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Thermochemistry Worksheet Class 11[1]

The document is a worksheet for Class 11 Chemistry focusing on Thermochemistry, containing multiple choice questions, assertion and reason questions, short answer questions, and case-based questions. It covers key concepts such as enthalpy, the first law of thermodynamics, and the differences between exothermic and endothermic reactions. The worksheet aims to assess students' understanding of thermochemical principles and calculations.

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Deepti Sharma
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73 views2 pages

Thermochemistry Worksheet Class 11[1]

The document is a worksheet for Class 11 Chemistry focusing on Thermochemistry, containing multiple choice questions, assertion and reason questions, short answer questions, and case-based questions. It covers key concepts such as enthalpy, the first law of thermodynamics, and the differences between exothermic and endothermic reactions. The worksheet aims to assess students' understanding of thermochemical principles and calculations.

Uploaded by

Deepti Sharma
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOCX, PDF, TXT or read online on Scribd
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Class 11 Chemistry Worksheet

Chapter: Thermochemistry

Section A: Multiple Choice Questions (MCQs)


1. Which of the following is an extensive property?
(a) Enthalpy (b) Temperature (c) Pressure (d) Density

2. The SI unit of heat is:


(a) Calorie (b) Joule (c) Kelvin (d) Watt

3. ΔH is equal to ΔU when:
(a) No work is done (b) Pressure is constant (c) Volume is constant (d) Temperature is constant

4. The enthalpy change for a reaction is:


(a) Dependent on the pathway (b) Independent of the pathway (c) Always negative (d) Always positive

5. Which of the following reactions is exothermic?


(a) Melting of ice (b) Evaporation of water (c) Combustion of methane (d) Boiling of water

6. The first law of thermodynamics is also known as:


(a) Law of conservation of mass (b) Law of conservation of energy (c) Law of entropy (d) None of these

7. In an endothermic reaction:
(a) Heat is absorbed (b) Heat is released (c) No heat change occurs (d) Temperature decreases always

8. The standard enthalpy of formation of an element in its standard state is:


(a) 1 kJ/mol (b) 0 kJ/mol (c) 100 kJ/mol (d) -1 kJ/mol

9. Hess’s Law is based on:


(a) Law of conservation of mass (b) Law of conservation of energy (c) Law of multiple proportions (d) None of
these

10. Which of the following is a state function?


(a) Work (b) Heat (c) Enthalpy (d) None of these

Section B: Assertion and Reason Questions


1. Assertion (A): The enthalpy of an exothermic reaction is negative.
Reason (R): In an exothermic reaction, heat is released.

2. Assertion (A): Enthalpy is a state function.


Reason (R): Enthalpy depends only on the initial and final states of the system.

3. Assertion (A): Combustion reactions are always endothermic.


Reason (R): Combustion requires energy to break bonds.

4. Assertion (A): ΔH = ΔU + PΔV.


Reason (R): The equation is valid under constant volume conditions.

5. Assertion (A): The specific heat of water is high.


Reason (R): Water has strong hydrogen bonding.

6. Assertion (A): Heat and work are path functions.


Reason (R): Their values depend on the process path taken.

7. Assertion (A): The enthalpy change of a reaction can be zero.


Reason (R): This happens when there is no heat exchange.

8. Assertion (A): In an isolated system, energy can be exchanged with the surroundings.
Reason (R): Isolated systems allow heat transfer.
9. Assertion (A): Hess’s Law is useful to calculate enthalpy changes for reactions that are difficult to perform.
Reason (R): Enthalpy is a state function.

10. Assertion (A): Evaporation of water is an exothermic process.


Reason (R): Evaporation releases heat into the surroundings.

Section C: Short Answer Questions (2 Marks Each)


1. Define enthalpy and write its mathematical expression.

2. State the first law of thermodynamics.

3. What is the enthalpy change when ice melts at 0°C?

4. Determine the enthalpy change for the formation of 2 moles of water:2H₂ (g) + O₂ (g) → 2H₂O (l)

Given:- ΔHf°(H₂O) = -285.8 kJ/mol

5. Explain the difference between exothermic and endothermic reactions.

Section D: Short Answer Questions (3 Marks Each)


1. Derive the relationship between ΔH and ΔU.

2. Calculate the work done when 1 mole of an ideal gas expands reversibly and isothermally from 1 L to 10 L at
300 K.

3. Explain Hess’s Law with an example.

4. Calculate the enthalpy change for the reaction:N₂ (g) + 3H₂ (g) → 2NH₃ (g)Given: ΔHf°(NH₃) = -46 kJ/mol
ΔHf° of N₂ and H₂ = 0 kJ/mol (as they are in elemental form)

Section E: Case-Based Questions

1. Read the passage and answer the questions that follow:


A student conducted an experiment to measure the heat of neutralization between HCl and NaOH. The
temperature of the solution increased. Based on this, answer the following:
(a) Is the reaction exothermic or endothermic?
(b) Write the thermochemical equation for the reaction.
(c) Explain why the temperature increased.

2. Read the passage and answer the questions that follow:


A gas is allowed to expand against a constant external pressure of 1 atm from a volume of 2 L to 5 L. During the
process, it absorbs 500 J of heat from the surroundings.
(a) Calculate the work done by the gas.
(b) Determine the change in internal energy of the system.
(c) Classify the process as endothermic or exothermic.

3.Calculate the enthalpy change for the reaction:C (graphite) + O₂ (g) → CO₂ (g)Given:- Enthalpy of formation of
CO₂(g) = -393.5 kJ/mol- Enthalpy of formation of elements in their standard state = 0

4.Find the enthalpy change for the combustion of methane:CH₄ (g) + 2O₂ (g) → CO₂ (g) + 2H₂O (l)Given:-
ΔHf°(CH₄) = -74.8 kJ/mol, ΔHf°(CO₂) = -393.5 kJ/mol, ΔHf°(H₂O) = -285.8 kJ/mol

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