PracticeMCQ_D21-Sept-2024
PracticeMCQ_D21-Sept-2024
O O O
|| || ||
(C) CH 3 – CH 2 – C – OH + CO2 (D) CH 3 – C – OH + H – C – H
2. Which of the following compounds is most reactive towards nucleophilic addition reactions ?
O O O O
|| || || ||
(A) CH 3 – C – H (B) CH 3 – C – CH3 (C) C–H (D) C – CH 3
7. Which product is formed when the compound CHO is treated with concentrated aqueous
KOH solution ?
O
+ ||
+
(A) KO CHO (B) CHO – OK + CH2OH
O O
+ || + + || + +
(C) KO C – OK+ + KO OK (D) C – KO + OK
(A) CH3 – CH – CH3 (B) CH3CH2CHO (C) CH3CH2 – C – CH2CH3 (D) CH3CH2COOH
| ||
OH O
15. ) Which is correct formula of Wilkinson catalyst ?
(A) [(Ph3P)3 RhCl] (B) [(Me3P)3 RhCl] (C) [(Ph3As)3 RhCl] (D) [(Me3As)3 RhCl]
16. ) What is common name of HOOC – (CH2)3 – COOH ?
(A) Malonic acid (B) Succinic acid (C) Glutaric acid (D) Adipic acid
17. ) Which of the following is Cannizzaro reaction ?
D
(A) 2CH3CHO + didl. (B) 2HCHO + conc. NaOH ¾¾
®
ether
(C) 2CH3Cl + 2Na ¾¾¾
® (D) 2CH3OH + Na ¾®
18. ) Which reagent is used in Gattermann reaction ?
(A) Cu/HX (B) Cu2X2/HX (C) CHCl3 + NaOH (D) Zn-H/HCl
19. ) Correct structure of cinnamaldehyde is ......
CH=CH–CHO CºC–CHO
(A) (B)
CH2–CH2–CHO CH2–CH=CH–CHO
(C) (D)
OCH 3 NO2 CH 3 Cl
31. ) By hydrolysis of which substance carboxylic acid can be obtained ?
(A) Acetone (B) Propanoyl chloride (C) Acetonitrile (D) Acetaldehyde
32. ) Which of the following compound will give disproportionation reaction in the presence of alkali ?
(A) Acetophenone (B) Acetone (C) Acetaldehyde (D) Formaldehyde
33. ) What is the final product ‘C’ in the following reaction ?
Cl2 /Red P
35. ) Propanoic acid ¾¾¾¾¾¾
® X. X = ..........
H2 O
(A) a-chloropropanoic acid (B) Propanol
(C) Propane (D) Propanal
36. ) Which of the following compound will not give silver mirror test ?
(A) Acetaldehyde (B) Methanal (C) Acetone (D) Benzaldehyde
H+
129) CH3CHO + NH2OH ¾¾¾¾
37.
- ® X. Identify product X.
H2O
(A) Acetaldehyde hydrazone (B) Acetaldoxime
(C) Schiff’s reagent (D) Acetoxime
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129) CH3CHO + NH2OH -H2O X. Identify product X.
(A) Acetaldehyde hydrazone (B) Acetaldoxime
(C) Schiff’s reagent (D) Acetoxime
38. ) What will be the hybridization of carbonyl carbon after nucleophillic addition reaction ?
(A) d3s (B) sp3 (C) sp (D) sp2
39. ) Which of the following compound has highest boiling point ?
(A) CH3CH2COOH (B) CH3 – CH 2 – C – OH (C) CH3 – CH2 – CH2OH (D) CH3 – C – CH 3
|| ||
O O
40. ) Which functional group is present in Acrolein ?
(A) – C – NH 2 (B) – C – H (C) – C – OH (D) – C º N
|| || ||
O O O
41. ) Which compound is used to prepare aniline blue in dye industry ?
(A) Benzene-1,4-dioicacid(B) Benzaldehyde (C) Benzoic acid (D) Acetone
42. ) Which of the following acid has highest value of pKa ?
(A) 2-Methyl propanoic acid (B) Propanoic acid
(C) Ethanoic acid (D) 2, 2-Dimethyl propanoic acid
1.dil. NaOH
43. ) Ethanal + Benzaldehyde ¾¾¾¾¾¾® X ‘X’ identify product “X”..
2. D; - H 2O
(A) 3-phenyl prop-2-enal (B) 3-phenyl propanal
(C) 3-phenyl prop-2-enol (D) 2-phenyl prop-2-enal
44. ) Which of the following compound is more reactive towards nucleophillic addition reaction ?
(A) Acetopheone (B) Benzaldehyde (C) Ethylphenylketone (D) Benzophenone
45. ) Which of the following substances on oxidation gives product having one carbon atom less ?
(A) Ethanal (B) Ethanol (C) Acetone (D) Ethanoic acid
46. ) Which compound is not a derivative of Carboxylic acid ?
(A) Acid chloride (B) Amide (C) Aldehyde (D) Anhydride
47. ) Which reagent does not reduce Ketone ?
(A) NH2 · NH2 + KOH (B) Zn · Hg + conc. (C) NH2 · NH2 + HCl (D) Mg · Hg + H2O
48. ) Which compound does not undergo aldol condensation ?
(A) Acetaldehyde (B) Monochloro acetaldehyde
(C) Dichloro acetaldehyde (D) Trichloro acetaldehyde
49. ) Which of the following order of acidic strength is correct for the following compounds ?
COOH COOH COOH
COOH
NO2
[i] [ii] [iii] [iv]
NO 2 CH3
(A) iii < iv < ii < i (B) ii < iv < i < iii (C) ii < i < iv < iii (D) iii < iv < i < ii
50. ) In which of the following reactions, hydrocarbon is not obtained ?
NH 2 — NH 2/KOH
NaBH4 (B) CH3CHO ¾¾¾¾¾¾¾¾¾ ®
(A) CH3 – CO – CH3 ¾¾¾¾ ® Ethylene Glycol
H2O 453-473 K
Zn · Hg / HI / Red P
(C) CH3COCH3 ¾¾¾¾¾¾ ® (D) CH3COOH ¾¾¾¾¾¾ ®
Conc.HCl 473 K
51. ) Which of the following compound will give Aldol condensation reaction ?
(A) Formaldehyde (B) Trimethyl acetaldehyde
(C) Trichloro acetaldehyde (D) Acetaldehyde
114) What is the IUPAC name of Acrolein ?
52.
(A) Prop-1-en-1-one (B) Prop-2-enal (C) Prop-1-en-2-ol (D) Prop-2-en-1-ol
113) How many p and s bonds are present in product obtained by oxidation of p-xylene by KMnO4/KOH
53.
and dil. H2SO4 ?
(A) 18, 5 (B) 16, 5 (C) 5, 18 (D) 5, 16
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54. ) Which is the suitable product of reaction
(i) KMnO 4/KOH
hex-3-ene ¾¾¾¾¾¾¾¾
(ii) dil. H2SO 4
®
(A) Butanoic acid (B) Ethanoic acid (C) Propanoic acid (D) Propanal
55. ) Which of the following is used for preparation of aniline blue in dye industry ?
(A) Adipic acid (B) Formic acid (C) Succinic acid (D) Benzoic acid
56. ) What is the correct order of acidity of compound (I), (II) and (III) ?
(I) 4-Nitrobenzoic acid
(II) 4-Methoxy Benzoic acid
(III) Benzoic acid
(A) I < II < III (B) I > III > II (C) I > II > III (D) I < III < II
57. ) Which one is the common name of the compound CH2 = CH – CHO ?
(A) Acrolein (B) Mesityl Oxide (C) Prop-2-Enal (D) Propanal-1-ene
58. ) Which of the following compound does not give cannizzaro reaction ?
CHO
(A) HCHO (B) CHO (C) (D) CH3CHO
CH3
59. ) Identify the product (C) in the following reaction :
NH Br + NaOH NaNO + HCl
CH 3COOH ¾¾¾
3® A ¾¾¾¾¾
2 ® B ¾¾¾¾¾¾
2 ®C
D H 2O
(A) CH3OH (B) CH3 – CH2OH (C) CH3 – CH2N2+Cl– (D) CH3 – CH2 – NH2
60. ) Identify the incorrect order of increasing acidic strength :
(A) CH3COOH < ClCH2COOH (B) ClCH2COOH < FCH2COOH
(C) FCH2CH2CH2COOH < CH3CHFCH2COOH (D) HCOOH < C6H5COOH
61. ) What will be the main product in the following reaction ?
OH –
CHO + CH3CHO ?
D
CH2 – CH – CHO
(C) | (D) CH = CH – COOH
OH
62. ) Which of the following will not give iodoform reaction with sodium hypoiodite ?
O OH
(A) (B)
77. Which of the organic products of the following reactions has the least boiling point ?
LiAlH4 NaBH4
(A) CH3 – CH2 – COOH ¾¾¾¾® (B) CH3 – C – CH3 ¾¾¾¾®
H2O H2O
||
NaBH4 O (BH3 )2
(C) CH3 – CH2 – CHO ¾¾¾¾® (D) CH3 – CH = CH2 ¾¾¾¾¾¾¾ ®
H2O H2 2 · OH –
O
78. What is the main product obtained by the cross-aldol condensation of benzene carbaldehyde and 1-
phenyl-ethane-1-one ?
(A) CH3
CH3 (B)
OH OH
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(C) (D) CH2
CH2OH
OH
CH3 (B)
OH OH
(C) (D) CH2
CH2OH
OH
100. Reaction between benzaldehyde and acetophenone in presence of dilute NaOH is known as ............
(A) Cross cannizzaro’s reaction (B) Cross aldol condensation
(C) Aldol condensation (D) Cannizzaro’s reaction
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