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PracticeMCQ_D21-Sept-2024

This document contains a series of multiple-choice questions (MCQs) for a chemistry practice exam aimed at 12th-grade students. The questions cover various topics in organic chemistry, including reaction mechanisms, compound properties, and functional groups. Each question is designed to test the students' understanding of chemical principles and reactions.

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0% found this document useful (0 votes)
8 views27 pages

PracticeMCQ_D21-Sept-2024

This document contains a series of multiple-choice questions (MCQs) for a chemistry practice exam aimed at 12th-grade students. The questions cover various topics in organic chemistry, including reaction mechanisms, compound properties, and functional groups. Each question is designed to test the students' understanding of chemical principles and reactions.

Uploaded by

himeshmale7
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
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DEV Institute, Gandhinagar

Chapter : 8 Std 12 : Chemistry Date : 08/02/25


Total Marks : 100 MCQs Practice Time : 1 Hour
//X Section A
• Choose correct answer from the given options. [Each carries 1 Mark] [100]
1. Addition of water to alkynes occurs in acidic medium and in the presence of Hg2+ ions as a catalyst.
Which of the following products will be formed on addition of water to but-1-yne under these
conditions.
O O
|| ||
(A) CH 3 – CH 2 – CH2 – C – H (B) CH 3 – CH 2 – C – CH3

O O O
|| || ||
(C) CH 3 – CH 2 – C – OH + CO2 (D) CH 3 – C – OH + H – C – H
2. Which of the following compounds is most reactive towards nucleophilic addition reactions ?
O O O O
|| || || ||
(A) CH 3 – C – H (B) CH 3 – C – CH3 (C) C–H (D) C – CH 3

3. The correct order of increasing acidic strength is....


(A) Phenol < Ethanol < Chloroacetic acid < Acetic acid
(B) Ethanol < Phenol < Chloroacetic acid < Acetic acid
(C) Ethanol < Phenol < Acetic acid < Chloroacetic acid
(D) Chloroacetic acid < Acetic acid < Phenol < Ethanol
O
||
4. Compound Ph – O – C – Ph can be prepared by the reaction of....
(A) Phenol and benzoic acid in the presence of NaOH.
(B) Phenol and benzoyl chloride in the presence of pyridine.
(C) Phenol and benzoyl chloride in the presence of ZnCl2.
(D) Phenol and benzaldehyde in the presence of palladium.
5. The reagent which does not react with both, acetone and benzaldehyde ?
(A) Sodium hydrogen sulphite (B) Phenyl hydrazine
(C) Fehling’s solution (D) Grignard reagent
6. Cannizzaro’s reaction is not given by.....
CHO
(A) (B) CHO (C) HCHO (D) CH3CHO
CH3

7. Which product is formed when the compound CHO is treated with concentrated aqueous
KOH solution ?
O
+ ||
+
(A) KO CHO (B) CHO – OK + CH2OH

O O
+ || + + || + +
(C) KO C – OK+ + KO OK (D) C – KO + OK

Wish You - All The Best


40%
H2SO4 Isomerisation
8. CH3 – C b CH A CH3 – C – CH3
1%
HgSO4 O
Structure of ‘A’ and type of isomerism in the above reaction are respectively.
(A) Prop-1-en-2-ol, metamerism (B) Prop-1-en-1-ol, tautomerism
(C) Prop-2-en-2-ol, geometrical isomerism (D) Prop-1-en-2-ol, tautomerism
9. Compounds A and C in the following reaction are ..........
H 2SO4 Hydroboration
(A) (B) oxidation (C)
(ii) H2O g
(A) identical (B) positional isomers (C) functional isomers (D) optical isomers
10. Which is the most suitable reagent for the following conversion ?
O O
CH3 – CH = CH – CH2 – C – CH3 d- CH3 – CH = CH – CH2 – C – OH

(A) Tollen’s reagent (B) Benzoyl peroxide


(C) I2 and NaOH solution (D) Sn and NaOH solution
11. In Clemmensen Reduction carbonyl compound is treated with ...........
(A) Zinc amalgam + HCl (B) Sodium amalgam + HCl
(C) Zinc amalgam + nitric acid (D) Sodium amalgam + HNO3
12. Which of the following compounds will give butanone on oxidation with alkaline KMnO4 solution ?
(A) Butan-1-ol (B) Butan-2-ol (C) Both of these (D) None of these
13. ) Jones reagent is ........... .
(A) Zn – Hg / HCl (B) CrO2Cl2/CS2 (C) CrO3 – H2SO4 (D) NH2 – NH2 / KOH
14. ) Which of the following compound gives halo form test ?

(A) CH3 – CH – CH3 (B) CH3CH2CHO (C) CH3CH2 – C – CH2CH3 (D) CH3CH2COOH
| ||
OH O
15. ) Which is correct formula of Wilkinson catalyst ?
(A) [(Ph3P)3 RhCl] (B) [(Me3P)3 RhCl] (C) [(Ph3As)3 RhCl] (D) [(Me3As)3 RhCl]
16. ) What is common name of HOOC – (CH2)3 – COOH ?
(A) Malonic acid (B) Succinic acid (C) Glutaric acid (D) Adipic acid
17. ) Which of the following is Cannizzaro reaction ?
D
(A) 2CH3CHO + didl. (B) 2HCHO + conc. NaOH ¾¾
®
ether
(C) 2CH3Cl + 2Na ¾¾¾
® (D) 2CH3OH + Na ¾®
18. ) Which reagent is used in Gattermann reaction ?
(A) Cu/HX (B) Cu2X2/HX (C) CHCl3 + NaOH (D) Zn-H/HCl
19. ) Correct structure of cinnamaldehyde is ......
CH=CH–CHO CºC–CHO

(A) (B)

CH2–CH2–CHO CH2–CH=CH–CHO
(C) (D)

146) Which has lowest pKa ?


20.
(A) CH3COOH (B) C6H5COOH (C) C6H5CH2COOH (D) CH3CH2COOH
21. ) Which of the following oxidising agents is used for preparation of benzaldehyde form methyl
benzene ?
(A) KMnO4/H2SO4 (B) CrO–3H2SO4 (C) CrO2Cl2 (D) K2Cr2O7/H2SO4

Wish You - All The Best


22. ) Which of the following compounds does not give Iodoform test ?
(A) Methyl alcohol (B) Acetone (C) Acetophenone (D) Isopropyl alcohol
23. ) What is the correct increasing order of acidity among the following ?
(A) NO2CH2CH2COOH < CH3CH2COOH < FCH2CH2COOH < ClCH2CH2COOH
(B) NO2CH2CH2COOH < FCH2CH2COOH < ClCH2CH2COOH < CH3CH2COOH
(C) FCH2CH2COOH < ClCH2CH2COOH < NO2CH2CH2COOH < CH3CH2COOH
(D) CH3CH2COOH < ClCH2CH2COOH < FCH2CH2COOH < NO2CH2CH2COOH
24. ) Out of the following compounds, which compound gives aldol condensation ?
(A) Methanal (B) 2-methyl pentanal]
(C) Benzaldehyde (D) 2,2-dimethyl butanal
25. ) Which is the best reagent for gaining good product of aldehyde from primary alcohol ?
(A) PCC (B) CrO3
(C) KMnO4 (D) Heating with Cu at 573 K
26. ) Which carboxylic acid is present in vinegar ?
(A) Benzoic acid (B) Methanoic acid (C) Ethanoic acid (D) Oxalic acid
27. ) Which type of hydrogen should be present in aldehyde or ketone compounds for aldol condensation
reaction ?
(A) a (B) b (C) g (D) d
28. ) Sodium salt of which acid is used as food preservative ?
(A) Phthellic acid (B) Adipic acid (C) Formic acid (D) Benzoic acid
29. ) Conjugate base of which of the following acid is weak ?
(A) CH3CH2CH(Br)COOH (B) CH3CH2CH(F)COOH
(C) CH3CH2CH(I)COOH (D) CH3CH2CH(Cl)COOH
30. ) For which acid the value of pKa is highest ?
COOH COOH COOH COOH

(A) (B) (C) (D)

OCH 3 NO2 CH 3 Cl
31. ) By hydrolysis of which substance carboxylic acid can be obtained ?
(A) Acetone (B) Propanoyl chloride (C) Acetonitrile (D) Acetaldehyde
32. ) Which of the following compound will give disproportionation reaction in the presence of alkali ?
(A) Acetophenone (B) Acetone (C) Acetaldehyde (D) Formaldehyde
33. ) What is the final product ‘C’ in the following reaction ?

HCN H3O+ Sodalime


CH 3CHO ¾¾¾® A ¾¾¾¾ ® B ¾¾¾¾¾® C
(A) Ethanol (B) Propane (C) Propanol (D) Propanoic acid
34. ) Which of the following compounds undergo aldol condensation ?

(A) H – CHO (B) CO – CH3 (C) CHO (D) CO

Cl2 /Red P
35. ) Propanoic acid ¾¾¾¾¾¾
® X. X = ..........
H2 O
(A) a-chloropropanoic acid (B) Propanol
(C) Propane (D) Propanal
36. ) Which of the following compound will not give silver mirror test ?
(A) Acetaldehyde (B) Methanal (C) Acetone (D) Benzaldehyde
H+
129) CH3CHO + NH2OH ¾¾¾¾
37.
- ® X. Identify product X.
H2O
(A) Acetaldehyde hydrazone (B) Acetaldoxime
(C) Schiff’s reagent (D) Acetoxime
Wish You - All The Best
129) CH3CHO + NH2OH -H2O X. Identify product X.
(A) Acetaldehyde hydrazone (B) Acetaldoxime
(C) Schiff’s reagent (D) Acetoxime
38. ) What will be the hybridization of carbonyl carbon after nucleophillic addition reaction ?
(A) d3s (B) sp3 (C) sp (D) sp2
39. ) Which of the following compound has highest boiling point ?
(A) CH3CH2COOH (B) CH3 – CH 2 – C – OH (C) CH3 – CH2 – CH2OH (D) CH3 – C – CH 3
|| ||
O O
40. ) Which functional group is present in Acrolein ?
(A) – C – NH 2 (B) – C – H (C) – C – OH (D) – C º N
|| || ||
O O O
41. ) Which compound is used to prepare aniline blue in dye industry ?
(A) Benzene-1,4-dioicacid(B) Benzaldehyde (C) Benzoic acid (D) Acetone
42. ) Which of the following acid has highest value of pKa ?
(A) 2-Methyl propanoic acid (B) Propanoic acid
(C) Ethanoic acid (D) 2, 2-Dimethyl propanoic acid
1.dil. NaOH
43. ) Ethanal + Benzaldehyde ¾¾¾¾¾¾® X ‘X’ identify product “X”..
2. D; - H 2O
(A) 3-phenyl prop-2-enal (B) 3-phenyl propanal
(C) 3-phenyl prop-2-enol (D) 2-phenyl prop-2-enal
44. ) Which of the following compound is more reactive towards nucleophillic addition reaction ?
(A) Acetopheone (B) Benzaldehyde (C) Ethylphenylketone (D) Benzophenone
45. ) Which of the following substances on oxidation gives product having one carbon atom less ?
(A) Ethanal (B) Ethanol (C) Acetone (D) Ethanoic acid
46. ) Which compound is not a derivative of Carboxylic acid ?
(A) Acid chloride (B) Amide (C) Aldehyde (D) Anhydride
47. ) Which reagent does not reduce Ketone ?
(A) NH2 · NH2 + KOH (B) Zn · Hg + conc. (C) NH2 · NH2 + HCl (D) Mg · Hg + H2O
48. ) Which compound does not undergo aldol condensation ?
(A) Acetaldehyde (B) Monochloro acetaldehyde
(C) Dichloro acetaldehyde (D) Trichloro acetaldehyde
49. ) Which of the following order of acidic strength is correct for the following compounds ?
COOH COOH COOH
COOH
NO2
[i] [ii] [iii] [iv]
NO 2 CH3
(A) iii < iv < ii < i (B) ii < iv < i < iii (C) ii < i < iv < iii (D) iii < iv < i < ii
50. ) In which of the following reactions, hydrocarbon is not obtained ?
NH 2 — NH 2/KOH
NaBH4 (B) CH3CHO ¾¾¾¾¾¾¾¾¾ ®
(A) CH3 – CO – CH3 ¾¾¾¾ ® Ethylene Glycol
H2O 453-473 K
Zn · Hg / HI / Red P
(C) CH3COCH3 ¾¾¾¾¾¾ ® (D) CH3COOH ¾¾¾¾¾¾ ®
Conc.HCl 473 K
51. ) Which of the following compound will give Aldol condensation reaction ?
(A) Formaldehyde (B) Trimethyl acetaldehyde
(C) Trichloro acetaldehyde (D) Acetaldehyde
114) What is the IUPAC name of Acrolein ?
52.
(A) Prop-1-en-1-one (B) Prop-2-enal (C) Prop-1-en-2-ol (D) Prop-2-en-1-ol
113) How many p and s bonds are present in product obtained by oxidation of p-xylene by KMnO4/KOH
53.
and dil. H2SO4 ?
(A) 18, 5 (B) 16, 5 (C) 5, 18 (D) 5, 16
Wish You - All The Best
54. ) Which is the suitable product of reaction
(i) KMnO 4/KOH
hex-3-ene ¾¾¾¾¾¾¾¾
(ii) dil. H2SO 4
®

(A) Butanoic acid (B) Ethanoic acid (C) Propanoic acid (D) Propanal
55. ) Which of the following is used for preparation of aniline blue in dye industry ?
(A) Adipic acid (B) Formic acid (C) Succinic acid (D) Benzoic acid
56. ) What is the correct order of acidity of compound (I), (II) and (III) ?
(I) 4-Nitrobenzoic acid
(II) 4-Methoxy Benzoic acid
(III) Benzoic acid
(A) I < II < III (B) I > III > II (C) I > II > III (D) I < III < II
57. ) Which one is the common name of the compound CH2 = CH – CHO ?
(A) Acrolein (B) Mesityl Oxide (C) Prop-2-Enal (D) Propanal-1-ene
58. ) Which of the following compound does not give cannizzaro reaction ?
CHO
(A) HCHO (B) CHO (C) (D) CH3CHO
CH3
59. ) Identify the product (C) in the following reaction :
NH Br + NaOH NaNO + HCl
CH 3COOH ¾¾¾
3® A ¾¾¾¾¾
2 ® B ¾¾¾¾¾¾
2 ®C
D H 2O
(A) CH3OH (B) CH3 – CH2OH (C) CH3 – CH2N2+Cl– (D) CH3 – CH2 – NH2
60. ) Identify the incorrect order of increasing acidic strength :
(A) CH3COOH < ClCH2COOH (B) ClCH2COOH < FCH2COOH
(C) FCH2CH2CH2COOH < CH3CHFCH2COOH (D) HCOOH < C6H5COOH
61. ) What will be the main product in the following reaction ?
OH –
CHO + CH3CHO ?
D

(A) CH2 – CH2 – CHO (B) CH = CH – CHO

CH2 – CH – CHO
(C) | (D) CH = CH – COOH
OH
62. ) Which of the following will not give iodoform reaction with sodium hypoiodite ?
O OH
(A) (B)

(C) CH3 – CHO (D) CH3 – CH2 – CO – CH2 – CH3


63. ) Which compound has maximum acidic strength of the following ?
(A) 4-methoxy benzoic acid (B) Benzoic acid
(C) 4-methoxy benzoic acid (D) 4-nitro benzoic acid
64. ) Which compound give Cannizzaro reaction from following ?
(A) CH3CHO (B) CCl3CHO (C) CH2ClCHO (D) CHCl2CHO
65. ) Which reagent is used to convert Allyl alcohol to propenal ?
(A) PCC (B) O3/H2O - Zn dust (C) DIBAL-H (D) All above
(1) CO2 /ether NaOH + CaO
100) C6H5CH2 – MgBr ¾¾¾¾¾¾¾
66. ® ‘X’’ ¾¾¾¾¾¾¾ ® ‘Y’ ?
(2) H 3O + D
What is the final product in this reaction ?
(A) C6H5CH3 (B) C6H5CH2CH3 (C) C6H6 (D) C6H5CH2OH
67. Which of the following acid has highest pKa value ?
(A) NCCH2COOH (B) O2NCH2COOH (C) FCH2COOH (D) C6H5CH2COOH
Wish You - All The Best
Which of the following acid has highest pKa value ?
(A) NCCH2COOH (B) O2NCH2COOH (C) FCH2COOH (D) C6H5CH2COOH
68. Which is the major product obtained by hydrolysis of compound formed by reaction between
formaldehyde and ethyl magnesium bromide ?
(A) Ethan-1-ol (B) Propan-2-ol
(C) Propan-1-ol (D) 2-methyl-propan-2-ol
KMnO4 / KOH Soda lime CH 3 Cl
69. P ¾¾¾¾¾¾¾® Q ¾¾¾¾¾¾ ® R ¾¾¾¾¾¾® S
D Anhy. AlCl 3
If P and S are toluene, Q & R are ...... and ........ respectively.
(A) Benzaldehyde, Benzoic acid (B) Benzaldehyde, Sodium benzoate
(C) Benzoic acid, Benzene (D) Benzene, Benzoic acid
D
70. Benzoyl chloride + Sodium benzoate ¾¾ ® ......
(A) Benzaldehyde (B) Benzyl alcohol (C) Benzyl benzoate (D) Benzoic anhydride
71. Which of the following compound undergoes aldol condensation ?
(A) Formaldehyde (B) Trichloro acetaldehyde
(C) Trimethyl acetaldehyde (D) Acetaldehyde
72. Which of the following compound upon oxidation gives isophthalic acid ? [GUJCET-2018]

(A) p-Xylene (B) m-Xylene (C) o-Xylene (D) m-Cresol


73. Which of the following is not a final product obtained by cross aldol condensation of ethanal and
propanal ?
(A) 3-Methyl-but-2-enal (B) 2-Methyl-pent-2-enal (C) But-2-enal (D) Pent-2-enal
74. Which of the following mixture can form an alloy ?
(A) Fe, Ni, Cr (B) Cr, Co, Na (C) Fe, Mn, Mg (D) Ni, Mg, Na
75. In manufacturing of sulphuric acid in presence of platinum catalyst, which metal impurity acts as
catalytic poison ?
(A) Fe (B) Cr (C) Cu (D) V
76. Which is the correct structural formula of Aspirin ?
OCOCH3 OH OCOCH3 COOCH3
OH COOCH3 COOH COOH
(A) (B) (C) (D)

77. Which of the organic products of the following reactions has the least boiling point ?
LiAlH4 NaBH4
(A) CH3 – CH2 – COOH ¾¾¾¾® (B) CH3 – C – CH3 ¾¾¾¾®
H2O H2O
||
NaBH4 O (BH3 )2
(C) CH3 – CH2 – CHO ¾¾¾¾® (D) CH3 – CH = CH2 ¾¾¾¾¾¾¾ ®
H2O H2 2 · OH –
O
78. What is the main product obtained by the cross-aldol condensation of benzene carbaldehyde and 1-
phenyl-ethane-1-one ?

(A) CH=CH–CHO (B) CH = CH – CO

(C) CH2 – CH = CH (D) CH2 – CH = CH – CO


79. Which compound does not give Benedict test ?
(A) C6H5CHO (B) (CH3 )2 · CHCHO (C) CH3CHO (D) (CH3 )3C · HCHO
80. Which order is improper for acidic strength ?
(A) O2N COOH > COOH > H3C COOH
(B) CH 3 – CH 2 – C H – COOH > CH 3 – C H – CH2 – COOH > C H 2 – CH2 – CH2 – COOH
| | |
Cl Cl Cl
(C) Cl3CCOOH > Cl2CHCOOH > ClCH2COOH
(D) HCOOH > CH3 COOH > C6H5COOH

Wish You - All The Best


81. Which product is obtained by the reaction of propanone with magnesium amalgam and water ?
CH3 CH3
(A) CH3 C C CH3 (B) CH3 – CH2 – CH3
OH OH
(C) CH 3 – C – CH 3 (D) CH3 CH CH CH3
||
O CHO CHO
82. Which compound is the least reactive ?
(A) Acetophenone (B) Benzaladehyde (C) Formaldehyde (D) Benzophenone
83. What is IUPAC name for isophthalic acid ?
(A) Benzene-1,3-dicarboxylicacid (B) Benzene-1,2-dicarboxylicacid
(C) Benzene-1,4-dicarboxylicacid (D) Benzene-1,5-dicarboxylicacid
84. What is the formula of Acrolein ?
(A) CH2 = CH – CHO (B) CH2 = CH – CN
(C) CH2 = CH – COOH (D) CH2 = CH – CONH2
85. Which of the following order of acidic strength is not correct ?
(A) Cl3 · C · COOH > Cl2 · CH · COOH > Cl · CH2 · COOH
(B) CH 3 – CH2 – C H – COOH > CH3 – C H – CH 2 – COOH > C H 2 – CH 2 – CH 2 – COOH
| | |
Cl Cl Cl
(C) H · COOH > CH3 COOH > C6 H5 COOH
(D) CH3COOH > CH3 · CH2 · COOH > (CH3)2 · CH · COOH
86. Which of the following compound does not react with concentrated alkali to give corresponding
alcohol and salt of carboxylic acid ?
(A) Benzaldehyde (B) Trimethyl acetaldehyde
(C) Dimethyl acetaldehyde (D) Formaldehyde
87. The solution of Fehling B contains .......... .
(A) Alkaline sodium potassium citrate. (B) Acidified Rochelle salt.
(C) Alkaline sodium potassium tartarate. (D) Acidified sodium potassium citrate.
88. Which of the following is the correct order of acidic strength ?
(A) CH3COOH > ClCH2COOH >Cl2CHCOOH > Cl3 · C · COOH
(B) Cl3 · C · COOH > Cl2CH · COOH >Cl · CH2COOH > CH3COOH
(C) CH3COOH > Cl3 · C · COOH >Cl2CH · COOH > Cl · CH2COOH
(D) CH3COOH > ClCH2COOH >Cl2 · CH · COOH > Cl3 · C · COOH
89. Identify the final product [D] obtained in the following sequence of reactions.
(i) LiAlH 4 H2SO 4
CH3CHO [A] [B]
(ii) H3O
+ D
Br
HBr
[D] [C]
Na / Dry ether

(A) HC = C – Na+ (B) (C) (D) C4H10

90. Identify product (A) in the following reaction :


O
Zn – Hg
(A) + 2H2O
Conc. HCl
O

(A) CH3
CH3 (B)

OH OH
Wish You - All The Best
(C) (D) CH2
CH2OH
OH
CH3 (B)

OH OH
(C) (D) CH2
CH2OH
OH

91. Identify the major product obtained in the following reaction :


O
+ D
+ 2[Ag(NH3)2] + 3–OH major product
H
O
OH OH OH OH

(A) (B) (C) (D)


COO– OH OH
COO–
92. Complete the following reaction

HCN OH Conc. H2SO4


O [C] [C] is ........
CN D

(A) COOH (B) OH (C) COOH (D) CHO


93. Which of the following option contains the correct match.
List-I List-II
(P) Clemmenson reduction (i) Con. KOH
(Q) Reimer Tiemann reaction (ii) Br 2/KOH
(R) Cannizzaro reaction (iii) CHCl3/KOH
(S) Hoffmann bromamide (iv) Zn-Hg/HCl
degradation reaction
Choose the correct option from the options given below.
(A) (P – i),(Q – ii),(R – iii),(S – iv) (B) (P – iv),(Q – iii),(R – i),(S – ii)
(C) (P – ii),(Q – iii),(R – iv),(S – i) (D) (P – iii),(Q – iv),(R – i),(S – ii)
94. Cannizzaro reaction is an example of disproportionation reaction. What is the catalyst used in
Cannizzaro reaction ?
(A) FeCl 3 (B) NaOH/H2O (C) ZnCl 2/H+ (D) H2/Pd/BaSO4
95. Compound X on reaction with O3 followed by Zn/H2O gives formaldehyde and 2-methyl propanal
as products. The compound X is
(A) 2-Methylbut-2-ene (B) Pent-2-ene (C) 3-Methylbut-1-ene (D) 2-Methylbut-1-ene
96. Match List-I with List-II.
List-I List-II (Reaction of
(Products formed) carbonyl compound with)
(a) Cyanohydrin (i) NH2OH
(b) Acetal (ii) RNH2
(c) Schiff's base (iii) alcohol
(d) Oxime (iv) HCN

Choose the correct answer from the options given below.


(A) (a - i),(b - iii),(c - ii),(d - iv) (B) (a - iv),(b - iii),(c - ii),(d - i)
(C) (a - iii),(b - iv),(c - ii),(d - i) (D) (a - ii),(b - iii),(c - iv),(d - i)
dry H3O +
97. RMgX + CO 2 ¾¾¾¾ ® Y ¾¾¾¾ ® RCOOH What is Y in the above reaction ?
ether
(A) RCOO–X+ (B) (RCOO)2Mg (C) RCOO–Mg+X (D) R3CO–Mg+X
98. Match List-I with List-II
List-I Wish You - All The BestList-II
COCl CHO
Match List-I with List-II
List-I List-II
COCl CHO

(A) H2 (I) Gatterman Koch reaction


Pb-BaSO4
SnCl 2 /HCl
(B) CH3 – CN ¾¾¾¾¾¾ +
® CH3 – CHO (ii) Etard reaction
H3O
CH3 CHO

(C) CrO 2Cl2 (III) Stephen reaction


H O+
3
CHO

(D) CO, HCl (IV) Rosenmund reaction


AlCl3(anhyd)

Choose the correct answer from the options given below :


(A) (A - IV),(B - III),(C - II),(D - I) (B) (A - I), (B - II), (C - III), (D - IV)
(C) (A - II),(B - III),(C - IV ),(D - I) (D) (A - III), (B - II), (C - I), (D - IV)
99. An alkene on ozonolysis gives methanal as one of the product. Its structure is
CH2 – CH = CH2 CH2CH2CH3 CH = CH – CH3 CH2 – CH2 – CH3
(A) (B) (C) (D)

100. Reaction between benzaldehyde and acetophenone in presence of dilute NaOH is known as ............
(A) Cross cannizzaro’s reaction (B) Cross aldol condensation
(C) Aldol condensation (D) Cannizzaro’s reaction

Wish You - All The Best


DEV Institute, Gandhinagar
Chapter : 8 Std 12 : Chemistry Date : 08/02/25
Total Marks : 100 MCQs Practice Time : 1 Hour
//X Section A
• Choose correct answer from the given options. [Each carries 1 Mark] [100]
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