01-12-2024

1103CJA101001240013 JA

PHYSICS

SECTION-I

1) A hollow sphere of radius R is filled completely with an ideal liquid of density ρ. Sphere is moving
horizontally with an acceleration 2g, where g is acceleration due to gravity in the space. If minimum

pressure of liquid is P , then pressure at the centre of sphere is :-

(A) P0 + ρgR
(B) P0 + 2ρgR
(C) P0 + ρgR

(D)

2) When at rest, a liquid stands at the same level in the tubes as shown in the figure. But as
indicated, a height difference h occurs when the system is given an acceleration a towards the right.

Then h is equal to

(A)

(B)

(C)

(D)

3) Figure shows a hydraulic press with the larger piston of diameter 35 cm at a height of 1.5 m
relative to the smaller piston of diameter 10 cm. The mass on the smaller piston is 20 kg. What is the
force exerted on the load by the larger piston? The density of oil in the press is 750 kg/m³. (Take g =
9.8m/s²)
(A)
(B)
(C) 500N
(D) 200N

4) Two cylinders of same cross-section and length L but made of two material of densities d1 and d2
are cemented together to form a cylinder of length 2L. The combination floats in a liquid of density d
with a length L/2 above the surface of the liquid. If d1 > d2 then :-

(A) d < d1

(B)
> d1

(C)
> d1

(D)
d1 > d

5) A container of height h fully filled with water of density ρ is falling with acceleration . A is top
most point while point B is bottom most point of tank then pressure difference between point A & B

is: (P is atmospheric pressure)

(A) ρgh
P0 +
(B)

(C) ρgh – P0

(D)

6) A vessel contains oil of density 0.8 gm/cc over mercury of density 13.6 gm/cc. A sphere floats with
half of it’s volume immersed in mercury and the other half in the oil. The density of material of
sphere. (in gm/cc)
(A) 14.4
(B) 7.2
(C) 3.6
(D) 12.2

7) Identify the correct choice.

(i) When a body floats in a liquid, it displaces the liquid whose weight is equal to its own weight.
(ii) When a body sinks in a liquid, it displaces the liquid whose volume is equal to its own volume.

(A) (i) is true but (ii) is false.

(B) (i) is false but (ii) is true.
(C) Both (i) and (ii) are true.
(D) Both (i) and (ii) are false.

8) A tube of length L is filled completely with incompressible liquid of mass M and closed at both the
ends. The tube is then rotated in a horizontal plane about one of its ends with a uniform angular
velocity w. The force exerted by the liquid on the tube at other end is :-

(A)

(B) Mω2L

(C)

(D)

9) The three vessels shown in fig. have same base area. Equal volumes of a liquid are poured in the

three vessels. The force on the base will be

(A) maximum in vessel A

(B) maximum in vessel B
(C) maximum in vssel C
(D) equal in all the vessels.

10) Three liquids of relative density d, 2d and 3d are mixed in equal proportions of weights. The
relative density of the mixture is :-

(A)

(B)

(C)
(D)

11) A cylindrical vessel containing a liquid is rotated about its axis so that the liquid rises at its sides
as shown in the figure. The radius of vessel is 5 cm and the angular speed of rotation is rad s–1.
The difference in the height, h(in cm) of liquid at the centre of vessel and at the side will be:

(A)

(B)

(C)

(D)

12) There is a circular tube in a vertical plane. Two liquids which do not mix and of densities d1 and
d2 are filled in the tube. Each liquid subtends 90° angle at centre. Radius joining their interface

makes an angle with vertical. Ratio is :

(A)

(B)

(C)

(D)
13) A u tube is rotated about one of the limbs with an angular velocity Find the difference in
height H of the liquid level. Density of the liquid is Diameter of the tube d < < L.

(A)

(B)

(C)

(D)

14) A barometer kept in an elevator acceleration upward reads 76 cm. The air pressure in the
elevator is

(A) 76 cm
(B) < 76 cm
(C) > 76 cm
(D) zero

3
15) A uniformly tapering vessel kept in vacuum is filled with a liquid of density 900 kg/m . The force

that acts on the base of the vessel due to the liquid is(g = 10 ms–2)

(A) 3.6 N
(B) 7.2 N
(C) 9.0 N
(D) 14.4 N

16) The side of glass aquarium is 1 m high and 2 m long. When the aquarium is filled to the top with
water, what is the total force against the side–

(A) 980 × 103 N

(B) 9.8 × 103 N
(C) 0.98 × 103 N
(D) 0.098 × 103 N

17) A uniform cylinder of length L and mass M having cross- sectional area A is suspended, with its
length vertical, form a fixed point by a massless spring, such that it is half submerged in a liquid of
density σ at equilibrium position. The extension x0 of the spring when it is in equilibrium is :

(A)

(B)

(C)

(D)

18) A liquid of mass 4 kg is filled in a flask as shown in figure. The force exerted by the flask on the

liquid is (g = 10 m/s2) [Neglect atmospheric pressure]:

(A) less than 40N

(B) greater than 40N
(C) 40 N
(D) zero

19) A cube of side 20cm is floating on a liquid with 5cm of the cube outside the liquid. If the density
of liquid is 0.8 gm/cc then the mass of the cube is

(A) 4.2 kg
(B) 4.8 kg
(C) 5kg
(D) 5.2 kg

20) A cubical container is completely filled with a liquid of density and closed from the top. The
force acting on it's side wall ABCD is:
(A)
(B)
(C)
(D)

SECTION-II

1) We immerse a cylindrical, 1 m long glass pipe into water upto its half height, then we close the
upper end by our finger. After this we slowly take the pipe out and turn it upside down (so the end
closed by a finger gets to the bottom, and the water on top). Find the length of the air column (in

mm) stuck under the water if the pressure outside is 105 kPa. Fill in OMR sheet

2) A solid floats with 1/3 of its volume immersed in liquid-A and with 3/5 of its volume immersed in
liquid-B. A homogenous mixture is created by mixing equal volumes of both liquid-A and B, then

fraction of solid immersed in mixture is a/b, fill the value of in OMR.

3) A cubical block is floating in a liquid with half of its volume immersed in the liquid. When the
whole system accelerates upwards with a net acceleration of g/3. The fraction of volume immersed

in the liquid will be Then the value of x is ___.

4) A uniform solid sphere of specific gravity 8 has a concentric spherical cavity and just sinks in

water. If the ratio of radius of cavity to that of outer radius of the sphere is then what will be the
value of x.

5) An ornament weighing 50 gram in air weighs only 46 gram in water. Assuming that some copper
is mixed with gold to prepare the ornament. Find the amount of copper (in grams) in it. Specific
gravity of gold is 20 and that of copper is 10.

CHEMISTRY

SECTION-I
1) Which of the following salt will give a green colour in fire works?

(A) Ca
(B) Ba
(C) Mg
(D) Sr

2) Ion having highest hydration enthalpy among the given alkaline earth metal ions is:

(A) Be2+
(B) Ba2+
(C) Sr2+
(D) Ca2+

3) When gypsum is heated to 393 K, it forms :

(A) Dead burnt plaster

(B) Anhydrous CaSO4
(C) CaSO4.5H2O
(D) CaSO4.0.5H2O

4) Molecules in which bond angle is changed due to back bonding w.r.t B/O/N.

(A) H3BO3
(B) B(OMe)3
(C) BF3
(D) N(SiH3)3

5) Given below are two statements :

Statement I : Boron is extremely hard indicating its high lattice energy
Statement II : Boron has highest melting and boiling point compared to its other group members.
In the light of the above statements, choose the most appropriate answer from the options given
below

(A) Statement I is incorrect but Statement II is correct

(B) Both Statement I and Statement II is correct
(C) Statement I is correct but Statement II is incorrect
(D) Both Statement I and Statement II is incorrect

6) Which of the following statement is false :

(A) Dry ice is solid CO2

(B) CO2 is weakly acidic
(C) CO2 and SiO2 are linear molecules
(D) CO2 is a gas while SiO2 is solid
7) Match the column :
Column I Column II

(A) B2H6 (P) (3c-4e⊝) bond

(B) Be2H4 (Q) (3c-2e⊝) bond

(C) Be2Cl4 (R) Central atom is sp3 hybridised

(D) Al2(CH3)6 (S) central atom is sp2 hybridised.

(A) A → P, R; B → Q, S; C → P, S; D → Q,R
(B) A → Q, R; B → P, S; C → P, Q; D → P,R
(C) A → Q, R; B → Q, S; C → P, S; D → Q,R
(D) A → S, R; B → R, S; C → P, S; D → P,R

8) Assertion : Between SiCl4 and CCl4, only SiCl4 reacts with water
Because :
Reason : SiCl4 is ionic and CCl4 is covalent

(A) If both assertion and reason are correct and reason is the correct explanation of the assertion
If both assertion and reason are correct, but reason is not the correct explanation of the
(B)
assertion
(C) If assertion is correct, but reason is incorrect
(D) If assertion is incorrect, but reason is correct.

9) Which of the following order is correct ?

(A) SiCl4 > SiF4 > SiBr4 > SiI4 (Lewis acid strength)
(B) H3BO3 > Na[B(OH)4] (B – O bond strength)
(C) CHCl3 < CHF3 (Acidic nature)
(D) BeF2 > BeCl2 > BeBr2 > BeI2 (Lewis acid nature)

10) The structure of diborane contains

(A) Four 2c-2e bonds and four 3c-2e bonds

(B) Two 2c-2e bonds and two 3c-2e bonds
(C) Two 2c-2e bonds and four 3c-2e bonds
(D) Four 2c-2e bonds and two 3c-2e bonds

11) Which one of the following is CORRECT order of stability ?

(A) B3⊕ < Al3⊕ < Ga3⊕ < In3⊕ < Tl3⊕
(B) Tl3⊕ < In3⊕ < Ga3⊕ < B3⊕ < Al3⊕
(C) Tl3⊕ < In3⊕ < Ga3⊕ < Al3⊕ < B3⊕
(D) B3⊕ < Al3⊕ < In3⊕ < Ga3⊕ < Tl3⊕

12) Select the CORRECT statement ?

 Ga is not really divalent, as the structure of GaCl2 has been shown to be Ga+[GaCl4]– which
(A)
contains Ga(I) and Ga(III)
Ga has incredibly low melting point because structure tends towards discrete diatomic
(B)
molecules rather than a metallic structure
Boron has an unusual crystal structure (B12 icosahedral) which results in the melting point
(C)
being very high.
(D) All are correct

13) Which of the following compound is used for estimation of CO ?

(A) I2O4
(B) I4O9
(C) I2O7
(D) I2O5

14)

B2H6 + 'X'

'Y'

Which of the following statement is correct for 'X' and 'Y' :-

(A) 'X' is ionic compound which on cooling it forms 'Y'
(B) 'X' ⇒ (BN)X , 'Y' ⇒ B3N3H6
(C) 'X' is white slippery solid and it has same structure as graphite
(D) 'Y' is nonpolar and it forms π complex with transition metal compounds

15)
X and Y respectively are :

(A) X = Metaboric acid; Y = Tetraboric acid

(B) X = Borax; Y = Metaboric acid
(C) X = Tetraboric acid; Y = Metaboric acid
(D) X = Tetraboric acid; Y = Borax

16) Me2SiCl2 (A) (B). The nature of product (B) may be

(A) only linear polymers

(B) only cyclic products
(C) (A) and (B) both
(D) none of these

17) An inorganic compound (A) made of two most occuring elements into the earth crust, having a
polymeric tetrahedral network structure. With carbon, compound (A) produces a poisonous gas (B)
which is the most stable diatomic molecule. Compounds (A) and (B) will be
(A) SiO2’ CO2
(B) SiO2’ CO
(C) SiC,CO
(D) SiO2’ N2

18) B(OH)3 + NaOH NaBO2 + Na[B(OH)4] + H2O.

How can this reaction is made to proceed in forward direction ?

(A) Addition of Cis 1, 2 diol

(B) Addition of NaBO2
(C) Addition of trans 1, 2 diol
(D) Addition of Na2HPO4

19) The catenation tendency of C, Si and Ge is in the order Ge < Si < C. The bond energies (in kJ
mol–1) of C — C, Si —Si and Ge—Ge bonds are respectively :

(A) 348, 260, 297

(B) 348, 297, 260
(C) 297, 348, 260
(D) 260, 297, 348

20) The correct statements among I to III regarding group 13 element oxides are,
(I) Boron trioxide is acidic (II) Oxides of aluminium and gallium are amphoteric
(III) Oxides of indium and thalliumare basic

(A) (I), (II) and (III)

(B) (II) and (III) only
(C) (I) and (III) only
(D) (I) and (II) only

SECTION-II

1)

Stable oxidation state of ‘Pb’ is +x, ‘Bi’ is + y and ‘Tl’ is +z, then value of ‘x + y + z’ is ?

2) Find the number of s-block elements which can produce ammoniated cation and ammoniated
electron with liquid ammonia.
Li, Na, K, Rb, Cs, Ca, Sr, Ba

3) Number of oxygen atoms shared per tetrahedron unit in Al2Si2O7 is X then find X.

4)

Find the maximum number of atoms that lie in the one plane in Be2H3CH3.
5) Number of B – O – B bonds in borax is x then value of is?

MATHEMATICS

SECTION-I

1) If is an imaginary cube root of unity, then equals:-

(A)
(B)
(C)
(D)

2) If a complex number z satisfies the equation , then is equal to:

(A)
(B)
(C) 1
(D) 2

3) If is a non real cube root of unity, then the expression is equal

to:-

(A) 0
(B) 3
(C) 1
(D) 2

4) If then

(A)
(B)
(C)
(D)

5) A value of for which is purely imaginary, is:

(A)

(B)
(C)

(D)

6) If is a purely imaginary number and , then value of is:

(A) 1
(B) 2
(C)

(D)

7) If , then is equal to:

(A) 244
(B) 224
(C) 245
(D) 265

8) Let and . Then =

(A)

(B) 3
(C)

(D)

9) If z is a complex number of unit modulus and argument , then equals

(A) Z
(B) - Z
(C)
(D)

10) Let , where x and y are real numbers, then eqia;s:

(A) -85
(B) 85
(C) -91
(D) 91

11) A complex number z=3+4i is rotated about another fixed complex number z1=1+2i in
anticlockwise direction by 45° angle then the complex number represented by new position of z in
argand plane is_______

(A)

(B)

(C)

(D) None of these

12) The equation represents:

(A) the line through the origin with slope .

(B) a circle of radius 1.

(C)
a circle of radius .
(D) the line through the origin with slope 1.

13) If then is equal to -

(A) -1
(B) 0
(C) 1
(D) None of these

14) If z be the complex number such that then minimum value of is

(A) 0
(B) 3
(C) 1
(D) 11

15) If the center and radius of the circle are respectively and , then
is equal to:

(A) 11
(B) 9
(C) 10
(D) 12

16) The area of the triangle with vertices A(z), B(iz) and C(z + iz) is:
(A) 1

(B)

(C)

(D)

17) The inequality represents region given by-

(A)
(B)
(C)
(D) None of these

18) If , represents a circle, find its centre

(A) (0, 0)
(B) (0, 1)
(C) (1, 0)
(D) (1, 1)

19) If and Z2 be two complex numbers such that is a purely imaginary number, then

is

(A) 1
(B) 5
(C) 3
(D) 2

20) If are the distinct roots, of the equation x2 - x + 1 = 0, then is equal to:

(A) -1
(B) 0
(C) 1
(D) 2

SECTION-II

1) Let be any complex number such that is a purely imaginary number. Then
2) Let c be the set of all complex numbers. Let

and then the number

of elements in is equal to___________

3) The equation represents a part of a circle having radius equal

to , then =

4) If then is equal to___________

5) Let a complex number satisfy . Then, the largest value of is

equal to
 ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. C D A D D B C A C B A C A C B B C C B B

SECTION-II

Q. 21 22 23 24 25
A. 9.00 5.00 6.00 7.00 30

CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. B A D D B C C C B D C D D D A C B A B A

SECTION-II

Q. 46 47 48 49 50
A. 6.00 8.00 1.00 7.00 1.00

MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. D A B A D B A C A D D D C C D B C C A C

SECTION-II

Q. 71 72 73 74 75
A. 3 1 3 2 7
 SOLUTIONS

PHYSICS

2)

3) Pressure on the smaller piston =

Pressure on the larger piston =

The difference between the two pressures =
where h = 1.5m and

Thus,

4)
m1g + m2g = FB

d1ALg + d2ALg =

(d1 + d2) ALg =

∴ d1 > d2 So
ie

5)

geff = g – =
So PA + ρ(geff)h = PB

PB – PA = ρ(geff)h =

6)

ρvg = 0.8 g + 13.6

ρ = 0.4 + 6.8
ρ = 7.2 gm/cc

7) Theoretical

8)

[F = ]

9) F = P × Area
F = ρgh × Area [height is greatest for C]

10)

11) Applying pressure equation from A to B

12) h1 = R – R sin
P1 = P3 = P0
h2 = R – R cos
h3 = R + R sin
P2 = P1 + d1g(h1 – h2) ...(1)
P2 = P3 + d2g(h3 – h2) ... (2)
d1(h1 – h2) = d2(h3 – h2)

13)

or

Pressure

or

14)

In rest state it will have height > 76 cm.

15) Force = P × A
=
900 × 10 × (0.4) × 2 × 10–3 = 7.2

16)

=103 × 9.8 × × (2 × 1)
= 9.8 × 103 N

17) At equilibrium
Kx0 = Mg – B

0
Kx = Mg –

0
X =

18) Force by flask on liquid is equal to mg of liquid.

19) Mg = ρVsg
M = ρVs
= 0.8 [20 × 20 × 15]
= 4800 gm
= 4.8 kg

20)

21)

0 0
P = [P + ρg(1 – x)]Ax
 0
⇒ ρgx2 – x(P + ρg) + =0

x(m) =

x(mm) =

Ans.

22)

ρ → density of solid
ρA = 3r

ρB =

ρmixture = ⇒ ⇒
Fraction of solid submerged in mixture

=
Answer a = 3, b = 7

23)
 24) (8 × ρW) =
8R3 – 8r3 = R3
7R3 = 8r3

25) Let m be the mass of the copper in ornaments. Then mass of gold in it is (50 – m).

Volume of copper

and volume of gold

when immersed in water

Decreases in weight = upthrust

or
or
m = 30g

CHEMISTRY

26) Ba imparts green colour in the Bunsen flame.

27) Hydration enthalpy

Down the group as size increases hydration enthalpy decreases
Order : Be2+ > Mg+2 > Ca+2 > Sr+2 > Ba+2

28)

29) In N(SiH3)3 molecule, bond angle changing due to back bonding because ‘N’ (central atom)
it donating its lone pair into vacant d-orbitals of ‘Si’.

30) Boron is non- metallic in nature. It is extremely hard and black coloured solid. It exists in
many allotropic forms. Due to very strong crystalline lattice, boron has unusually high melting
point and boiling point.

31) CO2 is linear but in SiO2 Si is Sp3 hybridised and not a linear molecule.

32) (A) B2H6 (Q) 3c-2e⊝ bond present

(R) central atom is sp3 hybridised.
(B) Be2H4 (Q) 3c-2e⊝ bond present
2
(S) central atom is sp hybridised.
(C) Be2Cl4 (P) 3c-4e⊝ bond present
(S) central atom is sp2 hybridised.
(D) Al2(CH3)6 (P) 3c-4e⊝ bond present
(R) central atom is sp3 hybridised.

33) SiCl4 undergoes hydrolysis because of vacant d-orbitals, CCl4 does not contain any vacant
orbital.

34)

As shown above, partial double bond is present between 'B' and 'O' in H3BO3. so H3BO3 has
more dB-O bond strength than. Na[B(OH)4].
So option (B) is correct.

35)
No. of (2C–2e⊖) bonds = 4
No. of (3C–2e⊖) bonds = 2

36)

Stability of higher oxidation decreases down the group due to inert pair effect.
Therefore correct order is :
Tl3⊕ < In3⊕ < Ga3⊕ < Al3⊕ < B3⊕.

37) (A) Ga is not really divalent, as the structure of GaCl2 has been shown to be Ga+[GaCl4]–
which contains Ga(I) and Ga(III) (B) Ga has incredibly low meltig point because structure
tends towards discrete diatomic molecules rather than a metallic structure.

38)

Quantitative estimation of CO is done by I2O5

CO + I2O5 → CO2 + I2
I2 + Na2S2O3 → NaI + Na2S4O6

39)
B2H6 reacts with NH3 in 1:2 mole ratio to give B3N3H6 (borazine) which has polar bonds due to
the electronegativity difference between B and N. Borazine is also called as inorganic benzene
which can form π complex with transition metal compounds.

40)

42)

The correct option is B

SiO2, CO
SiO2 + 2C → Si + 2CO.

43) Cis di-Ol react with Na[B(OH)4] and form complex so reaction move in forward direction.

44) Down the group bond energy decreases.

45) B2O3 is only acidic, Al2O3 and Ga2O3 are amphoteric and In2O3, Tl2O3, Tl2O are found to be
basic.

46)

Stable oxidation sate of Pb is +2, ‘Bi’ is + 3 and ‘Tl’ is +1 due to inert pair effect.
Therefore x = 2, y = 3, z = 1 ⇒2+3+1=6

47) Alkali and Alkaline earth metal when they dissolve in ammonia solution gives blue color
due to ammoniated electron or solvated electron.
 48) is

50)

MATHEMATICS

51)

52)

Comparing real and imaginary parts,

53)

=3

54)

55) is purely imaginary

56) is purely imaginary

57)

58)

, where

Then

59)
60)

62)
is the perp bisector of line joining 1 and i
Line passing through origin with slope 1

63)

are 5th root of unity

= Product of are 5th root of unity

= product of roots of

=
=1

65)
Centre =

radius =

66)

Let

Area of with is