Problem-Set-3-4
Problem-Set-3-4
1. Determine the empirical formulas for compounds with the following percent compositions:
(a) 15.8% carbon and 84.2% sulfur
(b) 40.0% carbon, 6.7% hydrogen, and 53.3% oxygen
2. Determine the empirical and molecular formula for chrysotile asbestos. Chrysotile has the
following percent composition: 28.03% Mg, 21.60% Si, 1.16% H, and 49.21% O. The molar mass for
chrysotile is 520.8 g/mol.
3. Polymers are large molecules composed of simple units repeated many times. Thus, they often
have relatively simple empirical formulas. Calculate the empirical formulas of the following
polymers:
(a) Lucite (Plexiglas); 59.9% C, 8.06% H, 32.0% O
(b) Saran; 24.8% C, 2.0% H, 73.1% Cl
(c) polyethylene; 86% C, 14% H
(d) polystyrene; 92.3% C, 7.7% H
(e) Orlon; 67.9% C, 5.70% H, 26.4% N
4. What is the empirical and molecular formula for sucralose? The percent composition is 36.25%
C, 4.82% H, 26.75% Cl and 32.19% O. The molar mass is 397.63 g/mole.
5. has an empirical formula of C3H4N2 and a molar mass of 204.23 g/mole. What is the correct
molecular formula?
6. A compound is found to contain 23.3% magnesium, 30.7% sulfur, and 46.0% oxygen. What is the
empirical formula of this compound?
7. What is the empirical formula for a compound containing 38.8% carbon, 16.2% hydrogen, and
45.1% nitrogen?
8. What is the empirical formula for a compound containing 26.57% potassium, 35.36% chromium,
and 38.07% oxygen?
9. What is the empirical formula of a compound comprising 1.8% hydrogen, 56.1% sulfur, and
42.1% oxygen?
10. A borane is a compound containing only boron and hydrogen. If a borane is found to contain
88.45% boron, what is its empirical formula?
11. What is the empirical formula of a compound containing 47.37% carbon, 10.59% hydrogen, and
42.04% oxygen?
12. Fructone is used in different types of perfumes as a synthetic fruit-aroma additive. It contains
55.17 % C, 8.046 % H and the rest being oxygen. Determine the empirical and molecular formula of
Fructone considering that its molar mass is 174.0 g/mol.
PERCENT COMPOSITION:
1. Analysis of a 12.04-g sample of a liquid compound composed of carbon, hydrogen, and nitrogen
showed it to contain 7.34 g C, 1.85 g H, and 2.85 g N. What is the percent composition of this
compound?
2. A 24.81-g sample of a gaseous compound containing only carbon, oxygen, and chlorine is
determined to contain 3.01 g C, 4.00 g O, and 17.81 g Cl. What is this compound’s percent
composition?
3. Calculate the percentage composition of butane, C4H10. How many percent of carbon and
hydrogen, by mass, does butane contain?