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h.d.a Theory Assignment’s

The document discusses halogen derivatives of alkanes, covering various topics such as classification, bond-line structures, reactions with alcohols, and nucleophilic substitution reactions. It includes questions on specific compounds, their reactions, and methods for preparation and conversion. Additionally, it outlines key reactions and rules related to halogen derivatives, such as Saytzeff's rule and the Kharash effect.

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sshivamsingh2007
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11 views

h.d.a Theory Assignment’s

The document discusses halogen derivatives of alkanes, covering various topics such as classification, bond-line structures, reactions with alcohols, and nucleophilic substitution reactions. It includes questions on specific compounds, their reactions, and methods for preparation and conversion. Additionally, it outlines key reactions and rules related to halogen derivatives, such as Saytzeff's rule and the Kharash effect.

Uploaded by

sshivamsingh2007
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Halogen Derivative of Alkane

Q.1) What do you understand by H.D.A? give the classification of H.D.A.

Q.2) Give Bond–line structure of these comp.


a) 2-Chloro Butane b) 2-methyl-2-Bromo pentane
c) Propylene di-bromide d) neo-pentyl Iodide

Q.3)Give Common name & IUPAC name of following compounds

Q.4) Give action of Chlorine in presence of Sunlight on-


i)methane ii)n-Propane iii) n-butane iv)neo-Pentane

Q.5) Explain the action of H-Br by Anti M.K. Rule and M.K. Rule with-
i) But-1-ene ii) 3-methyl But-1-ene iii) 2-Methyl propene iv)Pent-2-ene

Q.6) What happen when these alcohol comp. react with-


a) Lucas Reagent b)NaBr+H2SO4 c)KI+ H3PO4
d) RedP+Br e)RedP+I f )PCl3 g)PCl5
·
ALCOHOL COMPOUNDS are-
i)Ethanol ii)Propan-1-Ol iii)2-Methyl Propan-1-ol
Q.7) Give the preparation of monohaloalkane from-
a)Swarts Reaction b) Finkelstein Reaction

Q.8) Explain Darzen Method with Ethanol

Q.9)Explain what do you understand by Groove Process with one


example ?

Q.10)Explain Iodination of Ethane by using- HgO; dil.HNO3; HIO3.

Q.11)Explain what do you understand by Nucleophilic Substitution reaction


& give it’s type as well.

Q.12)Give action of “Ethyl Bromide” on-


i)aq.K-OH ii)moist.Ag2O iii)alc.K-CN iv)Ag-CN v)alc.NH3
vi)CH3-ONa vii) CH3-COOAg viii)alc.K-OH ix)Na-metal x)Mg-metal
Xi) Zn-metal Xii)Ag-NO2 Xiii)K-NO2.

Q.13) Conversion Reaction:-


i)Methane to Carbon tetrachloride. ii)methane to ethane nitrile
iii) propane to propene iv)ethane to ethyl fluoride
v)methanol to ethane carbylamine vi)ethanol to ethoxy ethane
vi)methane to ethane. vii)ethane to ethane
viii)propane to 2,3-Dimethyl Butane ix)ethane to propane
x)ethene to ethyl propanoate

Q.14)State & explain Saytzeff Rule

Q.15)Explain Optical activity with diagramatic representation


Q.16) Give Classification of optically active molecules.

Q.17) Explain Vant-Hoff & Le-Bel theory with one example.

Q.18) Define the following-


i)Enantiomer ii)Racemic Mixture

Q.19) Give preparation of Haloarene from Diazonium salt of Halide by-


a)Sandemeyer reaction b)Balz-scheimann reaction c) using K-I.

Q.20)What Happen When Chloro Benzene undergoes in these Process-


i)Halogenation ii)Nitration iii)Sulphonation iv)reaction with Na metal

Q.21)Friedel-Cra Reaction with Chloro Benzene.

1 2
Q22)Explain SN & SN Mechanism With Energy Profile Diagram.

Q23)Identify R & S Configuration in these molecules.


#NAMING REACTION OF H.D.A.

1.Kharash effect /Peroxide effects.


2.Groove process
3.Darzen method
4.Swarts Reaction
5.Finklestin reaction
6.Ammonolysis
7.Esterification
8.Williamsons synthesis method
9.Wurtz reaction
10.Grignard reaction
11.Satyzeff rule
12.sandemeyer reaction
13.Balz-sciemaan reaction
14.Wurtz-Fittig reaction
15.Fittig reaction
*HALOGEN DERVATIVE OF ALKANE*
#CONVERSION:-
1.Methane to Carbon tetra-chloride.
2.Dichloro Ethane to Ethane.
3.Propane to 1-Bromo Propane.
4.Methyl Bromide to Ethyl iodide.
5.Acetone to Sec-Propyl Bromide.
6.Butanone to Haloform.
7.Ethanol to Ethyl chloride (Darzen method)
8.Tert-Butyl alcohol to tert-Butyl Chloride (Groove Process).
9.Ethyne to Fluoro Ethane.
10.Ethyne to 2,3-Dimethyl Butane.
11.Ethene to Ethanol.
12.Methane to Propane Nitrile.
13.Westron to Propane Carbylamine.
14.Ethanol to Ethyl amine.
15.Methanal to Methyl Ethanoate
16.Ethene to Ethanoic acid.
17.But-1-ene to But-2-ene.
18.Propene to Propene.
19.Methane to Ethene.
20.3-Methyl But-1-ene to tert-Butyl Chloride.
21.1-Chloro-2-Methyl Butane to tert-Pentyl alcohol.
22.Methane to 2-Methoxy-2-Methyl Propane
23.2-Methyl Propene to 2,5-Dimethyl Hexane.
24.Ethylene Dichloride to Chloro Benzene.
25.Chloro Benzene to Biphenyl.
26.Benzoic Acid to Fluoro Benzene

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