XII revision V
XII revision V
Sn/HCl
A
6[H]
CH3-NO2
Zn/NH4Cl
B
4[H]
PART-III
25. what are the factors responsible for the anomalous behaviour of first element of the p-block ?
26. What is lanthanoid contraction explain its consequences
27. write a short note on postulates of werner's theory?
28. Derive the Relation between PH and POH
29. State faraday’s law of electrolysis ?
30 Write any three characters of catalysts ?
31.Differentiate primary secondary and tertiary alcohols using Lucas test
32. Write a short note on peptide bond ?
33. Write the mechanism of aldol condensation reaction ?
PART-IV
Answer the following all questions. 5 X 5 = 25
34.a) i) Describe mond process for refining nickel.(3)
ii) How will you identify borate radical ? (2)
(OR)
b) i) Write the balanced equation for the overall reaction of chlorine with cold. NaOH and hot NaOH (2)
ii) What are interstitial compounds? Give example (3)
35.a) [Ni(CN)4]2- is diamagnetic , while [NiCl4]2- is paramagnetic explain (5)
(OR)
b) i) Classify molecular crystal with an example for each type.(3)
ii)Explain hume -rothery rule for formation of alloys ? (2)
36.a) i) Derive an expression for ostwald dilution law(3)
ii) Ionic conductance at infinite dilution of Al3+ and SO42- 189 and 160 mho cm2 equiv-1 calculate the equivalent
and molar conductance of the electrolyte Al2(SO4)3 at infinite dilution. (2)
(OR)
b) i) Derive integrated rate law for a first order reaction A →product (3)
ii)Define Electroosmosis.(2)
37.a) i) How are the following conversion effected?
1) ethylene glycol → 1,4 dioxane(1 ½)
2) glycerol → acrolein(1 ½)
ii) How does ammonia react with formaldehyde ? Draw the structure of product. (2)
(OR)
b) I) write short note on Gabriel phthalimide synthesis (3)
ii) Write a test to identify primary amines.(2)
38. a) i) What is isoelectric point?(2)
ii) Draw the structures of Lactose and Maltose.(3)
(OR)
b) How the following polymers are prepared ?
i) Teflon ii) Nylon-6 iii) PHBV