NEET NEET

80.4% respectively. What is the average atomic

Yakeen NEET 2.0 2025 (Alpha)
(C) 25 (D) 20
mass of boron?
10 11
Q12 B has two isotopes B(19%) and B(81%).
(A) 10.8 (B) 10.6
Chemistry The atomic mass of B is
(C) 9.6 (D) None of these
DPP: 1 (A) 10.81 (B) 11.5
Some Basic Concept of Chemistry (C) 11 (D) 10.5 Q19 The nucleus of the element having atomic
number 25 and atomic weight 55 will contain
50
Q13 If an element Z exist in two isotopic form Z
Q1 What is matter? Q6 The state of matter can be changed by varying (A) 25 protons and 30 neutrons
52
and Z . The average atomic mass of Z is 51.7.
(A) Anything which has mass but does not (A) pressure (B) volume (B) 25 neutrons and 30 protons
Calculate the abundance of each isotopic
occupies space (C) mass (D) temperature (C) 55 protons
forms
(B) Anything which has mass and occupies (D) 55 neutrons
Q7 An element, X has the following (A) Z 50 (15%), Z 52 (85%)
space
isotopic composition, (B) Z 50 (85%), Z 52 (15%) Q20 He has two naturally occurring isotopes He − 3
(C) Anything which neither has mass nor
200
X : 90% (C) Z 50 (5%), Z 52 (95%) and He -4 . The average atomic mass of helium
occupies space
199
X : 8% (D) Z 50 (95%), Z 52 (5%) is 3.98 amu which isotope is more abundant in
(D) Anything which does not have mass but it
202
X : 2% nature
occupies space Q14 The ratio between the neutrons in C and Si
the weighted average atomic mass of the (A) He − 4
with respect to atomic masses 12 and 28 is
Q2 Which of the following statement is correct? naturally occuring element ' X ' is closest to (B) He − 3
(A) 2 : 3 (B) 3 : 2
(A) Liquids have definite volume but not the (A) 201 amu (B) 202 amu (C) both are equally abundant
(C) 3 : 7 (D) 7 : 3
definite shape (C) 199 amu (D) 200 amu (D) none of these
(B) Gases have neither definite volume nor Q15 Atomic mass of boron is 10.81 . It has two
definite shape Q8 An atoms has 26 electrons and its atomic
isotopes with 80% and 20% abundance
(C) Both A and B weight is 56. The number of neutrons in the
respectively. The atomic mass of the isotope
(D) None of the above nucleus of the atom will be
having 80% abundance is 11.01. The atomic
(A) 26 (B) 30
mass of the other isotope is
Q3 Which of the following conditions is most (C) 36 (D) 56
(A) 10.80 (B) 11.01
favorable for converting a gas into liquid?
Q9 Which of the following atom has more electrons (C) 10.01 (D) 21.82
(A) High pressure, low temperature
than neutrons
(B) Low pressure, low temperature Q16 Naturally occuring chlorine is 75% Cl35 which
(C) Low pressure, high temperature (A) C 37
− has an atomic mass of 35 amu and 25% Cl
(D) High pressure, high temperature (B) F
2− which has a mass of 37 amu. Calculate the
(C) O
3+ average atomic mass of chlorine –
Q4 In gaseous state, molecules can move (D) Al
(A) 35.5amu
(A) Only in one direction
Q10 Which property of an element is always a (B) 36.5amu
(B) Only in fixed path
whole number (C) 71amu
(C) Randomly in all directions
(A) Atomic weight (D) 72amu
(D) Upward and downward only
(B) Equivalent weight
Q17 Carbon occur in nature as a mixture of C 12 and
Q5 The gases are highly compressible because (C) Atomic number
C 13. Average atomic mass of carbon is 12.011
(A) the molecules move randomly (D) Atomic volume
what is the % aboundance of C12 in nature?
(B) the molecular force of attraction is very
Q11 The atomic weight of chlorine is 35.5. It has two (A) 99.8% (B) 98.9%
weak
isotopes of atomic weight 35 and 37. What is (C) 97.6% (D) 98.5%
(C) The separation between molecules is very
large the percentage of the heavier isotope in the
Q18 Boron has two isotopes boron-10 and boron-11
(D) The separating force is strong sample?
whose percentage abundances are 19.6% and
(A) 5 (B) 10

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 NEET NEET

Answer Key Yakeen NEET 2.0 (Alpha)

Q1 (B) Q11 (C) Physical Chemistry
Q2 (C) Q12 (A) DPP: 2
Some Basic Concept of Chemistry
Q3 (A) Q13 (A)

Q4 (C) Q14 (C) Q1 The volume occupied by 4.4 g of CO2 at STP Mass of one atom of an element is 8 × 10−24 g
Q5 (C) Q15 (C) is (Gram atomic mass of O = 16 g and C = 12 g) This is equal to
(A) 22.4 L (A) 4.8u
Q6 (D) Q16 (A)
(B) 2.24 L (B) 48u
Q7 (D) Q17 (B) (C) 0.224 L (C) 0.048u
(D) 0.1 L (D) 0.48u
Q8 (B) Q18 (A)

Q9 (C) Q19 (A) Q2 16 g of oxygen has same number of molecules Q7 1u is equal to

as in ( Gram atomic mass of O = 16 g, N = 14 g, C (A) 1.66 × 10−24 g
Q10 (C) Q20 (A)
= 12 g, H = 1 g) (B) 1.66 × 10−27 kg
(A) 16 g of CO (C) N1 g
A
(B) 28 g of N2 (D) All of these
Android App | iOS App | PW Website (C) 24 g of C2
(D) 1.0 g of H2 Q8 The weight of a molecule of the compound
C6 H12 O6 is about:
Q3 Calculate the mass of 6.022 × 1023 molecules (A) 180 g
of Calcium Carbonate. (Gram atomic mass of (B) 3 × 10−22 g
Ca = 40 g, O = 16 g and C = 12 g) (C) 22 × 10−22 g
(A) 50 g (D) 132 g
(B) 100 g
(C) 200 g Q9 Which state has maximum intermolecular force?

(D) None of these (A) Solid (B) Liquid

(C) Gas (D) Plasma
Q4 The number of molecules in 89.6 liters of a gas
at NTP are Q10 44.8 L of SO2 ( g) weigh how much gram at

(A) 6.02 × 10 23 STP ? (Gram atomic mass of S = 32 g and O =

(B) 2 × 6.02 × 10 23 16 g)
(C) 3 × 6.02 × 1023 (A) 128 g

(D) 4 × 6.02 × 1023 (B) 95 g

(C) 24 g
Q5 Aspirin has the formula C9 H8 O4 . How many (D) 50 g
atoms of oxygen are there in a tablet weighing
360mg ? Q11 11.2 L of O3 ( g) contains how many numbers

(A) 1.204 × 1023 of molecules?

(B) 1.08 × 1022 (A) NA molecules

(C) 1.204 × 1024 (B) NA /2 molecules

(D) 4.81 × 1021 (C) 2 NA molecules
(D) 3 NA molecules
Q6

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Q12 Number of atoms present in 49 g of H2 SO4 ? Q18 The number of atoms present in 16 g of oxygen
(Gram atomic mass of S = 32 g, O = 16 g and H = gas is: (Gram atomic mass of O = 16 g)
Answer Key
1 g) (A) 6. 02 × 1011.5
Q1 (B) Q12 (C)
(A) NA /7 (B) 3. 01 × 1023
(B) 7NA (C) 3. 01 × 10 11.5 Q2 (D) Q13 (A)
23
(C) 7NA /2 (D) 6. 02 × 10 Q3 (B) Q14 (C)
(D) 14NA
Q19 Number of atoms in 560 g of Fe ( atomic mass Q4 (D) Q15 (B)
Q13 Calculate number of oxygen atoms in 126 g of 56 g mol−1 ) is Q5 (D) Q16 (B)
HNO3 ? (A) Twice that of 70 g N2
Q6 (A) Q17 (B)
(A) 6 NA (B) Half that of 20 gH2
(B) 12 NA (C) Both are correct Q7 (D) Q18 (D)
(C) 3 NA (D) None of these
Q8 (B) Q19 (C)
(D) 14 NA
Q20 How many H -atoms are present in 0.046 g of Q9 (A) Q20 (D)
Q14 Calculate total number of electrons in ethanol?
Q10 (A) Q21 (C)
88 g of CO2 ? (A) 6 × 1020
(Gram atomic mass of C = 12g, O = 16g and (B) 1.2 × 1021 Q11 (B)
atomic number of C=6 , O =8) (C) 3 × 1021
(A) NA (D) 3.6 × 1021
(B) 32 NA Android App | iOS App | PW Website
Q21 Number of atoms of oxygen present in 10.6 g of
(C) 44 NA
Na2 CO3 will be
(D) 22 NA
(A) 6.02 × 1023
Q15 Calculate total number of valence electrons in (B) 12.04 × 1022
2.8 g of N3− ion (C) 1.806 × 1023
(A) 2.6 NA (D) 31.80 × 1028
(B) 1.6 NA
(C) 7.8 NA
(D) 0.8 NA

Q16 Calculate weight occupied by 12.04 × 1024

molecules of N2 ( g) ? Gram molecular mass of
N2 = 28 g)
(A) 280 g
(B) 560 g
(C) 112 g
(D) 200 g

Q17 The mass of CO2 ( g) sample containing 16 g

of carbon atoms?
(A) 50 g
(B) 58.6 g
(C) 42 g
(D) 15 g

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 NEET NEET

(B) 70.0 g (C) 48 g

Yakeen NEET 2.0 (Alpha) (C) 20.0 g (D) 96 g
(D) 40.0 g
Physical Chemistry Q18 The weight of a molecule of the compound
DPP: 3 Q12 Find mass of 18.066 × 1023 molecules of NH3 C6 H12 O6 is
Some Basic Concept of Chemistry ? (If atomic mass of N and H are 14 and 1 ) (A) 1.09 × 10−21 g
(A) 51 g (B) 2.988 × 10−22 g
Q1 1 mole of atom X has mass, 0.444 times the Q6 The number of atoms in 4.25 g of NH3 (B) 34 g (C) 5.025 × 10−23 g
mass of 1 mole of atom Y. Atomic mass of X is is approximately (C) 17 g (D) 16.023 × 10−23 g
2.96 times the mass of one atom of C − 12. (A) 6 × 1023 (D) None of these
Q19 5.6 litre of oxygen gas at STP contains
What is the atomic weight of Y. (B) 2 × 1023
23 Q13 Find mass of CO2 which have same molecules (A) 6.02 × 1023 atoms
(A) 15.77amu (C) 1.5 × 10
as present in 68 g of NH3 ? (B) 3.01 × 1023 atoms
(B) 80amu (D) 1 × 1023
(Gram atomic mass of C = 12 g, O = 16 g, H = 1 (C) 1.505 × 1023 atoms
(C) 46.66amu
Q7 Which sample contains the largest number of gand N = 14 g) (D) 0.7525 × 1023 atoms
(D) 40amu
atoms? (A) 88 g
Q20 A person adds 1.71 gram of sugar (C12 H22 O11 )
Q2 Which has the highest mass? (A) 1mg of C4 H10 (B) 176 g
in order to sweeten his tea. The number of
(A) 1 g-atom of C (B) 1mg of N2 (C) 44 g
carbon atoms added are (mol. mass of sugar
(B) 1/2 mole of CH4 (C) 1mg of Na (D) 132 g
= 342 )
(C) 10 mL of water (D) 1 mL of water
Q14 Find volume of CO2 ( g) at STP if it weighs 88 g (A) 3.6 × 1022
(D) 3.011 × 1023 atoms of oxygen
Q8 1amu is equal to ? (Atomic mass of C and O are 12 g and 32 g ) (B) 7.2 × 1021
Q3 The number of water molecules in 1 L of water (A) 1.00758 g (A) 44.8 L (C) 0.05
is (B) 0.000549 g (B) 67.2 L (D) 6.6 × 1022
(A) 18 (C) 1.66 × 10−24 g (C) 22.4 L
Q21 Which one of the following pairs of gases
(B) 18 × 1000 (D) 6.02 × 10−23 g (D) 89.6 L
contains the same of molecules? (Gram atomic
(C) NA
Q9 The mass of an atom of carbon -12 is : Q15 Find total number of neutrons in 56 g of CO ? If mass of N = 14 g, C = 12 g, O = 16 g, H = 1 g)
(D) 55.55 NA
(A) 1 g 12 C
6 and 16
8 O if Avogadro's No. = NA (A) 16 g of O2 and 14 g of N2
Q4 The least number of molecules are contained in: (B) 1.99 × 10−23 g (A) 28 NA (B) 8g of O2 and 22 g of C O2
(A) 2 g hydrogen (C) 1/12 g (B) 22 NA (C) 28 g of N2 and 22 g of CO2
(B) 8 g oxygen (D) 1.99 × 1023 g (C) 11 NA (D) 32 g of O2 and 32 g of N2
(C) 4 g nitrogen (D) None of these
Q10 An element, X has the following Q22 The number of water molecules present in a
(D) 16 g CO2
isotopic composition, Q16 Which of the following contains the greatest drop of water (volume 0.0018 ml ) at room
200
Q5 Arrange the following in the order of increasing X : 90% number of atoms? temperature is
mass (atomic mass; O = 16, Cu = 63, N = 14 199
X : 8% (A) 1.0 g of butane (C4 H10 ) (A) 6.023 × 1019
) 202
X : 2% (B) 1.0 g of nitrogen (N2 ) (B) 1.084 × 1018
(I) One atom of oxygen the weighted average atomic mass of the (C) 1.0 g of silver (Ag) (C) 4.84 × 1017
(II) One atom of nitrogen naturally occuring element ' X ' is closest to (D) 1.0 g of water (H2 O) (D) 6.023 × 1023
(III) 1 × 10−10 mole of oxygen (A) 201 amu (B) 202 amu
Q17 A sample of aluminium has a mass of 54.0 g . Q23 1amu is equal to
(IV) 1 × 10−10 mole of copper (C) 199 amu (D) 200 amu 1
What is the mass of the same number of (A) 12 of C − 12
(A) II < I < III < IV
1
Q11 Calculate the mass of 2.5 gram atoms of magnesium atoms? (At. wt. Al = 27, Mg = 24 ) (B) 14 of O − 16
(B) I < II < III < IV
oxygen. (A) 12 g (C) 1 g of H2
(C) III < II < IV < I
(A) 50.0 g (B) 24 g (D) 1.66 × 10−23 kg
(D) IV < II < III < I

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 NEET NEET

Answer Key Yakeen NEET 2.0 (Alpha)

Q1 (B) Q13 (B) Physical Chemistry
Q2 (A) Q14 (A) DPP: 4
Some Basic Concept of Chemistry
Q3 (D) Q15 (A)

Q4 (C) Q16 (A) Q1 The law of conservation of mass is valid for all Q6 The percentage of hydrogen in water and
Q5 (A) Q17 (C) the following, except hydrogen peroxide is 11.1 and 5.9 respectively.
(A) All chemical reactions These figures illustrate
Q6 (A) Q18 (B)
(B) Nuclear reactions (A) Law of multiple proportions
Q7 (D) Q19 (B) (C) Endothermic reactions (B) Law of conservation of mass
(D) Exothermic reactions (C) Law of constant proportions
Q8 (C) Q20 (A)
(D) Law of combining volumes
Q9 (B) Q21 (A) Q2 After a chemical reaction, the total mass of
reactants and products Q7 The law of definite proportions is not applicable
Q10 (D) Q22 (A)
(A) Is always increased to nitrogen oxide because
Q11 (D) Q23 (A) (B) Is always decreased (A) Nitrogen atomic weight is not constant
Q12 (A) (C) Is not changed (B) Nitrogen molecular weight is variable
(D) Is always less or more (C) Nitrogen equivalent weight is variable
(D) Oxygen atomic weight is variable
Q3 A sample of pure carbon dioxide, irrespective of
its source contains 27.27% carbon and Q8 The percentage of copper and oxygen in
Android App | iOS App | PW Website 72.73% oxygen. The data support samples of CuO obtained by different methods
(A) Law of constant composition were found to be the same. This illustrates the
(B) Law of conservation of mass law of
(C) Law of reciprocal proportions (A) Constant proportions
(D) Law of multiple proportions (B) Conservation of mass
(C) Multiple proportions
Q4 ng of substance X reacts with mg of substance
(D) Reciprocal proportions
Y to form pg of substance R and qg of
substance S . This reaction can be represented Q9 How A sample of calcium carbonate (CaCO 3)
as X + Y = R + S. The relation which can be has the following percentage composition:
established in the amounts of the reactants Ca = 40%; C = 12%; O = 48%
and the products will be If the law of constant proportions is true, then
(A) n − m = p − q the weight of calcium in 4g of a sample of
(B) n + m = p + q calcium carbonate obtained from another
(C) n = m source will be (Gram atomic mass of Ca = 40 g,
(D) p = q O = 16 g and C = 12 g)
(A) 0.016 g
Q5 Chemical equation is balanced according to
(B) 0.16 g
the law of
(C) 1.6 g
(A) Multiple proportion
(D) 16 g
(B) Reciprocal proportion
(C) Conservation of mass Q10 Cu forms two oxides cuprous and cupric
(D) Definite proportions oxides, which law can be proved by the weights

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 NEET NEET

of Cu and O ? Q16 Which of the following pairs of substances contain equal number of molecules
(A) Constant composition illustrate the law of multiple proportions (C) Equal volumes of all gases under same
(B) Multiple proportions (A) CO and CO2 conditions of temperature and pressure
(C) Reciprocal proportions (B) H2 O and D2 O contain equal number of atoms
(D) Definite proportions (C) NaCl and NaBr (D) The rates of diffusion of gases are inversely
(D) MgO and Mg(OH)2 proportional to the square root of their
Q11 Which of the following pairs of compound
densities
illustrate law of multiple proportions? Q17 1.0 g of an oxide of A contained 0.5 g of
(A) KOH, CsOH A. 4.0 g of another oxide of A contained 1.6 g Q22 Which one of the following pairs of gases
(B) H2 O, D2 O of A . The data indicate the law of contains the same of molecules? (Gram atomic
(C) Ethane, benzene (A) Reciprocal proportions mass of N = 14 g, C = 12 g, O = 16 g, H = 1 g)
(D) KCI, KBr (B) Constant proportions (A) 16 g of O2 and 14 g of N2
(C) Conservation of energy (B) 8g of O2 and 22 g of C O2
Q12 Element X forms five stable oxides with oxygen
(D) Multiple proportions (C) 28 g of N2 and 22 g of CO2
of formula X2 O, XO, X2 O3 , X2 O4 , X2 O5 . The
(D) 32 g of O2 and 32 g of N2
formation of these oxides explains Q18 2 g of hydrogen combine with 16 g of oxygen to
(A) Law of definite proportions form water and with 6 g of carbon to form Q23 Volume occupied by one molecule of water
(B) Law of partial pressures methane. In carbon dioxide 12 g of carbon are (density = 1 g cm−3 ) is
(C) Law of multiple proportions combined with 32 g of oxygen. These figures (A) 9.0 × 10−23 cm3
(D) Law of reciprocal proportions illustrate the law of (B) 6.023 × 10−23 cm3
(A) Multiple proportions (C) 3.0 × 10−23 cm3
Q13 Two samples of lead oxide were separately
(B) Constant proportions (D) 5.5 × 10−23 cm3
reduced to metallic lead by heating in a current
(C) Reciprocal proportions
of hydrogen. The weight of lead from one oxide Q24 How many years it would take to spend one
(D) Conservation of mass
was half the weight of lead obtained from the Avogadro's number of rupees at a rate of 10
other oxide. The data illustrates Q19 Equal volume of different gases at any definite lakh of rupees in one second?
(A) Law of reciprocal proportions temperature and pressure have (A) 1.90 × 109
(B) Law of constant proportions (A) Equal atoms (B) 1.90 × 1010
(C) Law of multiple proportions (B) Equal masses (C) 1.90 × 1011
(D) Law of equivalent proportions (C) Equal densities (D) 1.90 × 1012
(D) Equal molecules
Q14 Different proportions of oxygen in the various
oxides of nitrogen prove the Q20 Gay Lussac's law is not valid in the
(A) Equivalent proportion chemical reaction:
(B) Multiple proportion (A) H2 ( g) + Cl2 ( g) → 2HCl(g)
(C) Constant proportion (B) 3H2 ( g) + N2 ( g) → 2NH3 ( g)
(D) Conservation of matter (C) 2SO2 ( g) + O2 ( g) → 2SO3 ( g)
Δ
(D) CaCO ( s) →
Q15 Among the following pairs of compounds, the 3 CaO(s) + CO2 ( g)
one that illustrates the law of multiple Q21 Which of the following represents Avogadro's
proportions is hypothesis?
(A) NH3 and NCl3 (A) Gases react together in volumes which bear
(B) H2 S and SO2 a simple ratio to one another
(C) CuO and Cu2 O (B) Equal volumes of all gases under same
(D) CS2 and FeSO4 conditions of temperature and pressure

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 NEET NEET

Answer Key Yakeen NEET 2.0 (Alpha)

Q1 (B) Q13 (C) Physical Chemistry
Q2 (C) Q14 (B) DPP: 5
Some Basic Concept of Chemistry
Q3 (A) Q15 (C)

Q4 (B) Q16 (A) Q1 How many moles of electron weigh one Q7 The empirical formula of a compound is CH2 O.

Q5 (C) Q17 (D) kilogram? 0.0835 moles of the compound contains 1.0 g
(A) 6.023 × 1023 of hydrogen. The molecular formula of the
Q6 (A) Q18 (C) 1
(B) 9.108 × 1031 compound is
6.023
Q7 (C) Q19 (D) (C) 9.108 × 1054 (A) C6 H12 O6
1
Q8 (A) Q20 (D) (D) 9.108×6.023 × 108 (B) C5 H10 O5
(C) C4 H8 O4
Q9 (C) Q21 (B) Q2 The number of electrons in 3. 1mg of N O3 is (D) C3 H6 O3
(A) 32
Q10 (B) Q22 (A)
(B) 1.6 × 10−3 Q8 A compound (80 g) on analysis gave C =
Q11 (C) Q23 (C) (C) 9.6 × 1020 24 g, H = 4 g, O = 32 g. Its empirical formula
Q12 (C) Q24 (B) (D) 9.6 × 1023 is (Gram atomic mass of C = 12 g, O = 16 g, H = 1
g)
Q3 The total number of protons in 10 g of calcium (A) C2 H2 O2
carbonate is (N0 = 6.023 × 1023 ) (B) C2 H2 O
Android App | iOS App | PW Website (A) 1.5057 × 1024 (C) CH2 O2
(B) 2.0478 × 1024 (D) CH2 O
(C) 3.0115 × 1024
(D) 4.0956 × 1024 Q9 2.2 g of a compound of phosphorous and
Sulphur has 1.24 g of ' P ' in it. Its empirical
Q4 The number of moles of sodium oxide in 620 g formula is
of its is (A) P2 S3
(A) 1 mol (B) P3 S2
(B) 10 moles (C) P3 S4
(C) 18 moles (D) P4 S3
(D) 100 moles
Q10 An organic compound contains carbon,
Q5 1021 molecules are removed from 200mg of hydrogen and oxygen. Its elemental analysis
CO2 . The mole of CO2 left are gave C, 38.71% and H, 9.67% . The empirical
(A) 2.88 × 10−2 formula of the compound would be
(B) 28.2 × 10−3 (A) CH4 O
(C) 2.88 × 10−3 (B) CH3 O
(D) 28.8 × 103 (C) CH2 O
(D) CHO
Q6 The percentage of nitrogen in urea is about
(A) 46 (B) 85 Q11 An organic compound containing C, H and N
(C) 18 (D) 28 gave the following analysis C=
40%, H = 13.33%, N = 46.67% . Its empirical

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 NEET NEET

formula would be (Gram atomic mass of N = 14

g, C = 12 g, H = 1 g)
Answer Key
(A) CH4 N
Q1 (D) Q9 (D)
(B) CH5 N
(C) C2 H7 N2 Q2 (C) Q10 (B)
(D) C2 H7 N Q3 (C) Q11 (A)

Q12 An oxide of metal M has 40% by mass Q4 (B) Q12 (C)

of oxygen. Metal M has atomic mass of 24 .The Q5 (C) Q13 (C)
empirical formula of the oxide.
Q6 (A) Q14 (B)
(A) M2 O
(B) M2 O3 Q7 (A) Q15 (A)
(C) MO
Q8 (D)
(D) M3 O4

Q13 The empirical formula and molecular mass of a

compound are CH2 O and 180 g respectively. Android App | iOS App | PW Website
What will be the molecular formula of the
compound?
(A) C9 H18 O9
(B) CH2 O
(C) C6 H12 O6
(D) C2 H4 O2

Q14 0.30 g of an organic compound containing

C, H and O on combustion yields 0.44 gCO2
and 0.18 gH2 O. If one mol of compound
weighs 60 g, then molecular formula of the
compound is
(A) C3 H8 O
(B) C2 H4 O2
(C) CH2 O
(D) C4 H6 O

Q15 What is the empirical formula of the compound

which has the following percentage
composition: Carbon 80% , Hydrogen 20%. If
the molecular mass is 30, then also calculate
the molecular formula.
(A) CH3 , C2 H6
(B) C2 H2 , CH3
(C) C2 H6 , CH3
(D) CO3 , CH3

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 NEET NEET

hydrochloric acid according to the balanced Q17 The mass of carbon anode consumed (giving
Yakeen NEET 2.0 (Alpha) equation below. only carbon-dioxide) in the production of
2Al + 6HCl → 2AlCl3 + 3H2 270Kg of aluminium metal from bauxite by the
Physical Chemistry (A) 1.5 g Hall process is
DPP: 6
(B) 2.0 g (A) 180 kg
Some Basic Concept of Chemistry
(C) 3.0 g (B) 270 kg
(D) 6.0 g (C) 240 kg
Q1 When 200 g of lime stone is strongly heated, it (C) 22.4 litre (D) 11.2 litre
(D) 90 kg
undergoes thermal decomposition to form Q11 What is the total mass of products formed
Q6 What is the weight of oxygen required for
112 g of lime an unknown mass of carbon when 16 grams of CH4 is burned with excess
the complete combustion of 2.8 kg of
dioxide gas as CaCO 3 → CaO + CO2 What oxygen?
200 g 112 g ethylene?
(A) 32 g
will be the mass of CO2 formed? (A) 2.8 kg
(B) 36 g
(A) 88 g (B) 6.4 kg
(C) 44 g
(B) 24 g (C) 9.6 kg
(D) 80 g
(C) 64 g (D) 96 kg
(D) 40 g Q12 The volume of oxygen required for
Q7 How many grams of H2 are required to
complete combustion of 20ml of ethene is
Q2 How many grams of calcium oxide is obtained consume 2 mol of CO ?
(A) 30ml
on heating 100 g of CaCO 3( s) ? (Gram atomic mass of H = 1 g, C = 12 gand O =
(B) 60ml
(A) 50 g 16 g)
(C) 40ml
(B) 40 g CO(g) + 2H2 ( g) → CH3 OH(g)
(D) 50ml
(C) 56 g (A) 2 g
(D) 44 g (B) 4 g Q13 Volume of CO2 obtained at STP by the
(C) 8g complete decomposition of 9.85 g . The volume
Q3 The volume CO2 gas evolved at STP on
(D) 16 g of BaCO3 is
heating 50 g CaCO 3 : (Gram atomic mass of
(A) 2.24 lit (B) 1.12 lit
Ca = 40 g, C = 12 g and O = 16 g) Q8 When a certain amount of octane,C8 H18 , is
(C) 0.84 lit (D) 0.56 lit
Δ
CaCO3(s) → CaO(s) + CO2 (g) burnt completely, 7. 04 gCO2 is formed. What
(A) 11.2 litre (B) 22.4 litre is the mass of H2 O formed simultaneously? Q14 The volume of gas at STP produced by 100 g of
(C) 5.6 litre (D) 2.42 litre (A) 1. 62 g (B) 6. 48 g CaC2 with water
(C) 3. 24 g (D) 2. 28 g (A) 70 litre (B) 35 litre
Q4 What is the mass of glucose required to (C) 17.5 litre (D) 22.4 litre
produce 44 g of CO2 on complete Q9 The amount of zinc required to produce
combustion? 224 mL of H2 at STP on treatment with dilute Q15 How many grams of SO3 are produced from
(A) 30 g H2 SO4 will be 1 mol of S8 ?
(B) 45 g (Gram atomic mass of H = 1 g, O = 16 g, S = 32 (A) 1280.0 (B) 640.0
(C) 60 g g,and Zn = 65 g) (C) 960.0 (D) 320.0
(D) 22 g Zn(s) + H2 SO4 (aq) → ZnSO4 (aq) + H2 ( g)
Q16 If 1/2 moles of oxygen combine with aluminium
(A) 65 g
Q5 The volume of O2 at STP required for the to form Al2 O3 then weight of Aluminium metal
(B) 0.065 g
complete combustion of 4 g CH4 is used in the reaction is (Al = 27)
(C) 0.65 g
(Gram atomic mass of H = 1 g, C = 12 g and O = (A) 27 g
(D) 6.5 g
16 g ) (B) 18 g
CH4 ( g) + 2O2 ( g) ⟶ CO2 ( g) + 2H2 O(g) Q10 Calculate the mass of hydrogen formed when (C) 54 g
(A) 5.6 litre (B) 2.88 litre 27 g of aluminum reacts with excess (D) 40.5 g

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 NEET NEET

Answer Key Yakeen NEET 2.0 2025 (Alpha)

Q1 (A) Q10 (C) Physical Chemistry
Q2 (C) Q11 (D) DPP: 7
Some Basic Concept of Chemistry
Q3 (A) Q12 (B)

Q4 (A) Q13 (B) Q1 10 g of MnO2 on reaction with HCl forms (C) 1.7 g
Q5 (D) Q14 (B) 2.24 L of Cl2 ( g) at NTP , the percentage (D) 17.0 g
impurity of MnO2 is
Q6 (C) Q15 (B) Q5 The minimum mass of water needed to slake
MnO2 + 4HCl → MnCl2 + Cl2 + 2H2 O
1 kg of quicklime, assuming no loss by
Q7 (C) Q16 (B) (A) 87% (B) 25%
evaporation, is
(C) 33.3% (D) 13%
Q8 (C) Q17 (D) (A) 243.2 g
Q9 (C) Q2 According to the following reaction the (B) 642.8 g
minimum quantity in gm of H2 S needed to (C) 160.7 g
2+
precipitate 63.5gm of Cu ions will be (D) 321.4 g
nearly?
Android App | iOS App | PW Website Q6 What volume at STP of CO is required to
(Gram atomic mass of H = 1 g, Cu = 63.5 g and S
reduce one mole of Fe2 O3 in the following
=32 g)
+2 + reaction
Cu + H2 S → CuS + 2H
Fe2 O3 + CO → Fe + CO2
(A) 63.5 g
(Gram atomic mass of C = 12 g, O = 16 g, and Fe
(B) 31.75gm
=56 g)
(C) 34gm
(A) 11200 cm3
(D) 20gm
(B) 22400 cm3
Q3 A quantity of 2.76 g of silver carbonate on (C) 67200 cm3
being strongly heated yields a residue weighing (D) 33600 cm3
(Ag = 108)
Δ Q7 A gas is found to contain 2.34 grams of
Ag2 CO3 (s) → 2 Ag (s) + CO2 (g) nitrogen and 5.34 grams of oxygen. Simplest
+ 12 O2 (g) formula of the compound is:
(A) N2 O
(A) 2.16 g (B) NO
(B) 2.48 g (C) N2 O3
(C) 2.32 g (D) NO2
(D) 2.64 g
Q8 The weight of lime obtained by heating 200 kg
Q4 The minimum mass of sulphuric acid needed of 95% pure lime stone is
for dissolving 3 g of magnesium carbonate is (A) 98.4 kg
(Gramatomic mass of H = 1 g, C = 12 g, O = 16 g, (B) 106.4 kg
Mg =24 g and S = 32 g) (C) 112.8 kg
MgCO3 ( s) + H2 SO4 (aq) → MgSO4 (aq) (D) 122.6 kg
+ H2 O(l) + CO2 ( g)
Q9 The number of water molecules present in a
(A) 3.5 g
drop of water weighing 0.018 g is
(B) 7.0 g

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 NEET NEET
26
(A) 6.022 × 10 (C) 8.8 g of CO2
(B) 6.022 × 1019 (D) 192 g of SO4 2−
Answer Key
(C) 6.022 × 1023
Q16 Calculate the minimum number of moles in Q1 (D) Q10 (A)
(D) 6.022 × 1020
which option? Q2 (C) Q11 (A)
Q10 Percentage of Se in peroxidase anhydrous (A) 18.06 × 1023 atom of C
Q3 (A) Q12 (A)
enzyme is 0.5% by weight (At. Wt. = 78.4 ) (B) 12.04 × 1023 ions of SO4 2−
then minimum molecular weight of peroxidase (C) 24.08 × 1023 ions of SO4 2− Q4 (A) Q13 (C)
anhydrous enzyme is (D) 3.01 × 1023 molecules of O3 Q5 (D) Q14 (C)
(A) 1.568 × 104
Q17 Calculate total number of electrons and Q6 (C) Q15 (D)
(B) 1.568 × 103
protons in 32 g of SO2
(C) 15.68 Q7 (D) Q16 (D)
(A) 32 NA (B) 64 NA
(D) 2.136 × 104
(C) 16 NA (D) 8 NA Q8 (B) Q17 (A)
Q11 If mass % of oxygen in monovalent metal 'M' Q9 (D)
carbonate (M2 CO3 ) is 48% . Find atomic mass
of metal?
(A) 20 (B) 40
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(C) 30 (D) 10

Q12 Myoglobin stores oxygen for metabolic process

in muscle. Chemical analysis shows that it
contains 0.32%Fe by mass. If there is one Fe
atom per molecule of myoglobin, what is the
molar mass of myoglobin? [At. Mass of
Fe = 56u ]
(A) 1.75 × 104 g/mol
(B) 3.5 × 105 g/mol
(C) 1 × 104 g/mol
(D) 2.5 × 105 g/mol

Q13 An atom of an element weigh 6.4 × 10−23 g.

Number of gram atoms present in 30Kg of it?
(A) 650 (B) 700
(C) 778 (D) 540

Q14 A sample of ammonium phosphate

(NH4 )3 PO4 contains 3.18 moles of hydrogen
atoms. The number of moles of oxygen atoms in
the sample is
(A) 0.265 (B) 0.795
(C) 1.06 (D) 4.00

Q15 Maximum number of moles are present in

(A) 49 g of H2 SO4
(B) 63 g of HNO3

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 NEET NEET

Yakeen NEET 2.0 2025 (Alpha)

If 8 g of H2 is mixed with 16 gO2 ? Q18 Equal volume of N2 and H2 react to form
(A) 3 g ammonia under suitable condition then the
(B) 6g limiting reagent is
Physical Chemistry (C) 1 g (A) H2
DPP: 8
(D) 4 g (B) NH3
Some Basic Concept of Chemistry
(C) N2
Q12 Calculate the weight of FeO produced from
(D) No one reactant is limiting reagent
Q1 A measured temperature on Fahrenheit scale is (D) 58 g 6.7 g VO and 4.8 g Fe2 O3 .
∘
300 . What will this reading be on Celsius VO + Fe2 O3 → FeO + V2 O5 Q19 For the reaction:
Q7 1.0 g magnesium is burnt with 0.56 g of O2 in a
scale? (At. wt. of V = 51, At. wt. of Fe = 56 ) 7 A + 13 B + 15C → 17P
closed vessel. Which reactant is left in excess
(A) 40∘ C (A) 4.32 (B) 7.755 If 15 moles of A, 26 moles of B & 30.5 moles of
and how much?
(B) 94∘ C (C) 2.585 (D) 0.0718 C are taken initially then limiting reactant is
∘ (At. wt. Mg = 24, O = 16 )
(C) 148.8 C (A) A
(A) Mg, 0.16 g Q13 0.5 mole of H2 SO4 is mixed with 0.2 mole of
(D) 30∘ C (B) B
(B) O2 , 0.16 g Ca(OH)2 . The maximum number of moles of
(C) C
Q2 At what temperature are Celsius and (C) Mg, 0.44 g CaSO4 formed is:
(D) None of these
Fahrenheit the same? (D) O2 , 0.28 g (A) 0.2 (B) 0.5
(A) -30 (B) 30 (C) 0.4 (D) 1.5 Q20 How many mole of Zn (FeS2 ) can be made
Q8 Equal masses of iron and sulphur are heated
(C) -40 (D) 40 from 2 mole zinc, 3 mole iron and 5 mole sulphur.
together to form FeS. What fraction of the Q14 Limiting reagent in a chemical reaction is
(A) 2 mole (B) 3 mole
Q3 Convert 30 cm3 to dm3 . original mass of excess reactant is left that reactant which
(C) 4 mole (D) 5 mole
(A) 0.03 (B) 0.003 unreacted? ( Fe = 56, S = 32) (A) Left some amount unreacted after the
(C) 0.30 (D) 30 (A) 0.22 (B) 0.43 completion of reaction Q21 10 g H2 reacts with 64 g of O2 determine
(C) 0.86 (D) 0.57 (B) Reacts completely in the reaction number of moles of gaseous product formed
8 −1
Q4 If the speed of light is 3.0 × 10 ms ,
(C) Does not react in the reaction (A) 1 mole (B) 4 mole
calculate the distance covered by light in Q9 The mass of P4 O10 produced if 440 gm of
(D) All of these (C) 3 mole (D) 5 mole
2.00 ns. P4 S3 is mixed with 384 gm of O2 is:
(A) 0.060 m P4 S3 + O2 ⟶ P4 O10 + SO2 Q15 8 gH2 and 32 gO2 is allowed to react to form Q22 According to the equation,
(B) 6.00 m (A) 568gm water then which of the following statement is N2 O3 ( g) + 6H2 ( g) → 2NH3 (g) + 3H2 O(g)
(C) 0.600 m (B) 426gm correct? how many moles of NH3 ( g) could be formed
(D) 0.006 m (C) 284gm (A) O2 is limiting reagent from the reaction of 0.22 mol of N2 O3 ( g) with
(D) 369gm (B) O2 is reagent in excess 0.87 mol of H2 ( g) ?
Q5 What is the maximum amount of nitrogen
(C) H2 is limiting reagent (A) 0.29 mol
dioxide that can be produced by mixing 4.2gm Q10 The mass of Mg3 N2 produced if 48 gm of Mg
(D) 40 g water is formed (B) 0.44 mol
of NO(g) and 3.2gm of O2 ( g)? metal is reacted with 34gm of NH3 gas is
(C) 0.73 mol
(A) 4.60gm Mg + NH3 ⟶ Mg3 N2 + H2 Q16 The number of moles of ' B ' required to
(D) 1.1 mol
(B) 2.30gm (A) 200
3
gm produce 2.5 mole of AB4 according to
(C) 3.22gm (B) 100
3
gm equation: A + 4 B → AB4 Q23 The number of moles of C and D produced on
(D) 6.44gm (C) 400
3
gm (A) 1 (B) 10 mixing 5 moles of A and 7 moles of B are
(D) 150
3
gm (C) 5 (D) 15 respectively :
Q6 The weight of AgCl precipitated when a
(3 A + 5 B → 7C + 9D)
solution containing 5.85 g of NaCl is added to Q11 Calculate the amount of H2 which is left Q17 How many moles of lead (II) chloride will be
(A) 9 moles and 11 moles
a solution containing 3.4 g of AgNO3 is unreacted in the given reaction: formed from a reaction between 6.5 g of PbO
(B) 11.66 moles and 15 moles
(A) 28 g and 3.2 g of HCl ?
(C) 9.8 moles and 12.6 moles
(B) 9.25 g 2H2 + O2 → 2H2 O (A) 0.029 (B) 0.044
(D) 1 moles and 13 moles
(C) 2.87 g (C) 0.333 (D) 0.011

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 NEET NEET

Answer Key Yakeen NEET 2.0 2025 (Alpha)

Q1 (C) Q13 (A) Physical Chemistry
Q2 (C) Q14 (B) DPP: 9
Some Basic Concept of Chemistry
Q3 (A) Q15 (A)

Q4 (C) Q16 (B) Q1 Vanadium metal is added to steel to impart Q7 The multiple 5 × 0.2 after rounding off will be
Q5 (D) Q17 (A) strength. The density of vanadium is (A) 1 (B) 1.0
5.96 g/cm3 . Express this in the SI unit. (C) 1.00 (D) 1.000
Q6 (C) Q18 (A)
(A) 5.96 × 103
Q8 Add (0.001 + 0.02) upto the correct number of
Q7 (A) Q19 (B) (B) 59.6 × 103
significant figures
(C) 596 × 103
Q8 (B) Q20 (A) (A) 0.021 (B) 0.02
(D) 0.596 × 103
Q9 (B) Q21 (B) (C) 0.003 (D) 0.001
Q2 Convert 25365 mg to S.I. unit
Q10 (A) Q22 (A) Q9 One fermi is
(A) 253.65 g
Q11 (B) Q23 (C) −3 (A) 10−13 cm
(B) 25.365 × 10 kg
(B) 10−15 cm
Q12 (A) (C) 25.365 kg
(C) 10−10 cm
(D) 253.65 kg
(D) 10−12 cm
Q3 Convert 15.15 pm to basic unit
Q10 A picometre is written as
Android App | iOS App | PW Website (A) 15.15 × 10−13 m
(A) 10−9 m
(B) 1.515 × 10−12 m
−12 (B) 10−10 m
(C) 15.15 × 10 m
(C) 10−11 m
(D) 1.515 × 10−13 m
(D) 10−12 m
Q4 Pressure is determined as force per unit area of
Q11 Significant figures in 0.00051 are
the surface. The SI unit of pressure, pascal is as
(A) 5 (B) 3
shown below:
(C) 2 (D) 4
1 Pa = 1 N m−2
Q12 1 m3 in equal to
−2
If mass of air at sea level is 1034 g cm , (A) 100 litre (B) 10000 litre
calculate the pressure in pascal. (C) 10 litre (D) 1000 litre
(A) 1.01332 × 104 Pa
Q13 NX is produced by the following step of
(B) 1.01332 × 105 Pa
5 reactions:
(C) 10.01332 × 10 Pa
6
(D) 1.01332 × 10 Pa. M + X2 ⟶ MX2
3MX2 + X2 ⟶ M3 X8
Q5 How many significant figures are in 0. 0008 ?
M3 X8 + N2 CO3 ⟶ NX + CO2 + M3 O4
(A) 1 (B) 2
(C) 3 (D) 4 How much M (metal) is consumed to produces
206 gm of NX? (Take at. Wt. of
Q6 Round off 0.1525 upto three significant figures
M = 56, N = 23, X = 80)
(A) 0.153 (B) 0.152
(A) 42 gm
(C) 0.16 (D) 0.15

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 NEET NEET

(B) 56 gm (A) 0.05 mol

(C) 14 gm (B) 40 g
Answer Key
3
(D) 74 gm (C) 40mg
Q1 (A) Q11 (C)
(D) 4 g
Q14 In Habers process 30 litre of dihydrogen and Q2 (B) Q12 (D)
30 L of dinitrogen were taken for reaction
Q3 (C) Q13 (A)
which yielded only 50% of expected product.
What will be the composition of gaseous Q4 (B) Q14 (C)
mixture under the aforesaid condition in the Q5 (A) Q15 (A)
end.
Q6 (B) Q16 (D)
(A) N2 ( g) = 20 L; H2 ( g) = 0; NH3 ( g)
= 20 L Q7 (A) Q17 (C)
(B) N2 ( g) = 25 L; H2 ( g) = 30 L; NH3 ( g)
Q8 (B) Q18 (D)
= 10 L
(C) N2 ( g) = 25 L; H2 ( g) = 15 L; NH3 ( g) Q9 (A) Q19 (A)
= 10 L
Q10 (D)
(D) N2 ( g) = 10 L; H2 ( g) = 25 L; NH3 ( g)
= 15 L
Q15 If mass % of oxygen in monovalent metal 'M'
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carbonate (M2 CO3 ) is 48% . Find atomic mass
of metal?
(A) 20 (B) 40
(C) 30 (D) 10

Q16 The number of atoms in 20 gof SO3 is

approximately
(A) 1 × 1023
(B) 1.5 × 1023
(C) 2 × 1023
(D) 6 × 1023

Q17 The number of electrons in 3.1mgNO−

3 is:
(A) 32
(B) 1.6 × 10−3
(C) 9.6 × 1020
(D) 9.6 × 1023

Q18 How many moles of electron weigh one

kilogram?
(A) 6.023 × 1023
1
(B) 9.108 × 1031
6.023
(C) 9.108 × 1054
1
(D) 9.108×6.023 × 108

Q19 1.2 g of Mg (At mass 24) will produce MgO

equal to

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 NEET NEET

(C) 20,30 (D) 50,50 (C) 0.5 (D) 0.8

Yakeen NEET 2.0 2025 (Alpha)
Q13 Find mass by mass % of a solution of 20 ml Q20 An aqueous solution of ethanol contains 23 g of
Physical Chemistry volume having solute of mass 4 g. ( density of ethanol dissolved in 90 g of water. Find mole
DPP: 3 solution = 1.4 g/ml) fraction of ethanol in the solution.
Solutions (A) 7.14% (B) 8.2% (A) 34
(C) 9.64% (D) 14.28% (B) 35
Q1 If sea water is assumed to contain 40 g of salt What should be the mass by volume % of a (C) 27
Q14 What is the number of ppm of NaCl in the
per 200 g of sea water then percentage by solution which is 20% mass by mass? 1
(D) 11
solution with 117 g of NaCl dissolved in
mass of salt present is; (density of the solution is 1.02 g/ml )
500 mL of water? Q21 A liquid solution consists of three liquids A, B
(A) 15% (B) 40% (A) 13.2% (B) 10.2%
(A) 1.89 × 105 and C with mole fractions of A = 0.3 and mole
(C) 20% (D) 10% (C) 12.4% (D) 20.4%
(B) 2.78 × 105 fraction of B = 0.2. Find mole fraction of C.
Q2 If 2 moles of CaCO 3 is dissolved in 900 g of Q8 Calculate the mass of cane sugar required to (C) 9.12 × 105 (A) 0.5 (B) 0.2
water then percentage by mass of solution prepare 250 g of 25% cane sugar solution with (D) 6.54 × 105 (C) 0.3 (D) 0.7
formed is water.
Q15 What is the concentration of mercury in ppm if Q22 Find molarity of a sample of pure water.
(A) 36.36% (B) 9.9% (A) 6.25 g
3 g mercury is found in 15 kg sample of ocean Consider density = 1 g/ml .
(C) 18.18% (D) 11.75% (B) 187.5 g
water? (A) 27.7 (B) 33.3
(C) 18.75 g
Q3 0.5 moles of benzene was dissolved in 2 moles (A) 300 (B) 400 (C) 55.5 (D) 11.1
(D) 62.5 g
of toluene. Find mass % of benzene in the (C) 500 (D) 200
solution formed Q9 What is the concentration in mass/volume if Q23 A solution contains 50 g of CaCO 3 dissolved in
Q16 If 3.0mg of Cr+6 is dissolved in 3 L of water, 3 liters of water. Find the molarity of the solution
(A) 25.48% (B) 9.52% 67 g of solute is dissolved to make 1.2 litre of +6
find the concentration of Cr in ppm. formed.
(C) 15.92% (D) 17.48% solution?
(A) 2ppm (A) 12 (B) 13
(A) 6% (B) 8%
Q4 60ml of liquid A is mixed with another liquid B (B) 1ppm (C) 1
(D) 14
(C) 24% (D) 12% 6
and the solution was made up to 300ml. Find (C) 3ppm
volume % of liquid B in the solution formed Q10 What amount of solute is dissolved in 0.5 L of (D) 9ppm Q24 The concentration of CaCl2 solution is 0.5 mole
(A) 40% (B) 60% solution to make it 20%(w/v) ? L−1 . Find the moles of CaCl2 in 500 ml in the
Q17 What is the number of ppm of methanol solution.
(C) 20% (D) 80% (A) 120 g
dissolved in 68 g of water (taking 32gm ) (A) 0.25 (B) 0.45
(B) 150 g
Q5 A solute A was put into a solvent to make a (A) 160000 (B) 480000 (C) 0.3 (D) 0.5
(C) 100 g
solution of mass 240 gram. What should be the (C) 320000 (D) 520000
(D) 200 g
mass of A so that its mass % in solution is 40 ? Q25 What is the molality of a solution containing 2
Q18 A tank contains 5 moles of oxygen, 2 moles moles of a solute dissolved in 500 g of a
(A) 96g Q11 An aqueous solution of NaOH is 20% mass by
of nitrogen and 20 g of hydrogen at room solvent?
(B) 24 g mass. Find the mass of NaOH is 200 g of
temperature. (A) 3 (B) 2
(C) 48g solution.
Find the mole fraction of hydrogen. (C) 1 (D) 4
(D) 36 g (A) 40g 5
(A) 17
(B) 60g
Q6 How much solute should be dissolved in 20 ml 2
(B) 15 Q26 An aqueous solution of glucose is prepared by
(C) 20g
of solution so that mass by volume % of solute (C) 8 dissolving 45 g of glucose in 1 liter of water.
(D) 80 g 15
is 30? (D) 10 Find molality of solution formed.
17
(A) 6 g (B) 4 g Q12 A solution is made by mixing 50 g of water 20 g (A) 14
(C) 8 g (D) 10 g of salt and 30 g of sugar. Mass % of salt and Q19 A room has oxygen and nitrogen in mass ratio (B) 35
sugar are respectively. of 8 :7. Find mole fraction of oxygen gas. (C) 13
Q7
(A) 10,40 (B) 20,40 (A) 0.2 (B) 0.3 (D) 23

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 NEET NEET

Q27 A mixture of H2 and He contains 3 moles of

H2 &10 moles of He. Find molality of H2 .
Answer Key
(A) 35 (B) 82
Q1 (C) Q16 (B)
(C) 75 (D) 40
Q2 (C) Q17 (C)
Q28 If a mixture of two gases A and B contains gas
Q3 (D) Q18 (D)
A of mole fraction 0.3. Find molality of A . (Molar
mass of A = 10 g; B = 20 g ) Q4 (D) Q19 (C)
(A) 21.42 (B) 6.7 Q5 (A) Q20 (D)
(C) 12.14 (D) 8.21
Q6 (A) Q21 (A)
Q29 Fishes feel uncomfortable in warm water due to
Q7 (D) Q22 (C)
(A) físhes do not like warmness
(B) higher amount of impurities Q8 (D) Q23 (C)
(C) low solubility of oxygen at higher Q9 (A) Q24 (A)
temperature
Q10 (C) Q25 (D)
(D) greater population of fishes
Q11 (A) Q26 (A)

Q12 (C) Q27 (C)

Q13 (D) Q28 (A)

Q14 (A) Q29 (C)

Q15 (D)

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 NEET NEET

Q11 O2 is bubbled through water at 293 K . Assume Q16 Vapour pressure is achieved in
Yakeen NEET 2.0 2025 (Alpha) that O2 exerts a partial pressure of 0.98 bar, (A) open container
find the solubility of O2 in gL−1 . The value of (B) closed container
Physical Chemistry Henry's law constant KH for O2 is 34.84k bar. (C) both a & b
DPP: 4
(A) 0.05 (B) 0.08 (D) none of these
Solutions
(C) 0.07 (D) 0.01
Q17 At vapour pressure
Q1 The gas for which Henry's law is not applicable Q6 The factor which decreases the solubility of gas Q12 Gases with their Henry's constant values are (A) forward change is favoured
in aqueous solution is in liquid is given.The gas having maximum solubility will be (B) backward change is favoured
(A) HCl (A) low temperature Gas A − KH = 21.2 k bar (C) both forward & backward changes are
(B) N2 (B) interaction between molecules of gas & Gas B − KH = 11.2 k bar favoured but with equal rate
(C) Xe liquid Gas C − KH = 5.6 k bar (D) none of these
(D) He (C) high temperature Gas D − KH = 2.4 k bar
(D) high pressure (A) A
Q2 Unit of Henrys constant KH is same as that of
(B) B
(A) Volume (B) Temperature Q7 The gas dissolved in carbonated drinks escapes
(C) C
(C) Energy (D) Pressure an opening the bottle due to
(D) D
(A) increase in temperature
Q3 If partial pressure of Gas A = 0.4 bar, Gas
(B) increase in pressure Q13 The gas which is expected to have maximum
B = 0.2 bar and Gas C = 0.5 bar, then the
(C) decrease in pressure over gas value of KH will be
gas having maximum solubility (neglecting
(D) Increase in molecular interaction (A) BH3
other factors) is:
(B) CO2
(A) A Q8 A person feels more fatigue at high altitudes
(C) H2 S
(B) B due to
(D) He
(C) C (A) low pressure of oxygen
(D) All are equal soluble (B) low temperature Q14 An unopened soda has an aqueous
(C) nausea concentration of CO2 at 25∘ C equal to 0.05
Q4 Which law states that the amount of gas that is
(D) contraction of body mole kg−1 . The pressure of CO2 gas in the can
soluble in a liquid is directly proportional to the
is (KH = 0.34 mole /kg bar )
partial pressure of that gas above the liquid Q9 Henry's law is not applicable for aqueous
when the temperature is kept constant? solution of
(A) 0.671 bar
(A) Raoult's Law (B) Henry's Law (A) O2
(B) 1.49bar
(C) Coloumb's Law (D) Dalton's Law (B) N2
(C) 0.147 bar
(C) SO3
Q5 The value of Henry's constant (KH ) depends (D) 1.71bar
(D) He
on
Q15 At vapour pressure
(A) nature of the gas Q10 Henry’s law is not applicable at
(A) ( rate )evaporation = ( rate )condensation
(B) nature of the solvent (A) low pressure
(B) (rate )evaporation > ( rate )condensation
(C) temperature and pressure (B) high pressure
(C) (rate )evaporation < ( rate )condensation
(D) all of these (C) gas does not react with liquid
(D) None of the above
(D) high temperature

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 NEET

NEET Yakeen NEET 2.0 2025 (Alpha)

Answer Key Physical Chemistry
DPP: 5
Q1 (A) Q10 (B) Solutions
Q2 (D) Q11 (A)
Q1 The factor which affect vapour pressure is
Q3 (C) Q12 (D) (A) forces between liquid molecules
Q4 (B) Q13 (D) (B) temperature
(C) volatile solute
Q5 (D) Q14 (C)
(D) all of these
(B)
Q6 (C) Q15 (A)
Q2 Change in surface area has following effect on
Q7 (C) Q16 (B)
vapour pressure:
Q8 (A) Q17 (C) (A) increases
(B) decreases
Q9 (C)
(C) does not affect vapour pressure
(C)
(D) none of the above

Android App | iOS App | PW Website Q3 A solution which is ideal in nature follows.
(A) Graham's Law
(B) Ostwald Law
(C) Fleming's Law
(D) Raoult's Law
(D)
Q4 A container having liquid in equilibrium with its
vapour has volume of 10 L . If the volume of
container is reduced to 5 L, the vapour
pressure (consider constant temperature):
(A) is reduced by 50%
(B) is increased by 50%
(C) remain constant Q7 According to Raoult's law, vapour pressure of
(D) None of these a solution containing non-volatile solute, is
directly proportional to mole fraction of
Q5 If vapour pressure of 10 gram of a liquid solution
(A) solute
is P , then what is the vapour pressure of 5
(B) solvent
gram of same liquid solution?
(C) both solute and solvent
(A) P
(D) none of these
(B) 2P
(C) P/2 Q8 If P∘ → vapour pressure of solvent and
(D) none of these P → vapour pressure of solution then
(assume the solute used is non-volatile)
Q6 The correct relationship of vapour pressure
(A) P∘ > P
and temperature is given by
(B) P ∘ < P
(A)
(C) P∘ = P

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 NEET NEET
0
(D) none of these (C) 0.60 (D) 0.40 300 K, Vapour pr. Of pure liquid A (PA ) = 100
0
∘
torr Vapour pr. Of pure liquid B (PB ) = 300 torr]
Q9 Which of the following is not a characteristic of Q14 At 40 C, vapour pressure in torr of methanol
(A) 200 torr (B) 140 torr
ideal solution? and ethanol solution is P = 119x + 135, where
(C) 180 torr (D) none of these
(A) ΔVmix = 0 x is the mole fraction of methanol. Hence:
(B) ΔSmix = +ve (A) vapour pressure of pure methanol is 119 torr Q19 Boiling point of water is defined as
(C) ΔHmix = 0 (B) vapour pressure of pure ethanol is 135 torr the temperature at which-
(D) ΔGmix = +ve (C) vapour pressure of equimolar mixture of (A) Vapour pressure of water becomes equal to
each is 127 torr that of atmospheric pressure
(D) mixture is completely immiscible. (B) Bubbles are formed
(C) Steam comes out
Q10 Which of the following is the correct Q15 Mole fraction of the component A in vapour
(D) None of the above
mathematical expression for ideal solution of A phase is x1 and mole fraction of component A
and B? in liquid mixture is x2 then (PA 0 = vapour
(A) P = PAo XA + PBo XB pressure of pure A ; PB 0 = vapour pressure of
(B) P > PAo XA + PBo XB pure B ). then total vapour pressure of the liquid
(C) P < PAo XA + PBo XB mixture is
0
(D) None of these (A) PA x2
x1
0
Q11 A container contains component A with (B) PA x1
x2
P∘A = 200 mm and component B of 0
(C) PBx1
x2
P∘B = 500 mm. If moles of A = 2 and moles of 0
(D) PBx2
B = 3, find vapour pressure of solution if solute x1

is volatile. Q16 Two liquids A and B have P∘A : P∘B = 1 : 3 at a

(A) 120 mm certain temperature. If the mole fraction ratio of
(B) 520 mm XA : XB = 1 : 3, the mole fraction of A in
(C) 380 mm vapour in equilibrium with the solution at a
(D) 420 mm given temperature is
(A) 0.1 (B) 0.2
Q12 Benzene and toluene forms an ideal solution.
(C) 0.5 (D) 1.0
Vapour pressure of pure benzene is 100 torr
while that of pure toluene is 50 torr. If mole Q17 Benzene and toluene form two ideal solution A
1
fraction of benzene in liquid phase is 3 . Then and B at 313 K . Solution A (total pressure PA )
calculate the mole fraction of benzene in contains equal mole of toluene and benzene.
vapour phase. Solution B contains equal masses of both (total
(A) 23 pressure PB ). The vapour pressure of pure
(B) 12 benzene and pure toluene are 160 and
(C) 25 60 mmHg respectively at 313 K. Calculate the
(D) 13 value of PA /PB.
(A) 0.694 (B) 0.496
Q13 Mole fraction of the toluene in the vapour
(C) 0.964 (D) 0.732
phase which is in equilibrium with a solution of
benzene ( p∘ = 120 torr) and toluene (p∘ = 80 Q18 Two liquids A & B form an ideal solution. What is
torr) having 2.0 mol of each is: vapour pressure of solution containing 2 moles
(A) 0.50 (B) 0.25 of A and 3 moles of B at 300 K ? [Given: At

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 NEET NEET

Answer Key Yakeen NEET 2.0 2025 (Alpha)

Q1 (D) Q11 (C) Physical Chemistry
Q2 (C) Q12 (B) DPP: 6
Solutions
Q3 (D) Q13 (D)

Q4 (C) Q14 (B) Q1 Which of the following solution has least value Q5 A solution consists of two components X and Y.

Q5 (A) Q15 (A) of vapour pressure? Which of the following relation of interaction
(A) HCl + H2 O between molecules is true for ideal solution of X
Q6 (A) Q16 (A)
(B) NaOH + H2 O and Y ?
Q7 (B) Q17 (C) (C) R − OH + H2 O (A) X − X =Y−Y≠X−Y
(D) CH3 − Cl + H2 O (B) X − X ≠Y−Y=X−Y
Q8 (A) Q18 (D)
(C) X − X ≠ Y − Y ≠ X − Y
Q9 (D) Q19 (A) Q2 Solutions in which both the component has
(D) X − X = Y − Y = X − Y
nearly same polar nature as well as molecular
Q10 (A)
size will form. Q6 A solution which boils at constant temperature is
(A) ideal solution called
(B) non-ideal solution (A) Azeotrope
Android App | iOS App | PW Website (C) Both (A) & (B) (B) Ideal solution
(D) None of these (C) Saline water
(D) Alkaline solution
Q3 The diagram given below is a vapor pressure
composition diagram for a binary solution of A Q7 A mixture of water and benzene is a/an
and B In the solution, A − B interactions are (A) ideal solution
(B) non-ideal solution with positive deviation
(C) non-ideal solution with negative deviation
(D) none of these

Q8 An azeotropic mixture of two liquids boils at a

lower temperature than either of them when
(A) it is saturated
(B) it does not deviate from Raoults law
(C) it shows negative deviation from Raoults law
(D) it shows positive deviation from Raoults law
(A) similar to A − A and B − B interactions
(B) greater than A − A and B − B interactions Q9 Which of the following is not a characteristic of
(C) smaller than A − A and B − B interactions non-ideal solution with positive deviation?
(D) unpredictable (A) ΔVmix >0
(B) ΔHmix >0
Q4 Solution of methanol and ethanol will form
(C) ΔSmix < 0
(A) ideal solution
(D) ΔGmix < 0
(B) non-ideal solution with positive deviation
(C) non-ideal solution with negative deviation Q10 A solution of strong acid and water is an
(D) none (A) ideal solution
(B) non-ideal solution with positive deviation

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 NEET NEET

(C) non-ideal solution with negative deviation 40 g of CH3 OH. Total vapour pressure of the
(D) none of the above solution is approximately-
Answer Key
(A) 67 mmHg
Q11 A non-ideal solution with negative deviation are Q1 (C) Q10 (C)
(B) 35 mmHg
called Q2 (A) Q11 (A)
(C) 105 mmHg
(A) maximum boiling azeotropes
(D) 27 mmHg Q3 (C) Q12 (A)
(B) minimum boiling azeotropes
(C) both (A) & (B) Q17 Mixture of volatile components A and B has Q4 (A) Q13 (C)
(D) none of these total vapour pressure (in torr) Q5 (D) Q14 (C)
P = 254 − 119XA Where XA is mole fraction
Q12 Which of the following is a characteristic of non- Q6 (A) Q15 (B)
of A in mixture. The values of p0A and p0B (in torr)
ideal solution with negative deviation?
are Q7 (B) Q16 (A)
(A) ΔVmix < 0
(A) 254,119 (B) 119,254
(B) ΔHmix > 0 Q8 (D) Q17 (C)
(C) 135,254 (D) 154,119
(C) ΔSmix < 0 Q9 (C) Q18 (A)
(D) ΔGmix > 0 Q18 At 25∘ C , the vapour pressure of pure liquid A
(mol. mass = 40 ) is 100 torr, while that of pure
Q13 The correct expression for vapour pressure of a
liquid B is 40 torr, (mol. mass = 80 ). The vapour
solution containing volatile solute A and solvent Android App | iOS App | PW Website
pressure at 25∘ C of a solution containing 20 g
B is
of each A and B is
(A) P = P∘A XA − P∘B XB
(A) 80 torr (B) 59.8 torr
(B) P = P∘A + (P∘B × P∘A )XB
(C) 68 torr (D) 48 torr
(C) P = P∘B + (P∘A − P∘B )XA
(D) None of these

Q14 Colligative properties of the solution depend

upon
(A) nature of the solution
(B) nature of the solvent
(C) number of solute particles
(D) number of moles of solvent

Q15 Calculate the mole fraction of toluene in the

vapour phase which is in equilibrium with a
solution of benzene and toluene having a mole
fraction of toluene 0.50 .The vapour pressure of
pure benzene is 119 torr, that of toluene is 37 torr
at the same temperature.
(A) 0.327 (B) 0.237
(C) 0.732 (D) 0.456

Q16 The vapour pressures of ethyl alcohol and

methyl alcohol are 45 mmHg and 90 mmHg.
An ideal solution is formed at the same
temperature by mixing 60 g of C2 H5 OH with

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 NEET NEET

Find the molality of an aqueous solution of (C) 3.38 K

Yakeen NEET 2.0 2025 (Alpha) urea which has a boiling point of 102.08
∘
C. (D) 6.28 K
(Take Kb = 0.52 K kg mol−1 )
Physical Chemistry (A) 1 m (B) 2 m
Q16 The freezing point of the solution obtained by
DPP: 7 dissolving 0.5 moles of glucose in 500 g of water
(C) 3 m (D) 4 m
Solutions will be
Q11 The boiling point of 0.1 molal aqueous solution of (A) −1.86∘ C
Q1 Which of the following is the correct expression is lowered by 6 mm. What is the molar mass of urea is 100.18∘ C at 1 atm . The molal elevation (B) −3.2 ∘ C
for the relative lowering of vapour pressure of a the non-ionic substance? constant of water is (C) −0.92∘ C
−1
dilute solution? (A) 10.8 g (A) 0.2 K kg mol (D) −2.24∘ C
P∘A −PA
(A) n
= nB−AnA (B) 7.2 g (B) 0.8 K kg mol−1
P∘A Q17 In a cold climate, water gets frozen causing
P∘A −PA n (C) 4.4 g (C) 1.2 K kg mol−1
(B) = nA +BnB damage to the radiator of a car. Ethylene glycol is
P∘A (D) 6.4 g (D) 1.8 K kg mol−1
P∘A −PA n used as an anti-freezing agent. Calculate the
(C) = n +Bn
PA
PoA −PA
A B
Q6 The temperature at which the vapour pressure of Q12 A centimolal non aqueous solution of a non- amount of ethylene glycol to be added to 4 kg
(D) = nnB
PoA A a liquid becomes equal to the atmospheric electrolyte has elevation in boiling point of of water to prevent it from freezing at −6∘ C (Kf
pressure is known as 0.6∘ C . Find elevation in boiling point of the for water = 1.85 K kg mol−1 )
Q2 Find elevation in boiling point of a solution
(A) Boiling point same solution if molality is 0.4 mole/kg. (A) 8.04 g
obtained by dissolving 90 g of glucose in 200 g
(B) Freezing point (A) 12∘ C (B) 80.4 g
of water. ( Kb of H2 O = 0.52 K kg/ mole).
(C) Absolute temperature (B) 24∘ C (C) 0.80 g
(A) 2.6 K
(D) none of these (C) 6∘ C (D) 804.32 g
(B) 5.3 K
(D) 36∘ C
(C) 1.3 K Q7 Calculate the relative lowering in vapour Q18 The lowering of vapour pressure of a solvent by
(D) 4.2 K 100 g of a non-volatile solute
pressure (RLVP) if Q13 Find concentration of a non-electrolyte addition of a non-volatile solute to it is directly
of molar mass 100 g/mol is dissolved in 432 g solute required to lower the vapour pressure of a proportional to :
Q3 Find molar mass of a non-volatile solute whose
of water. solvent by 20% in mole fraction assuming (A) The strength of the solution
20 g on dissolving in 500 g of water produces a
(A) 0.04 (B) 0.07 concentrated solution. (B) The nature of the solute in the solution
solution having boiling point = 105.2∘ C .
(C) 0.06 (D) 0.09 (A) 0.2 (B) 0.4 (C) The atmospheric pressure
[Kb = 0.52 K kg mole−1 ] (C) 0.6 (D) 0.8 (D) All
Q8 A solution is obtained by dissolving 12 g of urea
(A) 8 g mol−1 (M = 60 ) in one litre of solution. Another Q14 Find depression in freezing point of a glucose Q19 The relative lowering of vapour pressure is equal
(B) 6 g mol−1 68.4 g of cane
solution is made by dissolving solution in which mole fraction of glucose is 0.25 to the mole fraction of the non-volatile solute,
(C) 4 g mol−1 sugar (M = 342) in a litre of solution at the . This statement was given by :
(D) 12 g mol−1 same temperature. The lowering of vapour (A) 34.4 K (A) Raoult (B) Henry
pressure in the first solution is (B) 18.2 K (C) Joule (D) Dalton
Q4 30 g of a non-volatile solute is dissolved in 360 g (A) nearly 5 times that of second solution (C) 24.6 K
of water at 100∘ C . If vapour pressure of solution (B) same as that of second solution (D) 6.2 K
Q20 The vapour pressure of a solution having solid as
is 570 mm of Hg, find molar mass of solute solute and liquid as solvent is
(C) double that of second solution
(A) 5.5 g Q15 Elevation in boiling point of an aqueous solution (A) Directly proportional to mole fraction of the
(D) nearly one fifth of the second solution
(B) 4.5 g of glucose is 2 K. Find the depression in freezing solvent
(C) 6.5 g Q9 Find boiling point of deci molal aqueous solution point of the same solution. (B) Inversely proportional to mole fraction of the
(D) 7.5 g of glucose. (Kb = 0.52 K kg/mole) (Kf = 1.86 K kg/mole and Kb = solvent
(A) 373.052 (B) 473.052 0.52 K kg/mole) (C) Directly proportional to mole fraction of the
Q5 The vapour pressure of water at 20∘ C is (C) 573.052 (D) 273.052 (A) 2.16 K solute
18 mm . When 20 g of a non-ionic substance is (B) 7.14 K (D)
dissolved in 100 g of water the vapour pressure Q10

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 NEET NEET

Inversely proportional to mole fraction of the (C) 75amu

solute (D) 120amu
Answer Key
Q21 If P0 and PS are the vapour pressure of solvent Q26 The vapour pressure of benzene at 90∘ C is Q1 (D) Q15 (B)
and its solution respectively. N1 and N2 are the 1020 torr. A solution of 5 g of a solute in Q2 (C) Q16 (A)
mole fraction of solvent and solute respectively 58.5 g benzene has vapour pressure 990 torr.
Q3 (C) Q17 (D)
then : The molecular weight of the solute is?
P0 Q4 (B) Q18 (A)
(A) Ps = (A) 220 (B) 120
N2
(B) P0 − Ps = P0 N2 (C) 320 (D) 222 Q5 (B) Q19 (A)
(C) Ps = P0 N2 Q27 The vapour pressure of a pure liquid solvent (X) Q6 (A) Q20 (A)
(D) (P0 −Ps ) =
N1
Ps ( N 1+N2 ) is decreased to 0.60 atm. from 0.80 atm on
Q7 (A) Q21 (B)
addition of a non volatile substance (Y). The mole
Q22 One mole of non volatile solute is dissolved in Q8 (B) Q22 (A)
fraction of (Y) in the solution is:-
two mole of water. The vapour pressure of the
(A) 0.20 (B) 0.25 Q9 (A) Q23 (D)
solution relative to that of water is
(C) 0.5 (D) 0.75
(A) 23 Q10 (D) Q24 (C)
(B) 13 Q11 (D) Q25 (B)
(C) 12
Q12 (B) Q26 (A)
(D) 32
Q13 (A) Q27 (B)
Q23 The vapour pressure of a dilute aqueous
Q14 (A)
solution of Glucose is 750 mm of mercury at
373 K . The mole fraction of solute is :
1
(A) 10
1
(B) 7.6 Android App | iOS App | PW Website
1
(C) 35
1
(D) 76

Q24 The vapour pressure of water at room

temperature is 23.8 mm of Hg. The vapour
pressure of an aqueous solution of sucrose with
mole fraction 0.1 is equal to:
(A) 23.9 mmHg
(B) 24.2mmHg
(C) 21.42 mmHg
(D) 31.44 mmHg

Q25 The vapour pressure of pure A is 10 torr and at

the same temperature when 1 g of B is dissolved
in 20gm of A, its vapour pressure is reduced to
A is 200amu,
9.0 torr. If the molecular mass of
then the molecular mass of B is:
(A) 100amu
(B) 90amu

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 NEET NEET

(D) 804.32 g Q16 Elevation in boiling point for 2 molal solution of

Yakeen NEET 2.0 2025 (Alpha) glucose is 2 K. The depression in the freezing
Q10 A solution containing10.2 g glycerine per litres
point for molal solution of glucose is2 K. The
Physical Chemistry is isotonic with a 2% solution of glucose.
relation between Kb and Kf is
DPP: 8 Molecular mass of glucose is 180 then molecular
(A) Kb = 2 Kf
Solutions mass of glycerine is
(B) Kf = 2 Kb
(A) 9.18 (B) 0.918
(C) Kb = Kf
Q1 A membrane which allows the movement of Q5 The freezing point of the solution obtained by (C) 91.8 (D) 918
(D) None of these
only solvent particles through it is called dissolving 0.5 moles of glucose in 500 g of water
Q11 Find the osmotic pressure of 12% solution of
(A) Animal membrane will be Q17 The process used for desalination of sea water is
cane sugar (mol. wt. 342) at
(B) Plant membrane (A) −1.86∘ C (A) Osmosis
27∘ C(d = 1 g/ml)
(C) Semipermeable membrane (B) −3.2 ∘ C (B) Centrifugation
(A) 9.2 atm
(D) Permeable membrane (C) −0.92∘ C (C) Reverse osmosis
(B) 5.62 atm
(D) −2.24∘ C (D) Distillation
Q2 Which of the following is not a characteristic of (C) 7.32 atm
osmosis? Q6 The solution having lesser value of osmotic (D) 8.64 atm
(A) Applicable only for solutions pressure is called
Q12 The osmotic pressure of a M/5 solution of
(B) Possible with semipermeable (A) Hypotonic solution
glucose at 47∘ C is
(C) Movement of only solvent takes place (B) Hypertonic solution
(A) 1.25 atm
(D) Irreversible (C) Isotonic solution
(B) 2.25 atm
(D) Osmotic solution
Q3 When FeCl3 reacts with K4[Fe(CN)6] in aqueous (C) 5.25 atm
solution blue colour of ferri ferrocyanide, Q7 The osmotic pressure of a solution is 2 atm at (D) 7.25 atm
Fe4[Fe(CN)6]3 is obtained. There are 0.1 M FeCl3 273 K then at 546 K , the osmotic pressure is
and 0.01 M K4[Fe(CN)6] solution are separated by (A) 0.5 atm
a semi-permeable membrane as shown and (B) 1 atm
Q13 The osmotic pressure of 5%(w/v) solution of
osmosis occurs then (C) 2 atm
urea at 27∘ C is
(D) 4 atm
(A) 20.5 atm
Q8 Osmotic pressure is 0.0821 atm at temperature (B) 10.5 atm
of 300 K. Find concentration in mole/litre. (C) 12.5 atm
(A) 0.33 (D) 15.5 atm
(B) 0.066
Q14 Correct expression for Van't Hoff factor in case of
(C) 3.3 × 10−3
association is
(A) blue colour is seen in side-B (D) 3
(A) i = 1 + ( n1 − 1) α
(B) blue colour is seen in side-A
Q9 In a cold climate, water gets frozen causing (B) i = 1 + (n − 1)α
(C) blue colour is seen in both sides A and B.
damage to the radiator of a car. Ethylene glycol is (C) i = 1 + ( n2 − 1) α
(D) no blue colour is seen in either side.
used as an anti-freezing agent. Calculate the (D) None of these
Q4 The process of separating solvent from its amount of ethylene glycol to be added to 4 kg
solution by applying pressure greater than of water to prevent it from freezing at −6∘ C (Kf Q15 Correct expression for Van't Hoff factor in case of
−1 dissociation of Al2 (SO4 )3 is
osmotic pressure is called for water = 1.85 K kg mol )
(A) i = 1 + 3α
(A) fractional distillation (A) 8.04 g
(B) i = 1 + 2α
(B) condensation (B) 80.4 g
(C) i = 1 + 4α
(C) distillation (C) 0.80 g
(D) reverse osmosis (D) i = 1 + α2

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 NEET NEET

Answer Key Yakeen NEET 2.0 2025 (Alpha)

Q1 (C) Q10 (C) Physical Chemistry
Q2 (D) Q11 (D) DPP: 9
Solutions
Q3 (D) Q12 (C)

Q4 (D) Q13 (A) Q1 Correct expression for Van't Hoff factor in case of molarity of solution of substance is

Q5 (A) Q14 (A) association is (A) 0.2 (B) 0.4

(A) i = 1 + ( n1 − 1) α (C) 0.5 (D) 0.9
Q6 (A) Q15 (C)
(B) i = 1 + (n − 1)α
Q7 Which of the following pairs of solutions
Q7 (D) Q16 (B) (C) i = 1 + ( n2 − 1) α
are expected to be isotonic at same
Q8 (C) Q17 (C) (D) None of these
temperature?
Q9 (D) Q2 Correct expression for Van't Hoff factor in case of (A) 0.1 M urea and 0.1 M NaCl
dissociation of Al2 (SO4 )3 is (B) 0.1 M urea and 0.2 M MgCl2
(A) i = 1 + 3α (C) 0.1 M NaCl and 0.1 M Na2 SO4
(B) i = 1 + 2α (D) 0.1 M Ca(NO3 )2 and 0.1 M Na2 SO4
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(C) i = 1 + 4α
Q8 A 0.2 molal aqueous solution of a weak acid HX
(D) i = 1 + α2
is 20% ionized. The freezing point of this solution
Q3 Elevation in boiling point for equimolal solutions is (Kf = 1.86 K kg/mole)
of NaCl, Al2 (SO4 )3 , BaCl2 and MgSO4 is (A) −0.45∘ C
highest for (assume α = 1 ) (B) −0.34∘ C
(A) NaCl (C) −0.54∘ C
(B) Na2 SO4 (D) −0.24∘ C
(C) Al2 (SO4 )3
Q9 An aqueous solution of NaCl contains 90 gram
(D) MgSO4
of water and 58.5
g of NaCl. If vapour pressure
Q4 Elevation in boiling point of 1 molal aqueous of water = 720 mm of Hg at that temperature,
solution of Na3 PO4 is (assume α = 0.2 ) find vapour pressure of the solution assuming
(A) 0.52∘ C 100% dissociation.
(B) 0.83∘ C (A) 480 mm
(C) 0.46∘ C (B) 624 mm
(D) 0.64∘ C (C) 464 mm
(D) 564 mm
Q5 The relationship between osmotic pressure of
equimolar solutions of KCl, Ca(NO3 )2 and Q10 K2[PtCl4] is 30% ionized in aqueous solution. The
Na2 SO4 is (α = 1) value of its Van't Hoff factor is:
(A) πNa2 SO4 < πCa2(NO3 )2 = πKCl (A) 1.2 (B) 1.4
(B) πKCl < πCa(NO3 )2 = πNa2 SO4 (C) 1.6 (D) 1.8
(C) πCa(NO3 )2 = πKCl = πNa2 SO4
Q11 The osmotic pressure of decimolar
(D) πCa(NO3 )2 ≠ πKCl ≠ πNa2 SO4
K4 [Fe(CN)6 ] at 227∘ C is (assuming

Q6 A solution of a non-electrolyte substance is α = 75% )

isotonic with decimolar solution of NaCl. The (A) 12.2 atm

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 NEET NEET

(B) 13.4 atm

(C) 15.9 atm
Answer Key
(D) 16.4 atm
Q1 (A) Q8 (A)
Q12 Osmotic pressure of 3.725%(w/v) solution of Q2 (C) Q9 (A)
KCl at 27∘ C is 21.6 atm. Find degree of
Q3 (C) Q10 (C)
dissociation of KCl.
(A) 20% (B) 30% Q4 (B) Q11 (D)
(C) 60% (D) 80% Q5 (B) Q12 (D)

Q13 Correct expression for degree of dissociation ' α ' Q6 (A) Q13 (A)
of electrolyte Ax By is given by
i−1
Q7 (D)
(A) α = x+y−1
i−1
(B) α = (1+y+1)
1−i
(C) α = 1−x−y Android App | iOS App | PW Website
(D) α (1+y+1)
= i−1

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 NEET NEET

Q10 If 1 mole of a non-volatile and non-electrolyte (B) Q

Yakeen NEET 2.0 2025 (Alpha) solute in 1000 g of water depresses the freezing (C) R
point by 1.86∘ C , then what will be the freezing (D) S
Physical Chemistry point of solution of 1 mole of the solute in 500 g
DPP: 10 Q15 Among the colligative properties of
of water?
Solutions ∘ solution, which one is the best method for
(A) −0.93 C
the determination of molecular masses of
(B) −1.86∘ C
Q1 The ebullioscopic constant of a liquid solvent is (A) 34.2%(w/w) Sugar ∘ proteins and polymers?
(C) 3.72C
the elevation of boiling point of (B) 18%(w/w) Glucose (A) Osmotic pressure
(D) −3.72∘ C
(A) one molar solution of non-volatile and (C) 6.00%(w/w) Urea (B) Lowering in vapour pressure
nonelectrolyte solute in it. (D) All the same Q11 What is the molecular mass of a non-ionizing (C) Lowering in freezing point
(B) one normal solution of non-volatile and solid if 10 g of this solid, when dissolved in 100 g (D) Elevation in boiling point
Q6 The molal boiling point elevation constant
nonelectrolyte solute in it. ∘ −1
of water forms a solution which freezes at
of water is 0.513 Ckgmol . When 0.1 mole Q16 5 g of urea is dissolved in one kg of water. Up to
(C) one formal solution of non-volatile and non- 1.24∘ C? Kf (H2 O) = 1.86∘ Ckgmolkg−1 .
of sugar is dissolved in 200 g of water, the what temperature, the solution may be cooled
electrolyte solute in it. (A) 250 (B) 150
solution boils under a pressure of 1 atm at before ice starts crystallizing out? ( Kf of water
(D) one molal solution of non-volatile and (C) 120 (D) 75
(A) 100.513∘ C = 1.86)
nonelectrolyte solute in it.
(B) 102.565∘ C Q12 It is more convenient to obtain the (A) −0.310∘ C
Q2 A solution containing 2.60 g of a non-volatile (C) 100.256∘ C molecular mass of an unknown solute by (B) −0.240∘ C
and non-electrolyte solute in 200 g of water (D) 101.025∘ C measuring the freezing point depression than by (C) −0.195∘ C
boils at 100.130∘ C at 1 atm . What is the molar measuring the boiling point elevation because (D) −0.155∘ C
Q7 The rise in the boiling point of a solution
mass of the solute? (A) Freezing point depression is a colligative
containing 1.8 g of glucose in 100 g of a solvent Q17 A solution containing 62 g ethylene glycol in
[Kb (H2 O) = 0.52 K − kg/mol] property, whereas boiling point elevation is
is 0.1∘ C . The molal elevation constant of the 250 g water is cooled to −10∘ C . If Kf for water
(A) 52.0 g mol−1 not. −1
solvent is is 1. 86 K Kg mol , the amount of water (in
(B) 152.0 g mol−1 (B) Freezing point depressions are larger than
(A) 1 K/m g) separated as ice is
(C) 104 g mol−1 boiling point elevations for the same solution.
(B) 10 K/m (A) 148 (B) 32
(D) 204 g mol−1 (C) Freezing point depressions are smaller than
(C) 0.01 K/m (C) 64 (D) 16
boiling point elevations for the same solution.
Q3 Water should boil at 90∘ C at pressure (D) 2731 K/m
(D) Freezing point depressions depends more on Q18 Of the following measurements, the one most
(A) 1 atm the amount of solute than boiling point
Q8 An aqueous solution of a non-volatile and non- suitable for the determination of the molecular
(B) > 1 atm
electrolyte solute (molecular mass = 150 ) boils elevation. mass of oxyhaemoglobin, a molecule with a
(C) < 1 atm
at 373.26 K. The composition of solution, in molecular mass of many thousands, is.
(D) Any of these Q13 When the depression in freezing point is carried
terms of mass percent of the solute, is (Kb of (A) the elevation of the boiling point.
out, the equilibrium exist between
Q4 The latent heat of vaporization of a liquid of water = 0.52) (B) the depression of the freezing point.
(A) liquid solvent and solid solvent.
molar mass80 g/mol and boiling point, 127∘ C (A) 50% (B) 7.5%
(B) liquid solute and solid solvent.
(C) the osmotic pressure.
is 8kcal/mol. The ebullioscopic constant of the (C) 6.98% (D) 75% (D) any of the previous three, as they are all
(C) liquid solute and solid solute.
liquid is equally good.
Q9 Dry air was passed successively through (D) liquid solvent and solid solute.
(A) 3.2 K − kg/mol
a solution of 5 g of solute in 80 g of water and Q19 On freezing an aqueous solution of sodium
(B) 0.04 K − kg/mol Q14 The molal depression constant for four liquids P,
then through pure water. The loss in mass of chloride, the solid that starts separating out is
(C) 0.32 K − kg/mol Q, R and S , respectively, are 1.84, 2.20, 3.15
solution was 2.5 g and that of pure solvent was (A) ice
(D) 0.52 K − kg/mol and 3.92. If 0.1 m urea solution is made in all the
0.04 g . What is the molecular mass of the solute? (B) sodium chloride
solvents, then the solution in which solvent will
Q5 Which of the following aqueous solution will (A) 70.3 (B) 71.43 (C) solution
show maximum depression in freezing point is
have the highest boiling point? (C) 14.28 (D) 14.06 (D) none of these
(A) P

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 NEET NEET

Answer Key Yakeen NEET 2.0 2025 (Alpha)

Q1 (D) Q11 (B) Physical Chemistry
DPP: 1
Q2 (A) Q12 (B)
Thermodynamics and Thermochemistry
Q3 (C) Q13 (A)

Q4 (A) Q14 (D) Q1 Thermodynamics is concerned with Q9 Internal energy is an example of

Q5 (A) Q15 (A) (A) Total energy of a system (A) Path function
(B) Energy changes in a system (B) State function
Q6 (C) Q16 (D)
(C) Rate of a chemical change (C) Both A and B
Q7 (A) Q17 (C) (D) Mass changes in nuclear reactions (D) None of these

Q8 (C) Q18 (C) Q2 Intensive property is Q10 The intensive property among these quantities is
Q9 (A) Q19 (A) (A) Moles (B) Volume (A) Enthalpy (B) Mass/volume
(C) Mass (D) Temperature (C) Mass (D) Volume
Q10 (D)
Q3 Which of the following is not a state function? Q11 In thermodynamics which one of the following is
(A) Pressure (B) Volume not an intensive property?
Android App | iOS App | PW Website (C) Temperature (D) Heat (A) Pressure (B) Density
(C) Volume (D) Temperature
Q4 Extensive property is
(A) Enthalpy (B) Density Q12 If in a container neither mass and nor heat
(C) Pressure (D) Temperature exchange occurs then it constitutes a
(A) Closed system
Q5 A refrigerator is an example of
(B) Open system
(A) Open system
(C) Isolated system
(B) Closed system
(D) Imaginary system
(C) Isolated system
(D) Non thermodynamic system Q13 Which of the following is not a state function?
(A) ΔS
Q6 Out of E, H, q, W and S which are state function?
(B) ΔG
(A) E, H, W (B) E, S, H, W
(C) ΔH
(C) E, H, S (D) E, H, q, W, S
(D) △Q
Q7 Which of the following statements are false?
Q14 Which of the following is not a state function
(A) Work is a state function
(A) Internal energy
(B) Temperature is a state function
(B) Enthalpy
(C) Change in state is completely defined when
(C) Work
initial and final state are specified
(D) Entropy
(D) Work appears at the boundary of the system
Q15 Which among the following is an extensive
Q8 Both q and w are_____________ function and
property of the system?
q + w is a_______________ function.
(A) Temperature
(A) State, State (B) State, path
(B) Volume
(C) Path, state (D) Path, path
(C) Refractive index

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 NEET NEET

(D) Viscosity Q21 A tightly closed thermo flask contains some ice
cubes. This constitutes
Answer Key
Q16 Which of the following is not a state function?
(A) Closed system
(A) Heat Q1 (B) Q13 (D)
(B) Open system
(B) Internal energy Q2 (D) Q14 (C)
(C) Isolated system
(C) Enthalpy
(D) Non-thermodynamic system Q3 (D) Q15 (B)
(D) Entropy
Q22 Choose the correct answer- A thermodynamic Q4 (A) Q16 (A)
Q17 Which of the following quantities is not a
state function is a quantity Q5 (B) Q17 (D)
state function?
(A) Used to determine heat changes
(A) Temperature (B) Entropy Q6 (C) Q18 (A)
(B) Whose value is independent of path
(C) Enthalpy (D) Work
(C) Used to determine pressure volume work Q7 (A) Q19 (A)
Q18 Which of the following is not an intensive (D) Whose value depends on temperature only
Q8 (C) Q20 (C)
property?
Q23 A thermodynamic quantity is that: Q9 (B) Q21 (C)
(A) Entropy (B) Pressure
(A) Which is used in thermochemistry
(C) Temperature (D) Molar volume Q10 (B) Q22 (B)
(B) Which obeys all the laws of thermodynamics
(C) Quantity which depends only on the state of Q11 (C) Q23 (C)
Q19 Which of the following is a state function and
also an extensive property? the system Q12 (C) Q24 (D)
(A) Internal energy (D) Quantity which is used in measuring thermal
(B) Pressure change
(C) Molar heat capacity
Q24 Which is not characteristic of thermo-chemical Android App | iOS App | PW Website
(D) Temperature
equation?
Q20 Warming ammonium chloride with sodium (A) It indicates physical state of reactants and
hydroxide in a test tube is an example of: products
(A) Closed system (B) It indicates whether the reaction is
(B) Isolated system exothermic or endothermic
(C) Open system (C) It indicates allotrope of reactants if present
(D) None of these (D) It indicates whether reaction would occur or
not

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 NEET NEET

(A) ΔE =Q+W (C) System emits heat and no work is done on it

Yakeen NEET 2.0 2025 (Alpha) (B) ΔE =Q−W (D) System absorbs heat and work is done by it

Physical Chemistry (C) ΔE = Q

Q15 Out of the following, the correct statement is:
(D) Q = W − ΔE
DPP: 2 (A) w is a state function
Thermodynamics and Thermochemistry Q10 A system absorbs 600 J of heat and does work (B) ΔE = q + w for every thermodynamic
equivalent to 300 J on its surroundings. The system at rest in the absence of external field
Q1 If 400 kJ work is done by the system and final volume of 4.50 L . The change in internal change in internal energy is (C) q = 0 for every cyclic process
150 kJ heat is given to system then what will be energy ΔU of the gas in joules will be: (A) 200 J (B) 300 J (D) ΔE = 0 for every cyclic process
effect on internal energy? (A) −500 J (C) 400 J (D) 600 J
Q16 In an isothermal expansion of an ideal gas
(A) Increases by 250 kJ (B) −505 J
Q11 A piston filled with 0.04 mol of an ideal gas (A) q=0
(B) Decreases by 250 kJ (C) +505 J
expands reversibly from 50.0 mL to 375 mL at (B) ΔV =0
(C) Increases by 600 kJ (D) 1136.25 J
a constant temperature of 37.0∘ C . As it does so, (C) ΔU = 0
(D) Increases by 600 kJ
Q6 A gas expands from 3.0 L to 3.5 L against an it absorbs 208 J of heat. The values of q and w (D) w = 0
Q2 In Isobaric process external pressure of 1 atm . Calculate the PV for the process will be
Q17 An ideal gas enclosed in a cylinder fitted with a
(A) Pressure is constant work done. (R = 8.314 J/molK, In 7.5 = 2.01)
frictionless and weight less piston, pushes it
(B) Temperature is constant (A) −0.5 L − atm (A) q = +208 J, w = +208 J
outside. What would be the sign convention for
(C) No heat is exchanged (B) −1 L − atm (B) q = +208 J, w = −208 J
the work?
(D) Volume is constant (C) −100 J (C) q = −208 J, w = −208 J
(A) Positive
(D) −200 J (D) q = −208 J, w = +208 J
Q3 For an adiabatic process which of the relations (B) Negative
is correct Q7 When 1 mole of a gas is heated at constant Q12 Which of the following is correct option for free (C) Zero
(A) PΔV = 0 volume, temperature is raised from 298 to expansion of an ideal gas under adiabatic (D) Cannot be predicted
(B) PΔV = 0 308 K . If heat supplied to the gas is 500 J then condition?
(C) q = 0 which statement is correct? (A) q = 0, ΔT < 0, w ≠ 0
(D) q = +W (A) q = w = 500 J, ΔU = 0 (B) q = 0, ΔT ≠ 0, w = 0
(B) q = ΔU = 500 J, w = 0 (C) q ≠ 0, ΔT = 0, w = 0
Q4 Under isothermal condition, a gas at 300 K
(C) q = −w = 500 J, ΔU = 0 (D) q = 0, ΔT = 0, w = 0
expands from 0.1 L to 0.25 L against a
(D) ΔU = 0, q = w = −500 J
constant external pressure of 2 bar. The work Q13 Which one of the following equation does not
done by the gas is (Given that 1 L bar = 100 J) Q8 A system is provided 50 J of heat and work done correctly represent the first law of
(A) −30 J on the system is 10 J. The change in internal thermodynamics for the given process?
(B) 5 kJ energy during the process is (A) Isothermal process: q= −w
(C) 25 J (A) 40 J (B) Cyclic process: q= −w
(D) 30 J (B) 60 J (C) Isochoric process: ΔE = q
(C) 80 J (D) Adiabatic process: ΔE = −w
Q5 A gas is allowed to expand in a well insulated
(D) 50 J
container against a constant external pressure of Q14 ΔE is always positive when
2.5 atm from an initial volume of 2.50 L to a Q9 The first law of thermodynamics is represented (A) System absorbs heat and work is done on it
by the equation: (B) System emits heat and work is done on it

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 NEET NEET

Answer Key Yakeen NEET 2.0 2025 (Alpha)

Q1 (B) Q10 (B) Physical Chemistry
Q2 (A) Q11 (B) DPP: 3
Thermodynamics and Thermochemistry
Q3 (C) Q12 (D)

Q4 (A) Q13 (D) Q1 In a constant volume process, internal energy (A) ΔH = 0

Q5 (B) Q14 (A) change is equal to (B) ΔW = 0
(A) Heat transferred (C) ΔQ = 0
Q6 (A) Q15 (D)
(B) Work done (D) ΔV = 0
Q7 (B) Q16 (C) (C) Zero
Q7 The first law of thermodynamics is only
(D) None of the mentioned
Q8 (B) Q17 (B) (A) The law of conservation of energy
Q9 (A) Q2 Which of the following is zero for an isochoric (B) The law of conservation of mass
process? (C) The law of conservation of momentum
(A) dP (D) Both (1) and (2)
(B) dV
Android App | iOS App | PW Website Q8 The internal energy of a substance
(C) dT
(A) Increases with increase in temperature
(D) dE
(B) Decreases with increase in temperature
Q3 In an isochoric process the increase in (C) Remains constant
internal energy is (D) Calculated by E = mc 2
(A) Equal to the heat absorbed
Q9 Inter-mixing of ideal gases (at the
(B) Equal to the heat evolved
same temperature) is an example of
(C) Equal to the work done
(A) Reversible isothermal
(D) Equal to the sum of the heat absorbed and
(B) Irreversible isothermal and adiabatic
work done
(C) Reversible adiabatic
Q4 It is general principle that the less energy a (D) None of these
system contains, it is
Q10 The process carried out in perfect insulation is
(A) Less stable (B) More stable
(A) Isothermal (B) Isobaric
(C) Unstable (D) More unstable
(C) Isochoric (D) Adiabatic
Q5 The process, in which no heat enters or leaves
Q11 During the adiabatic expansion of ideal gas,
the system, is termed as
which is correct?
(A) Isochoric (B) Isobaric
(A) Temperature increases
(C) Isothermal (D) Adiabatic
(B) q = 0
Q6 Which of the following is true for an (C) Temperature remains constant
adiabatic process? (D) ΔE = 0

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 NEET NEET

Q12 For isothermal expansion of ideal gas which is Q18 In an adiabatic expansion of an ideal gas
correct? (A) ΔT =0
Answer Key
(A) ΔH =0 (B) W = 0
Q1 (A) Q10 (D)
(B) ΔE =0 (C) q = 0
(C) ΔT = 0 (D) ΔU = 0 Q2 (B) Q11 (B)
(D) All Q3 (A) Q12 (D)

Q13 As per the First Law of thermodynamics, which of Q4 (B) Q13 (D)
the following statement would be appropriate: Q5 (D) Q14 (D)
(A) Energy of the system remains constant
Q6 (C) Q15 (A)
(B) Energy of the surroundings remains constant
(C) Entropy of the universe remains constant Q7 (A) Q16 (B)
(D) Energy of the universe remains constant
Q8 (A) Q17 (C)
Q14 For a particular process q = −10 kJ and Q9 (B) Q18 (C)
w = 25 kJ. Which of the following statements is
true?
(A) Heat flows from the surroundings to the
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system
(B) The system does work on the surroundings
(C) ΔE = −35 kJ
(D) None of the above is true

Q15 A system absorbs 10 kJ of heat and does 4 kJ

of work. The internal energy of the system
(A) Increases by 6kJ
(B) Decreases by 6 kJ
(C) Decreases by 14 kJ
(D) Increases by 14 kJ

Q16 The first law of thermodynamics expressed

(A) Law of conservation of momentum
(B) Law of conservation of energy
(C) Law of conservation of mass
(D) All of the above

Q17 The temperature of an ideal gas increases in an

(A) Adiabatic expansion
(B) Isothermal expansion
(C) Adiabatic compression
(D) Isothermal compression

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 NEET NEET

Q9 Two moles of an ideal monoatomic gases are The work done in an adiabatic process on ideal
Yakeen NEET 2.0 2025 (Alpha) allowed to expand adiabatically and reversibly gas by a constant external pressure would be
from 300 K to 200 K . The work done in the (A) Zero
Physical Chemistry system is (CV = 12.5 J/Kmol) (B) ΔE
DPP: 4
(A) −12.5 kJ (C) ΔH
Thermodynamics and Thermochemistry
(B) −2.5 kJ (D) ΔG

∘
(C) −625 kJ
Q1 One mole of an ideal gas at 25 C expands in Q5 The maximum work done in expanding 16 g Q15 A certain amount of zinc is dissolved in HCl at
(D) 500 kJ
volume from 1.0 L to 4.0 L at constant oxygen at 300 K and occupying a volume of 25∘ C in an open vessel. The type of process and
temperature. What work (in J) is done if the gas 5dm3 isothermally until the volume becomes Q10 Adiabatic expansion of ideal gas into the work done by the system respectively would
expands against vacuum (Pexternal = 0) ? 25dm3 is: vacuum correspond to be
(A) −4.0 × 102 (A) −2.01 × 103 J (A) w = 0 (A) Isothermal, positive
(B) −3.0 × 102 (B) 2.81 × 10−3 J (B) ΔE = 0 (B) Isobaric, negative
(C) −1.0 × 102 (C) 2.01 × 10−6 J (C) ΔH = 0 (C) Isochoric, zero
(D) Zero (D) 2.01 × 10−6 J (D) All of these (D) None

Q2 The maximum work obtained by an Q6 The internal energy change when a system goes Q11 The temperature of 1 mole of a gas is increased Q16 A system absorb 20 kJ heat and does 10 kJ
isothermal reversible expansion of 1 mole of an from state A to B is 40 kJ/mol. If the system by 1∘ C at constant pressure. The work done is: work then internal energy of system will be-
ideal gas at 27∘ C from 2.24 to 22.4 L is (R = 2 goes from A to B by a reversible path and (A) −R (A) Decreases by 10 kJ
−1
cal K mol−1 ) returns to state A by an irreversible path. What (B) 2R (B) Increases by 10 kJ
(A) −1381.8cal would be the change in internal energy? (C) R/2 (C) Increases by 30 kJ
(B) −600cal (A) 40 kJ (D) 3R (D) Decreases by 30 kJ
(C) −138.18cal (B) > 40 kJ
Q12 The relation of internal energy, enthalpy and Q17 5 mol of ideal gas expands isothermally and
(D) −690.9cal (C) < 40 kJ
work done can be represented by irreversibly from a pressure of 10 atm to 1 atm
(D) Zero
Q3 2 mole of an ideal gas at 27∘ C expands (A) ΔE = ΔH + W against constant external pressure of 1 atm work
isothermally and reversibly from a volume of 4 Q7 One mole of oxygen is allowed to expand (B) ΔE = W − ΔH at 300 K will be
litres to 40 litres. The work done (in kJ ) is: isothermally and reversibly from 5 m3 to 10 m3 (C) ΔH = ΔE + W (A) −15.921 kJ
(A) w = −28.72 kJ at 300 K . Calculate work done in expansion of (D) W = ΔE + ΔH (B) −11.224 kJ
(B) w = −11.488 kJ gas. (C) −110.83 kJ
Q13 A gas expands isothermally against a constant
(C) w = −5.736 kJ (A) −172.89 J (D) None of these
external pressure of 1 atm from a volume of
(D) w = −4.988 kJ (B) 1728.98 J 3 3
10 dm to a volume of 20 dm . It absorbs Q18 Match the column:
(C) −1728.98 J
Q4 The work done on the system when one mole of 800 J of thermal energy from its surroundings. Column-I Column-II
(D) 172.89 J
an ideal gas at 500 K is compressed The ΔU is a. Adiabatic process i. q = 0
1
isothermally and reversibly to 10 th of its original Q8 Isothermal free expansion of an ideal gas (A) −312 J b. Isothermal process ii. ΔH = 0
volume (R = 2cal) correspond to (B) +123 J c. Isoenthalpic process iii. ΔT = 0
(A) 500kcal (A) q = 0 (C) −213 J d. Isoentropic process iv. ΔS = 0
(B) 15.1kcal (B) W = 0 (D) +231 J (A) a-i, b-iv, c-ii, d-iii
(C) 25.03kcal (C) None of these (B) a-ii, b-i, c-iv, d-iii
Q14
(D) 2.303kcal (D) Both (A) and (B) (C) a-i, b-iii, c-ii, d-iv

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 NEET NEET

(D) a-i, b-iii, c-iv, d-ii to be ideal. What is the work for the process C to 4.48 L of an ideal gas at STP requires 12.0
∘
D? calories to raise its temperature by 15 C at
Q19 Which of the following is correct for free
constant volume. The Cp of the gas is:
expansion of ideal gas under isothermal
(A) 3 cal
condition:
(B) 4 cal
(A) q = 0, ΔT < 0, w < 0
(C) 7 cal
(B) q = 0, ΔT = 0, w = 0
(D) 6 cal
(C) q ≠ 0, ΔT = 0, w = 0
(D) q ≠ 0, ΔT = 0, w ≠ 0 (A) 12P1 V1 Q32 Calculate the amount of heat required to raise
(A) −800R ln 2
(B) 6P1 V1 the temperature of 5 g of iron from 25 C to
∘
Q20 An ideal gas receives 10 J of heat in a reversible (B) Zero
(C) 5P1 V1 ∘
75 C . The specific heat capacity of iron is
isothermal expansion. Then the work done by the (C) +200R ln 2
(D) P1 V1 0.45 J/g.
gas: (D) −600R ln 2
(A) 112.1 (B) 112.5
(A) Would be more than 10 J Q24 What is the final temperature of 0.10 mole
Q27 Heat capacity of H2 O at its boiling point is: (C) 112.9 (D) 112
(B) 10 J monoatomic ideal gas that performs 75 cal of
(A) 3calmol−1 K−1
(C) Would be less than 10 J work adiabatically if the initial temperature is Q33 For two mole of an ideal gas
(B) 5calmol−1 K−1
(D) Cannot be determined 227∘ C ? (A) Cv − Cp = R
(C) 7calmol−1 K−1
(use R = 2cal/K − mol ) (B) Cp − Cv = 2R
Q21 Net work done by the system in a cyclic process (A) 250 K (D) Infinite
(C) Cp − Cv = R
is equal to: (B) 300 K
Q28 For monoatomic ideal gas, the exact value of (D) Cv − Cp = 2R
(A) Zero (C) 350 K
the ratio of Cp,m and Cv,m is:
(B) △U (D) 750 K Q34 The heat required to raise the temperature of a
(A) 53
(C) ΔH body by 1 K is called
(D) q Q25 A given mass of gas expands from the state A to (B) 75 (A) Specific heat
the state B by three paths 1,2 and 3 as shown in (C) 97 (B) Thermal capacity
Q22 Heat absorbed by a system in going through a the figure. If w1 , w2 , and w3 respectively be the 9
(D) 11 (C) Water equivalent
cyclic process shown in figure is: magnitudes work done by the gas along three (D) None of these
Q29 Molar heat capacity of water in equilibrium with
paths then:
ice at constant pressure is: Q35 A gas expands adiabatically at constant pressure
(A) Zero 1/2
such that TV The value of (Cp /CV ) of the
(B) Infinity gas will be:
(C) 40.45 kJ K−1 mol−1 (A) 1.30 (B) 1.50
(D) 75.48JK−1 mol−1 (C) 1.70 (D) 2
7
(A) 10 πJ
6
(B) 10 πJ Q30 How many calories are required to heat 40
(C) 102 πJ grams of argon from 40 to 100∘ C at constant
(D) 104 πJ (A) w1 > w2 > w3 (B) w1 < w2 < w3 volume? (R = 2cal/molK)
(C) w1 = w2 = w3 (D) w2 < w3 < w1 (A) 120 (B) 2400
Q23 An ideal gas is taken around the cycle ABCA as
(C) 1200 (D) 180
shown in P − V diagram. The net work done Q26 Two moles of Helium gas undergo a reversible
during the cycle is equal to: cyclic process as shown in figure. Assuming gas Q31

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 NEET

NEET Yakeen NEET 2.0 2025(Alpha)

Answer Key Physical Chemistry
DPP: 5
Q1 (D) Q19 (B) Thermodynamics and Thermochemistry
Q2 (A) Q20 (B)
Q1 For which of the following reactions, ΔH is equal For the reaction A
→ B, ΔH = +24 kJ/ mole,
Q3 (B) Q21 (D) to ΔU ? For the reaction B
→ C, ΔH = −18 kJ/ mole.
Q4 (D) Q22 (C) (A) 2HI(g) → H2 ( g) + I2 ( g) The decreasing order of enthalpy of A, B, C
(B) 2SO2 ( g) + O2 ( g) → 2SO3 ( g) follows the order:
Q5 (A) Q23 (C)
(C) N2 ( g) + 3H2 ( g) → 2NH3 ( g) (A) A, B, C
Q6 (D) Q24 (A) (D) 2NO2 ( g) → N2 O4 ( g) (B) B, C, A
Q7 (C) Q25 (B) (C) C, B, A
Q2 The value of enthalpy change (ΔH) for the
(D) C, A, B
Q8 (D) Q26 (A) reaction C2 H5 OH (I)

Q9 (B) Q27 (D)

+3O2 ( g) → 2CO2 ( g) + 3H2 O (I) at 27∘ C Q6 Enthalpy is:
−1
is −1366.5 kJ mol . The value of internal (A) State function
Q10 (D) Q28 (A) energy change for the above reaction at this (B) Extensive
Q11 (A) Q29 (B) temperature will be: (C) None of them
(A) −1371.5 kJ (D) Both 1 and 2
Q12 (A) Q30 (D)
(B) −1369.0 kJ
Q13 (C) Q31 (D) Q7 16gm of O2 expand at constant pressure and
(C) −1364.0 kJ
273.15 K to occupy double its original volume.
Q14 (B) Q32 (B) (D) −1361.5 kJ
The work done during the process will be:
Q15 (B) Q33 (B) Q3 One mole of a non-ideal gas undergoes a change (A) w = −260cal
Q16 (B) Q34 (B) of state (2.0 atm, 3.0 L, 95 K) → (4.0 atm, (B) w = −180cal
5.0 L, 245 K) with a change in internal energy, (C) w = −130cal
Q17 (B) Q35 (B)
ΔU = 30.0 L atm. The change in enthalpy (D) w = −273.15cal
Q18 (C) (ΔH) is the process in L atm is:
Q8 Heat exchanged in a chemical reaction at the
(A) 40.0
constant temperature and pressure is known as
(B) 42.3
(A) Internal energy
(C) 44.0
Android App | iOS App | PW Website (B) Entropy
(D) Not defined, because process is not constant
(C) Enthalpy
Q4 The temperature of 2 moles of an ideal gas is (D) Free energy
raised from 27∘ C to 77∘ C . What is the value of
Q9 One mole of a non-ideal gas undergoes a change
ΔH − ΔU for the process?
of state (1.0 atm, 3.0 L, 200 K) to
(R = 8.3 J K−1 mol−1 )
(4.0 atm, 5.0 L, 250 K) with a change in
(A) 415 J
internal energy (ΔU) = 40 L-atm. The change
(B) 830 J
in enthalpy of the process in L-atm
(C) 1660 J
(A) 43 (B) 57
(D) None of these
(C) 42 (D) None of these
Q5
Q10

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 NEET NEET
∘
For the real gases reaction Q15 If S for H2 , Cl2 and HCl are 0.13, 0.22 and (C) ΔH = ΔE
2CO(g) + O2 ( g) → 2CO2 ( g); ΔH = . In 0.19 KJ K−1 mol−1 respectively. The total (D) ΔH = TΔS
−560 kJ change in standard entropy for the reaction
10 litre rigid vessel at 500 K the initial pressure Q21 Determine the entropy change for the reaction
H2 + Cl2 ⟶ 2HCl is:
given below:
is 70 bar and after the reaction it becomes 40 (A) 30 JK−1 mol−1
bar. The change in internal energy is 2H2( g) + O2( g) ⟶ 2H2 O(ℓ) at 300 K .
(B) 40 JK−1 mol−1
(A) −557 kJ If standard entropies of H2( g) , O2 ( g) and
(C) 60 JK−1 mol−1
(B) −530 kJ H2 O(ℓ) are 126.6, 201.20 and
(D) 20 JK−1 mol−1
(C) −563 kJ 68.0 J K−1 mol−1 respectively.
(D) None of these Q16 The enthalpy of vaporization for water is (A) −218.4 J K−1 mol−1
186.5KJ mol−1 , the entropy of its vaporization (B) −318.4 J K−1 mol−1
Q11 A vessel contains 100 litres of a liquid X. Heat is (C) −520.2 J K−1 mol−1
will be-
supplied to the liquid in such a fashion that, Heat (D) −128.6 J K−1 mol−1
(A) 0.5KJK−1 mol−1
given = change in enthalpy. The volume of the (B) 1.0KJK mol−1
−1
liquid increases by 2 litres. If the external Q22 Calculate the entropy change in melting of one
(C) 1.5KJK−1 mol−1
pressure is one atm, and 202.6 Joules of heat gm ice at 0∘ C if latent heat of ice is 80cal/g -
(D) 2.0KJK−1 mol−1
were supplied then, [U− total internal energy ] (A) 80 CalK−1
(A) ΔU = 0, ΔH = 0 Q17 The enthalpy of vaporization of per mole of (B) 20 CalK−1
(B) ΔU = +202.6 J, ΔH = +202.6 J ethanol (b.p. = 79.5∘ C and (C) 4.4 CalK−1
(C) ΔU = −202.6 J, ΔH = −202.6 J ΔS = 109.8JK−1 mol−1 ) is: (D) 0.3 CalK−1
(D) ΔU = 0, ΔH = +202.6 J (A) 27.35KJ/mol
Q23 Standard state means-
(B) 32.19KJ/mol
Q12 0.16 g of methane was subjected to combustion (A) 25∘ C and 70mmHg
(C) 38.70KJ/mol
at 27∘ C in a bomb calorimeter system. (B) 298 K and 760 cmHg
(D) 42.37KJ/mol
The temperature of the calorimeter system (C) 273 K and 1 atm
(including water) was found to rise by 0.5∘ C . Q18 In a spontaneous irreversible process the (D) 298 K and one atm
Heat of combustion of methane at constant total entropy of the system and surroundings
Q24 If 900 J/g of heat is exchanged at boiling point
pressure is(Heat capacity of the calorimeter (A) Remains constant
−1 of water, then what is increase in entropy?
system is 17.7 kJ K ). (B) Increases
(A) 43.4 J/Kmole
(A) −890 kJ (C) Decreases
(B) 87.2J/K mole
(B) −885 kJ (D) Zero
(C) 900 J/Kmole
(C) +890 kJ
Q19 The spontaneous nature of a reaction is (D) Zero
(D) +885 kJ
impossible if
Q13 In which reaction ΔS is positive: (A) ΔH is +ve, ΔS is also +ve
(A) H2 O(ℓ) → H2 O(s) (B) ΔH is −ve; ΔS is also -ve
(B) 3O2( g) → 2O3( g) (C) ΔH is −ve; ΔS is +ve
(C) H2 O(ℓ) → H2 O(g) (D) ΔH is +ve; ΔS is −ve
(D) N2( g) + 3H2( g) → 2NH3( g)

Q14 When the egg is hard boiled, there is- Q20 Which of the following is true for the reaction
(A) Increase in disorder H2 O(ℓ) ⇌ H2 O(g) at 100∘ C and 1
(B) Decrease in disorder atmosphere
(C) No change in disorder (A) ΔS =0
(D) ΔG is negative (B) ΔH =0

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 NEET

Answer Key
Q1 (A) Q13 (C)

Q2 (C) Q14 (A)

Q3 (C) Q15 (A)

Q4 (B) Q16 (A)

Q5 (B) Q17 (C)

Q6 (D) Q18 (B)

Q7 (D) Q19 (D)

Q8 (C) Q20 (D)

Q9 (B) Q21 (B)

Q10 (B) Q22 (D)

Q11 (D) Q23 (D)

Q12 (A) Q24 (A)

DPP SOLUTION
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• Subject – Physical Chemistry

• Chapter – Thermodynamics and

Thermochemistry

DPP No.- 04 By – Sudhanshu Sir

 Question Question

One mole of an ideal gas at 25°C expands in volume from 1.0 L to 4.0 L at constant The maximum work obtained by an isothermal reversible expansion of 1 mole of
temperature. What work (in J) is done if the gas expands against vacuum an ideal gas at 27°C from 2.24 to 22.4 L is (R = 2 cal K–1 mol–1)
(Pexternal = 0)?
1 –1381.8 cal
1 –4.0 × 102
2 –600 cal
2 –3.0 × 102
3 –138.18 cal
3 –1.0 × 102
4 –690.9 cal
4 Zero
 Question Question

2 mole of an ideal gas at 27°C expands isothermally and reversibly from a volume The work done on the system when one mole of an ideal gas at 500 K is
of 4 litres to 40 litres. The work done (in kJ) is: compressed isothermally and reversibly to
𝟏 th
of its original volume (R = 2 cal)
𝟏𝟎
1 w = –28.72 kJ
1 500 kcal

2 w = –11.488 kJ
2 15.1 kcal

3 w = –5.736 kJ
3 25.03 kcal

4 w = –4.988 kJ
4 2.303 kcal
 Question Question

The maximum work done in expanding 16g oxygen at 300 K and occupying a The internal energy change when a system goes from state A to B is 40 kJ/mol. If
volume of 5 dm3 isothermally until the volume becomes 25 dm3 is: the system goes from A to B by a reversible path and returns to state A by an
irreversible path. What would be the change in internal energy?
1 –2.01 × 103 J
1 40 kJ
2 2.81 × 10–3 J
2 > 40 kJ
3 2.01 × 10–6 J
3 < 40 kJ
4 –2.01 × 10–6 J
4 Zero
 Question Question

One mole of oxygen is allowed to expand isothermally and reversibly from 5 m3 to Isothermal free expansion of an ideal gas correspond to
10 m3 at 300 K. Calculate work done in expansion of gas.
1 q=0
1 –172.89 J
2 w=0
2 1728.98 J
3 None of these
3 –1728.98 J
4 Both (1) and (2)
4 172.89 J
 Question Question

Two moles of an ideal monoatomic gases are allowed to expand adiabatically and Adiabatic expansion of ideal gas into vacuum correspond to:
reversibly from 300K to 200 K. The work done in the system is (CV = 12.5 J/K mol)
1 w=0
1 –12.5 kJ
2 E = 0
2 –2.5 kJ
3 H = 0
3 –625 kJ
4 All of these
4 500 kJ
 Question Question

The temperature of 1 mole of a gas is increased by 1°C at constant pressure. The The relation of internal energy, enthalpy and work done can be represented by
work done is:
1 E = H + W
1 –R
2 E = W – H
2 2R
3 H = E + W
3 R/2
4 W = E + H
4 3R
 Question Question

A gas expands isothermally against a constant external pressure of 1 atm from a The work done in adiabatic process on ideal gas by a constant external pressure
volume of 10 dm3 to a volume of 20 dm3. It absorbs 800 J of thermal energy from would be
its surroundings. The U is
1 Zero
1 –312 J
2 E
2 +123 J
3 H
3 –213 J
4 G
4 +231 J
 Question Question

A certain amount of zinc is dissolved in HCl at 25oC in an open vessel. The type of A system absorb 20 kJ heat and does 10 kJ work then internal energy of system
process and the work done by the system respectively would be will be–

1 Isothermal, positive 1 Decreases by 10 kJ

2 Isobaric, negative 2 Increases by 10 kJ

3 Isochoric, zero 3 Increases by 30 kJ

4 None 4 Decreases by 30 kJ
 Question Question

5 mol of ideal gas expands isothermally and irreversibly from a pressure of 10 Match the column:
atm to 1 atm against constant external pressure of 1 atm work at 300 K will be: Column-I Column-II
a. Adiabatic process i. q=0
1 –15.921 kJ b. Isothermal process ii. H = 0
c. Isoenthalpic process iii. T = 0
2 –11.224 kJ d. Isoentropic process iv. S = 0

1 a-i, b-iv, c-ii, d-iii

3 –110.83 kJ
2 a-ii, b-i, c-iv, d-iii
4 None of these
3 a-i, b-iii, c-ii, d-iv

4 a-i, b-iii, c-iv, d-ii

 Question Question

Which of the following is correct for free expansion of ideal gas under isothermal An ideal gas receives 10 J of heat in a reversible isothermal expansion. Then the
condition: work done by the gas:

1 q = 0, T < 0, w < 0 1 Would be more than 10 J

2 q = 0, T = 0, w = 0 2 10 J

3 q  0, T = 0, w = 0 3 Would be less than 10 J

4 q  0, T = 0, w  0 4 Cannot be determined
 Question Question

Net work done by the system in a cyclic process is equal to: Heat absorbed by a system in going through a cyclic process shown in figure is:

1 Zero 1 107  J 30

V (in L)
2 ΔU 2 106  J
10 30
10
3 ΔΗ 3 102  J
P (in kPa)

4 q 4 104  J
 Question Question

An ideal gas is taken around the cycle ABCA as shown in P–V diagram. The net What is the final temperature of 0.10 mole monoatomic ideal gas that performs 75
work done during the cycle is equal to: cal of work adiabatically if the initial temperature is 227°C?
(use R = 2 cal/K-mol)
1 12P1V1 B
6P 1
1 250 K
Pressure

2 6P1V1
P1 C
A 2 300 K
3 5P1V1 V1 3V1
Volume 3 350 K
4 P 1 V1
4 750 K
 Question Question

A given mass of gas expands from the state A to the state B by three paths 1, 2 Two moles of Helium gas undergo a reversible cyclic process as shown in figure.
and 3 as shown in the figure. If w1, w2, and w3 respectively be the magnitudes Assuming gas to be ideal. What is the work for the process C to D?
work done by the gas along three paths then:
1 –800 Rℓn2
B
1 w1 > w2 > w 3 P 2 atm C

2 Zero
1 atm D
2 w1 < w2 < w 3 A A
3 300 K 400 K
T
2 3 +200 Rℓn2
3 w1 = w2 = w 3 1 B
V 4 –600 Rℓn2
4 w2 < w3 < w 1
 Question Question

Heat capacity of H2O at its boiling point is: For monoatomic ideal gas, the exact value of the ratio of Cp, m and Cv, m is:

1 3 cal mol–1 K–1 1

2 5 cal mol–1 K–1 2

3 7 cal mol–1 K–1

3

4 Infinite
4
 Question Question

Molar heat capacity of water in equilibrium with ice at constant pressure is: How many calories are required to heat 40 gram of argon from 40 to 100°C at
constant volume?
1 Zero
(R = 2 cal/mol K)

2 Infinity 1 120

3 40.45 kJ K–1 mol–1 2 2400

4 75.48 JK–1 mol–1 3 1200

4 180
 Question Question

4.48 L of an ideal gas at STP requires 12.0 calories to raise its temperature by 15°C Calculate the amount of heat required to raise the temperature of 5 g of iron from
at constant volume. The Cp of the gas is: 25°C to 75°C. The specific heat capacity of iron is 0.45 J/g.

1 3 cal 1 112.1

2 4 cal 2 112.5

3 7 cal 3 112.9

4 6 cal 4 112
 Question Question

For two mole of an ideal gas The heat required to raise the temperature of a body by 1 K is called

1 Cv – Cp = R 1 Specific heat

2 Cp – Cv = 2R 2 Thermal capacity

3 Cp – Cv = R 3 Water equivalent

4 Cv – Cp = 2R 4 None of these
 Question

A gas expands adiabatically at constant pressure such that TV1/2. The value of
(Cp/Cv) of the gas will be:

1 1.30

2 1.50

3 1.70

4 2
 NEET NEET
∘
A(g) + B(g) → C(g) Q15 Which one of the following has ΔS greater
Yakeen NEET 2.0 2025(Alpha) ΔU = −3.0 kcal ΔS = −10.0 cal/K than zero?
(R ≈ 2 calmol−1 K−1 ) (A) CaO(s) + CO2 ( g) ⇌ CaCO3 ( s)
Physical Chemistry (B) NaCl(aq) ⇌ NaCl(s)
DPP: 6
ΔG is (C) NaNO3 ( s) ⇌ Na+ (aq) + NO− 3 (aq)
Thermodynamics and Thermochemistry (A) −600 cal (D) N2 ( g) + 3H2 ( g) ⇌ 2NH3 ( g)
(B) −3600 cal
Q1 5 mole of an ideal gas expand reversibly from (A) Entropy increases Q16 The entropy of vaporization of benzene is
(C) 2400 cal
a volume of 8dm3 to 80dm3 at a temperature (B) Entropy decreases
(D) 3000 cal
85JK−1 mol−1 . When 117 g benzene vaporizes
of 27∘ C . The change in entropy is (C) Entropy increases and then decreases at its normal boiling point, the entropy change of
−1 Q11 Mark the correct statement
(A) 41.57JK (D) Free energy increases surrounding is :
(B) −95.73JK
−1 (A) For a chemical reaction to be feasible, ΔG (A) −85 J/K
Q6 Which of the following is true for the reaction?
(C) 95.73JK−1 should be zero (B) −85 × 1.5 J/K
H2 O(ℓ) ⇌ H2 O(g) at 100∘ C and 1 atm
(D) −41.57JK−1 (B) Entropy is a measure of order in a system (C) 85 × 1.55 J/K
pressure
(C) For a chemical reaction to be feasible, ΔG (D) None of these
Q2 Which of the following conditions is not (A) ΔS=0 should be positive
favourable for the feasibility of a process? (B) ΔH = TΔS
(D) The total energy of an isolated system is
Q17 1 mole of a diatomic ideal gas at 25∘ C is
(A) ΔH = −ve, TΔS = − ve and (C) ΔH = ΔU subjected to expand reversibly and adiabatically
constant
TΔS < ΔH (D) ΔH = 0 to ten times of its initial volume. Calculate the
(B) ΔH = + ve, TΔS = + ve and Q12 Two molecules of an ideal gas expand change in entropy during expansion (in
Q7 For a reaction to be spontaneous at all
TΔS > ΔH spontaneously into a vacuum. The work done is JK−1 mol−1 )
temperatures
(C) ΔH = − ve, TΔS = + ve and (A) 2J (A) R ln 10
(A) ΔG and ΔH should be negative
ΔH > TΔS (B) 4 J (B) −R ln 10
(B) ΔH = ΔG = 0
(D) ΔH = + ve, TΔS = + ve and (C) 8 J (C) 2.5R ln 10
(C) ΔG and ΔH should be positive
ΔH > TΔS (D) Zero (D) zero
(D) ΔH < ΔG
Q3 In which of the following cases, the reaction is Q13 Predict which of the following reaction (s) has a Q18 Three moles of an ideal gas expanded
Q8 For isothermal expansion in case of an ideal gas:
spontaneous at all temperatures? positive entropy change. spontaneously in to vacuum. Then which is
(A) ΔG = ΔS +
(A) ΔH > 0, ΔS > 0 I. Ag (aq) + Cl− (aq) → AgCl(s) correct?
(B) ΔG = ΔH
(B) ΔH < 0, ΔS > 0 II. NH4 Cl(s) → NH3 ( g) + HCl(g) (A) W = 0, ΔG = 0
(C) ΔG = −T. ΔS
(C) ΔH < 0, ΔS < 0 III. 2NH3 ( g) → N2 ( g) + 3H2 ( g) (B) W = 0, ΔG < 0
(D) None of these
(D) ΔH > 0, ΔS < 0 (A) I and II (B) III (C) W = 0, ΔG > 0
Q9 A reaction has ΔH = −33 kJ and (C) II and III (D) II (D) W ≠ 0, ΔG = 0
Q4 For an endothermic reaction, ΔS is positive. The
ΔS = −58 J/K. This reaction would be: Q14 Which of the following reactions is associated
reaction is: Q19 Match the following in List-I with List-II and select
(A) Spontaneous below a certain temperature
(A) Feasible when TΔS > ΔH with negative change in entropy? the correct option:
(B) Non-spontaneous at all temperature
(B) Feasible when ΔH > TΔS (A) 2SO3 ( g) → 2SO2 ( g) + O2 ( g)
(C) Spontaneous above a certain temperature
(C) Feasible at all temperatures (B) C2 H6 ( g) → C2 H4 ( g) + H2 ( g)
(D) Spontaneous at all temperature
(D) Not feasible at all (C) 2C (s , graphite) +O2 ( g) → 2CO(g)
Q10 For the reaction at 300 K. (D) 3C2 H2 ( g) → C6 H6 (l)
Q5 When potassium chloride is dissolved in water

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 NEET NEET

The entropy of fusion of water is Q28 Which of the following thermodynamic

5.260Cal/molK. calculate the enthalpy of properties must be associated with a reaction
fusion of water? spontaneous at only high temperatures
(A) 10.52kCal/mol (A) ΔH < 0, ΔS < 0
(B) 0.525kCal/mol (B) ΔH < 0, ΔS > 0
(C) 2.225kCal/mol (C) ΔH > 0, ΔS > 0
(D) 1.435kCal/mol (D) ΔH > 0, ΔS < 0
(A) a-iii, b-iv, c-i, d-ii
(B) a-i, b-iii, c-ii, d-iv Q24 The value of ΔH and ΔS for the reaction Q29 A + B −−−→ C + D
(C) a-iii, b-i, c-iv, d-ii Cgraphite + O2 ( g) → CO2 ( g) are −100 kJ ΔH = −10, 000 J mol−1
(D) a-iii, b-ii, c-i, d-iv and −100JK−1 respectively. The reaction will ΔS = −33. 3 J K−1 mol−1
be spontaneous at: At what temperature the reaction will occur
Q20 For the reaction 2Cl(g) → Cl2 ( g) (A) 1000 K spontaneous from left to right?
What are the sign of ΔH and ΔS ? (B) 900 K (A) = 300.3 K
(A) ΔH > 0, ΔS > 0 (C) 1100 K (B) > 300.3 K
(B) ΔH < 0, ΔS < 0 (D) At any temperature (C) < 300.3 K
(C) ΔH > 0, ΔS < 0 (D) None of these
(D) ΔH < 0, ΔS > 0 Q25 Criteria for spontaneity of process is:
(A) Maximum Randomness Q30 The entropy of vaporization of benzene is
Q21 For a spontaneous process (B) Maximum energy 85JK−1 mol−1 . When 117 g benzene vaporizes
(A) ΔG =0 (C) Minimum energy and max. randomness at its normal boiling point, the entropy change of
(B) ΔG < 0 (D) Minimum randomness and max. energy surrounding is :
(C) ΔG > 0 (A) −85 J/K
(D) Any of the above Q26 Standard entropy of N2 , H2 and NH3 are 60,40
−1 (B) −85 × 1.5 J/K
and 50JK mol−1 respectively.
(C) 85 × 1.55 J/K
Q22 Match the column: For the reaction 1/2 N2 +
(D) None of these
3/2H2 ⇌ NH3 , ΔH = −30 kJ to be at
equilibrium, the temperature should be: Q31 Which of the following condition regarding a
(A) 500 K chemical process ensures spontaneity at all
(B) 750 K temp.?
(C) 1000 K (A) ΔH < 0, ΔS > 0
(D) 1250 K (B) ΔH > 0, ΔS < 0
(C) ΔH < 0, ΔS < 0
Q27 Which of the following is correct for a
(D) ΔH > 0, ΔS > 0
spontaneous process?
(A) A → P, B → R, C → Q, D → S (A) ΔH < 0, ΔS > 0 at all possible
(B) A → R, B → P, C → Q, D → S temperature
(C) A → Q, B → R, C → P, D → S (B) ΔG > 0
(D) A → P, B → Q, C → R, D → S (C) ΔS > 0
(D) Ecell < 0
Q23

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 NEET

Answer Key
Q1 (C) Q17 (D)

Q2 (D) Q18 (B)

Q3 (B) Q19 (A)

Q4 (A) Q20 (B)

Q5 (A) Q21 (B)

Q6 (B) Q22 (A)

Q7 (A) Q23 (D)

Q8 (C) Q24 (B)

Q9 (A) Q25 (C)

Q10 (A) Q26 (B)

Q11

Q12
(D)

(D)
Q27

Q28
(A)

(C)
DPP SOLUTION
Q13 (C) Q29 (C)

Q14 (D) Q30 (B)

Q15 (C) Q31 (A) • Subject – Physical Chemistry

Q16 (B)

• Chapter – Thermodynamics and

Android App | iOS App | PW Website Thermochemistry

DPP No.- 07 By – Sudhanshu Sir

 Question Question

For a given reaction, H = 40 kJ mol–1 and S = 80 JK–1 mol–1. The reaction is A reaction occur spontaneously. If
spontaneous at (assume that H and S do not vary with temperature)
1 TS = H and both H and S are positive
1 T > 500

2 TS > H and both H and S are positive

2 T < 500

3 TS > H and both H and S are negative

3 All temperature

4 TS = H and both H is positive and S is negative

4 T > 298
 Question Question

Which of the following endothermic process is/are spontaneous? During an adiabatic process:

1 Melting of ice 1 Pressure is maintained constant

2 Evaporation of water 2 Gas is isothermally expanded

3 Heat of combustion 3 There is perfect heat insulation

4 Both (1) and (2) 4 The system changes heat with surroundings
 Question Question

The entropy of the universe Which of the following has highest entropy?

1 Tends towards a maximum 1 Mercury

2 Tends towards a minimum 2 Hydrogen

3 Tends to be zero 3 Water

4 Remains constant 4 Graphite

 Question Question

Which of the following processes is not accompanied by increase of entropy? For a reversible process at equilibrium, the change in entropy may be expressed
as:
1 Dissolution of NH4Cl in water
1 S = Tqrev
2 Burning of rocket fuel
qrev
2 S =
T
3 Sublimation of dry ice
ΔH
3 S =
T
4 Condensing steam

4 S = G
 Question Question

Entropy is a measure of When a solid is converted directly into gaseous state, the process is called
sublimation. The entropy change during the process is:
1 Disorder
1 Zero
2 Internal energy
2 Negative
3 Efficiency
3 Positive
4 Useful work done by the system
4 May be negative or zero
 Question Question

The enthalpy of vaporisation of a compound AB at its boiling point (127°C) is 6.4 The entropy change for the conversion of 1 mol of -tin (at 13°C, 1 atm) to 1 mol of
kJ mol–1. Its entropy of vaporisation is: -tin (13°C, 1 atm), if enthalpy of transition is 2.095 kJ mol–1 is:
1 2.56 kJ mol–1 1 7.32 J mol–1 K–1

2 16 J mol–1 K–1 2 14.62 J K–1 mol–1

3 16 × 10–3 J mol–1 3 56.3 J mol–1 K–1

4 1.6 × 103 kJ mol–1 4 0

 Question Question

The following data is known about the melting of a compound AB. H = 9.2 kJ 𝟓
When two mole of an ideal gas 𝐂𝐩,𝐦 = 𝐑 heated from 300 K to 600 K at constant
mol–1. S = 0.008 kJ K–1 mo1–1. Its melting point is: 𝟐
pressure. The change in entropy of gas (S) is:
1 736 K
3
1 R𝓁n2
2

2 1050 K
3
2 – R𝓁n2
2
3 1150 K
3 5R𝓁n2
4 1150C
5
4 R𝓁n2
2
 Question Question

𝟑
When two mole of an ideal gas 𝐂𝐯 = 𝐑 heated from 300 K to 600 K at constant The entropy change when two moles of ideal monoatomic gas is heated from
𝟐
200°C to 300°C reversibly and isochorically?
volume. The change in entropy of gas (S) is:
1 5Rln2 1

3
2 𝑅𝓁𝑛2 2
2

3 3Rln2
3

4 –3Rln2
4
 Question Question

𝟓
If one mole of an ideal gas 𝐂𝐩.𝐦. = 𝐑 is expanded isothermally at 300 K until it's When one mole of an ideal gas is compressed to half of its initial volume and
𝟐
simultaneously heated to twice its initial temperature, the change in entropy of
volume is tripled, then change in entropy of gas is:
gas (S) is:
1 Zero
1 Cp ln2

2 Infinity
2 Cv ln2
5
3 𝑅𝓁𝑛3
2 3 Rln2

4 R ln3 4 (Cv – R)ln2

 Question Question

Theheat of combustion of ethanol determined in a bomb calorimeter is –670.48 From the reaction P(White) → P(Red);
Kcals mole–1 at 25°C. What is ∆H at 25°C for the reaction: ∆H = –18.4 KJ. It follows that:

1 –335.24 Kcals. 1 Red P is readily formed from white P

2 –671.08 Kcals. 2 White P is readily formed from red P

3 –670.48 Kcals. 3 White P can not be converted to red P

4 +670.48 Kcals. 4 White P can be converted into red P and red P is more stable
 Question Question

Since the enthalpy of the elements in their standard states is taken to be zero. The Which of the following equations represents standard heat of formation of CH4?
heat of formation (∆Hf ) of compounds:
1 C(diamond) + 2H2(g) → CH4(g)
1 Is always negative
2 C(graphite) + 2H2(g) → CH4(g)
2 Is always positive
3 C(diamond) + 4H2(g) → CH4(g)
3 Is zero
4 C(graphite) + 4H2(g) → CH4(g)
4 May be positive or negative
 Question Question
Given enthalpy of formation of CO2(g) and CaO(s) are –94.0 KJ and –152 KJ The enthalpies of combustion of carbon and carbon monoxide are –393.5 KJ and
respectively and the enthalpy of the reaction: –283 KJ, respectively the enthalpy of formation of carbon monoxide is:
CaCO3(s) → CaO(s) + CO2(g) is 42 KJ.
1 –676.5 KJ
The enthalpy of formation of CaCO3(s) is

1 –42 KJ 2 –110.5 KJ

2 –202 KJ 3 110.5 KJ

3 +202 KJ 4 676.5 KJ

4 –288 KJ
 Question Question
The heat of combustion of CH4(g), C(s) and H2(g) at 25°C are –212.4 Kcal, –94.0 Standard enthalpy of formation is zero for.
Kcal and –68.4 Kcal respectively, the heat of formation of CH4 will be-
1 Cdiamond
1 +54.4 Kcal
2 Br(g)
2 –18.4 Kcal
3 Cgraphite
3 –375.2 Kcal
4 O3(g)
4 +212.8 Kcal
 Question Question
Heat of formation of CO2 is –94.0 Kcal. What would be the quantity of heat If S + O2 → SO2; ∆H = –298.2 kJ mol–1
𝟏
liberated, when 3 g of graphite is burnt in excess of oxygen: SO2 + O2 → SO3; ∆H = –98.7 kJ mol–1
𝟐
1 23.5 Kcals SO3 + H2O → H2SO4; ∆H = –130.2 kJ mol–1
𝟏
H2 + O2 → H2O; ∆H = –287.3 kJ mol–1
𝟐
Then the enthalpy of formation of H2SO4 at 298 K will be–
2 2.35 Kcals
1 –814.4 kJ mol–1
3 94.0 Kcals
2 –650.3 kJ mol–1
4 31.3 Kcals
3 –320.5 kJ mol–1

4 –433.5 kJ mol–1
 Question Question
𝟏 𝟏
The heat of reaction for 𝐀 + 𝐎𝟐 → 𝐀𝐎 is –50 kcal/mol and 𝐀𝐎 + 𝐎𝟐 → 𝐀𝐎𝟐 is Which of the reaction defines molar ∆Hf°?
𝟐 𝟐
100 kcal/mol. The heat of reaction (in kcal/mol) for A + O2 → AO2 will be: 1 CaO(s) + CO2(g) → CaCO3(s)

1 –50
1 1
2 Br2 (g) + H2 (g) → HBr(g)
2 2
2 +50
3
3 N2(g) + 2H2 (g) + O2 (g) → NH4 NO3 (s)
2
3 100
4 I2(g) + H2(g) → 2HI(g)
4 150
 Question Question
The enthalpy of formation of ammonia is –46.0 kJ mol–1. The enthalpy change for The molar heat of combustion of C6H6 is –3250 kJ mol–1. When 0.39 g of C6H6 is
following reaction is 2NH3 → N2 + 3H2 burnt in excess of oxygen in an open vessel, the amount of heat evolved is:

1 42.0 kJ mol–1 1 8.32 kJ

2 64.0 kJ mol–1 2 12.36 kJ

3 86.0 kJ mol–1 3 16.25 kJ

4 92.0 kJ mol–1 4 20.74 kJ

 Question Question
The enthalpy and entropy change for the reaction, Br2(l) + Cl2(g) → 2BrCl(g) are Assume each reaction is carried in open container. For which reaction H > E?
30 kJ mol–1 and 105 JK–1 mol–1 respectively. The temperature at which the reaction
will be in equilibrium is: 1 H2(g) + I2(g) → 2HI(g)

1 285.7 K
2 N2(g) + 3H2(g) → 2NH3(g)

2 273 K
3 PCl5(g) → PCl3(g) + Cl2(g)

3 450 K
4 SO2(g) + 1/2O2(g) → SO3(g)

4 300 K
 Question Question
The following reactions are given : U° of combustion of methane is –X kJ mol–1. The value of H° is:
CH4(g) + 2O2(g) → CO2(g) 2H2O(g); H = –x …(i)
1 –X –596 R
C(s) + O2(g) → CO2(g); H = –y …(ii)
H2(g) + 1/2O2(g) → H2O(g); H = –z ...(iii)
Calculate the heat of formation of CH4? 2 –X + 596 R

1 x+y+z
3 X + 596 R

2 y + 2z – x
4 X – 596 R

3 x – y – 2z

4 None of the above

 Question
Consider the following process:
A → 2B; H = +150 kJ
3B → 2C + D; H = –125 kJ
G + A → 2D; H = +350 kJ
For B + D → G + 2C; H will be

1 +525 kJ

2 +325 kJ

3 –175 kJ

4 –325 kJ
 NEET NEET

(D) May be negative or zero Q16 The entropy change when two moles of ideal
Yakeen NEET 2.0 2025(Alpha) monoatomic gas is heated from 200∘ C to
Q11 The enthalpy of vaporisation of a compound AB ∘
300 C reversibly and isochorically?
Physical Chemistry at its boiling point (127
∘
C) is 6.4 kJ mol−1 . Its (A) 32 Rℓn ( 300 )
DPP: 7 entropy of vaporisation is:
200
(B) 52 Rℓn ( 573 )
Thermodynamics and Thermochemistry (A) 2.56 kJ mol−1 273
(C) 3R ln( 573 )
(B) 16 J mol−1 K−1 473
(D) 32 Rℓn ( 573 )
Q1 For a given reaction,ΔH = 40 kJ mol−1 and (B) Tends towards a minimum (C) 16 × 10−3 J mol−1 473

ΔS = 80 JK mol−1 . The reaction is

−1 (C) Tends to be zero (D) 1.6 × 103 kJ mol−1 Q17 If one mole of an ideal gas (Cp.m. = 52 R)
spontaneous at (assume that ΔH and ΔS do (D) Remains constant
is expanded isothermally at 300 K until its
not vary with temperature) Q12 The entropy change for the conversion of1 mol
Q6 Which of the following has highest entropy? volume is tripled, then change in entropy of gas
(A) T > 500 of α-tin (at 13∘ C, 1 atm) to 1 mol of β -tin
(A) Mercury (B) Hydrogen is:
(B) T < 500 (13∘ C, 1 atm), if enthalpy of transition is
(C) Water (D) Graphite (A) Zero
(C) All temperature 2.095 kJ mol−1 is
(B) Infinity
(D) T > 298 Q7 Which of the following processes is (A) 7.32 J mol−1 K−1
(C) 5 Rℓn3
not accompanied by increase of entropy? (B) 14.62 J K−1 mol−1 2
Q2 A reaction occur spontaneously. If (D) R ln 3
(A) Dissolution of NH4 Cl in water (C) 56.3 J mol−1 K−1
(A) TΔS = ΔH and both ΔH and ΔS are
(B) Burning of rocket fuel (D) 0 Q18 When one mole of an ideal gas is compressed to
positive
(C) Sublimation of dry ice half of its initial volume and simultaneously
(B) TΔS > ΔH and both ΔH and ΔS are Q13 The following data is known about the melting of
(D) Condensing steam heated to twice its initial temperature, the
positive a compound AB. ΔH = 9.2 kJ mol−1 . ΔS
change in entropy of gas (ΔS) is:
(C) TΔS > ΔH and both ΔH and ΔS are Q8 For a reversible process at equilibrium, the = 0.008 kJ K−1 (A) Cp ln 2
−1
negative mol . Its melting point is:
change in entropy may be expressed as : (B) CV ln 2
(D) TΔS = ΔH and both ΔH is positive and (A) 736 K
(A) ΔS = Tqrev (C) R ln 2
ΔS is negative qrev (B) 1050 K
(B) ΔS = T (D) (CV − R) ln 2
(C) 1150 K
(C) ΔS = ΔH
Q3 Which of the following endothermic process T (D) 1150∘ C Q19 The heat of combustion of ethanol determined in
(D) ΔS = ΔG
is/are spontaneous?
a bomb calorimeter is −670.48 K. Cals mole−1
(A) Melting of ice Q14 When two mole of an ideal gas (Cp,m = 52 R) ∘
Q9 Entropy is a measure of at 25 C.
(B) Evaporation of water heated from 300 K to 600 K at constant
(A) Disorder What is ΔH at 25∘ C for the reaction:
(C) Heat of combustion pressure. The change in entropy of gas (ΔS) is:
(B) Internal energy (A) −335.24 K. Cals.
(D) Both (1) and (2) (A) 32 R ln 2
(C) Efficiency (B) −671.08 K. Cals.
(B) − 3 R ln 2
(D) Useful work done by the system 2 (C) −670.48 K Cals.
Q4 During an adiabatic process: (C) 5R ln 2
(A) Pressure is maintained constant (D) +670.48 K. Cals.
Q10 When a solid is converted directly into (D) 5 R ln 2
2
(B) Gas is isothermally expanded gaseous state, the process is called sublimation. Q20 From the reaction P( White )→ P( Red );
(C) There is perfect heat insulation The entropy change during the process is:
Q15 When two mole of an ideal gas (Cv = 32 R)
ΔH = −18.4KJ. It follows that:-
(D) The system changes heat with surroundings (A) Zero heated from 300 K to 600 K at constant
(A) Red P is readily formed from white P
(B) Negative volume. The change in entropy of gas (ΔS) is:
Q5 The entropy of the universe (B) White P is readily formed from red P
(C) Positive (A) 5 Rln 2 (B) 3 Rln 2
(A) Tends towards a maximum
2 (C) White P can not be converted to red P
(C) 3 Rln 2 (D) −3 Rln 2

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 NEET NEET
∘
(D) White P can be converted into red P and red (A) +54.4 Kcal Q30 Which of the reaction defines molar ΔHf ? Q35 The following reactions are given :
P is more stable (B) −18.4Kcal (A) CaO(s) + CO2 ( g) → CaCO3 ( s)
CH4 ( g) + 2O2 ( g) → CO2 ( g)2H2 O(g);
(C) −375.2 Kcal (B) 12 Br2 ( g) + 12 H2 ( g) → HBr(g)
Q21 Since the enthalpy of the elements in their ΔH = −x … (i)
(D) +212.8 Kcal (C) N2 ( g) + 2H2 ( g) + 32 O2 ( g)
standard states is taken to be zero. The heat of C(s) + O2 ( g) → CO2 ( g); ΔH = −y
formation (ΔHf ) of compounds: Q26 Standard enthalpy of formation is zero for
→ NH4 NO3 ( s)
(D) I2 ( g) + H2 ( g) → 2HI(g) … (ii)
(A) Is always negative (A) Cdiamond
H2 ( g) + 1/2O2 ( g) → H2 O(g); ΔH = −z
(B) Is always positive (B) Br(g) Q31 The enthalpy of formation of ammonia is … (iii)
(C) Is zero (C) Cgraphite −46.0 kJ mol−1 . The enthalpy change for
(D) May be positive or negative (D) O3(g) following reaction is 2NH3 → N2 + 3H2 Calculate the heat of formation of CH4 ?
(A) 42.0 kJ mol−1 (A) x + y + z
Q22 Which of the following equations represents Q27 Heat of formation of CO2 is −94.0 K. cal. What
(B) 64.0 kJ mol m−1 (B) y + 2z − x
standard heat of formation of CH4 ? would be the quantity of heat liberated, when
(C) 86.0 kJ mol−1 (C) x − y − 2z
(A) C(diamond) + 2H2 ( g) → CH4 ( g) 3 g of graphite is burnt in excess of oxygen:-
(D) 92.0 kJ mol−1 (D) none of the above
(B) C(graphite) + 2H2 ( g) → CH4 ( g) (A) 23.5 K cals
(C) C(diamond) + 4H2 ( g) → CH4 ( g) (B) 2.35 K cals Q32 The molar heat of combustion of C6 H6 is Q36 ΔU∘ of combustion of methane is
(D) C(graphite) + 4H2 ( g) → CH4 ( g) (C) 94.0 K cals −3250 kJ mol−1 . When 0.39 g of C6 H6 is −XkJmol−1 . The value of ΔH∘ is:
(D) 31.3 K cals burnt in excess of oxygen in an open vessel, the (A) −X − 596R
Q23 Given enthalpy of formation of CO2 ( g) and (B) −X + 596R
−1 amount of heat evolved is:
CaO(s) are −94.0KJ and −152KJ Q28 If S + O2 → SO2 ; ΔH = −298.2 kJ mol
(A) 8.32 kJ (C) X + 596R
respectively and the enthalpy of the reaction: 1
SO2 + O2 → SO3 ; ΔH = (B) 12.36 kJ (D) X − 596R
CaCO3 ( s) → CaO(s) + CO2 ( g) is 42KJ. 2
(C) 16.25 kJ
The enthalpy of formation of CaCO3 ( s) is −98.7 kJ mol−1 Q37 Consider the following process:
SO3 + H2 O → H2 SO4 ; ΔH = (D) 20.74 kJ
(A) −42KJ A → 2 B; ΔH = +150 kJ
(B) −202KJ −130.2 kJ mol−1 Q33 The enthalpy and entropy change for the 3 B → 2C + D; ΔH = −125 kJ
(C) +202KJ 1 G + A → 2D; ΔH = +350 kJ
H2 + O2 → H2 O; ΔH = reaction,Br2 (l) + Cl2 ( g) → 2BrCl(g) are
(D) −288KJ 2 For B + D → G + 2C; ΔH will be
30 kJ mol−1 and 105 Jk−1 mol−1 respectively.
−287.3 kJ mol−1 (A) +525 kJ
The temperature at which the reaction will be in
Q24 The enthalpies of combustion of carbon and Then the enthalpy of formation of H2 SO4 at (B) +325 kJ
equilibrium is:
carbon monoxide are −393.5KJ and −283KJ , 298 K will be- (C) −175 kJ
(A) 285.7 K
respectively the enthalpy of formation of carbon (A) −814.4 kJ mol − 1 (D) −325 kJ
(B) 273 K
monoxide is (B) −650.3 kJ mol−1
(C) 450 K
(A) −676.5KJ (C) −320.5 kJ mol−1
(D) 300 K
(B) −110.5KJ (D) −433.5 kJ mol−1
(C) 110.5KJ Q34 Assume each reaction is carried in open
Q29 The heat of reaction for A + 12 O2 → AO is
(D) 676.5KJ container. For which reaction ΔH
> ΔE ?
−50kcal/mol and AO + 12 O2 → AO2 is
(A) H2 ( g) + I2 ( g) → 2HI(g)
Q25 The heat of combustion of CH4( g) , C(s) and 100kcal/mol. The heat of reaction (in
(B) N2 ( g) + 3H2 ( g) → 2NH3 ( g)
H2( g) at 25∘ C are −212.4 Kcal, −94.0 Kcal kcal/mol ) for A + O2 → AO2 will be:
(C) PCl5 ( g) → PCl3 ( g) + Cl2 ( g)
and −68.4 Kcal respectively, the heat of (A) -50 (B) +50
(D) SO2 ( g) + 1/2O2 ( g) → SO3 ( g)
formation of CH4 will be- (C) 100 (D) 150

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 NEET NEET

Answer Key Yakeen NEET 2.0 2025 (Alpha)

Q1 (A) Q20 (D) Physical Chemistry
Q2 (B) Q21 (D) DPP: 9
Thermodynamics and Thermochemistry
Q3 (D) Q22 (B)

Q4 (C) Q23 (D) Q1 The heat of combustion of CH4 is ethanol at the same temp. and constant volume

Q5 (A) Q24 (B) −400 kJ mol−1 . will be :

Calculate the heat transfer when 40 g of H2 O is (A) RT − q
Q6 (B) Q25 (B)
formed upon combustion: (B) −q − RT
Q7 (D) Q26 (C) (A) +444.4 kJ (C) q − RT
(B) +888.8 kJ (D) q + RT
Q8 (B) Q27 (A)
(C) −444.4 kJ
Q9 (A) Q28 (A) Q6 For the combustion of 1 mole of liquid benzene
(D) −888.8 kJ
at 27∘ C , the heat of reaction at const. pressure is
Q10 (C) Q29 (B) 1
Q2 CH4 + O
→ CH3 OH; ΔH = −ve
2 2
given by
Q11 (B) Q30 (C) CH4 and CH3 OH
If enthalpy of combustion of C6 H6 (l) + 15/2O2 ( g) ⟶ 6CO2 ( g)
Q12 (A) Q31 (D) is −x & − y respectively which relation is + 3H2 O(l)
correct? ΔH = −78 kcal. What would be the heat of
Q13 (C) Q32 (C)
(A) x >y (B) x <y reaction at const. volume?
Q14 (C) Q33 (A) (C) x =y (D) x ≥y (A) −78.0 kcal
Q15 (C) Q34 (C) (B) −78.9 kcal
Q3 The heat of neutralization of LiOH and H2 SO4
(C) −77.1 kcal
Q16 (C) Q35 (C) at 25∘ C is −69.6 kJ mol−1 . The heat of
(D) 816.0 kcal
ionization of LiOH will be nearly :
Q17 (D) Q36 (A)
(A) 22.5 kJ mol − 1 Q7 Enthalpies of formation of C2 H4 ( g), CO2 ( g)
Q18 (D) Q37 (D) (B) 90 kJ mol−1 and H2 O at 25∘ C and 1 atm pressure be
Q19 (B) (C) 45 kJ mol−1 52, −394 and −286 kJ mol−1 respectively.
(D) 33.6 kJ mol−1 The enthalpy of combustion of C2 H4 ( g) will be:
(A) +1412 kJ mol−1
Q4 Na(s) ⟶ Na(g) , the heat of reaction is called (B) −1412 kJ mol−1
Android App | iOS App | PW Website as (C) +141.2 kJ mol−1
(A) Heat of vaporisation (D) −141.2 kJ mol−1
(B) Heat of atomisation
(C) Heat of sublimation Q8 In which of the following neutralization
(D) Both (B) and (C) reactions,the heat of neutralization will be the
highest?
Q5 Heat of combustion of ethanol at const. pressure (A) NH4 OH and CH3 COOH
and at temp. TK in found to be −qJmol−1 . (B) NH4 OH and HCl
−1
Hence, heat of combustion in (Jmol ) of (C) NaOH and CH3 COOH

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 NEET NEET

(D) NaOH and HCl Q14 On combustion, carbon forms two oxides CO The standard Gibbs energy of reaction (at At absolute zero temp. the entropy of all
and CO2 . Heat of formation of CO2 is 1000 K ) is −8.1 kJ mol−1 . Value of crystalline substance is taken be zero
Q9 Heat of combustion of a substance:
−393.5 kJ and that of CO is −110.5 kJ . Heat equilibrium constant is- (D) At absolute zero temp. the entropy of a
(A) is always positive
of combustion of CO is: (A) 2.6 (B) 6.2 perfectly crystalline solid is taken to be zero.
(B) is always negative
(A) −393.5 kJ (C) 8.2 (D) 10
(C) is equal to heat of formation
(B) −504.0 kJ
(D) Nothing can be said without reaction Q20 Calculate the Gibbs energy change when 1 mole
(C) −283.0 kJ
of NaCl is dissolved in water at 25∘ C . Lattice
Q10 The heat of formations of CO(g) and CO2 ( g) (D) 2830.0 kJ −1
energy of NaCl = 777.8 kJ mol ; ΔS for
are- 26.4kcal and −94.0kcal respectively. The
Q15 The equilibrium constant for a reaction is 100 dissolution = 0.043 kJmol−1 and hydration
heat of combustion of carbon monoxide will be
what will be the value of ΔG∘ ? energy of NaCl = −774.1 kJ mol−1 .
(A) −67.6kcal
R = 8.314JK−1 mol−1 , T = 300 K : (A) −9.114 kJ mol−1
(B) 36.5kcal
(A) −11488 kJ (B) −11.4 kJ mol−1
(C) −36.5kcal
(B) −11.488 kJ (C) −5.4 kJ mol−1
(D) −46.5kcal
(C) −12 kJ (D) −4.5 kJ mol−1
Q11 Which of the following statement is true? (D) −12000 kJ
Q21 For vaporization of water at 1 atm pressure, the
(A) ΔH is positive for exothermic reactions
Q16 For the reaction: N2 O4 (g)
⇌ 2 NO2 (g) values of ΔH and ΔS are 40.63 kJ mol−1 and
(B) ΔH is negative for endothermic reactions
ΔU = 2. 0 Kcal, Δ S = 50 cal K−1 at 108.8 JK −1
mol −1
respectively. The temp. at
(C) The enthalpy of fusion is negative
300 K which Gibbs energy change (ΔG) for this
(D) The heat of neutralization of strong acid with
Calculate ΔG transformation will be zero is:
strong base is always the same
(A) +12.4 kcal (A) 273.4 K
Q12 Given (B) −12.4 kcal (B) 393.4 K
(C) −6.4 kcal (C) 373.4 K
H2 ( g) + 1/2O2 ( g) → H2 O(g) + q1 (D) +6.4 kcal (D) 293.4 K
H2 ( g) + 1/2O2 ( g) → H2 O(l) + q2
Q17 Which relation is incorrect: Q22 Calculate ΔG∘ for the conversion of oxygen
The enthalpy of vaporization of water is equal to (A) ΔG = −TΔST to ozone, 3/2O2 ( g) ⟶ O3 ( g) at 298 K . If
(A) q1 + q2 (B) ΔG∘ = −2.303 RT log K KP for this conversion is 3 × 10−29 .
(B) q1 − q2 (C) ΔH = ΔU + Δng RT (A) +175.3 kJ mol−1
(C) q2 − q1 (D) Wuseful = ΔH (B) +162.7 kJ mol−1
(D) q1 q2 (C) −162.7 kJ mol−1
Q18 Which is always correct at equilibrium
∘ (D) −140.5 kJ mol−1
Q13 (A) ΔG =0
(B) ΔG = 0 Q23 Identify the correct statement regarding entropy.
(C) ΔSsystem = 0 (A) At 0∘ C , the entropy of a perfectly crystalline
(D) ΔE = 0 substance is taken to be zero.
(A) x + y (B) At absolute zeró temp. the entropy of a
Q19 For the water gas reaction
(B) x−y perfectly crystalline solid is positive.
(C) y − x C(s) + H2 O(g) ⇌ CO(g) + H2 ( g) (C)
(D) x − y/2

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 NEET

Answer Key
Q1 (C) Q13 (C)

Q2 (A) Q14 (C)

Q3 (A) Q15 (B)

Q4 (D) Q16 (B)

Q5 (A) Q17 (D)

Q6 (C) Q18 (B)

Q7 (B) Q19 (A)

Q8 (D) Q20 (A)

Q9 (B) Q21 (C)

Q10 (A) Q22 (B)

Q11

Q12
(D)

(C)
Q23 (D)
DPP SOLUTION
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• Subject – Physical Chemistry

• Chapter – Thermodynamics and

Thermochemistry

DPP No.- 08 By – Sudhanshu Sir

 Question Question

Enthalpy of neutralisation of CH3COOH by NaOH is –50.6 kJ/mol and the heat of If heat of dissociation of CHCl2COOH is 0.7 kcal/mol then ∆H for the reaction
neutralisation of a strong acid with NaOH is –55.9 kJ/mol. The value of ∆H for the CHCl2COOH + KOH → CHCl2COOK + H2O
ionisation of CH3COOH is
1 –13 kcal
1 3.5 kJ/mol
2 +13 kcal
2 4.6 kJ/mol
3 –14.4 kcal
3 5.3 kJ/mol
4 –13.7 kcal
4 6.4 kJ/mol
 Question Question

The bond dissociation energy of gaseous H2, Cl2 and HCl are 104, 58 and 103 kcal AB, A2 and B2 are diatomic molecules. If the bond enthalpies of A2, AB and B2 are
mol–1 respectively. The enthalpy of formation for HCl gas will be in the ratio 1 : 1 : 0.5 and enthalpy of formation of AB from A2 and B2 is – 100
kJ/mol–1. What is the bond enthalpy of A2?
1 –44.0 kcal
1 400 kJ/mol
2 –22.0 kcal
2 200 kJ/mol
3 22.0 kcal
3 100 kJ/mol
4 44.0 kcal
4 300 kJ/mol
 Question Question

Heat of combustion ∆Ho for C(s), H2(g) and CH4(g) are –94, –68 and –213 kcal/mol. If the bond energies of H–H, Br–Br and H–Br are 433, 192 and 364 kJ mol–1
Then, ∆Ho for respectively, then ∆Ho for the reaction H2(g) + Br2(g) → 2HBr(g) is
C(s) + 2H2(g) → CH4(g) is
1 –261 kJ
1 –17 kcal/mol
2 +103 kJ
2 –111 kcal/mol
3 +261 kJ
3 –170 kcal/mol
4 –103 kJ
4 –85 kcal/mol
 Question Question

The absolute enthalpy of neutralisation of the reaction, Given C(s) + O2(g) → CO2(g); H = –94.2 kcal
MgO(s) + 2HCl(aq) → MgCl2(aq) + H2O(l) will be H2(g) + 1/2O2(g) → H2O(g); H = –68.3 kcal
CH4(g) + 2O2(g) → CO2(g) + 2H2O(g);  H = –210.8 kcal
1 Less than –57.33 kJ mol–1
What will be heat of formation of CH4 in (kcal)?

2 –57.33 kJ mol–1 1 +45.9

3 Greater than –57.33 kJ mol–1 2 –20.0

4 57.33 kJ mol–1 3 +47.8

4 –47.3
 Question Question

From the given information, what is the standard enthalpy of formation for Consider the following reactions
Al2O3(s)? C(s) + O2(g) → CO2(g) + X kJ
2Al2O3(s) → 4Al(s) + 3O2(g); H°rxn = 3352 kJ CO(g) + 1/2O2(g) → CO2(g) + Y kJ
The heat of formation of CO(g) is
1 –6704 kJ/mol
1 –(X + Y) kJ/mol

2 –3352 kJ/mol
2 (X – Y) kJ/mol

3 –1676 kJ/mol
3 (Y – X) kJ/mol

4 1676 kJ/mol
4 (Y + X) kJ/mol
 Question Question

The enthalpy change for the following reaction is 368 kJ. Calculate the average N2(g) + 2O2(g) → 2NO2(g) + xkJ
O–F bond energy 2NO(g) + O2(g) → 2NO2(g) + ykJ
OF2(g) → O(g) + 2F(g) The enthalpy of formation of NO is

1 184 kJ/mol 1 x – 2y

368 kJ/mol 2 x–y

2

1
3 536 kJ/mol 3 (y – x)
2

4 736 kJ/mol 4
1
(x – y)
2
 Question Question

Consider the reaction: Use the given H°f value to determine enthalpy of reaction of the following
4NO2(g) + O2(g) → 2N2O5(g) rH = –111 kJ. If N2O5(s) is formed instead of N2O5(g) in reaction.
the above reaction the rH value will be (given DH of sublimation of N2O5 is 54 kJ NH3(g) + 3F2(g) → NF3(g) + 3HF(g)
mol–1) H°f (NH3, g) = –46.2 kJ/mol
H°f (NF3, g) = –113.0 kJ/mol
1 –219 kJ
H°f (HF, g) = –269.0 kJ/mol
1 –335.8 kJ/mol
2 –165 kJ

2 –873.8 kJ/mol
3 54 kJ

3 –697.2 kJ/mol
4 218 kJ

4 –890.4 kJ/mol
 Question Question

2 moles of an ideal gas is expanded isothermally and reversibly from 1 L to 10 L. When 0.5 g of sulphur is burnt to SO2, 4.6 kJ of heat is liberated. What is the
Find the enthalpy change in kJ mol–1. enthalpy of formation of Sulphur dioxide.

1 0 1 +147.2 kJ

2 11.7 2 –147 kJ

3 –11.7 3 –294.4 kJ

4 25 4 +294.4 kJ
 Question Question

The species which by definition has zero standard molar enthalpy of formation at The enthalpies of formation of N2O and NO at 298 K are 82 and 90 kJ mol–1. The
298 K is: enthalpy of the reaction:
Br2(g) N2O(g) + ½O2(g) → 2NO(g)
1
1 –8 kJ
2 Cl2(g)
2 98 kJ
3 H2O(g)
3 –74 kJ
4 CH4(g)
4 8 kJ
 Question Question

Calculate the heat required to make 6.4 Kg CaC2 from CaO(s) and C(s) from the The enthalpies of elements in their standard states are taken as zero. Hence the
reaction: enthalpy of formation of a compound
CaO(s) + 3C(s) → CaC2(s) + CO(g) given that fH°(CaO) = –151.6 kcal, fH° Should always be negative
1
(CaC2) = –14.2 kcal.
fH°(CO) = –26.4 kcal.
2 Should always be positive
1 5624 kcal
3 Will be equal to twice the energy of combination
2 1.11 × 104 kcal
4 May be positive or negative
3 86.24 × 103

4 1100 kcal
 Question Question

Which of the following equations represents standard heat of formation of For the reaction,
methane? 2H2O(l) → 2H2(g) + O2(g) H = 571.6 KJ
C (diamond) + 2H2(g) → CH4(g) fH° of water is:
1
1 285.8 kJ
2 C (graphite) + 2H2(g) → CH4(g)
2 –285.8 kJ
3 C (diamond) + 4H(g) → CH4(g)
3 1143.2 kJ
4 C (graphite) + 4H(g) → CH4(g)
4 –1143.2 kJ
 Question Question

Bond dissociation enthalpy is used to defining enthalpy change of a reaction as In which of the following case carbon-carbon bond dissociation energy is
maximum?
1 ΔHr = Σ(Bond dissociation enthalpy)Reactant – Σ(Bond dissociation enthalpy)Product
1 Ethane
2 ΔHr = Σ(Bond dissociation enthalpy)Product – Σ(Bond dissociation enthalpy)Reactant
2 Ethene
3 ΔHr = Σ(Bond dissociation enthalpy)Product + Σ(Bond dissociation enthalpy)Reactant
3 Butene
4 None of these
4 Ethyne
 Question Question

In which of the following case enthalpy of a reaction is just a bond dissociation Calculate ΔHreaction for
enthalpy of reactant? 𝟏 𝟏
H2 + Cl2 → HCl
𝟐 𝟐
1 PCl5 → PCl3 + Cl2 When bond dissociation enthalpy of H2, Cl2 and HCl is given as 433 kJ/mol, 243.5
kJ/mol and +431 kJ/mol respectively
2 H2 → 2H 1 –244.5 kJ/mol

1
3 H2O2 → H2O + O2 2 244.5 kJ/mol
2

4 CH2 = CH2 + H2 → C2H6 3 –92.75 kJ/mol

4 –93.25 kJ/mol
 Question Question

The enthalpy of dissociation of PH3 is 954 kJ/mol and that of P2H4 is 1.485 Which of the following acid has lowest value (magnitude) of heat neutralization?
MJ/mol. What is the bond enthalpy of P–P bond?
1 CH3COOH
1 213 kJ/mol
2 HCl
2 413 kJ/mol
3 HBr
3 200 kJ/mol
4 HI
4 Given data is incorrect
 Question Question

The enthalpy of neutralization of any strong acid and strong base is nearly equal The Enthalpy of neutralization of acetic acid and sodium hydroxide is –55.4kJ.
to What is the enthalpy of ionisation of acetic acid?
1 +57.3 kJ/mol 1 –5.54 kJ

2 –75.3 kJ/mol 2 +5.54 kJ

3 +75.3 kJ/mol 3 +1.9 kJ

4 –57.3 kJ/eq 4 –1.9 kJ

 Question Question

Heat of neutralization of strong acid by a strong base is equal to ΔH of In the heat released in neutralization of HCl and NaOH is 13.7 kcal/mol, the heat
released on neutralization of NaOH with CH3COOH is 3.7 kcal/mol. The H° of
1 H+ + OH– ⎯→ H2O
ionization of CH3OOOH is

H2O + H+ ⎯→ H3O+ 1 10.2 kcal

2

3 2H2 + O2 ⎯→ 2H2O 2 10 kcal

4 NH4OH + HCl ⎯→ NH4Cl + H2O 3 3.7 kcal

4 9.5 kcal
 Question Question
From the following bond energies:
Given that
H-H bond energy = 420 kJ mol–1
A(s) → A(l) H = x
CoC bond energy = 601 kJ mol–1
A(l) → A(g) H = y
C-C bond energy = 340 kJ mol–1
The heat of sublimation of A will be
C-H bond energy = 425 kJ mol–1
1 x–y Enthalpy for the reaction:
C2H2 + 2H2 → C2H6
2 x+y 1 –599 kJ mol–1

3 x or y 2 –580 kJ mol–1

4 –x + y 3 –625 kJ mol–1

4 –325 kJ mol–1
 Question Question

Consider the following reaction: Given that Bond energies of H2 and N2 are 400 kJ mol–1 and 240 kJ mol–1
(a) H+(aq) + Cl–(aq) → HCl(l) ; DH = –X1 kJ mol–1 respectively and Hf of NH3 is –120 kJ mol–1. Calculate the bond energy of N–H
(b) H2(g) + Cl2(g) → 2HCl(l) ; DH = –X2 kJ mol–1 bond:
(c) 1/2H2(g) + 1/2 Cl2(g) → HCl(l);DH = –X3 kJ mol–1
1 300 kJ mol–1
(d) H(g) + Cl(g) → HCl(l) ; DH = –X4 kJ mol–1
Enthalpy of formation of HCl(l) is:
2 250 kJ mol–1
1 –X1 kJ mol–1

3 410 kJ mol–1
2 –X2 kJ mol–1

4 280 kJ mol–1
3 –X3 kJ mol–1

4 –X4 kJ mol–1
 Question Question

Standard enthalpy of vapourisation H° for water is 40.66 kJ mol–1. The internal Enthalpy change for the reaction
energy of vapourisation of water will be: 2N (g) + 6H (g) → 2NH3 (g) is – 900 kJ
The dissociation energy of N – H bond is
1 +43.76 kJ mol–1
1 +450 kJ
2 +40.66 kJ mol–1
2 –450 kJ
3 +37.56 kJ mol–1
3 +150 kJ
4 None of these
4 –150 kJ
 DPP SOLUTION
• Subject – Physical Chemistry

• Chapter – Thermodynamics and

Thermochemistry

• DPP No.- 09 By – Sudhanshu Sir

 Question Question

The heat of combustion of CH3 is –400 kJ mol–1. Calculate the heat transfer when 𝟏
CH4 + O2 → CH3OH; H = –ve
𝟐
40 g of H2 is formed upon combustion:
If enthalpy of combustion of CH4 and CH3OH is –x & –y respectively which relation
1 +444.4 kJ is correct?

1 x>y
2 +888.8 kJ
2 x<y
3 –444.4 kJ
3 x=y
4 –888.8 kJ
4 xy
 Question Question

The heat of neutralization of LiOH and H2SO4 at 25°C is –69.6 kJ mol–1. The heat of Na(s) → Na(g), the heat of reaction is called as
ionization of LiOH will be nearly:
1 Heat of vaporisation
1 22.5 kJ mol–1

2 Heat of atomisation
2 90 kJ mol–1

3 Heat of sublimation
3 45 kJ mol–1

4 Both (2) and (3)

4 33.6 kJ mol–1
 Question Question

Heat of combustion of ethanol at const. pressure and at temp. TK in found to be For the combustion of 1 mole of liquid benzene at 27°C, the heat of reaction at
–q J mol–1. Hence, heat of combustion in (Jmol–1) of ethanol at the same temp. and const. pressure is given by
constant volume will be: C6H6(l) + 15/2O2(g) → 6CO2(g) + 3H2O(l)
H = –78 kcal. What would be heat of reaction at const. volume?
1 RT – q
1 –78.0 kcal
2 –q – RT
2 –78.9 kcal
3 q – RT
3 –77.1 kcal
4 q + RT
4 816.0 kcal
 Question Question

Enthalpies of formation of C2H4(g), CO2(g) and H2O at 25°C and 1 atm pressure be In which of the following neutralization reactions, the heat of neutralization will
52, –394 and –286 kJ mol–1 respectively. The enthalpy of combustion of C2H4(g) be the highest?
will be:
1 NH4OH and CH3COOH
1 +1412 kJ mol–1
2 NH4OH and HCl
2 –1412 kJ mol–1
3 NaOH and CH3COOH
3 +141.2 kJ mol–1
4 NaOH and HCl
4 –141.2 kJ mol–1
 Question Question

Heat of combustion of a substance: The heat of formations of CO(g) and CO2(g) are –26.4 kcal and –94.0 kcal
respectively.
1 Is always positive
The heat of combustion of carbon monoxide will be

2 Is always negative 1 –67.6 kcal

3 Is equal to heat of formation 2 36.5 kcal

4 Nothing can be said without reaction 3 –36.5 kcal

4 –46.5 kcal
 Question Question

Which of the following statement is true? Given

H2(g) + ½O2(g) → H2O(g) + q1
1 H is positive for exothermic reactions
H2(g) + ½O2(g) → H2O(l) + q2
The enthalpy of vaporisation of water is equal to
2 H is negative for endothermic reactions
1 q1 + q2

3 The enthalpy of fusion is negative

2 q1 – q2

4 The heat of neutralization of strong acid with strong base is always the same
3 q2 – q1

4 q1q2
 Question Question

If CH3COOH + OH– → CH3COO– + H2O + x kJ On combustion, carbon forms two oxides CO and CO2. Heat of formation of CO2 is
H+ + OH– → H2O + y kJ –393.5 kJ and that of CO is –110.5 kJ. Heat of combustion of CO is:
The enthalpy change for the reaction:
1 –393.5 kJ
CH3COOH → CH3COO– + H+ is

1 x+y 2 –504.0 kJ

2 x–y 3 –283.0 kJ

3 y–x 4 2830.0 kJ

4 x – y/2
 Question Question

The equilibrium constant for a reaction is 100 what will be the value of G°? For the reaction : N2O4(g) ⇌ 2NO2(g)
R = 8.314 JK–1 mol–1, T = 300 K: U = 2.0 kcal, S = 50 cal K–1 at 300 K calculate G?
1 –11488 kJ 1 +12.4 kcal

2 –11.488 kJ 2 –12.4 kcal

3 –12 kJ 3 –6.4 kcal

4 –12000 kJ 4 +6.4 kcal

 Question Question

Which relation is incorrect: Which is always correct at equilibrium:

1 G = –T ST 1 G° = 0

2 G° = –2.303 RT log K 2 G = 0

3 H = U + ngRT 3 Ssystem = 0

4 wuseful = H 4 E = 0
 Question Question

For the water gas reaction Calculate the Gibb’s energy change when 1 mole of NaCl is dissolved in water at
C(s) + H2O(g) ⇌ CO(g) + H2(g) 25°C. Lattice energy of NaCl = + 777.8 kJ mol–1; S for dissolution = 0.043 kJ mol–1
The standard Gibb’s energy of reaction (at 1000 K) is –8.1 kJ mol–1. Value of and hydration energy of NaCl = –774.1 kJ mol–1.
equilibrium constant is–
1 –9.114 kJ mol–1
1 2.6
2 –11.4 kJ mol–1
2 6.2
3 –5.4 kJ mol–1
3 8.2
4 –4.5 kJ mol–1
4 10
 Question Question

For vaporization of water at 1 atm pressure, the values of H and S are 40.63 kJ Calculate G° for the conversion of oxygen to ozone, 3/2O2(g) → O3(g) at 298 K. If
mol–1 and 108.8 JK–1 mol–1 respectively. The temp. at which Gibbs energy change KP for this conversion is 3 × 10–29.
(G) for this transformation will be zero is:
1 +175.3 kJ mol–1
1 273.4 K
2 +162.7 kJ mol–1
2 393.4 K
3 –162.7 kJ mol–1
3 373.4 K
4 –140.5 kJ mol–1
4 293.4 K
 Question

Identify the correct statement regarding entropy.

1 At 0°C, the entropy of a perfectly crystalline substance is taken to be zero.

2 At absolute zero temp. the entropy of a perfectly crystalline solid is positive.

3 At absolute zero temp. the entropy of all crystalline substance is taken be zero

4 At absolute zero temp. the entropy of a perfectly crystalline solid is taken to be

zero.