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class11 test

The document contains a series of chemistry questions covering topics such as molarity, molality, mass percentage, quantum numbers, hybridization, and electron configurations. It includes multiple-choice questions, assertion-reason questions, and problems requiring calculations related to chemical properties and reactions. Additionally, there are passages with related questions focusing on quantum mechanics and electron behavior.

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saloni garg
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0% found this document useful (0 votes)
3 views

class11 test

The document contains a series of chemistry questions covering topics such as molarity, molality, mass percentage, quantum numbers, hybridization, and electron configurations. It includes multiple-choice questions, assertion-reason questions, and problems requiring calculations related to chemical properties and reactions. Additionally, there are passages with related questions focusing on quantum mechanics and electron behavior.

Uploaded by

saloni garg
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
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1. What will be the molarity of solution which contains 5.

85 grams of sodium
chloride in 500 ml of solution
(a)4 mol/L (b) 20 mol/L (c) 0.2 mol/L (d) 2 mol/L

2. What will be the molality of solution containing 18.25 grams of HCl in 500ml
of water
(a) 0.1 m (b) 1 M (c) 1m (d) 0.5 m

3. What is the mass percentage of carbon in carbon dioxide?


(a) 0.034 % (b) 27.27% (c) 3.4 % (d) 28.7 %

4.. If the largest value of m for an electron is +2, then the electron may be
present in what type of sub shell?
a. s subshell b. d subshell c. p subshell d. f subshell

5. An electron has spin quantum number ms = +1/2 and magnetic quantum


number ml = +1. It cannot be present in
a. s orbital b. p orbital c. d orbital d. f orbital

6. The number of radial nodes in 3s and 2p respectively are


a. 2 and 0 b. 1 and 2 c. 0 and 2 d. 2 and 1

7. Which one of the following pairs of ions have the same electronic
configuration?
a. Cr3+, Fe3+ b. Fe3+, Mn2+ c. Fe3+, Co3+ d. Sc3+, Cr3+

8. Group 16 elements are also called


a. halogens
b. noble gases
c. Representative Elements
d. chalcogens 2

9. Which among the following elements has the highest negative electron gain
enthalpy?
a. Hydrogen b. Fluorine c. Chlorine d. Oxygen

10. Which of the following is not a transition element?


a. Fe b. Cu c. Zn d. Ni

11. The species that is isoelectronic with Na+ is ______


a. Ca2+ b. F- c. S2- d. K+

12. Identify the molecule which is not linear.


a.CO2 b. BeCl2 c. H2S d. HgCl2
13. Hybridisation in NH3 is …………….
a.sp b. sp2 c. sp3 d. sp3d

14. Which of the following diatomic molecules is paramagnetic in nature?


a. H2 b. N2 c. He2 d. O2

15. The group number, number of valence electrons, and valency of an element
with the atomic number 15, respectively, are:
a. 16, 5 and 2 b. 15, 5 and 3 c. 16, 6 and 3 d. 15, 6 and 2

Assertion Reason type questions


a. If both Assertion and Reason are correct and Reason is the correct
explanation of Assertion.
b. If both Assertion and Reason are correct but Reason is not the correct
explanation of Assertion.
c. If Assertion is correct and Reason is wrong.
d. If Assertion is wrong and Reason is correct.

16. Assertion: Number of moles of H2 in 0.224 L of hydrogen is 0.01 mole.


Reason: 22.4 L of H2 at STP contains 6.023 × 1023moles.

17. Assertion (A): The 19th electron in Potassium atom enters into 4 s orbital ad
not in the 3d orbital.
Reason (R): (n+l) rule is followed for determining the orbit of lowest energy
state.

18. Assertion (A): The energy of an electron is largely determined by the


principal quantum number.
Reason (R): The principal quantum number is a measure of the probable
distance of finding the electron around the nucleus.

19. Assertion: Boron has a smaller first ionisation enthalpy than beryllium.
Reason: The penetration of a 2s electron to the nucleus is more than the 2p
electron hence 2p electron is more shielded by the inner core of electrons than
the 2s electrons.

20.Assertion: PCl5 has trigonal bipyramidal shape.


Reason: There are 4 bond pairs and 1 lone pair around phosphorus in PCl5.

21.Assertion: O2 molecule is paramagnetic in nature.


Reason: Bond order of O2 is two.

2 Marks questions

22. Calculate the percentage of N in urea. (Molar mass of urea = 60 g mol -1 )


Molecular formula of Urea is NH2CONH2
23. An organic compound contains 144g of carbon and 12 g of hydrogen. If
molar mass of this compound is 78 gmol-1 , calculate: I. Empirical formula II.
Molecular formula

24. How many moles of ethane are required to produce 66 g CO2 after
combustion?

25.. What are isoelectronic species? Give any 4 examples.

26. Which is more polar, NF3 or NH3? Explain.

27. Draw the resonance structures of CO3

28.An ion with mass number 37 possesses one unit of negative charge. If the
ion conatins 11.1% more neutrons than the electrons, find the symbol of the ion

29.Which of the following species will have the largest and the smallest size?
Mg, Mg2+, Al, Al3+.

30.Show by a chemical reaction with water that Na2O is a basic oxide and
Cl2O7 is an acidic oxide.

31.Explain why cation are smaller and anions larger in radii than their parent
atoms?

32.Describe the hybridisation in case of PCl5. Why are the axial bonds longer
as compared to equatorial bonds?

3 Marks Questions

33.The Vividh Bharati station of All India Radio, Delhi, broadcasts on a


frequency of 1,368 kHz (kilo hertz). Calculate the wavelength of the
electromagnetic radiation emitted by transmitter. Which part of the
electromagnetic spectrum does it belong to?

34.Explain the structure of CO3 2– ion in terms of resonance.

35.Draw diagrams showing the formation of a double bond and a triple bond
between carbon atoms in C2H4 and C2H2 molecules.

36. What do you mean by limiting reagent? 400 g of N2 and 150 g of H2 are
mixed together to form NH3. Identify the limiting reagent and calculate the
amount of NH3 produced.

37.When electromagnetic radiation of wavelength 300 nm falls on the surface


of sodium, electrons are emitted with a kinetic energy of 1.68 ×105 J mol–1.
What is the minimum energy needed to remove an electron from sodium? What
is the maximum wavelength that will cause a photoelectron to be emitted

5 Marks Questions

38. Calculate the molality and molarity of 93 % H2SO4(mass/volume). The


density of the solution is 1.84 gram per ml

39.The first (Δi H1) and the second (Δi H2) ionization enthalpies (in kJ mol–1 )
and the (ΔegH) electron gain enthalpy (in kJ mol–1 ) of a few elements are
given below:

Which of the above elements is/are likely to be:

(a) the least reactive element.


(b) the more reactive group one metal. 4
(c) the reactive non-metals.
(d) the metal which can form a stable binary halide of the formula
MX2(X=halogen).
(e) the metal which can form a predominantly stable covalent halide of the
formula MX (X=halogen)?

Passage based MCQs

Passage 1 The position and energy of an electron is specified with the help of
four quantum numbers namely principal quantum number, azimuthal quantum
number, magnetic quantum number and spin quantum number. The permissible
values of these are: n=1, 2………. l= 0, 1, 2… (n-1) ml = -l ….0 ……. +l ms = +1/2
and -1/2 The electrons having the same value of n, l and ml are said to belong
to the same orbital. According to Pauli’s exclusion principle, an orbital can have
maximum of two electrons and these must have opposite spin.

1. For an electron having n=3, l=0, the orbital angular momentum quantum
number is (a) √3h/π (b) √6h/2π (c) Zero (d) 8√3h/π

2. Which of the following statements is not correct? (a) For Sodium, the
outermost electron has n=3, l=0, ml=0, ms=+1/2 (b) The orbitals having n=3,
l=2, ml=+2 and n=3, l=2, ml=-2 have same energies (c) For 4f electron, n=4,
l=3, ml=0, s=+1/2 is not possible (d) The orbitals 2d,3f and 4g are not possible

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