Test - 5 (Code-A) (Answers) All India Aakash Test Series for JEE (Main)-2022

All India Aakash Test Series for JEE (Main)-2022

TEST - 5 (Code-A)
Test Date : 07/02/2021

ANSWERS
PHYSICS CHEMISTRY MATHEMATICS
1. (4) 26. (1) 51. (1)
2. (4) 27. (3) 52. (2)
3. (2) 28. (3) 53. (2)
4. (4) 29. (4) 54. (2)
5. (3) 30. (1) 55. (3)
6. (4) 31. (4) 56. (2)
7. (1) 32. (3) 57. (2)
8. (1) 33. (2) 58. (4)
9. (3) 34. (4) 59. (4)
10. (3) 35. (4) 60. (3)
11. (1) 36. (4) 61. (1)
12. (2) 37. (3) 62. (4)
13. (2) 38. (3) 63. (3)
14. (2) 39. (3) 64. (1)
15. (2) 40. (2) 65. (1)
16. (2) 41. (1) 66. (1)
17. (2) 42. (4) 67. (3)
18. (1) 43. (3)
68. (4)
19. (1) 44. (3)
69. (3)
20. (4) 45. (1)
70. (3)
21. (06.00) 46. (05.00)
71. (18.00)
22. (24.00) 47. (06.00)
72. (20.00)
23. (17.00) 48. (05.00)
73. (04.00)
24. (05.00) 49. (56.00)
74. (05.00)
25. (66.00) 50. (48.00)
75. (05.00)

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All India Aakash Test Series for JEE (Main)-2022 Test - 5 (Code-A) (Hints & Solutions)

PART – A : PHYSICS Sol. : T2 = 1200 K

Q = nCv (T2 –T1)
1. Answer (4)
15 R
Vrms (He) M Ar =  5   900
Hint : = at same temperature 28 2
Vrms (Ar) MHe
= 10 kJ
V (He) 40
Sol : rms = = 3.16 6. Answer (4)
Vrms (Ar) 4
T2 T T
Hint :  = 1 − = 1− 3 = 1− 4
2. Answer (4) T1 T2 T3
Hint : QACB = WACB + UACB
Sol. : T2 = T1 T3 , T3 = T2 T4
Sol. :  60 = 30 + UACB
T32 = T11/2 T31/2 T4
 30 J = UACB = UADB
And, QADB = WADB + UADB T33/2 = T11/2 T4

= (10 + 30) J T3 = [T1 T42 ]1/3

= 40 J
Similarly T2 = [T12 T4 ]1/3
3. Answer (2)
7. Answer (1)
Hint : Lthermal = L0T(+ve)
Hint : W = PV
Sol. :
Sol. : = nRT
1
=  8.31(70)
FL0 2
Lmechanical. = ( –ve )
AY 291 J
FL0 8. Answer (1)
Leff. = 0  L0 T =
AY
Hint : Heat given is equal to heat taken.
F F
 Y = = Sol. : 192 × S(100 – 21.5) = 128 × 0.394 × (21.5
AT AT
– 8.4) + 240 × 4.18 × (21.5 – 8.4)
4. Answer (4)
660.65 + 13142
Hint :
Q1 Q2 Q3
= =  S=
T1 T2 T3 15072

Sol. : W1 = Q1 – Q2  S = 916 J kg–1 K–1.

W2 = Q2 – Q3 9. Answer (3)
W1 = W2 (Given) m 2 1
Hint : V =   = = m3
 2T2 = T1 + T3 p 8 4
T1 + T3 Sol. : PV = nRT  4 × 104 ×1/4 = nRT
T2 =
2
 nRT = 104
T2 = 500 K
3 3
5. Answer (3)  Internal energy = nRT =  10 4
2 2
V1 T1 = 1.5 × 104 J
Hint : =
V2 T2  Order = 104 J

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Test - 5 (Code-A) (Hints & Solutions) All India Aakash Test Series for JEE (Main)-2022

10. Answer (3) 16. Answer (2)

nfRT Hint : W = Area under PV graph
Hint : U =
2
1
Sol. : = 45
5 3 2
Sol. : U = 3  RT + 5  RT
2 2
= 10 J
 U = 15 RT
17. Answer (2)
11. Answer (1)
K1A1 + K2 A2
Hint : For adiabatic Hint : Keq. =
A1 + A2
PV = Constant
Sol. :
Sol. : TV = Constant

PVV = Constant
x+1=

2
x=
5
12. Answer (2)
Hint : Heat lost by water = 50 × 40 = 2000 cal. K1R 2 + K 2 3R 2
 K eq. =
Sol. : Let amount of ice be x g. 4R 2

x × 1/2 × 20 + (x – 20) × 80 = 2000 K 1 + 3K 2

=
90x = 3600 4

x = 40 g 18. Answer (1)

13. Answer (2) Hint : |W| = Area enclose by the curve.

Hint : f = 5 for O2 Sol. : A = ab

 7  7
Sol. : For rotational motion f = 2 = (  )(1)   = joule
2 2
14. Answer (2)
19. Answer (1)
Hint : l = l0  (T)
Hint : W1 = p(2V – V) = pV
Sol. : A(180° – 30°) = B(T – 30°)
Sol. : In isothermal process
4(180° – 30°) = 3(T – 30°)
 2V 
T = 230°C W2 = nRT ln  = nRT ln(2)
 V 
15. Answer (2)
 W2 = pV ln(2)
Hint. : Calculate Cprocess
W1 pV 1
Sol. : PV = RT  = =
W2 pV ln(2) ln(2)
 V.PV = K
 W2 = W1 ln(2)
PV2 = K
20. Answer (4)
3R R R
C = − =
2 2 −1 2 Hint : Q = nCpT, U = nCVT

Q = nCT Sol. : From previous problem solution we use

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All India Aakash Test Series for JEE (Main)-2022 Test - 5 (Code-A) (Hints & Solutions)

U nCv T Cv 5 PART – B : CHEMISTRY

= = =
Q nCp T Cp 7
26. Answer (1)
21. Answer (06.00) Hint : –COOH is principal functional group
Hint : Apply gas equation

P1 P 1
Sol. : = 2  n2 = moles Sol. :
n1T1 n2T2 48

 Mass leaking amount = 1 – (32 n2) 3-Chloro-5-cyclohexyl-6-hydroxy-5-methyl-3-

hexenoic acid
1
= gm 27. Answer (3)
3
22. Answer (24.00)
Hint : Heat lost by water = Heat gained by ice to Hint : DBE of is one

melt + Heat gained by water formed from ice.

Sol. : 300 × 1 × (50 – T) = 75 × 80 + 75 × 1 × Sol. : DBE = 2 so not on isomer

(T – 0) 375T = 15000 – 6000 = 9000

28. Answer (3)
9000 360
T= = = 24 Hint : Negative charge on more electronegative
375 15
atom is more stable
23. Answer (17.00)
2 Sol.: Stability order of negative charge
Hint :  = 1 +
f

 5R 3R  1 29. Answer (4)

Sol. : Cv =  + 2
 2 2  3 Hint : Formation of CN– ; compound must have
11R carbon
=
6 Sol. : In Lassaigne’s test of an organic
– –
17R compound, we do not get tests for CN and X
 CP =
6 ions, if the compound has nitrogen and halogen
CP 17 but not carbon.
= =
CV 11 30. Answer (1)
24. Answer (05.00) Hint : EWG increases acidic strength
Hint : PV = nkT Sol. : ERG decreases acidic strength. Inductive
−14
PV 10  13.6  1000  9.8 effect is distance dependent. That’s why III is
Sol. :  n = =  10−6
kT 1.38  10−23  273 most acidic.
= 3.5 × 105 31. Answer (4)
25. Answer (66.00)
Hint : P and S follows Huckel’s rule (4n + 2) e–
Hint : Mean square speed = v12 + v 22 + v 32 + v 42 + v 52
are completely delocalised over the entire cyclic
5
ring.
100 + 49 + 64 + 36 + 81
Sol. :  (v rms )
2
= = 66
5
Sol. :
 vrms = 66 m/s

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Test - 5 (Code-A) (Hints & Solutions) All India Aakash Test Series for JEE (Main)-2022

32. Answer (3) Sol. :

Hint : is most acidic pKa = 10

Sol. : More stable due to resonance

38. Answer (3)
Stability of conjugate base Hint : To show geometrical isomerism, molecule
should be able to produce two different spatial
33. Answer (2)
arrangements
Hint : AgCl = White ppt
Sol. :
Sol. : Cl− + Ag+ ⎯⎯→ AgCl white ppt, soluble
in NH4OH
39. Answer (3)
34. Answer (4)
Hint : Staggered form is more stable than
Hint : Bond dissociation energy for homolytic eclipsed form
1
Fission 
stability of formed radical

Sol. : Stability order

Sol. :

40. Answer (2)

35. Answer (4) Hint : EWG decreases basic strength

Hint : For tautomerism, molecule must have Sol. : Availability of lone pair on nitrogen
increases by ERG  basic strength increase
acidic hydrogen with resonance
41. Answer (1)
Hint : (I) is stable due to resonance
Sol. : cannot show Tautomerism Sol. : (II) have more number of -H(10) than III
order is I > II > III

36. Answer (4) 42. Answer (4)

Hint : In case of (1) second is more acidic than Hint : In chain isomerism → different carbon
first due to field effect skeletons should be present
Sol. : Isopentane and neopentane are chain
isomers
Sol. :
43. Answer (3)

37. Answer (3)

Hint : Aromatic cation

Hint : is less stable than due to Sol. : same charge density on each
carbon atom
Bredt’s rule

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All India Aakash Test Series for JEE (Main)-2022 Test - 5 (Code-A) (Hints & Solutions)

44. Answer (3) PART – C : MATHEMATICS

Hint : In case of alkene, carbon free radical and
51. Answer (1)
carbocations, –H is necessary for
Hint : Use truth table
hyperconjugation.
Sol. :
Sol. : (CH3)3C–CH=CH2 does not show
p Q p→q ~(p → q) ~q p ~ q
hyperconjugation effect
45. Answer (1) T T T F F F
Hint : Electrophile : Electron seeking T F F T T T

Sol. : Electrophile, F T T F T F

46. Answer (05.00) F F T F T F

Hint : Aromatic species follows Huckel’s rule are 52. Answer (2)
Hint : Total common roots = 4
Sol. : Naphthalene, Pyridine, Anilines aromatic
Sol. : z = ±1, ± i are common roots
Thiophene and Pyrrole are aromatic species. 53. Answer (2)
47. Answer (06.00) Hint : Use truth table
Sol. :
Hint : DBE of C5H10 = 1

(~ p  q )  ( p  q )
p q ~p ~ pq (q → p) pq
Sol. :

F
48. Answer (05.00) T T T F F F
T
Hint : EWG increases acidic strength T F F T T T
F
Sol. : Acidic strength order : F T T F T F
F
CF3COOH > CCl3COOH > NO2CH2COOH > F F T F T F

FCH2COOH > ClCH2COOH > HCOOH > 54. Answer (2)

Hint : Use concept of mathematical reasoning
> CH3COOH > Ph–OH Sol. : If x – 2y  9 then x  5 or y  –2.
55. Answer (3)
49. Answer (56.00) sin x
Hint : Use limit lim =1
Hint : N1V1 = N2V2 x→  x

1.4  10 1 – cos3 x
Sol. : % N = = 56 Sol. : lim
x →0 x·sin x·cos x
0.25
1 – cos x 1 + cos2 x + cos x
50. Answer (48.00) = 
x2 sin x
·cos x
x
Hint : % Br = 80  mass of AgBr
 100
188 mass of organic compound x
2 sin2
2 1 + cos2 x + cos x
= 
80 0.282 x 2 sin x
Sol. : % Br =   100 4 ·cos x
188 0.250 4 x
3
= 48 =
2

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Test - 5 (Code-A) (Hints & Solutions) All India Aakash Test Series for JEE (Main)-2022

56. Answer (2) 1 1

2S = S=
Hint : take x common in numerator and 2 4
denominator.

x – sin x  1 i
Sol.: lim = form e 4 = +
x → x + cos x
2
 2 2
sin x 60. Answer (3)
1–
1– 0
Hint : ln ( f ( x ) ) =
lim x = =1
x→  cos x 1 + 0
2
1+
x ln ( x + 1) + ln ( x + 2 ) + ... + ln ( x + 5 )
 lim sin x = Definite value in  –1, 1
x →
 Sol. : f(–5) =
57. Answer (2) ( x + 1) ( x + 2) ( x + 3) = ( x + 4) ( x + 6)...( x + 10) x = –5
Hint : Here  is cube root of unity and use 1 + 
+ 2 = 0 ( –4 )( –3 )( –2)( –1)(1)( 2)( 3 )( 4 )( 5 )
Sol. : Here z =  = 4! 5!
Hence 61. Answer (1)
( – 2 + 2) (2 –  + 2) Hint : kz = k z where k is a constant
( )
2
= 4– – 2
1
Sol. : 2021 z – = 2021 z – 1
=4– (2 +  – 2) 2021
=7 1
 z– = z –1
58. Answer (4) 2021
Hint : Given limit is of form 1.
 locus of z is straight line
Sol. :
62. Answer (4)
 sin x  sin x
A = lim  
x →0  x  x – sin x Hint : Distance from origin = x 2 + y 2 + z2
It’s 1 form.
lim g ( x )( f ( x ) – 1)
( ) (
Sol. : x 2 + y 2 + y 2 + z2 + z2 + x 2 = 72 ) ( )
Hence A = e x →0
lim
sin x  sin x 
– 1
 x 2 + y 2 + z2 = 6
x – sin x  x 
e x →0 = e
63. Answer (3)
–1 1
=e = sin x
e Hint : lim =0
x→  x
59. Answer (4)
 sin x + sin2x + ... + sin2020 x
n ( n + 1) ( n + 2 )
Sol. : lim =0
Hint : Zn = e x→  x
 1 
  64. Answer (1)
 n ( n + 1) ( n + 2 ) 
 z1 × z2 × z3 ….zk = e  
–
 Hint : When x → 0 , [x] = – 1 & |x| = – x
1
Where S =  Tk =
k =1 k ( k + 1) ( k + 1) ( k + 2 ) Sol. : Given limit is
 
1 e –1– x – 2 e –1 + h – 2
Sol. : S =  Tr =  r ( r + 1)( r + 2 ) lim
x →0 – –1 – x
= lim
h →0 –1 + h
r =1 r =1

( r + 2) – r 1 1
e –1 – 2 1
2S = = –
r ( r + 1)( r + 2 ) r ( r + 1) ( r + 1)( r + 2 ) = 2–
–1 e

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All India Aakash Test Series for JEE (Main)-2022 Test - 5 (Code-A) (Hints & Solutions)

65. Answer (1) p + e1/ x 1

Sol. : lim = =2
1 1
Hint : + 2 + ... → 1 x → 0+ 1 + q.e1/ x q
2 2
p + e1/ x
and lim =p=2
Sol. : S =
1 1
+ 2 + ... → 1 x → 0– 1 + qe1/ x
2 2
69. Answer (3)
But S < 1 Hence [S] = 0     3 
Hint : f(x) = sinx cosx if x  0,     ,
66. Answer (1)  2  2 
Hint : Given equation is (x – 1)3 + 8 = 0
    3 
 x = 1, 1 – 2, 1 – 2 – sin x cos x if x   ,     , 2 
 2   2 
Sol. : We have x 3 – 3 x 2 + 3 x + 7 = 0
    3 
Sol. : f  ( x ) =
cos 2 x
if x   0,    , 
 ( x – 1) 3
+8 =0 2  2  2 

 ( x – 1) 
3
– cos 2 x     3 
if x   ,     , 2 
   = 1 2 2   2 
 –2 
 x – 1 70. Answer (3)
  –2  = 1, , 
2
  Hint : Rotation theorem
 x = –1; 1 – 2; 1 – 22 Sol. : By rotation theorem if z1, z2 and z3 forms
  = –1,  = 1 – 2;  = 1 – 22 an equilateral triangle then
 Required expression = 32
67. Answer (3) z12 + z22 + z32 = z1z2 + z2 z3 + z3 z1

Hint : Rationalize and equate the real part 71. Answer (18.00)
1
to Hint : z1 – z + z – z2  z1 – z2
2
z+4 Sol. : z – 0 + z – 3 + z – 4i
Sol. : Let w =
2z + i
+ z – ( 5 + 12i )  18

( x + 4 ) + iy 2x – i ( 2y + 1) 72. Answer (20.00)

 w= 
2x + i ( 2y + 1) 2x – i ( 2y + 1) Hint : zz + z + z + c = 0 has radius
a – C
2x ( x + 4 ) + y ( 2y + 1) 1
Re ( w ) =
4 x 2 + ( 2y + 1)
2
=
2 (
Sol. : r2 =  – c = 32 + 42 – 5 = 20 )
73. Answer (04.00)
4x ( x + 4 ) + 2y ( 2y + 1) = 4x 2 + 4y 2 + 1 + 4y
x2 x3
Hint : ex = 1 + x + + + ...
2! 3!
4 x 2 + 16 x + 4y 2 + 2y = 4 x 2 + 4y 2 + 4y
e x – 1– x
Sol. : lim
Hence, it is a straight line. x →0 2x 2
 x2 x3 
68. Answer (4)  1 + x + + + ...  – 1– x
2! 3!
1 = lim  
Hint : Take e x common from Numerator and x =0 2x 2

Denominator and get L.H.L. and R.H.L. 1 1

=  =4
4 L

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Test - 5 (Code-A) (Hints & Solutions) All India Aakash Test Series for JEE (Main)-2022

74. Answer (05.00) 75. Answer (05.00)

Hint : z – z1 + z – z2 = 2a represent ellipse Hint : Simplify y then differentiate

when z1 – z2  2a (
Sol. : y = 2 sin4 x + cos4 x – sin2 x cos2 x )
Sol. : Here a2 – 2a  3
(
–4 1– 2sin2 x cos2 x )
 –3 < (a2 – 2a) < 3
( ) (
= 2 1– 3sin2 x cos2 x – 4 1– 2sin2 x cos2 x )
= 2 – 6 sin2 x cos2 x – 4 + 8 sin2 x cos2 x
 a(–1, 3)
= 2sin2 x cos2 x – 2
But aR+
sin2 2 x
 a(0, 3) = –2
2
But for a = 2, the equation represents a circle,
dy 2sin2x cos2 x.2
= = sin4 x
so a  ( 0,2 )  ( 2,3 ) dx x
dy 15 1
p+q+r =5 at x = = sin150 =
dx 72 2



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