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The document contains chapter-wise questions for Class 12 Chemistry, focusing on solutions, including short answer, matching type, assertion and reason type, and long answer questions. Topics covered include distillation, boiling point elevation and depression, solubility rules, osmotic pressure, and colligative properties. The questions aim to assess students' understanding of key concepts and principles related to solutions in chemistry.

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2 views

vnd.openxmlformats-officedocument.wordprocessingml.document&rendition=1

The document contains chapter-wise questions for Class 12 Chemistry, focusing on solutions, including short answer, matching type, assertion and reason type, and long answer questions. Topics covered include distillation, boiling point elevation and depression, solubility rules, osmotic pressure, and colligative properties. The questions aim to assess students' understanding of key concepts and principles related to solutions in chemistry.

Uploaded by

Selva Tailor's
Copyright
© © All Rights Reserved
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
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Chapter wise Questions

Class 12 Chapter -1-Solutions Subject: Chemistry

Short Answer Type Questions


1. Components of a binary mixture of two liquids A and B were being separated by
distillation. After some time separation of components stopped and composition of
vapour phase became same as that of liquid phase. Both the components started coming
in the distillate. Explain why this happened.

2. Explain why on addition of 1 mol of NaCl to 1 litre of water, the boiling point of water
increases, while addition of 1 mol of methyl alcohol to one litre of water decreases its
boiling point.
3. Explain the solubility rule "like dissolves like" in terms of intermolecular forces that exist
in solutions.
4. Concentration terms such as mass percentage, ppm, mole fraction and molality are
independent of temperature, however molarity is a function of temperature. Explain.
5. What is the significance of Henry's Law constant KH ?

6. Why are aquatic species more comfortable in cold water in comparison to warm water?

7. (a) Explain the following phenomena with the help of Henry's law.
(i) Painful condition known as bends.
(ii) Feeling of weakness and discomfort in breathing at high altitude.
(b) Why soda water bottle kept at room temperature fizzes on opening?
8. Why is the vapour pressure of an aqueous solution of glucose lower than that of water?

9. How does sprinkling of salt help in clearing the snow covered roads in hilly areas?
Explain the phenomenon involved in the process.

10. What is "semi permeable membrane"?

11. Give an example of a material used for making semipermeable membrane for carrying
out reverse osmosis.

Matching Type Questions


Note: In the following questions match the items given in Column I and Column II.
1. Match the items given in Column I and Column II.
Column I Column II
(i) Solution having same osmotic pressure at a given
(a) Saturated solution
temperature as that of given solution.
(ii) A solution whose osmotic pressure is less than
(b) Binary solution that of
another.
(c) Isotonic solution (iii) Solution with two components.

(d) Hypotonic solution (iv) A solution which contains maximum amount of


solute
that can be dissolved in a given amount of solvent at
a given
temperature.
(v) A solution whose osmotic pressure is more than
(e) Solid solution that of
another.
(f) Hypertonic solution (vi) A solution in solid phase.

2. Match the items given in Column I with the type of solutions given in Column II.
Column I Column II
(a) Soda water (i) A solution of gas in solid
(b) Sugar solution (ii) A solution of gas in gas
(c) German silver (iii) A solution of solid in liquid
(d) Air (iv) A solution of solid in solid
(e) Hydrogen gas in palladium (v) A solution of gas in liquid
(vi) A solution of liquid in solid

3. Match the laws given in Column I with expresions given in Column II.
Column I Column II
(a) Raoult's law (i) ΔTf = Kf m
(b) Henry's law (ii) π = CRT
(c) Elevation of boiling point (iii) p = x1p10 + x2p20
(d) Depression in freezing
(iv) ΔTb = Kb m
point

(e) Osmotic pressure (v) p = KH x


4. Match the terms given in Column I with expressions given in Column II.
Column I Column II
(i) Number of moles of the solute component /
(a) Mass percentage Volume
of solution in litres
(ii) Number of moles of a component / Total
(b) Volume percentage number of
moles of all the components
(iii) (Volume of the solute component in
(c) Mole fraction solution / Total
volume of solution) x 100
(iv) ( Mass of the solute component in solution/
(d) Molality Total
mass of the solution ) x 100
(v) Number of moles of the solute components /
(e) Molarity Mass
of solvent in kilograms

Assertion and Reason Type Questions


Note: In the following questions a statement of assertion followed by a statement of reason is
given. Choose the correct answer out of the following choices.
(i) Assertion and reason both are correct statements and reason is correct explanation for
assertion.
(ii) Assertion and reason both are correct statements but reason is not correct explanation for
assertion.
(iii) Assertion is correct statement but reason is wrong statement.
(iv) Assertion and reason both are incorrect statements.
(v) Assertion is wrong statement but reason is correct statement.
1. Assertion: Molarity of a solution in liquid state changes with temperature.
Reason: The volume of a solution changes with change in temperature.
2. Assertion: When methyl alcohol is added to water, boiling point of water increases.
Reason: When a volatile solute is added to a volatile solvent elevation in boiling point is
observed.
3. Assertion: When NaCl is added to water a depression in freezing point is observed.
Reason:
The lowering of vapour pressure of a solution causes depression in the freezing point.
4. Assertion: When a solution is separated from the pure solvent by a semi-permeable
membrane, the solvent molecules pass through it from pure solvent side to the solution side.
Reason: Diffusion of solvent occurs from a region of high concentration solution to a region
of low concentration solution.

Long Answer Type Questions


1. Define the following modes of expressing the concentration of a solution. Which of these
modes are independent of temperature and why?
(i) w/w (mass percentage)
(ii) V/V (volume percentage)
(iii) w/V (mass by volume percentage)
(iv) ppm. (parts per million)
(v) x (mole fraction)
(vi) M (Molarity)
(vii) m (Molality)
2. Explain the terms ideal and non-ideal solutions in the light of forces of interactions
operating between molecules in liquid solutions.
3. Why is it not possible to obtain pure ethanol by fractional distillation? What general name
is given to binary mixtures which show deviation from Raoult's law and whose components
cannot be separated by fractional distillation. How many types of such mixtures are there?
4. When kept in water, raisins swell in size. Name and explain the phenomenon involved.
Give three applications of the phenomenon.
5. Discuss biological and industrial importance of osmosis.
6. How can you remove the hard calcium carbonate layer of the egg without damaging its
semipermeable membrane? Can this egg be inserted into a bottle with a narrow neck without
distorting its shape? Explain the process involved.
7. Why is the mass determined by measuring a colligative property in case of some solutes is
abnormal? Discuss it with the help of the Van't Hoff factor.

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