Ejaet 10 1 114 123
Ejaet 10 1 114 123
com
European Journal of Advances in Engineering and Technology, 2023, 10(1):114-123
ABSTRACT
Activated carbon (AC) is a versatile, highly porous material with a large surface area and significant adsorptive
properties, making it indispensable across a wide range of industrial and environmental applications. This review
paper provides a detailed exploration of activated carbon, focusing on its synthesis methods, chemical and
physical properties, and extensive applications. The paper delves into the mechanisms of both physical and
chemical activation, examines the properties that make activated carbon a unique material, and outlines its
applications in areas like water treatment, air purification, energy storage, catalysis, and environmental
remediation. The paper concludes with an analysis of the challenges facing activated carbon utilization and
potential future advancements that could enhance its applications.
Keywords: Carbonization, precursor material, activation, porosity, surface area, adsorption, water treatment, and
air filtration.
_____________________________________________________________________________________________
INTRODUCTION
Activated carbon is a form of carbon processed to create small, low-volume pores that significantly increase its
surface area. This high surface area makes activated carbon an exceptionally powerful adsorbent, ideal for capturing
and holding molecules from liquid and gas phases. The material is produced from a variety of carbon-rich sources,
such as coal, wood, coconut shells, and agricultural residues (H Guan et al., 2013). By subjecting these materials to
carbonization and activation processes, manufacturers can tailor the pore structure and surface chemistry of
activated carbon to suit different industrial applications (Ogungbenro et al., 2018). The role of activated carbon in
industrial and environmental sectors is well-established. It has been widely used in water purification, air filtration,
and solvent recovery (Marsh & Reinoso, 2006). In recent years, the interest in activated carbon has expanded to
include applications in energy storage, such as in supercapacitors and batteries, as well as in emerging
environmental remediation technologies. Given the increasing importance of environmental sustainability, the
demand for effective and economical materials like activated carbon has surged (Li et al., 2013; Lua & Guo, 2000).
The purpose of this review is to comprehensively cover the synthesis, properties, and applications of activated
carbon, providing an in-depth look at its future potential (Marsh & Reinoso, 2006).
114
Tarikuzzaman M Euro. J. Adv. Engg. Tech., 2023, 10(1):114-123
significantly influences the properties of the final product, including its surface area, porosity, and adsorption
capacity. For instance, coconut shells are known to produce activated carbon with a high surface area and
microporous structure, ideal for gas-phase adsorption, while lignocellulosic materials like wood produce more
mesoporous activated carbon, which is better suited for liquid-phase adsorption.
Agricultural residues such as rice husks, sugarcane bagasse, and corn stover have gained attention as sustainable
and low-cost sources of activated carbon (Chen et al., 2011; Wang et al., 2014). These materials not only reduce
waste but also minimize the environmental impact associated with carbon production. Despite their differences, all
carbonaceous materials undergo similar thermal treatments to produce activated carbon, but the specific
characteristics of the precursor material determine the ultimate properties of the activated carbon.
Carbonization Process
The carbonization process is the first step in the production of activated carbon and involves the thermal
decomposition of the precursor material in an inert atmosphere, typically under nitrogen or argon. This process
occurs at temperatures ranging from 400°C to 900°C, during which the volatile components of the precursor are
driven off, leaving behind a carbon-rich chair. The carbonization process is crucial as it creates the initial
framework for the porous structure that will later be enhanced through activation. Carbonization typically results in
the formation of a material with a low surface area and limited porosity. However, by carefully controlling the
temperature and time of carbonization, it is possible to influence the distribution and size of pores in the final
product. For instance, higher carbonization temperatures often lead to the development of more extensive pore
networks. This stage lays the groundwork for the subsequent activation process, which further refines the material's
porosity and surface characteristics.
Physical Activation
Physical activation is one of the two primary methods used to transform carbonized material into activated carbon.
This method involves treating the char with oxidizing gases, such as steam or carbon dioxide, at high temperatures
between 800°C and 1100°C (Gale et al., 2021). The oxidizing gases react with the carbon in the chart, selectively
removing atoms from the material's surface and creating a network of pores. This process not only increases the
surface area of the carbon but also develops micropores that are critical for adsorption applications. The primary
advantage of physical activation is that it produces a highly microporous material with a large surface area,
typically ranging from 500 to 1500 m²/g. This makes it particularly well-suited for applications where the
adsorption of small molecules is required, such as in gas purification. However, the high temperatures and long
processing times required for physical activation can make this method energy-intensive and expensive. Despite
this, physical activation remains one of the most widely used techniques for producing activated carbon.
Chemical Activation
Chemical activation is an alternative method that involves treating the precursor material with chemical agents,
such as potassium hydroxide (KOH), phosphoric acid (H₃PO₄), or zinc chloride (ZnCl₂), before subjecting it to
carbonization (Gale et al., 2021). The chemical agent penetrates the carbonaceous material and assists in breaking
down its structure during carbonization, which typically takes place at lower temperatures (400°C to 600°C)
compared to physical activation. Chemical activation can produce activated carbon with both micropores and
mesopores, depending on the choice of chemical agent and processing conditions. The primary advantage of
chemical activation is that it can achieve higher porosity and surface area with less energy input compared to
physical activation. Furthermore, it offers more control over the pore size distribution, allowing to produce
mesoporous activated carbon, which is highly desirable for liquid-phase adsorption applications. However, the use
of chemical agents introduces environmental concerns, particularly with the disposal of chemical waste. Recent
advancements in green chemistry have focused on developing more sustainable chemical activation processes that
minimize environmental impact.
Alternative Synthesis Methods
In addition to the traditional physical and chemical activation methods, alternative synthesis approaches have
emerged in recent years. One such method is microwave-assisted activation, which uses microwave radiation to
rapidly heat the precursor material. This method is energy-efficient and allows for greater control over the
activation process, resulting in more uniform pore distribution. Another emerging technique is hydrothermal
carbonization, which involves treating biomass in water at elevated temperatures and pressures to produce
hydrochar. The hydrochar can then be activated to produce a highly porous carbon material. Template synthesis is
115
Tarikuzzaman M Euro. J. Adv. Engg. Tech., 2023, 10(1):114-123
another innovative approach that involves using a templating agent, such as silica, to create a highly ordered porous
structure in the carbon material. After carbonization, the template is removed, leaving behind a mesoporous or
microporous carbon structure. This method offers precise control over the pore size and distribution, making it ideal
for applications that require highly specific adsorption properties. As sustainability becomes increasingly important,
there has also been a push to use waste materials, such as food waste and industrial by-products, as precursors for
activated carbon production, reducing environmental impact and providing a low-cost source of carbon.
116
Tarikuzzaman M Euro. J. Adv. Engg. Tech., 2023, 10(1):114-123
Although activated carbon is not as conductive as materials like graphene or carbon nanotubes, its conductivity can
be enhanced by controlling the carbonization temperature or by incorporating conductive additives.
The thermal conductivity of activated carbon is also a critical property in applications where heat dissipation is
important, such as in catalysis or thermal insulation. Similar to its electrical conductivity, the thermal conductivity
of activated carbon can be tailored by adjusting the carbonization process or by impregnating the material with
metals or other conductive agents. The balance between adsorptive capacity and conductivity is particularly
important in applications like supercapacitors, where both properties are required for optimal performance.
117
Tarikuzzaman M Euro. J. Adv. Engg. Tech., 2023, 10(1):114-123
cycles (Chmiola et al., 2006). Activated carbon supercapacitors are known for their high-power density and long
cycle life, although they generally exhibit lower energy density compared to conventional batteries. The key to
improving the performance of supercapacitors lies in optimizing the porosity and surface chemistry of the activated
carbon (Li et al., 2020). By tailoring the pore size distribution, researchers can enhance the capacitance and charge
storage capacity of activated carbon-based supercapacitors. Beyond supercapacitors, activated carbon is also used as
an anode material in various types of batteries, including lithium-ion, sodium-ion, and zinc-air batteries. In these
applications, the porosity and electrical conductivity of activated carbon enable the rapid movement of ions within
the battery, contributing to improved performance. In lithium-ion batteries, for example, activated carbon can be
used to create high-performance anode materials with enhanced cycling stability and capacity retention.
Additionally, its ability to host various dopants and functional groups allows for the development of modified
carbon materials that enhance battery efficiency. Recent advancements have explored the use of hybrid carbon
materials, where activated carbon is combined with other carbon-based nanomaterials, such as graphene or carbon
nanotubes, to create electrodes with superior electrochemical properties. These hybrid materials offer improved
conductivity, higher surface areas, and enhanced ion transport pathways, making them promising candidates for
next-generation energy storage devices.
Catalysis
Activated carbon is also widely used in catalysis, either as a catalyst or as a support material for various catalytic
reactions. Its high surface area, tunable pore structure, and ability to adsorb reactants make it an effective catalyst in
many chemical processes, including hydrogenation, oxidation, and dehydrogenation reactions. The versatility of
activated carbon in catalysis stems from its ability to interact with a wide range of reactants and to be modified with
metal or metal oxide nanoparticles, which further enhance its catalytic properties. In catalytic hydrogenation
reactions, for example, activated carbon is often used as a support material for metal catalysts, such as palladium
(Pd), platinum (Pt), or nickel (Ni). The porous structure of the carbon provides a high surface area for the dispersion
of metal nanoparticles, improving the accessibility of active sites and enhancing reaction rates. Similarly, in
oxidation reactions, activated carbon can serve as both a catalyst and an adsorbent, facilitating the removal of
unwanted byproducts while promoting the desired reaction. One notable application of activated carbon in catalysis
is in environmental remediation, where it is used in catalytic converters to reduce the emissions of harmful gases,
such as carbon monoxide (CO), hydrocarbons, and nitrogen oxides (NOₓ), from vehicle exhaust systems. By
supporting catalytic metals like platinum or rhodium, activated carbon helps to convert these pollutants into less
harmful substances, such as carbon dioxide (CO₂) and nitrogen (N₂). In addition to its role as a support material,
activated carbon can also act as a catalyst for pollutant degradation in advanced oxidation processes (AOPs). In
these processes, activated carbon is used to generate reactive species, such as hydroxyl radicals (OH•), which are
highly effective at breaking down organic contaminants in water and air. The ability to modify the surface
chemistry of activated carbon through oxidation or doping further enhances its catalytic performance in these
applications.
Environmental Remediation
Environmental remediation is another critical area where activated carbon finds extensive application. Due to its
excellent adsorptive properties, activated carbon is used to remove pollutants from soil, groundwater, and industrial
effluents (Zhang et al., 2016). It is particularly effective at adsorbing organic pollutants, such as pesticides,
petroleum hydrocarbons, and polycyclic aromatic hydrocarbons (PAHs), as well as inorganic contaminants like
heavy metals and radioactive compounds. One of the key advantages of activated carbon in environmental
remediation is its versatility. It can be used in situ (directly at the contaminated site) or ex situ (in a treatment
facility) to capture pollutants from water or soil. In groundwater remediation, for example, activated carbon is often
employed in permeable reactive barriers (PRBs), where it acts as a passive filter that removes contaminants as
groundwater flows through the barrier. The high surface area of activated carbon allows for the efficient capture of
dissolved pollutants, preventing their migration and reducing the risk of groundwater contamination. Activated
carbon is also used in soil remediation to adsorb contaminants that have accumulated in the subsurface. It is highly
effective at immobilizing hydrophobic organic compounds, which can persist in soil for long periods and pose
significant environmental risks. By adsorbing these pollutants, activated carbon prevents their leaching into
groundwater and facilitates their eventual degradation by natural processes. In addition to its use in traditional
remediation techniques, activated carbon is also being integrated into emerging remediation technologies, such as
118
Tarikuzzaman M Euro. J. Adv. Engg. Tech., 2023, 10(1):114-123
bioremediation and phytoremediation. In these systems, activated carbon serves as an adsorbent and a catalyst for
microbial or plant-mediated degradation of pollutants. For example, in bioremediation, activated carbon can
enhance the microbial degradation of organic pollutants by providing a surface for microbial colonization and
facilitating the adsorption of substrates.
119
Tarikuzzaman M Euro. J. Adv. Engg. Tech., 2023, 10(1):114-123
activation processes used to produce activated carbon often require high energy inputs, particularly when physical
activation methods are employed. The use of chemical activators, such as potassium hydroxide (KOH) and zinc
chloride (ZnCl₂), also introduces the risk of generating hazardous byproducts that must be carefully managed.
Moreover, the regeneration and disposal of spent activated carbon present additional environmental challenges.
Thermal regeneration, which involves heating the spent carbon to remove adsorbed contaminants, consumes
significant energy and may lead to the release of pollutants, such as volatile organic compounds (VOCs), into the
atmosphere. Chemical regeneration methods, while effective in recovering the adsorptive capacity of activated
carbon, can produce hazardous chemical waste that requires treatment before disposal. These environmental costs
highlight the need for more sustainable approaches to both the production and regeneration of activated carbon.
Efforts are being made to reduce the environmental impact of activated carbon through the development of more
eco-friendly production techniques and the use of renewable precursor materials. For example, researchers are
exploring the potential of agricultural byproducts, such as coconut shells, rice husks, and corn stalks, as sustainable
sources of carbon for activated carbon production. These biomass-based materials not only reduce the reliance on
fossil fuel-derived precursors but also provide a means of recycling waste products that would otherwise contribute
to environmental pollution.
Additionally, the exploration of less energy-intensive activation methods, such as microwave-assisted activation
and hydrothermal carbonization, offers promising pathways for reducing the environmental impact of activated
carbon production. These methods require lower energy inputs and generate fewer harmful byproducts, making
them more environmentally sustainable alternatives to traditional activation techniques.
Advanced Applications in Emerging Technologies
As research on activated carbon continues to advance, its potential applications in cutting-edge technologies are
becoming more apparent. Beyond traditional uses in water and air purification, activated carbon is playing an
increasingly important role in fields such as carbon capture and storage (CCS), gas separation, and medical
applications.
• Carbon Capture and Storage (CCS)
With the growing emphasis on mitigating climate change, activated carbon is being explored for its potential in
carbon capture and storage (CCS) technologies (Ogungbenro et al., 2018). CCS is a process that involves capturing
carbon dioxide (CO₂) emissions from industrial sources and power plants and storing them underground to prevent
their release into the atmosphere. Activated carbon’s high surface area and tunable pore structure make it an
attractive material for capturing CO₂ from flue gases. By tailoring the pore size distribution and surface chemistry
of activated carbon, researchers have been able to enhance its selectivity for CO₂ over other gases, such as nitrogen
(N₂) and oxygen (O₂). In addition to its use in post-combustion CO₂ capture, activated carbon is being investigated
for its potential in direct air capture (DAC) technologies, which involve removing CO₂ directly from the
atmosphere. DAC systems face significant challenges related to the low concentration of CO₂ in ambient air but
activated carbon materials with high adsorption capacities and fast kinetics offer promising solutions for improving
the efficiency of these systems.
• Gas Separation
Another emerging application of activated carbon is in gas separation technologies, where it is used to selectively
adsorb certain gases from gas mixtures. This application is particularly important in industries such as natural gas
processing, hydrogen production, and air separation. Activated carbon’s tunable pore structure and surface
functionalization allow for the selective adsorption of gases based on their size, shape, and polarity.
For example, in natural gas processing, activated carbon is used to remove impurities such as sulfur compounds and
carbon dioxide from raw natural gas, improving its quality and reducing the risk of corrosion in pipelines. Similarly,
in hydrogen production, activated carbon can be used to separate hydrogen from other gases, such as methane or
carbon monoxide, through pressure swing adsorption (PSA) or temperature swing adsorption (TSA) processes. The
development of advanced carbon materials, such as metal-organic framework (MOF)-modified activated carbon,
has further enhanced the performance of activated carbon in gas separation applications. These hybrid materials
combine the high surface area and stability of activated carbon with the tunable pore structures of MOFs, resulting
in materials with improved selectivity and adsorption capacity for target gases.
120
Tarikuzzaman M Euro. J. Adv. Engg. Tech., 2023, 10(1):114-123
121
Tarikuzzaman M Euro. J. Adv. Engg. Tech., 2023, 10(1):114-123
alternative to traditional activated carbon materials while also contributing to the circular economy by recycling
waste products (H Guan et al., 2013).
• Integration with Advanced Technologies
The integration of activated carbon with advanced technologies, such as nanotechnology, biotechnology, and
artificial intelligence (AI), is expected to drive the development of next-generation materials with unprecedented
performance characteristics. For example, the combination of activated carbon with nanoscale materials, such as
carbon nanotubes or metal-organic frameworks (MOFs), is leading to the creation of hybrid materials with
enhanced adsorption capacity, selectivity, and catalytic activity. In addition, advances in biotechnology are enabling
the development of bio-inspired activated carbon materials, such as those derived from natural polymers or
produced using microbial processes. These bio-based carbons offer the potential for enhanced biocompatibility,
biodegradability, and functionality in medical and environmental applications.
CONCLUSIONS
Activated carbon remains a versatile and essential material with a wide range of applications, from water and air
purification to energy storage and catalysis. Its unique properties, including high surface area, tunable porosity, and
chemical stability, make it a critical component in many industrial processes and emerging technologies. However,
the environmental challenges associated with its production and regeneration, as well as the need for more
sustainable synthesis methods, highlight the importance of continued research in this field. Looking to the future,
the development of nanostructured and functionalized carbon materials, along with the exploration of renewable
precursor sources and green activation techniques, will play a key role in advancing the capabilities of activated
carbon. As new applications emerge, particularly in fields such as carbon capture, gas separation, and medical
technologies, activated carbon is poised to remain a cornerstone of material science and environmental engineering
for years to come.
REFERENCES
[1]. Cao, Q., Xie, K. C., Lv, Y. K., & Bao, W. R. (2006). Process effects on activated carbon with large
specific surface area from corn cob. Bioresource Technology, 97(1), 110–115.
https://doi.org/10.1016/j.biortech.2005.02.026
[2]. Chen, X., Chen, G., Chen, L., Chen, Y., Lehmann, J., McBride, M. B., & Hay, A. G. (2011). Adsorption of
copper and zinc by biochars produced from pyrolysis of hardwood and corn straw in aqueous solution.
Bioresource Technology, 102(19), 8877–8884. https://doi.org/10.1016/j.biortech.2011.06.078
[3]. Chmiola, J., Yushin, G., Gogotsi, Y., Portet, C., Simon, P., & Taberna, P.-L. (2006). Anomalous increase
in carbon capacitance at pore sizes less than 1 nanometer. Science, 313(5794), 1760–1763.
[4]. Das, D., Gaur, V., & Verma, N. (2004). Removal of volatile organic compound by activated carbon fiber.
Carbon, 42(14), 2949–2962. https://doi.org/10.1016/J.CARBON.2004.07.008
[5]. Gale, M., Nguyen, T., Moreno, M., & Gilliard-Abdulaziz, K. L. (2021). Physiochemical Properties of
Biochar and Activated Carbon from Biomass Residue: Influence of Process Conditions to Adsorbent
Properties. ACS Omega, 6(15), 10224–10233. https://doi.org/10.1021/acsomega.1c00530
[6]. H Guan, B. T., Abdul Latif, P., H Yap, T. Y., & Author, C. (2013). PHYSICAL PREPARATION OF
ACTIVATED CARBON FROM SUGARCANE BAGASSE AND CORN HUSK AND ITS PHYSICAL
AND CHEMICAL CHARACTERISTICS. In Int. J. Engg. Res. & Sci. & Tech.
http://www.ijerst.com/currentissue.php
[7]. Hu, W., Xiang, R., Lin, J., Cheng, Y., & Lu, C. (2021). Lignocellulosic biomass-derived carbon electrodes
for flexible supercapacitors: An overview. In Materials (Vol. 14, Issue 16). MDPI AG.
https://doi.org/10.3390/ma14164571
[8]. Ibrahim, B. M. (n.d.). Heavy metal ions removal from wastewater using various low-cost agricultural
wastes as adsorbents: a survey. https://doi.org/10.21271/zjpas
[9]. Li, Y., Du, Q., Liu, T., Peng, X., Wang, J., Sun, J., Wang, Y., Wu, S., Wang, Z., & Xia, Y. (2013).
Comparative study of methylene blue dye adsorption onto activated carbon, graphene oxide, and carbon
nanotubes. Chemical Engineering Research and Design, 91(2), 361–368.
122
Tarikuzzaman M Euro. J. Adv. Engg. Tech., 2023, 10(1):114-123
[10]. Li, Y., Zhang, D., Zhang, Y., He, J., Wang, Y., Wang, K., Xu, Y., Li, H., & Wang, Y. (2020). Biomass-
derived microporous carbon with large micropore size for high-performance supercapacitors. Journal of
Power Sources, 448. https://doi.org/10.1016/j.jpowsour.2019.227396
[11]. Lua, A. C., & Guo, J. (2000). Activated carbon prepared from oil palm stone by one-step CO2 activation
for gaseous pollutant removal. Carbon, 38(7), 1089–1097.
[12]. Marsh, H., & Reinoso, F. R. (2006). Activated carbon. Elsevier.
[13]. Ogungbenro, A. E., Quang, D. V., Al-Ali, K. A., Vega, L. F., & Abu-Zahra, M. R. M. (2018). Physical
synthesis and characterization of activated carbon from date seeds for CO2 capture. Journal of
Environmental Chemical Engineering, 6(4), 4245–4252. https://doi.org/10.1016/J.JECE.2018.06.030
[14]. Wang, Z., Wu, J., He, T., & Wu, J. (2014). Corn stalks char from fast pyrolysis as precursor material for
preparation of activated carbon in fluidized bed reactor. Bioresource Technology, 167, 551–554.
https://doi.org/10.1016/j.biortech.2014.05.123
[15]. Zhang, X., Guo, W., Ngo, H. H., Wen, H., Li, N., & Wu, W. (2016). Performance evaluation of powdered
activated carbon for removing 28 types of antibiotics from water. Journal of Environmental Management,
172, 193–200. https://doi.org/10.1016/J.JENVMAN.2016.02.038
123