Q No 1: Encircle the correct answer: CHAPTER 4

1. Forces of attraction which may be present b/w all kinds of atoms and molecules are
(a) Van der Waal’s forces (b) intra molecular
(c) London dispersion forces (d) Dipole induced dipole force
2. Hydrogen bonding is maximum in
(a) Ethanol (b) benzene (c) diethyl ether (d) water
3. When liquid water changes to ice its volume expands by
(a) 100 % (b) 5% (c) 9% (d) 4%
4. With the increase in dipole – Dipole forces non-ideality in a gas
(a) Increase (b) decrease (c) both a and b (d) have no effect
5. Long chains of Amino acids are coiled about one another into a spiral by
(a) Covalent bond (b) Ionic bonds (c) Hydrogen bonds (d) Van der Waal’s forces
6. The deciding criteria for determination of melting and boiling points in case of group – IV members
compound is
(a) Hydrogen bonding in compound (b) intermolecular forces in compound
(c) Chemical bonds in compound (d) molar mass of compound
7. Ethylene glycol has less V.P than ethanol be
(a) Molecular mass (b) size of molecule (c) H – bond (d) Ethylene less volatile than C2H5OH
8. Pressure cooker cooks food faster
(a) B.P decrease (b) more heat is absorbed (c) External “P” increase (d) V.P of H2O increase
9. Strength of dipole - dipole forces depend on
(a) Electro negativity difference (b) distance b/w two molecules
(c) both a and b (d) number of atoms in a molecule
10. With the increase in Vander Waal’s forces the non-ideality in a gas
(a) Increase (b) decrease (c) both a and b (d) have no effect
11. Correct statement about ideal gas
(a) Have forces of attraction (b) exist in nature
(c) J. Thomson effect is not applicable (d) all statements are incorrect
12. At S.T.P which of the following gas has the lowest density
(a) Ar (b) Cl2 (c) CH4 (d) N2
13. Which does not affect vapour pressure
(a) Nature of liquid (b) intermolecular forces (c) temp (d) none
14. ------- is the measure of average K.E of molecules of liquid.
(a) Velocity (b) heat (c) temp (d) speed
15. Which one is max soluble in H2O
(a) CH3OH (b) C2H5OH (c) C3H7OH (d) C6H5CH2OH
16. Ammonia gas is liquefied more easily than nitrogen, hence
(a) Van der Waal’s constant a and b of NH3> than of N2
(b) Van der Waal’s constant a and b of NH3< than of N2
(c) A(NH3) < (a (N2) but b (NH3) > b (N2) (d) A(NH3) > (a (N2) but b (NH3) < b (N2)
17. For an ideal gas the compressibility factor is equal to
(a) 0.5 (b) 1 (c) 1.5 (d) 2
18. Most ideal gas at room temp is
(a) CO2 (b) NH3 (c) SO2 (d) N2
19. Molar heat of vaporization of water is
(a) 40.7 kJmol–1 (b) 50.9 kJmol–1 (c) 40.7 k calmol–1 (d) 50.7 k calmol–1
20. Which one of the following parameters is very important for the non-ideal behavior of gases
(a) Low pressure and low volume (b) high volume and high temperature
(c) low temperature and high pressure (d) high temperature, high volume and high pressure
21. With the increase in polarizability, the ideal behavior of non-polar gases
(a) Increases (b) decreases (c) does not change (d) may or may not be changes
22. The value of compressibility factor for an ideal gas is
(a) Zero (b) unity (c) fraction (d) none of given
23. Which one of the following forces is the strongest
(a) Hydrogen bonding (b) dipole – dipole attraction (c) London dispersion forces (d) Debye forces
24. Conversion of vapours back into their liquid state is called
(a) Crystallization (b) distillation (c) vaporization (d) condensation
25. Vapour pressure is not affected by
(a) Nature of liquid (b) temperature (c) intermolecular forces (d) amount of liquid
26. The order of rate of diffusion of gases NH3, H2, HCl and CO is
(a) H2 > CO > HCl > NH3 (b) NH3 > H2 > CO > HCl
(c) H2 > NH3 > CO > HCl (d) HCl > CO > NH3 > H2
27. Different gases with same K.E move with -------- velocities
(a) Same (b) different (c) equal (d) none
28. At absolute zero
(a) Absolute volume is zero (b) gases liquefy
(c) all gases remain same (d) volume of gases reduce to actual volume
29. In Boyle’s law ----- graph is more informative
(a) Direct (b) inverse (c) both of these (d) none
30. Density of gas in S.I units is expressed as
(a) K g m–3 (b) Kgd m–3 (c) g d m–3 (d) g m–3
31. Which is correct
(a) 1 mm Hg = 1 torr = 1atm (b) 1 mm Hg = 760 torr = 1atm
(c) 760 mm Hg = 760 torr = 1atm (d) 760 mm Hg = 1 torr = 1atm
32. The boiling point of the halogens
(a) Increase down the group (b) decrease down the group
(c) Remains constant (d) difficult to predict
33. The boiling point of a compound is mostly raised by
(a) Intermolecular forces (b) intramolecular forces (c) both a & b (d) none
34. Which of the following sequence is correct
(a) ∆Hs > ∆Hv > ∆ Hf (b) ∆Hv > ∆Hs > ∆ Hf (c) ∆Hf > ∆Hs > ∆ Hv (d) all have same enthalpy
35. Gases deviate from ideal behavior at high pressure. Which is correct for non – ideality
(a) At high pressure, the gas molecule move in one direction only
(b) At high pressure, the collision b/w the gas molecule are increased manifold
(c) At high pressure, the volume of gas becomes insignificant
(d) At high pressure, the intermolecular attractions become significant
36. The value of R (in NmK–1 mol–1) is
(a) 8.214 (b) 8.314 (c) 0.0321 (d) 62.4
37. Ethyl Alcohol is soluble in water due to
(a) Dipole – dipole forces (b) Dipole – induced dipole forces
(c) Instantaneous dipole – induced dipole (d) hydrogen
38. Which one of the following gases show more deviation from ideal behavior
(a) CO2 (b) H2 (c) N2 (d) He
39. The deciding criteria for non-ideality is
(a) Polarity (b) molar mass (c) bonds (d) none
40. Boyle’s law is an example of ------- process
(a) Isothermal (b) isobaric (c) isochoric (d) all of given
41. The most abundant state of matter exist in universe is
(a) Solid (b) gas (c) liquid (d) plasma
42. The unit of gas constant R is
(a) JK–1 mol–1 (b) JK mol–1 (c) Cal K–2 mol–1 (d) both a and b
43. Correct expression for Charles’s law is
(a) V ∝T (b) V ∝ K (c) V = KT (d) both a and C
44. In dm3 atm K–1 mol–1 the value of ‘R’ is
(a) 0.821 (b) 0.0821 (c) 0.00821 (d) 0.000821
45. In Vander Waal’s equation, the pressure P in ideal gas equation is replaced by

( ) an an
2
an P+ an
(a) P= (b) 2 (c) P= (d) P= 2
V V V V
46. The temperature of V dm3 of an ideal gas is increased 4 times and pressure is doubled. The new volume is
(a) V dm3 (b) 2V dm3 (c) 8V dm3 (d) 6V dm3
47. Absolute zero is the temperature at which different gases are expected to have
(a) Same volume (b) different volume (c) zero volume (d) maximum volume
48. At constant temperature, the pressure of gas is reduced to one third the volume
(a) Decreases three time (b) Remains same
(c) Increases three time (d) first increase than decrease
49. Under which set of condition will CO has the greatest molar volume
(a) High T & high P (b) low T & high P (c) high T & low P (d) cannot be predicted
50. Observed pressure is almost equal to real pressure for a gas if
(a) A is small and b is large (b) a is large and b is small
(c) Both a and b are large (d) both a and b are small
51. When temperature of water decrease from 25 OC to 0 OC, its density
(a) First decreases then increase (b) first increase than decrease
(c) Remains same (d) by decreasing temperature density always increase
52. At higher temperature isothermal curve moves away from both the axes because of increase in
(a) Pressure (b) number of moles (c) volume (d) all of these
53. The temperature 32 dm3 of O2 was increased from 200 K to 400 K. The new volume will be
(a) 32 dm3 (b) 64 dm3 (c) 48 dm3 (d) 16 dm3
54. Main cause of deviation of real gases from ideal behavior is
(a) There are forces of attraction
(b) Actual volume of gas is not negligible as compared to total volume of vessel
(c) Gases exert pressure when strikes with the walls of the container (d) both a and b
55. Excluded volume b= ------- Vm
(a) 5 (b) 3 (c) 4 (d) 8
56. If a graph is plotted b/w ‘T’ on x-axis and volume on y – axis for 1 mole of a gas, then we get straight line,
which cuts, the temperature axis at
(a) – 300 0C (b) – 273, 16 0C (c) – 273 , 16 K (d) 273 0C
57. Bonding b/w two atoms within same molecule is
(a) Inter molecular (b) H – bonding (c) intramolecular (d) all of these
58. Pressure of one mole of an ideal gas is given by
−2
nRT RT RT
(a) (b) (c) (d) none
V V V
59. Amorphous solids do not have
(a) Sharp melting point (b) Regularity of structure
(c) Fixed by geometrical shape (d) all of these
60. Which of following is non crystalline solid
(a) Rubber (b) ZnS (c) HgS (d) Pbl
61. Most common form of matter around us is
(a) Solid (b) gas (c) liquid (d) plasma
62. For one mole of a gas the ideal gas equation is
1
(a) PV = nRT (b) PV = RT (c) PV = RT (d) both a and c
2
63. Mathematically Boyle’s law can be expressed as
1 k
(a) V ∝ (b) PV = K (c) V = (d) all of these
P P
64. Equal volume of all gases at same temperature and pressure contain equal number of molecules defined by
(a) Charles’s law (b) Combined law (c) Boyle’s law (d) Avogadro’s law
65. Maximum root mean square velocity is shown by the following gas
(a) SO2 (b) CO2 (c) Cl2 (d) N2
66. A container contain a gas at 1 atm. To compress it 1/3, the pressure applied is
(a) 1 atm (b) 2 atm (c) 3 atm (d) 6 atm
67. A fire extinguisher delivers 2.2 Kg of CO2. The volume of CO2 at room temperature is (molar volume at
R.T.P = 24 dm3)
(a) 12 dm3 (b) 120 dm3 (c) 1200 dm3 (d) 2400 dm3
68. Which of the following is most ideal at STP
(a) H2S (b) SO2 (c) H2 (d) NH3
69. If absolute temperature is doubled and P is also doubled the volume of the ideal gas
(a) Remains same (b) becomes double (c) reduced to ½ (d) first becomes double and then unchanged
70. Which is not the property of an ideal gas
(a) Particles have negligible volume (b) particles have zero mass
(c) Particles have no attractive forces (d) the average K.E is directly proportional to T
71. 1 atm is not equal to
(a) 760 torr (b) 101325 kPa (c) 1.47 psi (d) 1.01325 bar
72. Atmospheric pressure is due to partial pressure of
(a) N2 (b) CO2 (c) O2 (d) all of these
73. If volume of an ideal gas at 0 OC is 546 cm3. What is volume at 100 OC
(a) 566 cm3 (b) 846 cm3 (c) 746 cm3 (d) 646 cm3
74. At room temperature the correct order of Crms of CH4 and O2 gases is
(a) CH4 > O2 (b) CH4 < O2 (c) CH4 = O2 (d) all of these
75. Rate of evaporation is independent of
(a) Pressure (b) surface area (c) temperature (d) depends upon all
76. The B.P of a liquid ---- with external pressure
(a) Remains same (b) decrease (c) increase (d) Changes
77. Partial of diamond are packed by
(a) Covalent bond (b) H – bond (c) ionic bond (d) none of these
78. Which of the following is NOT the basic assumption of the kinetic theory of gases
(a) The collisions among the molecules of the gas are perfectly elastic
(b) The molecules of the gas are always in the state of senseless haphazard motion
(c) The pressure of a gas is due to collision of gas molecules with the wall of container
(d) The molecules exert appreciable attraction on each other
79. By increasing temperature boiling point of water will
(a) Increase (b) decrease (c) remain same (d) cannot be predicted
80. The molecule of which of the following gases have largest average K.E. at 250 OC
(a) Argon (b) Carbon mono oxide (c) Helium (d) all have same the same K.E
81. The compressibility factor of gas has value at which a gas show maximum non-ideality in behavior
(a) 1.5 (b) 1.1 (c) 1.0 (d) 0.9
82. For a given substance, which phase change has highest ∆H value
(a) Solid  liquid (b) Solid  gas (c) liquid  gas (d) Gas  liquid
83. ---- has highest ∆H, (enthalpy of vaporization)
(a) Butane (b) Isobutene (c) Pentane (d) Neopantane
84. The co-ordination number of cation in NaCl crystal is
(a) 1 (b) 4 (c) 8 (d) 6
85. The separation or purification of high boiling liquids under reduced pressure is carried out by
(a) Fractional distillation (b) Dry distillation
(c) Destructive distillation (d) Vacuum distillation
86. Which of the following is a crystalline solid?
(a) Rubber (b) Gases (c) sugar (d) glue
87. Which one of the following is true solid
(a) Metals (b) Amorphous (c) Crystalline (d) Vitreous
88. A real gas behaves mostly as an ideal gas, when temperature and pressure will
(a) High , high (b) low, low (c) High , low (d) Low, high