1. Calculate the standard enthalpy change, AHS, for the formation of 1 mol of strontium carbonate (the material that gives the red color in fireworks) from its elements, Sr(s) + C(graphite) + 20,(g) - SrCO,(s) ‘The information availableis (1) Sr(s) + $Ox(g) > S10(s) AHP = -592kI a) (2) SrO(s) + CO,(g) > SrCO,(s) HP = -234K) who SAM (3) C(graph eh +, o = CO, (g) AH? - 7394 Kd Se + "Oe 00 Cymer + 200 6c Se los + Qh Die S424 ~ ape any Seer See AUe Flame) > 5° CO, OH- -1220 2. ‘The combination of coke and steam produces a mixture called coal gas, which can be used as a fuel or as a starting material for other reactions, If we assume coke can be represented by graphite, the equation for the production of coal gas is, 2C() + 2H0(G) > CH,(@) + COs) Determine the standard enthalpy change for this reaction from the following standard enthalpies of reaction () C&) + H0(@) + COW + HL) AH = 113k) XQ (2) CO(®) + H:O(@) > COs(g) + Ha(@) AH’ = -41.2K) Dow Chrerger G) CH.) + H,O(@) + 3H,(e) + CO() AH? = 206.1kI Fle © 20 +2420 » 2COFAMe DHE BVI xR = BUG DCO *MHO pCOrt ts, Gtle “Ub J =206\ @ Bt + CD > Cryar thO Otte —20 aac ied ZC+Ztho * 1 Ze + UthO > COL CHy 3. One reaction involved in the conversion of iron ore to the m FeO(s) + CO(@) — Fets) + COLL) Calculate the standard enthalpy change for his reaction trom these rections of iron oxides with COz ‘ WA (1) 3Fe,0,(5) + CO(™) + 2Fe,0,(s) + CO,(g) AH? = -47.0K) Fig are = (@) Fes) + 360%) = 2Fe(s) + 3C0u) AN = -250K0 “FOL (3) Fe,0,(5) + CO(g) > 3 FeO(s) + CO,(e) AH - 1901) Fig and 3 © @DlA)ie0s + (#0 ~> Fe + CAO. An-as2-12-5 © FeO +(-A)CO2—> LB) Feady + CAVCO Ste ~1a=42 -b.%4. Calculate the enthalpy of reaction for the double replacement reaction that occurs between barium chloride and silver nitrate, Is this reaction endothermic or exothermic? Bath de NO, Ra Ws) #2 Agel CoH= (Bephr0)) 4. 2-Agel) — CR + 27% Wor) OH: oe 2f-100.3) =(-ASIH + 2(-12.) 5. Make the following conversions using the factor label method: a, 39.2 kJ =. calories | Sars ,teo8_ Nica b33 70 ca ies Qvitas b. 42 Calories =_joules Cal, _Loawers— ALIS 4 {3 xls 4 1Cor ‘ Leat “5 ) 6. If all 20.7 KJ of energy is added to 11.50g of ive at -10.0°C, what would be the final temperature of the HzO? What phase would it be in? Henk the ce 40.0% GCM OT = (2.00% eYNS) 09) 22377 Melt the ie 2 (Dies mess) 2 (33496) CUS) 2 B84 T Heat The cucite fy (00>. Gem BT =(4.1H MUS) (00-0) ee l2y Tota eNgy vsed- so fers L37 BBM tug2? BIO LT Enemy FEeracining= ZO 700-40 aM 0M Bot the water competery: Dua )ormes = 2260 «FF 25440 We dont have enagh enurgs to completety vapor! ee +e walt) So afer 10-7 ws 16 added, The water will be Pallas at OO7. Draw an energy diagram for each of these two reactions: a. 2He(g) + O2(g) —> 2H2O(g) AH = -483.6 kd Bone HBB HS b. COx(g) —> CO(g) + (1/2)0x(g) AH = 283.0 KI co + (4)On ef coal oer 8. A piece of copper (C=0.3861/g°C) is heated to 215.00°C and dropped into 42.8mL of water at 5.00°C. If the final temperature of the system is 7.50eC, what is the mass of the piece of copper? wad pier Emests -Coat (are 1055) 7.5-23 « — (D2) ovetnad (75-8) Mass Cogeet -(5.5% | 9. Is entropy increasing or decreasing in these reactions: a, 2C(s) + Ox(g) —>2COlg) Prereasis By ees b. 2Ha(g) + Or(g) —> 2Hz(g) 5 2H@ 0x8) —> ae), Teeceasins GMO —> OW, Lye (ens 4, NaCl(s) —> Nar(ag) + CH{aq) Fuccee sna, asses 10. 2Ca(s) + Ox(g) —> 2CaO(s)_- AH = -1271.0K How much energy is released when 55.7 grams of Calcium is converted to calcium oxide? S57 Cay (md G4, 12 TO HT (593 v5 oT Obla” amed Co