FIITJEE

ALL INDIA TEST SERIES

JEE (Main)-2025
TEST DATE: 12-01-2025

ANSWERS, HINTS & SOLUTIONS

SECTION – A

1. A
Sol. To detach
4 
 w  R3 g   T2r sin 
3 
R
4  r 
So,  w  R3 g   T2r r
3  R
2w g
So, r  R2
3T

2. B
Sol. When switch is closed q +q
q 3CV  q C

C 2C
So, q = CV
C2 V 2 (4CV)2
Initial energy, Ui  
2C 2(2C)
C2 V 2 (2CV)2
Final energy, Uf   2C
2C 2(2C)
(3CV q) (3CV q)
So, energy lost = Ui  Uf  3CV 2

3. A
hC
Sol. k1  


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AITS-OT-PCM(Sol.)-JEE(Main)/2025 2

2hC
3k1  

hC

1
So,  
3 2hC


hC
So,  
2

4. A
Sol. From Phasor diagram A1
Because intensity I is proportional to square of amplitude
So, I  (A12  A 22 )
A2
A12  A 22

5. A
Sol. When both S1 and S2 are open,
1.5 1
Current in the ammeter i   A
300  100  50 300
When both S1 and S2 are closed,
1.5  R  1.5R
i  
 100R   R  100  400R  30000
300   
 100  R 
So, according to the question,
1 1.5R

300 400R  30000
 R = 600 
6. C
K(4)2 K(4  q)(4  q)
Sol. 2

r (2) r2
So, 8  16  q2
 q = 2 2 C
7. B
Sol. From Brewster’s law
 = tan 60 = 3
8. B
dy 2a
Sol.   tan  (slope of the wire)
dx y
For no slipping tan  S
2a
So,  S
y0
2a
So, y 0 
S

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 3 AITS-OT-PCM(Sol.)-JEE(Main)/2025

9. B

Sol. Impulse momentum theorem along y-direction y
B
 quB cos dt  mu quB


 q B xucos dt  mu
0

xm
 qB0
 xdx  mu
0
q, m u x

2
xm
 qB0  mu
2
2mu
 xm 
qB0

10. A
t
dQ 12  
Sol. id   e
dt 100
12000 120
So, id after a time constant =  mA
100e e

11. D
Sol. 0.9A 0  A 0 e c(5)
and A 0  A 0 e c(15)
So,   (0.9)3  0.729

12. B
Sol. In the given circuit Req = 1M
and Ceq  4 F
 t 

 ReqCeq 
So, V  (10) 1  e
 
 
 t 


So, 4  10 1  e 4 
 
 
t

4
3
So, e 
5
5
So, t = 4n  
3

13. C
Sol. For a convex lens forming a real image
1 1 1
 
v u f
So, if u = v, then
u = v = 2f

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AITS-OT-PCM(Sol.)-JEE(Main)/2025 4

14. B
Sol. In forced oscillation
If F = F0cos (t)
F0
Then x = A sin (t  ), where A =
m(20  2 )

15. B
Sol. Suppose length AP = x
1m  m 2 mx 3
So,  x  x 2  
3   3 3

So, x  1/3
2

16. A
Sol. Heat required to melt the whole of ice is
Q1 = mST + mL
= 400  0.5  20 + 400  80 = 36000 cal
The maximum heat released by steam when the whole steam is converted into water at 0C
Q2 = mST + mL
= 50  1  100 + 540  50 = 32000 cal
Because Q2 < Q1, so the whole ice will not melt. Hence the final temperature of the mixture is
0C.

17. C
Sol. Thermal stress is given by Y  
So, for stress to be same
Y11  Y2  2
Y1  2 3
So,  
Y2 1 2

18. B
p2 p2
Sol. Q 
2  4 2  (220  4)
1 1   440 
5.5  p2     p2  
 8 432   8  432 
p2 (5.5)(8  432)
So,   5.4 MeV
24 2  4  440

19. C
Sol. From lens C, image is formed at 1 m along the direction of incident ray. So for the position of final
image from the final system is
1 1 1
 
v 1 1
1
 v m
2
1
So, magnification m 
2
1 1
So, separation between both the images =   2  0.5 cm
2 2

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 5 AITS-OT-PCM(Sol.)-JEE(Main)/2025

20. B
C
Sol. X
T
X1 273  173 100
Or  
X2 273  73 200
So, X2 = 2  0.0060 = 0.0120

SECTION – B

21. 770
Sol. For second pendulum
 (1  T)
2  2  2
g ga
ga a
So, 1  T   1
g g
So, a  gT  (10)(20  104 )(50)  1 m/s2
So, N  m(g  a)  770 N

22. 3
Sol. At the limiting situation
fS  mgsin   m2r
mgsin   m2r  Smgcos  fs

2r
So, S  tan  
gcos  30 2
mg sin + m r
 1 
(10)2  
1  10   3
So, S  
3  3
10 
 2 
 

23. 7
Sol. At the verge of toppling, normal applied by table will pass through point A
C. So, torque about point C,
d mg
mg(2dcos  0  d)  2mg(d  dcos 0 )  mg
2
2mg
1 0
2cos  0  1  2  2cos 0 
2 B C
7 mg
4cos 0 
2
7
So, cos 0 
8

24. 125
dL dm
Sol.  R(v1  v 2 )
dt dt
 (100)(0.5)(5  2.5)  125 J

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AITS-OT-PCM(Sol.)-JEE(Main)/2025 6

25. 2
VC
Sol. XC   1000 
I
Current lags behind voltage, so box has an inductor
R 800
Power factor = 0.8 = 
Z (800)  (X  1000)2
2
L
So, XL  1600 
1600
So, L   2 Henry
400
2 


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 7 AITS-OT-PCM(Sol.)-JEE(Main)/2025

Chemistry PART – B

SECTION – A

26. C
Sol. K 2Cr2 O7  cold. 4H2SO 4  2CrO3  2KHSO 4  2H2O

2K 2Cr2 O7  warm 8H2 SO4   2K 2 SO4  2Cr2 SO 4 3  8H2O  3O2

27. C
Sol. 2F2  2H2O  4HF  aq   O2  g 
3F2  3H2O  6HF  aq  O3  g

28. B
Sol. Ni2  in Ni  Br2 PPh3  2  
 NiBr2 PPh3 2 
Square planar Tetrahedral
Red colour Green coloured
Diamagnetic Paramagnetic
4
Tetrahedral splitting of Ni+2 in NiBr2  PPh3 2 will have configuration e 4 t 2 , thus unpaired electrons.

29. D
Sol. In (I) annulene systems, only peripheral bonds are counted but in (II) fused ring system only
connected benzoic bonds are counted.

30. C
Sol. O O H
H 1, 2 diketones in enol form strong
or O H-bonding with stable ring.

O
H
H

31. C
Sol.

V0 V0
Mono Di

Initial

3
V1 V0
4
Mono
Di

Monoatomic : P1.V05/3  P2 .V15/3

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AITS-OT-PCM(Sol.)-JEE(Main)/2025 8

7/5
3 
Diatomic : P1.V07/5  P2 .  V0 
4 

21
V  3  25
 1  
V0  4 

32. B
Sol. I2  I  I3
1 0.5 
Volume  1L 1  0.25 0.5  0.25 0.25
0.25 4
Kc  
0.75  0.25 3
1 1 1 4
 K c for I2  I  I3 is  1.15
2 2 2 3

33. C
Sol.
O
HO
O

K1
 
K2
 
 HO  
R OMe R OMe

O
O
K3
 MeOH 
  MeO
R O
R OH
3 step mechanism where K1  K 2 but K 3 is largely formed.

34. B
1 1 1
Sol.  RH .Z 2  2  2 
  2 5 

1  25  4 
9
 RH .Z 2  
108.5  10  25  4 

1 1 25  4
Z2  . 10

RH 1085  10 21
916  25  4

1085  21
Z2
B. E.  13.6 
n2
13.6  916  25  4
B.E. 
1085  21
B.E. = 54.4 eV

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 9 AITS-OT-PCM(Sol.)-JEE(Main)/2025

35. B
Sol. A  g K1
 2B  g A g K2
 C g
t0 1 atm 0 t0 1 atm 0
t = 10 min 1  x  y  2x t = 10 min 1  x  y  y
t 1  a  b  2a t 1  a  b  b
0 0
From question, a + b = 1 and 2a + b = 1.5
 a  b  0.5
P 2K 1 2a 2x K x
Now, B     1  1
PC K2 b y K2 y
Now, P10 min  1  x  y   2x  y  1.4
 x  y  0.4  PA  1  x  y  0.2 atm at t =10 min
1 Po 1 1
Now, K 1  K 2  .ln A  .ln  0.16 min1
t PA 10 0.2
 K1  K 2  0.08 min1

36. C
Sol. Rate: Addition of nucleophilic on polar   bond > Nucleophilic substitution S1  S2
 NH3 (nucleophile) attacks 1st at S1
Cl O
Cl

O N NH N CH3
S2
O
S1
NH3
 

Cl

Product

37. A
Sol. O O

H2N OH
NH2
Glutamine

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AITS-OT-PCM(Sol.)-JEE(Main)/2025 10

38. C
Sol.
ABMO*

Cl

3 membered ring act as an internal nucleophile.

39. C
Sol. H2 C2O 4 is obtained in pure form and is not much effected by surrounding conditions and is
therefore suitable as a primary standard.

40. C
Sol. Glycerin and H2O are highly miscible and most water molecules turned to glycerin via H-bond,
therefore, vapour pressure of solution decreases. Hence, depression in freezing point is
observed.

41. C
Sol. CHO COOH
CHO
H OH H OH 3
Br2 , H2 O H2 O2 /Fe
   CO2
 H
 OH
H OH H OH
OH
OH OH
KCN, NH4 Cl

COOH CN

H OH H OH
Hydrolysis

H OH H OH

OH OH

or or
COOH CN
HO H HO H
H OH H OH

OH OH

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 11 AITS-OT-PCM(Sol.)-JEE(Main)/2025

42. B
2
0.06 H 
Sol. Ecell  E o
cell  .log  
n PH2
 2
0.06 H 
Or, 0.70   0.28  0   .log    pH  7.0
2 1

43. B
Sol. 
Ph Ph Ph
X: Y: CH2 Z: O
Ph Ph Ph

NH2
SN 2

Ph
NH
OH
Ph

44. B
Sol. Factual
45. D
Charge of cation
Sol. Covalent character 
Size of cation
Covalent character  size of anion.
SECTION – B
46. 3
Sol. 2x  8  0  0  2
2x = 6
x = +3
47. 6
Sol. x
XeFx  H2 
 Xe  xHF
2
a mole a x mole
56
a
22400
60  0.25
and ax  1  1 x  6
1000
48. 2
Sol. 2
OH  sp3 d2
HO OH
x 1
Sn
HO OH y 3
OH z2

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AITS-OT-PCM(Sol.)-JEE(Main)/2025 12

49. 9
Sol. Statement number 1, 3 and 5 are correct.
3
Statement 3: Fe  Fe  OH3 ; Cr 3  Cr  OH3
Re d  brown Green
Statement 5: 2CuSO4  K 4 Fe  CN6   Cu2 Fe  CN6   K 2 SO 4
Chocolate brown

50. 7
nd 2
Sol. At 2 equivalence point; only HA  is left.
H   K a2  K a3  1010

3  A3 
Now; K a1  K a2  K a3  H   
H3 A 
 A 3  103  10 8  1012
  107
H3 A  10 10 
3

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 13 AITS-OT-PCM(Sol.)-JEE(Main)/2025

Mathematics PART – C

SECTION – A
51. D
5
Sol. f(0). f   can be positive, negative or equal to zero.
4
52. D
 
Sol.   0, 
 2
53. C
Sol. A=I
54. B
Sol. Centroid, G  (2, 0)
1
Slope of GH =
3
55. A
Sol. Minimum distance between x  4 1  y 2 and x  2 2y  y 2 x is 4.
56. D
Sol. y2cos(x2y) (2xy + x 2y) + x2y  2xy = 0
 x2 
 cos(x2y) d(x2y) = d  
 y 
x2
 sin(x2y) =  c where c = 0
y
57. B
100
 yi 2  100  101 201
i 1
Sol. y  = 6767
100 100  6
58. A
Sol. (B, B)  R  B  P(A)  R is reflexive
R is not symmetric
(B, C), (C, D)  R  (B, D)  R  B, C, D  P(A)
So, R is transitive.
59. C
Sol. Domain is x  (1, 1). The corresponding graph in this interval is given



2  2x 
y  tan1  
 1  x2 

3
1 1 O 1 1 y=cos1(4x 3x)

2 2



2

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AITS-OT-PCM(Sol.)-JEE(Main)/2025 14

60. A
Sol. a3 = 453  a = 45, 45, 452
61. D
  e x 2 1  1 
  2  x 1
  x  1 
  
Sol. f(x) = sin   2x  1  x 1
  2
1 x 1

62. D
3  1 ˆ  3  ˆ
Sol. Displacement =  1   i  1  2  j 
2 2  2   
3  3 
  1
 2
time, t = 2

0.2
displacement
Use, velocity =
time
63. D
11! 10! 9!
 2
Sol. P= 2!2!2! 2!2! 2! = 37
9! 10 45
C2
2!2!

64. B
1 1 1
x2 sin x x2 x4
Sol. 1 6
dx  
x
dx   1  
6 120
dx
0 0 0
1
17 sin x 1703
  dx 
18 0 x 1800
65. D
      
Sol. AB  BC  CD  DE  EF  FA  6  GH

66. A
2 2
x x x x
2 2    
 x   xy   xy    xy   xy   y  y y y x
2
Sol. g(xy) + h       xy   
y 2 2 y
67. A
Sol. Let  = x + iy ; x, y  I+
 x2  y2 = 4  x = 2, y = 0
 slope = 0
68. D
  3 
 2cos  
e   2 
 
 = 2  e  1 cos  3  

1 1 e
Sol.  3n  2 !   3n  1!  e   3

3  e
 
 2  
n 1

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 15 AITS-OT-PCM(Sol.)-JEE(Main)/2025

69. A
7 27
Sol. = ,= 
2 2
70. C
Sol. The circles have 3 common tangents of lengths 2 2 , 2 2 and 0 respectively.

SECTION – B
71. 9036
5
Sol. C1(10C2 + 10C3 + ….. + 10C5) + 5C2(10C1 + ….. + 10
C4) + 5C3(10C0 + ….. + 10
C3) + 5C4(10C0 + 10
C1 +
10
C2) + 5C5(10C0 + 10C1) = 9036
72. 7
Sol. Let tanx = t  t2 + 4t(3  ) + 64 = 0
D < 0    (1, 9).
73. 7
1 1
Sol. I(x) = ln(xex + 1)  ln(xex) + ln(xex  1) + c
2 2
1  x 4 e4x  2x 2 e2x  1 
= ln  c
4  x 4 e4x 
=  = 4,  = 2,  = 1
74. 8
Sol. Set S bounds the shaded region
2

1 1
2 O 2

1

75. 50
20 2 30 30 30
Sol. Coeff. of x in (1  x ) = C10 or C20

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