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CTY B Lot PT 2 Main 07 01 2023

The document is a question paper for the FIITJEE JEE (Main) examination, covering Physics, Chemistry, and Mathematics with a total of 300 marks. It includes instructions for candidates on how to fill the OMR sheet, the marking scheme, and guidelines for the examination process. The paper consists of multiple-choice questions and numerical-based questions across three sections, with specific rules regarding answer marking and prohibited items in the examination hall.

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0% found this document useful (0 votes)
18 views18 pages

CTY B Lot PT 2 Main 07 01 2023

The document is a question paper for the FIITJEE JEE (Main) examination, covering Physics, Chemistry, and Mathematics with a total of 300 marks. It includes instructions for candidates on how to fill the OMR sheet, the marking scheme, and guidelines for the examination process. The paper consists of multiple-choice questions and numerical-based questions across three sections, with specific rules regarding answer marking and prohibited items in the examination hall.

Uploaded by

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Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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FIITJEE – JEE (Main)

Physics, Chemistry & Mathematics


QP Code: 131736
BATCHES – 2224 – B – Lot – Pt – 2

Time Allotted: 3 Hours Maximum Marks: 300

 Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
 You are not allowed to leave the Examination Hall before the end of the test.

Important Instructions
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR
sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.

A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each Section is further divided into Two Parts: Part-A & B in the OMR.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided
for rough work.
6. No candidate is allowed to carry any textual material, printed or written, bits of papers, clip boards, log
tables, slide rule, calculator, cellular phones, pagers and electronic devices ext. except the Admit Card
inside the examination hall / room.

B. Filling of OMR Sheet:


1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each
character of your Enrolment No. and write in ink your Name, Test Centre and other details at the
designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
4. Do not fold or make any stray marks on the Answer Sheet.

C. Marking Scheme for All Two Parts:


(i) Part-A (01-20) – Contains Twenty (20) multiple choice objective questions which have four (4) options
each and only one correct option. Each question carries +4 marks which will be awarded for every correct
answer and -1 mark will be deducted for every incorrect answer.

(ii) Part-B (01-05) contains five (05) Numerical based questions, the answer of which maybe positive or negative
numbers or decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and each question carries +4 marks for correct
answer and there will be no negative marking.

Name of the Candidate :_______________________________________________

Batch :_______________________ Date of Examination :____________________

Enrolment Number :___________________________________________________

FIITJEE Ltd. 142, New Civic Centre, Opposite Incometax Building, Bhilai (C.G.) 490006 Phone-8871095808,0788- 4035204,
Website: www.fiitjeebhilai.com
TWO_YEAR_CRP(2224)_B-LOT_PHASE-2(CPT-2) 2

SECTION – I : PHYSICS
(PART – A)
Single Correct Questions
This section contains 20 Single Correct Questions out of which only one option is correct

1. A planet has twice the density of earth but the acceleration due to gravity on its surface is
exactly the same as on the surface of earth. Its radius in terms of radius of earth R will be:
(A) R/4 (B) R/2 (C) R/3 (D) R/8.
2. A mass M is supported by a massless string wound round a uniform
cylinder of mass M and radius R. On releasing the mass from rest, it will
fall with acceleration:
R
1 M
(A) g (B) g
2
1 2
(C) g (D) g M
3 3

3. A 3 kg ball strikes a heavy rigid wall with a speed of 10 m/s


at an angle of 60° with the wall. It gets reflected with the
same speed at 60° with the wall. If the ball is in contact with 60°
the wall for 0.2 s, the average force exerted on the ball by N
the wall is:
(A) 300 N (B) zero 60°
(C) 150 3 N (D) 150 N Wall

4. A particle moves on x-axis according to the equation x = x0 sin2 t, the motion is simple
harmonic
(A) with amplitude x0 (B) with amplitude 2x0
(C) with time period (2/) (D) with time period (/)

5. A thin circular ring of mass M and radius R is rotating about its axis with a constant angular velocity .
Two objects, each of mass m, are attached gently to the opposite ends of a diameter of the ring. The
ring rotates now with an angular velocity:
M ( M  2m) M ( M  m)
(A) (B) (C) (D)
M m M  2m M  2m M
6. An isolated particle of mass m is moving in horizontal plane (x-y), along the x-axis, at a certain height
above ground. It suddenly explodes into two fragments of masses m/4 and 3m/4. An instant later, the
smaller fragment is at y = +15cm. The larger fragment at this instant is at:
(A) y = –5 cm (B) y = -15 cm (C) y = +5 cm (D) y = +15 cm

7. Two particles of masses M and 2M are at a distance D apart. Under their mutual gravitational
force they start moving towards each other. The acceleration of their centre of mass when
they are D/2 apart is
2GM 4 GM 8GM
(A) (B) (C) (D) zero
D2 D2 D2
8. A block Q of mass M is placed on a horizontal frictionless surface AB C
and a body P of mass m is released on its frictionless slope. As P
slides by a length L on this slope of inclination , the block Q would P
slide by a distance:
M
Q 
A B
m m M m mL cos 
(A) L cos  (B) L (C) (D)
M M m mL cos  mM

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TWO_YEAR_CRP(2224)_B-LOT_PHASE-2(CPT-2) 3

9. A disc is rolling without slipping with angular velocity . P and Q


are two points equidistant from the centre C as shown. The order P
C
of magnitude of velocity is:
Q
(A) VQ > VC > VP (B) VP > VC > VQ
(C) VP > VC, VQ = VC / 2 (D) VP < VC > VQ

10. Moment of inertia of a ring about a diameters is I0. The moment of inertia of the ring about a tangent
perpendicular to the plane of the ring will be:
(A) I0 (B) 2I0 (C) 3I0 (D) 4I0

11. An equilateral triangle ABC has its centre at O as shown in figure. A


Three forces 10 N, 5N and F are acting along the sides AB, BC
and AC. Magnitude of force F so that the net torque about ‘O’ is
zero, will be: O
(A) 15 N (B) 5 N C
B 5N
(C) 50 N (D) 2 N
10N F

12. A disc is rotating with an angular velocity 0. A constant retarding torque is applied on it to stop the
disc. Its angular velocity becomes 0/2 after n rotations. How many more rotations will it make before
coming to rest?
n n
(A) n (B) 2n (C) (D)
2 3
13. When a sphere rolls without slipping, the ratio of its kinetic energy of translation to its total kinetic
energy is:
(A) 1 : 7 (B) 1 : 2 (C) 1 : 1 (D) 5 : 7

14. An inclined plane makes an angle of 30° with the horizontal. A solid cylinder rolling down this inclined
plane from rest without slipping has a linear acceleration equal to:
g 5g 2g 5g
(A) (B) (C) (D)
3 7 3 14
15. A concentric hole of radius R/2 is cut from a thin circular plate of mass M and radius R. The moment of
inertia of the remaining plate about its axis will be:
13 11 13 15
(A) MR 2 (B) MR 2 (C) MR 2 (D) MR 2
24 24 32 32

16. If the change in the value of ‘g’ at a height h above the surface of the earth is the same as a
depth x below it, then (both x and h being much smaller than the radius of the earth):
(A) x = h (B) x = 2 h (C) x = 1/2 h (D) x = h2.

17. Four particles each of mass m are placed at the corners of a square of side length l. The radius of
gyration of the system about an axis perpendicular to the square and passing through centre is
l l
(A) (B) (C) l (D) ( 2 )l
2 2
18. Two particles P and Q initially at rest, move towards each other under a mutual force of attraction. At
the instant when the speed of P is v and the speed of Q is 2v, the speed of the centre of mass of the
system is
(A) 3v (B) 1.5 v
(C) v (D) zero
19. A man of mass M stands at one end of a plank of length L which lies at rest on a frictionless surface.
The man walks to the other end of the plank. If the mass of the plank is M/3, the distance that the man
moves relative to the ground is
3L 4L
(A) (B)
4 5
L L
(C) (D)
4 3
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TWO_YEAR_CRP(2224)_B-LOT_PHASE-2(CPT-2) 4

20. A 2 kg stone is suspended from a wire and its length change by 1%. If the Young’s modulus
of the material of wire is 2  1011 N/m2, the area of cross–section of the wire is
(A) 10–3 mm2 (B) 10–2 mm2
–1 2
(C) 10 mm (D) 1 mm2

(PART – B)
(Integer Type)
Part-C (01-05) contains five (05) Numerical based questions, the answer of which maybe positive or negative
numbers or decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and each question carries +4 marks for correct
answer and there will be no negative marking.

1. A uniform elastic rod of cross- sectional area A,


natural length L and Young's modulus Y is placed on
a smooth horizontal surface. Now two horizontal
forces (of magnitude F and 3F) directed along the
length of rod and in opposite directions act at its ends
as shown. After the rod has acquired steady state, the
xF
extension of the rod is given by L . Calculate x.
YA

2 Figure below shows a massless pulley, a spring of


constant K = 250 N/m and a mass 1 kg. On displacing
the mass slightly, find its frequency (approximate) of its K
vertical oscillation

3. Two weights W1 and W2 in equilibrium and at rest, are suspended as


W1
shown in figure. Then the ratio is
W2

4. A man of mass m stands on a platform of equal mass m pulls himself by two


ropes passing over pulleys as shown. If he pulls each rope with a force equal
to half his weight, his upward acceleration would be

5. A 1 kg block is being pushed against a wall by a force F = 75 N as shown in


figure. The coefficient of friction is 0.25. The magnitude of acceleration of the
block is

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TWO_YEAR_CRP(2224)_B-LOT_PHASE-2(CPT-2) 5

SECTION – II : CHEMIS
STRY
(PART – A)
Single Correct Questions
This section contains 20 Single Correct Questions out of which only one option is correct

1. For the following equilibrium


NH4HS(s) NH3(g) + H2S(g) ; partial pressure of NH3 will increase
(A) If NH3 is added after equilibrium is established
(B) if H2S is added after equilibrium is established
(C) NH4HS is added into the container
(D) volume of the flask is decreased

2. To 100 mL of 0.1 M AgNO3 solution solid K2SO4 is added. The minimum concentration of K2SO4 that
shows the precipitation is? [KSP for Ag2SO4 = 6.4  10-5 M]
(A) 0.1 M (B) 6.4  10-3 M
(C) 5.4  10-7 M (D) 6.4  10-5 M

For Q 3 - Q4 consider the following data from the reaction between A and B.

[A] [B] Initial rate mol litre–1 sec–1


mol litre–1 mol litre–1 300 K 320 K
2.5 × 10–4 3.0 × 10–5 5.0 × 10–4 2.0 × 10–3
5.0 × 10–4 6.0 × 10–5 4.0 × 10–3 -

1.0 × 10–3 6.0 × 10–5 1.6 × 10 –2 -

3. The order of reaction with respect to A and with respect to B, respectively -


(A) 2,1 (B) 3,0 (C)2,0 (D) 2,3

4. Select the correct statement


(A) The rate c onstant at 300 K is 2.6 x 10 - 6
(B) from the data, it can be concluded that the reaction is endothermic.
(C) The rate of reaction decreases with increase in temperature
(D) The value of pre – exponential factor for the reaction is independent of temperature

5. Which isomer of 1-hexene shows geometrical isomerism?


(A) Chain isomer (B) Position isomer
(C) Optical isomer (D) None of these

6. Degree of ionisation of 1 M HCOOH is decreased to a maximum extent in presence of :


(A) 1 M HCHO (B) 1 M NaOH (C) 1 M HCOONa (D) equally in all

7. We have acidic buffer of CH3COONa and CH3COOH. One or more of the following operations will not
change pH :
I : diluting the mixture ten times
II : adding small amount of HCl
III : adding small amount of NaOH
IV : adding equal moles of CH3COONa and CH3COOH into the buffer
Select correct alternate(s) :
(A) I, III, IV (B) II, III (C) I, II,III (D) I,II,III, IV

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TWO_YEAR_CRP(2224)_B-LOT_PHASE-2(CPT-2) 6

8. The rate of a reaction is expressed in different ways as follows :


1 d[C] 1 d[D] 1 d[ A] d[B]
   
2 dt 3 dt 4 dt dt
The reaction is:
 4 AD   B + 3 DC
 CA + BD    (D) B + DC

9. Which of the following carbonium ion is most stable?

(A) CH3CH2CH2CH2 (B) CH3CH2CH2CHCH3


CH3 CH3
(C) CH3 - C - CH2 (D) H3 C - C
CH3 C2 H 5

10. For the simultaneous equilibria,


2C  s   O 2  g 
 2CO  g  ,Kc1

2CO  g   O 2 
 2CO 2  g  ,Kc 2

Initially 2 and 4 moles of carbon and oxygen respectively are taken in a one litre vessel at 40°C.
Calculate the value of Kc 2 if the equilibrium moles of oxygen and CO 2 are 2.9 and 0.6 respectively.
(A) 0.07 (B) 0.39
(C) 0.12 (D) 0.09

11. In which of the following compound the electron releasing tendency(+ I effect) of CH 3 group is
maximum?
(A) CH3F (B) CH3Cl
(C) CH3Br (D) CH3I

12. KSP of CuS, Ag2S and HgS are 10-31, 10-44 and 10-54 respectively. Select the correct order for their
solubility in water
(A) Ag2S > HgS > CuS (B) HgS > CuS > Ag2S
(C) HgS > Ag2S > CuS (D) Ag2S > CuS > HgS

13. In which of the following compound chlorine displays +R as well as –I effect?


Cl Cl

(A) (B)

Cl
CH2Cl
(C) (D)

14. A following mechanism has been proposed for reaction


2A + B  D + E
A + B  C + D ( slow)
A + C  E ( fast)
The rate law expression for the reaction is
(A) r = K[A]2[B] (B) r = K[A][B]
(C) r = K [A]2 (D) r = [A][C]

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TWO_YEAR_CRP(2224)_B-LOT_PHASE-2(CPT-2) 7

15. Which of the following compound does not display geometrical isomerism?
CH3
Cl CH3
(A) (B) C
Cl CH3
C2 H5

(C) (D) CH2 = CH – CH = CH – CH 2 – CH = CH2

16. Which of the following compound has the most acidic strength?
(A) FCH2CH2COOH (B) ClCH2CH2COOH

(C) CH3CHCOOH (D) CH3CHCOOH


Cl F

17. Which of the following compound has the most basic strength?
(A) CH3CH2OH (B) CH3CH2NH2
(C) CH3CH2NO2 (D) CH3CH2Cl

18. Which buffer solution has maximum pH ?


(A) mixture which is 0.1 M in CH3COOH and 0.1 M in CH3COONa [pKa (CH3COOH) = 4.74]
(B) mixture which is 0.2 M CH3COOH and 0.2 M in CH3COONa
(C) mixture which is 0.1 M in NH4Cl and 0.1 M in NH4OH [pKa (NH4+) = 9.26]
(D) all the solution have equal pH which is 4.74

19. Which is the geometrical isomer of the compound given below?


F

F
F F

(A) (B)

F F
F F
(C) (D)

F F

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TWO_YEAR_CRP(2224)_B-LOT_PHASE-2(CPT-2) 8

20. For the reversible reaction N2(g) + 3H2(g) 2NH3(g) at 500º , the value of Kp is
1.44 × 10–5 when partial pressure is measured in atmospheres. The corresponding value of KC, with
concentration in mole litre–1, is
1.44 10 5 1.44  10 5 1.44 10 5 1.44 105
2
(A)
(0.082  500) (B) (8.314  773)
2
(C) (0.082  773)
2
(D) (0.082  773)
2

(PART – B)
(Integer Type)
Part-C (01-05) contains five (05) Numerical based questions, the answer of which maybe positive or negative
numbers or decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and each question carries +4 marks for correct
answer and there will be no negative marking.

1. The total number of cyclic isomers of C6H12, which are optically active is _______.

2. The half time of first order decomposition of nitramide is 2.1 hour at 15°C.
NH2NO2(aq.) N2O(g) + H2O(l)
If 6.2 g of NH2NO2 is allowed to decompose, calculate the time in hrs taken for NH2NO2 to
decompose 99%.

3. 5 moles of SO2 and 5 moles of O2 are allowed to react to form SO3 in a closed vessel. At the
equilibrium stage 60% of SO2 is used up. The total number of moles of SO2 ,O 2 and SO3 in the
vessel at equilibrium is

4. The CaCO3 is heated in a closed vessel of volume 1 litre at 600 K to form CaO and CO2. The
 CaO(s)  CO 2(g)
CaCO3(s) 
minimum weight of CaCO3 required to establish the equilibrium
is Kp = 4.9atm) At wt of Ca = 40

5. Consider the following molecule:

H3C CH2 C N CH3


CH3 How many hyper conjugation structures are possible for this molecule?

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TWO_YEAR_CRP(2224)_B-LOT_PHASE-2(CPT-2) 9

SEC
CTION – I : MATHEMATICS
(PART – A)
Single Correct Questions
This section contains 20 Single Correct Questions out of which only one option is correct

1. If sin , sin  and cos  are in G.P. Then roots of the equation x2 + 2x cot  + 1 = 0 are always
(A) Real (B) Equal (C) Imaginary (D) Greater than 1

2. The minimum value of 3 tan2  + 12 cot2  is


(A) 6 (B) 12 (C) 24 (D) 15

3. Angle between the tangents drawn at the end of the chord x  y  a  0 to a parabola y 2  4ax is
  
(A) (B) (C) (D) None of these
3 6 4
k k 1
4. If the roots of the equation 42    2  0 are of the form and then the value of  is
k 1 k2
(A) 2k (B) 7 (C) 2 (D) k+1
5. If ASB is a focal chord of a parabola y 2  4ax and AS=4, SB = 5 then length of latus rectum of the
parabola is
80 9 20
(A) (B) (C) (D) none of these
9 80 9
6. If the normals at the end points of a variable chord PQ of the parabola y 2 – 4y – 2x = 0 are
perpendicular, then the tangents at P and Q will intersect at
(A) x + y = 3 (B) 3x – 7 = 0 (C) y + 3 = 0 (D) 2x + 5 = 0

7. Number of real normal(s) to a parabola y2 = 4ax passing though the focus is


(A) 1 (B) 3 (C) 0 (D) 2

8. If tangents at A and B on the parabola y2 = 4ax intersect at the point C, then ordinates of A, C and B
are
(A) always in A.P. (B) always in G.P. (C) always in H.P. (D) none of these

5 5
 1 i 3   1 i 3 
If z  
 2    2 
9. then
   
(A) Re(z)=0 (B) Im(z)=0 (C) Re(z)= - 1 (D) Re(z)  0, Im (z)  0
10. For n  3, the nth roots of unity are in
(A) AP (B) GP (C) HP (D) None of these \

11. If x, 2x + 2, 3x + 3 are in GP then the fourth term is


(A) 27 (B) -27 (C) 13.5 (D) -13.5

a 3
12. If 2  3  43 and 2
a b
 3b  47, then the respectively value of ‘a’ and ‘b’ are
(A) 3, 4 (B) 4, 3 (C) 16, 27 (D) 8, 9

13. If three positive real numbers a, b, c are in AP with abc = 4 then the minimum value of b is
1/3
(A) 4 (B) 3 (C) 2 (D) 1/2

If both the roots of x  ax  a  0 are greater than 2, then


2
14.
(A) a   , 4  (B) a   0, 2  (C) a   4,   (D) none of these

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TWO_YEAR_CRP(2224)_B-LOT_PHASE-2(CPT-2) 10

Let a, b, c are positive real numbers forming an A.P. If ax  bx  c  0 has real roots then
2
15.
a c a c a c a c
(A)  2 3 (B)   2 3 (C)   2 3 (D)  2 3
c a c a c a c a

16. If tan 1 , tan  2 , tan 3 are the real roots of x3   a  1 x 2   b  a  x  b  0 ,


where 1 , 2 ,3   0,   then 1   2  3 is equal to
  3
(A) (B) (C) (D) 
2 4 4
If a, b, c are odd integers then roots of the equation ax  bx  c  0
2
17.
(A) can’t be Rational (B) can be Rational (C) always Real (D) nothing can be said

If two roots of x  ax  bx  c  0 are equal in magnitude but opposite in signs then


3 2
18.
(A) a + bc = 0 (B) a2 = bc (C) ab = c (D) a – b + c = 0

 7
19. If log3 2, log 3 (2 x  5) and log 3  2 x   are in AP then
 2
(A) x is an even integer (B) x is an odd integer
(C) x > 3 (D) x can assume two integral values

If ax  bx  c  0 and bx  cx  a  0 have a common root and a, b, c are non-zero real numbers


2 2
20.
a 3  b3  c 3
then is equal to
abc
(A) 1 (B) 2 (C) 3 (D) none of these

(PART – B)
(Integer Type)
Part-C (01-05) contains five (05) Numerical based questions, the answer of which maybe positive or negative
numbers or decimals (e.g., 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and each question carries +4 marks for correct
answer and there will be no negative marking.

1. If P(0,8) is one end of focal chord PQ of a parabola y 2  16 x  8 y  0 then slope of the normal Q is__

2. If the sum of the series 1.1! + 2.2! + 3.3! +……..+ 20.20! is n! -1 then the absolute value of n-19 is ____

Number of distinct solution for equation  x      x  2    x  3   0 , if  is a real no. is


2 2 2
3

4. If the numbers a, b, c, d, e form an A.P. then the value of a  4b + 6c  4d + e is

5. If a, b, c are positive real numbers then the number of real roots of the equation ax2  b | x |  c  0 is
(|x| is always positive)

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TWO_YEAR_CRP(2224)_B-LOT_PHASE-2(CPT-2) 11

FIITJEECOMMON TEST
BATCHES: Two Year CRP (2224) B-LOT
PHASE TEST – 2 Paper Code
JEE-MAIN LEVEL
ANSWER KEY
SET–A
ANSWER KEYS [SET – A]

PHYSICS C.CODE CHEMISTRY C.CODE MATHEMATICS C.CODE


1 B P110902 1 A C110403 1 A A
2 D P110715 2 B C110501 2 B B
3 C P110613 3 A C110601 3 B D
4 D P111102 4 D C110602 4 B B M110102
5 C P110723 5 B C111401 5 A A M110902
6 A P110604 6 C C110504 6 D D M110904
7 D P110901 7 C C110504 7 A A
8 D P110614 8 B C110601 8 A A M110903
9 B P110807 9 D C111303 9 D B
10 D P110703 10 C C110402 10 B B
11 A P110708 11 A C111301 11 B D
12 D P110710 12 D C110501 12 B B M110202
13 D P110807 13 B C111301 13 C A
14 A P110810 14 B C110607 14 D D M110106
15 D P110707 15 C C111403 15 A A M110103
16 B P110902 16 D C111302 16 B B M110117
17 A P110705 17 B C111302 17 A A
18 D P110604 18 C C110504 18 C C M110108
19 C P110604 19 B C111403 19 B B
20 B P111101 20 D C110402 20 C C M110103
PART – B PART – B PART - B
1 2 P111101 1 8 C111404 1 2 2
2 5 P111104 2 14 C110604 2 2 2
3 1.25 P110403 3 8.5 C111502 3 1 1 M110118
4 0 P110407 4 10 C110504 4 0 0 M110501
5 20 P110411 5 8 C111303 5 0 0 M110115

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TWO_YEAR_CRP(2224)_B-LOT_PHASE-2(CPT-2) 12

Hint or solutions
PHYSICS
1. B

2. D
1 1
TR  MR2   T  Ma ......... 1
2 2
Mg  T  Ma ..............  2 
2
From (1) and (2); a g
3
3. C
2mv sin  2  3  10 sin 60
Favg    150 3 N
t 0.2
4. D

5. C
M
MR 2   (mR 2  2  MR 2 )' , ' 
M  2m
6. A
Before explosion, particle was moving along x-axis, i.e., it has no y-component of velocity. Therefore,
the centre of mass will not move in y-direction or we can say ycom  0.
m1 y1  m2 y 2 (m / 4)(15)  (3m / 4)( y )
Now, y com   0 or y  5cm
m1  m2 (m / 4  3m / 4)
7. D

8. D
Here, the x co-ordinate of centre of mass of the system remains unchanged when the mass m moved
a distance L cos  , let the mass ( m  M ) moves a distance x in the backward direction.
mL cos 
 ( M  m) x  mL cos   0  x
mM
9. B
OP > OC > OQ ;  VP > VC > VQ P
C
Q
O

10. D
1 I
I0  Idia  MR 2  cm , Itangent  Icm  MR2  4I0
2 2
11. A
Fd – 10d – 5d = 0; F = 15 N
12. D
2
Since  2  0  2 where  = 2n
2
2  
0  0  2
 2   0 2  n
 2  and 0     (2)(2n)  n 
2n  2  3
 
13. D
1 2
mv
KT 2 1 KT 1 5
    
K 1 2 1 2 I K 1 2 7
mv  I 1 2
2 2 MR 5
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TWO_YEAR_CRP(2224)_B-LOT_PHASE-2(CPT-2) 13

14. A
g sin  gsin 30 1
a  = g
I 1 3
1 1
MR 2 2
15. D
 M  R  M
2
Mass of hole ( M )   2   
 R  4  4 R/2
Moment of inertial of remaining plate
2 R
1 1 R 15
 MR 2  M    MR 2
2 2 2 32
16. B

17. A l
m m
l  2
I  mr  4m    m(2l 2 )
2
l/ 2
2
2ml 2 l l/ 2 l/ 2 l
 Radius of gyration k   C.M.
4m 2 l/ 2
m m
18. D
Since no external force acts, initially both particle at rest. So speed of centre of mass of system is
zero.

20. B

PART – B
1. 2

2. 5

3. 1.25
Resolving forces at point A along string AB
w1 cos 370  w 2
w1 5

w2 4
4. 0
For (man + platform) system :
2mg – 4T = 2m(a)
 mg  mg
 2mg  4    2m(a ) [T  2 ]
 2 
a=0
5. 20 m/s2
Fvertical = 75  3/5 = 45 N
4
Frictional force = N = 0.25 75  =15N
5
Down ward force = Weight of block = 10 N
45  10  15
Acceleration =  20 m/s2
1

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TWO_YEAR_CRP(2224)_B-LOT_PHASE-2(CPT-2) 14

CHEMISTRY
1: A
2: (B)
Ag2SO4(s) 
 2Ag+(aq) + SO42-(aq)


[SO42-] = = 6.4 x 10-3


3 A
4: D ; from the data H cannot be predicted .
5: B
Position isomer of 1-hexene like 2-hexene and 3-hexene show geometrical isomerism.

6: C , common ion effect


7: C

pH = pKa + log = pKa + log

pH’ = pKa + log


so pH ≠pH’ for most values of a .
8: B
9: D
10: C 

2C  s   O2  g 
 2CO  g ,Kc1
Initial conc: 2 4 -
Eqm conc: - 4-x-y 2x-2y



2CO  g  O2 
 2CO2  g ,Kc 2
Eqm conc: 2x-2y 4-x-y 2y

[CO2] = 0.6 = 2y
[O2] = 4-x-y = 2.9

Solving : y = 0.3 ; x = 0.8 ; Kc2 = =0.12


11 A
There is maximum electronegative difference in C – X bond in CH3F
12: D
13: B
Chlorine displays +R effect through resonance.

14: B
15: C
(C) does not show geometrical isomerism.
16: D
‘F’ is more electron withdrawing than Cl.
17: B
Amines are most basic out of the given compounds
18: C
19: B
(B) is the correct geometrical isomer.

20: D

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TWO_YEAR_CRP(2224)_B-LOT_PHASE-2(CPT-2) 15

PART – B
21: 8
C C C

+ +
C C C C C
22 : 14
For first order reaction
2.303 A 0.693
t log 0 k
k A & t1/ 2
2.303 A
t  t1/ 2 log 0
So, 0.693 A
Here A0 is initial concentration & A is the concentration of NH4NO2 at time t
2.303 0.1 100
t  t1/ 2 log
0.693 0.1
T = 14hrs

23. 8.5
1 

SO2  O2 
 SO3
2
a a

a
a
a  a 2 a
Total mole at equilibrium
a

= 2a 2 ………… (1)
60

Put a = 5, 100 = 0.6 in equation (1)
5(0.6)
So, total mole =2(5) - 2
= 8.5

24: 10
V x pCO2 = nRT ; n = 0.1 mole ; CaCO3 wt = 10 gm

25: 8
8  - H for Hyper conjugation

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TWO_YEAR_CRP(2224)_B-LOT_PHASE-2(CPT-2) 16

MATHEMATICS
1. A
using log m n  n log m and log a a  1
2. B
sinx >0: cosx>0; cosx  1
sin x  cos 2 x
 5 1
sin 2 x  sin x  1  0  sin x   0, 
 2 
3. B
xx1  yy1  9
 y1  0 and x1  1
So, Points is (1, 0)
Now, use T2 = SS1

4. B
k 1 2
 k 
k 2 2 3
 1
  2     7
4 4

5. A
Let A  Vertex, AP  chord of x2 = 4y such that slope of AP is cot.
Let P  ( 2t, t2)
t t
Slope of AP =  cot =  t = 2cot
2 2
Now, AP = 4t 2  t 4 = t 4  t 2 = 4cot cosec = 4cos . cosec2α

6. D
Since normals at P and Q are perpendicular, the tangents at P and Q will also be
perpendicular but any two perpendicular tangents of a parabola always intersect on its
directrix. The parabola is (y – 2)2 = 2( x +2). So its directrix is 2x + 5 = 0
7. A
We know any side of the triangle is more than the difference of the remaining two sides so
that |PR – PQ|  RQ
 The required point P will be the point of intersection of the line RQ with parabola which is
(a, 2a) as PQ is a tangent to the parabola.
8. A
A  (at12, 2at1)
B  (at22, 2at2)
Tangents at A and B will intersect at the point C, whose coordinate is given by
(at1t2, a(t1+t2)) clearly ordinate of A , C and B are always in A.P.
9. D
Equation of line is x + 3y = 3
Co-ordinate of M    , 
12 9
 5 5
1 9 27
So, Area of  is = 3 =
2 5 10
10. B
One condition will be a2 = 2b2
b2 = 9 and a2 = 18

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TWO_YEAR_CRP(2224)_B-LOT_PHASE-2(CPT-2) 17

3
 e
2
11. B
3 5
e1   e2 
5 3
be = 5
than b = 3 and a = 4

12. B
Let 2a  x,3b  y
We get two equation in x and y solve them, and we get values of a and b.
13. C
x 2  2x  x  2  x = 1 and –2
But x cant be = –2
Hence there is only one solution.
14 D
(i) f(2)>0  a<4 (ii) a2-4a0  a   , 0   4,  
15. A
D  0  b 2  4ac  0
a  c
2
 16ac  0
a c a c
  2  12   2 3
c a c a
16. B
 tan    a  1 ;  tan 
1 1 tan  2   b  a  ; tan 1.tan  2 . tan 3  b

tan 1   2  3   1  1   2  3 
4
17. A
(12  x)8/7  (27 x)8/7    x  128
c
18. Let  ,  ,    a    1  2        2   2  b       3 
a
19. B
 x  0; x 2  1  0; x  1  x  1 ........... 1
Now x2  1  1  x2  2  0  x    2, 2  ...........  2
From (1) and (2)

20. C
 bc  a    ab  c  ac  b 
2
2 2 2

 a 3  b3  c 3  3abc

INTEGER
1. y  mx  c touches the curve
x2
So, (4x  c)2  1
4
D=0
65
Thus, C2 
4
So, 2 values of ‘C’.

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TWO_YEAR_CRP(2224)_B-LOT_PHASE-2(CPT-2) 18

a 
2. y = 1 – 2x passes through  ,0 
e 
Hence, e = 2ª
And y = 1 – 2x is tangent So, 1  a2 (e2  1)  4a2
On solving we get e = 2

3. This equation has only one solution for  = 0

4.  a  b   3b  c   3c  d    e  d   0
2
5. a x  b x  c  0 no real value of x

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