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Chapter 2. Atoms and Elements Chapter 2. Atoms and Elements
Solution Manual for Chemistry A Molecular Approach 3rd Edition by Tro ISBN
0321809246 9780321809247
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Student Objectives
Describe scanning tunneling microscopy (STM) and how atoms are imaged on surfaces.
Define atom and element.
State and understand the law of conservation of mass (also from Section 1.2).
State and understand the law of definite proportions.
State and understand the law of multiple proportions.
Know the four postulates of Dalton’s atomic theory.
Describe J. J. Thomson’s experiments with the cathode ray tube and understand how they
provide evidence for the electron.
Describe Robert Millikan’s oil‐drop experiment and understand how it enables measurement of
the charge of an electron.
2.7 Finding Patterns: The Periodic Law and the Periodic Table
Understand the relationship between mass and count of objects such as atoms.
Define mole and Avogadro’s number.
Calculate and interconvert between number of moles and atoms.
Calculate and interconvert between number of moles and mass.
Section Summaries
Lecture Outline
TeachingLctureOutlineTps
2.1 Imaging and Moving Individual Atoms Intro figure: tip of an STM
Description of scanning tunneling microscopy (STM) moving across a surface
Introduction to macroscopic and microscopic Figure 2.1 Scanning Tunneling
perspectives. Microscopy
Definitions of atom and element. Figure 2.2 Imaging Atoms
2.3 Modern Atomic Theory and the Laws That Led to It unnumbered figure: models and
Law of conservation of mass photos of Na and Cl 2 forming
o Matter is neither created nor destroyed. NaCl
o Atoms at the start of a reaction may recombine to Example 2.1 Law of Definite
form different compounds, but all atoms are Proportions
accounted for at the end. unnumbered figure: models of
o Mass of reactants = mass of products. CO and CO 2 illustrating the law of
Law of definite proportions multiple proportions
o Different samples of the same compound have Example 2.2 Law of Multiple
the same proportions of constituent elements Proportions
independent of sample source or size. Chemistry in Your Day: Atoms
Law of multiple proportions and Humans
John Dalton’s atomic theory
Chapter 2. Atoms and Elements Chapter 2. Atoms and Elements
TeachingLctureOutlineTps
Chapter 2. Atoms and Elements Chapter 2. Atoms and Elements
TeachingLctureOutlineTps
2.1 Imaging and Moving Individual Atoms STM is not actually showing
Other STM images can be found readily on the Internet. images of atoms like one might
It is useful to reiterate the analogies about size; the one imagine seeing with a light
used in the chapter compares an atom to a grain of sand microscope.
and a grain of sand to a large mountain range. Atoms are not colored spheres;
the images use color to
distinguish different atoms.
2.2 Early Ideas about the Building Blocks of Matter Theories are not automatically
The view of matter as made up of small, indestructible accepted and may be unpopular
particles was ignored because more popular philosophers for long periods of time.
like Aristotle and Socrates had different views. Leucippus Philosophy and religion can be
and Democritus may have been proven correct, but they supported by arguments; science
had no more evidence for their ideas than Aristotle did. requires that theories be testable
and therefore falsifiable.
Observations and data led scientists to question models;
the scientific method promotes the use of a cycle of
such inquiry.
2.3 Modern Atomic Theory and the Laws That Led to It Measurements to establish early
That matter is composed of atoms grew from experiments atomic theories were performed
and observations. at the macroscopic level. The
Conceptual Connection 2.1 The Law of Conservation of scientists observed properties
Mass for which they could collect data
Investigating the law of definite proportions requires (e.g., mass or volume).
preparing or decomposing a set of pure samples of a
compound like water.
Investigating the law of multiple proportions requires
preparing or decomposing sets of pure samples from
related compounds like NO, NO 2 , and N 2 O 5 .
Conceptual Connection 2.2 The Laws of Definite and
Multiple Proportions
Chapter 2. Atoms and Elements Chapter 2. Atoms and Elements
TeachingLctureOutlineTps
2.4 The Discovery of the Electron Figure 2.3 Cathode Ray Tube
TeachingLctureOutlineTps
TeachingLctureOutlineTps
TeachingLctureOutlineTps
TeachingLctureOutlineTps
LectureTachingOutlinepsT
Isotopic abundances are invariant in typical lab‐sized samples mistakenly) presume that
because of such large numbers of atoms. the mass of an isotope is
Conceptual Connection 2.5 The Nuclear Atom, Isotopes, and Ions equal to the sum of the
The history of chemistry involves considerable cultural and masses of the protons and
gender diversity. Examples include both Lavoisiers (French), neutrons in that isotope.
Dalton (English), Thomson (English), Marie Curie
(Polish/French), Mendeleev (Russian), Millikan (American),
Robert Boyle (Irish), Amedeo Avogadro (Italian).
The Chemistry in Your Day box gives a broad description of the
origin of atoms.
2.7 Finding Patterns: The Periodic Law and the Periodic Table The periodic table is
Other displays of the periodic table can be found in journals better at predicting
(Schwartz, J. Chem. Educ . 2006, 83, 849; Moore, J. Chem. Educ. microscopic properties,
2003, 80, 847; Bouma, J. Chem. Educ. 1989, 66, 741), books, though macroscopic
and on the Internet. properties are also
Periodic tables are arranged according to the periodic law but often illustrated.
can compare many features, e.g. phases of matter, sizes of atoms,
and common ions. These are presented as a series of figures in
the text.
Chemistry and Medicine: The Elements of Life provides an
opportunity to relate the topics to everyday life. Some of the
other elements in the figure and table represent trace
minerals that are part of good nutrition. The periodic law
accounts for why some are necessary and others are toxic.
Chapter 2. Atoms and Elements Chapter 2. Atoms and Elements
LectureTachingOutlinepsT
LectureTachingOutlinepsT
2.8 Atomic Mass: The Average Mass of an unnumbered figure: periodic table box for Cl
Element’s Atoms Example 2.5 Atomic Mass
Average atomic mass is based on Figure 2.16 The Mass Spectrometer
natural abundance and isotopic masses. Figure 2.17 The Mass Spectrum of Chlorine
Mass spectrometry
o atoms converted to ions and
deflected by magnetic fields to
separate by mass
o output data: relative mass vs.
relative abundance
2.9 Molar Mass: Counting Atoms by Weighing unnumbered figure: pennies containing ~1 mol of
Them Cu
Mole concept and Avogadro’s number unnumbered figure: 1 tbsp of water contains ~1
LectureTachingOutlinepsT
LectureTachingOutlinepsT
Terms, Concepts, Skills Figures, Tables, and Solved Example Pitfalls
2.8 Atomic Mass: The Average Mass of an Element's Atoms The Students are tempted to
masses of isotopes must be reconciled with an element calculate average atomic mass
having only whole number quantities of protons and by adding together isotopic
neutrons; the values should be nearly integral since the masses and dividing by the
mass of electrons is so small. number of isotopes.
Mass spectrometry is an effective way to demonstrate Atomic mass on the periodic
where values of natural abundance are obtained. table is usually not integral
even though elements have only
whole numbers of protons and
neutrons.
2.9 Molar Mass: Counting Atoms by Weighing Them Many students are intimidated
Review the strategy for solving numerical problems: by estimating answers in
sort, strategize, solve, check. calculations involving powers
Estimating answers is an important skill; the number of of ten.
atoms will be very large (i.e. some large power of
ten) even from a small mass or small number of
moles. Conceptual Connection 2.7 Avogadro’s Number
Conceptual Connection 2.8 The Mole
Chapter 2. Atoms and Elements Chapter 2. Atoms and Elements
Additional Problem for Converting between Calculate the number of moles of iron in a sample that
23
Number of Moles and Number of Atoms has 3.83 x 10 atoms of iron.
(Example 2.6)
23
Sort Given 3.83 x 10 Fe atoms
You are given a number of iron atoms and Find mol Fe
asked to fi nd the amount of iron in moles.
Relationships Used
23
6.022 x 1 0 = 1 mol (Avogadro’s number)
Solve Solution
Additional Problem for Converting between Calculate the number of grams of silver in an
Mass and Number of Moles (Example 2.7) American Silver Eagle coin that contains
Relationships Used
107.87 g Ag = 1 mol Ag
Solve Solution
Follow the conceptual plan to solve the problem. 107. 87 g Ag
0.288 mol Ag = 31.07 g Ag
Start with 0.288 mol, the given number, and multiply 1 mol Ag
by the molar mass of silver.
31.07 g = 31.1 g Ag
22
Additional Problem for the Mole Concept— What mass of iron (in grams) contains 1.20 10
Converting between Mass and Number of atoms of Fe? A paperclip contains about that number
Atoms (Example 2.8) of iron atoms.
22
Sort Given 1.20 10 Fe atoms
You are given a number of iron atoms and asked Find g Fe
to find the mass of Fe.
Relationships Used
6.022 10 23
= 1 mol (Avogadro’s number)
55.85 g Fe = 1 mol Fe
Solve Solution
Follow the conceptual plan to solve the problem. 1 mol Fe 55.85 g Fe
22
1.20 10 Fe atoms
Begin with 1.20 x 1022 atoms of Fe, multiply by 6.022 10
23
Fe atoms 1 mol Fe
22
Additional Problem for the Mole Concept An iron sphere contains 8.55 10 iron atoms.
(Example 2.9) What is the radius of the sphere in centimeters?
3
The density of iron is 7.87 g/cm .
22
Sort Given 8.55 10 Fe atoms
3
You are given the number of iron atoms in a sphere d = 7.87 g/cm
and the density of iron. You are asked to find the Find radius (r) of a sphere
radius of th e sphere.
3
3V 3 1.00757 cm
3
r = 3 = = 0.622 cm
4 4
Check The units (cm) are correct and the magnitude of the
answer makes sense compared with previous
problems.
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love, has restored to Meleander all the honours he formerly enjoyed,
together with new honours and marks of favour undreamed of. Then
at last Eroclea is presented to him and his restored reason stands
the test of happiness. Explanations ensue; all part friends; and
“sorrows are changed to bride-songs.”
It will be seen that Ford’s conception of madness is by no means
a low one; he has not debased it by making it a sport for those to
whom it is a thing to fleer and jest at; he has introduced it into
comedy indeed, but it must be remembered that Ford’s tragi-comedy
is a wholly different thing from the gross buffooneries of Fletcher,
Dekker and Middleton, and that the madness of Meleander, though
resembling that of Lear, is on a far lower scale. It rises now and then
to unusual heights, but remains at their exalted level for so short a
time that we never look at it seriously for long. The gloom is also
lightened by the antics of the whimsical Corax, whose triumphs of
psycho-medical skill would, no doubt, in happier times, have induced
him to set up a private Bedlam of his own!
In considering Chettles’ “Tragedy of Hoffman”[96:1] we are met by
an initial difficulty of authorship, for the resemblance between this
play and “Hamlet,” as well as between Lucibella and Ophelia, would
suggest plagiarism. The question, however, is difficult to decide, and
can hardly be discussed here. Whatever be the solution, Lucibella is
a most effective character. To a certain degree her madness is
merely conventional. But there are numerous touches of real art in
her portrayal, and she is not degraded like the Gaoler’s Daughter in
“The Two Noble Kinsmen” by being made “a motley to the view.” On
the contrary, as one editor points out, Chettle surpasses
Shakespeare by making her, unlike Ophelia, directly instrumental in
bringing about the dénouement of the play.
The madness of Lucibella is brought about by the murder of her
lover, Lodowick, through the agency of Hoffman. In her mad
wanderings she discovers the skeletons of Hoffman’s father, and of
Prince Otho, for whose death her lover’s murderer is also
responsible. Eventually the mischief caused by the first shock is
undone by a second; Lucibella recovers her reason. Hear her in her
first ravings:
She cannot make up her mind whether her lover is really dead or
not. Only conscious of a vague calamity, she cries:
So saying, she knocks violently at the door of the vault; those who
surround her fear that she will “do violence upon herself.” She
understands:
This ditty is reminiscent of the descent to the cave, but the next
moment the memory of that is gone and only the consciousness of
her loss remains:
But at length, gradually and before our eyes, she recovers her lost
reason. Her speech to the Duchess of Luneberg shews what seems
to be the wandering of her still distraught mind. She displays the
rich clothes of Otho:
And she breaks into song again. But shortly afterwards she
recognises the two corpses, and as Lorick unfolds the ghastly story
of Hoffman’s crime the princess comes to her right mind again. At
the end of the scene she declares her complete sanity:
“Melancholy
And at the height, too, near akin to madness . . .
. . . His senses are distracted,” says Paulo,
“Not one, but all; and if I can collect them
With all the various ways invention
Or industry e’er practised, I shall write it
My masterpiece.”[100:1]
Who can wonder, for “Protean Paulo” with his quaint devices shews
a truly super-human versatility. At all events, he succeeds in
gathering the “scatter’d sense” of Cardenes, who thanks him
profusely for having been
“hangmen,
That come to bind my hands, and then to drag me
Before the judgment seat: now they are new shapes,
And do appear like Furies, with steel whips
To scourge my ulcerous soul. Shall I then fall
Ingloriously and yield? No! spite of Fate,
I will be forced to hell like to myself.
Though you were legions of accursed spirits,
Thus would I fly among you.”[102:1]
He flings himself on the ground, foaming and biting the earth, only
to be disarmed, bound and carried “to some dark room.” He will be
tended by physicians from Bedlam, who will try
The climax could hardly be more effective, were it not for Lord
Lovell, who, before winding up the business of the play, thinks it
necessary to point the moral in the most objectionable manner, only
surpassed by Massinger himself elsewhere:
he commands him:
“not Hercules
Could have knock’d out his brains, for he had none”;
[120:1]
“O melancholy!
Who ever yet could find thy bottom? find
The ooze, to show what coast thy sluggish crare
Might easiliest harbour in,”[127:2]
he is expressing feelings shared by anyone who tries to fathom the
treatment of melancholy by Shakespeare’s own contemporaries.
There was no common and generally recognised conception of
melancholy as of the more obvious forms of insanity. Hence it
becomes impossible to consider the question of melancholy from the
standpoint of medicine, still less to make any division such as the
threefold medical division of to-day, into acute melancholia, excited
melancholia, and that alternation of depression and excitement
known as “folie circulaire.” We shall instead divide our subject more
broadly and simply into Melancholy True and Melancholy False,
taking but a few typical cases to illustrate each of these divisions in
turn.
By Melancholy True is meant what we call nowadays
“melancholia,”—that is, a mental disease in which the prevailing
symptom is depression,—a mental disease from the author’s point of
view and not merely from ours. Some cases which would come
under this heading have already, for convenience’ sake, been treated
above. There is the melancholia of Penthea, hardly distinguishable
from madness, and utilised dramatically in a similar way. There is
also the melancholy of Palador, which seems to us less a case for the
physician than it did to the author. Ford’s conception of melancholy
as a disease is clearly influenced by Burton, and he would no doubt
have agreed with the doctors of Christopher Sly that “Melancholy is
the Nurse of frenzy,”[128:1] if, indeed, he would not have gone
farther and declined to distinguish between them. Other cases of
melancholia are merely described, and will hardly repay study. Such
is Viola’s well-known description of one (imaginary) girl who
In the next scene, however, when the presence of the bride makes
the hurt keener, her tongue is loosened. No sweeter song, in spite of
the rather vulgar criticism of Evadne, can be found outside
Shakespeare than the only one Aspatia gives us:
“Lay a garland on my hearse,
Of the dismal yew,
Maidens, willow trenches bear;
Say I died true;
My love was false, but I was firm
From my hour of birth.
Upon my buried body lie
Lightly, gentle earth.”[130:1]
“Fie on’t madam!” says Evadne, “The words are so strange, they are
able to make one dream of hobgoblins.”
The effect of Aspatia’s appearances enhances enormously the
effect of the play as a whole.