautionary Statements - Storage

Not applicable.

Precautionary Statements - Disposal

Dispose of contents/container at an approved waste disposal plant

Additional Information
Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand.

3. COMPOSITION/INFORMATION ON INGREDIENTS
Lube oil is a complex mixture of highly refined lubricating base stocks and additives.
Composition Information:

Name CAS Number % Concentration

Solvent Refined, Hydrotreated Heavy Paraffinic 64742-54-7 98-99
Distillate
2,6-di-tert-butylphenol 128-39-2 0.1-1

All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume.

4. FIRST AID MEASURES

First Aid Measures

General Advice: In case of accident or if you feel unwell, seek medical advice immediately (show directions
for use or safety data sheet if possible).

Inhalation: Remove to fresh air. If not breathing, institute rescue breathing. If breathing is difficult,
ensure airway is clear, give oxygen and continue to monitor. If heart has stopped,
immediately begin cardiopulmonary resuscitation (CPR). If symptoms occur get medical
attention.

Skin Contact: Wash skin with plenty of soap and water. If irritation or other symptoms occur get medical
attention. Wash contaminated clothing and clean shoes before reuse. Any injection injury
from high pressure equipment should be evaluated immediately by a physician as
potentially serious (See NOTES TO PHYSICIAN).

Eye Contact: Flush immediately with large amounts of water for at least 15 minutes. Eyelids should be
held away from the eyeball to ensure thorough rinsing. Gently remove contacts while
flushing. Get medical attention if irritation persists.

Ingestion: Rinse mouth out with water. If spontaneous vomiting occurs, keep head below hips, or if
patient is lying down, turn body and head to side to prevent aspiration and monitor for
breathing difficulty. Never give anything by mouth to an unconscious person. Keep affected
person warm and at rest. If symptoms develop, seek medical attention.

Most important signs and symptoms, both short-term and delayed with overexposure

Adverse Effects: Preexisting skin conditions and/or respiratory disorders may be aggravated by exposure to
this product.

Indication of any immediate medical attention and special treatment needed

Notes To Physician: SKIN: Leaks or accidents involving high-pressure equipment may inject a stream of material
through the skin and initially produce an injury that may not appear serious. Only a small

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puncture wound may appear on the skin surface but, without proper treatment and
depending on the nature, original pressure, volume, and location of the injected material,
can compromise blood supply to an affected body part. Prompt surgical debridement of the
wound may be necessary to prevent irreversible loss of function and/or the affected body
part. High pressure injection injuries may be SERIOUS SURGICAL EMERGENCIES.

5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
For small fires, Class B fire extinguishing media such as CO2, dry chemical, foam (AFFF/ATC) or water spray can be used. For
large fires, water spray, fog or foam (AFFF/ATC) can be used. Firefighting should be attempted only by those who are adequately
trained and equipped with proper protective equipment.

Unsuitable extinguishing media

Do not use a solid water stream as it may scatter and spread fire.

Specific hazards arising from the chemical

The product is not combustible per the OSHA Hazard Communication Standard, but will ignite and burn at temperatures exceeding
the flash point.

Hazardous combustion products

Smoke, carbon monoxide, and other products of incomplete combustion.

Explosion data
Sensitivity to Mechanical Impact No.
Sensitivity to Static Discharge No.

Special protective equipment and precautions for firefighters

Avoid using straight water streams. Water spray and foam (AFFF/ATC) must be applied carefully to avoid frothing and from as far a
distance as possible. Avoid excessive water spray application. Use water spray to cool exposed surfaces from as far a distance as
possible. Keep run-off water out of sewers and water sources.

Additional firefighting tactics

Not applicable.

NFPA Health 1 Flammability 1 Instability 0 Special Hazard -

6. ACCIDENTAL RELEASE MEASURES

Personal precautions: Keep public away. Isolate and evacuate area. Shut off source if safe to do so.

Protective equipment: Use personal protection measures as recommended in Section 8.

Emergency procedures: Advise authorities and National Response Center (800-424-8802) if the product has
entered a water course or sewer. Notify local health and pollution control agencies, if
appropriate.

Environmental precautions: Avoid release to the environment. Avoid subsoil penetration.

Methods and materials for Prevent further leakage or spillage if safe to do so.
containment:

Methods and materials for cleaning Use suitable absorbent materials such as vermiculite, sand, or clay to clean up residual
up: liquids. Recover and return free product to proper containers.

7. HANDLING AND STORAGE

Safe Handling Precautions: Avoid contact with skin, eyes and clothing. Do not swallow. Avoid breathing vapors or mists.

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Use good personal hygiene practices. Wash thoroughly after handling. Use personal
protection measures as recommended in Section 8. Do not cut, drill, grind or weld on empty
containers since explosive residues may remain. Refer to applicable EPA, OSHA, NFPA
and consistent state and local requirements.

High-pressure injection of any material through the skin is a serious medical emergency
even though the small entrance wound at the injection site may not initially appear serious.
These injection injuries can occur from high-pressure equipment such as paint spray or
grease or guns, fuel injectors, or pinhole leaks in hoses or hydraulic lines and should all be
considered serious. High pressure injection injuries may be SERIOUS SURGICAL
EMERGENCIES (See First Aid Section 4).

Storage Conditions: Store in properly closed containers that are appropriately labeled and in a cool,
well-ventilated area. Containers that have been opened must be carefully resealed and kept
upright to prevent leakage. Store away from incompatible materials.

Incompatible Materials Strong oxidizing agents.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Name ACGIH TLV OSHA PELS: OSHA - Vacated PELs NIOSH IDLH
Solvent Refined, Hydrotreated Mineral oil, highly/severely - - -
Heavy Paraffinic Distillate refined, inhalable fraction
64742-54-7 5 mg/m3 TWA
2,6-di-tert-butylphenol - - - -
128-39-2
Notes: The manufacturer has voluntarily elected to provide exposure limits contained in OSHA's
1989 air contaminants standard in its SDSs, even though certain of those exposure limits
were vacated in 1992.

Engineering measures: Local or general exhaust required when using at elevated temperatures that generate
vapors or mists.

Personal protective equipment

Eye protection: Use goggles or face-shield if the potential for splashing exists.

Skin and body protection: Wear neoprene, nitrile or PVA gloves to prevent skin contact. Glove suitability is based on
workplace conditions and usage. Contact the glove manufacturer for specific advice on
glove selection and breakthrough times. Wear appropriate protective clothing.

Respiratory protection: Use a NIOSH approved organic vapor chemical cartridge or supplied air respirators when
there is the potential for airborne exposures to exceed permissible exposure limits or if
excessive vapors are generated. Observe respirator assigned protection factors (APFs)
criteria cited in federal OSHA 29 CFR 1910.134. Self-contained breathing apparatus should
be used for fire fighting.

Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes and clothing. Wash hands before breaks and immediately after handling the
product.

9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Physical State Liquid
Appearance Clear Liquid
Color Clear
Odor Petroleum
Odor Threshold No data available.

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Property Values (Method)

Melting Point / Freezing Point No data available.
Initial Boiling Point / Boiling Range No data available.
Flash Point > 220 °C / > 428 °F (Cleveland Open-Cup)
Evaporation Rate No data available.
Flammability (solid, gas) Not applicable.
Flammability Limit in Air (%):
Upper Flammability Limit: No data available.
Lower Flammability Limit: No data available.
Explosion limits: No data available.
Vapor Pressure No data available.
Vapor Density No data available.
Specific Gravity / Relative Density 0.88
Water Solubility No data available.
Solubility in other solvents No data available.
Partition Coefficient No data available.
Decomposition temperature No data available.
pH: No available data.
Autoignition Temperature No data available.
Kinematic Viscosity ≥ 28.8 mm2/s @ 40°C / 104°F (ASTM D445)
Dynamic Viscosity No data available.
Explosive Properties No data available.
VOC Content (%) 0.12-37.7 (w/w)
Density No data available.
Bulk Density Not applicable.

10. STABILITY AND REACTIVITY

Reactivity The product is non-reactive under normal conditions.

Chemical stability Stable under recommended storage conditions.

Possibility of hazardous reactions None under normal processing.

Hazardous polymerization Will not occur.

Conditions to avoid Sources of heat or ignition.

Incompatible Materials Strong oxidizing agents.

Hazardous decomposition products None known under normal conditions of use.

11. TOXICOLOGICAL INFORMATION

Potential short-term adverse effects from overexposures

Inhalation Overheating may produce vapors which may cause respiratory irritation, dizziness and
nausea.

Eye contact Exposure to vapor or contact with liquid may cause mild eye irritation, including tearing,
stinging, and redness.

Skin contact Prolonged or repeated exposure may cause dermatitis, folliculitis or oil acne.

Ingestion May cause irritation of the mouth, throat and gastrointestinal tract.

Acute toxicological data

Name Oral LD50 Dermal LD50 Inhalation LC50

Solvent Refined, Hydrotreated > 5000 mg/kg (Rat) > 2000 mg/kg (Rabbit) > 5.5 mg/l (Rat) 4 h

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Heavy Paraffinic Distillate

64742-54-7
2,6-di-tert-butylphenol > 5000 mg/kg (Rat) > 10 g/kg (Rabbit) -
128-39-2

Delayed and immediate effects as well as chronic effects from short and long-term exposure

This product is considered to have a low order of acute and chronic oral and dermal toxicity.

Adverse effects related to the physical, chemical and toxicological characteristics

Signs and Symptoms Repeated or prolonged skin contact may cause drying, reddening, itching and cracking.

Sensitization Not expected to be a skin or respiratory sensitizer.

Mutagenic effects None known.

Carcinogenicity Cancer designations are listed in the table below

Name ACGIH IARC NTP OSHA
(Class) (Class)
Solvent Refined, Mineral oil, poorly/mildly Mineral oil, untreated or Mineral oil, poorly/mildly Not Listed
Hydrotreated Heavy refined mildly treated refined
Paraffinic Distillate Suspected Human Carcinogenic to humans (1) Known to be human
64742-54-7 Carcinogen (A2) Mineral oil, highly refined carcinogen
Mineral oil, highly/severely Not Classifiable (3)
refined, inhalable fraction
Not Classifiable (A4)
2,6-di-tert-butylphenol Not Listed Not Listed Not Listed Not Listed
128-39-2

Reproductive toxicity None known.

Specific Target Organ Toxicity Not classified.

(STOT) - single exposure

Specific Target Organ Toxicity Not classified.

(STOT) - repeated exposure

Aspiration hazard Not classified.

12. ECOLOGICAL INFORMATION

Ecotoxicity Harmful to aquatic life with long lasting effects.

Name Algae/aquatic plants Fish Toxicity to Crustacea

Microorganisms
Solvent Refined, - 96-hr LC50 = 5000 mg/L - 48-hr EC50 = 1000 mg/L
Hydrotreated Heavy Rainbow trout Daphnia magna
Paraffinic Distillate
64742-54-7
2,6-di-tert-butylphenol - - - 48-hr EC50 = 0.45 mg/l
128-39-2 Daphnia magna

Persistence and degradability No information available.

Bioaccumulation Contains component(s) with the potential to bioaccumulate.

Mobility in soil No information available.

Other adverse effects No information available.

13. DISPOSAL CONSIDERATIONS

SDS ID NO.: 0298MAR019 Product name: Marathon Petroleum Premium AW II Hydraulic Oil Page 6 of 9
0298MAR019 Marathon Petroleum Premium AW II Revision Date 05/22/2015
Hydraulic Oil
_____________________________________________________________________________________________

Description of Waste Residues

No information available.

Safe Handling of Wastes

Handle in accordance with applicable local, state, and federal regulations. Use personal protection measures as required.

Disposal of Wastes / Methods of Disposal

The user is responsible for determining if any discarded material is a hazardous waste (40 CFR 262.11). Dispose of in accordance
with federal, state and local regulations.

Methods of Contaminated Packaging Disposal

Empty containers should be completely drained and then discarded or recycled, if possible. Do not cut, drill, grind or weld on empty
containers since explosive residues may be present. Dispose of in accordance with federal, state and local regulations.

14. TRANSPORT INFORMATION

DOT (49 CFR 172.101):
UN Proper Shipping Name: Not Regulated
UN/Identification No: Not applicable
Class: Not applicable.
Packing Group: Not applicable.

TDG (Canada):
UN Proper Shipping Name: Not Regulated
UN/Identification No: Not applicable.
Transport Hazard Class(es): Not applicable.
Packing Group: Not applicable.

15. REGULATORY INFORMATION

US Federal Regulatory Information:

US TSCA Chemical Inventory Section 8(b): This product and/or its components are listed on the TSCA
Chemical Inventory.

EPA Superfund Amendment & Reauthorization Act (SARA):

SARA Section 302: This product may contain component(s) that have been listed on EPA's Extremely
Hazardous Substance (EHS) List:
Name CERCLA/SARA - Section 302 Extremely Hazardous
Substances and TPQs
Solvent Refined, Hydrotreated Heavy Paraffinic Distillate NA
2,6-di-tert-butylphenol NA

SARA Section 304: This product may contain component(s) identified either as an EHS or a CERCLA
Hazardous substance which in case of a spill or release may be subject to SARA reporting
requirements:
Name Hazardous Substances RQs
Solvent Refined, Hydrotreated Heavy Paraffinic Distillate NA
2,6-di-tert-butylphenol NA

SARA Section 311/312: The following EPA hazard categories apply to this product:

None

SARA Section 313: This product may contain component(s), which if in exceedance of the de minimus
threshold, may be subject to the reporting requirements of SARA Title III Section 313 Toxic
Release Reporting (Form R).

SDS ID NO.: 0298MAR019 Product name: Marathon Petroleum Premium AW II Hydraulic Oil Page 7 of 9
0298MAR019 Marathon Petroleum Premium AW II Revision Date 05/22/2015
Hydraulic Oil
_____________________________________________________________________________________________

Name CERCLA/SARA 313 Emission reporting:

Solvent Refined, Hydrotreated Heavy Paraffinic Distillate None
2,6-di-tert-butylphenol None

State and Community Right-To-Know Regulations:

The following component(s) of this material are identified on the regulatory lists below:

Solvent Refined, Hydrotreated Heavy Paraffinic Distillate

Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: Not Listed
Pennsylvania Right-To-Know: Not Listed
Massachusetts Right-To Know: Not Listed
Florida Substance List: Not Listed
Rhode Island Right-To-Know: Not Listed
Michigan Critical Materials Register List: Not Listed
Massachusetts Extraordinarily Hazardous Substances: Not Listed
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Carcinogen
New Jersey - Environmental Hazardous Not Listed
Substances List:
Illinois - Toxic Air Contaminants: Present
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:
2,6-di-tert-butylphenol
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: Not Listed
Pennsylvania Right-To-Know: Not Listed
Massachusetts Right-To Know: Not Listed
Florida Substance List: Not Listed
Rhode Island Right-To-Know: Not Listed
Michigan Critical Materials Register List: Not Listed
Massachusetts Extraordinarily Hazardous Substances: Not Listed
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Not Listed
Substances List:
Illinois - Toxic Air Contaminants: Not Listed
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:

Canada DSL/NDSL Inventory: This product and/or its components are listed either on the Domestic Substances List (DSL)
or are exempt.

Canadian Regulatory Information: This product has been classified in accordance with the hazard criteria of the Controlled
Products Regulations and the SDS contains all of the information required by those
regulations.

Name Canada - WHMIS: Classifications of Canada - WHMIS: Ingredient

Substances: Disclosure:
2,6-di-tert-butylphenol D2B 1%

Note: Uncontrolled product according to WHMIS classification criteria.

SDS ID NO.: 0298MAR019 Product name: Marathon Petroleum Premium AW II Hydraulic Oil Page 8 of 9
0298MAR019 Marathon Petroleum Premium AW II Revision Date 05/22/2015
Hydraulic Oil
_____________________________________________________________________________________________

16. OTHER INFORMATION

Prepared By Toxicology and Product Safety

Revision Notes

Revision Date 05/22/2015

Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information is intended as guidance for safe handling, use, processing, storage,
transportation, accidental release, clean-up and disposal and is not considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text.

SDS ID NO.: 0298MAR019 Product name: Marathon Petroleum Premium AW II Hydraulic Oil Page 9 of 9
Oatey 95/5 Lead Free Plumbing Solder
Oatey Co.
Version No: 1.2 Issue Date: 11/23/2020
Safety Data Sheet according to OSHA HazCom Standard (2012) requirements Print Date: 11/25/2020
S.GHS.USA.EN

SECTION 1 Identification

Product Identifier
Product name Oatey 95/5 Lead Free Plumbing Solder

Chemical Name Not Applicable

Synonyms Not Available

Other means of 22004, 22018, 22025, 22017, 53026, 53181, 53027, 53189, 53171, 53173, 53175,53177, 53190, 29031, 53170, 53172, 53174,
identification 53176

Recommended use of the chemical and restrictions on use

Relevant identified uses Joining Copper Pipes. Joining Copper Tubing.

Name, address, and telephone number of the chemical manufacturer, importer, or other responsible party
Registered company name Oatey Co.

Address 20600 Emerald Parkway, Cleveland, OH 44135 United States

Telephone 216-267-7100

Fax Not Available

Website oatey.com

Email [email protected]

Emergency phone number

Association / Organisation Chemtrec
Emergency telephone
1-800-424-9300 (Outside the US 1-703-527-3887)
numbers
Other emergency
1-877-740-5015 (Emergency First Aid)
telephone numbers

SECTION 2 Hazard(s) identification

Classification of the substance or mixture

Classification Not Applicable

Label elements

Hazard pictogram(s) Not Applicable

Signal word Not Applicable

Hazard statement(s)
Not Applicable

Hazard(s) not otherwise classified

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Oatey 95/5 Lead Free Plumbing Solder

Not Applicable

Precautionary statement(s) Prevention

Not Applicable

Precautionary statement(s) Response

Not Applicable

Precautionary statement(s) Storage

Not Applicable

Precautionary statement(s) Disposal

Not Applicable

SECTION 3 Composition / information on ingredients

Substances
See section below for composition of Mixtures

Mixtures
CAS No %[weight] Name

7440-31-5 94.5-95.5 tin

7440-36-0* 4.5-5.5 antimony

SECTION 4 First-aid measures

Description of first aid measures

If this product comes in contact with the eyes:

Wash out immediately with fresh running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally
Eye Contact
lifting the upper and lower lids.
Seek medical attention without delay; if pain persists or recurs seek medical attention.
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

If skin or hair contact occurs:

Skin Contact Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.

If dust is inhaled, remove from contaminated area.

Encourage patient to blow nose to ensure clear breathing passages.
Inhalation
Ask patient to rinse mouth with water but to not drink water.
Seek immediate medical attention.

IF SWALLOWED, REFER FOR MEDICAL ATTENTION, WHERE POSSIBLE, WITHOUT DELAY.

For advice, contact a Poisons Information Centre or a doctor.
Urgent hospital treatment is likely to be needed.
In the mean time, qualified first-aid personnel should treat the patient following observation and employing supportive
measures as indicated by the patient's condition.
If the services of a medical officer or medical doctor are readily available, the patient should be placed in his/her care and a
copy of the SDS should be provided. Further action will be the responsibility of the medical specialist.
If medical attention is not available on the worksite or surroundings send the patient to a hospital together with a copy of the
Ingestion SDS.

Where medical attention is not immediately available or where the patient is more than 15 minutes from a hospital or
unless instructed otherwise:
INDUCE vomiting with fingers down the back of the throat, ONLY IF CONSCIOUS. Lean patient forward or place on left side
(head-down position, if possible) to maintain open airway and prevent aspiration.
NOTE: Wear a protective glove when inducing vomiting by mechanical means.

Most important symptoms and effects, both acute and delayed

See Section 11

Indication of any immediate medical attention and special treatment needed

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Treat symptomatically.

SECTION 5 Fire-fighting measures

Extinguishing media
DO NOT use halogenated fire extinguishing agents.
Metal dust fires need to be smothered with sand, inert dry powders.
DO NOTUSE WATER, CO2 or FOAM.
Use DRY sand, graphite powder, dry sodium chloride based extinguishers, G-1 or Met L-X to smother fire.
Confining or smothering material is preferable to applying water as chemical reaction may produce flammable and explosive hydrogen gas.
Chemical reaction with CO2 may produce flammable and explosive methane.
If impossible to extinguish, withdraw, protect surroundings and allow fire to burn itself out.

Special hazards arising from the substrate or mixture

Fire Incompatibility Reacts with acids producing flammable / explosive hydrogen (H2) gas

Special protective equipment and precautions for fire-fighters

Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus plus protective gloves in the event of a fire.
Prevent, by any means available, spillage from entering drains or water courses.
Use fire fighting procedures suitable for surrounding area.
Fire Fighting
DO NOT approach containers suspected to be hot.
Cool fire exposed containers with water spray from a protected location.
If safe to do so, remove containers from path of fire.
Equipment should be thoroughly decontaminated after use.

DO NOTdisturb burning dust. Explosion may result if dust is stirred into a cloud, by providing oxygen to a large surface of hot
metal.
DO NOT use water or foam as generation of explosive hydrogen may result.
With the exception of the metals that burn in contact with air or water (for example, sodium), masses of combustible metals do
not represent unusual fire risks because they have the ability to conduct heat away from hot spots so efficiently that the heat of
combustion cannot be maintained - this means that it will require a lot of heat to ignite a mass of combustible metal. Generally,
metal fire risks exist when sawdust, machine shavings and other metal 'fines' are present.
Metal powders, while generally regarded as non-combustible:
May burn when metal is finely divided and energy input is high.
May react explosively with water.
May be ignited by friction, heat, sparks or flame.
Fire/Explosion Hazard May REIGNITE after fire is extinguished.
Will burn with intense heat.
Note:
Metal dust fires are slow moving but intense and difficult to extinguish.
Containers may explode on heating.
Dusts or fumes may form explosive mixtures with air.
Gases generated in fire may be poisonous, corrosive or irritating.
Hot or burning metals may react violently upon contact with other materials, such as oxidising agents and extinguishing
agents used on fires involving ordinary combustibles or flammable liquids.
Temperatures produced by burning metals can be higher than temperatures generated by burning flammable liquids
Some metals can continue to burn in carbon dioxide, nitrogen, water, or steam atmospheres in which ordinary combustibles
or flammable liquids would be incapable of burning.

SECTION 6 Accidental release measures

Personal precautions, protective equipment and emergency procedures

See section 8

Environmental precautions
See section 12

Methods and material for containment and cleaning up

Clean up all spills immediately.

Avoid contact with skin and eyes.
Minor Spills Control personal contact with the substance, by using protective equipment.
Use dry clean up procedures and avoid generating dust.
Place in a suitable, labelled container for waste disposal.

Continued...
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· Do not use compressed air to remove metal dusts from floors, beams or equipment
· Vacuum cleaners, of flame-proof design, should be used to minimise dust accumulation.
· Use non-sparking handling equipment, tools and natural bristle brushes.
Major Spills · Provide grounding and bonding where necessary to prevent accumulation of static charges during metal dust handling and
transfer operations
· Cover and reseal partially empty containers.
· Do not allow chips, fines or dusts to contact water, particularly in enclosed areas.

Personal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 Handling and storage

Precautions for safe handling

Develop work practices and procedures that prevent particulate from coming in contact with worker skin, hair, or personal
clothing.
If work practices and/or procedures are ineffective in controlling airborne exposure or visual particulate from deposition on
skin, hair, or clothing, provide appropriate cleaning/washing facilities.
Procedures should be written that clearly communicate the facility's requirements for protective clothing and personal
hygiene. These clothing and personal hygiene requirements help keep particulate from being spread to non-production areas
or from being taken home by the worker.
Never use compressed air to clean work clothing or other surfaces.
Fabrication processes may leave a residue of particulate on the surface of parts, products or equipment that could result in
employee exposure during subsequent material handling activities.
As necessary, clean loose particulate from parts between processing steps. As a standard hygiene practice, wash hands
Safe handling
before eating or smoking.
To prevent exposure, remove surface scale or oxidation formed on cast or heat treated products in an adequately ventilated
process prior to working the surface.
Exposure to elements found in the metal, its alloys or recycled materials, may result as a result of inhalation, ingestion, and
skin contact, when melting, casting, dross handling, pickling, chemical cleaning, heat treating, abrasive cutting, welding,
grinding, sanding, polishing, milling, crushing, or otherwise heating or abrading the surface of this material in a manner which
generates particulates.
Exposure may also occur during repair or maintenance activities on contaminated equipment such as: furnace rebuilding,
maintenance or repair of air cleaning equipment, structural renovation, welding, etc.
Particulate depositing on hands, gloves, and clothing, can be transferred to the breathing zone and inhaled during normal
hand to face motions such as rubbing of the nose or eyes, sneezing, coughing, etc.

Store in original containers.

Keep containers securely sealed.
Store in a cool, dry area protected from environmental extremes.
Store away from incompatible materials and foodstuff containers.
Protect containers against physical damage and check regularly for leaks.
Other information Observe manufacturer's storage and handling recommendations contained within this SDS.
For major quantities:
Consider storage in bunded areas - ensure storage areas are isolated from sources of community water (including
stormwater, ground water, lakes and streams}.
Ensure that accidental discharge to air or water is the subject of a contingency disaster management plan; this may require
consultation with local authorities.

Conditions for safe storage, including any incompatibilities

Bulk bags: Reinforced bags required for dense materials.

CARE: Packing of high density product in light weight metal or plastic packages may result in container collapse with product
Suitable container
release
Heavy gauge metal packages / Heavy gauge metal drums

Storage incompatibility Many metals may incandesce, react violently, ignite or react explosively upon addition of concentrated nitric acid.

SECTION 8 Exposure controls / personal protection

Control parameters

Occupational Exposure Limits (OEL)

INGREDIENT DATA

Source Ingredient Material name TWA STEL Peak Notes

US NIOSH Recommended Metallic tin, Tin flake, Tin metal, Tin 2 Not Not [*Note: The REL also applies to
tin
Exposure Limits (RELs) powder mg/m3 Available Available other inorganic tin compounds (as

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Oatey 95/5 Lead Free Plumbing Solder

Source Ingredient Material name TWA STEL Peak Notes

Sn) except tin oxides.]
Tin and inorganic compounds,
US ACGIH Threshold Limit excluding Tin hydride and Indium 2 Not Not
tin Pneumoconiosis
Values (TLV) tin oxide, as Sn (Inhalable mg/m3 Available Available
particulate matter)
[*Note: The REL also applies to
US NIOSH Recommended Antimony metal, Antimony powder, 0.5 Not Not
antimony other antimony compounds (as
Exposure Limits (RELs) Stibium mg/m3 Available Available
Sb).]

US OSHA Permissible
0.5 Not Not
Exposure Levels (PELs) - antimony Antimony and compounds (as Sb) Not Available
mg/m3 Available Available
Table Z1
US ACGIH Threshold Limit 0.5 Not Not
antimony Antimony and compounds, as Sb Skin & URT irr
Values (TLV) mg/m3 Available Available

Exposure controls

Metal dusts must be collected at the source of generation as they are potentially explosive.
Avoid ignition sources.
Good housekeeping practices must be maintained.
Dust accumulation on the floor, ledges and beams can present a risk of ignition, flame propagation and secondary
explosions.
Do not use compressed air to remove settled materials from floors, beams or equipment
Vacuum cleaners, of flame-proof design, should be used to minimise dust accumulation.
Use non-sparking handling equipment, tools and natural bristle brushes. Cover and reseal partially empty containers. Provide
grounding and bonding where necessary to prevent accumulation of static charges during metal dust handling and transfer
operations.
Do not allow chips, fines or dusts to contact water, particularly in enclosed areas.
Metal spraying and blasting should, where possible, be conducted in separate rooms. This minimises the risk of supplying
oxygen, in the form of metal oxides, to potentially reactive finely divided metals such as aluminium, zinc, magnesium or
titanium.
Work-shops designed for metal spraying should possess smooth walls and a minimum of obstructions, such as ledges, on
which dust accumulation is possible.
Wet scrubbers are preferable to dry dust collectors.
Bag or filter-type collectors should be sited outside the workrooms and be fitted with explosion relief doors.
Cyclones should be protected against entry of moisture as reactive metal dusts are capable of spontaneous combustion in
humid or partially wetted states.
Local exhaust systems must be designed to provide a minimum capture velocity at the fume source, away from the worker, of
0.5 metre/sec.
Local ventilation and vacuum systems must be designed to handle explosive dusts. Dry vacuum and electrostatic
Appropriate engineering precipitators must not be used, unless specifically approved for use with flammable/ explosive dusts.
controls
Air contaminants generated in the workplace possess varying 'escape' velocities which, in turn, determine the 'capture velocities'
of fresh circulating air required to effectively remove the contaminant.

Type of Contaminant: Air Speed:

welding, brazing fumes (released at relatively low velocity into moderately still air) 0.5-1.0 m/s (100-200 f/min.)

Within each range the appropriate value depends on:

Lower end of the range Upper end of the range

1: Room air currents minimal or favourable to capture 1: Disturbing room air currents

2: Contaminants of low toxicity or of nuisance value only. 2: Contaminants of high toxicity

3: Intermittent, low production. 3: High production, heavy use

4: Large hood or large air mass in motion 4: Small hood-local control only

Simple theory shows that air velocity falls rapidly with distance away from the opening of a simple extraction pipe. Velocity
generally decreases with the square of distance from the extraction point (in simple cases). Therefore the air speed at the
extraction point should be adjusted, accordingly, after reference to distance from the contaminating source. The air velocity at
the extraction fan, for example, should be a minimum of 1-2.5 m/s (200-500 f/min.) for extraction of gases discharged 2 meters
distant from the extraction point. Other mechanical considerations, producing performance deficits within the extraction
apparatus, make it essential that theoretical air velocities are multiplied by factors of 10 or more when extraction systems are
installed or used.

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Personal protection

Safety glasses with side shields

Chemical goggles.
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy
document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task. This should
Eye and face protection include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience.
Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the
event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should
be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers
have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 or national equivalent]

Skin protection See Hand protection below

Protective gloves eg. Leather gloves or gloves with Leather facing

Experience indicates that the following polymers are suitable as glove materials for protection against undissolved, dry solids,
where abrasive particles are not present.
polychloroprene.
Hands/feet protection nitrile rubber.
butyl rubber.
fluorocaoutchouc.
polyvinyl chloride.
Gloves should be examined for wear and/ or degradation constantly.

Body protection See Other protection below

Overalls.
P.V.C apron.
Other protection Barrier cream.
Skin cleansing cream.
Eye wash unit.

Respiratory protection
Particulate. (AS/NZS 1716 & 1715, EN 143:2000 & 149:001, ANSI Z88 or national equivalent)

Respirators may be necessary when engineering and administrative controls do not adequately prevent exposures.
The decision to use respiratory protection should be based on professional judgment that takes into account toxicity information, exposure
measurement data, and frequency and likelihood of the worker's exposure - ensure users are not subject to high thermal loads which may result in
heat stress or distress due to personal protective equipment (powered, positive flow, full face apparatus may be an option).
Published occupational exposure limits, where they exist, will assist in determining the adequacy of the selected respiratory protection. These may
be government mandated or vendor recommended.
Certified respirators will be useful for protecting workers from inhalation of particulates when properly selected and fit tested as part of a complete
respiratory protection program.
Use approved positive flow mask if significant quantities of dust becomes airborne.
Try to avoid creating dust conditions.

SECTION 9 Physical and chemical properties

Information on basic physical and chemical properties

Appearance Silver wire

Relative density (Water =

Physical state Solid 9 - 11
1)
Partition coefficient
Odour Not Available Not Available
n-octanol / water
Auto-ignition temperature
Odour threshold Not Available Not Available
(°C)
Decomposition
pH (as supplied) Not Available Not Available
temperature
Melting point / freezing
232.22 - 240 Viscosity (cSt) Not Available
point (°C)

Initial boiling point and

Not Available Molecular weight (g/mol) Not Available
boiling range (°C)

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Flash point (°C) Not Available Taste Not Available

Evaporation rate Not Available Explosive properties Not Available

Flammability Not Available Oxidising properties Not Available
Surface Tension (dyn/cm
Upper Explosive Limit (%) Not Available Not Applicable
or mN/m)
Lower Explosive Limit (%) Not Available Volatile Component (%vol) Not Available

Vapour pressure (kPa) Not Available Gas group Not Available

Solubility in water Immiscible pH as a solution (1%) Not Available

Vapour density (Air = 1) Not Available VOC (weight %) 0

SECTION 10 Stability and reactivity

Reactivity Not reactive under normal conditions of use.

Unstable in the presence of incompatible materials.

Chemical stability Product is considered stable.
Hazardous polymerisation will not occur.

Possibility of hazardous
No dangerous reaction known under conditions of normal use.
reactions

Conditions to avoid Contact with incompatible materials.

Acids.
Incompatible materials Strong oxidizing agents.
Chlorine.

Hazardous decomposition
No hazardous decomposition products are known.
products

SECTION 11 Toxicological information

Information on toxicological effects

The material is not thought to produce either adverse health effects or irritation of the respiratory tract following inhalation.
Nevertheless, adverse systemic effects have been produced following exposure of animals by at least one other route and good
Inhaled
hygiene practice requires that exposure be kept to a minimum and that suitable control measures be used in an occupational
setting.

Ingestion Expected to be a low ingestion hazard.

Skin contact is not thought to produce harmful health effects. Systemic harm, however, has been identified following exposure of
Skin Contact animals by at least one other route and the material may still produce health damage following entry through wounds, lesions or
abrasions.

Although the material is not thought to be an irritant, direct contact with the eye may cause transient discomfort characterised by
Eye
tearing or conjunctival redness (as with windburn). Slight abrasive damage may also result.

Long-term exposure to the product is not thought to produce chronic effects adverse to the health; nevertheless exposure by all
routes should be minimized as a matter of course.
Chronic
Metallic dusts generated by the industrial process give rise to a number of potential health problems. The larger particles, above
5 micron, are nose and throat irritants.

Acute Toxicity Carcinogenicity

Skin Irritation/Corrosion Reproductivity

Serious Eye
STOT - Single Exposure
Damage/Irritation
Respiratory or Skin
STOT - Repeated Exposure
sensitisation

Mutagenicity Aspiration Hazard

Legend: – Data either not available or does not fill the criteria for classification
– Data available to make classification

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Oatey 95/5 Lead Free Plumbing Solder

SECTION 12 Ecological information

Toxicity

Oatey 95/5 Lead Free Endpoint Test Duration (hr) Species Value Source
Plumbing Solder Not Available Not Available Not Available Not Available Not Available

Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity
3. EPIWIN Suite V3.12 (QSAR) - Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5.
ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8.
Vendor Data

DO NOTdischarge into sewer or waterways.

Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air
No Data available for all ingredients No Data available for all ingredients

Bioaccumulative potential
Ingredient Bioaccumulation

No Data available for all ingredients

Mobility in soil
Ingredient Mobility
No Data available for all ingredients

SECTION 13 Disposal considerations

Waste treatment methods

· Recycle wherever possible or consult manufacturer for recycling options.

· Consult State Land Waste Management Authority for disposal.
Product / Packaging DO NOTallow wash water from cleaning or process equipment to enter drains.
disposal It may be necessary to collect all wash water for treatment before disposal.
In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.
Where in doubt contact the responsible authority.

SECTION 14 Transport information

Labels Required
Marine Pollutant NO

Land transport (DOT): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Transport in bulk according to Annex II of MARPOL and the IBC code

Not Applicable

SECTION 15 Regulatory information

Safety, health and environmental regulations / legislation specific for the substance or mixture

tin is found on the following regulatory lists

US ACGIH Threshold Limit Values (TLV) US NIOSH Recommended Exposure Limits (RELs)
US AIHA Workplace Environmental Exposure Levels (WEELs) US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory
US DOE Temporary Emergency Exposure Limits (TEELs) US TSCA Chemical Substance Inventory - Interim List of Active Substances

Continued...
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Oatey 95/5 Lead Free Plumbing Solder

antimony is found on the following regulatory lists

Chemical Footprint Project - Chemicals of High Concern List US EPA Integrated Risk Information System (IRIS)
US ACGIH Threshold Limit Values (TLV) US EPCRA Section 313 Chemical List
US AIHA Workplace Environmental Exposure Levels (WEELs) US NIOSH Recommended Exposure Limits (RELs)
US ATSDR Minimal Risk Levels for Hazardous Substances (MRLs) US OSHA Permissible Exposure Levels (PELs) - Table Z1
US Clean Air Act - Hazardous Air Pollutants US OSHA Permissible Exposure Limits - Annotated Table Z-1
US CWA (Clean Water Act) - Priority Pollutants US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory
US CWA (Clean Water Act) - Toxic Pollutants US TSCA Chemical Substance Inventory - Interim List of Active Substances
US DOE Temporary Emergency Exposure Limits (TEELs)

Federal Regulations

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Section 311/312 hazard categories

Flammable (Gases, Aerosols, Liquids, or Solids) No

Gas under pressure No

Explosive No
Self-heating No
Pyrophoric (Liquid or Solid) No
Pyrophoric Gas No

Corrosive to metal No
Oxidizer (Liquid, Solid or Gas) No
Organic Peroxide No

Self-reactive No
In contact with water emits flammable gas No

Combustible Dust No
Carcinogenicity No
Acute toxicity (any route of exposure) No

Reproductive toxicity No
Skin Corrosion or Irritation No
Respiratory or Skin Sensitization No

Serious eye damage or eye irritation No

Specific target organ toxicity (single or repeated exposure) No

Aspiration Hazard No

Germ cell mutagenicity No

Simple Asphyxiant No

Hazards Not Otherwise Classified No

US. EPA CERCLA Hazardous Substances and Reportable Quantities (40 CFR 302.4)

Name Reportable Quantity in Pounds (lb) Reportable Quantity in kg

Antimony 5000 2270

State Regulations

US. California Proposition 65

None Reported

National Inventory Status

National Inventory Status
USA - TSCA Yes

Yes = All CAS declared ingredients are on the inventory

Legend: No = One or more of the CAS listed ingredients are not on the inventory and are not exempt from listing(see specific ingredients
in brackets)

SECTION 16 Other information

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Oatey 95/5 Lead Free Plumbing Solder

Initial Date 11/15/2020

Other information
The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks
in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available
engineering controls must be considered.

Definitions and abbreviations

PC－TWA: Permissible Concentration-Time Weighted Average
PC－STEL: Permissible Concentration-Short Term Exposure Limit
IARC: International Agency for Research on Cancer
ACGIH: American Conference of Governmental Industrial Hygienists
STEL: Short Term Exposure Limit
TEEL: Temporary Emergency Exposure Limit。
IDLH: Immediately Dangerous to Life or Health Concentrations
OSF: Odour Safety Factor
NOAEL :No Observed Adverse Effect Level
LOAEL: Lowest Observed Adverse Effect Level
TLV: Threshold Limit Value
LOD: Limit Of Detection
OTV: Odour Threshold Value
BCF: BioConcentration Factors
BEI: Biological Exposure Index

end of SDS
 SAFETY DATA SHEET

1. Identification
Product identifier Oatey CPVC Flowguard Gold UVI One-Step Yellow Cement
Other means of identification
Product code 1203E
Synonyms Part Numbers: 31910(TV), 31911(TV), 31912, 31913, 31914, 31656, 31657, 32200, 32201, 32202,
32203, 31660, 31661, 31662, 31663, 31917, 31918, 31919, 31920
Recommended use Joining CPVC Pipes
Recommended restrictions None known.
Manufacturer/Importer/Supplier/Distributor information
Company Name Oatey Co.
Address 4700 West 160th St.
Cleveland, OH 44135

Telephone 216-267-7100
E-mail [email protected]
Transport Emergency Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887)
Emergency First Aid 1-877-740-5015
Contact person MSDS Coordinator

2. Hazard(s) identification
Physical hazards Flammable liquids Category 2

Health hazards Acute toxicity, oral Category 4

Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2A
Specific target organ toxicity, single exposure Category 3 respiratory tract irritation
Specific target organ toxicity, single exposure Category 3 narcotic effects
Aspiration hazard Category 1
OSHA defined hazards Not classified.

Label elements

Signal word Danger

Hazard statement Highly flammable liquid and vapor. Harmful if swallowed. May be fatal if swallowed and enters
airways. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May
cause drowsiness or dizziness.
Precautionary statement
Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly
closed. Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Avoid breathing mist or vapor. Wash thoroughly after
handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a
well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection.

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 Response If swallowed: Immediately call a poison center/doctor. If on skin (or hair): Take off immediately all
contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and
keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison center/doctor if
you feel unwell. Rinse mouth. Do NOT induce vomiting. If skin irritation occurs: Get medical
advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated
clothing and wash before reuse. In case of fire: Use appropriate media to extinguish.
Storage Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis.
classified (HNOC) May form explosive peroxides. Contains a chemical classified by the US EPA as a suspected
possible carcinogen.
Supplemental information
Not applicable.

3. Composition/information on ingredients
Mixtures
Chemical name CAS number %
Furan, Tetrahydro- 109-99-9 30-60

Methyl ethyl ketone 78-93-3 10-30

Ethene, chloro-, homopolymer, 68648-82-8 10-20

chlorinated

Acetone 67-64-1 5-15

Cyclohexanone 108-94-1 5-15

Silica, amorphous, fumed 112945-52-5 1-5

*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.

4. First-aid measures
Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON
CENTER or doctor/physician if you feel unwell.
Skin contact Take off immediately all contaminated clothing. Wash with plenty of soap and water. If skin
irritation occurs: Get medical advice/attention.
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Ingestion Call a physician or poison control center immediately. Do not induce vomiting. If vomiting occurs,
keep head low so that stomach content doesn't get into the lungs. Aspiration may cause
pulmonary edema and pneumonitis.
Most important Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe eye
symptoms/effects, acute and irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May
delayed cause respiratory irritation. Vapors have a narcotic effect and may cause headache, fatigue,
dizziness and nausea. Skin irritation. May cause redness and pain.
Indication of immediate Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water
medical attention and special immediately. While flushing, remove clothes which do not adhere to affected area. Call an
treatment needed ambulance. Continue flushing during transport to hospital. In case of shortness of breath, give
oxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed.
General information Take off all contaminated clothing immediately. Ensure that medical personnel are aware of the
material(s) involved, and take precautions to protect themselves. Wash contaminated clothing
before reuse.

5. Fire-fighting measures
Suitable extinguishing media Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source
the chemical of ignition and flash back. During fire, gases hazardous to health may be formed.
Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
and precautions for firefighters
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Fire fighting In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do
equipment/instructions so without risk.
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards Highly flammable liquid and vapor. This product contains tetrahydrofuran that may form explosive
organic peroxide when exposed to air or light or with age.

6. Accidental release measures

Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
protective equipment and low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area).
emergency procedures Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or
vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective
clothing. Ventilate closed spaces before entering them. Local authorities should be advised if
significant spillages cannot be contained. For personal protection, see section 8 of the SDS.
Methods and materials for Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take
containment and cleaning up precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles
(wood, paper, oil, etc.) away from spilled material. This product is miscible in water.

Large Spills: Stop the flow of material, if this is without risk. Use water spray to reduce vapors or
divert vapor cloud drift. Dike the spilled material, where this is possible. Cover with plastic sheet to
prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the
product and place into a container for later disposal. Prevent entry into waterways, sewer,
basements or confined areas. Following product recovery, flush area with water.

Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers
for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Environmental precautions Avoid discharge into drains, water courses or onto the ground.

7. Handling and storage

Precautions for safe handling Vapors may form explosive mixtures with air. Do not handle, store or open near an open flame,
sources of heat or sources of ignition. Protect material from direct sunlight. Explosion-proof
general and local exhaust ventilation. Take precautionary measures against static discharges. All
equipment used when handling the product must be grounded. Use non-sparking tools and
explosion-proof equipment. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and
clothing. Avoid prolonged exposure. Do not taste or swallow. When using, do not eat, drink or
smoke. Wear appropriate personal protective equipment. Wash hands thoroughly after handling.
Observe good industrial hygiene practices.
Conditions for safe storage, Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge
including any incompatibilities build-up by using common bonding and grounding techniques. Store in a cool, dry place out of
direct sunlight. Store in original tightly closed container. Store in a well-ventilated place. Store
away from incompatible materials (see Section 10 of the SDS).

8. Exposure controls/personal protection

Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

Components Type Value

Acetone (CAS 67-64-1) PEL 2400 mg/m3
1000 ppm
Cyclohexanone (CAS PEL 200 mg/m3
108-94-1)
50 ppm
Furan, Tetrahydro- (CAS PEL 590 mg/m3
109-99-9)
200 ppm
Methyl ethyl ketone (CAS PEL 590 mg/m3
78-93-3)
200 ppm
US. OSHA Table Z-3 (29 CFR 1910.1000)

Components Type Value

Silica, amorphous, fumed TWA 0.8 mg/m3
(CAS 112945-52-5)
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 US. OSHA Table Z-3 (29 CFR 1910.1000)

Components Type Value

20 mppcf
US. ACGIH Threshold Limit Values

Components Type Value

Acetone (CAS 67-64-1) STEL 750 ppm
TWA 500 ppm
Cyclohexanone (CAS STEL 50 ppm
108-94-1)
TWA 20 ppm
Furan, Tetrahydro- (CAS STEL 100 ppm
109-99-9)
TWA 50 ppm
Methyl ethyl ketone (CAS STEL 300 ppm
78-93-3)
TWA 200 ppm
US. NIOSH: Pocket Guide to Chemical Hazards

Components Type Value

Acetone (CAS 67-64-1) TWA 590 mg/m3
250 ppm
Cyclohexanone (CAS TWA 100 mg/m3
108-94-1)
25 ppm
Furan, Tetrahydro- (CAS STEL 735 mg/m3
109-99-9)
250 ppm
TWA 590 mg/m3
200 ppm
Methyl ethyl ketone (CAS STEL 885 mg/m3
78-93-3)
300 ppm
TWA 590 mg/m3
200 ppm
Silica, amorphous, fumed TWA 6 mg/m3
(CAS 112945-52-5)
Biological limit values
ACGIH Biological Exposure Indices

Components Value Determinant Specimen Sampling Time

Acetone (CAS 67-64-1) 50 mg/l Acetone Urine *
Cyclohexanone (CAS 80 mg/l 1,2-Cyclohexan Urine *
108-94-1) ediol, with
hydrolysis
8 mg/l Cyclohexanol, Urine *
with hydrolysis
Furan, Tetrahydro- (CAS 2 mg/l Tetrahydrofura Urine *
109-99-9) n
Methyl ethyl ketone (CAS 2 mg/l MEK Urine *
78-93-3)
* - For sampling details, please see the source document.
Exposure guidelines
US - California OELs: Skin designation
Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin.
US - Minnesota Haz Subs: Skin designation applies
Cyclohexanone (CAS 108-94-1) Skin designation applies.

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 US - Tennessee OELs: Skin designation
Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin.
US ACGIH Threshold Limit Values: Skin designation
Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin.
Furan, Tetrahydro- (CAS 109-99-9) Can be absorbed through the skin.
US. NIOSH: Pocket Guide to Chemical Hazards
Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin.
Appropriate engineering Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 air
controls changes per hour) should be used. Ventilation rates should be matched to conditions. If
applicable, use process enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure limits have not been
established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency
shower must be available when handling this product.
Individual protection measures, such as personal protective equipment
Eye/face protection Face shield is recommended. Wear safety glasses with side shields (or goggles).
Skin protection
Hand protection Wear appropriate chemical resistant gloves.
Other Wear appropriate chemical resistant clothing.
Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such
considerations as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash
work clothing and protective equipment to remove contaminants.

9. Physical and chemical properties

Appearance
Physical state Liquid.
Form Translucent liquid.
Color Yellow / Gold
Odor Solvent.
Odor threshold Not available.
pH Not available.
Melting point/freezing point Not available.
Initial boiling point and boiling 151 °F (66.11 °C)
range
Flash point 14.0 - 23.0 °F (-10.0 - -5.0 °C)
Evaporation rate 5.5 - 8
Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower 1.8
(%)
Flammability limit - upper 11.8
(%)
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure 145 mm Hg @ 20 C
Vapor density 2.5
Relative density 0.94 +/- 0.02
Solubility(ies)
Solubility (water) Negligible
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature Not available.

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Decomposition temperature Not available.
Viscosity 500 - 1500 cP
Other information
Bulk density 7.8 lb/gal
VOC (Weight %) < 490 g/l SQACMD 1168/M316A

10. Stability and reactivity

Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous No dangerous reaction known under conditions of normal use.
reactions
Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the
flash point. Contact with incompatible materials.
Incompatible materials Acids. Strong oxidizing agents. Ammonia. Amines. Isocyanates. Caustics.
Hazardous decomposition No hazardous decomposition products are known.
products

11. Toxicological information

Information on likely routes of exposure
Inhalation May be fatal if swallowed and enters airways. Headache. Nausea, vomiting. May cause irritation
to the respiratory system. Vapors have a narcotic effect and may cause headache, fatigue,
dizziness and nausea. Prolonged inhalation may be harmful.
Skin contact Causes skin irritation.
Eye contact Causes serious eye irritation.
Ingestion May be fatal if swallowed and enters airways. Harmful if swallowed. Harmful if swallowed. Droplets
of the product aspirated into the lungs through ingestion or vomiting may cause a serious
chemical pneumonia.
Symptoms related to the Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe
physical, chemical and eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May
toxicological characteristics cause respiratory irritation. Skin irritation. May cause redness and pain. Symptoms of
overexposure may be headache, dizziness, tiredness, nausea and vomiting.
Information on toxicological effects
Acute toxicity May be fatal if swallowed and enters airways. Narcotic effects. May cause respiratory irritation.
Components Species Test Results
Acetone (CAS 67-64-1)
Acute
Dermal
LD50 Rabbit 20 ml/kg
Inhalation
LC50 Rat 50 mg/l, 8 Hours
Oral
LD50 Rat 5800 mg/kg
Cyclohexanone (CAS 108-94-1)
Acute
Dermal
LD50 Rabbit 948 mg/kg
Inhalation
LC50 Rat 8000 ppm, 4 hours
Oral
LD50 Rat 1540 mg/kg

* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation Causes skin irritation.
Serious eye damage/eye Causes serious eye irritation.
irritation
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Respiratory or skin sensitization
Respiratory sensitization Not available.
Skin sensitization This product is not expected to cause skin sensitization.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity In 2012 USEPA Integrated Risk Information System (IRIS) reviewed a two species inhalation
lifetime study on THF conducted by NTP (1998). Male rats developed renal tumors and female
mice developed liver tumors while neither the female rats nor the male mice showed similar
results. Because the carcinogenic mechanisms could not be identified clearly in either species for
either tumor, the EPA determined that the male rat and female mouse findings are relevant to the
assessment of carcinogenic potential in humans. Therefore, the IRIS review concludes that these
data in aggregate indicate that there is "suggestive evidence of carcinogenic potential" following
exposure to THF by all routes of exposure.
IARC Monographs. Overall Evaluation of Carcinogenicity
Cyclohexanone (CAS 108-94-1) 3 Not classifiable as to carcinogenicity to humans.
Silica, amorphous, fumed (CAS 112945-52-5) 3 Not classifiable as to carcinogenicity to humans.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity - Narcotic effects. May cause drowsiness and dizziness. Respiratory tract irritation.
single exposure
Specific target organ toxicity - Not classified.
repeated exposure
Aspiration hazard May be fatal if swallowed and enters airways.
Chronic effects Prolonged inhalation may be harmful.

12. Ecological information

Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Components Species Test Results
Acetone (CAS 67-64-1)
Aquatic
Fish LC50 Fathead minnow (Pimephales promelas) > 100 mg/l, 96 hours
Cyclohexanone (CAS 108-94-1)
Aquatic
Fish LC50 Fathead minnow (Pimephales promelas) 481 - 578 mg/l, 96 hours

* Estimates for product may be based on additional component data not shown.
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulative potential No data available.
Partition coefficient n-octanol / water (log Kow)
Acetone (CAS 67-64-1) -0.24
Cyclohexanone (CAS 108-94-1) 0.81
Furan, Tetrahydro- (CAS 109-99-9) 0.46
Methyl ethyl ketone (CAS 78-93-3) 0.29
Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations

Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material
and its container must be disposed of as hazardous waste. Do not allow this material to drain into
sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used
container. Dispose of contents/container in accordance with local/regional/national/international
regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
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Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some
products product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.

14. Transport information

DOT
UN number UN1133
UN proper shipping name Adhesives
Transport hazard class(es)
Class 3
Subsidiary risk -
Label(s) 3
Packing group II
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Special provisions T11, TP1, TP8, TP27
Packaging exceptions 150
Packaging non bulk 201
Packaging bulk 243
IATA
UN number UN1133
UN proper shipping name Adhesives
Transport hazard class(es)
Class 3
Subsidiary risk -
Packing group II
Environmental hazards No.
ERG Code 3L
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
IMDG
UN number UN1133
UN proper shipping name ADHESIVES
Transport hazard class(es)
Class 3
Subsidiary risk -
Packing group II
Environmental hazards
Marine pollutant No.
EmS F-E, S-D
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Transport in bulk according to Not available.
Annex II of MARPOL 73/78 and
the IBC Code

15. Regulatory information

US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Acetone (CAS 67-64-1) LISTED
Cyclohexanone (CAS 108-94-1) LISTED
Furan, Tetrahydro- (CAS 109-99-9) LISTED
Methyl ethyl ketone (CAS 78-93-3) LISTED

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Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - Yes
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous No
chemical
SARA 313 (TRI reporting)
Not regulated.

Other federal regulations

Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and
Chemical Code Number
Acetone (CAS 67-64-1) 6532
Methyl ethyl ketone (CAS 78-93-3) 6714
Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c))
Acetone (CAS 67-64-1) 35 %WV
Methyl ethyl ketone (CAS 78-93-3) 35 %WV
DEA Exempt Chemical Mixtures Code Number
Acetone (CAS 67-64-1) 6532
Methyl ethyl ketone (CAS 78-93-3) 6714
US state regulations
US. Massachusetts RTK - Substance List
Acetone (CAS 67-64-1)
Cyclohexanone (CAS 108-94-1)
Furan, Tetrahydro- (CAS 109-99-9)
Methyl ethyl ketone (CAS 78-93-3)
Silica, amorphous, fumed (CAS 112945-52-5)
US. New Jersey Worker and Community Right-to-Know Act
Acetone (CAS 67-64-1)
Cyclohexanone (CAS 108-94-1)
Furan, Tetrahydro- (CAS 109-99-9)
Methyl ethyl ketone (CAS 78-93-3)
US. Pennsylvania Worker and Community Right-to-Know Law
Acetone (CAS 67-64-1)
Cyclohexanone (CAS 108-94-1)
Furan, Tetrahydro- (CAS 109-99-9)
Methyl ethyl ketone (CAS 78-93-3)
Silica, amorphous, fumed (CAS 112945-52-5)
US. Rhode Island RTK
Acetone (CAS 67-64-1)
Cyclohexanone (CAS 108-94-1)
Furan, Tetrahydro- (CAS 109-99-9)
Methyl ethyl ketone (CAS 78-93-3)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Canada Domestic Substances List (DSL) Yes

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 Country(s) or region Inventory name On inventory (yes/no)*
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory No
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

16. Other information, including date of preparation or last revision

Issue date 27-May-2015
Revision date -
Version # 01
HMIS® ratings Health: 2
Flammability: 3
Physical hazard: 0
NFPA ratings
3
2 0

Disclaimer The information in the sheet was written based on the best knowledge and experience currently
available. Oatey Co. cannot anticipate all conditions under which this information and its product,
or the products of other manufacturers in combination with its product, may be used. It is the
user’s responsibility to ensure safe conditions for handling, storage and disposal of the product,
and to assume liability for loss, injury, damage or expense due to improper use.

Oatey CPVC Flowguard Gold UVI One-Step Yellow Cement SDS US

926350 Version #: 02 Revision date: 3-12-2020 Issue date: 5-27-2015 10 / 10
 SAFETY DATA SHEET

1. Identification
Product identifier Oatey No. 5 Paste Flux
Other means of identification
SDS number 1610E
Synonyms Part Numbers: No 5- 30011, 30013, 30014, 30038, 30041, 48307, 48420, 48421, 48422, 48423,
53017, 53060, 53200, Hot Weather- 30062
Recommended use Joining Copper Pipes. Joining Copper Tubing.
Recommended restrictions None known.
Manufacturer/Importer/Supplier/Distributor information
Company Name Oatey Co.
Address 4700 West 160th St.
Cleveland, OH 44135
Telephone 216-267-7100
E-mail [email protected]
Transport Emergency Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887)
Emergency First Aid 1-877-740-5015
Contact person MSDS Coordinator

2. Hazard(s) identification
Physical hazards Not classified.

Health hazards Skin corrosion/irritation Category 1B

Serious eye damage/eye irritation Category 1
OSHA defined hazards Not classified.

Label elements

Signal word Danger

Hazard statement Causes severe skin burns and eye damage.
Precautionary statement
Prevention Wash thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face
protection. Do not breathe dusts or mists.
Response If swallowed: Rinse mouth. Do not induce vomiting. If on skin (or hair): Take off immediately all
contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. If
inhaled: Remove person to fresh air and keep comfortable for breathing. Immediately call a
poison center/doctor. If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
Storage Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise None known.
classified (HNOC)
Supplemental information
Not applicable.

3. Composition/information on ingredients
Mixtures
Chemical name CAS number %
Petrolatum 8009-03-8 60-100

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 Zinc chloride 7646-85-7 10-30

Water 7732-18-5 3-7

Ammonium chloride 12125-02-9 1-5

4. First-aid measures
Inhalation If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.
Call a physician if symptoms develop or persist.
Skin contact Take off immediately all contaminated clothing. Rinse skin with water/shower. Call a physician or
poison control center immediately. Chemical burns must be treated by a physician. Wash
contaminated clothing before reuse.
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Continue rinsing. Call a
physician or poison control center immediately. Remove contact lenses, if present and easy to do.
Ingestion Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If
vomiting occurs, keep head low so that stomach content doesn't get into the lungs.
Most important Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms may
symptoms/effects, acute and include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including
delayed blindness could result.
Indication of immediate Provide general supportive measures and treat symptomatically. Chemical burns: Flush with water
medical attention and special immediately. While flushing, remove clothes which do not adhere to affected area. Call an
treatment needed ambulance. Continue flushing during transport to hospital. Keep victim under observation.
Symptoms may be delayed.
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.

5. Fire-fighting measures
Suitable extinguishing media Water spray. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from During fire, gases hazardous to health may be formed.
the chemical
Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
and precautions for firefighters
Fire fighting Use water spray to cool unopened containers.
equipment/instructions
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards No unusual fire or explosion hazards noted.

6. Accidental release measures

Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
protective equipment and low areas. Wear appropriate protective equipment and clothing during clean-up. Do not touch
emergency procedures damaged containers or spilled material unless wearing appropriate protective clothing. Ensure
adequate ventilation. Local authorities should be advised if significant spillages cannot be
contained. For personal protection, see section 8 of the SDS.
Methods and materials for Stop the flow of material, if this is without risk. Use water spray to reduce vapors or divert vapor
containment and cleaning up cloud drift. Dike far ahead of spill for later disposal. Prevent entry into waterways, sewer,
basements or confined areas. Following product recovery, flush area with water. For waste
disposal, see section 13 of the SDS.
Environmental precautions Avoid discharge into drains, water courses or onto the ground.

7. Handling and storage

Precautions for safe handling Do not get this material in contact with eyes. Do not get this material in contact with skin. Avoid
prolonged exposure. Do not get this material on clothing. Provide adequate ventilation. Wear
appropriate personal protective equipment. Observe good industrial hygiene practices.
Conditions for safe storage, Store locked up. Store in original tightly closed container. Store away from incompatible materials
including any incompatibilities (see Section 10 of the SDS).

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8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

Components Type Value Form

Petrolatum (CAS PEL 5 mg/m3 Mist.
8009-03-8)
Zinc chloride (CAS PEL 1 mg/m3 Fume.
7646-85-7)
US. ACGIH Threshold Limit Values

Components Type Value Form

Ammonium chloride (CAS STEL 20 mg/m3 Fume.
12125-02-9)
TWA 10 mg/m3 Fume.
Petrolatum (CAS TWA 5 mg/m3 Inhalable fraction.
8009-03-8)
Zinc chloride (CAS STEL 2 mg/m3 Fume.
7646-85-7)
TWA 1 mg/m3 Fume.
US. NIOSH: Pocket Guide to Chemical Hazards

Components Type Value Form

Ammonium chloride (CAS STEL 20 mg/m3 Fume.
12125-02-9)
TWA 10 mg/m3 Fume.
Petrolatum (CAS STEL 10 mg/m3 Mist.
8009-03-8)
TWA 5 mg/m3 Mist.
Zinc chloride (CAS STEL 2 mg/m3 Fume.
7646-85-7)
TWA 1 mg/m3 Fume.
Biological limit values No biological exposure limits noted for the ingredient(s).
Exposure guidelines Occupational Exposure Limits are not relevant to the current physical form of the product.
Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level. Eye
wash facilities and emergency shower must be available when handling this product.
Individual protection measures, such as personal protective equipment
Eye/face protection Wear safety glasses with side shields (or goggles) and a face shield.
Skin protection
Hand protection Wear appropriate chemical resistant gloves.
Other Wear appropriate chemical resistant clothing.
Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene Always observe good personal hygiene measures, such as washing after handling the material
considerations and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.

9. Physical and chemical properties

Appearance
Physical state Solid.
Form Solid. Paste.
Color Not available.
Odor Not available.
Odor threshold Not available.
pH Not available.

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Melting point/freezing point Not available.
Initial boiling point and boiling 638 °F (336.67 °C)
range
Flash point 540.0 °F (282.2 °C)
Evaporation rate Not available.
Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower Not available.
(%)
Flammability limit - upper Not available.
(%)
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure Not available.
Vapor density >1
Relative density 1.1
Solubility(ies)
Solubility (water) Insoluble
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity 20000 - 40000 cP
Other information
VOC (Weight %) 29 g/l 3% by weight

10. Stability and reactivity

Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous No dangerous reaction known under conditions of normal use.
reactions
Conditions to avoid Contact with incompatible materials.
Incompatible materials Strong oxidizing agents.
Hazardous decomposition No hazardous decomposition products are known.
products

11. Toxicological information

Information on likely routes of exposure
Inhalation Prolonged inhalation may be harmful. May cause irritation to the respiratory system.
Skin contact Causes severe skin burns.
Eye contact Causes serious eye damage.
Ingestion Causes digestive tract burns.
Symptoms related to the Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms may
physical, chemical and include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including
toxicological characteristics blindness could result.
Information on toxicological effects
Acute toxicity Not available.
Skin corrosion/irritation Causes severe skin burns and eye damage.
Serious eye damage/eye Causes serious eye damage.
irritation
Respiratory or skin sensitization
Respiratory sensitization Not available.
Skin sensitization This product is not expected to cause skin sensitization.
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Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity None known.
IARC Monographs. Overall Evaluation of Carcinogenicity
Petrolatum (CAS 8009-03-8) 3 Not classifiable as to carcinogenicity to humans.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity - Not classified.
single exposure
Specific target organ toxicity - Not classified.
repeated exposure
Aspiration hazard Not available.
Chronic effects Prolonged inhalation may be harmful.

12. Ecological information

Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulative potential No data available.
Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations

Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material
and its container must be disposed of as hazardous waste. Do not allow this material to drain into
sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used
container. Dispose of contents/container in accordance with local/regional/national/international
regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some
products product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.

14. Transport information

DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78 and
the IBC Code

15. Regulatory information

US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.

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 OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Ammonium chloride (CAS 12125-02-9) LISTED
Zinc chloride (CAS 7646-85-7) LISTED
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous No
chemical
SARA 313 (TRI reporting)
Chemical name CAS number % by wt.
Zinc chloride 7646-85-7 10-30
Ammonium chloride 12125-02-9 1-5
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
US state regulations
US. Massachusetts RTK - Substance List
Ammonium chloride (CAS 12125-02-9)
Petrolatum (CAS 8009-03-8)
Zinc chloride (CAS 7646-85-7)
US. New Jersey Worker and Community Right-to-Know Act
Ammonium chloride (CAS 12125-02-9)
Petrolatum (CAS 8009-03-8)
Zinc chloride (CAS 7646-85-7)
US. Pennsylvania Worker and Community Right-to-Know Law
Ammonium chloride (CAS 12125-02-9)
Petrolatum (CAS 8009-03-8)
Zinc chloride (CAS 7646-85-7)
US. Rhode Island RTK
Ammonium chloride (CAS 12125-02-9)
Zinc chloride (CAS 7646-85-7)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Chemical Substances (AICS) Yes
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) Yes
Europe European Inventory of Existing Commercial Chemical Yes
Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) No
Korea Existing Chemicals List (ECL) Yes

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 Country(s) or region Inventory name On inventory (yes/no)*
New Zealand New Zealand Inventory Yes
Philippines Philippine Inventory of Chemicals and Chemical Substances Yes
(PICCS)
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

16. Other information, including date of preparation or last revision

Issue date 26-October-2014
Revision date 19-February-2015
Version # 03
HMIS® ratings Health: 3
Flammability: 0
Physical hazard: 0
Disclaimer The information in the sheet was written based on the best knowledge and experience currently
available. Oatey Co. cannot anticipate all conditions under which this information and its product,
or the products of other manufacturers in combination with its product, may be used. It is the
user’s responsibility to ensure safe conditions for use, handling, storage and disposal of the
product, and to assume liability for loss, injury, damage or expense due to improper use.

Oatey No. 5 Paste Flux SDS US

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 MSDS No: OTH050E8
Issue Date: 15 Apr 2008
Page: 1 of 4
MATERIAL SAFETY DATA SHEET

SECTION 1 PRODUCT AND COMPANY IDENTIFICATION

Trade Name: OATEY PLUMBER’S PUTTY
Product No.: 31166, 31170, 31174
Product Use: Stainless fixture setting compound.
Formula: See SECTION 2
Synonyms: Putty.
Firm Name & OATEY CO. 4700 West 160th Street P.O. Box 35906 Cleveland,
Mailing Address: Ohio 44135, U.S.A. http://www.oatey.com
Oatey Phone Number: (216) 267-7100 or (800) 321-9532
Emergency Phone For Emergency First Aid call 1-303-623-5716 COLLECT. For
Numbers: chemical transportation emergencies ONLY, call Chemtrec at
1-800-424-9300. Outside the US: 1-703-527-3887.
Prepared By: Corporate Director – Safety and Environmental Compliance
Preparation Date: April 15, 2008

SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS

INGREDIENTS: %wt/wt: CAS NUMBER: ACGIH TLV TWA: OSHA PEL TWA: OTHER:
Limestone 60 - 90% 1317-65-3 10 mg/M3 15 mg/M3 None
(Total dust)
Hydrocarbon oil 10 - 30% 64742-52-5 5 mg/M3 5 mg/M3 None
Talc 1 - 5% 14807-96-6 2 mg/M3 2 mg/M3 None
Clay 1 – 5% 68953-58-2 10 mg/M3 10 mg/M3 None

OSHA Hazard Classification: Not hazardous

SECTION 3 HAZARDS IDENTIFICATION

Emergency Overview:
White putty with a mild petroleum odor. May cause mechanical irritation of the eyes.

SECTION 4 FIRST AID MEASURES

CALL 1-303-623-5716 COLLECT
Skin: Wash all exposed areas with soap and water.
Eyes: If material gets into eyes or if fumes cause irritation, immediately
flush eyes with plenty of water until chemical is removed. If
irritation persists, get medical attention immediately.
Inhalation: Not a likely route of entry.
Ingestion: DO NOT INDUCE VOMITING. Rinse mouth with water. Call a physician.

SECTION 5 FIRE FIGHTING MEASURES

Flashpoint / Method: Not applicable
Flammability: LEL = ND, UEL = ND
Extinguishing Use dry chemical, CO2, or foam to extinguish fire. Cool fire
Media: exposed container with water. Water may be ineffective as an
extinguishing agent.
Special Fire As appropriate for surrounding fire.
Fighting
Procedure:
Unusual Fire and None
Explosion
Hazards:
Hazardous Combustion will produce toxic and irritating vapors including
Decomposition carbon monoxide and carbon dioxide.
Products:
 MSDS No: OTH050E8
Issue Date: 15 Apr 2008
Page: 2 of 4
SECTION 6 ACCIDENTAL RELEASE MEASURES
Spill or Sweep up dried material and dispose of with ordinary trash.
Leak
Procedures:

SECTION 7 HANDLING AND STORAGE

Handling: No special handling required. Wash thoroughly after handling.
Use good hygiene practices.
Storage: Store in a cool, dry area.
Other: None.

SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION

Ventilation: Use with adequate ventilation.
Respiratory If putty dries and becomes dusty, wear a dust respirator
Protection: during clean-up.
Skin Gloves are not normally required.
Protection:
Eye Safety glasses with side shields are recommended.
Protection:
Other: Eye wash should be available.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Boiling Point: Not applicable
Melting Point: Not applicable
Vapor Pressure: Not determined
Vapor Density: Not determined
Volatile Components: Not determined
Solubility In Water: Negligible.
pH: Not applicable
Specific Gravity: 2.0 @ 20 Degrees C
Evaporation Rate: Not applicable
Appearance: White Putty
Odor: Petroleum odor
Will Dissolve In: Not determined
Material Is: Putty

SECTION 10 STABILITY AND REACTIVITY

Stability: Stable.
Conditions To Avoid: Avoid heat, flames and other sources of ignition.
Hazardous Combustion will produce toxic and irritating vapors
Decomposition including carbon monoxide and carbon dioxide.
Products:
Incompatibility/ Strong oxidizing agents.
Materials To Avoid:
Hazardous Will not occur.
Polymerization:
 MSDS No: OTH050E8
Issue Date: 15 Apr 2008
Page: 3 of 4
SECTION 11 TOXICOLOGICAL INFORMATION
Inhalation: Not a likely route of entry.
Skin: May cause mild irritation. Prolonged and repeated contact
may cause dermatitis.
Eye: Contact may cause irritation.
Ingestion: Swallowing may cause a laxative effect including cramps and
diarrhea.
Chronic Prolonged or repeated overexposure cause dermatitis.
Toxicity:
Toxicity Data: Not available
Sensitization: None of the components are known to cause sensitization.
Carcinogenicity: None of the components are listed as a carcinogen or suspect
carcinogen by NTP, IARC or OSHA.
Mutagenicity: None of the components are known to be mutagenic.
Reproductive None of the components are known to be toxic to reproduction.
Toxicity:
Medical None known.
Conditions
Aggravated By
Exposure:

SECTION 12 ECOLOGICAL INFORMATION

No ecotoxicological information known.
VOC This product has very low VOC level.
Information:

SECTION 13 DISPOSAL CONSIDERATIONS

Waste Disposal: Dispose in accordance with current local, state and federal
regulations.
RCRA Hazardous Waste Number: Not a hazardous waste.
EPA Hazardous Waste ID Number: Not a hazardous waste.
EPA Hazard Waste Class: Not a hazardous waste.

SECTION 14 TRANSPORT INFORMATION

DOT Less than 1 Liter (0.3 gal) Greater than 1 Liter (0.3 gal)
Proper Shipping Name: Not regulated. Not regulated.
Hazard Class/Packing Group: None None
UN/NA Number: None None
Hazard Labels: None None
IMDG
Proper Shipping Name: Not regulated
Hazard Class/Packing Group: None
UN Number: None
Label: None

2004 North American Emergency Response Guidebook Number: None

 MSDS No: OTH050E8
Issue Date: 15 Apr 2008
Page: 4 of 4
SECTION 15 REGULATORY INFORMATION
Hazard Category for Section Not hazardous.
Section 302 Extremely This product does not contain chemicals regulated
Hazardous Substances (TPQ): under SARA Section 302.
Section 313 Toxic Chemicals: This product does not contain any chemicals regulated
under SARA Title III Section 313.
CERCLA 103 Reportable This product does not contain any chemicals regulated
Quantity: under CERCLA.
California Proposition 65: This product does not contain any chemicals subject
To California Proposition 65 regulation.
TSCA Inventory: All of the components of this product are listed on
the TSCA inventory.
Canadian WHIMS Classification: Not a controlled product.
This product has been classified in accordance with
the hazard criteria of the Controlled Products
Regulations (CPR) and the MSDS contains all the
information required by the CPR.

SECTION 16 OTHER INFORMATION

NFPA and HMIS:
NFPA Hazard Signal: Health: 0 Flammability: 0 Reactivity: 0 Special: None
HMIS Hazard Signal: Health: 0 Flammability: 0 Reactivity: 0 PPE: A

Disclaimer:
The information herein has been compiled from sources believed to be reliable, up-
to-date, and is accurate to the best of our knowledge. However, Oatey cannot give
any guarantees regarding information from other sources, and expressly does not make
warranties, nor assumes any liability for its use.
 SAFETY DATA SHEET

1. Identification
Product identifier Oatey Purple Primer Large Diameter Pipe
Other means of identification
Product code 1402E

Recommended use Joining PVC Pipes

Recommended restrictions None known.
Manufacturer/Importer/Supplier/Distributor information
Company Name Oatey Co.
Address 4700 West 160th St.
Cleveland, OH 44135

Telephone 216-267-7100
E-mail [email protected]
Transport Emergency Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887)
Emergency First Aid 1-877-740-5015
Contact person MSDS Coordinator

2. Hazard(s) identification
Physical hazards Flammable liquids Category 2

Health hazards Acute toxicity, oral Category 4

Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2A
Specific target organ toxicity, single exposure Category 3 respiratory tract irritation
Specific target organ toxicity, single exposure Category 3 narcotic effects
Aspiration hazard Category 1
OSHA defined hazards Not classified.

Label elements

Signal word Danger

Hazard statement Highly flammable liquid and vapor. Harmful if swallowed. May be fatal if swallowed and enters
airways. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May
cause drowsiness or dizziness.
Precautionary statement
Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly
closed. Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Avoid breathing mist or vapor. Wash thoroughly after
handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a
well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection.
Response If swallowed: Immediately call a poison center/doctor. If on skin (or hair): Take off immediately all
contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and
keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison center/doctor if
you feel unwell. Rinse mouth. Do NOT induce vomiting. If skin irritation occurs: Get medical
advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated
clothing and wash before reuse. In case of fire: Use appropriate media to extinguish.
Oatey Purple Primer Large Diameter Pipe SDS US
926738 Version #: 01 Revision date: 12-1-2017 Issue date: 1 / 10
05-27-2015
 Storage Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis.
classified (HNOC) May form explosive peroxides. Contains a chemical classified by the US EPA as a suspected
possible carcinogen.
Supplemental information
Not applicable.

3. Composition/information on ingredients
Mixtures
Chemical name CAS number %
Furan, Tetrahydro- 109-99-9 40-60

Acetone 67-64-1 10-25

Cyclohexanone 108-94-1 10-25

Methyl ethyl ketone 78-93-3 10-25

*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.

4. First-aid measures
Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON
CENTER or doctor/physician if you feel unwell.
Skin contact Take off immediately all contaminated clothing. Wash with plenty of soap and water. If skin
irritation occurs: Get medical advice/attention.
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Ingestion Call a physician or poison control center immediately. Do not induce vomiting. If vomiting occurs,
keep head low so that stomach content doesn't get into the lungs. Aspiration may cause
pulmonary edema and pneumonitis.
Most important Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe eye
symptoms/effects, acute and irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May
delayed cause respiratory irritation. Vapors have a narcotic effect and may cause headache, fatigue,
dizziness and nausea. Skin irritation. May cause redness and pain.
Indication of immediate Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water
medical attention and special immediately. While flushing, remove clothes which do not adhere to affected area. Call an
treatment needed ambulance. Continue flushing during transport to hospital. In case of shortness of breath, give
oxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed.
General information Take off all contaminated clothing immediately. Ensure that medical personnel are aware of the
material(s) involved, and take precautions to protect themselves. Wash contaminated clothing
before reuse.

5. Fire-fighting measures
Suitable extinguishing media Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source
the chemical of ignition and flash back. During fire, gases hazardous to health may be formed.
Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
and precautions for firefighters
Fire fighting In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do
equipment/instructions so without risk.
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards Highly flammable liquid and vapor. This product contains tetrahydrofuran that may form explosive
organic peroxide when exposed to air or light or with age.

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6. Accidental release measures
Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
protective equipment and low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area).
emergency procedures Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or
vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective
clothing. Ventilate closed spaces before entering them. Local authorities should be advised if
significant spillages cannot be contained. For personal protection, see section 8 of the SDS.
Methods and materials for Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take
containment and cleaning up precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles
(wood, paper, oil, etc.) away from spilled material. This product is miscible in water.

Large Spills: Stop the flow of material, if this is without risk. Use water spray to reduce vapors or
divert vapor cloud drift. Dike the spilled material, where this is possible. Cover with plastic sheet to
prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the
product and place into a container for later disposal. Prevent entry into waterways, sewer,
basements or confined areas. Following product recovery, flush area with water.

Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers
for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Environmental precautions Avoid discharge into drains, water courses or onto the ground.

7. Handling and storage

Precautions for safe handling Vapors may form explosive mixtures with air. Do not handle, store or open near an open flame,
sources of heat or sources of ignition. Protect material from direct sunlight. Explosion-proof
general and local exhaust ventilation. Take precautionary measures against static discharges. All
equipment used when handling the product must be grounded. Use non-sparking tools and
explosion-proof equipment. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and
clothing. Avoid prolonged exposure. Do not taste or swallow. When using, do not eat, drink or
smoke. Wear appropriate personal protective equipment. Wash hands thoroughly after handling.
Observe good industrial hygiene practices.
Conditions for safe storage, Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge
including any incompatibilities build-up by using common bonding and grounding techniques. Store in a cool, dry place out of
direct sunlight. Store in original tightly closed container. Store in a well-ventilated place. Store
away from incompatible materials (see Section 10 of the SDS).

8. Exposure controls/personal protection

Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

Components Type Value

Acetone (CAS 67-64-1) PEL 2400 mg/m3
1000 ppm
Cyclohexanone (CAS PEL 200 mg/m3
108-94-1)
50 ppm
Furan, Tetrahydro- (CAS PEL 590 mg/m3
109-99-9)
200 ppm
Methyl ethyl ketone (CAS PEL 590 mg/m3
78-93-3)
200 ppm
US. ACGIH Threshold Limit Values

Components Type Value

Acetone (CAS 67-64-1) STEL 750 ppm
TWA 500 ppm
Cyclohexanone (CAS STEL 50 ppm
108-94-1)
TWA 20 ppm
Furan, Tetrahydro- (CAS STEL 100 ppm
109-99-9)
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 US. ACGIH Threshold Limit Values

Components Type Value

TWA 50 ppm
Methyl ethyl ketone (CAS STEL 300 ppm
78-93-3)
TWA 200 ppm
US. NIOSH: Pocket Guide to Chemical Hazards

Components Type Value

Acetone (CAS 67-64-1) TWA 590 mg/m3
250 ppm
Cyclohexanone (CAS TWA 100 mg/m3
108-94-1)
25 ppm
Furan, Tetrahydro- (CAS STEL 735 mg/m3
109-99-9)
250 ppm
TWA 590 mg/m3
200 ppm
Methyl ethyl ketone (CAS STEL 885 mg/m3
78-93-3)
300 ppm
TWA 590 mg/m3
200 ppm
Biological limit values
ACGIH Biological Exposure Indices

Components Value Determinant Specimen Sampling Time

Acetone (CAS 67-64-1) 50 mg/l Acetone Urine *
Cyclohexanone (CAS 80 mg/l 1,2-Cyclohexan Urine *
108-94-1) ediol, with
hydrolysis
8 mg/l Cyclohexanol, Urine *
with hydrolysis
Furan, Tetrahydro- (CAS 2 mg/l Tetrahydrofura Urine *
109-99-9) n
Methyl ethyl ketone (CAS 2 mg/l MEK Urine *
78-93-3)
* - For sampling details, please see the source document.
Exposure guidelines
US - California OELs: Skin designation
Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin.
US - Minnesota Haz Subs: Skin designation applies
Cyclohexanone (CAS 108-94-1) Skin designation applies.
US - Tennessee OELs: Skin designation
Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin.
US ACGIH Threshold Limit Values: Skin designation
Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin.
Furan, Tetrahydro- (CAS 109-99-9) Can be absorbed through the skin.
US. NIOSH: Pocket Guide to Chemical Hazards
Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin.
Appropriate engineering Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 air
controls changes per hour) should be used. Ventilation rates should be matched to conditions. If
applicable, use process enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure limits have not been
established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency
shower must be available when handling this product.
Individual protection measures, such as personal protective equipment
Eye/face protection Face shield is recommended. Wear safety glasses with side shields (or goggles).

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 Skin protection
Hand protection Wear appropriate chemical resistant gloves.
Other Wear appropriate chemical resistant clothing.
Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such
considerations as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash
work clothing and protective equipment to remove contaminants.

9. Physical and chemical properties

Appearance
Physical state Liquid.
Form Translucent liquid.
Color Purple
Odor Solvent.
Odor threshold Not available.
pH Not available.
Melting point/freezing point Not available.
Initial boiling point and boiling 151 °F (66.11 °C)
range
Flash point 14.0 - 23.0 °F (-10.0 - -5.0 °C)
Evaporation rate 5.5 - 8
Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower 1.8
(%)
Flammability limit - upper 11.8
(%)
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure 145 mm Hg @ 20 C
Vapor density 2.5
Relative density 0.9 +/- 0.02
Solubility(ies)
Solubility (water) Negligible
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity < 100 cP
Other information
Bulk density 7.5 lb/gal
VOC (Weight %) <550 g/l SQACMD Method 304

10. Stability and reactivity

Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous No dangerous reaction known under conditions of normal use.
reactions
Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the
flash point. Contact with incompatible materials.
Incompatible materials Acids. Strong oxidizing agents. Ammonia. Amines. Isocyanates. Caustics.
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Hazardous decomposition No hazardous decomposition products are known.
products

11. Toxicological information

Information on likely routes of exposure
Inhalation May be fatal if swallowed and enters airways. Headache. Nausea, vomiting. May cause irritation
to the respiratory system. Vapors have a narcotic effect and may cause headache, fatigue,
dizziness and nausea. Prolonged inhalation may be harmful.
Skin contact Causes skin irritation.
Eye contact Causes serious eye irritation.
Ingestion May be fatal if swallowed and enters airways. Harmful if swallowed. Harmful if swallowed. Droplets
of the product aspirated into the lungs through ingestion or vomiting may cause a serious
chemical pneumonia.
Symptoms related to the Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe
physical, chemical and eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May
toxicological characteristics cause respiratory irritation. Skin irritation. May cause redness and pain. Symptoms of
overexposure may be headache, dizziness, tiredness, nausea and vomiting.
Information on toxicological effects
Acute toxicity May be fatal if swallowed and enters airways. Narcotic effects. May cause respiratory irritation.
Components Species Test Results
Acetone (CAS 67-64-1)
Acute
Dermal
LD50 Rabbit 20 ml/kg
Inhalation
LC50 Rat 50 mg/l, 8 Hours
Oral
LD50 Rat 5800 mg/kg
Cyclohexanone (CAS 108-94-1)
Acute
Dermal
LD50 Rabbit 948 mg/kg
Inhalation
LC50 Rat 8000 ppm, 4 hours
Oral
LD50 Rat 1540 mg/kg

* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation Causes skin irritation.
Serious eye damage/eye Causes serious eye irritation.
irritation
Respiratory or skin sensitization
Respiratory sensitization Not available.
Skin sensitization This product is not expected to cause skin sensitization.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity In 2012 USEPA Integrated Risk Information System (IRIS) reviewed a two species inhalation
lifetime study on THF conducted by NTP (1998). Male rats developed renal tumors and female
mice developed liver tumors while neither the female rats nor the male mice showed similar
results. Because the carcinogenic mechanisms could not be identified clearly in either species for
either tumor, the EPA determined that the male rat and female mouse findings are relevant to the
assessment of carcinogenic potential in humans. Therefore, the IRIS review concludes that these
data in aggregate indicate that there is "suggestive evidence of carcinogenic potential" following
exposure to THF by all routes of exposure.
IARC Monographs. Overall Evaluation of Carcinogenicity
Cyclohexanone (CAS 108-94-1) 3 Not classifiable as to carcinogenicity to humans.

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 OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity - Narcotic effects. May cause drowsiness and dizziness. Respiratory tract irritation.
single exposure
Specific target organ toxicity - Not classified.
repeated exposure
Aspiration hazard May be fatal if swallowed and enters airways.
Chronic effects Prolonged inhalation may be harmful.

12. Ecological information

Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Components Species Test Results
Acetone (CAS 67-64-1)
Aquatic
Fish LC50 Fathead minnow (Pimephales promelas) > 100 mg/l, 96 hours
Cyclohexanone (CAS 108-94-1)
Aquatic
Fish LC50 Fathead minnow (Pimephales promelas) 481 - 578 mg/l, 96 hours

* Estimates for product may be based on additional component data not shown.
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulative potential No data available.
Partition coefficient n-octanol / water (log Kow)
Acetone (CAS 67-64-1) -0.24
Cyclohexanone (CAS 108-94-1) 0.81
Furan, Tetrahydro- (CAS 109-99-9) 0.46
Methyl ethyl ketone (CAS 78-93-3) 0.29
Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations

Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material
and its container must be disposed of as hazardous waste. Do not allow this material to drain into
sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used
container. Dispose of contents/container in accordance with local/regional/national/international
regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some
products product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.

14. Transport information

DOT
UN number UN1993
UN proper shipping name Flammable liquids, n.o.s. (Methyl ethyl ketone RQ = 24307 LBS, Acetone RQ = 38373 LBS)
Transport hazard class(es)
Class 3
Subsidiary risk -
Label(s) 3
Packing group II
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 Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Special provisions IB2, T7, TP1, TP8, TP28
Packaging exceptions 150
Packaging non bulk 202
Packaging bulk 242
IATA
UN number UN1993
UN proper shipping name Flammable liquid, n.o.s. (Methyl ethyl ketone, Acetone)
Transport hazard class(es)
Class 3
Subsidiary risk -
Packing group II
Environmental hazards No.
ERG Code 3H
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
IMDG
UN number UN1993
UN proper shipping name FLAMMABLE LIQUID, N.O.S. (Methyl ethyl ketone, Acetone)
Transport hazard class(es)
Class 3
Subsidiary risk -
Packing group II
Environmental hazards
Marine pollutant No.
EmS F-E, S-E
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Transport in bulk according to Not available.
Annex II of MARPOL 73/78 and
the IBC Code

15. Regulatory information

US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Acetone (CAS 67-64-1) LISTED
Cyclohexanone (CAS 108-94-1) LISTED
Furan, Tetrahydro- (CAS 109-99-9) LISTED
Methyl ethyl ketone (CAS 78-93-3) LISTED
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - Yes
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous No
chemical
SARA 313 (TRI reporting)
Not regulated.

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Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and
Chemical Code Number
Acetone (CAS 67-64-1) 6532
Methyl ethyl ketone (CAS 78-93-3) 6714
Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c))
Acetone (CAS 67-64-1) 35 %WV
Methyl ethyl ketone (CAS 78-93-3) 35 %WV
DEA Exempt Chemical Mixtures Code Number
Acetone (CAS 67-64-1) 6532
Methyl ethyl ketone (CAS 78-93-3) 6714
US state regulations
US. Massachusetts RTK - Substance List
Acetone (CAS 67-64-1)
Cyclohexanone (CAS 108-94-1)
Furan, Tetrahydro- (CAS 109-99-9)
Methyl ethyl ketone (CAS 78-93-3)
US. New Jersey Worker and Community Right-to-Know Act
Acetone (CAS 67-64-1)
Cyclohexanone (CAS 108-94-1)
Furan, Tetrahydro- (CAS 109-99-9)
Methyl ethyl ketone (CAS 78-93-3)
US. Pennsylvania Worker and Community Right-to-Know Law
Acetone (CAS 67-64-1)
Cyclohexanone (CAS 108-94-1)
Furan, Tetrahydro- (CAS 109-99-9)
Methyl ethyl ketone (CAS 78-93-3)
US. Rhode Island RTK
Acetone (CAS 67-64-1)
Cyclohexanone (CAS 108-94-1)
Furan, Tetrahydro- (CAS 109-99-9)
Methyl ethyl ketone (CAS 78-93-3)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Canada Domestic Substances List (DSL) Yes
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

16. Other information, including date of preparation or last revision

Issue date 05-27-2015
Revision date -
Version # 01
HMIS® ratings Health: 2
Flammability: 3
Physical hazard: 0

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NFPA ratings
3
2 0

Disclaimer The information in the sheet was written based on the best knowledge and experience currently
available. Oatey Co. cannot anticipate all conditions under which this information and its product,
or the products of other manufacturers in combination with its product, may be used. It is the
user’s responsibility to ensure safe conditions for handling, storage and disposal of the product,
and to assume liability for loss, injury, damage or expense due to improper use.

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 SAFETY DATA SHEET

1. Identification
Product identifier Oatey Purple Primer- NSF Listed for PVC and CPVC
Other means of identification
Product code 1402E
Synonyms Part Numbers: 30755(TV), 30756(TV), 30757(TV), 30758, 30759, 30927
Recommended use Joining PVC Pipes
Recommended restrictions None known.
Manufacturer/Importer/Supplier/Distributor information
Company Name Oatey Co.
Address 4700 West 160th St.
Cleveland, OH 44135

Telephone 216-267-7100
E-mail [email protected]
Transport Emergency Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887)
Emergency First Aid 1-877-740-5015
Contact person MSDS Coordinator

2. Hazard(s) identification
Physical hazards Flammable liquids Category 2

Health hazards Acute toxicity, oral Category 4

Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2A
Specific target organ toxicity, single exposure Category 3 respiratory tract irritation
Specific target organ toxicity, single exposure Category 3 narcotic effects
Aspiration hazard Category 1
OSHA defined hazards Not classified.

Label elements

Signal word Danger

Hazard statement Highly flammable liquid and vapor. Harmful if swallowed. May be fatal if swallowed and enters
airways. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May
cause drowsiness or dizziness.
Precautionary statement
Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly
closed. Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Avoid breathing mist or vapor. Wash thoroughly after
handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a
well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection.
Response If swallowed: Immediately call a poison center/doctor. If on skin (or hair): Take off immediately all
contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and
keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison center/doctor if
you feel unwell. Rinse mouth. Do NOT induce vomiting. If skin irritation occurs: Get medical
advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated
clothing and wash before reuse. In case of fire: Use appropriate media to extinguish.
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 Storage Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis.
classified (HNOC) May form explosive peroxides. Contains a chemical classified by the US EPA as a suspected
possible carcinogen.
Supplemental information
Not applicable.

3. Composition/information on ingredients
Mixtures
Chemical name CAS number %
Acetone 67-64-1 25-40

Cyclohexanone 108-94-1 25-40

Furan, Tetrahydro- 109-99-9 15-30

Methyl ethyl ketone 78-93-3 15-30

*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.

4. First-aid measures
Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON
CENTER or doctor/physician if you feel unwell.
Skin contact Take off immediately all contaminated clothing. Wash with plenty of soap and water. If skin
irritation occurs: Get medical advice/attention.
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Ingestion Call a physician or poison control center immediately. Do not induce vomiting. If vomiting occurs,
keep head low so that stomach content doesn't get into the lungs. Aspiration may cause
pulmonary edema and pneumonitis.
Most important Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe eye
symptoms/effects, acute and irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May
delayed cause respiratory irritation. Vapors have a narcotic effect and may cause headache, fatigue,
dizziness and nausea. Skin irritation. May cause redness and pain.
Indication of immediate Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water
medical attention and special immediately. While flushing, remove clothes which do not adhere to affected area. Call an
treatment needed ambulance. Continue flushing during transport to hospital. In case of shortness of breath, give
oxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed.
General information Take off all contaminated clothing immediately. Ensure that medical personnel are aware of the
material(s) involved, and take precautions to protect themselves. Wash contaminated clothing
before reuse.

5. Fire-fighting measures
Suitable extinguishing media Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source
the chemical of ignition and flash back. During fire, gases hazardous to health may be formed.
Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
and precautions for firefighters
Fire fighting In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do
equipment/instructions so without risk.
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards Highly flammable liquid and vapor. This product contains tetrahydrofuran that may form explosive
organic peroxide when exposed to air or light or with age.

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6. Accidental release measures
Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
protective equipment and low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area).
emergency procedures Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or
vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective
clothing. Ventilate closed spaces before entering them. Local authorities should be advised if
significant spillages cannot be contained. For personal protection, see section 8 of the SDS.
Methods and materials for Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take
containment and cleaning up precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles
(wood, paper, oil, etc.) away from spilled material. This product is miscible in water.

Large Spills: Stop the flow of material, if this is without risk. Use water spray to reduce vapors or
divert vapor cloud drift. Dike the spilled material, where this is possible. Cover with plastic sheet to
prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the
product and place into a container for later disposal. Prevent entry into waterways, sewer,
basements or confined areas. Following product recovery, flush area with water.

Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers
for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Environmental precautions Avoid discharge into drains, water courses or onto the ground.

7. Handling and storage

Precautions for safe handling Vapors may form explosive mixtures with air. Do not handle, store or open near an open flame,
sources of heat or sources of ignition. Protect material from direct sunlight. Explosion-proof
general and local exhaust ventilation. Take precautionary measures against static discharges. All
equipment used when handling the product must be grounded. Use non-sparking tools and
explosion-proof equipment. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and
clothing. Avoid prolonged exposure. Do not taste or swallow. When using, do not eat, drink or
smoke. Wear appropriate personal protective equipment. Wash hands thoroughly after handling.
Observe good industrial hygiene practices.
Conditions for safe storage, Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge
including any incompatibilities build-up by using common bonding and grounding techniques. Store in a cool, dry place out of
direct sunlight. Store in original tightly closed container. Store in a well-ventilated place. Store
away from incompatible materials (see Section 10 of the SDS).

8. Exposure controls/personal protection

Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

Components Type Value

Acetone (CAS 67-64-1) PEL 2400 mg/m3
1000 ppm
Cyclohexanone (CAS PEL 200 mg/m3
108-94-1)
50 ppm
Furan, Tetrahydro- (CAS PEL 590 mg/m3
109-99-9)
200 ppm
Methyl ethyl ketone (CAS PEL 590 mg/m3
78-93-3)
200 ppm
US. ACGIH Threshold Limit Values

Components Type Value

Acetone (CAS 67-64-1) STEL 750 ppm
TWA 500 ppm
Cyclohexanone (CAS STEL 50 ppm
108-94-1)
TWA 20 ppm
Furan, Tetrahydro- (CAS STEL 100 ppm
109-99-9)
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 US. ACGIH Threshold Limit Values

Components Type Value

TWA 50 ppm
Methyl ethyl ketone (CAS STEL 300 ppm
78-93-3)
TWA 200 ppm
US. NIOSH: Pocket Guide to Chemical Hazards

Components Type Value

Acetone (CAS 67-64-1) TWA 590 mg/m3
250 ppm
Cyclohexanone (CAS TWA 100 mg/m3
108-94-1)
25 ppm
Furan, Tetrahydro- (CAS STEL 735 mg/m3
109-99-9)
250 ppm
TWA 590 mg/m3
200 ppm
Methyl ethyl ketone (CAS STEL 885 mg/m3
78-93-3)
300 ppm
TWA 590 mg/m3
200 ppm
Biological limit values
ACGIH Biological Exposure Indices

Components Value Determinant Specimen Sampling Time

Acetone (CAS 67-64-1) 50 mg/l Acetone Urine *
Cyclohexanone (CAS 80 mg/l 1,2-Cyclohexan Urine *
108-94-1) ediol, with
hydrolysis
8 mg/l Cyclohexanol, Urine *
with hydrolysis
Furan, Tetrahydro- (CAS 2 mg/l Tetrahydrofura Urine *
109-99-9) n
Methyl ethyl ketone (CAS 2 mg/l MEK Urine *
78-93-3)
* - For sampling details, please see the source document.
Exposure guidelines
US - California OELs: Skin designation
Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin.
US - Minnesota Haz Subs: Skin designation applies
Cyclohexanone (CAS 108-94-1) Skin designation applies.
US - Tennessee OELs: Skin designation
Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin.
US ACGIH Threshold Limit Values: Skin designation
Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin.
Furan, Tetrahydro- (CAS 109-99-9) Can be absorbed through the skin.
US. NIOSH: Pocket Guide to Chemical Hazards
Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin.
Appropriate engineering Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 air
controls changes per hour) should be used. Ventilation rates should be matched to conditions. If
applicable, use process enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure limits have not been
established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency
shower must be available when handling this product.
Individual protection measures, such as personal protective equipment
Eye/face protection Face shield is recommended. Wear safety glasses with side shields (or goggles).

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 Skin protection
Hand protection Wear appropriate chemical resistant gloves.
Other Wear appropriate chemical resistant clothing.
Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such
considerations as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash
work clothing and protective equipment to remove contaminants.

9. Physical and chemical properties

Appearance
Physical state Liquid.
Form Translucent liquid.
Color Purple
Odor Solvent.
Odor threshold Not available.
pH Not available.
Melting point/freezing point Not available.
Initial boiling point and boiling 151 °F (66.11 °C)
range
Flash point 14.0 - 23.0 °F (-10.0 - -5.0 °C)
Evaporation rate 5.5 - 8
Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower 1.8
(%)
Flammability limit - upper 11.8
(%)
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure 145 mm Hg @ 20 C
Vapor density 2.5
Relative density 0.84 +/- 0.02 @20°C
Solubility(ies)
Solubility (water) Negligible
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other information
Bulk density 7 lb/gal
VOC (Weight %) < 550 g/l SQACMD Method 24

10. Stability and reactivity

Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous No dangerous reaction known under conditions of normal use.
reactions
Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the
flash point. Contact with incompatible materials.
Incompatible materials Acids. Strong oxidizing agents. Ammonia. Amines. Isocyanates. Caustics.
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Hazardous decomposition No hazardous decomposition products are known.
products

11. Toxicological information

Information on likely routes of exposure
Inhalation May be fatal if swallowed and enters airways. Headache. Nausea, vomiting. May cause irritation
to the respiratory system. Vapors have a narcotic effect and may cause headache, fatigue,
dizziness and nausea. Prolonged inhalation may be harmful.
Skin contact Causes skin irritation.
Eye contact Causes serious eye irritation.
Ingestion May be fatal if swallowed and enters airways. Harmful if swallowed. Harmful if swallowed. Droplets
of the product aspirated into the lungs through ingestion or vomiting may cause a serious
chemical pneumonia.
Symptoms related to the Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe
physical, chemical and eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May
toxicological characteristics cause respiratory irritation. Skin irritation. May cause redness and pain. Symptoms of
overexposure may be headache, dizziness, tiredness, nausea and vomiting.
Information on toxicological effects
Acute toxicity May be fatal if swallowed and enters airways. Narcotic effects. May cause respiratory irritation.
Components Species Test Results
Acetone (CAS 67-64-1)
Acute
Dermal
LD50 Rabbit 20 ml/kg
Inhalation
LC50 Rat 50 mg/l, 8 Hours
Oral
LD50 Rat 5800 mg/kg
Cyclohexanone (CAS 108-94-1)
Acute
Dermal
LD50 Rabbit 948 mg/kg
Inhalation
LC50 Rat 8000 ppm, 4 hours
Oral
LD50 Rat 1540 mg/kg

* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation Causes skin irritation.
Serious eye damage/eye Causes serious eye irritation.
irritation
Respiratory or skin sensitization
Respiratory sensitization Not available.
Skin sensitization This product is not expected to cause skin sensitization.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity In 2012 USEPA Integrated Risk Information System (IRIS) reviewed a two species inhalation
lifetime study on THF conducted by NTP (1998). Male rats developed renal tumors and female
mice developed liver tumors while neither the female rats nor the male mice showed similar
results. Because the carcinogenic mechanisms could not be identified clearly in either species for
either tumor, the EPA determined that the male rat and female mouse findings are relevant to the
assessment of carcinogenic potential in humans. Therefore, the IRIS review concludes that these
data in aggregate indicate that there is "suggestive evidence of carcinogenic potential" following
exposure to THF by all routes of exposure.
IARC Monographs. Overall Evaluation of Carcinogenicity
Cyclohexanone (CAS 108-94-1) 3 Not classifiable as to carcinogenicity to humans.

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 OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity - Narcotic effects. May cause drowsiness and dizziness. Respiratory tract irritation.
single exposure
Specific target organ toxicity - Not classified.
repeated exposure
Aspiration hazard May be fatal if swallowed and enters airways.
Chronic effects Prolonged inhalation may be harmful.

12. Ecological information

Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Components Species Test Results
Acetone (CAS 67-64-1)
Aquatic
Fish LC50 Fathead minnow (Pimephales promelas) > 100 mg/l, 96 hours
Cyclohexanone (CAS 108-94-1)
Aquatic
Fish LC50 Fathead minnow (Pimephales promelas) 481 - 578 mg/l, 96 hours

* Estimates for product may be based on additional component data not shown.
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulative potential No data available.
Partition coefficient n-octanol / water (log Kow)
Acetone (CAS 67-64-1) -0.24
Cyclohexanone (CAS 108-94-1) 0.81
Furan, Tetrahydro- (CAS 109-99-9) 0.46
Methyl ethyl ketone (CAS 78-93-3) 0.29
Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations

Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material
and its container must be disposed of as hazardous waste. Do not allow this material to drain into
sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used
container. Dispose of contents/container in accordance with local/regional/national/international
regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some
products product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.

14. Transport information

DOT
UN number UN1993
UN proper shipping name Flammable liquids, n.o.s. (Methyl ethyl ketone RQ = 26274 LBS, Acetone RQ = 13130 LBS)
Transport hazard class(es)
Class 3
Subsidiary risk -
Label(s) 3
Packing group II
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 Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Special provisions IB2, T7, TP1, TP8, TP28
Packaging exceptions 150
Packaging non bulk 202
Packaging bulk 242
IATA
UN number UN1993
UN proper shipping name Flammable liquid, n.o.s. (Methyl ethyl ketone, Acetone)
Transport hazard class(es)
Class 3
Subsidiary risk -
Packing group II
Environmental hazards No.
ERG Code 3H
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
IMDG
UN number UN1993
UN proper shipping name FLAMMABLE LIQUID, N.O.S. (Methyl ethyl ketone, Acetone)
Transport hazard class(es)
Class 3
Subsidiary risk -
Packing group II
Environmental hazards
Marine pollutant No.
EmS F-E, S-E
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Transport in bulk according to Not available.
Annex II of MARPOL 73/78 and
the IBC Code

15. Regulatory information

US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Acetone (CAS 67-64-1) LISTED
Cyclohexanone (CAS 108-94-1) LISTED
Furan, Tetrahydro- (CAS 109-99-9) LISTED
Methyl ethyl ketone (CAS 78-93-3) LISTED
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - Yes
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous No
chemical
SARA 313 (TRI reporting)
Not regulated.

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Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and
Chemical Code Number
Acetone (CAS 67-64-1) 6532
Methyl ethyl ketone (CAS 78-93-3) 6714
Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c))
Acetone (CAS 67-64-1) 35 %WV
Methyl ethyl ketone (CAS 78-93-3) 35 %WV
DEA Exempt Chemical Mixtures Code Number
Acetone (CAS 67-64-1) 6532
Methyl ethyl ketone (CAS 78-93-3) 6714
US state regulations
US. Massachusetts RTK - Substance List
Acetone (CAS 67-64-1)
Cyclohexanone (CAS 108-94-1)
Furan, Tetrahydro- (CAS 109-99-9)
Methyl ethyl ketone (CAS 78-93-3)
US. New Jersey Worker and Community Right-to-Know Act
Acetone (CAS 67-64-1)
Cyclohexanone (CAS 108-94-1)
Furan, Tetrahydro- (CAS 109-99-9)
Methyl ethyl ketone (CAS 78-93-3)
US. Pennsylvania Worker and Community Right-to-Know Law
Acetone (CAS 67-64-1)
Cyclohexanone (CAS 108-94-1)
Furan, Tetrahydro- (CAS 109-99-9)
Methyl ethyl ketone (CAS 78-93-3)
US. Rhode Island RTK
Acetone (CAS 67-64-1)
Cyclohexanone (CAS 108-94-1)
Furan, Tetrahydro- (CAS 109-99-9)
Methyl ethyl ketone (CAS 78-93-3)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Canada Domestic Substances List (DSL) Yes
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

16. Other information, including date of preparation or last revision

Issue date 27-May-2015
Revision date -
Version # 01
HMIS® ratings Health: 2
Flammability: 3
Physical hazard: 0

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NFPA ratings
3
2 0

Disclaimer The information in the sheet was written based on the best knowledge and experience currently
available. Oatey Co. cannot anticipate all conditions under which this information and its product,
or the products of other manufacturers in combination with its product, may be used. It is the
user’s responsibility to ensure safe conditions for handling, storage and disposal of the product,
and to assume liability for loss, injury, damage or expense due to improper use.

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 SAFETY DATA SHEET

1. Identification
Product identifier Oatey PVC Heavy Duty Clear or Gray Cement
Other means of identification
SDS number 1102E
Synonyms Part Numbers: Clear 30850, 30863, 30876(TV), 30882, 31008(TV), 31011, 31950, 31951, 31952,
31953 Gray 30349, 31093, 31094, 31095, 31105, 31118, 31978, 31979, 31980, 31981, 32050,
32051, 32052, 32210, 32211
Recommended use Joining PVC Pipes
Recommended restrictions None known.
Manufacturer/Importer/Supplier/Distributor information
Company Name Oatey Co.
Address 4700 West 160th St.
Cleveland, OH 44135
Telephone 216-267-7100
E-mail [email protected]
Transport Emergency Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887)
Emergency First Aid 1-877-740-5015
Contact person MSDS Coordinator

2. Hazard(s) identification
Physical hazards Flammable liquids Category 2

Health hazards Acute toxicity, oral Category 4

Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2A
Specific target organ toxicity, single exposure Category 3 respiratory tract irritation
Specific target organ toxicity, single exposure Category 3 narcotic effects
Aspiration hazard Category 1
OSHA defined hazards Not classified.

Label elements

Signal word Danger

Hazard statement Highly flammable liquid and vapor. Harmful if swallowed. May be fatal if swallowed and enters
airways. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May
cause drowsiness or dizziness.
Precautionary statement
Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only outdoors or in a
well-ventilated area. Keep container tightly closed. Ground/bond container and receiving
equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking
tools. Take precautionary measures against static discharge. Avoid breathing mist or vapor. Wash
thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective
gloves/protective clothing/eye protection/face protection.
Response Rinse mouth. Do NOT induce vomiting. If skin irritation occurs: Get medical advice/attention. If
eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash
before reuse. In case of fire: Use appropriate media to extinguish.
Storage Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.

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Hazard(s) not otherwise Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis.
classified (HNOC) May form explosive peroxides. Contains a chemical classified by the US EPA as a suspected
possible carcinogen.
Supplemental information
Not applicable.

3. Composition/information on ingredients
Mixtures
Chemical name CAS number %
Furan, Tetrahydro- 109-99-9 30-60

2-Propanone 67-64-1 10-30

Cyclohexanone 108-94-1 10-30

Polyvinyl chloride 9002-86-2 10-30

Methyl ethyl ketone 78-93-3 5-10

Colloidal silicon dioxide 112945-52-5 1-5

*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.

4. First-aid measures
Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON
CENTER or doctor/physician if you feel unwell.
Skin contact Take off immediately all contaminated clothing. Wash with plenty of soap and water. If skin
irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before
reuse.
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Ingestion Call a physician or poison control center immediately. Do not induce vomiting. If vomiting occurs,
keep head low so that stomach content doesn't get into the lungs. Aspiration may cause
pulmonary edema and pneumonitis.
Most important Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation.
symptoms/effects, acute and Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. May
delayed cause redness and pain.
Indication of immediate Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water
medical attention and special immediately. While flushing, remove clothes which do not adhere to affected area. Call an
treatment needed ambulance. Continue flushing during transport to hospital. In case of shortness of breath, give
oxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed.
General information Take off all contaminated clothing immediately. IF exposed or concerned: Get medical
advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take
precautions to protect themselves. Wash contaminated clothing before reuse.

5. Fire-fighting measures
Suitable extinguishing media Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source
the chemical of ignition and flash back. During fire, gases hazardous to health may be formed.
Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
and precautions for firefighters
Fire fighting In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do
equipment/instructions so without risk.
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards Highly flammable liquid and vapor. This product contains tetrahydrofuran that may form explosive
organic peroxide when exposed to air or light or with age.

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6. Accidental release measures
Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
protective equipment and low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area).
emergency procedures Wear appropriate protective equipment and clothing during clean-up. Avoid inhalation of vapors or
mists. Do not touch damaged containers or spilled material unless wearing appropriate protective
clothing. Ventilate closed spaces before entering them. Local authorities should be advised if
significant spillages cannot be contained. For personal protection, see section 8 of the SDS.
Methods and materials for Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take
containment and cleaning up precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles
(wood, paper, oil, etc.) away from spilled material.

Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Cover with plastic sheet to prevent spreading. Use a non-combustible material like
vermiculite, sand or earth to soak up the product and place into a container for later disposal. Use
water spray to reduce vapors or divert vapor cloud drift. Prevent entry into waterways, sewer,
basements or confined areas. Following product recovery, flush area with water.

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Environmental precautions Avoid discharge into drains, water courses or onto the ground.

7. Handling and storage

Precautions for safe handling Vapors may form explosive mixtures with air. Do not handle, store or open near an open flame,
sources of heat or sources of ignition. Protect material from direct sunlight. Take precautionary
measures against static discharges. All equipment used when handling the product must be
grounded. Use non-sparking tools and explosion-proof equipment. Do not taste or swallow. Avoid
breathing mist or vapor. Avoid contact with skin. Avoid contact with eyes. Avoid prolonged
exposure. Avoid contact with clothing. Provide adequate ventilation. Wear appropriate personal
protective equipment. Observe good industrial hygiene practices. When using, do not eat, drink or
smoke. Wash hands thoroughly after handling.
Conditions for safe storage, Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge
including any incompatibilities build-up by using common bonding and grounding techniques. Store in original tightly closed
container. Store in a cool, dry place out of direct sunlight. Store in a well-ventilated place. Store
away from incompatible materials (see Section 10 of the SDS). Keep in an area equipped with
sprinklers.

8. Exposure controls/personal protection

Occupational exposure limits
U.S. - OSHA

Components Type Value Form

Colloidal silicon dioxide TWA 0.8 mg/m3 Unspecified.
(CAS 112945-52-5)
20 mppcf Unspecified.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Components Type Value

Polyvinyl chloride (CAS STEL 5 ppm
9002-86-2)
TWA 1 ppm
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

Components Type Value Form

2-Propanone (CAS 67-64-1) PEL 2400 mg/m3
1000 ppm
Cyclohexanone (CAS PEL 200 mg/m3
108-94-1)
50 ppm
Furan, Tetrahydro- (CAS PEL 590 mg/m3
109-99-9)
200 ppm

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 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

Components Type Value Form

Methyl ethyl ketone (CAS PEL 590 mg/m3
78-93-3)
200 ppm
Polyvinyl chloride (CAS PEL 5 mg/m3 Respirable fraction.
9002-86-2)
15 mg/m3 Total dust.
US. OSHA Table Z-3 (29 CFR 1910.1000)

Components Type Value

Colloidal silicon dioxide TWA 0.8 mg/m3
(CAS 112945-52-5)
20 mppcf
US. ACGIH Threshold Limit Values

Components Type Value Form

2-Propanone (CAS 67-64-1) STEL 750 ppm
TWA 500 ppm
Cyclohexanone (CAS STEL 50 ppm
108-94-1)
TWA 20 ppm
Furan, Tetrahydro- (CAS STEL 100 ppm
109-99-9)
TWA 50 ppm
Methyl ethyl ketone (CAS STEL 300 ppm
78-93-3)
TWA 200 ppm
Polyvinyl chloride (CAS TWA 1 mg/m3 Respirable fraction.
9002-86-2)
U.S. - NIOSH

Components Type Value Form

Colloidal silicon dioxide REL 6 mg/m3 Unspecified.
(CAS 112945-52-5)
US. NIOSH: Pocket Guide to Chemical Hazards

Components Type Value

2-Propanone (CAS 67-64-1) TWA 590 mg/m3
250 ppm
Colloidal silicon dioxide TWA 6 mg/m3
(CAS 112945-52-5)
Cyclohexanone (CAS TWA 100 mg/m3
108-94-1)
25 ppm
Furan, Tetrahydro- (CAS STEL 735 mg/m3
109-99-9)
250 ppm
TWA 590 mg/m3
200 ppm
Methyl ethyl ketone (CAS STEL 885 mg/m3
78-93-3)
300 ppm
TWA 590 mg/m3
200 ppm

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Biological limit values
ACGIH Biological Exposure Indices

Components Value Determinant Specimen Sampling Time

2-Propanone (CAS 67-64-1) 50 mg/l Acetone Urine *
Cyclohexanone (CAS 80 mg/l 1,2-Cyclohexan Urine *
108-94-1) ediol, with
hydrolysis
8 mg/l Cyclohexanol, Urine *
with hydrolysis
Furan, Tetrahydro- (CAS 2 mg/l Tetrahydrofura Urine *
109-99-9) n
Methyl ethyl ketone (CAS 2 mg/l MEK Urine *
78-93-3)
* - For sampling details, please see the source document.
Exposure guidelines
US - California OELs: Skin designation
Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin.
US - Minnesota Haz Subs: Skin designation applies
Cyclohexanone (CAS 108-94-1) Skin designation applies.
US - Tennessee OELs: Skin designation
Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin.
US ACGIH Threshold Limit Values: Skin designation
Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin.
Furan, Tetrahydro- (CAS 109-99-9) Can be absorbed through the skin.
US. NIOSH: Pocket Guide to Chemical Hazards
Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin.
Appropriate engineering Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 air
controls changes per hour) should be used. Ventilation rates should be matched to conditions. If
applicable, use process enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure limits have not been
established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency
shower must be available when handling this product.
Individual protection measures, such as personal protective equipment
Eye/face protection Wear safety glasses with side shields (or goggles).
Skin protection
Hand protection Wear appropriate chemical resistant gloves.
Other Wear appropriate chemical resistant clothing.
Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene When using, do not eat, drink or smoke. Wash hands after handling and before eating.
considerations

9. Physical and chemical properties

Appearance Opaque.or Translucent.
Physical state Liquid.
Form Liquid.
Color Gray or Clear.
Odor Solvent.
Odor threshold Not available.
pH Not available.
Melting point/freezing point Not available.
Initial boiling point and boiling 151 °F (66.11 °C)
range
Flash point 14.0 - 23.0 °F (-10.0 - -5.0 °C)
Evaporation rate 5.5 - 8
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Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower Not available.
(%)
Flammability limit - upper Not available.
(%)
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure 145 mm Hg @ 20 C
Vapor density 2.5
Relative density 0.88 - 0.92
Solubility(ies)
Solubility (water) Negligible
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity 1200 - 2500 cP
Other information
Bulk density 7.5 lb/gal
VOC (Weight %) <510 g/l SQACMD 1168/M316A

10. Stability and reactivity

Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous No dangerous reaction known under conditions of normal use.
reactions
Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the
flash point. Contact with incompatible materials.
Incompatible materials Acids. Strong oxidizing agents. Ammonia. Amines. Isocyanates. Caustics.
Hazardous decomposition No hazardous decomposition products are known.
products

11. Toxicological information

Information on likely routes of exposure
Inhalation May be fatal if swallowed and enters airways. Vapors have a narcotic effect and may cause
headache, fatigue, dizziness and nausea. Prolonged inhalation may be harmful. May cause
irritation to the respiratory system.
Skin contact Causes skin irritation.
Eye contact Causes serious eye irritation.
Ingestion May be fatal if swallowed and enters airways. Harmful if swallowed.
Symptoms related to the Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May
physical, chemical and cause redness and pain. Symptoms of overexposure may be headache, dizziness, tiredness,
toxicological characteristics nausea and vomiting.
Information on toxicological effects
Acute toxicity May be fatal if swallowed and enters airways. Narcotic effects. May cause respiratory irritation.
Components Species Test Results
Cyclohexanone (CAS 108-94-1)
Acute
Dermal
LD50 Rabbit 948 mg/kg
Inhalation
LC50 Rat 8000 ppm, 4 hours

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Components Species Test Results
Oral
LD50 Rat 1540 mg/kg

* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation Causes skin irritation.
Serious eye damage/eye Causes serious eye irritation.
irritation
Respiratory or skin sensitization
Respiratory sensitization Not available.
Skin sensitization This product is not expected to cause skin sensitization.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity Suspected of causing cancer. In 2012 USEPA Integrated Risk Information System (IRIS)
reviewed a two species inhalation lifetime study on THF conducted by NTP (1998). Male rats
developed renal tumors and female mice developed liver tumors while neither the female rats nor
the male mice showed similar results. Because the carcinogenic mechanisms could not be
identified clearly in either species for either tumor, the EPA determined that the male rat and
female mouse findings are relevant to the assessment of carcinogenic potential in humans.
Therefore, the IRIS review concludes that these data in aggregate indicate that there is
"suggestive evidence of carcinogenic potential" following exposure to THF by all routes of
exposure. This product contains polyvinyl chloride (PVC) that is not a fabricated product, and is
therefore, defined and regulated as a toxic and hazardous substance under 29 C.F.R. §
1910.1017 due to the presumed presence of residual vinyl chloride monomer. The concentrations
of residual vinyl chloride calculated to be contained in this product are well below the threshold for
classification in accordance with 29 C.F.R. § 1910.1200.
IARC Monographs. Overall Evaluation of Carcinogenicity
Colloidal silicon dioxide (CAS 112945-52-5) 3 Not classifiable as to carcinogenicity to humans.
Cyclohexanone (CAS 108-94-1) 3 Not classifiable as to carcinogenicity to humans.
Polyvinyl chloride (CAS 9002-86-2) 3 Not classifiable as to carcinogenicity to humans.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Polyvinyl chloride (CAS 9002-86-2) Cancer
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity - Respiratory tract irritation. Narcotic effects.
single exposure
Specific target organ toxicity - Not classified.
repeated exposure
Aspiration hazard May be fatal if swallowed and enters airways.
Chronic effects Prolonged inhalation may be harmful.

12. Ecological information

Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Components Species Test Results
Cyclohexanone (CAS 108-94-1)
Aquatic
Fish LC50 Fathead minnow (Pimephales promelas) 481 - 578 mg/l, 96 hours

* Estimates for product may be based on additional component data not shown.
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulative potential No data available.
Partition coefficient n-octanol / water (log Kow)
2-Propanone (CAS 67-64-1) -0.24
Cyclohexanone (CAS 108-94-1) 0.81
Furan, Tetrahydro- (CAS 109-99-9) 0.46
Methyl ethyl ketone (CAS 78-93-3) 0.29
Mobility in soil No data available.

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Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations

Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material
and its container must be disposed of as hazardous waste. Do not allow this material to drain into
sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used
container. Dispose of contents/container in accordance with local/regional/national/international
regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some
products product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.

14. Transport information

DOT
UN number UN1133
UN proper shipping name Adhesives
Transport hazard class(es)
Class 3
Subsidiary risk -
Label(s) 3
Packing group II
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Special provisions T11, TP1, TP8, TP27
Packaging exceptions 150
Packaging non bulk 201
Packaging bulk 243
IATA
UN number UN1133
UN proper shipping name Adhesives
Transport hazard class(es)
Class 3
Subsidiary risk -
Packing group II
Environmental hazards No.
ERG Code 3L
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
IMDG
UN number UN1133
UN proper shipping name ADHESIVES
Transport hazard class(es)
Class 3
Subsidiary risk -
Packing group II
Environmental hazards
Marine pollutant No.
EmS F-E, S-D
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Transport in bulk according to Not available.
Annex II of MARPOL 73/78 and
the IBC Code

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15. Regulatory information
US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Polyvinyl chloride (CAS 9002-86-2) Cancer
Central nervous system
Liver
Blood
Flammability
CERCLA Hazardous Substance List (40 CFR 302.4)
2-Propanone (CAS 67-64-1) LISTED
Cyclohexanone (CAS 108-94-1) LISTED
Furan, Tetrahydro- (CAS 109-99-9) LISTED
Methyl ethyl ketone (CAS 78-93-3) LISTED
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - Yes
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous No
chemical
SARA 313 (TRI reporting)
Not regulated.

Other federal regulations

Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and
Chemical Code Number
2-Propanone (CAS 67-64-1) 6532
Methyl ethyl ketone (CAS 78-93-3) 6714
Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c))
2-Propanone (CAS 67-64-1) 35 %WV
Methyl ethyl ketone (CAS 78-93-3) 35 %WV
DEA Exempt Chemical Mixtures Code Number
2-Propanone (CAS 67-64-1) 6532
Methyl ethyl ketone (CAS 78-93-3) 6714
US state regulations
US. Massachusetts RTK - Substance List
2-Propanone (CAS 67-64-1)
Colloidal silicon dioxide (CAS 112945-52-5)
Cyclohexanone (CAS 108-94-1)
Furan, Tetrahydro- (CAS 109-99-9)
Methyl ethyl ketone (CAS 78-93-3)
US. New Jersey Worker and Community Right-to-Know Act
2-Propanone (CAS 67-64-1)
Cyclohexanone (CAS 108-94-1)
Furan, Tetrahydro- (CAS 109-99-9)
Methyl ethyl ketone (CAS 78-93-3)

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 Polyvinyl chloride (CAS 9002-86-2)
US. Pennsylvania Worker and Community Right-to-Know Law
2-Propanone (CAS 67-64-1)
Colloidal silicon dioxide (CAS 112945-52-5)
Cyclohexanone (CAS 108-94-1)
Furan, Tetrahydro- (CAS 109-99-9)
Methyl ethyl ketone (CAS 78-93-3)
US. Rhode Island RTK
2-Propanone (CAS 67-64-1)
Cyclohexanone (CAS 108-94-1)
Furan, Tetrahydro- (CAS 109-99-9)
Methyl ethyl ketone (CAS 78-93-3)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins. This product contains trace amounts of chemicals
known to the state of California to cause cancer. Under normal use conditions, exposure to these chemicals at levels above
the State of California “No significant Risk Level” (NSRL) are unlikely. The use of proper personal protective equipment
(PPE) and ventilation guidelines noted in Section 8 will minimize exposure levels to these chemicals.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Chemical Substances (AICS) Yes
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) Yes
Europe European Inventory of Existing Commercial Chemical No
Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) Yes
Korea Existing Chemicals List (ECL) Yes
New Zealand New Zealand Inventory Yes
Philippines Philippine Inventory of Chemicals and Chemical Substances Yes
(PICCS)
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

16. Other information, including date of preparation or last revision

Issue date 04-August-2014
Revision date 15-December-2014
Version # 02
HMIS® ratings Health: 2
Flammability: 3
Physical hazard: 0
Disclaimer The information in the sheet was written based on the best knowledge and experience currently
available.

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Date Printed: 4/2/2020 Page 1 / 6

Safety Data Sheet

* Trusted Quality Since 1921 *
www.rustoleum.com

1. Identification
Product Name: PRO LSPR 6PK MARK FLUORESCENT Revision Date: 4/2/2020
ORANGE

Product Identifier: 2554838 Supercedes Date: 5/12/2017

Recommended Use: Marking Paint/Aerosols

Supplier: Rust-Oleum Corporation Manufacturer: Rust-Oleum Corporation

11 Hawthorn Parkway 11 Hawthorn Parkway
Vernon Hills, IL 60061 Vernon Hills, IL 60061
USA USA

Preparer: Regulatory Department

Emergency Telephone: 24 Hour Hotline: 847-367-7700

2. Hazard Identification

Classification
Symbol(s) of Product

Signal Word
Danger

Possible Hazards
27% of the mixture consists of ingredient(s) of unknown acute toxicity.

GHS HAZARD STATEMENTS

Flammable Aerosol, category 1 H222 Extremely flammable aerosol.
Compressed Gas H280 Contains gas under pressure; may explode if heated.
Carcinogenicity, category 2 H351 Suspected of causing cancer.
STOT, repeated exposure, category 2 H373 May cause damage to organs through prolonged or repeated exposure.

GHS LABEL PRECAUTIONARY STATEMENTS

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. NO
SMOKING.
P211 Do not spray on an open flame or other ignition source.
P251 Do not pierce or burn, even after use.
P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50°C / 122°F.
P410+P403 Protect from sunlight. Store in a well-ventilated place.
P201 Obtain special instructions before use.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local, regional and national regulations.
Date Printed: 4/2/2020 Page 2 / 6
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P314 Get medical advice/attention if you feel unwell.

3. Composition / Information On Ingredients

HAZARDOUS SUBSTANCES
Chemical Name CAS-No. Wt.% GHS Symbols GHS Statements
Range
Propane 74-98-6 10-25 GHS04 H280

n-Butane 106-97-8 2.5-10 GHS04 H280

Naphtha, Petroleum, Hydrotreated Light 64742-49-0 2.5-10 GHS08 H304

Hydrotreated Light Distillate 64742-47-8 2.5-10 GHS08 H304

Xylenes (o-, m-, p- Isomers) 1330-20-7 2.5-10 GHS02-GHS07 H226-315-319-332

Barium Sulfate 7727-43-7 2.5-10 GHS07 H332

GHS02-GHS07-
Ethylbenzene 100-41-4 1.0-2.5 H225-304-332-351-373
GHS08

Stoddard Solvent 8052-41-3 0.1-1.0 GHS08 H304-372

GHS02-GHS07-
Octane 111-65-9 0.1-1.0 H225-304-315-336
GHS08

Pigment Orange 13 3520-72-7 0.1-1.0 Not Available Not Available

Crystalline Silica / Quartz 14808-60-7 0.1-1.0 Not Available Not Available

4. First-Aid Measures
FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical
attention. Do NOT allow rubbing of eyes or keeping eyes closed.
FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation
develops or persists.
FIRST AID - INHALATION: If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is
experienced, get medical assistance immediately. Remove to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation.
FIRST AID - INGESTION: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the
lungs and cause severe lung damage. Get immediate medical attention. If swallowed, get medical attention.

5. Fire-Fighting Measures

EXTINGUISHING MEDIA: Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Dry Sand, Water Fog

UNUSUAL FIRE AND EXPLOSION HAZARDS: FLASH POINT IS LESS THAN 20°F. EXTREMELY FLAMMABLE LIQUID AND
VAPOR!Water spray may be ineffective. Closed containers may explode when exposed to extreme heat. Vapors may form explosive
mixtures with air. Vapors can travel to a source of ignition and flash back. Isolate from heat, electrical equipment, sparks and open
flame. Perforation of the pressurized container may cause bursting of the can. Closed containers may explode when exposed to
extreme heat due to buildup of steam.
SPECIAL FIREFIGHTING PROCEDURES: Evacuate area and fight fire from a safe distance. Full protective equipment including
self-contained breathing apparatus should be used. Water may be used to cool closed containers to prevent pressure buildup and
possible autoignition or explosion. Use water spray to keep fire-exposed containers cool. Containers may explode when heated.
Special Fire and Explosion Hazard (Combustible Dust): No Information

6. Accidental Release Measures

Date Printed: 4/2/2020 Page 3 / 6
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled liquid with sand or earth. DO NOT use
combustible materials such as sawdust. Remove all sources of ignition, ventilate area and remove with inert absorbent and non-
sparking tools. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers. Isolate
the hazard area and deny entry to unnecessary and unprotected personnel. Ventilate area, isolate spilled material, and remove with
inert absorbent. Dispose of contaminated absorbent, container, and unused contents in accordance with local, state, and federal
regulations.

7. Handling and Storage

HANDLING: Wash thoroughly after handling. Wash hands before eating. Use only in a well-ventilated area. Follow all SDS and
label precautions even after container is emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist.
Remove contaminated clothing and launder before reuse. Use only with adequate ventilation. Avoid contact with eyes, skin and
clothing.
STORAGE: Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Contents under
pressure. Do not store above 120 ° F. Store large quantities in buildings designed and protected for storage of flammable aerosols.
Contents under pressure. Do not expose to heat or store above 120 ° F. Product should be stored in tightly sealed containers and
protected from heat, moisture, and foreign materials. Keep away from heat, sparks, flame and sources of ignition. Avoid excess
heat.
Advice on Safe Handling of Combustible Dust: No Information

8. Exposure Controls / Personal Protection

Weight % ACGIH TLV- ACGIH TLV- OSHA PEL-

Chemical Name CAS-No. Less Than TWA STEL
OSHA PEL-TWA
CEILING
Propane 74-98-6 20.0 N.E. N.E. 1000 ppm N.E.
n-Butane 106-97-8 10.0 N.E. 1000 ppm N.E. N.E.
Naphtha, Petroleum,
64742-49-0 10.0 N.E. N.E. N.E. N.E.
Hydrotreated Light
Hydrotreated Light Distillate 64742-47-8 10.0 N.E. N.E. N.E. N.E.
Xylenes (o-, m-, p- Isomers) 1330-20-7 5.0 100 ppm 150 ppm 100 ppm N.E.
Barium Sulfate 7727-43-7 5.0 5 mg/m3 N.E. 15 mg/m3 N.E.
Ethylbenzene 100-41-4 5.0 20 ppm N.E. 100 ppm N.E.
Stoddard Solvent 8052-41-3 1.0 100 ppm N.E. 500 ppm N.E.
Octane 111-65-9 1.0 300 ppm N.E. 500 ppm N.E.
Pigment Orange 13 3520-72-7 1.0 N.E. N.E. N.E. N.E.
Crystalline Silica / Quartz 14808-60-7 1.0 0.025 mg/m3 N.E. 50 µg/m3 N.E.

PERSONAL PROTECTION

ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne
levels below recommended exposure limits. Use explosion-proof ventilation equipment. Prevent build-up of vapors by opening all
doors and windows to achieve cross-ventilation. Provide general dilution of local exhaust ventilation in volume and pattern to keep
TLV of hazardous ingredients below acceptable limits.
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be
followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with organic
vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed
exposure limits.
SKIN PROTECTION: Use impervious gloves to prevent skin contact and absorption of this material through the skin.
EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further information regarding personal
protective equipment and its application. Refer to safety supervisor or industrial hygienist for further guidance regarding types of
personal protective equipment and their applications.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing
immediately and launder before reuse.
Engineering Measures for Combustible Dust: No Information
Date Printed: 4/2/2020 Page 4 / 6

9. Physical and Chemical Properties

Appearance: Aerosolized Mist Physical State: Liquid
Odor: Solvent Like Odor Threshold: N.E.
Specific Gravity: 0.857 pH: N.A.
Freeze Point, °C: N.D. Viscosity: N.D.
Solubility in Water: Slight Partition Coefficient, n-octanol/
water: N.D.
Decompostion Temp., °C: N.D.
Boiling Range, °C: -37 - 537 Explosive Limits, vol%: 0.9 - 12.6
Flammability: Supports Combustion Flash Point, °C: -96
Evaporation Rate: Faster than Ether Auto-ignition Temp., °C: N.D.
Vapor Density: Heavier than Air Vapor Pressure: N.D.

(See "Other information" Section for abbreviation legend)

10. Stability and Reactivity

CONDITIONS TO AVOID: Avoid temperatures above 120°F (49°C). Avoid all possible sources of ignition.
INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies.
HAZARDOUS DECOMPOSITION: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits
acrid smoke and irritating fumes. Contains solvents which may form carbon monoxide, carbon dioxide, and formaldehyde.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.

11. Toxicological Information

EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes Serious Eye Irritation
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Substance may cause slight skin irritation. Prolonged or repeated contact may
cause skin irritation.
EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. High gas, vapor, mist or dust concentrations may be harmful if
inhaled. Avoid breathing fumes, spray, vapors, or mist. High vapor concentrations are irritating to the eyes, nose, throat and lungs.
Prolonged or excessive inhalation may cause respiratory tract irritation.
EFFECTS OF OVEREXPOSURE - INGESTION: Harmful if swallowed.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Overexposure to xylene in laboratory animals has been associated with
liver abnormalities, kidney, lung, spleen, eye and blood damage as well as reproductive disorders. Effects in humans, due to chronic
overexposure, have included liver, cardiac abnormalities and nervous system damage. IARC lists Ethylbenzene as a possible human
carcinogen (group 2B). Reports have associated repeated and prolonged occupational overexposure to solvents with permanent
brain and nervous system damage. May cause central nervous system disorder (e.g., narcosis involving a loss of coordination,
weakness, fatigue, mental confusion, and blurred vision) and/or damage. High concentrations may lead to central nervous system
effects (drowsiness, dizziness, nausea, headaches, paralysis, and blurred vision) and/or damage.
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact

ACUTE TOXICITY VALUES

The acute effects of this product have not been tested. Data on individual components are tabulated below:
CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50
106-97-8 n-Butane N.E. N.E. 658 mg/L Rat
64742-49-0 Naphtha, Petroleum, Hydrotreated Light >5000 mg/kg Rat >3160 mg/kg Rabbit >4951 mg/L Rat
64742-47-8 Hydrotreated Light Distillate >5000 mg/kg Rat >2000 mg/kg Rabbit >5000 mg/L Rat
1330-20-7 Xylenes (o-, m-, p- Isomers) 3500 mg/kg Rat >4350 mg/kg Rabbit 29.08 mg/L Rat
7727-43-7 Barium Sulfate 307000 mg/kg Rat N.E. N.E.
100-41-4 Ethylbenzene 3500 mg/kg Rat 15400 mg/kg Rabbit 17.4 mg/L Rat
111-65-9 Octane N.E. N.E. >23.36 mg/L Rat
3520-72-7 Pigment Orange 13 >5000 mg/kg Rat N.E. N.E.
14808-60-7 Crystalline Silica / Quartz 5500 mg/kg Rat 5500 100 mg/L

N.E. - Not Established

12. Ecological Information

ECOLOGICAL INFORMATION: Product is a mixture of listed components. Product is a mixture of listed components.
Date Printed: 4/2/2020 Page 5 / 6

13. Disposal Information

DISPOSAL INFORMATION: Dispose of material in accordance to local, state, and federal regulations and ordinances. This product
as supplied is a USEPA defined ignitable hazardous waste. Dispose of unusable product as a hazardous waste (D001) in
accordance with local, state, and federal regulation. Do not incinerate closed containers.

14. Transport Information

Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)
UN Number: N.A. 1950 1950 N.A.

Paint and Related Spray

Proper Shipping Name: Aerosols Aerosols, flammable Aerosols
Products in Ltd Qty

Hazard Class: N.A. 2 2.1 N.A.

Packing Group: N.A. N.A. N.A. N.A.
Limited Quantity: Yes Yes Yes Yes

15. Regulatory Information

U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
Gas under pressure, Carcinogenicity, Specific target organ toxicity (single or repeated exposure)
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:

Chemical Name CAS-No.

Xylenes (o-, m-, p- Isomers) 1330-20-7
Ethylbenzene 100-41-4
Toxic Substances Control Act:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(b) if exported from
the United States:
Chemical Name CAS-No.
Castor oil, sulfated, sodium salt 68187-76-8

U.S. State Regulations:

California Proposition 65:

WARNING: Cancer and Reproductive Harm - www.P65Warnings.ca.gov.

Date Printed: 4/2/2020 Page 6 / 6

16. Other Information

HMIS RATINGS
Health: 2* Flammability: 4 Physical Hazard: 0 Personal Protection: X

NFPA RATINGS
Health: 2 Flammability: 4 Instability 0

Maximum Incremental Reactivity 0.82

SDS REVISION DATE: 4/2/2020
REASON FOR REVISION: Revision Description Changed
Product Composition Changed
Substance and/or Product Properties Changed in Section(s):
09 - Physical & Chemical Properties
14 - Transport Information
15 - Regulatory Information
16 - Other Information
Revision Statement(s) Changed
Legend: N.A. - Not Applicable, N.D. - Not Determined, N.E. - Not Established

Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be
accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of
these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by
the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or
reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with
caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and
examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable
international, federal, state, and local laws and regulations.
 SAFETY DATA SHEET
Oxygen

Section 1. Identification
GHS product identifier : Oxygen
Chemical name : oxygen
Other means of : Molecular oxygen; Oxygen molecule; Pure oxygen; O2; UN 1072; Dioxygen; Oxygen
identification USP, Aviator’s Breathing Oxygen (ABO)
Product type : Gas.
Product use : Synthetic/Analytical chemistry.
Synonym : Molecular oxygen; Oxygen molecule; Pure oxygen; O2; UN 1072; Dioxygen; Oxygen
USP, Aviator’s Breathing Oxygen (ABO)
SDS # : 001043
Supplier's details : Airgas USA, LLC and its affiliates
259 North Radnor-Chester Road
Suite 100
Radnor, PA 19087-5283
1-610-687-5253

24-hour telephone : 1-866-734-3438

Section 2. Hazards identification

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : OXIDIZING GASES - Category 1
substance or mixture GASES UNDER PRESSURE - Compressed gas

GHS label elements

Hazard pictograms :

Signal word : Danger

Hazard statements : May cause or intensify fire; oxidizer.
Contains gas under pressure; may explode if heated.
Precautionary statements
General : Read and follow all Safety Data Sheets (SDS’S) before use. Read label before use.
Keep out of reach of children. If medical advice is needed, have product container or
label at hand. Close valve after each use and when empty. Use equipment rated for
cylinder pressure. Do not open valve until connected to equipment prepared for use.
Use a back flow preventative device in the piping. Use only equipment of compatible
materials of construction. Open valve slowly. Use only with equipment cleaned for
Oxygen service.
Prevention : Keep away from clothing and other combustible materials. Keep reduction valves,
valves and fittings free from oil and grease.
Response : In case of fire: Stop leak if safe to do so.
Storage : Protect from sunlight. Store in a well-ventilated place.
Disposal : Not applicable.
Hazards not otherwise : None known.
classified

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Oxygen

Section 3. Composition/information on ingredients

Substance/mixture : Substance
Chemical name : oxygen
Other means of : Molecular oxygen; Oxygen molecule; Pure oxygen; O2; UN 1072; Dioxygen; Oxygen
identification USP, Aviator’s Breathing Oxygen (ABO)
Product code : 001043

CAS number/other identifiers

CAS number : 7782-44-7
Ingredient name % CAS number
oxygen 100 7782-44-7
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects
persist or are severe. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean
shoes thoroughly before reuse.
Ingestion : As this product is a gas, refer to the inhalation section.

Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : Contact with rapidly expanding gas may cause burns or frostbite.
Inhalation : No known significant effects or critical hazards.
Skin contact : Contact with rapidly expanding gas may cause burns or frostbite.
Frostbite : Try to warm up the frozen tissues and seek medical attention.
Ingestion : As this product is a gas, refer to the inhalation section.
Over-exposure signs/symptoms
Eye contact : No specific data.
Inhalation : No specific data.
Skin contact : No specific data.
Ingestion : No specific data.

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.

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Oxygen

Section 4. First aid measures

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media
Unsuitable extinguishing : None known.
media

Specific hazards arising : Contains gas under pressure. Oxidizing material. This material increases the risk of
from the chemical fire and may aid combustion. Contact with combustible material may cause fire. In a
fire or if heated, a pressure increase will occur and the container may burst or explode.
Hazardous thermal : No specific data.
decomposition products

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Contact supplier immediately for specialist advice. Move containers from fire
area if this can be done without risk. Use water spray to keep fire-exposed containers
cool. If involved in fire, shut off flow immediately if it can be done without risk.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Shut off all ignition sources. No flares, smoking or flames in hazard area.
Avoid breathing gas. Provide adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Put on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

Environmental precautions : Ensure emergency procedures to deal with accidental gas releases are in place to avoid
contamination of the environment. Inform the relevant authorities if the product has
caused environmental pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up

Small spill : Immediately contact emergency personnel. Stop leak if without risk. Use spark-proof
tools and explosion-proof equipment.
Large spill : Immediately contact emergency personnel. Stop leak if without risk. Use spark-proof
tools and explosion-proof equipment. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.

Section 7. Handling and storage

Precautions for safe handling

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Oxygen

Section 7. Handling and storage

Protective measures : Put on appropriate personal protective equipment (see Section 8). Contains gas under
pressure. Avoid breathing gas. Do not puncture or incinerate container. Use
equipment rated for cylinder pressure. Close valve after each use and when empty.
Protect cylinders from physical damage; do not drag, roll, slide, or drop. Use a suitable
hand truck for cylinder movement.
Avoid contact with eyes, skin and clothing. Empty containers retain product residue
and can be hazardous. Keep away from clothing, incompatible materials and
combustible materials. Keep reduction valves free from grease and oil.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved area.
including any Store away from direct sunlight in a dry, cool and well-ventilated area, away from
incompatibilities incompatible materials (see Section 10). Cylinders should be stored upright, with valve
protection cap in place, and firmly secured to prevent falling or being knocked over.
Cylinder temperatures should not exceed 52 °C (125 °F). Separate from reducing
agents and combustible materials. Store away from grease and oil. Keep container
tightly closed and sealed until ready for use. See Section 10 for incompatible materials
before handling or use.

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
Ingredient name Exposure limits
oxygen None.

Appropriate engineering : Good general ventilation should be sufficient to control worker exposure to airborne
controls contaminants.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: safety glasses with side-
shields.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.

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Oxygen

Section 8. Exposure controls/personal protection

Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use. Respirator selection must be based on known or anticipated exposure
levels, the hazards of the product and the safe working limits of the selected respirator.

Section 9. Physical and chemical properties

Appearance
Physical state : Gas. [Compressed gas.]
Color : Colorless. Blue.
Odor : Odorless.
Odor threshold : Not available.
pH : Not available.
Melting point : -218.4°C (-361.1°F)
Boiling point : -183°C (-297.4°F)
Critical temperature : -118.15°C (-180.7°F)
Flash point : [Product does not sustain combustion.]
Evaporation rate : Not available.
Flammability (solid, gas) : Extremely flammable in the presence of the following materials or conditions: reducing
materials, combustible materials and organic materials.
Lower and upper explosive : Not available.
(flammable) limits
Vapor pressure : Not available.
Vapor density : 1.1 (Air = 1)
Specific Volume (ft 3/lb) : 12.0482
Gas Density (lb/ft ) 3
: 0.083
Relative density : Not applicable.
Solubility : Not available.
Solubility in water : Not available.
Partition coefficient: n- : 0.65
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Not applicable.
Flow time (ISO 2431) : Not available.
Molecular weight : 32 g/mole

Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Hazardous reactions or instability may occur under certain conditions of storage or use.
reactions Conditions may include the following:
contact with combustible materials
Reactions may include the following:
risk of causing fire
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Oxygen

Section 10. Stability and reactivity

Conditions to avoid : No specific data.

Incompatible materials : Highly reactive or incompatible with the following materials:

combustible materials
reducing materials
grease
oil

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.

Hazardous polymerization : Under normal conditions of storage and use, hazardous polymerization will not occur.

Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Not available.
Irritation/Corrosion
Not available.
Sensitization
Not available.
Mutagenicity
Not available.
Carcinogenicity
Not available.
Reproductive toxicity
Not available.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Not available.
Specific target organ toxicity (repeated exposure)
Not available.
Aspiration hazard
Not available.

Information on the likely : Not available.

routes of exposure
Potential acute health effects
Eye contact : Contact with rapidly expanding gas may cause burns or frostbite.
Inhalation : No known significant effects or critical hazards.
Skin contact : Contact with rapidly expanding gas may cause burns or frostbite.
Ingestion : As this product is a gas, refer to the inhalation section.

Symptoms related to the physical, chemical and toxicological characteristics

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Oxygen

Section 11. Toxicological information

Eye contact : No specific data.
Inhalation : No specific data.
Skin contact : No specific data.
Ingestion : No specific data.

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.

General : No known significant effects or critical hazards.

Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates
Not available.

Section 12. Ecological information

Toxicity
Not available.

Persistence and degradability

Not available.

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
oxygen 0.65 - low

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

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Oxygen

Section 13. Disposal considerations

Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Empty Airgas-owned pressure vessels should be returned to Airgas. Waste packaging
should be recycled. Incineration or landfill should only be considered when recycling is
not feasible. This material and its container must be disposed of in a safe way. Empty
containers or liners may retain some product residues. Do not puncture or incinerate
container.

Section 14. Transport information

DOT TDG Mexico IMDG IATA
UN number UN1072 UN1072 UN1072 UN1072 UN1072

UN proper OXYGEN, OXYGEN, OXYGEN, OXYGEN, OXYGEN,

shipping name COMPRESSED COMPRESSED COMPRESSED COMPRESSED COMPRESSED
Transport 2.2 (5.1) 2.2 2.2 (5.1) 2.2 (5.1) 2.2 (5.1)
hazard class(es)

Packing group - - - - -
Environmental No. No. No. No. No.
hazards
“Refer to CFR 49 (or authority having jurisdiction) to determine the information required for shipment of the
product.”

Additional information
DOT Classification : Limited quantity Yes.
Quantity limitation Passenger aircraft/rail: 75 kg. Cargo aircraft: 150 kg.
Special provisions A52
TDG Classification : Product classified as per the following sections of the Transportation of Dangerous
Goods Regulations: 2.13-2.17 (Class 2), 2.23-2.25 (Class 5).
Explosive Limit and Limited Quantity Index 0.125
ERAP Index 3000
Passenger Carrying Vessel Index 50
Passenger Carrying Road or Rail Index 75
Special provisions 42
IATA : Quantity limitation Passenger and Cargo Aircraft: 75 kg. Cargo Aircraft Only: 150 kg.

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.

Transport in bulk according : Not available.

to IMO instruments

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Oxygen

Section 15. Regulatory information

U.S. Federal regulations : TSCA 8(a) CDR Exempt/Partial exemption: This material is listed or exempted.

Clean Air Act Section 112 : Not listed

(b) Hazardous Air
Pollutants (HAPs)
Clean Air Act Section 602 : Not listed
Class I Substances
Clean Air Act Section 602 : Not listed
Class II Substances
DEA List I Chemicals : Not listed
(Precursor Chemicals)
DEA List II Chemicals : Not listed
(Essential Chemicals)
SARA 302/304
Composition/information on ingredients
No products were found.
SARA 304 RQ : Not applicable.
SARA 311/312
Classification : Refer to Section 2: Hazards Identification of this SDS for classification of substance.

State regulations
Massachusetts : This material is listed.
New York : This material is not listed.
New Jersey : This material is listed.
Pennsylvania : This material is listed.
California Prop. 65
This product does not require a Safe Harbor warning under California Prop. 65.
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
Montreal Protocol
Not listed.

Stockholm Convention on Persistent Organic Pollutants

Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
Inventory list
Australia : This material is listed or exempted.
Canada : This material is listed or exempted.
China : This material is listed or exempted.
Europe : This material is listed or exempted.
Japan : Japan inventory (ENCS): Not determined.
Japan inventory (ISHL): Not determined.
New Zealand : This material is listed or exempted.
Philippines : This material is listed or exempted.

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Oxygen

Section 15. Regulatory information

Republic of Korea : This material is listed or exempted.
Taiwan : This material is listed or exempted.
Thailand : Not determined.
Turkey : Not determined.
United States : This material is active or exempted.
Viet Nam : This material is listed or exempted.

Section 16. Other information

Hazardous Material Information System (U.S.A.)
Health / 0

Flammability 0
Physical hazards 3

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS®
ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
National Fire Protection Association (U.S.A.)

0 Flammability
Health 0 0 Instability/Reactivity
OX
Special

Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Procedure used to derive the classification
Classification Justification
OXIDIZING GASES - Category 1 Expert judgment
GASES UNDER PRESSURE - Compressed gas According to package
History
Date of printing : 9/22/2020
Date of issue/Date of : 9/22/2020
revision
Date of previous issue : 2/3/2018
Version : 1
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient

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Oxygen

Section 16. Other information

MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
References : Not available.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.

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 SAFETY DATA SHEET
Propane

Section 1. Identification
GHS product identifier : Propane
Chemical name : propane
Other means of : Propyl hydride; n-Propane; Dimethyl methane; Bottled gas; propane in gaseous state;
identification propane liquefied, n-Propane; Dimethylmethane; Freon 290; Liquefied petroleum gas;
Lpg; Propyl
hydride; R 290; C3H8; UN 1075; UN 1978; A-108; Hydrocarbon propellant.
Product type : Liquefied gas
Product use : Synthetic/Analytical chemistry.
Synonym : Propyl hydride; n-Propane; Dimethyl methane; Bottled gas; propane in gaseous state;
propane liquefied, n-Propane; Dimethylmethane; Freon 290; Liquefied petroleum gas;
Lpg; Propyl
hydride; R 290; C3H8; UN 1075; UN 1978; A-108; Hydrocarbon propellant.
SDS # : 001045
Supplier's details : Airgas USA, LLC and its affiliates
259 North Radnor-Chester Road
Suite 100
Radnor, PA 19087-5283
1-610-687-5253

24-hour telephone : 1-866-734-3438

Section 2. Hazards identification

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : FLAMMABLE GASES - Category 1
substance or mixture GASES UNDER PRESSURE - Liquefied gas

GHS label elements

Hazard pictograms :

Signal word : Danger

Hazard statements : Extremely flammable gas.
Contains gas under pressure; may explode if heated.
May cause frostbite.
May displace oxygen and cause rapid suffocation.
May form explosive mixtures with air.
Precautionary statements
General : Read and follow all Safety Data Sheets (SDS’S) before use. Read label before use.
Keep out of reach of children. If medical advice is needed, have product container or
label at hand. Close valve after each use and when empty. Use equipment rated for
cylinder pressure. Do not open valve until connected to equipment prepared for use.
Use a back flow preventative device in the piping. Use only equipment of compatible
materials of construction. Always keep container in upright position. Approach
suspected leak area with caution.
Prevention : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
Response : Leaking gas fire: Do not extinguish, unless leak can be stopped safely. In case of
leakage, eliminate all ignition sources.
Storage : Protect from sunlight. Store in a well-ventilated place.

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Propane

Section 2. Hazards identification

Disposal : Not applicable.
Hazards not otherwise : Liquid can cause burns similar to frostbite.
classified

Section 3. Composition/information on ingredients

Substance/mixture : Substance
Chemical name : propane
Other means of : Propyl hydride; n-Propane; Dimethyl methane; Bottled gas; propane in gaseous state;
identification propane liquefied, n-Propane; Dimethylmethane; Freon 290; Liquefied petroleum gas;
Lpg; Propyl
hydride; R 290; C3H8; UN 1075; UN 1978; A-108; Hydrocarbon propellant.
Product code : 001045

CAS number/other identifiers

CAS number : 74-98-6
Ingredient name % CAS number
Propane 100 74-98-6
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention if irritation occurs.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects
persist or are severe. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.
Skin contact : Wash contaminated skin with soap and water. Remove contaminated clothing and
shoes. To avoid the risk of static discharges and gas ignition, soak contaminated
clothing thoroughly with water before removing it. Get medical attention if symptoms
occur. In case of contact with liquid, warm frozen tissues slowly with lukewarm water
and get medical attention. Do not rub affected area. Wash clothing before reuse.
Clean shoes thoroughly before reuse.
Ingestion : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get
medical attention if adverse health effects persist or are severe. Ingestion of liquid can
cause burns similar to frostbite. If frostbite occurs, get medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband. As this product rapidly becomes a gas when
released, refer to the inhalation section.

Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : Liquid can cause burns similar to frostbite.
Inhalation : No known significant effects or critical hazards.
Skin contact : Dermal contact with rapidly evaporating liquid could result in freezing of the tissues or
frostbite.
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Propane

Section 4. First aid measures

Frostbite : Try to warm up the frozen tissues and seek medical attention.
Ingestion : Ingestion of liquid can cause burns similar to frostbite.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:, frostbite
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:, frostbite
Ingestion : Adverse symptoms may include the following:, frostbite

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media
Unsuitable extinguishing : None known.
media

Specific hazards arising : Contains gas under pressure. Extremely flammable gas. In a fire or if heated, a
from the chemical pressure increase will occur and the container may burst, with the risk of a subsequent
explosion. The vapor/gas is heavier than air and will spread along the ground. Gas
may accumulate in low or confined areas or travel a considerable distance to a source
of ignition and flash back, causing fire or explosion.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Contact supplier immediately for specialist advice. Move containers from fire
area if this can be done without risk. Use water spray to keep fire-exposed containers
cool. If involved in fire, shut off flow immediately if it can be done without risk. If this is
impossible, withdraw from area and allow fire to burn. Fight fire from protected location
or maximum possible distance. Eliminate all ignition sources if safe to do so.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode. For
incidents involving large quantities, thermally insulated undergarments and thick textile
or leather gloves should be worn.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : Accidental releases pose a serious fire or explosion hazard. No action shall be taken
personnel involving any personal risk or without suitable training. Evacuate surrounding areas.
Keep unnecessary and unprotected personnel from entering. Do not touch or walk
through spilled material. Shut off all ignition sources. No flares, smoking or flames in
hazard area. Avoid breathing gas. Provide adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Put on appropriate personal protective
equipment.

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Propane

Section 6. Accidental release measures

For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

Environmental precautions : Ensure emergency procedures to deal with accidental gas releases are in place to avoid
contamination of the environment. Avoid dispersal of spilled material and runoff and
contact with soil, waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up

Small spill : Immediately contact emergency personnel. Stop leak if without risk. Use spark-proof
tools and explosion-proof equipment.
Large spill : Immediately contact emergency personnel. Stop leak if without risk. Use spark-proof
tools and explosion-proof equipment. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.

Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Contains gas under
pressure. Do not get in eyes or on skin or clothing. Avoid breathing gas. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do
not enter storage areas and confined spaces unless adequately ventilated. Do not
puncture or incinerate container. Use equipment rated for cylinder pressure. Close
valve after each use and when empty. Protect cylinders from physical damage; do not
drag, roll, slide, or drop. Use a suitable hand truck for cylinder movement.
Use only non-sparking tools. Empty containers retain product residue and can be
hazardous. Store and use away from heat, sparks, open flame or any other ignition
source. Use explosion-proof electrical (ventilating, lighting and material handling)
equipment.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved area.
including any Store away from direct sunlight in a dry, cool and well-ventilated area, away from
incompatibilities incompatible materials (see Section 10). Eliminate all ignition sources. Cylinders
should be stored upright, with valve protection cap in place, and firmly secured to
prevent falling or being knocked over. Cylinder temperatures should not exceed 52 °C
(125 °F). Keep container tightly closed and sealed until ready for use. See Section 10
for incompatible materials before handling or use.

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
Ingredient name Exposure limits
Propane NIOSH REL (United States, 10/2016).
TWA: 1800 mg/m³ 10 hours.
TWA: 1000 ppm 10 hours.
OSHA PEL (United States, 5/2018).
TWA: 1800 mg/m³ 8 hours.
TWA: 1000 ppm 8 hours.
OSHA PEL 1989 (United States, 3/1989).
TWA: 1800 mg/m³ 8 hours.
TWA: 1000 ppm 8 hours.
ACGIH TLV (United States, 3/2019). Oxygen
Depletion [Asphyxiant]. Explosive potential.
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Propane

Section 8. Exposure controls/personal protection

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: safety glasses with side-
shields.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. If contact with the liquid is possible, insulated gloves suitable for low
temperatures should be worn. Considering the parameters specified by the glove
manufacturer, check during use that the gloves are still retaining their protective
properties. It should be noted that the time to breakthrough for any glove material may
be different for different glove manufacturers. In the case of mixtures, consisting of
several substances, the protection time of the gloves cannot be accurately estimated.
Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Thermal hazards : If there is a risk of contact with the liquid, all protective equipment worn should be
suitable for use with extremely low temperature materials.

Section 9. Physical and chemical properties

Appearance
Physical state : Gas.
Color : Colorless.
Odor : Odorless.BUT MAY HAVE SKUNK ODOR ADDED.
Odor threshold : Not available.
pH : Not available.
Melting point : -187.6°C (-305.7°F)
Boiling point : -42.1°C (-43.8°F)

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Propane

Section 9. Physical and chemical properties

Critical temperature : 96.55°C (205.8°F)
Flash point : Closed cup: -104°C (-155.2°F)
Open cup: -104°C (-155.2°F)
Evaporation rate : Not available.
Flammability (solid, gas) : Extremely flammable in the presence of the following materials or conditions: open
flames, sparks and static discharge and oxidizing materials.
Lower and upper explosive : Lower: 1.8%
(flammable) limits Upper: 8.4%
Vapor pressure : 109 (psig)
Vapor density : 1.6 (Air = 1)
Specific Volume (ft 3/lb) : 8.6206
Gas Density (lb/ft 3) : 0.116 (25°C / 77 to °F)
Relative density : Not applicable.
Solubility : Not available.
Solubility in water : 0.0244 g/l
Partition coefficient: n- : 1.09
octanol/water
Auto-ignition temperature : 287°C (548.6°F)
Decomposition temperature : Not available.
Viscosity : Not applicable.
Flow time (ISO 2431) : Not available.
Molecular weight : 44.11 g/mole
Aerosol product
Heat of combustion : -46012932 J/kg

Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow gas to accumulate in low or confined areas.

Incompatible materials : Oxidizers

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.

Hazardous polymerization : Under normal conditions of storage and use, hazardous polymerization will not occur.

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Propane

Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Not available.
Irritation/Corrosion
Not available.
Sensitization
Not available.
Mutagenicity
Not available.
Carcinogenicity
Not available.
Reproductive toxicity
Not available.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Not available.
Specific target organ toxicity (repeated exposure)
Not available.
Aspiration hazard
Not available.

Information on the likely : Not available.

routes of exposure
Potential acute health effects
Eye contact : Liquid can cause burns similar to frostbite.
Inhalation : No known significant effects or critical hazards.
Skin contact : Dermal contact with rapidly evaporating liquid could result in freezing of the tissues or
frostbite.
Ingestion : Ingestion of liquid can cause burns similar to frostbite.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:, frostbite
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:, frostbite
Ingestion : Adverse symptoms may include the following:, frostbite

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.

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Propane

Section 11. Toxicological information

Potential chronic health effects
Not available.
General : No known significant effects or critical hazards.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates
Not available.

Section 12. Ecological information

Toxicity
Not available.

Persistence and degradability

Not available.

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
Propane 1.09 - low

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations

Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Empty Airgas-owned pressure vessels should be returned to Airgas. Waste packaging
should be recycled. Incineration or landfill should only be considered when recycling is
not feasible. This material and its container must be disposed of in a safe way. Empty
containers or liners may retain some product residues. Do not puncture or incinerate
container.

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Propane

Section 14. Transport information

DOT TDG Mexico IMDG IATA
UN number UN1978 UN1978 UN1978 UN1978 UN1978

UN proper PROPANE SEE PROPANE PROPANE SEE PROPANE PROPANE

shipping name ALSO ALSO
PETROLEUM PETROLEUM
GASES, GASES,
LIQUEFIED LIQUEFIED
(propane)
Transport 2.1 2.1 2.1 2.1 2.1
hazard class(es)

Packing group - - - - -
Environmental No. No. No. No. No.
hazards
“Refer to CFR 49 (or authority having jurisdiction) to determine the information required for shipment of the
product.”

Additional information
DOT Classification : Limited quantity
Yes.

Packaging instruction
Passenger aircraft
Quantity limitation: Forbidden.

Cargo aircraft
Quantity limitation: 150 kg

Special provisions
19, T50

For domestic transportation only, UN1075 may be substituted for the UN number
shown as long as the substitution is consistent on package markings, shipping
papers, and emergency response information. See 49 CFR 172.102 Special Provision
19.
Containers of NON-ODORIZED liquefied petroleum gas must be marked either
NON-ODORIZED or NOT ODORIZED as of September 30, 2006. [49 CFR 172.301(f),
326(d), 330(c) and 338(e)]

TDG Classification : Product classified as per the following sections of the Transportation of Dangerous
Goods Regulations: 2.13-2.17 (Class 2).
Explosive Limit and Limited Quantity Index 0.125
ERAP Index 3000
Passenger Carrying Vessel Index 65
Passenger Carrying Road or Rail Index Forbidden
Special provisions 29, 42
IATA : Quantity limitation Passenger and Cargo Aircraft: Forbidden. Cargo Aircraft Only: 150
kg.

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.

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Propane

Section 14. Transport information

Transport in bulk according : Not available.
to IMO instruments

Section 15. Regulatory information

U.S. Federal regulations : TSCA 8(a) CDR Exempt/Partial exemption: Not determined
Clean Air Act (CAA) 112 regulated flammable substances: propane
Clean Air Act Section 112 : Not listed
(b) Hazardous Air
Pollutants (HAPs)
Clean Air Act Section 602 : Not listed
Class I Substances
Clean Air Act Section 602 : Not listed
Class II Substances
DEA List I Chemicals : Not listed
(Precursor Chemicals)
DEA List II Chemicals : Not listed
(Essential Chemicals)
SARA 302/304
Composition/information on ingredients
No products were found.
SARA 304 RQ : Not applicable.
SARA 311/312
Classification : Refer to Section 2: Hazards Identification of this SDS for classification of substance.

State regulations
Massachusetts : This material is listed.
New York : This material is not listed.
New Jersey : This material is listed.
Pennsylvania : This material is listed.
California Prop. 65
This product does not require a Safe Harbor warning under California Prop. 65.
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.

Montreal Protocol
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
Inventory list
Australia : This material is listed or exempted.
Canada : This material is listed or exempted.
China : This material is listed or exempted.
Europe : This material is listed or exempted.

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Propane

Section 15. Regulatory information

Japan : Japan inventory (ENCS): This material is listed or exempted.
Japan inventory (ISHL): This material is listed or exempted.
New Zealand : This material is listed or exempted.
Philippines : This material is listed or exempted.
Republic of Korea : This material is listed or exempted.
Taiwan : This material is listed or exempted.
Thailand : Not determined.
Turkey : This material is listed or exempted.
United States : This material is active or exempted.
Viet Nam : This material is listed or exempted.

Section 16. Other information

Hazardous Material Information System (U.S.A.)
Health / 2

Flammability 4
Physical hazards 0

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS®
ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
National Fire Protection Association (U.S.A.)

4 Flammability
Health 2 0 Instability/Reactivity
Special

Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Procedure used to derive the classification
Classification Justification
FLAMMABLE GASES - Category 1 Expert judgment
GASES UNDER PRESSURE - Liquefied gas Expert judgment
History
Date of printing : 11/15/2020
Date of issue/Date of : 11/15/2020
revision
Date of previous issue : 10/5/2020
Version : 1.02

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Propane

Section 16. Other information

Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
References : Not available.
Other special : The information below is given to call attention to the issue of “Naturally occurring
considerations radioactive materials”. Although Radon-222 levels in the product represented by this
MSDS do not present any direct Radon exposure hazard, customers should be aware of
the potential for Radon daughter build up within their processing systems, whatever the
source of their product streams. Radon-222 is a naturally occurring radioactive gas
which can be a contaminant in natural gas. During subsequent processing , Radon
tends to be concentrated in Liquefied Petroleum Gas streams and in product streams
having a similar boiling point range. Industry experience has shown that this product
may contain small amounts of Radon-222 and its radioactive decay products, called
Radon “daughters”. The actual concentration of Radon-222 and radioactive daughters
in the delivered product is dependent on the geographical source of the natural gas and
storage time prior to delivery. Process equipment (i.e. lines, filters, pumps and reaction
units) may accumulate significant levels of radioactive daughters and show a gamma
radiation reading during operation. A potential external radiation hazard exists at or near
any pipe valve or vessel containing a Radon enriched stream, or containing internal
deposits of radioactive material due to the transmission of gamma radiation through its
wall. Field studies reported in the literature have not shown any conditions that subject
workers to cumulative exposures in excess of general population limits. Equipment
emitting gamma radiation should be presumed to be internally contaminated with alpha
emitting decay products which may be a hazard if inhaled or ingested. Protective
equipment such as coveralls, gloves, and respirator (NIOSH/MHSA approved for high
efficiency particulates and radionuclides, or supplied air) should be worn by personnel
entering a vessel or working on contaminated process equipment to prevent skin
contamination, ingestion, or inhalation of any residues containing alpha radiation.
Airborne contamination may be minimized by handling scale and/or contaminated
materials in a wet state.

Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.

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 SAFETY DATA SHEET

1. Identification
Product identifier Red Grease
Other means of identification
Product code 03079
Recommended use Lubricating grease
Recommended restrictions None known.
Manufacturer/Importer/Supplier/Distributor information
Manufactured or sold by:
Company name CRC Industries, Inc.
Address 885 Louis Dr.
Warminster, PA 18974 US
Telephone
General Information 215-674-4300
Technical 800-521-3168
Assistance
Customer Service 800-272-4620
24-Hour Emergency 800-424-9300 (US)
(CHEMTREC) 703-527-3887 (International)
Website www.crcindustries.com

2. Hazard(s) identification
Physical hazards Flammable aerosols Category 1
Gases under pressure Liquefied gas
Health hazards Skin corrosion/irritation Category 2
Specific target organ toxicity, single exposure Category 3 narcotic effects
Aspiration hazard Category 1
Environmental hazards Hazardous to the aquatic environment, Category 3
long-term hazard
OSHA defined hazards Not classified.

Label elements

Signal word Danger

Hazard statement Extremely flammable aerosol. Contains gas under pressure; may explode if heated. May be fatal if
swallowed and enters airways. Causes skin irritation. May cause drowsiness or dizziness. Harmful
to aquatic life with long lasting effects.
Precautionary statement
Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open
flame or other ignition source. Do not apply while equipment is energized. Pressurized container:
Do not pierce or burn, even after use. Extinguish all flames, pilot lights and heaters. Vapors will
accumulate readily and may ignite. Use only with adequate ventilation; maintain ventilation during
use and until all vapors are gone. Open doors and windows or use other means to ensure a fresh
air supply during use and while product is drying. If you experience any symptoms listed on this
label, increase ventilation or leave the area. Avoid breathing mist or vapor. Wash thoroughly after
handling. Wear protective gloves. Avoid release to the environment.
Response If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. If on skin: Wash
with plenty of water. If skin irritation occurs: Get medical attention. Take off contaminated clothing
and wash before reuse. If inhaled: Remove person to fresh air and keep comfortable for
breathing. Call a poison center/doctor if you feel unwell.

Material name: Red Grease SDS US

03079 Version #: 01 Issue date: 07-16-2015 1/8

 Storage Store in a well-ventilated place. Store locked up. Protect from sunlight. Do not expose to
temperatures exceeding 50°C/122°F. Exposure to high temperature may cause can to burst.
Disposal Dispose of contents/container in accordance with local/regional/national regulations.
Hazard(s) not otherwise Static accumulating flammable liquid can become electrostatically charged even in bonded and
classified (HNOC) grounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion.
Supplemental information
15% of the mixture consists of component(s) of unknown long-term hazards to the aquatic environment.

3. Composition/information on ingredients
Mixtures
Chemical name Common name and synonyms CAS number %
Heptane, branched, cyclic and 426260-76-6 40 - 50
linear
Propane 74-98-6 10 - 20
Specific chemical identity and/or percentage of composition has been withheld as a trade secret.

4. First-aid measures
Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON
CENTER or doctor/physician if you feel unwell.
Skin contact Remove contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical
advice/attention. Wash contaminated clothing before reuse.
Eye contact Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. Get medical attention if irritation develops and persists.
Ingestion Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If
vomiting occurs, keep head low so that stomach content doesn't get into the lungs.
Most important May cause drowsiness and dizziness. Headache. Nausea, vomiting. Aspiration may cause
symptoms/effects, acute and pulmonary edema and pneumonitis. Skin irritation. May cause redness and pain.
delayed
Indication of immediate Provide general supportive measures and treat symptomatically. Keep victim under observation.
medical attention and special Symptoms may be delayed.
treatment needed
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.

5. Fire-fighting measures
Suitable extinguishing media Water spray. Foam. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide, sand or earth
may be used for small fires only.
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from Contents under pressure. Pressurized container may rupture when exposed to heat or flame. This
the chemical product is a poor conductor of electricity and can become electrostatically charged. If sufficient
charge is accumulated, ignition of flammable mixtures can occur. Static electricity accumulation
may be significantly increased by the presence of small quantities of water or other contaminants.
Material will float and may ignite on surface of water. During fire, gases hazardous to health may
be formed.
Special protective equipment Firefighters must use standard protective equipment including flame retardant coat, helmet with
and precautions for firefighters face shield, gloves, rubber boots, and in enclosed spaces, SCBA.
Fire-fighting In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without
equipment/instructions risk. Containers should be cooled with water to prevent vapor pressure build up.
General fire hazards Extremely flammable aerosol. Contents under pressure. Pressurized container may rupture when
exposed to heat or flame.

Material name: Red Grease SDS US

03079 Version #: 01 Issue date: 07-16-2015 2/8

6. Accidental release measures
Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
protective equipment and low areas. Remove all possible sources of ignition in the surrounding area. Many vapors are
emergency procedures heavier than air and will spread along ground and collect in low or confined areas (sewers,
basements, tanks). Wear appropriate protective equipment and clothing during clean-up. Avoid
breathing mist or vapor. Emergency personnel need self-contained breathing equipment. Do not
touch damaged containers or spilled material unless wearing appropriate protective clothing.
Ventilate closed spaces before entering them. Use appropriate containment to avoid
environmental contamination. Local authorities should be advised if significant spillages cannot be
contained. For personal protection, see section 8 of the SDS.
Methods and materials for Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep
containment and cleaning up combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water.
Stop the flow of material, if this is without risk. Prevent product from entering drains. Wipe up with
absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.
For waste disposal, see section 13 of the SDS.
Environmental precautions Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid
discharge into drains, water courses or onto the ground. Inform appropriate managerial or
supervisory personnel of all environmental releases. Use appropriate containment to avoid
environmental contamination.

7. Handling and storage

Precautions for safe handling Minimize fire risks from flammable and combustible materials (including combustible dust and
static accumulating liquids) or dangerous reactions with incompatible materials. Pressurized
container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective.
Do not spray on a naked flame or any other incandescent material. Do not smoke while using or
until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to
heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The
metal container will conduct electricity if it contacts a live source. This may result in injury to the
user from electrical shock and/or flash fire. Avoid breathing mist or vapor. Avoid contact with eyes,
skin, and clothing. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate
personal protective equipment. Wash hands thoroughly after handling. Observe good industrial
hygiene practices. Avoid release to the environment. For product usage instructions, please see
the product label.
Conditions for safe storage, Level 3 Aerosol.
including any incompatibilities
Pressurized container. Protect from sunlight and do not expose to temperatures exceeding
50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open flame,
heat or other sources of ignition. This material can accumulate static charge which may cause
spark and become an ignition source. Avoid spark promoters. These alone may be insufficient to
remove static electricity. Store in a well-ventilated place. Store away from incompatible materials
(see Section 10 of the SDS).

8. Exposure controls/personal protection

Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components Type Value
Propane (CAS 74-98-6) PEL 1800 mg/m3
1000 ppm
US. NIOSH: Pocket Guide to Chemical Hazards
Components Type Value
Propane (CAS 74-98-6) TWA 1800 mg/m3
1000 ppm
Biological limit values No biological exposure limits noted for the ingredient(s).
Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level. Eye
wash facilities and emergency shower must be available when handling this product.
Individual protection measures, such as personal protective equipment
Eye/face protection Wear safety glasses with side shields (or goggles).

Skin protection
Hand protection Wear protective gloves such as: Nitrile. Neoprene.
Material name: Red Grease SDS US

03079 Version #: 01 Issue date: 07-16-2015 3/8

 Other Wear appropriate chemical resistant clothing.
Respiratory protection If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a
NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-contained
breathing apparatus in confined spaces and for emergencies. Air monitoring is needed to
determine actual employee exposure levels.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene When using do not smoke. Always observe good personal hygiene measures, such as washing
considerations after handling the material and before eating, drinking, and/or smoking. Routinely wash work
clothing and protective equipment to remove contaminants.

9. Physical and chemical properties

Appearance
Physical state Liquid.
Form Aerosol.
Color Red.
Odor Solvent.
Odor threshold Not available.
pH Not available.
Melting point/freezing point Not available.
Initial boiling point and boiling 175 °F (79.4 °C)
range
Flash point < 20 °F (< -6.7 °C) Tag Closed Cup
Evaporation rate Fast.
Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower 1.2
(%)
Flammability limit - upper 6.7
(%)
Vapor pressure 2428.1 hPa estimated
Vapor density > 1 (air = 1)
Relative density 0.67 estimated
Solubility (water) Slightly soluble.
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity (kinematic) Not available.
Percent volatile 60 % estimated

10. Stability and reactivity

Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous No dangerous reaction known under conditions of normal use.
reactions
Conditions to avoid Heat, flames and sparks. Contact with incompatible materials.
Incompatible materials Strong oxidizing agents.
Hazardous decomposition No hazardous decomposition products are known.
products

11. Toxicological information

Information on likely routes of exposure
Inhalation May cause drowsiness and dizziness. Headache. Nausea, vomiting. Prolonged inhalation may be
harmful.

Material name: Red Grease SDS US

03079 Version #: 01 Issue date: 07-16-2015 4/8

 Skin contact Causes skin irritation.
Eye contact Direct contact with eyes may cause temporary irritation.
Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious
chemical pneumonia.
Symptoms related to the Headache. May cause drowsiness and dizziness. Nausea, vomiting. Aspiration may cause
physical, chemical and pulmonary edema and pneumonitis. Skin irritation. May cause redness and pain.
toxicological characteristics
Information on toxicological effects
Acute toxicity May be fatal if swallowed and enters airways. Narcotic effects.
Product Species Test Results
Red Grease
Acute
Dermal
LD50 Rabbit 3922 mg/kg estimated
Inhalation
LC50 Rat 133 mg/l, 4 hours estimated
Oral
LD50 Rat 11111 mg/kg estimated

* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation Causes skin irritation.
Serious eye damage/eye Direct contact with eyes may cause temporary irritation.
irritation
Respiratory sensitization Not a respiratory sensitizer.
Skin sensitization This product is not expected to cause skin sensitization.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
IARC Monographs. Overall Evaluation of Carcinogenicity
Not available.
US. National Toxicology Program (NTP) Report on Carcinogens
Not available.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity - May cause drowsiness and dizziness.
single exposure
Specific target organ toxicity - Not classified.
repeated exposure
Aspiration hazard May be fatal if swallowed and enters airways. If aspirated into lungs during swallowing or vomiting,
may cause chemical pneumonia, pulmonary injury or death.
Chronic effects Prolonged inhalation may be harmful.

12. Ecological information

Ecotoxicity Harmful to aquatic life with long lasting effects.
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)
Propane 2.36
Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations

Disposal of waste from If discarded, this product is considered a RCRA ignitable waste, D001. Collect and reclaim or
residues / unused products dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not
puncture, incinerate or crush. Dispose in accordance with all applicable regulations.
Material name: Red Grease SDS US

03079 Version #: 01 Issue date: 07-16-2015 5/8

Hazardous waste code D001: Waste Flammable material with a flash point <140 F
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.

14. Transport information

DOT
UN number UN1950
UN proper shipping name Aerosols, flammable, Limited Quantity, MARINE POLLUTANT (Heptanes)
Transport hazard class(es)
Class 2.1
Subsidiary risk -
Label(s) 2.1
Packing group Not applicable.
Environmental hazards
Marine pollutant Yes
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Special provisions N82
Packaging exceptions 306
Packaging non bulk None
Packaging bulk None
IATA
UN number UN1950
UN proper shipping name Aerosols, flammable, Limited Quantity
Transport hazard class(es)
Class 2.1
Subsidiary risk -
Packing group Not applicable.
Environmental hazards Yes.
ERG Code 10L
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Other information
Passenger and cargo Allowed.
aircraft
Cargo aircraft only Allowed.
IMDG
UN number UN1950
UN proper shipping name AEROSOLS, LIMITED QUANTITY, MARINE POLLUTANT
Transport hazard class(es)
Class 2
Subsidiary risk -
Packing group Not applicable.
Environmental hazards
Marine pollutant Yes
EmS Not available.
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.

15. Regulatory information

US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
SARA 304 Emergency release notification
Not regulated.
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
Material name: Red Grease SDS US

03079 Version #: 01 Issue date: 07-16-2015 6/8

 CERCLA Hazardous Substances: Reportable quantity
Not listed.
Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National
Response Center (800-424-8802) and to your Local Emergency Planning Committee.
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Propane (CAS 74-98-6)
Safe Drinking Water Act Not regulated.
(SDWA)
Food and Drug Not regulated.
Administration (FDA)
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Section 311/312 Immediate Hazard - Yes
Hazard categories Delayed Hazard - No
Fire Hazard - Yes
Pressure Hazard - Yes
Reactivity Hazard - No
SARA 302 Extremely No
hazardous substance
US state regulations
US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)
Not listed.
US. New Jersey Worker and Community Right-to-Know Act
Propane (CAS 74-98-6)
US. Massachusetts RTK - Substance List
Propane (CAS 74-98-6)
US. Pennsylvania Worker and Community Right-to-Know Law
Propane (CAS 74-98-6)
US. Rhode Island RTK
Propane (CAS 74-98-6)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
Volatile organic compounds (VOC) regulations
EPA
VOC content (40 CFR 63 %
51.100(s))
Consumer products Not regulated
(40 CFR 59, Subpt. C)
State
Consumer products Not regulated
VOC content (CA) 63 %
VOC content (OTC) 63 %
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Chemical Substances (AICS) No
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) No
Europe European Inventory of Existing Commercial Chemical No
Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) No
Korea Existing Chemicals List (ECL) No

Material name: Red Grease SDS US

03079 Version #: 01 Issue date: 07-16-2015 7/8

 Country(s) or region Inventory name On inventory (yes/no)*
New Zealand New Zealand Inventory No
Philippines Philippine Inventory of Chemicals and Chemical Substances Yes
(PICCS)
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

16. Other information, including date of preparation or last revision

Issue date 07-16-2015
Prepared by Allison Cho
Version # 01
Further information Not available.
HMIS® ratings Health: 2
Flammability: 4
Physical hazard: 0
Personal protection: B
NFPA ratings Health: 2
Flammability: 4
Instability: 0
NFPA ratings
4
2 0

Disclaimer The information contained in this document applies to this specific material as supplied. It may not
be valid for this material if it is used in combination with any other materials. This information is
accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to
be accurate. Before using any product, read all warnings and directions on the label. For further
clarification of any information contained on this (M)SDS consult your supervisor, a health & safety
professional, or CRC Industries.

Material name: Red Grease SDS US

03079 Version #: 01 Issue date: 07-16-2015 8/8

 SAFETY DATA SHEET

Section 1 – Product & Company Identification

Product Name:
RIDGID Nu-Clear Thread Cutting Oil (United States)

Product Catalog No.:

11461, 11481, 41575, 41585, 42513, 70835

Recommended Use:
Thread Cutting

Restrictions on Use:
Industrial use only

Company Information:

North America Australia

Ridge Tool Company Ridge Tool Australia
400 Clark Street 127 Metrolink Circuit
Elyria, Ohio 44035-6001 Campbellfield, VIC 3061
1-800-519-3456 1-800-743-443
(8:00 am – 5:00 pm EST, M-F) (8:30 am – 5:00 pm AEST, M-F)
Emergency Telephone Emergency Telephone
call 9-1-1 or local emergency number call 000 or local emergency number
www.RIDGID.com www.RIDGID.com.au

Issue Date: May 2, 2018

Revision: K

• Français – 11
• Castellano – pág. 21
1
 Product Name: RIDGID Nu-Clear Thread Cutting Oil (United States)

Section 2 – Hazards Identification

Hazard Classification
This product is classified as not hazardous per US OSHA 29CFR 1910.1200
(HazCom 2012)

Label Elements

Hazard Symbol: No symbol

Signal Word: No signal word.

Hazard Statement: Not applicable

Precautionary Not applicable

Statements

Other hazards which do not None.

result in GHS classification:

Section 3 – Composition / Information On Ingredients

General information: This product does not contain silicone or chlorinated additives.

Hazardous Component(s):
Chemical name CAS-No. Concentration
Mineral oil Confidential 20 - <50%
Paraffin oils Confidential 20 - <50%
Vegetable oil Confidential 1 - <5%
Specific chemical identities and/or exact percentages have been withheld as trade secrets.

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 Product Name: RIDGID Nu-Clear Thread Cutting Oil (United States)

Section 4 – First Aid Measures

Ingestion: Rinse mouth thoroughly. Call a POISON CENTER/doctor if you feel unwell.
Do NOT induce vomiting.

Inhalation: Move to fresh air. Call a POISON CENTER/doctor if you feel unwell.

Skin Contact: Remove contaminated clothing and shoes. Wash contact areas with soap
and water. If skin irritation occurs: Get medical advice/attention.

Eye contact: Flush thoroughly with water. If irritation occurs, get medical assistance.
Continue to rinse for at least 15 minutes.

Most important symptoms/effects, acute and delayed

Symptoms: No data available.

Indication of immediate medical attention and special treatment needed

Treatment: Get medical attention if symptoms occur.

Section 5 – Fire Fighting Measures

General Fire Hazards: No unusual fire or explosion hazards noted.

Suitable (and unsuitable) extinguishing media

Suitable extinguishing Water spray, fog, CO2, dry chemical, or regular foam. Use fire-
media: extinguishing media appropriate for surrounding materials.

Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media:

Specific hazards arising from Heat may cause the containers to explode. During fire, gases hazardous to
the chemical: health may be formed.

Special protective equipment and precautions for firefighters

Special fire fighting No data available.

procedures:

Special protective equipment Firefighters must use standard protective equipment including flame
for fire-fighters: retardant coat, helmet with face shield, gloves, rubber boots, and in
enclosed spaces, SCBA.

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 Product Name: RIDGID Nu-Clear Thread Cutting Oil (United States)

Section 6 – Accidental Release Measures

Personal precautions, See Section 8 of the SDS for Personal Protective Equipment. Do not touch
protective equipment and damaged containers or spilled material unless wearing appropriate
emergency procedures: protective clothing. Keep unauthorized personnel away. Ensure adequate
ventilation.

Methods and material for Absorb with sand or other inert absorbent. Stop the flow of material, if this is
containment and cleaning without risk.
up:

Environmental Precautions: Avoid release to the environment. Do not contaminate water sources or
sewer. Prevent further leakage or spillage if safe to do so.

Section 7 – Handling And Storage

Precautions for safe handling: Observe good industrial hygiene practices. Wear appropriate personal
protective equipment. Do not expose to intense heat as product may
expand and pressurize container.

Conditions for safe storage, Store in original tightly closed container. Avoid contact with oxidizing
including any agents. Store away from incompatible materials. Shelf Life: 720 Days
incompatibilities:

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 Product Name: RIDGID Nu-Clear Thread Cutting Oil (United States)

Section 8 – Exposure Controls / Personal Protection

Exposure Limits
Chemical name Type Exposure Limit Values Source

Mineral oil - Mist. PEL 5 mg/m3 US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000) (01
2017)
Mineral oil - Mist. TWA 5 mg/m3 US. OSHA Table Z-1-A (29 CFR
1910.1000) (1989)
Paraffin oils - Inhalable fraction. TWA 5 mg/m3 US. ACGIH Threshold Limit Values (03
2014)
Paraffin oils - Mist. PEL 5 mg/m3 US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000) (02
2006)
Paraffin oils - Mist. TWA 5 mg/m3 US. OSHA Table Z-1-A (29 CFR
1910.1000) (1989)
Vegetable oil - Total dust. PEL 15 mg/m3 US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000) (02
2006)
Vegetable oil - Respirable fraction. PEL 5 mg/m3 US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000) (02
2006)

Protective Measures: Use personal protective equipment as required.

Respiratory Protection: In case of inadequate ventilation use suitable respirator. Seek advice from
supervisor on the company's respiratory protection standards.

Eye Protection: Wear safety glasses with side shields (or goggles).

Skin and Body Protection: Wear protective clothing appropriate for the risk of exposure. Be aware of other
hazards such as rotating parts. Contact health and safety professional or
manufacturer for specific information.

Hygiene measures: Always observe good personal hygiene measures, such as washing after
handling the material and before eating, drinking, and/or smoking. Routinely
wash work clothing to remove contaminants. Discard contaminated footwear
that cannot be cleaned.

Section 9 – Physical And Chemical Properties

Appearance
Physical state: Liquid
Form: No data available.
Color: Yellow
Odor: Mild petroleum/solvent
Odor threshold: No data available.
pH: No data available.
Melting point/freezing point: No data available.

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 Product Name: RIDGID Nu-Clear Thread Cutting Oil (United States)

Initial boiling point and boiling range: No data available.

Flash Point: 196.11 °C (385.00 °F)
Evaporation rate: No data available.
Flammability (solid, gas): No data available.
Upper/lower limit on flammability or explosive limits
Flammability limit - upper (%): No data available.
Flammability limit - lower (%): No data available.
Explosive limit - upper (%): No data available.
Explosive limit - lower (%): No data available.
Vapor pressure: No data available.
Vapor density: No data available.
Relative density: 0.878
Solubility(ies)
Solubility in water: Insoluble
Solubility (other): No data available.
Partition coefficient (n-octanol/water): No data available.
Auto-ignition temperature: No data available.
Decomposition temperature: No data available.
Viscosity: 43 mm2/s (40 °C, Measured)

Other information
VOC: 1.1 % (Method 24)
9.4 g/l (ASTM E 1868-10)

Section 10 – Stability And Reactivity

Reactivity: Not reactive during normal use.

Chemical Stability: Material is stable under normal conditions.

Possibility of hazardous None under normal conditions.

reactions:

Conditions to avoid: Avoid heat or contamination.

Incompatible Materials: No data available.

Hazardous Decomposition Thermal decomposition or combustion may liberate carbon oxides and
Products: other toxic gases or vapors.

Section 11 – Toxicological Information

Information on likely routes of exposure

Ingestion: May be ingested by accident. Ingestion may cause irritation and malaise.

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 Product Name: RIDGID Nu-Clear Thread Cutting Oil (United States)

Inhalation: Inhalation is the primary route of exposure. In high concentrations, vapors,

fumes or mists may irritate nose, throat and mucus membranes.

Skin Contact: Prolonged skin contact may cause redness and irritation.

Eye contact: Eye contact is possible and should be avoided.

Symptoms related to the physical, chemical and toxicological characteristics

Ingestion: No data available.

Inhalation: No data available.

Skin Contact: No data available.

Eye contact: No data available.

Information on toxicological effects

Acute toxicity (list all possible routes of exposure)

Oral
Product: Not classified for acute toxicity based on available data.

Dermal
Product:
Not classified for acute toxicity based on available data.

Inhalation
Product: Not classified for acute toxicity based on available data.

Repeated dose toxicity

Product: No data available.

Skin Corrosion/Irritation
Product: No data available.

Serious Eye Damage/Eye Irritation

Product: No data available.

Respiratory or Skin Sensitization

Product: No data available.

Carcinogenicity
Product: No data available.

IARC Monographs on the Evaluation of Carcinogenic Risks to Humans

No carcinogenic components identified

US. National Toxicology Program (NTP) Report on Carcinogens:

No carcinogenic components identified

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 Product Name: RIDGID Nu-Clear Thread Cutting Oil (United States)

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050):

No carcinogenic components identified

Germ Cell Mutagenicity

In vitro
Product: No data available.

In vivo
Product: No data available.

Reproductive toxicity
Product: No data available.

Specific Target Organ Toxicity - Single Exposure

Product: No data available.

Specific Target Organ Toxicity - Repeated Exposure

Product: No data available.

Aspiration Hazard
Product: No data available.

Other effects: No data available.

Section 12 – Ecological Information

General information: This product has not been evaluated for ecological toxicity or other
environmental effects.

Section 13 – Disposal Consideration

Disposal instructions: Discharge, treatment, or disposal may be subject to national, state, or local
laws. Dispose of waste at an appropriate treatment and disposal facility in
accordance with applicable laws and regulations, and product
characteristics at time of disposal. It is the responsibility of the product user
or owner to determine at the time of disposal, which waste regulations must
be applied.

Contaminated Packaging: Empty containers should be taken to an approved waste handling site for
recycling or disposal.

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 Product Name: RIDGID Nu-Clear Thread Cutting Oil (United States)

Section 14 – Transportation Information

DOT
Not regulated.

IMDG
Not regulated.

IATA
Not regulated.

Section 15 – Regulatory Information

US Federal Regulations

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

None present or none present in regulated quantities.

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Hazard categories
This product is classified as not hazardous per US OSHA 29CFR 1910.1200 (HazCom 2012)

SARA 313 (TRI Reporting)

None present or none present in regulated quantities.

US State Regulations

US. California Proposition 65

No ingredient regulated by CA Prop 65 present.

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 Product Name: RIDGID Nu-Clear Thread Cutting Oil (United States)

Section 16 – Other Information

Prepared by:. . . . . . . . . . . . Ridge Tool Company (Operating Standard 6-101)

Issue Date: . . . . . . . . . . . . .May 2, 2018

Last Revision Date: . . . . . . March 8, 2017

RIDGE TOOL BELIEVES THE STATEMENTS, TECHNICAL INFORMATION AND RECOM-

MENDATIONS CONTAINED HEREIN ARE RELIABLE BUT THEY ARE GIVEN WITHOUT WARRANTY
OR GUARANTEE OF ANY KIND, EXPRESSED OR IMPLIED, AND WE ASSUME NO RESPONSIBILITY
FOR ANY LOSS, DAMAGE OR EXPENSE, DIRECT OR CONSEQUENTIAL, ARISING OUT OF THEIR
USE.

10 Rev. K
 FICHE SANTÉ/SÉCURITÉ

1 – Identification du produit et du fournisseur

Produit:
RIDGID Nu-Clear Thread Cutting Oil (Etats-Unis)

Réf. catalogue:
11461, 11481, 41575, 41585, 42513, 70835

Emploi recommandé:
Filetage mécanique

Restrictions d'utilisation:
Usage industriel seulement

Fournisseur:

North America
Ridge Tool Company
400 Clark Street
Elyria, Ohio 44035-6001
1-800-519-3456
(Etats-Unis) (du lundi au vendredi de 8h
à 17h EST)
Téléphone d’urgence:
composer le 9-1-1 ou appeler les
services d’urgences appropriés
www.RIDGID.com

Date de publication: le 2 mai 2018

Révision K

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 Produit: RIDGID Nu-Clear Thread Cutting Oil (Etats-Unis)

2 – Identification des risques

Classe de Danger
Ce produit est classé comme non dangereux selon la norme américaine OSHA
29CFR 1910.1200 (HazCom 2012)

Éléments d’Étiquetage

Symbole de Danger: Aucun symbole

Mention Aucun mot indicateur.

d'Avertissement:

Mention de Danger: Non applicable

Conseils de Prudence Non applicable

Autres dangers ne donnant Aucun(e).

pas lieu à classement selon le
SGH:

3 – Composition du produit et renseignements sur ses ingrédients

Informations générales: Ce produit ne contient pas de silicone ou d'additifs chlorés.

Composant(s) dangereux:
Désignation chimique N° CAS Concentration
Mineral oil Confidentiel 20 - <50%
Paraffin oils Confidentiel 20 - <50%
Vegetable oil Confidentiel 1 - <5%
Les identités chimiques spécifiques et-ou les pourcentages exacts ont été refusées comme les secrets commerciaux.

4 – Premiers soins

Ingestion: Rincer soigneusement la bouche. Appeler un CENTRE ANTIPOISON/un

médecin en cas de malaise. NE PAS faire vomir.

Inhalation: Transporter à l’air frais. Appeler un CENTRE ANTIPOISON/un médecin en

cas de malaise.

Contact avec la Peau: Enlever les vêtements et les chaussures contaminés. Laver les zones de
contact à l'eau et au savon. En cas d’irritation cutanée: consulter un
médecin.

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 Produit: RIDGID Nu-Clear Thread Cutting Oil (Etats-Unis)

Contact oculaire: Rincer avec soin à l'eau. En cas d'irritation, consulter un médecin.
Continuer à rincer pendant au moins 15 minutes.

Symptômes/effets les plus importants, aigus et différés

Symptômes: Aucune information disponible.

Indication d’un besoin médical immédiat et traitement spécial requis

Traitement: Consulter un médecin en cas de symptômes.

5 – Lutte contre les incendies

Dangers d'Incendie Généraux: Aucun risque exceptionnel d'incendie et d'explosion.

Moyens d'extinction appropriés (et inappropriés)

Moyens d’extinction Eau pulvérisée, brouillard, CO2, agent chimique sec ou mousse standard.
appropriés: Choisir le moyen d'extinction de l'incendie en tenant compte d'autres
produits chimiques éventuels.
Moyens d’extinction Ne pas lutter contre l'incendie au jet d'eau pour ne pas propager les
inappropriés: flammes.

Dangers spécifiques dus au La chaleur peut provoquer l’explosion des récipients. En cas d'incendie,
produit chimique: des gaz dangereux pour la santé peuvent se former.

Équipement de protection spécial et précautions pour les pompiers

Procédures spéciales de lutte Aucune information disponible.

contre l'incendie:

Équipement de protection Les pompiers doivent porter un équipement de protection standard,

spécial pour le personnel notamment vêtement ignifuge, casque à masque facial, gants, bottes en
préposé à la lutte contre le caoutchouc et, dans les espaces clos, un appareil respiratoire autonome.
feu:

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 Produit: RIDGID Nu-Clear Thread Cutting Oil (Etats-Unis)

6 – Lutte contre les déversements accidentels

Précautions individuelles, Voir l’équipement de protection individuelle à la Section 8. Ne pas toucher

équipement de protection et les récipients endommagés ou le produit déversé à moins de porter les
procédures d’urgence: vêtements de protection appropriés. Maintenir à distance le personnel non
autorisé. Assurer une ventilation adéquate.

Méthodes et matériel de Absorber le produit avec du sable ou un autre absorbant inerte. Arrêter le
confinement et de débit de matière, si ceci est sans risque.
nettoyage:

Précautions pour la Protection Éviter le rejet dans l’environnement. Ne pas contaminer les sources d'eau
de l’Environnement: ou les égouts. Endiguer la fuite ou le déversement si cela peut être fait
sans danger.

7 – Manipulation et stockage

Précautions à prendre pour une Se conformer aux bonnes pratiques d’hygiène industrielle. Porter un
manipulation sans danger: équipement de protection personnelle approprié. N'exposez pas à la
chaleur intense comme le produit peut développer et pressuriser le
récipient.

Conditions d’un stockage sûr, Conserver dans le récipient d'origine hermétiquement fermé. Éviter tout
y compris d’éventuelles contact avec des agents comburants. Conserver à l’écart des matières
incompatibilités: incompatibles. Durée de conservation: 720 jours

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8 – Risques d’exposition et protection individuelle

Limites d'Exposition
Désignation chimique Type Valeurs Limites d'Exposition Source

Mineral oil - Brouillard PEL 5 mg/m3 Les Etats-Unis. La Table d'OSHA z-1 les
Limites pour les Polluants Aériens (29 CFR
1910.1000) (01 2017)
Mineral oil - Brouillard TWA 5 mg/m3 Les Etats-Unis. La Table d'OSHA z-1 les
Limites pour les Polluants Aériens (29 CFR
1910.1000) (1989)
Paraffin oils - Fraction inhalable. TWA 5 mg/m3 Les Etats-Unis. Valeurs de Limite de Seuil
d'ACGIH (03 2014)
Paraffin oils - Brouillard PEL 5 mg/m3 Les Etats-Unis. La Table d'OSHA z-1 les
Limites pour les Polluants Aériens (29 CFR
1910.1000) (02 2006)
Paraffin oils - Brouillard TWA 5 mg/m3 Les Etats-Unis. La Table d'OSHA z-1 les
Limites pour les Polluants Aériens (29 CFR
1910.1000) (1989)
Vegetable oil - poussière totales PEL 15 mg/m3 Les Etats-Unis. La Table d'OSHA z-1 les
Limites pour les Polluants Aériens (29 CFR
1910.1000) (02 2006)
Vegetable oil - Fraction alvéolaire. PEL 5 mg/m3 Les Etats-Unis. La Table d'OSHA z-1 les
Limites pour les Polluants Aériens (29 CFR
1910.1000) (02 2006)

Mesures de protection: Utiliser l’équipement de protection individuel requis.

:
Protection respiratoire: En cas de ventilation insuffisante, porter un appareil respiratoire approprié.
Demander l'avis du superviseur sur les normes de protection respiratoire de la
société.

Protection des Yeux: Porter des lunettes de sécurité à écrans latéraux ou des lunettes étanches.

Protection de la peau et du Porter des vêtements de protection appropriés au risque d'exposition. Soyez
corps: conscient des autres dangers tels que les pièces en rotation. Contacter un
professionnel de la santé et de la sécurité ou un fabricant pour obtenir des
informations spécifiques.

Mesures d'hygiène: Toujours adopter de bonnes pratiques d'hygiène personnelle, telles que lavage
après manipulation de la substance et avant de manger, de boire ou de fumer.
Laver régulièrement la tenue de travail pour éliminer les contaminants. Mettre
au rebut les chaussures qui ne peuvent pas être lavées.

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9 – Caractéristiques physiques et chimiques

Aspect
État: Liquide
Forme: Aucune information disponible.
Couleur: Jaune
Odeur: Légère, Pétrole/solvant
Seuil de perception de l’odeur: Aucune information disponible.
pH: Aucune information disponible.
Point de fusion/point de congélation: Aucune information disponible.
Température d'ébullition initiale et intervalle d'ébullition: Aucune information disponible.
Point d'éclair: 196.11 °C (385.00 °F)
Taux d’évaporation: Aucune information disponible.
Inflammabilité (solide, gaz): Aucune information disponible.
Limites supérieures/inférieures d'inflammabilité ou d'explosivité
Limites d’inflammabilité - supérieure (%): Aucune information disponible.
Limites d’inflammabilité - inférieure (%): Aucune information disponible.
Limites d’explosivité - supérieure (%) : Aucune information disponible.
Limites d’explosivité - inférieure (%): Aucune information disponible.
Pression de vapeur: Aucune information disponible.
Densité de vapeur: Aucune information disponible.
Densité relative: 0.878
Solubilités
Solubilité dans l’eau: Insoluble
Solubilité (autre): Aucune information disponible.
Coefficient de partition (n-octanol/eau): Aucune information disponible.
Température d’auto-inflammation: Aucune information disponible.
Température de décomposition: Aucune information disponible.
Viscosité: 43 mm2/s (40 °C, Mesurée)

AUTRES INFORMATIONS
VOC: 1.1 % (Method 24)
9.4 g/l (ASTM E 1868-10)

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10 – Stabilité et réactivité

Réactivité: Non réactif pendant l'utilisation normale.

Stabilité Chimique: Ce produit est stable dans des conditions normales.

Possibilité de Réactions Aucun(e)(s) dans les conditions normales.

Dangereuses:

Conditions à Éviter: Éviter tout chauffage ou contamination.

Matières Incompatibles: Aucune information disponible.

Produits de Décomposition La décomposition thermique ou la combustion peut libérer des oxydes de

Dangereux: carbone et d'autres gaz ou vapeurs toxiques.

11 – Données toxicologiques

Informations sur les voies d’exposition probables

Ingestion: Peut être ingéré par accident. L'ingestion peut provoquer irritation et
malaises.

Inhalation: L'inhalation est la principale voie d'exposition. À concentration élevée, les

vapeurs, émanations ou brouillards peuvent être irritants pour le nez, la
gorge et les muqueuses.

Contact avec la Peau: Le contact prolongé avec la peau peut entraîner des rougeurs et de
l'irritation.

Contact oculaire: Le contact oculaire est possible ; il doit être évité.

Symptômes liés aux caractéristiques physiques, chimiques et toxicologiques

Ingestion: Aucune information disponible.

Inhalation: Aucune information disponible.

Contact avec la Peau: Aucune information disponible.

Contact oculaire: Aucune information disponible.

Informations sur les effets toxicologiques

Toxicité aiguë (répertorier toutes les voies d'exposition possibles)

Ingestion
Produit: Non classé comme présentant une toxicité aiguë d'après les données
disponibles.

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Contact avec la peau

Produit:
Non classé comme présentant une toxicité aiguë d'après les données
disponibles.

Inhalation
Produit: Non classé comme présentant une toxicité aiguë d'après les données
disponibles.

Toxicité à dose répétée

Produit: Aucune information disponible.

Corrosion ou Irritation de la Peau

Produit: Aucune information disponible.

Blessure ou Irritation Grave des Yeux

Produit: Aucune information disponible.

Sensibilisation Respiratoire ou Cutanée

Produit: Aucune information disponible.

Cancérogénicité
Produit: Aucune information disponible.
Monographies du CIRC sur l’évaluation des risques de cancérogénicité pour l’homme
Aucun composant cancérigène identifié :

États-Unis. Rapport du NTP (National Toxicilogy Program) sur les cancérogènes :

Aucun composant cancérigène identifié

ÉTATS-UNIS. Substances spécialement réglementées par l’OSHA (29 CFR 1910.1001-

Aucun composant cancérigène identifié 1050)

Mutagénicité des Cellules Germinales

In vitro
Produit: Aucune information disponible.

In vivo
Produit: Aucune information disponible.

Toxicité pour la reproduction

Produit: Aucune information disponible.

Toxicité Spécifique au Niveau de l'Organe Cible- Exposition Unique

Produit: Aucune information disponible.

Toxicité Spécifique au Niveau de l'Organe Cible- Expositions répétées

Produit: Aucune information disponible.

Risque d'Aspiration
Produit: Aucune information disponible.

Autres effets: Aucune information disponible.

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12 – Données écologiques

Informations générales: Ce produit n'a pas été évalué pour la toxicité écologique ou d'autres effets
de l'environnement.

13 – Recyclage

Instructions pour l'élimination: Le rejet, le traitement et l'élimination peuvent être soumis à des lois
nationales, régionales ou locales. Éliminer les déchets dans une installation
de traitement et d'élimination des déchets appropriée conformément aux
lois et aux réglementations en vigueur et en fonction des caractéristiques
du produit au moment de l'élimination. C'est la responsabilité de l'utilisateur
de produit ou du propriétaire pour déterminer au moment de la disposition,
qui se perdent les règlements doivent être appliqués.

Emballages Contaminés: Les conteneurs vides doivent être acheminés vers un site agréé pour le
traitement des déchets à des fins de recyclage ou d'élimination.

14 – Transport

Ministère des transports des États-Unis (Department of Transportation, DOT)

Non réglementé.

IMDG
Non réglementé.

IATA
Non réglementé.

15 – Réglementation
Réglementations Fédérales des Etats-Unis

ÉTATS-UNIS. Substances spécialement réglementées par l’OSHA (29 CFR 1910.1001-1050)

Aucun présent ou aucun présent dans des quantités réglementées.

Superfund Amendments and Reauthorization Act de 1986 (SARA)

Catégories de danger
Ce produit est classé comme non dangereux selon la norme américaine OSHA 29CFR 1910.1200 (HazCom
2012)

SARA 313 (Déclaration au TRI)

Aucun présent ou aucun présent dans des quantités réglementées.

États-Unis - Réglementation des États

États-Unis - Proposition 65 de la Californie

Aucun composant réglementé par la Proposition 65 de la Californie n’est présent.
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16 – Renseignements divers

Rédaction : Ridge Tool Company (OPSTD 6-101)

Date de publication : le 2 mai 2018

Dernière révision : le 8 mars 2017

Quoi que la société Ridge Tool estime que les affirmations, informations techniques et
recommandations ci-présentes sont dignes de confiance, celles-ci ne sont données
qu’à titre indicatif, sans aucune garantie expresse ou implicite, et ne sauraient engager
la responsabilité civile de la société en cas de pertes, dommages et intérêts, voire frais
directs ou indirects relevant de leur application.

20 Rev. K
 HOJA DE DATOS DE SEGURIDAD

Sección 1 – Identificación del producto y la compañía

Nombre del producto:

RIDGID Nu-Clear Thread Cutting Oil (Estados Unidos)

No. de catálogo:
11461, 11481, 41575, 41585, 42513, 70835

Uso recomendado:
Para cortar roscas

Restricciones de utilización:
Uso industria seulement

Nombre de la compañía:

North America
Ridge Tool Company
400 Clark Street
Elyria, Ohio 44035-6001, EE. UU.
Teléfono 1-800-519-3456 (EE. UU.) (8:00 a 17:00 hora
estándar del este, lunes a viernes)
Teléfono de emergencia: Llame al 9-1-1 o al teléfono de
emergencia local
www.RIDGID.com

Fecha de publicación: 2 de mayo de 2018

Révision: K

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 Producto: RIDGID Nu-Clear Thread Cutting Oil (Estados Unidos)

Sección 2 – Identificación de peligros

Clasificación de Peligro
Este producto está clasificado como no peligroso según la norma OSHA 29CFR
1910.1200 (HazCom 2012)

Elementos de la Etiqueta

Símbolo de Peligro: No hay símbolo

Palabra de Advertencia: No hay palabra de advertencia.

Indicación de Peligro: No aplicable

Consejos de Prudencia No aplicable

Otros peligros que no dan Ninguno.

lugar a clasificación SGA:

Sección 3 – Composición e información sobre

ingredientes
Información general: Este producto no contiene silicona o aditivos clorados.

Componente(s) peligroso(s):
Determinación química No. CAS Concentración
Mineral oil Confidencial 20 - <50%
Paraffin oils Confidencial 20 - <50%
Vegetable oil Confidencial 1 - <5%
Las identidades químicas específicas y/o los porcentajes exactos han sido retenidos como secretos de fabricación.

Sección 4 – Primeros auxilios

Ingestión: Enjuagar a fondo la boca. Llamar a un CENTRO DE TOXICOLOGÍA /
médico si la persona se encuentra mal. NO provocar el vómito.

Inhalación: Trasladar al aire libre. Llamar a un CENTRO DE TOXICOLOGÍA / médico

si la persona se encuentra mal.

Contacto con la Piel: Quitar ropa y zapatos contaminados. Lave las áreas de contacto con agua
y jabón. En caso de irritación cutánea: Consultar a un médico.

Contacto con los ojos: Lave con abundante agua. Si aparece irritación, busque asistencia médica.
Continuar enjuagando durante al menos 15 minutos.

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Los síntomas y efectos más importantes, tanto los agudos como los retardados

Síntomas: No hay datos disponibles.

Indicación de asistencia médica inmediata y tratamiento especial necesario

Tratamiento: Obtenga atención médica en caso de síntomas.

Sección 5 – Medidas contra incendios

Riesgos Generales de Ningún riesgo excepcional de incendio o explosión señalado.

Incendio:

Medios de extinción adecuados (y no adecuados)

Medios de extinción Agua pulverizada, neblina, CO2, polvos químicos, o espuma normal
apropiados: Seleccione el medio de extinción más apropiado, teniendo en cuenta la
posible presencia de otros productos químicos.

Medios de extinción no No utilice chorro de agua, pues extendería el fuego.

apropiados:
Peligros específicos derivados El calor puede ocasionar explosión de los recipientes. En caso de incendio
de la sustancia química: se pueden formar gases nocivos.

Equipo especial de protección y medias de precaución para los bomberos

Medidas especiales de lucha No hay datos disponibles.

contra incendios:

Equipos de protección Los bomberos deben utilizar un equipo de protección estándar incluyendo
especial que debe llevar el chaqueta ignífuga, casco con careta, guantes, botas de goma, y, en
personal de lucha contra espacios cerrados, equipo de respiración autónomo (SCBA, según sus
incendios: siglas en inglés).

Sección 6 – Medidas en caso de liberación accidental

Precauciones personales, Consulte la sección 8 de la FDS sobre equipo de protección personal. No

equipo de protección y toque los recipientes dañados o el material derramado a menos que esté
procedimientos de usando ropa protectora adecuada. Mantener alejado al personal no
emergencia: autorizado. Asegúrese una ventilación apropiada.

Métodos y material de Absorber con arena u otro absorbente inerte. Detenga el flujo del material,
contención y de limpieza: si esto no representa un riesgo.

Precauciones Relativas al Evitar su liberación al medio ambiente. No contamine el drenaje o el

Medio Ambiente: alcantarillado. Impedir nuevos escapes o derrames de forma segura.

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Sección 7 – Manipulación y almacenamiento

Precauciones para una Respete las normas para una manipulación correcta de productos
manipulación segura: químicos. Use equipo protector personal adecuado. No exponga al calor
intenso cuando el producto puede ampliar y presurizar el contenedor.

Condiciones de Guárdese en el recipiente original bien cerrado. Evite el contacto con

almacenamiento seguro, agentes reductores. Consérvese alejado de materiales incompatibles. Vida
incluidas posibles útil: 720 días
incompatibilidades:

Sección 8 – Controles contra la exposición: protección personal

Valores Límite
Determinación química Tipo Valores Límite de Exposición Fuente

Mineral oil - Niebla PEL 5 mg/m3 NOS. OSHA la tabla Z-1 límites para
contaminantes del aire (29 CFR
1910.1000) (01 2017)
Mineral oil - Niebla TWA 5 mg/m3 NOS. OSHA la Tabla Z-1-A (29 CFR
1910.1000) (1989)
Paraffin oils - Fracción inhalable TWA 5 mg/m3 EE.UU. ACGIH Valores umbrales límite
(03 2014)
Paraffin oils - Niebla PEL 5 mg/m3 NOS. OSHA la tabla Z-1 límites para
contaminantes del aire (29 CFR
1910.1000) (02 2006)
Paraffin oils - Niebla TWA 5 mg/m3 NOS. OSHA la Tabla Z-1-A (29 CFR
1910.1000) (1989)
Vegetable oil - Polvo total PEL 15 mg/m3 NOS. OSHA la tabla Z-1 límites para
contaminantes del aire (29 CFR
1910.1000) (02 2006)
Vegetable oil - Fracción respirable PEL 5 mg/m3 NOS. OSHA la tabla Z-1 límites para
contaminantes del aire (29 CFR
1910.1000) (02 2006)

Medidas de protección: Utilizar los equipos de protección individual según las necesidades.

Protección respiratoria: En caso de ventilación insuficiente, utilice un equipo respiratorio adecuado.

Consulte al supervisor sobre la norma de la compañía de protección
respiratoria.

Protección de los Ojos: Use gafas de seguridad con protectores laterales (o gafas estancas).

Protección de la Piel y del Use ropa protectora apropiada para el riesgo de exposición. Tenga en cuenta
Cuerpo: otros peligros, como las piezas giratorias. Comuníquese con el profesional o
fabricante de salud y seguridad para obtener información específica.

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Medidas de higiene: Seguir siempre buenas medidas de higiene personal, como lavarse después
de manipular el material y antes de comer, beber y/o fumar. Lave
rutinariamente la ropa de trabajo para eliminar los contaminantes. Deseche el
calzado contaminado que no se pueda limpiar.

Sección 9 – Propiedades físicas y químicas

Aspecto
Forma/estado: Líquido
Forma/Figura: No hay datos disponibles.
Color: Amarillo
Olor: Ligero, petróleo/solvente
Umbral de olor: No hay datos disponibles.
pH: No hay datos disponibles.
Punto de fusión / Punto de congelación: No hay datos disponibles.
Punto inicial de ebullición e intervalo de ebullición: No hay datos disponibles.
Punto de inflamación: 196.11 °C (385.00 °F)
Tasa de evaporación: No hay datos disponibles.
Inflamabilidad (sólido, gas): No hay datos disponibles.
Límites superior/inferior de inflamabilidad o de explosividad
Límite superior de inflamabilidad (LSI) (%): No hay datos disponibles.
Límite inferior de inflamabilidad (LII) (%): No hay datos disponibles.
Límite superior de explosividad (%): No hay datos disponibles.
Límite inferior de explosividad (%): No hay datos disponibles.
Presión de vapor: No hay datos disponibles.
Densidad del vapor: No hay datos disponibles.
Densidad relativa: 0.878
Solubilidad(es)
Solubilidad en agua: Insoluble
Solubilidad (otra): No hay datos disponibles.
Coeficiente de reparto (n-octanol/agua): No hay datos disponibles.
Temperatura de autoignición: No hay datos disponibles.
Temperatura de descomposición: No hay datos disponibles.
Viscosidad: 43 mm2/s (40 °C, medido)

OTRA INFORMACIÓN
VOC: 1.1 % (Method 24)
9.4 g/l (ASTM E 1868-10)

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Sección 10 – Estabilidad y reactividad

Reactividad: No reactivo durante uso normal.

Estabilidad Química: El material es estable bajo condiciones normales.

Posibilidad de Reacciones Ningunos en circunstancias normales.

Peligrosas:

Condiciones que Deben Evite el calor o la contaminación.

Evitarse:

Materiales Incompatibles: No hay datos disponibles.

Productos de Descomposición La descomposición térmica o la combustión pueden liberar óxido de

Peligrosos: carbono u otros gases o vapores tóxicos.

Sección 11 – Información toxicológica

Información sobre posibles vías de exposición

Ingestión: Puede ingerirse accidentalmente. La ingestión puede causar irritación y

malestar.

Inhalación: La inhalación es la principal vía de exposición. En concentraciones altas,

los vapores, humos o neblinas pueden irritar la nariz, la garganta y las
membranas mucosas.

Contacto con la Piel: El contacto prolongado con la piel puede causar rubor e irritación.

Contacto con los ojos: El contacto con los ojos es posible y debe evitarse.

Síntomas relacionados a las características físicas, químicas y toxicológicas

Ingestión: No hay datos disponibles.

Inhalación: No hay datos disponibles.

Contacto con la Piel: No hay datos disponibles.

Contacto con los ojos: No hay datos disponibles.

Información sobre los efectos toxicológicos

Toxicidad aguda (listar todas las vías de exposición posibles)

Ingestión
Producto: No clasificado en cuanto a toxicidad aguda con los datos disponibles.

26 Rev. K
 Producto: RIDGID Nu-Clear Thread Cutting Oil (Estados Unidos)

Contacto dermal
Producto:
No clasificado en cuanto a toxicidad aguda con los datos disponibles.

Inhalación
Producto: No clasificado en cuanto a toxicidad aguda con los datos disponibles.

Toxicidad por dosis repetidas

Producto: No hay datos disponibles.

Corrosión/Irritación Cutáneas
Producto: No hay datos disponibles.

Lesiones Oculares Graves/Irritación Ocular

Producto: No hay datos disponibles.

Sensibilización de la Piel o Respiratoria

Producto: No hay datos disponibles.

Carcinogenicidad
Producto: No hay datos disponibles.

Monografías de IARC sobre la evaluación de los riesgos carcinogénicos para los humanos
No se identificaron componentes carcinogénicos

Programa Nacional de Toxicología de EUA (NTP). Reporte sobre carcinógenos

No se identificaron componentes carcinogénicos

EEUU. OSHA Sustancias específicamente reguladas (29 CFR 1910.1001-1050)

No se identificaron componentes carcinogénicos

Mutagenicidad en Células Germinales

En vitro
Producto: No hay datos disponibles.

En vivo
Producto: No hay datos disponibles.

Toxicidad para la reproducción

Producto: No hay datos disponibles.

Toxicidad Sistémica Específica de Órganos Diana- Exposición Única

Producto: No hay datos disponibles.

Toxicidad Sistémica Específica de Órganos Diana- Exposiciones Repetidas

Producto: No hay datos disponibles.

Peligro por Aspiración

Producto: No hay datos disponibles.

Otros síntomas: No hay datos disponibles.

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 Producto: RIDGID Nu-Clear Thread Cutting Oil (Estados Unidos)

Sección 12 –Información ecológica

Información general: Este producto no ha sido evaluado para la toxicidad ecológica u otros
efectos ambientales.

Sección 13 – Consideraciones
relativas a la eliminación

Instrucciones para la Las actividades de descarga, tratamiento o eliminación pueden estar

eliminación: sujetos a leyes nacionales, estatales o locales. Elimine el residuo en una
instalación adecuada de tratamiento y eliminación de acuerdo con las leyes
y reglamentos correspondientes y características del producto en el
momento de la eliminación. Es responsabilidad del usuario del producto o
propietario para determinar en el momento de la disposición, que las
regulaciones de residuos debe ser aplicado.

Envases Contaminados: Los contenedores vacíos deben ser llevados a un sitio de manejo aprobado
para desechos, para el reciclado o eliminación.

Sección 14 – Información de
transporte
DOT
No reglamentado.

IMDG
No reglamentado.

IATA
No reglamentado.

Sección 15 – Información sobre

reglamentos

Reglamentos Federales de EE.UU.

EEUU. OSHA Sustancias específicamente reguladas (29 CFR 1910.1001-1050)

No están presentes, o no están presentes en lascantidades reguladas.

Ley de Enmiendas y Reautorización del Superfondo de 1986 (SARA)

Categorías de peligro
Este producto está clasificado como no peligroso según la norma OSHA 29CFR 1910.1200 (HazCom 2012)

SARA 313 (Reporte TRI, Acerca del Inventario de Liberación de Sustancias Tóxicas)
No están presentes, o no están presentes en lascantidades reguladas.

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 Producto: RIDGID Nu-Clear Thread Cutting Oil (Estados Unidos)

Regulaciones de un Estado de EUA

Proposición 65 del Estado de California, EUA

No hay presencia de ningún ingrediente reguladopor CA Prop 65.

Sección 16 – Información adicional

Preparado por: Ridge Tool Company (OPSTD 6-101)

Fecha de emisión: 2 de mayo de 2018

Fecha de la última revisión: 8 de mars de 2017

RIDGE TOOL CONSIDERA QUE TODAS LAS DECLARACIONES, INFORMACIÓN TÉCNICA Y

RECOMENDACIONES EN EL PRESENTE DOCUMENTO SON CONFIABLES, PERO SE PRESENTAN
SIN GARANTÍA ALGUNA, SEA EXPRESA O IMPLÍCITA, Y NO ASUMIMOS RESPONSABILIDAD
ALGUNA POR PÉRDIDAS, DAÑOS O GASTOS, DIRECTOS O CONSECUENTES, QUE SURJAN DE
SU USO.

29 Rev. K
Victaulic® Lubricant SDS
(Safety Data Sheet) 05.02
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product Identifier
Product name : Victaulic Lubricant
1.2. Intended Use Of The Product
Use of the substance/preparation : A Pipe Joint Lubricant. For professional use only.
1.3. Name, Address, And Telephone Of The Responsible Party
Company Manufacturer
Victaulic Company JTM Products, Inc.
4901 Kesslersville Road 31025 Carter Street
Easton, PA 18045 Solon, OH 44139
610-559-3300 440-287-2302
web: www.victaulic.com
1.4. Emergency telephone number
Emergency number : 610-559-3300 Hours 9am-5pm EST M-F

SECTION 2: Hazards identification

2.1. Classification of the Substance or Mixture
Classification (GHS-US)
This material is not classified as hazardous in accordance with OSHA 29 CFR 1910.1200.
2.2. Label Elements
GHS-US labeling
Not applicable
2.3. Other Hazards
No additional information available
2.4. Unknown acute toxicity (GHS US)
70 – 80% of the mixture consists of ingredient(s) of unknown acute toxicity.

SECTION 3: Composition/information on ingredients

3.1. Substances
Not applicable
3.2. Mixtures
Name Product Identifier % Classification (GHS-US)
Fatty acids, tall-oil, potassium salts (CAS No) 61790-44-1 70–80 Not classified
1,2-Propylene glycol (CAS No) 57-55-6 10–20 Not classified
Mica (CAS No) 12001-26-2 5–10 Not classified

Victaulic® Lubricant | Safety Data Sheet | Publication 05.02

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SECTION 4: Description of first aid measures

4.1. Description of first aid measures

First-aid measures general : Never give anything by mouth to an unconscious person. If you
feel unwell, seek medical advice (show the label where possible).
First-aid measures after inhalation : If symptoms occur: go into open air and ventilate suspected area.
Keep at rest and in a position comfortable for breathing.
First-aid measures after skin contact : Remove contaminated clothing. Gently wash with plenty of soap
and water. Wash contaminated clothing before reuse.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries : Not expected to present a significant health hazard under
normal conditions of use.
Symptoms/injuries after inhalation : Not expected to present a significant inhalation hazard.
Symptoms/injuries after skin contact : May cause irritation from prolonged/repeated periods of use.
Symptoms/injuries after eye contact : May cause eye irritation.
Symptoms/injuries after ingestion : May cause gastrointestinal irritation.
4.3 Indication of any immediate medical attention and special treatment needed
If you feel unwell, get medical advice and attention.
SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media : Use extinguishing media appropriate for surrounding fire.
Unsuitable extinguishing media : Do not use a heavy water stream. Use of heavy stream of water
may spread fire.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Not considered flammable but may burn at high temperatures.
Explosion hazard : Product is not explosive.
Reactivity : Hazardous reactions will not occur.
5.3. Advice for firefighters
Precautionary measures fire : Exercise caution when fighting any chemical fire.
Firefighting instructions : Use water spray or fog for cooling exposed containers.
Protection during firefighting : Do not enter fire area without proper protective equipment,
including respiratory protection.

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SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

General measures : Avoid all contact with eyes, skin, or clothing.
6.1.1. For non-emergency personnel
Protective equipment : Use appropriate personal protection equipment (PPE).
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters.
6.3. Methods and material for containment and cleaning up
For containment : Absorb and/or contain spill with inert material, then place in
suitable container.
Methods for cleaning up : Clear up spills immediately and dispose of waste safely.
6.4. Reference to other sections
See heading 8, exposure controls and personal protection.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Precautions for safe handling : Avoid all contact with eyes, skin, or clothing.
Hygiene measures : Handle in accordance with good industrial hygiene and safety
procedures. Wash hands and other exposed areas with mild
soap and water before eating, drinking, or smoking and again
when leaving work.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Comply with applicable regulations.
Storage conditions : Store in a dry, cool and well-ventilated place.
Incompatible products : Strong acids. Strong bases. Strong oxidizers.
7.3. Specific end use(s)
A Pipe Joint Lubricant. For professional use only.

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8.1. Control parameters

Mica (12001-26-2)
USA ACGIH ACGIH TWA (mg/m³) 3 mg/m³
USA NIOSH NIOSH REL (TWA) (mg/m³) 3 mg/m³ (containing <1% Quartz)
USA IDLH US IDLH (mg/m³) 1500 mg/m³ (containing <1% Quartz)

8.2. Exposure controls

Appropriate engineering controls : Ensure adequate ventilation, especially in confined areas.

Emergency eye wash fountains and safety showers should be
available in the immediate vicinity of any potential exposure.
Ensure all national/local regulations are observed.
Personal protective equipment : Not generally required but may be necessary as conditions
warrant.
Materials for protective clothing : Chemically resistant materials and fabrics.
Hand protection : Protective gloves.
Eye protection : Safety glasses
Skin and body protection : Wear suitable protective clothing.
Respiratory protection : Use NIOSH-approved air-purifying or supplied-air respirator
where airborne concentrations of vapor or mist are expected to
exceed exposure limits.
Other information : When using, do not eat, drink or smoke.

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SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : Liquid
Appearance : Amber viscous paste
Odor : Mild
Odor threshold : No data available
pH : 11
Relative evaporation rate (butyl acetate=1) : No data available
Melting point : < 0°C (32°F)
Freezing point : No data available
Boiling point : > 104°C (220°F)
Flash Point : > 104°C (220°F)
Auto-ignition temperature : No data available
Decomposition Temperature : No data available
Flammability (solid, gas) : No data available
Vapor pressure : No data available
Relative vapor density at 20°C : No data available
Relative density : 1.08 (water = 1)
Density : 9.01 lbs/gal
Solubility : Soluble in water
Log Pow : No data available
Log Kow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidizing properties : No data available
Explosive limits : Not applicable
9.2. Other information
VOC content : 146 g/L

SECTION 10: Stability and reactivity

10.1. Reactivity
Hazardous reactions will not occur.
10.2. Chemical stability
Stable at standard temperature and pressure.
10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures.
10.5. Incompatible materials
Strong acids. Strong bases. Strong oxidizers.
10.6. Hazardous decomposition products
Carbon oxides (CO, CO 2). Silicon oxides.

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SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity : Not classified
1,2-Propylene glycol (57-55-6)
LD50 oral rat 20000 mg/kg
LD50 dermal rabbit 20800 mg/kg

Skin corrosion/irritation : Not classified (pH: 11).

Serious eye damage/irritation : Not classified (pH: 11).
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated : Not classified
exposure)
Aspiration hazard : Not classified
Potential Adverse human health effects and : Not expected to present a significant hazard under normal
symptoms conditions of use.
Symptoms/injuries after inhalation : Not expected to present a significant inhalation hazard.
Symptoms/injuries after skin contact : May cause skin irritation through repeated/prolonged periods of use.
Symptoms/injuries after eye contact : May cause eye irritation.
Symptoms/injuries after ingestion : May cause gastrointestinal irritation.
SECTION 12: Ecological information

12.1. Toxicity
1,2-Propylene glycol (57-55-6)
LC50 fishes 1 51600 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [static])
EC50 Daphnia 1 10000 mg/l (Exposure time: 24 h - Species: Daphnia magna)
EC50 other aquatic organisms 1 19000 mg/l (Exposure time: 96 h - Species: Pseudokirchneriella subcapitata)
LC50 fish 2 41 (41 - 47) mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [static])
EC50 Daphnia 2 1000 mg/l (Exposure time: 48 h - Species: Daphnia magna [Static])
12.2. Persistence and degradability
Victaulic Lubricant
Persistence and degradability Not established.
12.3. Bioaccumulative potential
Victaulic Lubricant
Bioaccumulative potential Not established.
1,2-Propylene glycol (57-55-6)
BCF fish 1 <1
12.4. Mobility in soil
No additional information available
12.4. Other adverse effects
Other information : Avoid release to the environment.

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SECTION 13: Disposal considerations

13.1. Waste treatment methods

Waste disposal recommendations : Dispose of waste material in accordance with all local, regional,
national, and international regulations.

SECTION 14: Transport information

In accordance with ICAO/IATA/DOT/TDG
14.1. UN number
Not regulated for transport.
14.2. UN proper shipping name
Not regulated for transport.
14.3. Additional information
Overland transport
No additional information available
Transport by sea
No additional information available
Air transport
No additional information available

SECTION 15: Regulatory information

15.1. US Federal regulations

1,2-Propylene glycol (57-55-6)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
EPA TSCA Regulatory Flag Y2 - Y2 - indicates an exempt polymer that is a polyester and
is made only from reactants included in a specified list of low
concern reactants that comprises one of the eligibility criteria for
the exemption rule.
Fatty acids, tall-oil, potassium salts (61790-44-1)
Listed on the United States TSCA (Toxic Substances Control Act) inventory

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15.3. US State regulations

Mica (12001-26-2)
U.S. - Connecticut - Hazardous Air Pollutants - HLVs (30 min)
U.S. - Connecticut - Hazardous Air Pollutants - HLVs (8 hr)
U.S. - Hawaii - Occupational Exposure Limits - TWAs
U.S. - Idaho - Non-Carcinogenic Toxic Air Pollutants - Acceptable Ambient Concentrations
U.S. - Idaho - Non-Carcinogenic Toxic Air Pollutants - Emission Levels (ELs)
U.S. - Idaho - Occupational Exposure Limits - Mineral Dusts
U.S. - Massachusetts - Right To Know List
U.S. - Michigan - Occupational Exposure Limits - TWAs
U.S. - Minnesota - Hazardous Substance List
U.S. - Minnesota - Permissible Exposure Limits - TWAs
U.S. - New Hampshire - Regulated Toxic Air Pollutants - Ambient Air Levels (AALs) - 24-Hour
U.S. - New Hampshire - Regulated Toxic Air Pollutants - Ambient Air Levels (AALs) - Annual
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - New York - Occupational Exposure Limits - Mineral Dusts
U.S. - North Dakota - Air Pollutants - Guideline Concentrations - 8-Hour
U.S. - Oregon - Permissible Exposure Limits - Mineral Dusts
U.S. - Pennsylvania - RTK (Right to Know) List
U.S. - Tennessee - Occupational Exposure Limits - TWAs
U.S. - Texas - Effects Screening Levels - Long Term
U.S. - Texas - Effects Screening Levels - Short Term
U.S. - Vermont - Permissible Exposure Limits - TWAs
U.S. - Washington - Permissible Exposure Limits - STELs
U.S. - Washington - Permissible Exposure Limits - TWAs
1,2-Propylene glycol (57-55-6)
U.S. - Minnesota - Hazardous Substance List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) List
U.S. - Texas - Effects Screening Levels - Long Term
U.S. - Texas - Effects Screening Levels - Short Term

SECTION 16: Other information

Other information : This document has been prepared in accordance with the SDS requirements of the
OSHA Hazard Communication Standard 29 CFR 1910.1200.
This information is based on our current knowledge and is intended to describe the product for the purposes of
health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any
specific property of the product.
SDS US (GHS HazCom)
Installation Note
Reference should always be made to the I-100 Victaulic Field Installation Handbook for This product shall be manufactured by Victaulic or to Victaulic specifications. All products
the product you are installing. Handbooks are included with each shipment of Victaulic to be installed in accordance with current Victaulic installation/assembly instructions.
products for complete installation and assembly data, and are available in PDF format Victaulic reserves the right to change product specifications, designs and standard
on our website at www.victaulic.com. equipment without notice and without incurring obligations.
Warranty Trademarks
Refer to the Warranty section of the current Price List or contact Victaulic for details. Victaulic and Zero-Flex are registered trademarks of Victaulic Company.

05.02 1941 Rev J Updated 04/2017 © 2017 Victaulic Company. All rights reserved.
victaulic.com 8
 March 16, 2021

Wade Robinson
Mullins Mechanical & Welding
622 Fertilla St
Carrollton, GA 30117

Project Amazon

Mr. Robinson:

This letter is to confirm that silicone is not intentionally utilized as a product component
or in the basic manufacturing process of Victaulic Vic Lube. Further information
regarding Vic Lube content and use can be referred to in Victaulic SDS 05.02.

I trust this information satisfies your requirements. If you require additional information,
please contact me.

Very truly yours,

Martin Wyatt
Global Quality Assurance Manager

Victaulic® is an ISO 9001 certified company

4901 Kesslersville Road Tel: 610/559-3300 • Fax: 610/250-8817 P.O. Box 31
Easton, PA 18040 Customer Service: 1-800-742-5842 Easton, PA 18044-0031
www.victaulic.com