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Moderated Set-I MS

The document is a marking scheme for a Class XI Chemistry exam, detailing the answers and marks allocated for each question across multiple sections. It includes specific answers for multiple-choice questions, detailed explanations for conceptual questions, and calculations for chemical reactions. The scheme outlines the criteria for scoring, emphasizing correct definitions, examples, and reasoning.

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YASH GAMER YT
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11 views4 pages

Moderated Set-I MS

The document is a marking scheme for a Class XI Chemistry exam, detailing the answers and marks allocated for each question across multiple sections. It includes specific answers for multiple-choice questions, detailed explanations for conceptual questions, and calculations for chemical reactions. The scheme outlines the criteria for scoring, emphasizing correct definitions, examples, and reasoning.

Uploaded by

YASH GAMER YT
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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MARKING SCHEME

CLASS-XI SUBJECT- CHEMISTRY


Q. NO. ANSWER MARKS
SECTION A
1 D 1
2 C 1
3 C 1
4 A 1
5 C 1
6 B 1
7 C 1
8 A 1
9 C 1
10 C 1
11 A 1
12 D 1
13 D 1
14 A 1
15 C 1
16 C 1
SECTION B
17 molecular mass of C6H12O6 = 180 u and Mohr’s salt [FeSO4 (NH4)2SO4 1+1
7H2O].= 392 u
18 The added electron in oxygen goes to second quantum level. Due to 2
small size of oxygen, it experiences repulsion from other electrons
much more in comparison to that in sulphur because in sulphur, the
electron is added to 3rd quantum level in which larger space is
available for movement.
19 Correct statement and explanation with example. 2
20 Correct formula and steps, 2
Answer= 959.73 J K- Mol-
21 The increasing order of the pH would be; 2
CH3COONa < KNO3 < C6H5COONH4 < NH4Cl
OR
− − − −
RO > CH3COO > OH > Cl .
SECTION C
22 (a) Correct definition of ionisation enthalpy 1
(b) (i) The correct first ionisation enthalpy order is
½
S< P< O<N
Correct reason ½
(ii) Since non metallic character increases along a period and 1
decreases down a group. So non- metallic character increases in the
order: P<S<N<O
23 NO(g)+ 1/2O2(g)⇌ NO2(g)
ΔG°= ∆fG°NO2-[∆fG°NO+ 1/2∆fG°(O2)] 1+1+1
=52.0-87.0- 1/2 x 0= -35 KJ mol-1
Now, log K = -∆G°/2.303 X 8.314 JK-1mol-1 X 298 K
Or K = 2.06 x 106
(OR)

2N2(g) + O2(g) ⇌ 2N2O(g)


Initial moles: 0.482 0.933 0
Moles at eqm.: (0.482 – x) (0.933 – x/2) x 1
Molar conc: 0.482-x/10 0.938-(x/2)/10 x/10
As Kc = 2.0 × 10–37 is very small, this means that the amount of N 2 and 1
O2 reacted (x) is very small. Hence, at equilibrium,
we have[N2] = 0.0482 mol L–1,[O2] = 0.0933 mol L–1, [N2O] = 0.1x mol L–
1 ½
-37
Kc=2.0 x 10 given
On solving this we get, x ≈6.6 x 10-20 ½
∴N2O=0.1x=6.6 x 10-21 mol L-1
24 CO(g) + 2H2(g)⇌CH3OH(g); ΔHr° = – 92 kJ/mol 1+1+1
(i) When pressure is doubled, equilibrium will shift in the direction
where pressure decreases i.e., forward direction.
(ii) As this is an exothermic reaction, so the equilibrium will shift in
backward direction when the temperature is doubled.
(iii)When concentration of CO is doubled, equilibrium will shift in
forward direction.
25 (i) 14 1+1+1
(ii) Maximum two electrons can be associated with quantum
numbers, n=3, l=1 and m=−1 in an atom.
(iii) principal quantum number is 4, then 32 electrons.
26 (i) It is false, exothermic reaction is not always spontaneous. 1.5 x 2
If ΔS = +ve and T. ΔS> ΔH. The process will be non spontaneous even
it. It is endothermic.
(ii) The entropy of vapour is more than that of liquid, so entropy
increases during vaporization.
27 Moles of hydrogen = 4.07 g/ 1.008g = 4.04
Moles of carbon = 24.27 g/ 12. 01g = 2 021 .
Moles of chlorine = 71.65g /35 .453g =2. 021
since 2.021 is smallest value, division by it gives a ratio of 2:1:1 for
H:C:Cl. In case the ratios are not whole numbers, then they may be
converted into whole number by multiplying by the suitable
coefficient.
CH2Cl is, thus, the empirical formula of the above compound.
Determine empirical formula mass by adding the atomic masses of
various atoms present in the empirical formula. For CH 2Cl, empirical
formula mass is 12.01 + (2 ×1.008) + 35.453 = 49.48 g
(b) Divide Molar mass by empirical formula mass = 2 = (n)
(c) Multiply empirical formula by n obtained above to get the
molecular formula Empirical formula = CH 2Cl, n = 2. Hence molecular
formula is C2H4Cl2.
28 (a) Correct definition with suitable example 1
(b) (i) CH4 (g) + 2O2 -----🡪CO2 (g) + 2 H2O (l) ∆H= -890.3 kj/mol
(ii) C (s) + O2 -----------🡪CO2 (g) ∆H= -393.5 kj/mol 1

(iii) H2 + ½ O2 ------🡪H2O (l) ∆H= -285.8 kj/mol


To find out C + 2H2 (g) -----------🡪 CH4 (g) ∆H= ?
Eq.(ii) + 2 eq. (iii) -eq. (i),
∆H = -393.5 +2 (-285.8)-(-890.3) = -74.5kJ/mol 1

SECTION-D
29 (i) 4d 1+1+2
(ii) a , due to n=0 is not possible.
(iii) No two electrons in an atom can have the same set of four
quantum numbers or an orbital can have maximum two electrons and
these must have opposite spin.
OR
a. 2p b 4s
30 a). 33 % 1
OR
OR
lone pair is localised on central atom but bond pair is distributed
between the two. (or any suitable answer) 1
b). 1 1
c). Square planar and Bent (or V-shaped) 1+1

SECTION-E
31 a. Hydrogen atom. It consists of only one proton. 1x5
b. Wave number = 1/ wavelength
Wavelength = 5800 A0 = 5800 x 10-10 m
Wave number = 1/5800 x 10-10 m = 1.72 x 106 m -1
c. Balmer Series
d. 1s2 2s2 2p6 3s2 3p6 3d5 4s1
e. There is a very small heavy positive body present within the atom.
f. . (i) 17Cl35 (ii) 92U233
g. (i) Boron (ii) Potassium
32 Correct explanation based on MO configuration. 5X1
33 (i) Correct definition with examples. 3
(ii) Correct reasons.
2
OR
Correct explanation and reasons in each part. 2+1+1+1

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