CENTRE FOR

DISTANGE LLEARNING
OBAFEMI AWOLOWO UNIVERSITY ILE-JFE, OSUN
APRIL 2023, FIRST CONTACT sTATE, NIGERIA
CHEMISTRY EXAMINATiON, Time
JUPEBAllowed: 3 Hours
Answer all
SECTION A:questions
In both
1. Given the
MUL
LTIPLE CHOICEsections.
QUESTIONS
operation 6.079
2. A 9.160 g B.9 15872072g+3.00
AD3 mm' paraffin oil flm ce157 g
g. the correct answer is?
1.0x 10! nm B 1.0xferms a
10- hmn C. 0.1 x 10- 10-7
ate the thickness of the flm in nanomoter,
D a t e analysis, glven three mennurements 22.40, 22.70 and 22.10. if the true value is 23.00.
A Drecise o c a n d accuracy of the measurerment and calculate the absoluta erro
e. 0.80
D not precise, not acc Bprecise, not accurate, 0.60 C not precise, accuraie, 0.60.
4. The basic Sl unit equivalence of one
A Kgms-! B Kgms- C newton is?
Kgms D Kgns
D. Rutherford in his gold foil experiment suggests that an atom consist mosty empty space due to
Tenecion of some alpha particles B defiection of some alpha partices C passage of most alpha particles
particles through the foil
rect vahues of me
6. Given n =3 the correct
A 0 9 0 1,0,-1 32,1,0,-1,-2,-3 C01,0,-1 D 0 1,0,-1 2,1,0,-1,-2
7. What s the total number of electrons that can be found in each of the following sets of quantum numbers,
(0) n=5 m=+1, () n=5 ms = (ü) n=3(=2
A 10,4, 8 B 4 10, 8 C' 8, 25, 10 D 25, 8, 10
8. Hydrogen undergo ionization to form H*.calculate the ionization energy.
A 218x 10-1 B 218x 10" 2.81 x 101" J
9 odnnes eguation except
A Spin B prindpal C Bzimuthal D magnetic ma
10. The correct emission spectrum of hydrogen is glven as
A 468 nm, violet B 486 nm violet C 434 nm violet D 410 nm violet
11. An element Qin the periodic table has the electron confguration 1s'2s2p° What periad and grcep ia ?
A 2,5 B
12 5,2e
their ionic fom Be Li 0- N- F, screening effect is highest
in which one? A B O- C N D F is ?
13. The number of ions of aluminium present in 0.05 mol of Al,0,
A. 0.602x 10 lonsB 6.02 x 10 lons C 3.01 x 10 lons D 6.c2x 103 ions
100 em² dlstlled waler, what is tho molar
14. Y is a 1.2 M solution made by dissolving 4.08 g of substance Win
mass of W? A 43 B 34 C 12 D 40.08
15. Given cC0, dH,0, the correct values for coemcients
the equation of reacion ten 2 10 C 2. 13, 8. 10 D 1,6,4, 5
reacted with sodium carboale, whatis the
16. Carbonate of Barium was deposited when 5 58 g of barium chioride
A 558g B 5.92g C 295 g D' 5 29 g
amount in g of barium carbonate forned? combustion to form 7.92 g H,0 and 9.70 g Co, Calcuate the empirical
17.A hydrocarbon of unknown mass undergo
olo cf the hydrocarbon. A. CHe B CH ) acid according to the equation
18. A student dissolved 40 g of Magnesium ribbo .Given that 1,50 g of H, was lberated calc ate the percentage
Mg 2HNOag) 3 D4A 68%
ylekd. A 45.5%
reaction Cutg) + H,SO(aa)- CuS0, Hi the oxidation states of Cu at the
19. Given the equation of
C 0.2 D 0.0
d of the reaction is. A 2,0 B 22
The corect axpression in agroerment with definition of precipltation reaction is2K 2KNO(n)
20. The
PBlz) +2KNO(ag) B Pb(NOo)za)+ PBla
Pb (NO)9) 2Klag) 2KNO) DPb(NO,1)ay + 2Kl,) PBi) 2KNO,aa)
C Pb(NO;3))2a0) +2Kl,ag) PBI¡ea) + is given as
standard enthalpy of neutralization
equation which best describes theNaOH+
21. The HCI NaCl + H,0
A Zn + HCI ZnCi, + H, B
 C Ca(OH), 2HNO, -Ca(NO,D2 2H,0 D
2NaOHH,S0, Na, SO, 2H,0
22 Borane reacts with ammoria to form ammonia borene, what is the reguirement for the type of bonding bowe
ona and botanerA aone pair in borane B a bond palr in ammonig an emcty orbital in borane
23. The correct equation which correlates with the
B NaCl)
definition of Latice energy is? A Na, Cl NaCl()
Na+ a C NaCl) - Nat
24. The following molecules are polar except A NH, B H,0 C HF ip+ C NaCl)
25 The mclecular geometry and bond anglo
C tetrahedral, 109.5 D
of Xef, is A tetraedral, 90 B square planar, 109.5°
square planar, 90

The diagram above

23-29. represents the phase diagram of carbon(iV)oxlde. Use tha diagram to answer
20. Based ch ts
questions
phase diagram, wthich is the densest state for CO:? (ay Sold (b)
iquid (c) gas (dy
27. What is true regard1ng co orr temperatures
Cecomposes. (c) it has a above 31 'C? (arlt can never be liquified. (b) I!
28. A1 10 atm, dry lce is -100) it issa plsnma.
heatod from-t
29 condensation (b) melting only (c) sublimatin enanges occur? (a) freezing, then
What is the normal melting polint of CO;? (a) -78 5C (o) -5A7then boiling
50.7 'C (c) 31 "C (O) It doesnt
30. 100cm of oxygen and havea normal
exploded, Deterrine th t neesured at room taemperature and pres5 ue
mensurements. (a) 125 cm 140c When brought back to the ora moced and
ditions ot
31. Which of these real ganes behavetn (a) none of these
ényoxine, an important homone that contros he ) coz (b) H, (c) NH> (¡) He
he nyrod gland. If0.455 g of thyroxine is dissobad ins o n the body, can be lsolated fom
depression Cons.
Pure benzene freezes at 5 444C and b r e , he frenzing point of the
g/mol C) 2330 g/mcl D) 285 .12 E1or the molal
33. When a
imol E 1280
addertr60 l l a alus of thyrokine? froezing-point
A) 777 000 atmol R 7n
non-volatle
solute is a
point --the freezing point . , andhee sovent, the solution vanorrrpress1ure1
decreases, Increases, decreases, decreass laeoss
h a semipermeable mom he boillng
nGredses, decreases, inGreases, decreases Dy decrea
roases, incteases, decreases, iicreas moraneA)
the following racton: CaHe (1) + 1ses, increases, decreases,
be A. +, . o l + ,+D +.+. 502 (9) increases
33. Predict which
(s) has a
3COz(g)+4HO(g). The signs of AH, S and aG
wil
() NHag)+ HC1(a) negative entropy change ()CHa(g) + 20:(a)
it C. l end ll D. I onty NH.C1is)) 2H:0() (1)
+
36 Given the 2KC10(s) - 2CI0:(s) O:tg)1 -COata)
AI and Il+2H;0(1)
folilcwing deta. B.l and
NH, Nz) +H, AH = 463
 ZH) + 0,
ZN2() + 6H.
38. Which of thet o t
2H,0H-484K] Coloulate tho a
4NH, A, 43AKI o reaion,
-1268 ndo,+1268KJ D. +438KJ
A.q= loWing is orrect expression of the lave
AH-WB.
40 Aspontaneous reaAH g+WC. AU
=9+WD
first
AU= AH PAV
themodyrnamics?
3negative and AS isnsoe (a) both aH and 4S are nogatvo (b) AH and aS are positive
41. Dinltrogen (c) aH
tetroxide (N:O) vede (dy aH is positlve and 4S ia negative
Jimol K, at what temnanposes lo rutrogen dioxide (NO:), If aH 58.02 kJmol and 4S 170.1
272.7°C (d+98.23°c are reactants and products are at equlibrium7 (a)
42
+56.5°C (b)+320.5°C (c)
n be recton
reaction at 100KSo2+%0:ESo,
AG (1000K
=519kJ, What is the equilprium constant Kp for the
43 (Re 6.3 14 Jmolk).
-1.87 (A)
sOlolysis of dilute copper b c h o d 5 3(D)1.87
44. Theelemes
TOyas of
dlute B:sodium
becomes acidic C. becomes akaine D. remelns unchano esuling
the cathode equedus chlanide using mercury alectrodes was carried out. The specles at
molecularoR Dde ot moiectar hydrogen Bformatbon of sodium Covolution of
45. 32 The reducion potentials of the electrodes of a
0.57 V. calculate he free energy cell, WwDXIX are, WiW= 0.83V and X*X =
2044kJ B-25.55k.J C-384TkJ D-50.18kJ change that attends the cell reaction at 2509c IF96500C) A.
4 The activation energy for the reaction,
tion energy of the reactionA+B-C+D
with AH =+ 159.6kJimol is 84k.Jimol. What woukd
C +D+A+ B? A
243.6 kJimol B4kJimol B. -84 kJimol C: 758kJmol D
47. Fora cartain reacton, the
overall rate law is gl
the reactlon, in mo/s, when [A] 0.0222M and SgNen nn R=0.0161
(B) =0.085 [A B]*, Calaulate the initial rata of
M. A. 1.1 x 10- B 4.0 x 10-C. 1.5 x 10
D. 1.8 x 10-$
48. The rate constant and the initial
conoentratcn of the
0 026 s and O01M respectively at 59C, at what timereactant
for the reaction, N:O. (g) - 2NO: (a) is
atratio
is the concontration of NO exnctly hat the initial
4w.ys26s G28 sD 266
49 For reaction:
one fourth the rate of disnppearanee f i aant is A the rate of diaappearance of x is
disappearance of X C: the rate of fomation of Z is hat the ppenrncerate of
of Yis half the rate of
consumpton of wD. the rato of
formation of Yand Z are equal
50 An element J of relatlve atomic
mass 55 was deposited by electrolysis. If 1 99 g o
tia elernent
was
elerment 17 A-2 8'e2r -3D +2 0amperes of current Bow for 90 minutes, whn Ir the charge on
SECTION B ESSAY
fat. State any two of Dalton's atomic theary.
State the main contributions of each of the foliowing to the atomic structure, J.J Thomsan,
Bohr Rahert Mkan,
b Gven the foldd Niels um numbers, ldentiy the correct and
n4, 3, m 2, ms +
Incarrec set with feassns
(). n= 2, (= 1, m 1, ms = +1 (), n= 5. (-4, mt2 n=
(v) n=3,(= 1, m=3, ms =
co) In a titrimetric analysis, a student reguir
solution to neutralze completely 24 n a soon containing 1.273 g Na,Co, in 250 e] o
HCI solution. Calculate the
concentration of the acid in Kgm
Na 23, C= 12, O = 16, H -1, Ci 35 5
(u). An olectron of mass 9.1 x 10-2g in ground state undergo
excitation to reach n 3, calculata ita wäve'ength
d.
ha6.525 x 102* {S. Ry =1.096776 x10 m!
electron atinlty (Hh innie rai arange in order inceasing (0 ionization enerqy (o negatye
2a(l). Solid iron conducts electrlclty while sold iron () chlortde does not. Fxniain
(i), Detemine the shapes and bond angles in each of the following based on valenco
sthell electron cai repulsion
theory. (CHj, NH;, H,0*. NH;)
 argen cectesing ofder of covalency () LIF, LICI, LIBr, I (0) UCI Nac
and in constryction wtile racby wel as graphite rod haa variguaalti ctrical conductors
40g of Potassium tetraoxomanganatavi readts w 35 g of eon stucture and bonding
o ne equation given armanium lron ) tetraoxosulphate ()
0 Balance the iooie teacticn re(S0) MnSo, (NH,),So, AN.0
detormine the amount in56,excess
16, N= 14, H=1, Fe S=32of excess regstert
m(V) calculateraction
the yleld(9in find the kiniting roactunt (v)
MSO, (K = 39, Mn = 55,O
3a.) Adirect currernt of 1.63Ais
passedt
seGonds at 75% curent etfickency. Caicutate the voluon of copar (unuiphata for 4hours 20 minutes 10
a23C and 800 dof mmHg (F 98500C. Molar volume 49gen ghven of in cm' at the anode if measured
diagram and
the elactrot tbalanced equaton of raacicns,
explan the princgle and prcesses invcved in
3b ) Explain the term nwith Znc
W) Asoluticon contains 1mol of lund Aon trom Racuit s law
5G, the vapor pressure of liqudA is 2 8 5 e
vapor pressutm of this solution is 314 terr at
4a ) Thehegative
d dborane
doviaion? Give the reasonf o r r
pressure of liquid Eis 365 torr. Does it
(BzH) ls used as a
shown below. rocketfuel The equation for the combustion ot ditorane is
Bkgt 30. B:Ox +34,O
Calcat the anthalpy ct combustan of
SHig BHsg AH 36 kJ mol diborane (B;He) in kJ moi-1, usng the foowing data
Haiai+o.
OtgH0e AH=-286 kJ mct
)
2B,-OB;O3 H= -1274 J mol
Consider the follcwlng chemical change Catag
Hag CHa Given the data bel ow
CH $2 219
Ha
C.H 47 229

Calcutate the standard free energy sG at

reaction 25°C for the reacton, and
The inital rate
comment on the
Ecataety nt tha
of
hypothetical reaction: 4Ha+
concentrations H, and NO. with the resuits NOca
of H;O(eNie was measure1 te
glven be ow. veral startino
Experimental No [H21 (NO Rate
18 x 10-3
2.1 x 10-2 S.4 x 10
3.6 x 10 2.1 x 10
10,8 10-5
6.3 10 49x 1o-4
Using tthese data deternine
the reacioe
(b) The m
(o) Calculate Hheate constn
oot mea scu
Irutrogen ga3 0c iN