excerciseOnCombustion
excerciseOnCombustion
1. Determine the HHV and LHV (on molar as well as mass basis) at 298 K for
gaseous n-decane (C10 H22 , Mol. Wt. 142.284). Data: hof,C10 H22 = -249,659
kJ kJ kJ
kmol
, hof,H2 O(l) = -285,857 kmol , hof,CO2 = -393,546 kmol .
2. Heptane (C7 H16 ) is burnt with 50% excess air. Determine (a) stoichiometric
air-fuel ratio (b) actual air-fuel ratio (c)oxygen present in products by volume
and (d) calorific value
8. Determine the constant pressure Adiabatic Flame temperature (at 1 atm) for
the combustion of a CH4 -air mixture if :
10. Propane (C3 H8 ) is burnt with stoichiometric air in a constant volume cylinder
such that no heat escapes from the cylinder. If the initial temperature of the
mixture is 200 ◦ C, what is the final temperature of the products.
11. Air enriched with Oxygen is stored in a cylinder such that the O2 to N2 ratio
is 1:2 (rather than 1:3.76 that is available in the surrounding air). If acetylene
is burnt with this air in a stoichiometric amount what is the adiabatic flame
temperature? You can assume that initial temperature of the reactants is
25◦ C.
12. Methane (CH4 ) at 25o C, enters the combustor of a simple open gas turbine
power plant and burns completely with 400% of theoretical air entering the
compressor at 25 ◦ C, 1 atm. Products of combustion exit the turbine at 577
◦
C, 1 atm. The rate of heat transfer from the gas turbine is estimated as
10% of the net power developed. Determine the net power output, in MW,
if the fuel mass flow rate is 1200 kg/h. Kinetic and potential energy effects
are negligible.
13. A closed, rigid vessel initially contains a gaseous mixture of 1kmol of pentane
(C5 H12 ) and 150% of theoretical air at 25 ◦ C, 1 atm. If the mixture burns
completely, determine the heat transfer from the vessel, in kJ, and the final
pressure, in atm, for a final temperature of 800K.