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TITRATION for lab exams send

The document outlines various titration experiments involving sodium carbonate, hydrochloric acid, sodium hydroxide, oxalic acid, and potassium permanganate. Each section details the aim, required apparatus and chemicals, principles, procedures, and endpoints for determining the concentration of the respective solutions. The experiments utilize indicators like methyl orange and phenolphthalein to identify the endpoint of the titrations.

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Anish Bidar
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4 views

TITRATION for lab exams send

The document outlines various titration experiments involving sodium carbonate, hydrochloric acid, sodium hydroxide, oxalic acid, and potassium permanganate. Each section details the aim, required apparatus and chemicals, principles, procedures, and endpoints for determining the concentration of the respective solutions. The experiments utilize indicators like methyl orange and phenolphthalein to identify the endpoint of the titrations.

Uploaded by

Anish Bidar
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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VOLUMETRIC ANLYSIS

(SODIUM CARBONATE AND HYDROCHLORIC ACID)

AIM- To estimate the amount of hydrochloric acid present in ________ ml of given


solution, 0.05M sodium carbonate solution is supplied.

APPARATUS REQUIRED- Burette, Pipette, Conical flask, Burette stand, Tile, Wash
bottle, and Beakers.

CHEMICALS REQUIRED- Hydrochloric acid solution, Sodium carbonate solution


(0.05M).

INDICATOR- Methyl orange.

PRINCIPLE-
2 HCl + Na2CO3 → 2 NaCl + H 2O + CO2

NUMBER OF MOLES OF HCl = 2, NUMBER OF MOLES OF Na2CO3= 1

END POINT- Pale yellow to Pale pink.

M1V1 M 2V2
FORMULA- = ,
n1 n2

Sodium carbonate Hydrochloric acid


M1 = molarity M 2 = molarity
V1 = volume V2 = volume
n1 = no of moles n 2 = no of moles
w  1000
M2 =
M V
M = GMW = 36.5
V = volume
w = weight
PROCEDURE-
1. Clean Burette is filled with HCl solution till zero mark including nozzle part with
out any air bubble in the column.
2. 20 ml of sodium carbonate solution is pipetted out and transferred in to conical
flask.
3. One or two drops of methyl orange indicator is added to the conical flask. The
colour of solution turns yellow.
4. The solution in the flask is now titrated with HCl solution until the colour of
solution in conical flask turns pale pink. This is the end point.
5. Note down the final burette reading.
6. Repeat the processes until two constant congruent readings are obtained.
TABLE-
Serial no Volume of Burette reading Volume of HCl
sodiumcarbonate solution in ml
Initial Final
in ml (a–b)
(a) (b)
1 20
2 20
3 20

TITRATION-(SODIUM CARBONATE AND HYDROCHLORIC ACID)

AIM- To estimate the amount of sodium carbonate present in ________ ml of given


solution, 0.1 M Hydrochloric acid solution is supplied.

APPARATUS REQUIRED- Burette, Pipette, Conical flask, Burette stand, Tile, Wash
bottle, and Beakers.

CHEMICALS REQUIRED- Hydrochloric acid solution(0.1M), Sodium carbonate


solution.

INDICATOR- Methyl orange

PRINCIPLE-
2 HCl + Na2CO3 → 2 NaCl + H 2O + CO2

NUMBER OF MOLES OF HCl = 2, NUMBER OF MOLES OF Na2CO3= 1

END POINT- Pale yellow to Pale pink.

M1V1 M 2V2
FORMULA- = ,
n1 n2
Hydrochloric acid Sodium carbonate
M1 = molarity M 2 = molarity
V1 = volume V2 = volume
n1 = no of moles n 2 = no of moles
w  1000
M2 =
M V
M = GMW = 106
V = volume
w = weight
PROCEDURE-
1. Clean Burette is filled with HCl solution till zero mark including nozzle part with
out any air bubble in the column
2. 20 ml of sodium carbonate solution is pipetted out and transferred in to conical
flask.
3. One or two drops of methyl orange indicator is added to the conical flask. The
colour of solution turns yellow.
4. The solution in the flask is now titrated with HCl solution until the colour of
solution turns pale pink. This is the end point.
5. Note down the final burette reading.
6. Repeat the processes until two constant congruent readings are obtained.
TABLE-
Serial no Volume of Burette reading Volume of HCl
sodiumcarbonate solution in ml
Initial Final
in ml (a–b)
(a) (b)
1 20
2 20
3 20

TITRATION- (SODIUM HYDROXIDE AND OXALIC ACID)

AIM- To estimate the amount of Sodium hydroxide present in _________ ml of given


solution, 0.1M oxalic acid solution is supplied.

APPARATUS REQUIRED- Burette, Pipette, Conical flask, Burette stand, Tile, Wash
bottle, and Beakers.

CHEMICALS REQUIRED- oxalic acid solution(0.1M) , Sodium hydroxide solution

INDICATOR- phenophthalein.

PRINCIPLE-
2 NaOH + H 2C 2O4 → Na2C 2O4 + 2 H 2O
NUMBER OF MOLES OF NaOH = 2, NUMBER OF MOLES OF OXALIC ACID =1

END POINT- Colour less to Pale pink.

M1V1 M 2V2
FORMULA- = ,
n1 n2

Oxalic acid Sodium hydroxide


M1 = molarity M 2 = molarity
V1 = volume V2 = volume
n1 = no of moles n 2 = no of moles
w  1000
M2 =
M V
M = GMW = 40
V = volume
w = weight
PROCEDURE-
1. Clean Burette is filled with NaOH solution till zero mark including nozzle part
with out any air bubble in the column
2. 20 ml of oxalic acid solution is pipetted out and transferred in to conical flask .
3. One or two drops of phenophthalein indicator is added to the conical flask. The
colour of solution remains colour less.
4. The solution in the flask is now titrated with NaOH solution until the colour of
solution turns to permanent pale pink. This is the end point.
5. Note down the final burette reading.
6. Repeat the processes until two constant congruent readings are sobtained.

TABLE-
Serial no Volume of Burette reading Volume of
Oxalic acid in NaOH solution
Initial Final
ml in ml (a–b)
(a) (b)
1 20
2 20
3 20

TITRATION-2 (SODIUM HYDROXIDE AND OXALIC ACID)

AIM- To estimate the amount of oxalic acid present in _________ ml of given solution,
0.2M sodium hydroxide solution is supplied.

APPARATUS REQUIRED- Burette, Pipette, Conical flask, Burette stand, Tile, Wash
bottle, and Beakers.

CHEMICALS REQUIRED- oxalic acid solution, Sodium hydroxide solution

INDICATOR- phenophthalein.

PRINCIPLE-
2 NaOH + H 2C 2O4 → Na2C 2O4 + 2 H 2O
NUMBER OF MOLES OF NaOH = 2, NUMBER OF MOLES OF OXALIC ACID =1

END POINT- Colour less to Pale pink.

M1V1 M 2V2
FORMULA- = ,
n1 n2
Oxalic acid Sodium hydroxide
M1 = molarity M 2 = molarity
V1 = volume V2 = volume
n1 = no of moles n 2 = no of moles
w  1000
M2 =
M V
M = GMW = 126
V = volume
w = weight
PROCEDURE-
1. Clean Burette is filled with NaOH solution till zero mark including nozzle part
with out any air bubble in the column
2. 20 ml of oxalic acid solution is pipetted out and transferred in to conical flask .
3. One or two drops of phenophthalein indicator is added to the conical flask. The
colour of solution remains colour less.
4. The solution in the flask is now titrated with NaOH solution until the colour of
solution turns to permanent pale pink. This is the end point.
5. Note down the final burette reading.
6. Repeat the processes until two constant congruent readings are obtained.

TABLE-
Serial no Volume of Burette reading Volume of
Oxalic acid in NaOH solution
Initial Final
ml in ml (a–b)
(a) (b)
1 20
2 20
3 20
TITRATION-3 (POTASSIUM PERMANGANATE AND MOHR’S SALT
SOLUTION)

AIM- To estimate the amount of KMnO4 present in _________ ml of given solution,


0.1M ferrous ammonium sulphate solution is supplied.

APPARATUS REQUIRED- Burette, Pipette, Conical flask, Burette stand, Tile, Wash
bottle, and Beakers.

CHEMICALS REQUIRED- KMnO4solution , Ferrous Ammonium sulphate


solution(0.1M), dilute H2SO4

INDICATOR- KMnO4 is self indicator.

PRINCIPLE-
2 KMnO4 + 8H 2 SO4 + 10FeSO4 → K 2 SO4 + 2 MnSO4 + 5Fe2 (SO 4 )3 + 8H 2O
NUMBER OF MOLES OF KMnO4 = 2,
NUMBER OF MOLES OF FERROUS AMMONIUM SULPHATE = 10

END POINT- Colour less to Pale pink.


M1V1 M 2V2
FORMULA- = ,
n1 n2
Ferrous Ammonium sulphate Solution KMnO 4 solution
M1 = molarity M 2 = molarity
V1 = volume V2 = volume
n1 = no of moles n 2 = no of moles
w  1000
M2 =
M V
M = GMW = 158
V = volume
w = weight
PROCEDURE-
1. Clean Burette is filled with KMnO4 solution till zero mark including nozzle part
with out any air bubble in the column
2. 20 ml of Ferrous Ammonium sulphate solution is pipetted out and transferred in
to conical flask .
3. 20 ml of dilute H2SO4 solution is added to the conical flask. The colour of
solution remains colour less.
4. The solution in the flask is now titrated with KMnO4 solution until the colour of
solution turns to permanent pale pink.this is the end point.
5. Note down the final burette reading.
6. Repeat the processes until two constant congruent readings are obtained.

TABLE-
Serial no Volume of Burette reading Volume of
Ferrous KMnO4
Initial Final
Ammonium solution in ml
(a) (b)
sulphate in ml (a–b)
1 20
2 20
3 20
TITRATION-3 (POTASSIUM PERMANGANATE AND MOHR’S SALT
SOLUTION)

AIM- To estimate the amount of Ferrous Ammonium sulphate present in _________ ml


of given solution, 0.02M KMnO4 solution is supplied.
APPARATUS REQUIRED- Burette, Pipette, Conical flask, Burette stand, Tile, Wash
bottle, and Beakers.
CHEMICALS REQUIRED- KMnO4solution , Ferrous Ammonium sulphate solution,
dilute H2SO4
INDICATOR- KMnO4 is self indicator.
PRINCIPLE-
2 KMnO4 + 8H 2 SO4 + 10FeSO4 → K 2 SO4 + 2 MnSO4 + 5Fe2 (SO 4 )3 + 8H 2O
NUMBER OF MOLES OF KMnO4 = 2, NUMBER OF MOLES OF FERROUS
AMMONIUM SULPHATE = 10
END POINT- Colour less to Pale pink.

M1V1 M 2V2
FORMULA- = ,
n1 n2
Ferrous Ammonium sulphate Solution KMnO 4 solution
M1 = molarity M 2 = molarity
V1 = volume V2 = volume
n1 = no of moles n 2 = no of moles
w  1000
M2 =
M V
M = GMW = 392
V = volume
w = weight
PROCEDURE-
1. Clean Burette is filled with KMnO4 solution till zero mark including nozzle part
with out any air bubble in the column
2. 20 ml of Ferrous Ammonium sulphate solution is pipetted out and transferred in
to conical flask .
3. 20 ml of dilute H2SO4 is added to the conical flask. The colour of solution
remains colour less.
4. The solution in the flask is now titrated with KMnO4 solution until the colour of
solution turns to permanent pale pink. This is the end point.
5. Note down the final burette reading.
6. Repeat the processes until two constant congruent readings are obtained.
TABLE-
Serial no Volume of Burette reading Volume of
Ferrous KMnO4
Initial Final
Ammonium solution in ml
(a) (b)
sulphate in ml (a–b)
1 20
2 20
3 20
TITRATION-4 (POTASSIUM PERMANGANATE AND OXALIC ACID)

AIM- To estimate the amount of oxalic acid present in _________ ml of given solution,
0.02M KMnO4 solution is supplied.

APPARATUS REQUIRED- Burette, Pipette, Conical flask, Burette stand, Tile, Wash
bottle, and Beakers.

CHEMICALS REQUIRED- oxalic acid solution , KMnO4 solution(0.02M), dilute


H2SO4 solution

INDICATOR- KMnO4 is self indicator


PRINCIPLE-
2 KMnO4 + 3 H 2 SO4 + 5H 2C 2O4 → K 2 SO4 + 2 MnSO4 + 10CO2 + 8H 2O
NUMBER OF MOLES OF KMnO4 = 2 NUMBER OF MOLES OF OXALIC ACID = 5

END POINT- Colour less to Pale pink.

M1V1 M 2V2
FORMULA- =
n1 n2

KMnO4 solution Oxalic acid


M1 = molarity M 2 = molarity
V1 = volume V2 = volume
n1 = no of moles n 2 = no of moles
w  1000
M2 =
M V
M = GMW = 126
V = volume
w = weight
PROCEDURE-
1. Clean Burette is filled with KMnO4 solution till zero mark including nozzle part
with out any air bubble in the column
2. 20 ml of oxalic acid solution is pipetted out and transferred in to conical flask .
3. 20 ml of dilute H2SO4 is added to the conical flask and heated till 600C. The
colour of solution remains colour less.
4. The solution in the flask is now titrated with KMnO4 solution in hot condition
until the colour of solution turns to permanent pale pink. This is the end point.
5. Note down the final burette reading.
6. Repeat the processes until two constant congruent reading obtained.

TABLE-
Serial no Volume of Burette reading Volume of
Oxalic acid in KMnO4
Initial Final
ml solution in ml
(a) (b)
(a–b)
1 20
2 20
3 20

TITRATION-4 (POTASSIUM PERMANGANATE AND OXALIC ACID)

AIM- To estimate the amount of KMnO4 present in _________ ml of given solution,


0.05M oxalic acid solution is supplied.
APPARATUS REQUIRED- Burette, Pipette, Conical flask, Burette stand, Tile, Wash
bottle, and Beakers.
CHEMICALS REQUIRED- oxalic acid solution, KMnO4 solution, dilute H2SO4
solution
INDICATOR- KMnO4 is self indicator
PRINCIPLE-
2 KMnO4 + 3 H 2 SO4 + 5H 2C 2O4 → K 2 SO4 + 2 MnSO4 + 10CO2 + 8H 2O
NUMBER OF MOLES OF KMnO4 = 2 NUMBER OF MOLES OF OXALIC ACID = 5

END POINT- Colour less to Pale pink.

M1V1 M 2V2
FORMULA- =
n1 n2

KMnO4 solution Oxalic acid


M1 = molarity M 2 = molarity
V1 = volume V2 = volume
n1 = no of moles n 2 = no of moles
w  1000
M2 =
M V
M = GMW = 158
V = volume
w = weight
PROCEDURE-
1. Clean Burette is filled with KMnO4 solution till zero mark including nozzle part
with out any air bubble in the column
2. 20 ml of oxalic acid solution is pipetted out and transferred in to conical flask .
3. 20 ml of dilute H2SO4 is added to the conical flask and heated till 600C. The
colour of solution remains colour less.
4. The solution in the flask is now titrated with KMnO4 solution in hot condition
until the colour of solution turns to permanent pale pink.this is the end point.
5. Note down the final burette reading.
6. Repeat the processes until two constant congruent reading obtained.
TABLE-
Serial no Volume of Burette reading Volume of
Oxalic acid in KMnO4
Initial Final
ml solution in ml
(a) (b)
(a–b)
1 20
2 20
3 20

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