Silicone Rubber
Silicone Rubber
Introduction
From this article, you will learn what silicone rubber molding is, its products, and their
uses.You will learn:
Silicone rubber is a modern elastomer that has properties that differentiates it from
organic elastomers such as natural rubber, latex, and polyurethane. It is made from
silicone and oxygen, which are two of the most common elements on earth and exist
as silica and silicate. The silicon base for silicone rubber was isolated in the early
19th century but did not find commercial use until the middle of the 20th century.
When silicone rubber was first synthesized, it was believed that it did not have any
practical or commercial use. In the 20th century, electric motors and generators were
a common part of industrial operations. Since they generated a great deal of heat,
they need to be covered in a heat resistant material. At the time, resin impregnated
glass fibers seemed to be the solution. Unfortunately, the resin material could not
endure the heat from small motors.
In the search for a heat resistant material, scientists synthesized the first silicone
polymer that could withstand the heat of the motors and generators. The discovery
led to the production of silicone rubber, which was initiated by Dow Chemical and
Dow Corning in 1943. As engineers studied the material, they discovered its broader
use for other products.
Fluorosilicone Rubber
Fluorosilicone rubber has the same structure as silicone rubber with fluorine added
to its polymer chain. It combines the best properties of fluorocarbons and silicones
and is solvent and oil resistant, able to withstand extremely low temperatures with
high temperature stability, and will not deform when placed under pressure. As with
other forms of silicone rubber, fluorosilicone rubber can be molded, extruded, and
calendered and is widely used in aerospace and automotive applications. The main
characteristic of fluorosilicone rubber, compared to regular silicone rubber, is its
exceptional resistance to the effects of fuels, oils, and chemicals, which makes it
more expensive.
Methyl Group – The methyl group is a dimethyl silicone elastomer group and was
the first group of silicone elastomers to be developed.
Methyl and Phenyl Groups – Methyl and phenyl groups are referred to as
methyl-phenyl silicone elastomers and were developed for low temperature
applications.
Methyl and Vinyl Groups – Methyl and vinyl groups are helped in the
vulcanization process by the vinyl content.
Methyl, Phenyl, and Vinyl Groups – Methyl, phenyl, and vinyl groups are
another group that is good for low temperature applications.
Fluorine, Vinyl, and Methyl Groups – Fluorine, vinyl, and methyl groups are
fluorosilicone rubber known for its resistance to the effects of oil, fuels, and solvents.
Chapter Three: How Silicone Rubber is Made
Silicone, known as polysiloxane, is a polymer that has a rubber-like consistency with
molecules having chains of oxygen and silicon atoms. It is different from other forms
of polymers in that it does not have carbon as its backbone. The primary ingredient
of silicone is silica, which is found in sand. Silicone differs from silicon in that it is
flexible, softer, and resistant to the effects of extreme heat.
Compounding
The PDMS is cross-linked using heat or radiation to create bonds between the
PDMS chains, the result of which is a three-dimensional network structure. The
various types of silicone are produced by adding phenyl, methyl, fluorine, or vinyl
groups to the PDMS chains during its synthesis. Each of the different groups gives
the silicone rubber different properties and characteristics. The completed compound
can be molded or extruded to create different shapes.
Final Form
The final step in the production of silicone rubber involves determining the final form
to be used for the production of various types of rubber products. This is achieved by
adding fillers and additives to enhance specific properties and add color. The steps
in its manipulation are designed to produce the properties for the industry where it
will be used.
Crosslinking – The crosslinking process for silicone rubber includes the use of
various peroxides or platinum catalysts to create mechanical stability.
Fillers – Fillers are used to enhance tear resistance or increase conductivity and
include pyrogenic silica and carbon black.
Stabilizers – The different forms of stabilizers are added to improve silicone
rubber’s heat resistance.
Flame Retardants – Flame retardants include carbon black, aluminum
trihydrate, zinc, platinum, and various ceric compounds.
Pigments – One of the notable features of silicone rubber is its color, which is
normally black, red, or gray. The high transparency of silicone rubber makes it easy
to color it to meet design specifications.
Vulcanization
Silicone rubber is shaped, formed, and configured using various methods depending
on the type of product or part that is being manufactured. Once shaped, the rubber
product undergoes vulcanization, which involves a curing agent that heats the
product to cross link the polymer chains. High temperature vulcanization (HTV) is
completed at 150°C up to 200°C (302°F up to 392°F) while room temperature
vulcanization (RTV) is completed at room temperature
HTV vulcanization is completed in a heat press for several minutes and is used to
produce high strength silicone rubbers for industrial use. RTV curing happens rather
slowly using a platinum catalyst, about 24 hours, and is used to produce soft, pliable
silicone rubber products that are very soft or medium soft.
Chapter Four: Silicone Rubber Molds
A special use for silicone rubber is the formation of silicone molds used for mold
making using various materials including resins, gypsum, wax, and other materials.
Silicone molds make it easy to create custom products and designs using silicone
molds that are durable, long lasting, and have exceptional repeatability. The
inorganic nature of silicone rubber enables it to resist the effects of temperature
changes, exposure to chemicals, and natural contaminants such as bacteria and
fungus.
A common use for silicone molding is the creation of prototypes in order to examine
a product design. Since the creation of metal molds is time consuming, labor
intensive, and costly, silicone molds provide a cost effective alternative. Aside from
their use in prototyping, they assist in the creation of beta units for market testing
and consumer input. Although 3D printing is ideal for quickly creating one off
samples, silicone molds are capable of short production runs for testing.
Step One - The master, which is the part design, can be created using 3D printing
and made of a plastic resin. Its surface should be free of detail marks and washed to
remove any tackiness.
Step Two - The master must have a flat back with a small draft angle, which is a
slight taper along the edge of the master. Limited tapering makes it possible to easily
separate the master from the mold. The mold housing should be made of non-
porous material with a flat bottom.
Step Three - Mold release is applied to the mold housing and master. Once
applied, it takes ten minutes for it to dry.
Step Four - The silicone rubber solution should be carefully mixed and be vibrated
to remove any air bubbles. The mixture is then poured into the mold housing starting
with the lowest part of the housing and gradually moving upward.
Step Five - The curing process takes one hour to one week depending on the type
of silicone rubber. Once the mold is completely cured, silicone is removed from the
containment box, and the master is removed from the silicone mold. The completed
mold can be used multiple times by spraying the silicone mold with the release
solution.
Two Part Silicone Mold
The beginning steps for the creation of a two part silicone mold are the same as
those for a one part silicone mold, which is the creation and selection of the master.
Step One - In the first step, the master is embedded in clay, which should be
sulfur free and oil based. This part of the process defines the parting line. The
master is positioned in a mold box where a pour hole and air hole are added.
Step Two - For proper alignment of the two halves of the mold, keys that have a
tongue and groove appearance are evenly placed in the clay around the mold. Mold
keys are holes in the clay that will be filled with silicone rubber and serve as
guidance during the casting process.
Step Three - A specific amount of silicone rubber is mixed to completely cover the
first half of the mold. This aspect of the process is carefully calculated for
determining the amount for the second half of the mold. The mixture is poured over
half of the master and is allowed to cure.
Step Four - The sides of the mold box are removed to expose the clay, master,
and cured silicone. The master is left in the silicone, and the clay is removed along
with the silicone in the mold keys.
Step Five - The mold box is constructed around the master and silicone. A release
agent is applied to the master, mold keys, and silicone prior to pouring the silicone
rubber. As with the original pouring, the silicone rubber is carefully and precisely
measured such that it easily flows over the master, mold keys, and silicone.
Step Six - The finished two part silicone rubber mold is removed from the mold
box and separated to remove the master. The halves of the mold form the cavity for
shaping a part, component, or piece of art.
The use of silicone rubber is an ideal solution for mold making due to the resilience
and strength of silicone rubber. Rubber molds made of silicone can be used multiple
times to produce parts, components, and decorative items. The rubber mold making
process is quick, easy, and can be completed quickly to fit customer requirements,
which is essential in modern industry.
With two part silicone rubber molds, the tight seal between the halves limits the
creation of a parting line in the casting process. One part silicone molds, due to their
structure, do not have the potential for any form of parting line. In both cases, the
created molds have all the properties required for the creation of high quality
castings.
Extrusion
The extrusion of silicone rubber parts includes heating and compressing the raw
silicone material through a die that has the cross-sectional shape of the final product.
The raw silicone rubber is loaded into a hopper that is connected to the barrel of the
extruder. The barrel contains one or more screws that move the raw material along
the barrel to the die. During the movement toward the die, the raw material is heated,
melts, and is compressed. As the material is forced through the die, it takes the
desired shape after which it is cooled, cured, and cut to the desired lengths.
Extrusion takes many forms including film and sheet extrusion, each of which is used
to achieve different benefits. The extrusion process is low cost, allows for high
volume production runs, and is ideal for producing tubing, gaskets, seals, and wire
insulation.
Calendaring
Calendaring is used to produce thin sheets of silicone rubber through the use of
rollers or bowls with each roller rotating in the opposite direction of its opposing roll
at an even and controlled speed. One roll in each pair has a nip adjustment to
control the thickness of the silicone rubber material. A silicone rubber calendar can
contain two or more rolls. The silicone rubber material is heated and fed into the rolls
in strip or pig form on one side of the nip and is squeezed to form sheets of silicone
rubber.
Injection Molding
Injection molding is the most common process for forming silicone rubber parts that
vary in size, complexity, and final application. The process involves the use of a
screw type plunger that is similar to that of an extruder. As with an extruder, the raw
silicone material is loaded into a hopper connected to the barrel and screw. The
material is heated as it moves along the barrel toward a tightly sealed die that has
the shape of the final part. The pressure created by the movement of the screw
forces the raw material into every portion of the die.
The shot, the amount of material injected into the die, increases in density as the
pressure of the injection machine rises and fills the die cavity. The key to the
increasing pressure is the slow movement of the screw that helps to sustain and
maintain continuous, even pressure. The silicone rubber cools during injection, which
accelerates the solidification process and makes up 80% of the molding cycle.
Liquid Injection Molding
Liquid injection molding involves the use of liquid silicone rubber that is injected into
the mold cavity by a nozzle. The difference between injection molding and liquid
injection molding is the mechanical mixing of the silicone rubber material prior to it
being injected into the mold, which is completed by two plungers. One of the
plungers contains the base material reinforced with additives and fibers. The second
plunger has the catalyst compound that activates the mixing.
The advantages of liquid injection molding include shorter curing time, the ability to
produce intricate and complex designs with extremely close tolerances, high volume
production, automated process design, and the use of thermal imaging to prevent
molding errors.
Compression Molding
Compression molding includes the use of heated molds that contain the precise
amount of silicone rubber, referred to as the charge, to form the final product. A
heated plunger that has the upper half of the mold attached to it applies 15,000 psi to
20,000 psi of pressure to drive the silicone material to every corner of the upper and
lower halves of the mold cavity. The pressure is maintained until the silicone rubber
component completely cures.
The major benefit of compression molding is its cost, which makes it ideal for
producing low volume production runs. The process is capable of producing small,
minute parts up to large and complex ones with a short set up time.
Transfer Molding
Transfer molding involves the use of a mold, plunger injection machine, and silicone
rubber material. The process begins by placing the raw silicone rubber material or
charge into the transfer pot that is below the plunger and above the mold. Under
intense hydraulic pressure, the plunger forces the silicone rubber through a small
hole or sprue at the top of the mold into the mold cavity where it is tightly held and
allowed to cure.
The process of transfer molding is very precise and produces components with less
flash and waste. Transfer molding is able to produce parts with small tolerances and
complex shapes with tighter control of dimensional tolerances. Although it has
similarities to compression molding in that it uses compression to mold parts, the
mold cavity is not divided into halves, and the raw silicone rubber material charge is
located in the pot and not the lower half of the mold.
Electrical Insulation
Silicone rubber is quite commonly used as a wire and cable insulator, connector
seal, and switch boot. Its high temperature resistance and ability to withstand
extreme weather conditions makes it an ideal insulation material. Silicone rubber
insulation remains flexible, waterproof, and resistant to arcing and cracking even
after several years of use. The strength and durability of silicone rubber insulation is
capable of protecting the most sensitive components.
Automotive Parts
Hoses, gaskets, seals, and other vehicle components are essential for the safe and
continued performance of a vehicle. They have to be able to endure the harsh
treatment they have to withstand during the operation of a vehicle’s engine. It is for
these reasons that silicone rubber is the material that is used to produce the most
critical components of an engine. It has the strength, toughness, and impact
resistance required and is long lasting.
Aerospace
Parts and components for use in aerospace applications have to be exceptionally
durable and capable of withstanding constant abuse. Critical factors in aerospace
manufacturing are the ability to endure radical changes in temperature, radiation,
and routine exposure to various chemicals. The high performance of silicone rubber
makes it perfectly suited for the needs of aerospace conditions.
Medical Equipment
The food and drug administration has established stringent guidelines in regard to
the types of materials that can be used to produce medical equipment due to the
sensitive nature of patient care. Included in the regulations for materials are being
chemically inert, biocompatible, and being able to be sterilized. Unlike materials for
airplanes and vehicles, medical devices have to perform in sanitary conditions and
be in constant use, such as catheters and tubing.
Silicone rubber is an ideal material for medical applications due to its flexibility,
transparency, and lubricity. Aside from being used for tubing and protection of
wounds, it is used for orthopedic padding and other devices that come in contact
with the body. Silicone rubber parts are implanted in the body as body part
replacements due to their durability and biocompatibility.
Cookware
Silicone rubber is used in the production of food and cookware due to it being non-
toxic and food safe. As a cooking material, it satisfies the standards required by the
food and drug administration (FDA) and can be made in aesthetically pleasing
colors. Silicone rubber is widely used in bakeware since it does not leach and
damage the taste or odor of the food being prepared.
Utensils made of silicone rubber are non-sticking and easy to clean. When used in
the preparation of food, they require less oil, which makes the food healthier and
more nutritious. The many shapes of silicone cookware, whether it is baking pans or
mixing bowls, are dishwasher safe or can be washed by hand without being
scratched or damaged.
Along with its resistance to high temperatures, silicone rubber can endure cold
temperatures without becoming brittle or cracking. It retains its elasticity at -70deg;C
(-94deg;F), which are temperatures that cause organic rubbers to become brittle.
Silicone rubber retains its properties and structure over a wide range of temperatures
in any conditions.
Hygienic
Silicone rubber is non-toxic and easy to sterilize. It is non-porous, which makes it
impossible for bacteria or viruses to build up and grow. This aspect of silicone rubber
makes it ideal for the manufacture of medical equipment, food processing devices,
and cookware. When silicone items are cleaned, solvents easily remove any surface
contamination. Additionally, the sanitary property of silicone rubber makes it the ideal
material for use in cleanrooms and environments that require a high standard of
cleanliness.
Chemical Resistance
Silicone rubber does not experience any change in its properties when exposed to
oils, solvents, and assorted other chemicals. When it is submerged in water, it
retains its mechanical strength and electrical properties. It is used in motors due to
its ability to resist the effects of oil at high temperatures and is unaffected by polar
organic compounds and dilute acids.
Fire Resistance
UL 94 HB is a test for the horizontal burning rate of a substance or material that has
been released by Underwriters Laboratories (UL). It is used to classify materials as
to how they burn in different orientations and thicknesses. The six classifications of
materials range from 5VA to HB with HB being the slowest burning rate. Silicone
rubber has a UL 94 HB rating. When it burns, it produces limited black smoke and no
noxious gases.
Conclusion
Silicone rubber molding is a method for shaping, forming, and fabricating silicone
rubber parts and products using a heated metal mold.
The various forms of silicone rubber vary in their hardness and pliability, which
makes the material an ideal choice for applications that require a durable and flexible
material that is resistant to high temperatures and wear.
Silicone, known as polysiloxane, is a polymer that has a rubber-like consistency with
molecules having chains of oxygen and silicon atoms. It is different from other forms
of polymers in that it does not have carbon as its backbone.
Silicone rubber is an essential part of a wide range of products and is manufactured
using a variety of methods, each of which is capable of producing parts that meet the
expectations and requirements of an application. The choice of fabrication method
varies between molding processes, extrusion, and calendaring with each method
able to produce parts with the correct hardness, heat resistance, and electrical
conductive.
Along with its many positive properties, silicone rubber is a long-lasting, durable
material that seldom needs to be replaced. It is used for kitchen utensils and toys as
well as gaskets, seals, and automotive parts.