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Tutorial Heat effects

The document contains tutorial questions related to thermodynamics, including calculations of standard heat for specific reactions at different temperatures, the application of Hess's Law to determine the heat of formation for n-butane, heat transfer in a heat exchanger, and the estimation of latent heat of vaporization for Benzene using Watson's equation. Each question requires specific thermodynamic principles and equations to solve. The tutorial is dated October 18, 2023.

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Didintle George
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4 views

Tutorial Heat effects

The document contains tutorial questions related to thermodynamics, including calculations of standard heat for specific reactions at different temperatures, the application of Hess's Law to determine the heat of formation for n-butane, heat transfer in a heat exchanger, and the estimation of latent heat of vaporization for Benzene using Watson's equation. Each question requires specific thermodynamic principles and equations to solve. The tutorial is dated October 18, 2023.

Uploaded by

Didintle George
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
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CTH260S Tutorial 4 18/10/2023

Question 1
(a) Calculate the standard heat at 298 K for the following reaction:
C 2 H 4 ( g ) + H 2 O( g ) → C 2 H 5 OH ( g )
(b) For the same reaction, what is the standard heat of reaction at 400 K if the heat
capacity is given by the equation below?

Cp = R( A + BT + CT 2 + DT −2 )

Question 2
A reaction such as the formation of n-butane: 4C(s) + 5H 2 (g) → C 5 H 10 ( g )
is not feasible in practice. However, this equation results from combination of the following
combustion reactions:

1 : C(s) + O 2 (g) → CO 2 (g) ΔH 0298 = −393509 J


2 : H 2 (g) + O 2 (g) → H 2 O(l) ΔH 0298 = −285830 J
3 : CO 2 (g) + H 2 O(l) → C 4 H 10 (g) + O 2 (g) ΔH 0298 = 2877396 J

Balance the three equations and use Hess’s Law to calculate the heat of formation of n-
butane.

Question 3
For steady flow in a heat exchanger at approximately atmospheric pressure, what is the
heat transferred when 10 mol of SO2 is heated from 200 to 1100°C?

Question 4
Given that the latent heat of vaporization of Benzene at 25°C is 433.3 J/g, use Watson’s
equation to estimate the latent heat at the boiling point (80°C). The critical temperature of
Benzene is 562 K.

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