ARIHANT VATSALYA ACADEMY

JEE MAIN 2025

SAMPLE PAPER – 14
TIME ALLOWED: 3 HOURS MAXIMUM MARKS: 300

 GENERAL INSTRUCTION:
1. There are three subjects in the question paper consisting of Physics (Q. no. 1 to 25), Chemistry (Q, no.
26 to 50), and Mathematics (Q. no. 51 to 75).
2. Each subject is divided into two sections. Section A consists of 20 multiple-choice questions & Section B
consists of 5 numerical value-type questions.
3. There will be only one correct choice in the given four choices in Section A. For each question for
Section A, 4 marks will be awarded for correct choice, 1 mark will be deducted for incorrect choice
questions and zero marks will be awarded for not attempted questions.
4. For Section B questions, 4 marks will be awarded for correct answers and zero for unattempted and
incorrect answers.
5. Any textual, printed, or written material, mobile phones, calculator etc. is not allowed for the students
appearing for the test.
6. All calculations/written work should be done in the rough sheet is provided with the Question Paper.

PHYSICS
(SECTION-A)

1. A wire frame in the shape of an equilateral triangle is hinged at one vertex so that it can swing freely in a vertical
plane, with the plane of the triangle always remaining vertical. The side of the frame is frame will be m. The
√

time period in seconds of small oscillations of the

A) B) √ C) D)
√ √ √

2. The dimensions of angular momentum are

A) B) C) D)
3. There are two identical small holes on the opposite sides of a tank containing liquid. The tank is open at the top.
The difference in height between the two holes is h. As the liquid comes out of the two holes, the tank will
experience a net horizontal force proportional to.

A) √ B) h C) D)
4. One end of a long metallic wire of length L is tied to the ceiling. The other end is tied to a mass less spring of
force constant K. A mass m hangs freely from the free end of the spring. The area of cross-section and Young's
modulus of the wire are A and Y respectively. If the mass is slightly pulled down and released, it will oscillate
with a time period T equal to

5. Internal energy of the gas as it expands according to the graph AB which is a recatangular hyperbola

A) Increasing continuously C) Always constant

B) decreasing continuously D) Initially Increasing then decreasing.
6. There are four concentric shells A,B,C and D of radii a,2a,3a and 4a respectively. Shells B & D are given charges

+q & -q respectively. Shell C is now earthed. The potential 1 difference is _______( )

A) B) C) D)

7. Two Identical discs initially at rest are in contact on a table. A third disc of same mass but of double radius strikes
them symmetrically and itself comes to rest after impact. The co-efficient of restitution is:

A) B) C) D)

8. Find out the value of current through 30 resistance for the given circuit

A) 10 amp B) 6 amp C) 4 amp D) zero

9. One plate of a capacitor is connected to a spring as shown in figure. Area of both the plates is A. In steady state
separation between the plates is 0.8d (spring was unstretched and the distance between the plates was d when the
capacitor was uncharged). The force constant of the spring is approximately
10. The current through 3 mH inductor in steady after closing switch S is

A) ampere B) ampere C) 1 ampere D) ampere

11. STATEMENT-1: Time constants of the circuits shown in the figure are same.

AND
STATEMENT-2: Instantaneous current through the capacitor branch is same at any instant for both the circuits, if
batteries are inserted in the circuits at .
A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1
B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1
C) Statement-1 is True, Statement-2 is False D) Statement-1 is False, Statement-2 is True

12. A small sphere A of mass m and radius r rolls without slipping inside a large fixed hemispherical bowl of radius
R(>> r) as shown in figure. If the sphere starts from rest at the top point of the hemisphere. Find the normal force
exerted by the small sphere on the hemisphere when it is at the bottom B of the hemisphere.

A) B) C) D)

13. Refractive index of a prism is √ and the angle of prism is 60°. The minimum angle of incidence of a ray that will

be transmitted through the prism is____________.

A) 30° B) 40° C) 60° D) 90°
14. The radius of the conducting loop shown in figure is R. Magnetic field is decreasing at a constant rate α.
Resistance per unit length of the loop is ρ. Then current in wire AB is ( AB is one of the diameters)
 A) B) C) D)

15. In YDSE, coherent monochromatic light having wavelength 600 nm has fallen on slits. First order bright fringe is
at 4.84 mm from central maxima. Determine the wavelength for which the first order dark fringe will be observed
at same location on screen ? Take D = 3m
A) 600 nm B) 1200 nm C) 300 nm D) 900 nm
16. Two capacitors having capacitance C1 & C2 are connected in series and a potential difference V is applied across
them. Then:

be the potentials drop & energy store in respectively.

Match the entries in Column-I with Column-II:

A) C)
B) D)
17. A changing electric field produces magnetic field. The direction of this magnetic field is
A) In the direction of electric field C) Perpendicular to the direction of electric field
B) In the direction opposite to the electric field D) Independent of the direction of electric field
18. A photon collides with a stationary hydrogen atom in ground state ineleastically. Energy of the colliding photon is
10.2 eV. After a time interval of the order of microsecond another photon collides with same hydrogen atom
inelastically with an energy of 15 eV. What will be observed by the detector?
A) 2 photons of energy 10.2 eV B) 2 photons of energy 1.4 eV
C) one photon of energy 0.2 eV and an electron of energy 1.4 eV
D) one photon of energy 10.2 eV and an electron of energy 1.4 eV
19. Two short bar magnets of magnetic moment M each are placed at a distance 2 d apart. The magnetic field.
Midway between them at P is

20. Graph shows a hypothetical speed distribution for a ample of N gas particles (for ). If Vave and Vrms

are the average speed and rms speed of the gas molecules, then

PHYSICS
(SECTION-B)

21. A half section of thin uniform pipe of mass m and radius r is released from rest. Pipe rolls without slipping. The
change in PE of pipe when it has rolled through 90° is Then the value of n is____________.

22. The system is pushed by a force F as shown in figure. All surfaces are smooth except between B and C friction

coefficient between B and C is u. Minimum value of F to prevent block B from downward slipping is ( ) .

Then the value of n is__________.

23. A uniform stick of length 1 and mass m lies on a smooth table. It rotates with angular velocity ω about an axis
perpendicular to the table and though one end of the stick. The angular momentum of the stick about the end is

Find the value of n____________.

24. A uniform ring of mass m is lying at a distance √3a from centre of a sphere of mass M just over the sphere where
√
a is the radius of ring as well as that of sphere. Then, gravitational force exerted is then the value of n

is___________.

25. Two tuning forks A & B when sounded together produces 4 beats/s. If B is loaded with wax then also beat
frequency remains same. Frequency of A is 242 Hz, find frequency of B?

CHEMISTRY
(SECTION-A)

26. Which of the following is not the name of an element with atomic number 104?
A) Noble B) Rutherfordium C) Kurchatovium D) Unnilqauadium
27. During halogen test, sodium fusion is boiled with con.HNO, to
A) remove unreacted sodium C) extract halogen from organic compound
B) decompose cyanide or sulphide of sodium D) Maintain the p" of extract
28. In the ionization of N. to N, the electron is lost from a
A) orbital B) π-orbial C) orbial D) π-orbial
29. A certain substance 'A' tetramerises in water to the extent of 80%. A solution of 2.5g of 'A' in 100g of water
lowers the freezing point by 0.3°C. The m.wt of 'A' is (Kf =1.86k.kg.mol-1)
A) 122 B) 31 C) 44 D) 62
30. Which technique among the following is most appropriate in separation of a mixture of 100 mg of p-nitrophenol
and picric acid?
A) Steam distillation C) Sublimation
B) Distillation under reduced pressure. D) Thin layer chromatography.
31. The equilibrium constants and for the reactions and respectively are in the ratio of
1:9. If the degree of dissociation of X and Z be equal then the ratio of total pressure at these equilibria is
A) 1:36 B) 1:1 C) 1:3 D) 1:9
32. Transition metal complex with the highest value of crystal field splitting energy (4) will be
A) B) C) D)
33. The major product of the reaction is
34. When an aldehyde is heated with Fehilings solution, a reddish brown precipitate is formed which is
A) C)
B) D)
35. Which of the following cannot be prepared by using willamson's synthesis?
A) Methoxy benzene ether C) t-butyl methyl ether
B) Benzyl p-nitro phenyl D) Ditertiary butyl ether
36. Among the following the metal with the highest melting point will be
A) Hg B) Ag C) Go D) Cs
37. The element of group 15 which can form a strong bond with hydrogen is
A) Nitrogen B) Phosphorous C) Arsenic D) Antimony
38. Which of the following is not a mineral of fluorine?
A) Fluorspar B) Cryolite C) Fluoroapetite D) Carnallite
39. Consider the following statements:
According to Werner's theory
i) Secondary valencies are non-ionisable and directional
ii) Secondary valencies are satisfied by neutral molecules or negative ions.
iii) Ligands form coordinate bonds with metal ions or atoms.
iv) The charge on the complex ion is always equal to the oxidation state of the metal atom.
A) all are correct C) (i), (ii) and (iv) are correct
B) (i), (ii) and (iii) are correct D) (iii) and (iv) are correct

40. Zinc and mercury do not show variable valency like other d-block elements because
A) They are soft B) Their (n-1) d-shells are completely filled
C) They have only two electrons in the outermost shell
D) Their d-shells are incompletely filled.

41. Assertion (A): The purple colour of KMnO, is due to charge transfer transition
 Reason (R): The intense colour, in most of the transition metal complexes is due to d-d transition.
A) Both A and R are true and R is the correct explanation of A
B) Both A and R are true but R is not the correct explanation of A
C) A is true but R is false D) A is false but R is true

42. Which of the following doesn't undergo Friedal-craft's reaction?

A) Xylene B) Nitrobenzene C) Common D) Toluene
43. Match the transition element ions given in Column I with the characteristic (s) of products given in Column II.

A) a-RS, b-PQ, c-PRS, d- QRS C) a -PRS, b-RS, c-PQ, d-QRS

B) a- PQ, b-RS, c- PRS, d-QRS D) a-RS, b-PQ, c-QRS, d-PRS
44. Oxidation state of iodine in is
A) +7 B) +5 C) +1 D) -1
45. Which of the following does not give a white precipitate when dilute hydrochloric acid is added?
A) B) C) D)

CHEMISTRY
(SECTION-B)

46. The wave length of an electron and a neutron will become equal when the velocity of electron is x times the
velocity of neutron. The value of x is (nearest integer)
(Mass of electron = 9.1 × 10-31 kg), (Mass of neutron = 1.6 × 10-27 kg)
47. The major product in the following reaction is

The degree of unsaturation of product P is_____________.

48. The volume of 0.15M H2SO4 solution required to neutralise 15 ml of 0.5M KOH in presence of phenolphthalein
indicator is ml.
49. An known amine A with benzene sulphonyl chloride yields a derivative which dissolves in aq.KOH solution.
Compound A on reaction with nitrous acid gives an alcohol B which responds to iodoform test. If hydrochloride
of A contains 37.2% of chlorine by weight, the total number of carbon atoms present in compounds A and B
is____.
50. .

If the molecular weight of tripe tide formed by X is 189, the value of n is__________.

MATHEMATICS
(SECTION-A)

51. If a denotes the number of permutation of n different things taken all at a time, b the number of permutation of n-2
different things taken 10 at a time and c, the number of permutations of n-12 different things taken all at a time
such that a = 182be, then value of n is:
A) 10 B) 12 C) 14 D) 18
52. STATEMENT-1: is discontinuous at all Integers, where [.] denotes G.I.F
STATEMENT - 2: If a function is non-differentiable at a point then it may be continuous at that point
A) Statement 1 is true, statement 2 is true C) Statement 1 is true, statement 2 is false
B) Statement 1 is false, statement 2 is false D) Statement 1 is false, statement 2 is true

53. If a,b,c are real, then | | be is decreasing in:

54. If pth,qth,rth, terms of a G.P are the positive numbers a,b,c respectively then angle between the vectors ̂
̂ ̂ and ̂ ̂ ̂ is:

A) B) C) 0
D) ( )
√

55. Consider the data on X taking the values 0, 2, 4, 8,……..2” with frequencies respectively. If

the mean of this data is , then n is equal to____.

A) 15 B) 8 C) 4 D) 6
56. Complete set of real values of 'a' for which the equation has all its roots real
A) [3/4 4) B) [1,∞) C) [2,∞) D) [0,∞)

57. The value of ∫ is; (where [.] denotes greatest integer function)
A) 10π B) -20π C) 20π D) -10π
58. Statement-1: The number of non-negative integral solutions of is 132
 Statement-2: For is divisible by (n!)n.
A) Statement 1 is true, statement 2 is true C) Statement 1 is true, statement 2 is false
B) Statement 1 is false, statement 2 is false D) Statement 1 is false, statement 2 is true

59. Of all the functions that can be defined from the set { } { } a mapping is randomly seleted.
The chance that the selected mapping is strictly monotonic is
A) B) C) D)

60. Three distinct numbers a, a, a, are in increasing G.P and then the value
of , if , is the terw of the given G.P is:
A) B) C) D)

61. Let √ then { } { } denotes the fractional part of x) is equal to: 19

19
A) 2 B) 319 C) 0 D) 1

62. If ∫ then the value of for

A) A-Q;B-P;C-S;D-R C) A-Q;B-S;C-P;D-R
B) A-Q; B-S;C-R;D-P D) A-Q; B-P;C-Q;D-S
63. A curve passing through (2,3) and satisfying the differential equation

A) C)
B) D)

( ) ( ) ( )
64. Let Then is equal to

A) B) C) 1 D) 0

65. A 13 ft. ladder is leaning against a wall when its base starts to slide away. At the instant when the base is 12 ft.
away from the wall, the base is moving away from the wall at the rate of 5 ft/sec. The rate at which the angle &
between the ladder and the ground is changing is
A) B) C) D)
66. Two aero planes I and II bomb a target in succession. The probabilities of I and II scoring a hit correctly are 0.3
and 0.2, respectively. The second plane will bomb only if the first misses the target. The probability that the target
is hit by the second plane is
A) 0.06 B) 0.14 C) 0.312 D) 0.70

67. The area of the region bounded by the curve y

(where [.] denotes greatest integer function is:)

68. If , then: (where [.]represents greatest integer function)

69. Let , where is necessarily increasing in the

interval

70. The largest integral value of x satisfying the inequality is:

A) 0 B) 1 C) 2 D) 3

MATHEMATICS
(SECTION-B)

71. Let O be an interior point of AABC such that then ratio of the area of ∆ABC to the area of
∆AOC is___________________.
72. Find number of integral values of k for which the line 3x+4y-k=0, lies between the circles
and , without cutting a chord on either of circle.
73. Let ⃗ ̂ ̂ ̂ ⃗⃗ ̂ ̂ ⃗ ̂ ̂ ̂ . If the equation ⃗ ⃗⃗ ⃗ ̂ ̂ ̂ has
a non-trivial solution, then find the sum of all distinct possible values of α.
74. For each positive integer n, consider the point P with abscissa n on the curve . If represents the

shortest distance from the point P to the line then has value , then K is
√
∞
75. Let ∫ . If is the point where f(x) attains it's local minimum value
then value of is;
 PHYSICS

1. D 2. D 3. B 4. B 5. C 6. A 7. A 8. D 9. A 10. B
11. C 12. B 13. A 14. D 15. B 16. A 17. C 18. D 19. B 20. D
21. 2 22. 5 23. 3 24. 8 25. .

CHEMISTRY

26. A 27. B 28. A 29. D 30. D

31. A 32. D 33. A 34. C 35. D 36. B 37. A 38. D 39. B 40. B
41. B 42. B 43. A 44. A 45. B 46. 1758 47. 3 48. 25 49. 6 50. 1

MATHEMATICS

51. C 52. D 53. A 54. A 55. D 56. A 57. B 58. A 59. B 60. A
61. D 62. C 63. D 64. D 65. B 66. C 67. C 68. A 69. B 70. B
71. 3 72. 30 73. 7 74. 2 75. 7