5
5
(memory based)
INSTRUCTIONS
· This question paper contains total 150 questions divided into four parts:
Part I : Physics Q. No. 1 to 40
Part II : Chemistry Q. No. 41 to 80
Part III : Mathematics Q. No. 81 to 125
Part IV : (A) English Proficiency Q. No. 126 to 140
(B) Logical Reasoning Q. No. 141 to 150
· All questions are multiple choice questions with four options, only one of them is correct.
· Each correct answer awarded 3 marks and –1 for each incorrect answer.
· Duration of paper 3 Hours
bonds CH3
(b) high electron gain enthalpy of phosphorus -
HIOOH
(c) high oxidation state of phosphorus A ¾¾¾
4®B
¾¾¾® C
(d) presence of two –OH groups and one P–H O
bond
69. The pair in which both species have same CHO
magnetic moment (spin only value) is : (a) (b)
(a) [Cr(H2O)6]2+ , [CoCI4]2– CH3
CH3
(b) [Cr(H 2O6 ) 2+ 3+
,[Fe(H 2 O)6 ] CHO
CHO
(c) 2+ 2+
[Mn (H 2 O) 6 ) , [Cr(H 2 O) 6 ]
(c) (d)
(d) [CoCl 4 ) 2- 2+
, [Fe(H 2 O) 6 ]
CHO
74. Nucleophilic addition reaction will be most (a) 176.66 ml (b) 156.6 ml
favoured in (c) 116.0 ml (d) 196.1 ml
(a) (CH3)2C = O
PART - III : MATHEMATICS
(b) CH3CH2CHO
81. A class has 175 students. The following data
(c) CH3CHO shows the number of students obtaining one or
O
|| more subjects. Mathematics 100, Physics 70,
(d) CH3 – CH2 – CH2C – CH3 Chemistry 40; Mathematics and Physics 30,
Mathematics and Chemistry 28, Physics and
75. Identify the prdouct C in the series Chemistry 23; Mathematics, Physics and
Na / C H OH Chemistry 18. How many students have offered
CH 3CN ¾¾¾¾¾¾
2 5
®A Mathematics alone?
HNO Cu / 573K (a) 35 (b) 48 (c) 60 (d) 22
¾¾¾¾ 2 ® B ¾¾¾¾¾ ®C
82. If x sin3 q + y cos3 q = sin q cos q and
(a) CH3COOH (b) CH3CH2NHOH
x sin q = y cos q, then x2 + y2 =
(c) CH3CONH2 (d) CH3CHO
(a) 1 (b) 2
76. When NH3 is passed over heated metal A, its
amide is formed. The metal is (c) 0 (d) None of these
(a) Mg (b) K (c) Al (d) Pb 83. If cos 7q = cos q – sin 4q, then the general value
of q is
77. Insulin production and its action in human body
np np p
are responsible for the level of diabetes. This (a) , + ( -1) n
compound belongs to which of the following 6 3 18
categories ? np np p
(b) , + ( -1) n
(a) An enzyme (b) A hormone 3 3 18
(c) A co-enzyme (d) An antibiotic np np p
78. Which statement is incorrect about peptide (c) , ±
4 3 18
bond?
np np p
(a) C–N bond length in proteins is longer than (d) , + ( -1) n
usual C–N bond length. 4 3 18
(b) Spectroscopic analysis shows planar z+2
84. If the real part of is 4, z ¹ 1, then the locus
structure of - C - NH - bond. z -1
||
O of the point representing z in the complex plane
(c) C–N bond length in proteins is smaller than is
usual C–N bond length. (a) a straight line parallel to x-axis
(d) None of these (b) a straight line equally inclined to axes
79. A mixture of chlorides of copper, cadmium, (c) a circle with radius 2
chromium, iron and aluminium was dissolved in 1
(d) a circle with radius
water acidified with HCl and hydrogen sulphide 2
gas was passed for sufficient time. It was filtered, 85. If a and b are the roots of x2 – x + 1 = 0, then the
boiled and a few drops of nitric acid were added equation whose roots are a100 and b100 are
while boiling. To this solution ammonium (a) x2 – x + 1 = 0 (b) x2 + x – 1 = 0
2
chloride and sodium hydroxide were added and (c) x – x – 1 = 0 (d) x2 + x + 1 = 0
filtered. The filterate shall give test for. 86. The set of all real x satisfying the inequality
(a) Sodium and iron 3 ,| x |
(b) Sodium and aluminium ³ 0, is
4,| x |
(c) Aluminium and iron (a) [–3, 3] È (–¥, –4) È (4, ¥)
(d) Sodium, iron, cadmium and Al (b) (–¥, –4) È (4, ¥)
80. Volume of 3% solution of sodium carbonate
(c) (–¥, –3) È (4, ¥)
necessary to neutralise a litre of 0.1 N sulphuric
acid (d) (–¥, –3) È (3, ¥)
87. If x satisfies | 3 x – 2 | + | 3x – 4 | + | 3x – 6 | ³ 12, then æ1 ö
8 8 -4 (c) (–1, 2), ç , - 1÷
è2 ø
(a) 0 £ x ³ (b) x ³ or
3 3 3 æ1 ö
8 (d) (1, 2), ç , - 1÷
(c) x £ 0 or x ³ (d) x ³ 2 only è2 ø
3
88. In how many ways can 5 boys and 5 girls be 95. A pair of tangents are drawn from the origin to
seated at a round table so that no two girls may the circle x2 + y2+ 20 (x + y) + 20 = 0, then the
be together ? equation of the pair of tangent are
(a) 4! (b) 5! (c) 4! + 5! (d) 4! × 5! (a) x 2 + y2 - 5xy = 0
89. A box contains two white balls, three black balls (b) x 2 + y2 + 2x + y = 0
and four red balls. In how many ways can three
(c) x 2 + y 2 – xy + 7 = 0
balls be drawn from the box if at least one black
ball is to be included in the draw? (d) 2x 2 + 2y2 + 5xy = 0
(a) 64 (b) 129 96. An ellipse has OB as semi minor axis, F and F '
(c) 84 (d) None of these
its focii and the angle FBF ' is a right angle.
90. The coefficient of the middle term in the
Then the eccentricity of the ellipse is
expansion of (2 + 3x)4 is :
(a) 6 (b) 5! (c) 8! (d) 216 1 1 1 1
(a) (b) (c) (d)
91. If C0, C1, C2, .............. Cn denote the binomial 2 2 4 3
coefficientsin theexpansion of (1 + x)n, then the 97. If the line 2x – 3y = k touches the parabola
value of y2 = 6x, then find the value of k.
C0 + (C0 + C1) + (C0+ C1 + C2) + .... (a) –15/4 (b) –27/4 (c) –1/4 (d) –3/4
+ (C0+ C1 + .....+ Cn–1) 98. S and T are the foci of an ellipse and B is an end
(a) n.2n–1 (b) n.2n of the minor axis. If STB is an equilateral triangle,
(c) (n – 1).2n–1 (d) (n – 1).2n then the eccentricity of the ellipse is
92. The sum of the series 1 1 1 2
1 + 2 .2 + 3 .22 + 4 .23 + .... + 100 .299 is (a) (b) (c) (d)
4 3 2 3
(a) 100 .2100 + 1 (b) 99 .2100 + 1
99. 5 3 2 2
Let f(x) = (x – 1)(x + 1), g(x) = (x – 1)(x – x + 1)
(c) 99 .2100 – 1 (d) 100 .2100 + 1
93. The quadratic equation whose roots are the x and let h(x) be such that f(x) = g(x)h(x). Then
and y intercepts of the line passing through (1, 1) lim h(x) is
x®1
and making a triangle of area A with the
co-ordinate axes is (a) 0 (b) 1 (c) 3 (d) 5
100. In the truth table for the statement (p Ù q) ® (q Ú ~ p),
(a) x 2 + Ax + 2A = 0 the last column has the truth value in the
(b) x 2 - 2Ax + 2A = 0 following order is
(c) x 2 - Ax + 2 A = 0 (a) TTFF (b) FTTT
(d) None of these (c) TFTT (d) TTTT
94. If 4a2 + b2 + 2c2 + 4ab – 6ac – 3bc = 0, the family 101. If the value of mode and mean is 60 and 66
of lines ax + by + c = 0 is concurrent at one or the respectively, then the value of median is
other of the two points- (a) 70 (b) 64 (c) 90 (d) 50
102. Find the variance of the data given below
æ 1ö
(a) ç -1, - ÷ , (–2, –1) Size of item 3.5 4.5 5.5 6.5 7.5 8.5 9.5
è 2ø
Frequency 3 7 22 60 85 32 8
æ 1ö
(b) (–1, –1), ç -2, - ÷ (a) 1.29 (b) 2.19
è 2ø
(c) 1.32 (d) None of these
103. Let R be the relation on the set R of all real 111. The function f (x) = (x(x–2))2 is increasing in the
numbers, defined by aRb If |a – b| £ 1. Then, R is set
(a) reflexive and symmetric only (a) (– ¥, 0) È (2, ¥) (b) (– ¥, 1)
(b) reflexive and transitive only (c) (0, 1) È (2, ¥) (d) (1, 2)
(c) equivalence 112. If a2 x4 + b2 y4 = c4, then the maximum value of
(d) None of the above xy is
104. The greatest and least values of c c2 c c2
(sin–1 x)2 + (cos–1 x)2 are respectively (a) (b) (c) (d)
ab 2 ab 2 ab 2ab
p2 p -p 2
(a) and 0 (b) and (x - 1)
4 2 2 113. ò dx is equal to
2 2 (x + 1) x 4 + 1
2
5p p p2 - p2
(c) and (d) and æ x2 +1 ö
4 8 4 4 sec -1 ç +c
105. The value of
(a) ç 2 x ÷÷
è ø
é1 æ æ 63 ö ö ù æ x2 +1 ö
cos ê cos -1 ç cos çç sin -1 ÷ ÷ ú is – 1
sec -1 ç +c
êë 2 ç
è è 8 ÷ø ÷ø úû (b)
2 ç 2 x ÷÷
è ø
(a) 3/16 (b) 3/8 (c) 3/4 (d) 3/2
-1 æ x + 1 ö
2
1
( x – 3) ( x – 3) 2 ç +c
ç 2 ÷÷
1 (c) sec
2 è ø
106. The determinant 1 ( x – 4 ) ( x – 4) 2 (d) None of these
1 ( x – 5) ( x – 5) 2 p /2
sin x
vanishes for 114. Evaluate ò 1 + cos2 x
dx
(a) 3 values of x (b) 2 values of x 0
(c) 1 values of x (d) No value of x (a) p/2 (b) p/4 (c) p/3 (d) p
107. If the lines lx + my + n = 0, mx +ny + l = 0 and 115. Area intercepted by the curves y = cos x,
nx + ly + m = 0 are concurrent then x Î[0, p] and y = cos 2x, x Î[0, p] , is
(a) l + m + n = 0 (b) l – m – n = 0
3p 3 3 3p 3 3
(c) l + m – n = 0 (d) m + n – l = 0 (a) (b) (c) (d)
2 2 4 4
x 2 x3 dy 116. The general solution of the differential equation
108. If y =1 + x + + +....¥, then is equal to
2! 3! dx dy
+ sin( x + y ) = sin( x - y ) is
(a) x (b) 1 dx
(c) y (d) None of these (a) log tany + sin x = C
y
(b) log tan + 2sin x = C
ì x 2 + 3x - 10 2
ï , when x ¹ -5 y
109. If f (x) = í x 2 + 2x - 15
(c) tan + log sin x = C
ï a , when x = -5 2
î
(d) None of these
is continuous at x = –5, then the value of ‘a’ will be 117. The solution to the differential equation
(a) 3/2 (b) 7/8 (c) 8/7 (d) 2/3 dy yf ' (x ) - y 2
= where f (x) is a given function
110. The equation of all lines having slope 2 which dx f (x )
1 is
are tangent to the curve y = , x ¹ 3 , is
x -3 (a) f(x) = y(x + c) (b) f(x) = cxy
(a) y = 2 (b) y = 2x (c) f(x) = c(x + y) (d) yf(x) = cx
(c) y = 2x + 3 (d) None of these
uur uur uur 125. A shopkeeper wants to purchase two articles A
118. If a , b , c are three unit vectors such that
uur uur uur uur ur and B of cost price ` 4 and ` 3 respectively. He
a + b + c = 0 , where 0 is null vector, then thought that he may earn 30 paise by selling article
uur uur uur uur uur uur
a .b + b . c + c . a is : A and 10 paise by selling article B. He has not to
purchase total articles worth more than ` 24. If
3 he purchases the number of articles of A and B, x
(a) – 3 (b) – 2 (c) - (d) 0
2 and y respectively, then linear constraints are
119. If vectors 2i – j + k, i + 2j – 3k and 3i + aj + 5k are (a) x ³ 0, y ³ 0, 4x +3 y £ 24
coplanar, then the value of a is (b) x ³ 0, y ³ 0, 30x + 10 y £ 24
(a) 2 (b) –2 (c) –1 (d) –4 (c) x ³ 0, y ³ 0, 4x +3 y ³ 24
120. The coordinates of the point where the line (d) x ³ 0, y ³ 0, 30x +40 y ³ 24
through the points A (3, 4, 1) and B (5, 1, 6) crosses
the XY-plane are PART - IV : ENGLISH
æ 13 23 ö æ 13 23 ö
(a) ç , ,0÷ (b) ç - , , 0 ÷ DIRECTIONS (Qs. 126 - 128): Out of the four
è5 5 ø è 5 5 ø alternatives, choose the one which express the correct
æ 13 23 ö æ 13 -23 ö meaning of the word.
(c) ç , - ,0÷ (d) ç - , ,0÷
è 5 5 ø è 5 5 ø 126. SAGACIOUS
121. Find the angle between the two planes 2x + y – 2z = 5 (a) Shameless (b) Wise
and 3x – 6y – 2z = 7. (c) Powerless (d) Foolish
(a) cos–1 (4/21) (b) cos–1 (2/21) 127. REMEDIAL
–1
(c) cos (1/21) (d) cos–1 (5/21) (a) Corrective (d) Proficient
122. For k = 1, 2, 3 the box Bk contains k red balls and (c) Damaging (d) Optional
1 1 128. RETICENT
(k + 1) white balls. Let P(B1 ) = , P(B2 ) = and (a) Confident (d) Sad
2 3
1 (c) Truthful (d) Secretive
P(B3 )= . A box is selected at random and a ball
6 DIRECTIONS (Qs. 129 - 131): Choose the word
is drawn from it. If a red ball is drawn, then the opposite is meaning to the given word.
probability that it has come from box B2, is
129. FIDELITY
35 14 10 12
(a) (b) (c) (d) (a) Faith (b) Devotedness
78 39 13 13 (c) Allegiance (d) Treachery
123. The probability of India winning a test match 130. INFRANGIBLE
against West Indies is 1/2. Assuming indepen-
(a) Complecated (d) Breakable
dence from match to match, the probability that
(c) Weird (d) Software
in a 5 match series India’s second win occurs at
131. PROGENY
the third test, is –
(a) Kid (b) Parent
(a) 2/3 (b) 1/2 (c) 1/4 (d) 1/8
(c) Friend (d) Enemy
124. An object is obseved from the points A, B and
C lying in a horizontal straight line which DIRECTIONS (Qs. 132 - 134): A part of sentence is
passes directly underneath the object. The underlined. Below are given alternatives to the
angular elevation at B is twice that at A and at underlined part (a), (b), (c) and (d) which may improve
C three times that at A. It AB = a, BC = b, then the sentence. Choose the correct alternative.
the height of the object is 132. It was not possible to drag any conclusion so he
b a left the case.
(a) (a + b) (3b – a) (b) (a + b) (3b – a) (a) Fetch (b) Find
2a b
a 2a (c) Draw (d) No improvement
(c) (a + b) (3b – a) (d) (a + b) (3b – a)
2b b
133. I am looking after my pen which is missing. 141. In a certain code language ‘DOME’ is written as
(a) Looking for (b) Looking in ‘8943’ and ‘MEAL’ is written as ‘4321’. What
(c) Looking back (d) No improvement group of letters can be formed for the code
134. “Mind your language !” he shouted. ‘38249’?
(a) change (b) inspect (a) EOADM (b) MEDOA
(c) hold (d) No improvement (c) EMDAO (d) EDAMO
142. Find the missing number from the given
DIRECTIONS (Qs. 135 - 137): Fill in the blanks.
response.
135. I ..... to go there when I was student.
93 27 79 38 67 16
(a) liked (b) used
(c) prefer (d) denied
136. She was angry ...... me.
(a) at (d) about 63 37 42
(c) with (d) in
137. You should not laugh ...... the poor.
(a) on (b) at 3 4 ?
(c) with (d) over Fig. 1 Fig. 2 Fig. 3
DIRECTIONS (Qs. 138 - 140): In the questions below, (a) 5 (b) 6 (c) 8 (d) 9
143. Which of the following correctly represents the
each passage consists of six sentences. The first and
relationship among illiterates, poor people and
sixth sentence are given in the beginning. The middle
unemployed?
four sentences in each have been removed and jumbled
up. These are labeled as P, Q, R and S. Find out people
order for the four sentences. (a) (b)
Þ a = g tan q =
16 g
12. (d) As the disc is in combined rotation and 20. (c) Applying gas equation, pV = nRT
translation, each point has a tangential We can write, p1V = n1RT1 and p2V = n2RT2
velocity and a linear velocity in the forward p 2 n 2 T2 1 2T
direction. From figure Þ = ´ = ´ =2
p1 n1 T1 1 T
vnet (for lowest point) v/R
= v – Rw = v – v = 0 Þ p2 = 2p
and acceleration
v2 v2 21. (d) We know, Vrms = 3RT
= +0= v=R
M
R R Þ % increase in
(since linear speed is constant)
13. (d) Gravitaional field inside the shell is zero, so 3RT2 3RT1
-
no work required. M M ´ 100
Vrms =
14. (d) 15. (b) 3RT1
16. (c) Heat current in first rod (copper)
M
390 ´ A(0 - q)
= T2 - T1
l = ´100
Here q is temperature of the junction and A T1
& l are area and length of copper rod.
Heat current in second rod (steel) 400 - 300
= ´ 100
46 ´ A(q - 100) 300
=
l 20 - 17.32
In series combination, heat current remains = ´ 100 = 15.5%
17.32
same. So, 22. (b) We know that
390 ´ A(0 - q) 46 ´ A(q - 100) PAVA = nART, PBVB = nBRT
=
l l and Pf (VA + VB) = (nA + nB) RT
– 390 q = = 46 q – 4600 Pf (VA + VB) = PAVA + PBVB
436 q = 4600 Þ q = 10.6ºC
17. (d) Stefan’s law for black body radiation æP V +P V ö
\ Pf = ç A A B B ÷
Q = se AT4 è VA + VB ø
1/ 4
é Q ù 1.4 ´ 0.1 + 0.7 ´ 0.15
T=ê 2 ú
= MPa = 0.98 MPa
êë s(4pR ) úû 0.1 + 0.15
Here e = 1 dx
23. (a) Velocity, v = = - A w sin (w t + p / 4)
A = 4pR2 dt
18. (d) For all process Velocity will be maximum, when
DU = DQ – DW wt + p/4 = p/2 or wt = p/2 – p/4 = p/4
does not change as it depends on initial or t = p/4w
final states. 24. (c) Velocity of wave v = nl
19. (a) The efficiency of the heat engine is v
where n = frequency of wave Þ n =
T æ 273 + 27K ö 4 v 396 l
h = 1- 2 = 1- ç = n2 = 2 = = 396 Hz
T1 è 273 + 427K ÷ø 7 l 2 100 ´ 10-2
W no. of beats = n 1 – n2 = 4
But h =
Q1 æ xö
25. (d) y = x0 cos2p ç nt - ÷
W 1.0kW è lø
\ Q1 = = =1.75kW =0.417 kcal / s 2p
h 4/7 y = x0 cos (vt – x) [Qv = nl]
Thus, the engine would require 417 cal of heat l
æ dy ö 2p
per second, to deliver the requisite amount of çè ÷ø
dt max = x0 × l v = 2v(given) \ l = px0
work.
r r
26. (b) 2 2 2 31. (b) v and B are in same direction so that
Fnet = F + F + 2F cos 60° = 3F
magnetic force on electron becomes zero,
27. (a) Initial energy of combined system only electric force acts. But force on electron
1 1 due to electric field is opposite to the
U1 = CV12 + CV22 direction of velocity.
2 2
32. (a)
V + V2
Final common potential, V = 1 , m0 N1N 2A
2 33. (d) M=
Final energy of system, l
2 4p´ 10-7 ´ 300 ´ 400 ´ 100 ´ 10-4
1 æ V + V2 ö =
U2 = 2 ´ C ç 1 0.2
2 è 2 ÷ø = 2.4p × 10–4 H
Hence loss of energy = U1 – U2 IS N P 1 1
34. (c) = = Þ IS = ´ 4 = 1 A
1 IP NS 4 4
= C ( V1 - V2 )
2
4 35. (c)
28. (d) Fuse wire should be such that it melts 36. (b) Frequency does not change on refraction.
immediatley when strong current flows 37. (b) Cutting a lens in transverse direction
through the circuit. The same is possible if its doubles their focal length i.e. 2f.
melting point is low and resistivity is high. Using the formula of equivalent focal length,
29. (b) \ 4i1 + 2(i1 + i2) – 3 + 4i1 = 16V ...(i) 1 1 1 1 1
Using Kirchhoff’s second law in the closed = + + +
f f1 f2 f3 f4
loop we have We get equivalent focal length as f/2.
9 – i2 – 2(i1 + i2) = 0 …(ii) 38. (b) n1 l1 = n2 l2
Solving equations (i) and (ii), we get
10 × 7000 = n2 × 5000 Þ n2 = 14
i1 = 1.5 A and i2 = 2 A
39. (b) I ® ON
\ current through 2W resistor = 2 + 1.5 = 3.5 A. II ® OFF
30. (b) The magnetic field at C due to first conductor In IInd state it is used as a amplifier it is
m I active region.
is B1 = 0 (since, point C is separated
2p 3d 2 40. (b) Y = A + (A.B) = (A + A).(A + B)
d 3d =A+B
by d + = from 1st conductor). The
2 2 Þ OR gate
direction of field is perpendicular to the
plane of paper and directed outwards. PART - II : CHEMISTRY
The magnetic field at C due to second wt ´1000
41. (d) Molarity (M) =
m 10 mol. wt. ´ vol (mL)
conductor is B2 = 0 (since, point C wt. 1000
2p d 2 2= ×
d 63 250
is separated by from 2nd conductor) 63
2
wt. = g
The direction of field is perpendicular to the 2
plane of paper and directed inwards. 100
wt. of 70% acid = ´ 31.5 = 45 g
Since, direction of B1 and B2 at point C is in 70
opposite direction and the magnetic field at 42. (d) Radius of hydrogen atom = 0.530 Å, Number
C is zero, therefore, of excited state (n) = 2 and atomic number
B1 = B2 of hydrogen atom (Z) = 1. We know that the
Bohr radius.
m0 I m 10
= 0 n2 (2)2
2p 3d 2 2p d 2 (r ) = ´ Radius of atom = ´ 0.530
On solving I = 30.0 A Z 1
= 4 × 0.530 = 2.12 Å
43. (d) The screening effect of inner electron of the (2 x)2
nucleus causes the decrease in ionization Kc = = 10-6
(1 - x)
potential, therefore the order of the screening
It shows that (1 – x) < 2x
effect is
51. (c) Kp = Kc(RT)Dn;
f<d<p<s æ 1ö 3 1
Dn = 1 - ç1 + ÷ = 1 - = -
Hence, the screening effect of d-electron is è 2ø 2 2
less than p-electron. Kp
44. (b) Rare gases; as the e– is to be removed from \ = (RT ) -1 / 2
Kc
stable configuration.
45. (c) Amongst isoelectronic species, ionic radii 52. (c) Na2S4O6
of anion is more than that of cations. Further 2 + 4x – 12 = 0
size of anion increase with increase in –ve 4 x – 10 = 0
charge and size of cation decrease with 10 ∗5
increase in + ve charge. Hence ionic radii x= =
4 2
decreases from O– to Al3+.
∗5
46. (b) B2 and O2 are paramagnetic due to presence Oxidation state of S is =
2
of un paired electron. MO electronic
53. (a) Zn + H2SO4 ↑ ZnSO4 + H2
configuration of B2 is :
Zn + 2NaOH ↑ Na2ZnO2 + H2
s1s 2 s *1s 2 s2s 2 s * 2 s 2 p2 p1x = p2 p1y [ Ratio of volumes of H2 evolved is 1 : 1
MO electorn i.e. configuration of O2 is : 54. (d) The stability of alkali metal hydrides
2 2 2 2 decreases from Li to Cs. It is due to the fact
s1s s *1s s2s s * 2s s 2 p z2 p2 p x2
that M–H bonds becomes weaker with
= p2 p 2y p * 2 p1x = p * 2 p1y increase in size of alkali metals as we move
47. (b) RMS velocity of molecules depends on down the group from Li to Cs. Thus the
mass. If mol. wt. increases, rms velocity of order of stability of hydrides is
melocules decreases. LiH > NaH > KH > RbH > CsH
1 55. (d) –NO 2 group, being strong electron
rms µ withdrawing, disperses the –ve charge,
m.wt
hence stabilizes the concerned carbanion.
The order of increasing m. wt. is
56. (a) A chiral object or structure has four different
H 2 < N 2 < O 2 < HBr groups attached to the carbon.
Order of Vrms of molecules.
* *
HBr < O 2 < N 2 < H 2 . 57. (d) The structure CH 3 C H Br C H Br COOH
48. (a) DH = DH(product) – DH(reactant) has two different chiral carbon atoms, hence
number of enantiomers (optically active
162 = 2 × DH H - DH H 2
forms) is 2n = 22 = 4
162 58. (a) Electrolysis of a concentrated aqueous
DH H = (Q DH H 2 = 0)
2 solution of either sodium or potassium salts
DHH = 81 Kcal of saturated carboxylic acids yields higher
49. (c) By bomb calorimeter we get DE . alkane at anode.
2RCOOK ¾¾ ¾ ¾¾® 2 RCOO - + 2 K +
Electrolyt ic
2C6 H 6 (l) + 15 O 2 (g) ¾¾® Oxidation Anode Cathode
12CO2(g) + 6H2O (l) -
At anode 2RCOO ® 2RCOO + 2e ¾ ¾® –
DH – DE = DnRT
= (12 – 15) × 8.314 × 300 = – 7.483 kJ R — R + 2CO2
50. (b) I2 2I
– At Cathode 2K + + 2e – ® 2K
2K + H 2 O ® 2KOH + H 2
1–x 2x
(Kolbe's Method)
OH Cl 66. (d) At high pressure the extent of adsorption
59. (c) CH ≠ CH + HO, , Cl∗ ↑ follows zero order kinetics.
CH =CH 67. (d) F2 is expected to have highest bond energy
but the correct decreasing order is
OH Cl
Cl2 > Br2 > F2 because of fluorine atom has
HO - ± Cl
¾¾¾¾¾
® CH CH ¾¾¾¾
® very small size due to which there is a high
- H 2O
inter electronic repulsion between two
OH Cl fluorine atoms so the bond between two
Unstable
fluorine gets weaker and need less energy.
Cl 68. (a) The acids which contain P–H bond have
CH – CHO strong reducing properties. Thus H3PO2
Cl acid is good reducing agent as it contains
2 , 2-Dichloro
-acetaldehyde two P–H bonds. For example, it reduces
60. (a) Green house gases such as CO2, ozone, AgNO3 to metallic silver.
methane, the chlorofluoro carbon compounds 4 AgNO3 + 2H2O + H3PO2 —®
and water vapour form a thick cover around
4Ag + 4HNO3 + H3PO4
the earth which prevents the IR rays emitted
69. (b) [Cr(H2O)6]2+ Cr is in Cr2+ form
by the earth to escape. It gradually leads to
increase in temperature of atmosphere.
61. (c) No change in density. Cr 2+
24 3d 4s
62. (c) When equal weights of different solutes are
present in equal volumes of solution the Fe 3+
molarity is inversely related to molecular 26 3d 4s
mass of the solute. Mol. mass of NaCl is
In [Fe(H2O)]2+ Fe2+ form. Both will have 4
less than KCl. Hence, molarity of NaCl
unpaired electrons.
solution will be more.
70. (a) Due to stronger–I-effect of F than that of
E.wt ´ Q Cl, CHF3 should be more acidic than
63. (c) m= ;
96500 CHCl3. But actually reverse is true.
m ´ 96500
\ E.wt = This is due to : CCl3- left after the
Q
removal of a proton from CHCl3 is
22.2 ´ 96500 stabilised due to presence of d-orbitals in
= = 60.3
2 ´ 5 ´ 60 ´ 60
At wt. 177
Cl than: CF3– left after the removal of a
Oxidation state = = =3
Eq. wt . 60.3 proton from CHF3 which is not stabilised
due to the absence of d-orbitals on F.
64. (d) At cathodes : Fe+ + 2e - ¾¾
® Fe;
71. (d) SN2 mechanism is followed in case of
Fe3+ + 3e - ¾¾ ® Fe primary and secondary halides i.e., SN2
At. wt. At. wt. reaction is favoured by small groups on the
(E Fe )1 = ; (E Fe )2 = carbon atom attached to halogens so
2 3
(E Fe )1 3 CH3 CH2 Br > CH3 CH2 CH2 Br >
Hence, = CH3
(E Fe ) 2 2 |
65. (c) The velocity constant doubles for every CH3– CH – CH2Br > CH3 – C – Br
10°C rise in temperature. | |
CH3 CH3
+ve charge density on carbon atom of
Å carbonyl group. More hindered carbonyl
72. (b) OH + H ¾® O—H
Å group becomes less reactive. So in the given
H case CH3CHO is the right choice.
Na / C H OH
75. (d) CH 3CN ¾¾ ¾2¾5¾
¾® CH 3CH 2 NH 2
(A)
H HNO Cu
H H
¾¾ ¾
¾2 ® CH CH OH ¾¾® CH CHO
3 2 3
( B) 573 K ( C)
Å 76. (b) When Potassium is treated with ammonia,
¬¾ then potassium amide is obtained.
1
K + NH 3 ¾¾® KNH 2 + H 2
Pot. amide 2
77. (b) Insulin is a biochemically active peptide
harmone secreted by pancreas.
78. (a) Due to resonance,
O O–
|| | +
73. (a) Dil.KMnO – C – NH – – C = NH – , C – N
¾¾¾¾¾
4®
bond acquires some double bond character,
hence shorter in length.
79. (b) CuS and CdS are precipitated by H2S.
CH3 Hydroxide of Al will pass into the solution
OH in the form of NaAlO2 being amphoteric in
HIO
¾¾¾
4®
nature. Hence filtrate will give test for
OH sodium and aluminium.
CH3 80. (a) Normality of 3% Na2CO3.
vic cis diol
3×1000
N= = 0.566 N
CH2 H 53×100
OH – For H2SO4 sol. N1 = 0.1, V1 = 100 mL
OO ¾¾®
For Na2CO3 sol. N2 = 0.566.
CH3
Now apply N1V1 = N2V2
– O N1V1 0.1´ 1000 mL
CH2 V2 = N = = 176.66mL
– 2 0.566
OO ¾¾® O
PART - III : MATHEMATICS
CH3 CH3
81. (c) n (M alone)
H+ = n(M) – n(M Ç C) – n(M ÇP) + n(M ÇC Ç P)
= 100 – 28 – 30 + 18 = 60
O O
D M P
¬¾¾ OH
– H2O
CH3 CH3
C
74. (c) Aldehydes are more reactive than ketones
due to +I effect of –CH3 group. There are
C
two – CH3 group in acetone which reduces
82. (a) x sin 3 q + y cos 3 q = sin q cos q ....(i) b = –w2, where w ¹ 1 is a cube root of unity..
Hence, a and b are the roots of the eq. If line (1) touches parabola (2) then roots of
quadratic equation (3) is equal
x 2 - ( a + b) x + ab = 0 Þ x 2 - 2Ax + 2A = 0 \ (–9)2 = 4 × 1 × (– 3k) Þ k = – 27/4
94. (a) 4a2 + b2 + 2c2 + 4ab – 6ac – 3bc
º (2a + b)2 – 3(2a + b) c + 2c2 = 0 x2 y2
98. (c) Let eq. of ellipse be =1, +
Þ (2a + b – 2c) (2a + b – c) = 0 Þ c = 2a + b a 2 b2
S is (–ae, 0), T is (ae, 0) and B is (0, b).
1
or c = a + b Y
2
B
The equation of the family of lines is
æ 1ö
a(x + 2) + b(y + 1) = 0 or a(x + 1) + b ç y + ÷ = 0 S T
X
è 2ø
giving the point of concurrence (–2, –1) or
æ 1ö
Þ SB = (0 + ae) 2 + b 2
ç -1, - ÷ .
è 2ø
Also SB2 = ST2 Þ 4a 2e 2 = a 2 e 2 + b 2
Þ 3a 2 e 2 = a 2 (1 - e 2 ) = a 2 - a 2 e 2 ( x5 - 1)( x3 + 1)
Þ xlim
1
Þ 4a 2 e 2 = a 2 Þ e 2 = Þ e =
1 ®1 ( x2 - 1)( x 2 - x + 1)
4 2 x 5 - 15
99. (d) Given f (x) = g(x) h(x) = lim = 5 ´ 14 = 5
x ®1 x -1
f ( x)
Þ h (x) = 100. (d) T T T T
g ( x)
101. (b) Mode = 3 Median – 2 Mean
f ( x) 1 1
Þ lim h( x) = xlim \ Median = (mode + 2 mean) = (60+ 2× 66)= 64
x ®1 ®1 g ( x) 3 3
102. (c) Occurance(xi) Frequency (fi) Freq* (xi) (xi-mean) (xi-mean)2 fi(xi-mean)2
3.5 3 10.5 –3.59 12.887 38.661
4.5 7 31.5 –2.59 6.707 46.952
5.5 22 121 121 2.528 55.609
6.5 60 390 –0.59 0.348 20.876
7.5 85 637.5 0.41 0.168 14.298
8.5 32 272 1.41 1.988 63.632
9.5 8 76 2.41 5.809 46.47
Total 217 1538.5 - - 286.498
and the greatest value is
Sf i ( xi – x ) 2 286.49
Variance s2 = = é æ - p p ö 2 p2 ù 2
Sf i 217 2 êç - ÷ + ú i.e. 5p .
= 1.32 êëè 2 4 ø 16 úû 4
103. (a) Since, | a - a | = 0 £1,so aRa, " a Î R 105. (c) The given trigonometric ratio
\ R is reflexive. é1 æ æ -1 1 ö ö ù
= cos ê ç cos ç cos ÷ ú
Now, aRb Þ | a - b | £1Þ | b - a | £1Þ bRa ë2è è 8 ø ÷ø û
\ R is symmetric. æ1 1ö
But R is not transitive as = cos ç cos -1 ÷
è2 8ø
1R2, 2R3 but 1 R 3
æ 1ö
[Q|1 – 3| = 2 > 1] 1 + cos ç cos -1 ÷
104. (c) We have, (sin–1 x)2 + (cos–1 x)2 è 8ø 3
= =
= (sin–1 x + cos –1 x)2 – 2 sin–1 x. cos–1 x 2 4
p2 æp ö 106. (d) The given determinant vanishes, i.e.,
= - 2 sin -1 x ç - sin -1 x÷
4 è2 ø 1 x - 3 ( x - 3)2
p2 1 x - 4 ( x - 4)2 = 0
= - p sin -1 x + 2 (sin -1 x ) 2
4
1 x - 5 ( x - 5)2
é p p2 ù
= 2 ê (sin -1 x ) 2 - sin -1 x + ú Expanding along C1, we get
êë 2 8 úû
(x – 4)(x – 5)2 – (x – 5)(x – 4)2 – {(x – 3)(x –5)2
éæ pö
2
p2 ù – (x – 5)(x – 3)2} + (x – 3)(x – 4)2
= 2 ê ç sin -1 x - ÷ + ú – (x – 4)(x – 3)2 = 0
êë è 4ø 16 úû
Þ (x – 4)(x – 5)(x – 5 – x + 4)
æ p2 ö p2 – (x – 3)(x – 5)(x – 5 – x + 3)
Thus, the least value is 2 çç ÷÷ i.e. +(x – 3)(x – 4) (x – 4 –x + 3) = 0
è 16 ø 8
Þ – (x – 4)(x – 5) + 2(x – 3)(x – 5) – (x – 3) \ maximum value of
(x – 4) = 0 c4 c4 c8
a2 x4. b2y4 = . =
Þ – x2 + 9x – 20+ 2x2 – 16x + 30 – x2 + 7x – 12 = 0 2 2 4
Þ – 32 + 30 = 0 Þ –2 = 0 æ c8 ö
1/4
c2
Which is not possible, hence no value of x Maximum value of xy = çç 2 2 ÷÷ =
satisfies the given condition. è 4a b ø 2ab
107. (a) Since the lines are concurrent, so
æ 1ö
l m n x 2 ç1 - 2 ÷ dx
è x ø
113. (b) I=ò
m n l = 0 Þ 3lmn – l3 – m3 – n3 = 0 1ö æ 1ö
1/2
æ
n l m x2 ç x + ÷ ç x2 + 2 ÷
è x ø è x ø
Þ (l + m + n) (l2 + m2 + n2 – lm – mn – nl) = 0
1 æ 1ö
Þ l + m + n = 0 [Q l2 + m2 + n2 > lm + mn + n] Let x + = p Þ ç1 - 2 ÷ dx = dp
x è x ø
dy
108. (c) y = ex Þ = ex = y
dx dp 1 p
I= ò = sec-1
(x - 2) (x + 5) -7 7 p p2 - 2 2 2
109. (b) lim f (x) = = =
x ®-5 (x + 5) (x - 3) -8 8 æ x2 +1 ö
1
= sec -1 ç +c
110. (d) The equation of the given curve is
2 ç 2x ÷÷
è ø
1
y= , x ¹ 3. p /2
x -3 sin x
The slope of the tangent to the given curve
114. (b) Let I = ò
1 + cos2 x
dx
0
dy -1 Let cos x = t and – sin x dx = dt.
at any point (x, y) is given by =
dx ( x - 3) 2 Now, x = 0 Þ t = cos 0 = 1 and
For tangent having slope 2, we must have p p
-1 x= Þ t = cos = 0
2= 2 2
( x - 3 )2 0
sin x æ -dt ö dt
0
1 \ I= ò 2ç
è sin x ÷ø = -ò 2
Þ 2(x – 3)2 = – 1Þ (x – 3)2 = - 1 1+ t 1 1+ t
2
which is not possible as square of a real -1
0 é pù p
= éë tan t ùû = - ê0 - ú =
number cannot be negative. 1 ë 4û 4
Hence, there is no tangent to the given curve
115. (d)
having slope 2.
111. (c) Here, f(x) = (x(x – 2))2
Þ f ¢(x) = 4x (x – 2) (x – 1)
For f(x) as increasing, f ¢(x) > 0
So, 4x (x – 1) (x – 2) > 0 Þ x(x – 1) (x – 2) > 0