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Btech Ase, Ape-Up, Ee, Ece, Rsee - Chemistry I

This document outlines the structure and content of the End Semester Examination for Chemistry I at the University of Petroleum and Energy Studies for May 2022. It includes instructions, sections with various questions covering topics such as calorimetry, fuel comparison, corrosion control, and water analysis. The exam consists of multiple sections with a total of 100 marks, requiring students to demonstrate their understanding of chemical principles and calculations.

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dabus4857
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26 views3 pages

Btech Ase, Ape-Up, Ee, Ece, Rsee - Chemistry I

This document outlines the structure and content of the End Semester Examination for Chemistry I at the University of Petroleum and Energy Studies for May 2022. It includes instructions, sections with various questions covering topics such as calorimetry, fuel comparison, corrosion control, and water analysis. The exam consists of multiple sections with a total of 100 marks, requiring students to demonstrate their understanding of chemical principles and calculations.

Uploaded by

dabus4857
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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Name:

Enrolment No:

UNIVERSITY OF PETROLEUM AND ENERGY STUDIES


End Semester Examination, May 2022
Course: Chemistry I Semester: II
Program: B. Tech. AE, APE-Up, EE, ECE, RSEE Time : 03 hrs.
Course Code: CHEM 1011 Max. Marks: 100

Instructions:
1. All questions are compulsory.
2. Write all parts of a question at one place.

SECTION A
(5Qx4M=20Marks)
S. No. Marks CO
Q1 Discuss the various types of correction made in bomb calorimeter. 4 CO1
Q2 When one mole of liquid benzene is completely burnt in O 2 at constant
pressure to form liquid water and CO 2 gas, ∆H is -781 Kcal at 25oC.
4 CO2
Calculate the heat of this reaction at constant volume at the same
temperature. (R = 2 Cal/K/mol).
Q3 Compare gaseous fuel with liquid fuel in terms of Calorific Value,
4 CO1
storage, risk of fire hazards and smoke.
Q4 0.257 g of an organic substance was Kjeldahlized by heating with conc.
sulphuric acid and then distilled with excess of strong alkali. The
ammonia gas evolved was absorbed in 50 ml of N/10 HCl, which 4 CO1
required 23.2 ml of N/10 NaOH for neutralization. Determine the % of
nitrogen in the substance.
Q5 Briefly discuss microemulsion method used for the synthesis of
4 CO5
nanoparticles.
SECTION B
(4Qx10M= 40 Marks)
Q6 10 CO4
How can corrosion be controlled by
(i) Modification of environment
(ii) Relative areas of anode and cathode
(iii) Sacrificial protection
(iv) Protective coatings
Explain each with suitable examples.
Q7 (i) In a polymer sample, 20 % of the molecules have a molecular mass 5
20000; 40 % have 30000 and the rest have 40000. Calculate PDI.
CO5
(ii) X-rays of wavelength 36 nm is diffracted at an angle of 40 o.
Calculate the inter-planar spacing assuming third order diffraction. 5
Q8 For thermal decomposition of N2O, the proposed mechanism is:

10 CO2

Derive the rate law in terms of N2O.


Q9 A sample of water contains following impurities: Mg(HCO 3)2 = 73
mg/lt, CaCl2 = 222 mg/lt, MgSO4 = 120 mg/lt, CaSO4 = 164 mg/lt.
Calculate the quantity of lime (74% pure) and soda (90% pure) needed
for softening 5000 litre of water.
10 CO3
OR
With the help of suitable diagram and reactions, discuss zeolite process
used for the softening of hard water. List out its advantages and
disadvantages.

SECTION-C
(2Qx20M=40 Marks)
Q 10 10 CO4
(i) The standard reduction potential of Cu2+/Cu and Ag+/ Ag
electrodes are +0.337 V and +0.799 V respectively. Construct a
galvanic cell using these electrodes so that its E ocell is positive. For
what [Ag+] will the EMF of cell be zero if [Cu2+] is 0.01M.
OR
a. For Barium hydroxide, calculate ˄0 (molar conductivity) at
250C from the following. ˄0 NaOH =248.61 Sm2mol-1 ; ˄0NaCl
= 126.45 Sm2mol-1 ; ˄0BaCl2 = 279.96 Sm2mol-1 10
b. Differentiate between specific conductance and molar
conductance. How they are interrelated?

(ii) In a particular cell, 0.01M solution of KCl gave a resistance of


15Ω while 0.01M solution of HCl gave a resistance of 51.4Ω at
the same temperature. If the specific conductance of 0.01M KCl is
0.1409Sm-1, calculate cell constant, specific conductance and
equivalent conductance of HCl solution.
OR
a. What is salt bridge? What is its function in a galvanic cell?
Justify your answer.
b. What is electrochemical series? Discuss briefly five
applications of electrochemical series with suitable
examples.
Q 11 (i) A sample of water on analysis was found to contain the following
impurities:

10
Impurity MgCO3 Ca(HCO3)2 CaCl2 MgCl2
Quantity (mg/L) 7 5 9 6
Mol. Wt. 84 162 111 95
Calculate the temporary, permanent and total hardness of water in ppm. CO3

(ii) 500 mL of water sample, on titration with N/50 HCl gave a titre
value of 29 mL to phenolphthalein end point and another 500 mL 10
of the sample on titration with same acid gave a titre value of 58
mL to methyl orange end point. Calculate the alkalinity present in
the sample and comment on the type of alkalinity present.

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