SAFETY DATA SHEET

Based upon Regulation (EC) No. 1907/2006, as amended by Regulation (EC) No. 453/2010

Solvent Cleaner
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier:
Product name : Solvent Cleaner
Product type REACH : Mixture

1.2 Relevant identified uses of the substance or mixture and uses advised against:
1.2.1 Relevant identified uses
Cleansing product

1.2.2 Uses advised against

No uses advised against known

1.3 Details of the supplier of the safety data sheet:

Supplier of the safety data sheet
SOUDAL N.V.
Everdongenlaan 18-20
B-2300 Turnhout
☎ +32 14 42 42 31
+32 14 42 65 14
[email protected]

Manufacturer of the product

SOUDAL N.V.
Everdongenlaan 18-20
B-2300 Turnhout
☎ +32 14 42 42 31
+32 14 42 65 14
[email protected]

1.4 Emergency telephone number:

24h/24h (Telephone advice: English, French, German, Dutch):
+32 14 58 45 45 (BIG)

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture:
2.1.1 Classification according to Regulation EC No 1272/2008
Classified as dangerous according to the criteria of Regulation (EC) No 1272/2008
Class Category Hazard statements
Flam. Liq. category 2 H225: Highly flammable liquid and vapour.
Eye Irrit. category 2 H319: Causes serious eye irritation.
STOT SE category 3 H335: May cause respiratory irritation.
STOT SE category 3 H336: May cause drowsiness or dizziness.
Aquatic Chronic category 2 H411: Toxic to aquatic life with long lasting effects.

2.1.2 Classification according to Directive 67/548/EEC-1999/45/EC

Classified as dangerous in accordance with the criteria of Directives 67/548/EEC and 1999/45/EC
F; R11 - Highly flammable.
Xi; R36 - Irritating to eyes.
R66 - Repeated exposure may cause skin dryness or cracking.
R67 - Vapours may cause drowsiness and dizziness.
N; R51-53 - Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.

2.2 Label elements:

Labelling according to Regulation EC No 1272/2008 (CLP)
Drawn up according to the criteria of Regulation (EU) No 487/2013, 4th adaptation of Regulation (EC) No 1272/2008

Signal word Danger

134-15960-447-en

Created by: Brandweerinformatiecentrum voor gevaarlijke stoffen vzw (BIG) Publication date: 2008-07-15
Technische Schoolstraat 43 A, B-2440 Geel Date of revision: 2014-10-07
http://www.big.be
© BIG vzw
Reason for revision: CLP
Revision number: 0100 Product number: 46475 1 / 16
 Solvent Cleaner
H-statements
H225 Highly flammable liquid and vapour.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H411 Toxic to aquatic life with long lasting effects.
P-statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P280 Wear protective gloves and eye protection/face protection.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
P337 + P313 If eye irritation persists: Get medical advice/attention.
P501 Dispose of contents/container in accordance with local/regional/national/international regulation.
Supplemental information
EUH066 Repeated exposure may cause skin dryness or cracking.
Labelling according to Directive 67/548/EEC-1999/45/EC (DSD/DPD)
Labels

Highly flammable Harmful Dangerous for the

environment
R-phrases
36 Irritating to eyes
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
66 Repeated exposure may cause skin dryness or cracking
67 Vapours may cause drowsiness and dizziness
S-phrases
(02) (Keep out of the reach of children)
16 Keep away from sources of ignition - No smoking
33 Take precautionary measures against static discharges
43 In case of fire, use powder extinguisher
61 Avoid release to the environment. Refer to special instructions/safety data sheets.
(62) (If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label)

2.3 Other hazards:

CLP
May be ignited by sparks
Gas/vapour spreads at floor level: ignition hazard

DSD/DPD
May be ignited by sparks
Gas/vapour spreads at floor level: ignition hazard

SECTION 3: Composition/information on ingredients

3.1 Substances:
Not applicable

3.2 Mixtures:

Name CAS No Classification Classification according to

Conc. (C) Note Remark
REACH Registration No EC No according to DSD/DPD CLP

hydrocarbons, C7-C9, n-alkanes, isoalkanes, 30%<C<5 F; R11 Flam. Liq. 2; H225 (1)(10) Constituent
cyclics 0% Xn; R65 Asp. Tox. 1; H304
01-2119473851-33 R66 STOT SE 3; H336
R67 Aquatic Chronic 2; H411
N; R51-53
n-butyl acetate 123-86-4 1%<C<10 R10 Flam. Liq. 3; H226 (1)(2)(10) Constituent
01-2119485493-29 204-658-1 % R66 STOT SE 3; H336
R67

Reason for revision: CLP Publication date: 2008-07-15

Date of revision: 2014-10-07

Revision number: 0100 Product number: 46475 2 / 16

 Solvent Cleaner
acetone 67-64-1 10%<C<3 F; R11 Flam. Liq. 2; H225 (1)(2)(10) Constituent
01-2119471330-49 200-662-2 0% Xi; R36 Eye Irrit. 2; H319
R66 STOT SE 3; H336
R67
(1) For R-phrases and H-statements in full: see heading 16
(2) Substance with a Community workplace exposure limit
(10) Subject to restrictions of Annex XVII of Regulation (EC) No. 1907/2006

SECTION 4: First aid measures

4.1 Description of first aid measures:
General:
Check the vital functions. Unconscious: maintain adequate airway and respiration. Respiratory arrest: artificial respiration or oxygen. Cardiac arrest: perform
resuscitation. Victim conscious with laboured breathing: half-seated. Victim in shock: on his back with legs slightly raised. Vomiting: prevent
asphyxia/aspiration pneumonia. Prevent cooling by covering the victim (no warming up). Keep watching the victim. Give psychological aid. Keep the victim
calm, avoid physical strain. Depending on the victim's condition: doctor/hospital.
After inhalation:
Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service.
After skin contact:
Wash immediately with lots of water. Take victim to a doctor if irritation persists.
After eye contact:
Rinse immediately with plenty of water. Take victim to an ophthalmologist if irritation persists.
After ingestion:
Rinse mouth with water. Immediately after ingestion: give lots of water to drink. Do not induce vomiting. Consult a doctor/medical service if you feel
ll
4.2 Most important symptoms and effects, both acute and delayed:
4.2.1 Acute symptoms
After inhalation:
Irritation of the respiratory tract. Nausea. Headache. Central nervous system depression. Behavioural disturbances. Dizziness. Feeling of weakness.
Disturbances of consciousness.
After skin contact:
ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: Dry skin. Cracking of the skin.
After eye contact:
Irritation of the eye tissue. Redness of the eye tissue.
After ingestion:
Risk of aspiration pneumonia.
4.2.2 Delayed symptoms
No effects known.

4.3 Indication of any immediate medical attention and special treatment needed:
If applicable and available it will be listed below.

SECTION 5: Firefighting measures

5.1 Extinguishing media:
5.1.1 Suitable extinguishing media:
Polyvalent foam. Alcohol-resistant foam. BC powder. Carbon dioxide.
5.1.2 Unsuitable extinguishing media:
Solid water jet ineffective as extinguishing medium. Water spray ineffective as extinguishing medium.

5.2 Special hazards arising from the substance or mixture:

Upon combustion: CO and CO2 are formed.

5.3 Advice for firefighters:

5.3.1 Instructions:
If exposed to fire cool the closed containers by spraying with water. Do not move the load if exposed to heat. Take account of environmentally hazardous
firefighting water. Use water moderately and if possible collect or contain it.
5.3.2 Special protective equipment for fire-fighters:
Gloves. Protective goggles. Head/neck protection. Heat/fire exposure: compressed air/oxygen apparatus.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures:
Stop engines and no smoking. No naked flames or sparks. Spark- and explosionproof appliances and lighting equipment.
6.1.1 Protective equipment for non-emergency personnel
See heading 8.2
6.1.2 Protective equipment for emergency responders
Gloves. Protective goggles. Head/neck protection.
Suitable protective clothing
See heading 8.2
Reason for revision: CLP Publication date: 2008-07-15
Date of revision: 2014-10-07

Revision number: 0100 Product number: 46475 3 / 16

 Solvent Cleaner
6.2 Environmental precautions:
Contain leaking substance. Dam up the liquid spill. Try to reduce evaporation. Prevent soil and water pollution. Prevent spreading in sewers. Use appropriate
containment to avoid environmental contamination.

6.3 Methods and material for containment and cleaning up:

Take up liquid spill into absorbent material, e.g.: sand/earth. Scoop absorbed substance into closing containers. Carefully collect the spill/leftovers. Clean
contaminated surfaces with an excess of water. Take collected spill to manufacturer/competent authority. Wash clothing and equipment after handling.

6.4 Reference to other sections:

See heading 13.

SECTION 7: Handling and storage

The information in this section is a general description. If applicable and available, exposure scenarios are attached in annex. Always use the relevant exposure
scenarios that correspond to your identified use.

7.1 Precautions for safe handling:

Keep away from naked flames/heat. Insufficient ventilation: keep naked flames/sparks away. Take precautions against electrostatic charges. Avoid prolonged
and repeated contact with skin. Keep container tightly closed. Remove contaminated clothing immediately. Do not discharge the waste into the drain.
Insufficient ventilation: use spark-/explosionproof appliances and lighting system.

7.2 Conditions for safe storage, including any incompatibilities:

7.2.1 Safe storage requirements:
Storage temperature: room temperature. Store at room temperature. Keep out of direct sunlight. Keep container in a well-ventilated place. Limited time of
storage. Meet the legal requirements. Max. storage time: 365 day(s).
7.2.2 Keep away from:
Heat sources, ignition sources, oxidizing agents, (strong) acids.
7.2.3 Suitable packaging material:
HDPE.
7.2.4 Non suitable packaging material:
No data available

7.3 Specific end use(s):

If applicable and available, exposure scenarios are attached in annex. See information supplied by the manufacturer.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters:
8.1.1 Occupational exposure
a) Occupational exposure limit values
If limit values are applicable and available these will be listed below.

The Netherlands
Aceton Time-weighted average exposure limit 8 h (Public 501 ppm
occupational exposure limit value)
Time-weighted average exposure limit 8 h (Public 1210 mg/m³
occupational exposure limit value)
Short time value (Public occupational exposure limit 1002 ppm
value)
Short time value (Public occupational exposure limit 2420 mg/m³
value)
n-Butylacetaat Time-weighted average exposure limit 8 h (Private 99 ppm
occupational exposure limit value)
Time-weighted average exposure limit 8 h (Private 480 mg/m³
occupational exposure limit value)

EU
Acetone Time-weighted average exposure limit 8 h 500 ppm
(Indicative occupational exposure limit value)
Time-weighted average exposure limit 8 h 1210 mg/m³
(Indicative occupational exposure limit value)

Belgium
Acétate de n-butyle Time-weighted average exposure limit 8 h 150 ppm
Time-weighted average exposure limit 8 h 723 mg/m³
Short time value 200 ppm
Short time value 964 mg/m³
Acétone Time-weighted average exposure limit 8 h 500 ppm
Time-weighted average exposure limit 8 h 1210 mg/m³
Short time value 1000 ppm

Reason for revision: CLP Publication date: 2008-07-15

Date of revision: 2014-10-07

Revision number: 0100 Product number: 46475 4 / 16

 Solvent Cleaner
Acétone Short time value 2420 mg/m³

USA (TLV-ACGIH)
Acetone Time-weighted average exposure limit 8 h (TLV - 500 ppm
Adopted Value)
Short time value (TLV - Adopted Value) 750 ppm
n-Butyl acetate Time-weighted average exposure limit 8 h (TLV - 150 ppm
Adopted Value)
Short time value (TLV - Adopted Value) 200 ppm

France
Acétate de n-butyle Time-weighted average exposure limit 8 h (VL: 150 ppm
Valeur non réglementaire indicative)
Time-weighted average exposure limit 8 h (VL: 710 mg/m³
Valeur non réglementaire indicative)
Short time value (VL: Valeur non réglementaire 200 ppm
indicative)
Short time value (VL: Valeur non réglementaire 940 mg/m³
indicative)
Acétone Time-weighted average exposure limit 8 h (VRC: 500 ppm
Valeur réglementaire contraignante)
Time-weighted average exposure limit 8 h (VRC: 1210 mg/m³
Valeur réglementaire contraignante)
Short time value (VRC: Valeur réglementaire 1000 ppm
contraignante)
Short time value (VRC: Valeur réglementaire 2420 mg/m³
contraignante)

UK
Acetone Time-weighted average exposure limit 8 h 500 ppm
(Workplace exposure limit (EH40/2005))
Time-weighted average exposure limit 8 h 1210 mg/m³
(Workplace exposure limit (EH40/2005))
Short time value (Workplace exposure limit 1500 ppm
(EH40/2005))
Short time value (Workplace exposure limit 3620 mg/m³
(EH40/2005))
Butyl acetate Time-weighted average exposure limit 8 h 150 ppm
(Workplace exposure limit (EH40/2005))
Time-weighted average exposure limit 8 h 724 mg/m³
(Workplace exposure limit (EH40/2005))
Short time value (Workplace exposure limit 200 ppm
(EH40/2005))
Short time value (Workplace exposure limit 966 mg/m³
(EH40/2005))
b) National biological limit values
If limit values are applicable and available these will be listed below.
8.1.2 Sampling methods
If applicable and available it will be listed below.
Acetone (ketones 1) NIOSH 1300
Acetone (ketones I) NIOSH 2555
Acetone (organic and inorganic gases by Extractive FTIR) NIOSH 3800
Acetone (Volatile Organic compounds) NIOSH 2549
Acetone OSHA 69
Butyl acetate (Volatile Organic compounds) NIOSH 2549
n-Butyl Acetate (Esters I) NIOSH 1450
n-Butyl Acetate OSHA 1009
8.1.3 Applicable limit values when using the substance or mixture as intended
If limit values are applicable and available these will be listed below.
8.1.4 DNEL/PNEC values
DNEL - Workers
n-butyl acetate
Effect level (DNEL/DMEL) Type Value Remark
DNEL Long-term systemic effects inhalation 480 mg/m³
Acute systemic effects inhalation 960 mg/m³
Long-term local effects inhalation 480 mg/m³
Acute local effects inhalation 960 mg/m³

Reason for revision: CLP Publication date: 2008-07-15

Date of revision: 2014-10-07

Revision number: 0100 Product number: 46475 5 / 16

 Solvent Cleaner
acetone
Effect level (DNEL/DMEL) Type Value Remark
DNEL Acute local effects inhalation 2420 mg/m³
Long-term systemic effects dermal 186 mg/kg bw/day
Long-term systemic effects inhalation 1210 mg/m³
DNEL - General population
n-butyl acetate
Effect level (DNEL/DMEL) Type Value Remark
DNEL Long-term systemic effects inhalation 102.34 mg/m³
Acute systemic effects inhalation 859.7 mg/m³
Long-term local effects inhalation 102.34 mg/m³
Acute local effects inhalation 859.7 mg/m³
acetone
Effect level (DNEL/DMEL) Type Value Remark
DNEL Long-term systemic effects dermal 62 mg/kg bw/day
Long-term systemic effects inhalation 200 mg/m³
Long-term systemic effects oral 62 mg/kg bw/day
PNEC
n-butyl acetate
Compartments Value Remark
Fresh water 0.18 mg/l
Marine water 0.018 mg/l
Aqua (intermittent releases) 0.36 mg/l
STP 35.6 mg/l
Fresh water sediment 0.981 mg/kg sediment dw
Marine water sediment 0.0981 mg/kg sediment dw
Soil 0.0903 mg/kg soil dw
acetone
Compartments Value Remark
Fresh water 10.6 mg/l
Marine water 1.06 mg/l
Aqua (intermittent releases) 21 mg/l
Fresh water sediment 30.4 mg/kg sediment dw
Marine water sediment 3.04 mg/kg sediment dw
Soil 29.5 mg/kg soil dw
STP 100 mg/l
8.1.5 Control banding
If applicable and available it will be listed below.

8.2 Exposure controls:

The information in this section is a general description. If applicable and available, exposure scenarios are attached in annex. Always use the relevant exposure
scenarios that correspond to your identified use.
8.2.1 Appropriate engineering controls
Keep away from naked flames/heat. Insufficient ventilation: keep naked flames/sparks away. Take precautions against electrostatic charges. Measure the
concentration in the air regularly. Work under local exhaust/ventilation.
8.2.2 Individual protection measures, such as personal protective equipment
Avoid prolonged and repeated contact with skin. Keep container tightly closed. Do not eat, drink or smoke during work.
a) Respiratory protection:
Wear gas mask with filter type A if conc. in air > exposure limit.
b) Hand protection:
Gloves.
c) Eye protection:
Protective goggles.
d) Skin protection:
Head/neck protection. Protective clothing.
8.2.3 Environmental exposure controls:
See headings 6.2, 6.3 and 13

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties:
Physical form Liquid
Odour Characteristic odour
Odour threshold No data available
Colour Colourless
Particle size Not applicable (liquid)
Explosion limits No data available
Flammability Highly flammable liquid and vapour.

Reason for revision: CLP Publication date: 2008-07-15

Date of revision: 2014-10-07

Revision number: 0100 Product number: 46475 6 / 16

 Solvent Cleaner
Log Kow Not applicable (mixture)
Dynamic viscosity No data available
Kinematic viscosity No data available
Melting point No data available
Boiling point No data available
Flash point 12 °C
Evaporation rate No data available
Relative vapour density No data available
Vapour pressure No data available
Solubility No data available
Relative density 0.80
Decomposition temperature No data available
Auto-ignition temperature No data available
Explosive properties No chemical group associated with explosive properties
Oxidising properties No chemical group associated with oxidising properties
pH No data available

9.2 Other information:

Absolute density 791 kg/m³

SECTION 10: Stability and reactivity

10.1 Reactivity:
May be ignited by sparks. Gas/vapour spreads at floor level: ignition hazard.

10.2 Chemical stability:

Stable under normal conditions.

10.3 Possibility of hazardous reactions:

Reacts with (some) acids and with (strong) oxidizers.

10.4 Conditions to avoid:

Keep away from naked flames/heat. Insufficient ventilation: keep naked flames/sparks away. Take precautions against electrostatic charges.

10.5 Incompatible materials:

Oxidizing agents, (strong) acids.

10.6 Hazardous decomposition products:

Upon combustion: CO and CO2 are formed.

SECTION 11: Toxicological information

11.1 Information on toxicological effects:
11.1.1 Test results

Acute toxicity

Solvent Cleaner
No (test)data on the mixture available
hydrocarbons, C7-C9, n-alkanes, isoalkanes, cyclics
Route of exposure Parameter Method Value Exposure time Species Value Remark
determination
Oral LD50 Equivalent to OECD >5840 mg/kg bw Rat (male/female) Experimental value
401
Dermal LD50 >4 ml/kg bw 24 h Rat (male/female) Experimental value
Dermal LD50 >2920 ml/kg bw 24 h Rat Experimental value
Inhalation (vapours) LC50 Equivalent to OECD >23.2 mg/l air 4h Rat (male/female) Experimental value
403
n-butyl acetate
Route of exposure Parameter Method Value Exposure time Species Value Remark
determination
Oral LD50 Equivalent to OECD 12789 mg/kg Rat (male) Experimental value
423
Oral LD50 Equivalent to OECD 10760 mg/kg bw Rat (female) Experimental value
423
Dermal LD50 Equivalent to OECD >14112 mg/kg bw 24 h Rabbit Experimental value
402 (male/female)
Inhalation (vapours) LC50 OECD 403 >21 mg/l air 4h Rat (male/female) Experimental value

Reason for revision: CLP Publication date: 2008-07-15

Date of revision: 2014-10-07

Revision number: 0100 Product number: 46475 7 / 16

 Solvent Cleaner
acetone
Route of exposure Parameter Method Value Exposure time Species Value Remark
determination
Oral LD50 Equivalent to OECD 5800 mg/kg Rat (female) Experimental value
401
Dermal LD50 Equivalent to OECD 20000 mg/kg Rabbit (male) Experimental value
402
Dermal LD50 >7426 mg/kg bw Rabbit (female) Weight of evidence
Inhalation (vapours) LC50 Other 76 mg/l 4h Rat (female) Experimental value
Inhalation (vapours) LCL0 Other 16000 ppm 4h Rat Experimental value
Classification is based on the relevant ingredients
Conclusion
Not classified for acute toxicity

Corrosion/irritation

Solvent Cleaner
No (test)data on the mixture available
n-butyl acetate
Route of exposure Result Method Exposure time Time point Species Value Remark
determination
Eye Not irritating OECD 405 24; 48; 72 hours Rabbit Experimental value Single treatment
Skin Not irritating Equivalent to 4h 24; 48; 72 hours Rabbit Experimental value
OECD 404
Inhalation Slightly irritating Human 3-5 minutes Human Experimental value
(vapours) observation
acetone
Route of exposure Result Method Exposure time Time point Species Value Remark
determination
Eye Irritating OECD 405 24; 48; 72 hours Rabbit Weight of evidence
Skin Not irritating Other 3 day(s) 24; 48; 72 hours Guinea pig Weight of evidence
Inhalation Slightly irritating Human 20 minutes Human Literature
observation study
Classification is based on the relevant ingredients
Conclusion
Irritating to the eyes
Irritating to the skin

Respiratory or skin sensitisation

Solvent Cleaner
No (test)data on the mixture available
n-butyl acetate
Route of exposure Result Method Exposure time Observation time Species Value determination Remark
point
Skin Not sensitizing 24 h 24 hours Human Inconclusive,
insufficient data
acetone
Route of exposure Result Method Exposure time Observation time Species Value determination Remark
point
Skin Not sensitizing Guinea pig 48 hours Hamster (female) Experimental value
maximisation test
Skin Not sensitizing Human observation Human Literature
Classification is based on the relevant ingredients
Conclusion
Not classified as sensitizing for inhalation
Not classified as sensitizing for skin

Specific target organ toxicity

Solvent Cleaner
No (test)data on the mixture available
n-butyl acetate
Route of exposure Parameter Method Value Organ Effect Exposure time Species Value
determination
Inhalation NOAEC EPA OTS 500 ppm No effect 13 weeks (6h/day, 5 Rat Experimental
(vapours) 798.2450 days/week) (male/female) value
Inhalation Central nervous Drowsiness, Literature study
(vapours) system dizziness

Reason for revision: CLP Publication date: 2008-07-15

Date of revision: 2014-10-07

Revision number: 0100 Product number: 46475 8 / 16

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acetone
Route of exposure Parameter Method Value Organ Effect Exposure time Species Value
determination
Oral NOAEL Equivalent to 20 mg/l No effect 13 week(s) Mouse Experimental
OECD 408 (male/female) value
Dermal Not relevant,
expert
Inhalation NOAEC Other 19000 ppm No effect 8 week(s) Rat (male) Literature
(vapours)
Inhalation Human 361 ppm Central nervous neurotoxic 2 day(s) Human Inconclusive,
(vapours) observation system effects insufficient data
study
Classification is based on the relevant ingredients
Conclusion
Vapours may cause drowsiness and dizziness.

Mutagenicity (in vitro)

Solvent Cleaner
No (test)data on the mixture available
n-butyl acetate
Result Method Test substrate Effect Value determination
Negative with metabolic Equivalent to OECD 471 Bacteria (S.typhimurium) No effect Experimental value
activation, negative without
metabolic activation
Negative without metabolic Equivalent to OECD 473 Chinese hamster lung No effect Experimental value
activation fibroblasts
acetone
Result Method Test substrate Effect Value determination
Negative Equivalent to OECD 471 Bacteria (S.typhimurium) No effect Experimental value
Negative Equivalent to OECD 473 Chinese hamster ovary (CHO) No effect Experimental value

Mutagenicity (in vivo)

Solvent Cleaner
No (test)data on the mixture available
n-butyl acetate
Result Method Exposure time Test substrate Organ Value determination
Negative OECD 474 24 h Mouse (male/female) Bone marrow Read-across
acetone
Result Method Exposure time Test substrate Organ Value determination
Negative 13 week(s) Mouse (male/female) Literature

Carcinogenicity

Solvent Cleaner
No (test)data on the mixture available
n-butyl acetate
Route of Parameter Method Value Exposure time Species Value Organ Effect
exposure determination
Inhalation Data waiving
Dermal Data waiving
Oral Data waiving
acetone
Route of Parameter Method Value Exposure time Species Value Organ Effect
exposure determination
Dermal NOEL Other 79 mg 51 week(s) Mouse (female) Literature No effect

Reproductive toxicity

Solvent Cleaner
No (test)data on the mixture available
n-butyl acetate
Parameter Method Value Exposure time Species Effect Organ Value
determination
Developmental toxicity LOAEC Equivalent to 1500 ppm 6 week(s) Rat Minor skeletal Foetus Experimental
OECD 414 variations value
Maternal toxicity LOAEC Equivalent to 1500 ppm 6 week(s) Rat Reduced food General Experimental
OECD 414 consumption value
Effects on fertility NOAEC OECD 416 2000 ppm 70 day(s) Rat No effect Experimental
(male/female) value

Reason for revision: CLP Publication date: 2008-07-15

Date of revision: 2014-10-07

Revision number: 0100 Product number: 46475 9 / 16

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acetone
Parameter Method Value Exposure time Species Effect Organ Value
determination
Developmental toxicity NOAEC Equivalent to 11000 ppm 6-19 days Rat Experimental
OECD 414 (gestation, (male/female) value
daily)
Effects on fertility NOAEL Other 900 mg/kg 13 week(s) Rat (male) No effect Literature
bw/day
Classification is based on the relevant ingredients
Conclusion CMR
Not classified for reprotoxic or developmental toxicity
Not classified for mutagenic or genotoxic toxicity
Not classified for carcinogenicity

Toxicity other effects

Solvent Cleaner
No (test)data on the mixture available
n-butyl acetate
Parameter Method Value Organ Effect Exposure time Species Value
determination
Skin Skin dryness or Literature study
cracking
acetone
Parameter Method Value Organ Effect Exposure time Species Value
determination
Skin Skin dryness or Literature study
cracking
Classification is based on the relevant ingredients
Conclusion
Repeated exposure may cause skin dryness or cracking.

Chronic effects from short and long-term exposure

Solvent Cleaner
No effects known.

SECTION 12: Ecological information

12.1 Toxicity:
Solvent Cleaner
No (test)data on the mixture available
hydrocarbons, C7-C9, n-alkanes, isoalkanes, cyclics
Parameter Method Value Duration Species Test design Fresh/salt Value determination
water
Acute toxicity fishes LC50 OECD 203 3 - 10 mg/l 96 h Oncorhynchus Experimental value
mykiss
Acute toxicity invertebrates EC50 OECD 202 4.6 - 10.0 48 h Daphnia magna Experimental value
mg/l
n-butyl acetate
Parameter Method Value Duration Species Test design
Fresh/salt Value determination
water
Acute toxicity fishes LC50 OECD 203 18 mg/l 96 h Pimephales Flow-through Fresh water Experimental value;
promelas system Lethal
Acute toxicity invertebrates EC50 44 mg/l 48 h Daphnia magna Static system Fresh water Experimental value;
Nominal
concentration
Toxicity algae and other aquatic EC50 674.7 mg/l 72 h Desmodesmus Static system Fresh water Experimental value;
plants subspicatus Growth rate
Long-term toxicity aquatic NOEC OECD 211 23 mg/l 21 day(s) Daphnia magna Fresh water Read-across;
invertebrates Reproduction
Toxicity aquatic micro- IC50 356 mg/l 40 h Tetrahymena Static system Fresh water Experimental value;
organisms pyriformis Nominal
concentration

Reason for revision: CLP Publication date: 2008-07-15

Date of revision: 2014-10-07

Revision number: 0100 Product number: 46475 10 / 16

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acetone
Parameter Method Value Duration Species Test design
Fresh/salt Value determination
water
Acute toxicity fishes LC50 EU Method 5540 mg/l 96 h Salmo gairdneri Static system Fresh water Experimental value;
C.1 Nominal
concentration
Acute toxicity invertebrates LC50 Other 12600 mg/l 48 h Daphnia magna Static system Fresh water Experimental value;
Nominal
concentration
Toxicity algae and other aquatic EC50 >7000 mg/l 96 h Selenastrum Static system Fresh water Experimental value;
plants capricornutum Nominal
concentration
Classification of the mixture is based on the relevant ingredients of the mixture

Conclusion
Toxic to aquatic organisms
Toxic to aquatic life with long lasting effects.

12.2 Persistence and degradability:

hydrocarbons, C7-C9, n-alkanes, isoalkanes, cyclics
Biodegradation water
Method Value Duration Value determination
OECD 301F: Manometric Respirometry Test 98 % 28 day(s) Read-across
n-butyl acetate
Biodegradation water
Method Value Duration Value determination
OECD 301D: Closed Bottle Test 83 % 28 day(s) Experimental value
Phototransformation air (DT50 air)
Method Value Conc. OH-radicals Value determination
AOPWIN v1.92 3.3 day(s) 0.5E6 /cm³ Experimental value
Half-life water (t1/2 water)
Method Value Primary Value determination
degradation/mineralisation
Other 2 year(s) Primary degradation Calculated value
acetone
Biodegradation water
Method Value Duration Value determination
OECD 301B: CO2 Evolution Test 90.9 % 28 day(s) Experimental value

Conclusion
Contains readily biodegradable component(s)

12.3 Bioaccumulative potential:

Solvent Cleaner
Log Kow
Method Remark Value Temperature Value determination
Not applicable (mixture)
hydrocarbons, C7-C9, n-alkanes, isoalkanes, cyclics
Log Kow
Method Remark Value Temperature Value determination
No data available
n-butyl acetate
BCF fishes
Parameter Method Value Duration Species Value determination
BCF 14 Pisces Literature study
Log Kow
Method Remark Value Temperature Value determination
OECD 117 2.3 25 °C Experimental value

Reason for revision: CLP Publication date: 2008-07-15

Date of revision: 2014-10-07

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acetone
BCF fishes
Parameter Method Value Duration Species Value determination
BCF 0.69 Pisces
BCF other aquatic organisms
Parameter Method Value Duration Species Value determination
BCF BCFWIN 3 Calculated value
Log Kow
Method Remark Value Temperature Value determination
-0.24 Test data
Conclusion
Does not contain bioaccumulative component(s)

12.4 Mobility in soil:

n-butyl acetate
(log) Koc
Parameter Method Value Value determination
log Koc SRC PCKOCWIN v2.0 1.268 - 1.844 QSAR
Volatility (Henry's Law constant H)
Value Method Temperature Remark Value determination
28.5 Pa.m³/mol 25 °C Experimental value

Conclusion
Contains component(s) with potential for mobility in the soil

12.5 Results of PBT and vPvB assessment:

Due to insufficient data no statement can be made whether the component(s) fulfil(s) the criteria of PBT and vPvB according to Annex XIII of
Regulation (EC) No 1907/2006.

12.6 Other adverse effects:

Solvent Cleaner
Global warming potential (GWP)
None of the known components is included in the list of fluorinated greenhouse gases (Regulation (EC) No 517/2014)
Ozone-depleting potential (ODP)
Not classified as dangerous for the ozone layer (Regulation (EC) No 1005/2009)

n-butyl acetate
Global warming potential (GWP)
Not included in the list of fluorinated greenhouse gases (Regulation (EC) No 517/2014)
Ground water
Ground water pollutant

SECTION 13: Disposal considerations

The information in this section is a general description. If applicable and available, exposure scenarios are attached in annex. Always use the relevant exposure
scenarios that correspond to your identified use.

13.1 Waste treatment methods:

13.1.1 Provisions relating to waste
Waste material code (Directive 2008/98/EC, Decision 2000/0532/EC).
07 06 04* (wastes from the MFSU of fats, grease, soaps, detergents, disinfectants and cosmetics: other organic solvents, washing liquids and mother
liquors). Hazardous waste according to Directive 2008/98/EC.
13.1.2 Disposal methods
Remove to an authorized plant for the destruction, neutralization and elimination of hazardous waste. Remove waste in accordance with local and/or
national regulations. Hazardous waste shall not be mixed together with other waste. Different types of hazardous waste shall not be mixed together if this
may entail a risk of pollution or create problems for the further management of the waste. Hazardous waste shall be managed responsibly. All entities
that store, transport or handle hazardous waste shall take the necessary measures to prevent risks of pollution or damage to people or animals. Do not
discharge into drains or the environment. Dispose of at authorized waste collection point.
13.1.3 Packaging/Container
Waste material code packaging (Directive 2008/98/EC).
15 01 10* (packaging containing residues of or contaminated by dangerous substances).

SECTION 14: Transport information

Road (ADR)
14.1 UN number:
UN number 1993
14.2 UN proper shipping name:

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Date of revision: 2014-10-07

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Proper shipping name Flammable liquid, n.o.s. (hydrocarbons, C7-C9, n-alkanes, isoalkanes,
cyclics), Special provision 640D
14.3 Transport hazard class(es):
Hazard identification number 33
Class 3
Classification code F1
14.4 Packing group:
Packing group II
Labels 3
14.5 Environmental hazards:
Environmentally hazardous substance mark yes
14.6 Special precautions for user:
Special provisions 274
Special provisions 601
Special provisions 640D
Limited quantities Combination packagings: not more than 1 liter per inner packaging for
liquids. A package shall not weigh more than 30 kg. (gross mass)

Rail (RID)
14.1 UN number:
UN number 1993
14.2 UN proper shipping name:
Proper shipping name Flammable liquid, n.o.s. (hydrocarbons, C7-C9, n-alkanes, isoalkanes,
cyclics), Special provision 640D
14.3 Transport hazard class(es):
Hazard identification number 33
Class 3
Classification code F1
14.4 Packing group:
Packing group II
Labels 3
14.5 Environmental hazards:
Environmentally hazardous substance mark yes
14.6 Special precautions for user:
Special provisions 274
Special provisions 601
Special provisions 640D
Limited quantities Combination packagings: not more than 1 liter per inner packaging for
liquids. A package shall not weigh more than 30 kg. (gross mass)

Inland waterways (ADN)

14.1 UN number:
UN number 1993
14.2 UN proper shipping name:
Proper shipping name Flammable liquid, n.o.s. (hydrocarbons, C7-C9, n-alkanes, isoalkanes,
cyclics), Special provision 640D
14.3 Transport hazard class(es):
Class 3
Classification code F1
14.4 Packing group:
Packing group II
Labels 3
14.5 Environmental hazards:
Environmentally hazardous substance mark yes
14.6 Special precautions for user:
Special provisions 274
Special provisions 601
Special provisions 640D
Limited quantities Combination packagings: not more than 1 liter per inner packaging for
liquids. A package shall not weigh more than 30 kg. (gross mass)

Sea (IMDG/IMSBC)
14.1 UN number:
UN number 1993
14.2 UN proper shipping name:
Proper shipping name Flammable liquid, n.o.s. (koolwaterstoffen, C7-C9, n-alkanen, iso-
alkanen, cyclische stoffen)
14.3 Transport hazard class(es):
Class 3

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Date of revision: 2014-10-07

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14.4 Packing group:
Packing group II
Labels 3
14.5 Environmental hazards:
Marine pollutant P
Environmentally hazardous substance mark yes
14.6 Special precautions for user:
Special provisions 274
Limited quantities Combination packagings: not more than 1 liter per inner packaging for
liquids. A package shall not weigh more than 30 kg. (gross mass)
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code:
Annex II of MARPOL 73/78 Not applicable, based on available data

Air (ICAO-TI/IATA-DGR)
14.1 UN number:
UN number 1993
14.2 UN proper shipping name:
Proper shipping name Flammable liquid, n.o.s. (koolwaterstoffen, C7-C9, n-alkanen, iso-
alkanen, cyclische stoffen)
14.3 Transport hazard class(es):
Class 3
14.4 Packing group:
Packing group II
Labels 3
14.5 Environmental hazards:
Environmentally hazardous substance mark yes
14.6 Special precautions for user:
Special provisions A3
Passenger and cargo transport: limited quantities: maximum net quantity 1 L
per packaging

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture:
European legislation:
VOC content Directive 2010/75/EU
VOC content Remark
>=90 %

REACH Annex XVII - Restriction

Contains component(s) subject to restrictions of Annex XVII of Regulation (EC) No 1907/2006: restrictions on the manufacture, placing on the market
and use of certain dangerous substances, mixtures and articles.
Designation of the substance, of the group of Conditions of restriction
substances or of the mixture
· hydrocarbons, C7-C9, n-alkanes, isoalkanes, Liquid substances or mixtures which are 1. Shall not be used in:
cyclics regarded as dangerous in accordance with — ornamental articles intended to produce light or colour effects by means of different
· n-butyl acetate Directive 1999/45/EC or are fulfilling the phases, for example in ornamental lamps and ashtrays,
· acetone criteria for any of the following hazard classes — tricks and jokes,
or categories set out in Annex I to Regulation — games for one or more participants, or any article intended to be used as such, even with
(EC) No 1272/2008: ornamental aspects,2. Articles not complying with paragraph 1 shall not be placed on the
(a) hazard classes 2.1 to 2.4, 2.6 and 2.7, 2.8 market.3. Shall not be placed on the market if they contain a colouring agent, unless
types A and B, 2.9, 2.10, 2.12, 2.13 categories 1 required for fiscal reasons, or perfume, or both, if they:
and 2, 2.14 categories 1 and 2, 2.15 types A to — can be used as fuel in decorative oil lamps for supply to the general public, and,
F; — present an aspiration hazard and are labelled with R65 or H304,4. Decorative oil lamps
(b) hazard classes 3.1 to 3.6, 3.7 adverse for supply to the general public shall not be placed on the market unless they conform to
effects on sexual function and fertility or on the European Standard on Decorative oil lamps (EN 14059) adopted by the European
development, 3.8 effects other than narcotic Committee for Standardisation (CEN).5. Without prejudice to the implementation of other
effects, 3.9 and 3.10; Community provisions relating to the classification, packaging and labelling of dangerous
(c) hazard class 4.1; substances and mixtures, suppliers shall ensure, before the placing on the market, that the
(d) hazard class 5.1. following requirements are met:
a) lamp oils, labelled with R65 or H304, intended for supply to the general public are visibly,
legibly and indelibly marked as follows: “Keep lamps filled with this liquid out of the reach of
children”; and, by 1 December 2010, “Just a sip of lamp oil — or even sucking the wick of
lamps — may lead to life- threatening lung damage”;
b) grill lighter fluids, labelled with R65 or H304, intended for supply to the general public are
legibly and indelibly marked by 1 December 2010 as follows: “Just a sip of grill lighter may
lead to life threatening lung damage”;
c) lamp oils and grill lighters, labelled with R65 or H304, intended for supply to the general
public are packaged in black opaque containers not exceeding 1 litre by 1 December 2010.6.
No later than 1 June 2014, the Commission shall request the European Chemicals Agency to
prepare a dossier, in accordance with Article 69 of the present Regulation with a view to
ban, if appropriate, grill lighter fluids and fuel for decorative lamps, labelled R65 or H304,
intended for supply to the general public.7. Natural or legal persons placing on the market
for the first time lamp oils and grill lighter fluids, labelled

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with R65 or H304, shall by 1 December 2011, and annually thereafter, provide data on
alternatives to lamp oils and grill lighter fluids labelled R65 or H304 to the competent
authority in the Member State concerned. Member States shall make those data available
to the Commission.’
· hydrocarbons, C7-C9, n-alkanes, isoalkanes, Substances classified as flammable gases 1. Shall not be used, as substance or as mixtures in aerosol dispensers where these aerosol
cyclics category 1 or 2, flammable liquids categories dispensers are intended for supply to the general public for entertainment and decorative
· n-butyl acetate 1, 2 or 3, flammable solids category 1 or 2, purposes such as the following:
· acetone substances and mixtures which, in contact — metallic glitter intended mainly for decoration,
with water, emit flammable gases, category 1, — artificial snow and frost,
2 or 3, pyrophoric liquids category 1 or — “whoopee” cushions,
pyrophoric solids category 1, regardless of — silly string aerosols,
whether they appear in Part 3 of Annex VI to — imitation excrement,
that Regulation or not. — horns for parties,
— decorative flakes and foams,
— artificial cobwebs,
— stink bombs.2. Without prejudice to the application of other Community provisions on
the classification, packaging and labelling of substances, suppliers shall ensure before the
placing on the market that the packaging of aerosol dispensers referred to above is marked
visibly, legibly and indelibly with:
“For professional users only”.3. By way of derogation, paragraphs 1 and 2 shall not apply to
the aerosol dispensers referred to Article 8 (1a) of Council Directive 75/ 324/EEC.4. The
aerosol dispensers referred to in paragraphs 1 and 2 shall not be placed on the market
unless they conform to the requirements indicated.

National legislation The Netherlands

Solvent Cleaner
Waste identification (the LWCA (the Netherlands): KGA category 03
Netherlands)
Waterbezwaarlijkheid 6
National legislation France
Solvent Cleaner
No data available

National legislation Belgium

Solvent Cleaner
No data available

15.2 Chemical safety assessment:

No chemical safety assessment is required.

SECTION 16: Other information

Full text of any R-phrases referred to under headings 2 and 3:
R10 Flammable
R36 Irritating to eyes
R51 Toxic to aquatic organisms
R53 May cause long-term adverse effects in the aquatic environment
R65 Harmful: may cause lung damage if swallowed
R66 Repeated exposure may cause skin dryness or cracking
R67 Vapours may cause drowsiness and dizziness
Full text of any H-statements referred to under headings 2 and 3:
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H411 Toxic to aquatic life with long lasting effects.
(*) = INTERNAL CLASSIFICATION BY BIG
PBT-substances = persistent, bioaccumulative and toxic substances
DSD Dangerous Substance Directive
DPD Dangerous Preparation Directive
CLP (EU-GHS) Classification, labelling and packaging (Globally Harmonised System in Europe)

The information in this safety data sheet is based on data and samples provided to BIG. The sheet was written to the best of our ability and according to the
state of knowledge at that time. The safety data sheet only constitutes a guideline for the safe handling, use, consumption, storage, transport and disposal
of the substances/preparations/mixtures mentioned under point 1. New safety data sheets are written from time to time. Only the most recent versions
may be used. Old versions must be destroyed. Unless indicated otherwise word for word on the safety data sheet, the information does not apply to
substances/preparations/mixtures in purer form, mixed with other substances or in processes. The safety data sheet offers no quality specification for the
substances/preparations/mixtures in question. Compliance with the instructions in this safety data sheet does not release the user from the obligation to
take all measures dictated by common sense, regulations and recommendations or which are necessary and/or useful based on the real applicable
circumstances. BIG does not guarantee the accuracy or exhaustiveness of the information provided and cannot be held liable for any changes by third
parties. This safety data sheet is only to be used within the European Union, Switzerland, Iceland, Norway and Liechtenstein. Any use outside of this area is
at your own risk. Use of this safety data sheet is subject to the licence and liability limiting conditions as stated in your BIG licence agreement or when this is
failing the general conditions of BIG. All intellectual property rights to this sheet are the property of BIG and its distribution and

Reason for revision: CLP Publication date: 2008-07-15

Date of revision: 2014-10-07

Revision number: 0100 Product number: 46475 15 / 16

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reproduction are limited. Consult the mentioned agreement/conditions for details.

Reason for revision: CLP Publication date: 2008-07-15

Date of revision: 2014-10-07

Revision number: 0100 Product number: 46475 16 / 16