PROF TUTORIALS

CHM 101 PDR TUTORIAL QUESTIONS.

(d) Probable error
Answer: A
1. Find the relative accuracy if the mean
6. Determinate error cannot be corrected
is 2.4g and true value is 3.7g
by
(a) 0.2917 (b) 0.2968
(a) Calibration of apparatus
(c) 0.6486 (d) 0.6497
(b) Use of blank control
Answer: C
(c) Use of parallel determination
2. Given a mean of 27.99 and true value
(d) Use of internal standard
of 34.75, calculate the relative error
Answer: B
(a) −0.195 (b) −0.1946
7. An error that leads to another error is
(c) −0.994 (d) 0.195
(a) propagation (b) spawning (c)
Answer: A
sprinted (d) none of the above
3. Solve the following and round off to
Answer: A
correct significant figures 58.7 +
8. Find the mean of the concentration in
0.0394 − 4.296789
Vanadium: 3.65, 4.11, 3.59, 7.51,
(a) 54.013 (b) 54.4
3.95, 3.87, 4.06, 1.48, 3.76, 11.49
(c) 54.0126 (d) 54.012667
(a) 2.48 (b) 3.86
Answer: B
(c) 4.25 (d) 3.29
4. The two kinds of errors that affect
Answer: B
scientific measurement are
9. Simplify (4.18−58.16) × (3.38−3.01)
(a) Instrumental and personal error
(a) −19.97 (b) −20 (c) −19.972 (d)
(b) Constant and systematic
none
(c) Determinate and random
Answer: B
(d)Indeterminate and random
10. Precision is refer to as description in
Answer: C
a data
5. Which of the following can be used to
(a) Logical accuracy
estimate accuracy
(b) Measurement that are within 1
(a) Absolute error
min
(b) standard deviation
(c) Highly accurate data
(c) average error
 PROF TUTORIALS
CHM 101 PDR TUTORIAL QUESTIONS.
(d) Level of measurement and (a) Accuracy (b) Data
exactness of data (c) Precision (d) Error
Answer: D Answer: C
11. Convert 6.3056 to 3 significant figure 17. A boy measured the mass of a ball as
(a) 6.32 (b) 6.31 (c) 6.34 (d) 6.30 52.63g and the actual mass of the ball
Answer: B is 58.78g. Calculate the percentage
12. Given a mean of 27.99 and the true relative error
value of 34.75. Calculate the relative (a) 10.3% (b) 10.5%
error (c) 10.7% (d) −10.13%
(a) 0.195 (b) 0.230 Answer: B
(c) 0.994 (d) –0.115 18. A scientist measured an object to
Answer: A have a mean of 6.36 while the value
13. Find the mean deviation of 4.31, 3.20, is 6.20. Calculate the percentage
4.09, 11.09, 3.02, 4.30 and 5.06 relative error.
(a) 0.54 (b) 0.52 (c) 0.20 (d) 0.30 (a) 3.57% (b) 4.76%
Answer: A (c) 2.58% (d) 5.91%
14. Accuracy is estimated in one of Answer: C
following 19. Determinate error are classified into
(a) Absolute error (b) Standard error (a) 4 (b) 7 (c) 2 (d) 8
(c) Probable error (d) Standard Answer: C
deviation 20. ________ are error due to apparatus
Answer: A or reagent
15. Round off 58.3 + 0.039 –25.92 to 3 (a) Instrumental error
significant figure (b) Operative error
(a) 32.41 (b) 32.42 (c) 32.4 (d) 22.4 (c) Personal error
Answer: C (d) Methodical error
16. ________is the degree of closeness Answer: A
between replicate set of measurement 21. Error is divided into
or analysis (a) 3 (b) 4 (c) 7 (d) 2
 PROF TUTORIALS
CHM 101 PDR TUTORIAL QUESTIONS.
Answer: D scientific notation, it can be written as
22. An error that varies from one (a) 3.085 × 10⁴ (b) 3.08 × 10⁴
measurement to another is called (a) (c) 3.09 × 10⁴ (d) 3.085 × 10⁴
Random error (b) Operative error (c) Answer: B
Instrumental error (d) Systematic 29. Determinate Errors can be minimized
error by any of the following except?
Answer: D (a) Running a blank determination
23. Calculate (58 × 2.568) ÷ 4186 (b) Running parallel determinations
Answer: 3.6 (c) Calibration of apparatus
24. Use the data below to (d) Use of External Standard
Answer question 24 and 25 Answer: D
ATOMIC THEORY AND
3.65, 4.11, 3.59, 7.51, 3.95, 3.87, STATES OF MATTER
4.06, 1.48, 3.60, 3.76, 3.99 30. Two elements contain 10 protons
25. If the true mean value is 3.92, the each. Find the number of their
absolute error is electrons X- and X+ respectively
(a) 0.32 (b) –0.32 (c) 0.08 (d) –0.08 (a) 11 and 9 (b) 9 and 11
Answer: ………….. (c) 10 and 11 (d) 11 and 19
26. The percentage relative accuracy is Answer: ……………
(a) 0.9184% (b) 91.84% 31. Find the empirical formula of the
(c) 0.9796% (d) 97.96% compound which contains 47.35%C,
Answer: D 10.60% and 42.5%
27. The result obtained from the (a) C3H8O2
operation: 38.91 × (6.81 − 6.730) is (b) C3H8O3
Y. The value of Y is (c) C3H4O6
(a) 3.1128 (b) 3.113 (c) 3.11 (d) 3 (d) C2H5OH
Answer: C Answer: …….....
28. The number 30,849.28 recorded to 32. 31. X2+ contains 10 electrons,
three significant figures, using Calculate the atomic number of X
 PROF TUTORIALS
CHM 101 PDR TUTORIAL QUESTIONS.
(a) 12 (b) 11 (c) 13 (d) 10 (a) 16:1 (b) 1:16 (c) 1:4 (d) 4:1
Answer Answer:
33. When elements combine, they do so 38. Who discovered the planetary mode
in of atom?
(a) Multiple whole number ratio (a) Ernest Rutherford.
(b) Simple whole number fraction (b) J.J Thompson
(c) Multiple number ratio (c) Robert Milikan
(d) None (d) Eugene Goldstein
Answer: D [The right Answer is Answer:
Simple Whole number Ratio] 39. Who named Electron?
34. What is the electronic configuration (a) G.J. Stoney
of Oxygen? (b) J.J Thompson
(a) 1𝑠²2𝑠²2𝑝⁴ (b) 1𝑠²2𝑠²2𝑝⁶ (c) Ernest Rutherford
(c) 1𝑠²2𝑠²2𝑝⁴ (d) None (d) Erwin Schrodinger
Answer: Answer: ………….
35. Energy level III can hold a maximum 40. Who performed Cathode rays
of 18 electrons. How many orbitals discharge tube experiment?
does the energy level have (a) Sir J.J. Thompson
(a) 3 (b) 6 (c) 9 (d) 10 (b) Sir Ernest Rutherford
Answer: C (c) Sir John Dalton
36. Find the atomic number of the (d) Neils Bohr
electron Z2+ with 10 electrons Answer: ……………
(a) 12 (b) 11 (c) 10 (d) 9 41. 40. Which experiment led to the
Answer: ………. discovery of Electrons?
37. Equal volumes of hydrogen and (a) Cathode rays discharge tube
oxygen diffuse through a porous experiment
partition in 12 and 48 minutes (b) Alpha Scattering Experiment
respectively. What is the density of (c) Gold Foil experiment
oxygen relative to that of hydrogen (d) Oil Drop Experiment
 PROF TUTORIALS
CHM 101 PDR TUTORIAL QUESTIONS.
Answer: 46. 45. The characteristics odour of
pineapple is due to ethyl butyrate, a
42. 500cm³ of oxygen diffuse through a
compound containing carbon,
porous partition in 20 seconds. How
hydrogen and oxygen. Combustion of
long would it take 200cm³ of carbon
2.78mg of ethyl butyrate leads to
dioxide to diffuse through it
formation of 6.32mg of CO2 and
(a) 9.4s (b) 4.9s (c) 8.7s (d) 6.0s
2.58mg of H2O. Calculate the
Answer:
empirical formula (a) C6H12O2 (b)
43. If A and B are both gases, Ma and Mb
C6H22O12 (c) None of the option
are their masses respectively and Ea
Answer:
and Eb are their velocity, which of the
47. 46. How many moles of ammonia
following is true?
are there in 500cm³ of the gas?
(a) 𝐸𝑎 > 𝐸𝑏 (b) 𝐸𝑎 > 𝐶𝑂2 + 𝐻2𝑂 is
(a) 0.22mole (b) 0.022mole
Answer: 𝟐𝑪𝟔𝑯𝟏𝟒 + 𝟏𝟗𝑶𝟐 → 𝟏𝟐𝑪𝑶𝟐
(c) 0.002mole (d) 2.00mol
+ 𝟏𝟒𝑯𝟐𝑶
44. Calculate the empirical formula of a Answer:
compound containing 40.2%K,
48. A sample of aluminum has a mass of
26.9%Cr and the remaining being
5.4g. What is the number of moles of
oxygen [ =39, C =52, =16]
aluminum present?
(a) K2CrO4 (b) K2Cr2O4
(a) 2.0moles (b) 20moles
(c) K2CrO4 (d) K2Cr2O7
(c) 0.02moles (d) 0.2moles
Answer:
Answer:
45. 44. An experiment showed that
49. How many moles of H2SO4 are there
13.88g of calcium were obtained
in 10g of the substance [H = 1, S = 32,
from the combination of 5g of
O = 16g/mol.]
calcium with chlorine. What is the
(a) 0.12mol. (b) 0.2mol
formula of calcium chloride?
(c) 0.02mol (d) 0.001mol
[CA=40, Cl = 35.5g/mol.] (a) CaCl2
Answer:
(b) CaCl (c) CaCl3 (d) None
Answer:
 PROF TUTORIALS
CHM 101 PDR TUTORIAL QUESTIONS.
50. How many moles of glucose C6H12O6 55. What is the percentage by mass of
are there in 1.09g of this substance each element Mg, N, and O in
[C=12, H=1, O=16] Magnesium trioxonitrate (V)
Answer: 6.06 x 10-³mol. respectively?
51. 8g of iron when burned in air yielded Answer: 16.2%, 18.9% and 64.9%
11.40g of its oxide. What is the 56. Find the percentage by mass of each
empirical formula of this oxide? [𝐹𝑒 element Ca, C and O in limestone
= 56, 𝑂 = 16] respectively
(a) Fe2O3 (b) FeO3 Answer: 40%, 12% and 48%
(c) FeO2 (d) Fe2O 57. 0.6025g sample of a chloride salt was
Answer ………….. dissolved in water and the chloride
52. An oxide of antimony is found to precipitated by adding excess silver
contain 24.73% oxygen. What is its nitrate. The precipitate of silver
empirical formula chloride was filtered, washed, dried
[Sb = 122, O = 16] and found to weigh 0.7134g.
(a) Sb2O5 (b) SbO3 Calculate the percentage of chloride
(c) Sb2O (d) Sb2O2 in the sample. [Cl=35.5, AgCl=107.9]
Answer: (a) 29.29% (b) 30.03%
53. What mass of CH3CH2COOH would (c) 25% (d) 40%
be dissolved in a mixture of 60g of Answer:
H2O and 55g of CH3CH2CH2OH? If 58. Find the percentage by mass of each
the mole fraction of propionic acid is element Zn, S, O and H respectively.
0.054 Answer: 22.6%, 11.1%, 61.3%,
(a) 17.91g (b) 20.91g (c) 30g (d) 25g 4.9%.
Answer 59. Sodium combines with oxygen as
54. How many moles of atoms of oxygen follow: 4𝑁(𝑔) + 𝑂2(𝑔) → 2𝑁𝑎2𝑂(𝑠)
are there in 0.1mole of S𝑂2 What is the mass of O2 needed to
Answer: 0.2mol burn 4.6g of sodium? (a)1.6g (b)1.4g
(c)1.2g (d)1.0g Answer
 PROF TUTORIALS
CHM 101 PDR TUTORIAL QUESTIONS.
60. 14.28g of hydrogen react with 85.72g Answer: A
of carbon. What is the empirical 64. 𝑎𝐴 + 𝑏𝐵 ↔ 𝑐𝐶 + 𝑑𝐷, what is the
formula of the compound? [C=12, backward equilibrium constant
H=1] Answer:
(a) CH3 (b) CH4 (c) CH (d) CH2 65. Consider the following equilibrium at
Answer 127℃. Calculate Kp for the reaction,
61. How many moles of atoms of oxygen if kc=2.6×10-5 2𝑁𝐻3(𝑔) → 𝑁2(𝑔) +
are there in 0.1 mol. of sulphur (IV) 3𝐻2(𝑔)
oxide and what is the mass of the (a) 0.028 (b) 0.048 (c) 0.821 Answer:
sample of the Oxide. 66. In the reaction, 𝑁2 + 3𝐻2 → 2𝑁𝐻3.
Answer: 0.2mol and 6.4g The unit for Kc?
62. Calculate the Relative Molecular (a) mol-2dm⁶ (b) mol²dm⁶
Mass of the following: (c) mol-2dm-6 (d) mol²dm-6
Copper(II)oxide, Washing soda, Answer:
Quick lime, calcium tetraoxosulphate 67. What is the oxidation number of O in
(VI) and Magnesium trioxonitrate (v) O3-
Respectively (a) -1/3 (b) 1/3 (c) 3 (d) -3
Answer: 80, 286, 56, 148 Answer:
REDOX-EQUILIBRIA, CHEMICAL 68. Balance the equation 2MnO4- +
EQUILIBRIA, ACID-BASE SO32- + H+ SO42- + Mn2+ + H2O
EQUILIBRIA, CHEMICAL Answer: 𝟐𝑴𝒏𝑶−𝟒 + 𝟓𝑺𝑶𝟐𝟑− + 𝟔𝑯
KINETICS AND → 𝟐𝑴𝒏² + 𝟓𝑺𝑶𝟐𝟒− + 𝟑𝑯𝟐𝑶
THERMOCHEMISTRY 69. H2S (g) + Cl2 (g) 2HCl (g) + S (g).
63. The equilibrium constant of the The Reducing agent in the above
reaction between 0.012moldm-3 of reaction is? (a) Cl2 (b) H2S (c) HCl
propanol and 0.832moldm-3 of (d) S
botanic acid to give 0.174moldm-3 Answer:
propylbutanoate is 70. A Lewis base ________
(a) 3.03 (b) 4.01 (c) 3.43 (a) Donates lone pair of electrons
 PROF TUTORIALS
CHM 101 PDR TUTORIAL QUESTIONS.
(b) Donate proton 75. The oxidation number of an
(c) Accept lone pair of electrons uncombined atom of Lithium is (a) 0
(d) Accept protons (b) +1 (c) -1 (d) 2
Answer: Answer:
71. At 1100K, Kc=4.2 x 10-6 for the gas 76. The solution that resists changes in
phase reaction, 2𝐻2𝑆(𝑔) ↔ 2𝐻2(𝑔) + PH when limited amount of acid or
𝑆2(𝑔), What concentration of S2 can base is added to it is _________
be expected when 0.200 mole of H2S Answer: Buffer
comes to equilibrium at 1100K in an 77. The name of the scientist that define
otherwise empty 1L vessel? the PH scale is
(a) 3.5 x 10-3 (a) Peter Sorensen
(b) 3.0 x 10-2 (b) Peter Sorensen
(c) 4.5 x 10-3 (c) Peter Soren
Answer: Answer:
72. Photolytic reaction take place in the 78. If 2SO3 (g) 2SO2 (g) + O2 (g). ΔH= -
presence of Ve. Which factor will increase the
(a) Chemical (b) Heat yield of SO2 (g)?
(c) Light (d) None (a) Decrease in temperature
Answer: (b) Increase in temperature
73. When an element loses an electron, it (c) Decrease in pressure
becomes (d) Increase in pressure
(a) Positively Charged Answer:
(b) Negatively Charged 79. For a reaction at equilibrium between
(c) Neutral propanol and butanoic acid, 0.012M
Answer: of propanol, 0.832M butanoic acid
74. When an element gain an electron, it and 0.174M propyl butanoate were
becomes (a) Positively Charged (b) concentrations at equilibrium.
Negatively Charged (c) Neutral Calculate the equilibrium constant of
Answer: the reaction.
 PROF TUTORIALS
CHM 101 PDR TUTORIAL QUESTIONS.
(a) 3.03 (b) 4.01(c) 3.23 (d) 3.35 86. 85. When Δn is 0, _________ (a)
Kp=Kc (b) KpKc (a) All of the option
Answer:
Answer:
80. A+ B C+D. ΔH =−10 for 2C + 2D 87. For the reaction 𝑎𝐴 + 𝑏𝐵 ↔ 𝑐𝐶 + 𝑑𝐷.
2A + 2B. ΔH is? What is Δn?
(a) -20 (b) 20 (c) 10 (d) -10 (a) 𝛥𝑛 = (𝑎 + 𝑏) − (𝑐 + 𝑑)
Answer: (b) 𝛥𝑛 = (𝑎 −𝑏) + (𝑐 + 𝑑)
81. A redox reaction is made up of and (c) 𝛥𝑛 = (𝑎 + 𝑏) + (𝑐 + 𝑑)
reaction
(d) 𝛥𝑛 = (𝑎 − 𝑏) − (𝑐 − 𝑑)
(a) Oxidation and reduction
Answer:
(b) Chemical and Electrical
88. For the dissociation of sulphur (vi)
Answer:
oxide at 120⁰C the value of Kp with
82. The relationship between Kp and Kc
partial pressure is 1.78 x 106atm.
is ________?
Calculate the corresponding
Answer: Kp = Kc (RT)Δn
value of Kc assuming ideal
83. What mass of copper (II) sulphate
behavior of gases.
could be obtained by starting with
R=0.08205atmdm³/mol./k.
10g of copper (II) oxide from the
(a) 5.52 x 10-8mol/dm-3
following reaction CuO (s) + H2SO4
(b) 5.52 x 10-8mol/dm-6
(l) CuSO4 (s) + H2O (l)
Answer:
(a) 20.15g (b) 30.25g
89. If "a" moles of nitrogen and "b" mole
(c) 16.34g (d) 19.79g
of oxygen in a volume of "V" dm³ at
Answer a particular temperature, "x" is the
number of moles of oxygen and
84. When Δn is +ve, ________
nitrogen converted to nitrogen (IV)
(a) Kp > Kc (b) Kp < Kc (c) Kp = Kc
oxide under equilibrium condition,
Answer:
what is the Kc and Kp ?
85. When Δn is -ve, ________ (a) Kp >
Answer:
Kc (b) Kp < Kc (c) Kp = Kc
Answer:
 PROF TUTORIALS
CHM 101 PDR TUTORIAL QUESTIONS.
90. C(s) + O2 (g) 2CO2 (g). Calculate the ethanol and ethanoic acid remain
enthalpy change ΔH for C unreacted in the system. (Kc=4.01)?
=113.2Kj/mol ΔH for CO2 = Answer: 0.422moles of ethanoate
393Kj/mol. and water, 0.578 mol. if ethanol and
(a) 559.6kj/mol (b) -559.6kj/mol. 0.578 mol. of ethanoic acid remain
(c) -600kj/mol. (d) 600kj/mol. unreacted.
Answer: 94. How many moles of phosphorus
91. If "a" moles of propanoic acid and "b" penta chloride must be added to a litre
moles of propanol react in a vessel vessel at 250⁰C to obtain a
"V" dm³ volume. If "x" moles of concentration of 0.1mol of chlorine
water is produced at equilibrium at per litre? Given .
temperature T, then Kc is 95. R= 0.0825atmdm³K-¹mol-¹.
_________? (a) 0.432mol. (b) 0.341mol.
Answer: (c) 0.23mol. (d) 0.26mol
92. One mole of ethanoic acid is mixed Answer:
with 1 mole of ethanol at 25⁰C and 96. In the equilibrium 𝐴 + 𝐵 ↔ 𝐶 + 𝐷.
after equilibrium is reached, a The initial concentrations of both A
titration with standard alkali solution and B are 1.6mol/dm³, at 298K the
shows that 0.666 mol of ethanoic acid equilibrium mixture contains
has reacted to form ethyl ethanoate. 1.2mol/dm³ of C. Determine the value
What is the value of Kc? of Kc?
(a) 4.01 (b) 3.03 (c) 6.02 (d) 5.03 (a) 9 (b) 10 (c) 8 (d) 7
Answer: Answer:
93. When 0.5 mol of ethanol is added to 97. What is the expression for Kc in the
1 mol of ethanoic acid at the same reaction 2E(g) + F(g) 2G(g)
temperature. How much of ethyl Answer:
ethanoate will be formed at 98. How is the equilibrium constant for
equilibrium? And what mole of the forward reaction (Kf) related to
that of the reverse reaction (Kr). (a)
 PROF TUTORIALS
CHM 101 PDR TUTORIAL QUESTIONS.
Kr is the multiplicative inverse of Kf. 103. Calculate the solubility in
(b) Kr is the additive inverse of Kf (c) g/dm³ at 298K if AgCl in 0.1M HCl.
Kr has no relationship with Kf KSP of AgCl = 1.8 x 10-8 mol²dm-6.
Answer: Molar mass of AgCl = 143.5g/mol.
99. A saturated solution of BaSO4 at 25⁰C (a) 2.58 x 10-7 g/dm³ (b) 2.89 x 10-7
was found experimentally to have g/dm³
concentration of 4 x 10-5 mol./dm³. Answer:
What is the solubility product of this 104. If Kc for the equilibrium reaction for
salt? the formation of ethylethanoate from
(a) 1.6 x 10-9 mol²dm-6 ethanol and ethanoic acid at 25⁰C is
(b) 1.8 x 10-9moldm-3 4.00. Calculate the mass of ester
(c) 1.6 x 10-9moldm-3 formed if 2 mole of acid and 2 moles
(d) 1.8 x 10-9mol²dm-6 of alcohol are mixed and allowed to
Answer: reach equilibrium. M.M of ester is
100. Which of the following 88g/mol. (a) 128g (b) 141g (c) 117.4g
quantum numbers defines the main (d) 108g Answer:
energy level the electrons occupies 105. If Keq of silver chloride AgCl is 1.8 x
(a) Azimuthal (b) Magnetic (c) Spin 10-10 mol²dm-6. Calculate it's
(d) Principal solubility in (I) Pure Water (II) 0.1M
Kcl Solution.
Answer: D
Answer: 1.34 x 10-5M and 1.8 x10-9
101. Reducing agent is mol/dm³
_________? (a) oxidised (b) Reduced 106. For the reaction H2 (g) + I2 (g) 2HI
(c) None of the above (g). The equilibrium constant for the
Answer: above reaction is 64 at
102. Oxidizing agent is 107. 450⁰C. If 6 moles of hydrogen and 3
_________? (a) reduced (b) Oxidised moles of iodine are mixed in a 1-dm³
(c) all of the above vessel at this temperature, what will
Answer: be the concentration in mol/dm³ of
 PROF TUTORIALS
CHM 101 PDR TUTORIAL QUESTIONS.
each of the three components (H2, I2, 111. Oxidation number of Na of NaOH is
and HI) when equilibrium is reached? (a) +1 (b) -1 (c) -2 (d) +2
Answer: 3.16M, 0.16M, 5.68M Answer:
108. E(g) + F(g) 2G(g) + H(g). ΔH is 112. State the effect of pressure on
negative. Which of the following will reaction N2O4 (g) 2NO2 (g)
increase the yield of G? (a) Removing Answer: Low Pressure will favour
Some G. (b) Using a larger closed the forward reaction and product
vessel (c) Adding a positive Catalyst. formation while a high pressure will
(d) Increasing the temperature. favour the backward reaction.
Answer: A 113. States the effect of pressure on the
2NO2 (g) N2O4 (g). reaction 3Fe(s) + 4H2O (g)
109. What happens when the total pressure Fe3O4(s) + 4H2 (g). (a) Favours
of the equilibrium reaction above is forward reaction (b) Favours
increased? (a) Production of more Backward reaction (c) Has no effect
N2O4 in the mixture (b) No effect on Answer:
the concentrations (c) Production of 114. Oxidation is the gain of electron
more NO2 in the mixture. while reduction is loss of electron (a)
Answer: B False (b) True
110. States the effect of pressure on the Answer:
reaction N2 (g) + 3H2 (g) 2NH3 (g) 115. Oxidation is the addition of hydrogen
Answer: The forward reaction results and reduction is the addition of
in a decrease in the number of moles oxygen (a) False (b) True Answer:
and hence a decrease in the pressure 116. For a reversible at equilibrium, the
of the system while the backward value of ΔG must be ________? (a) 0
reaction results in an increase in the (b) +Ve (c) -Ve
number of moles and hence an Answer:
increase in the pressure of the system 117. Calculate the formula of a compound
Answer: which has the following of
magnesium of 9.8%, sulphur 13%,
 PROF TUTORIALS
CHM 101 PDR TUTORIAL QUESTIONS.
oxygen 26%, water of crystallization (a) Oxidizing Agent
51.2% (a) MgSO.7H2O (b) (b) Reducing Agent
MgSO4.6H2O (c) MgSO4 Answer:
Answer: 123. Addition of Electronegative Elements
118. Oxidation number of hydrogen is -1 is _________?
in which of the following? (a) Oxidation (b) Reduction
(a) NaH (b) NaOH Answer
(c) NH2SO4 (d) None 124. Mn + Zn2+ Mn2+ + Zn. Which of
Answer: A these oxidised?
119. A+B C+D ΔH = +Ve. _______ is (a) Mn (b) Zn (c) Mn2+ (d) Zn2+
endothermic while ________ is Answer:
exothermic? 125. Oxidation is the addition of
(a) Forward reaction is / Backward electropositive elements and
reaction reduction is the removal of
(b) Backward reaction/Forward electronegative elements
reaction (a) False (b) True.
Answer:
Answer:
120. State the effect of temperature on
reaction N2 (g) + O2 (g) 2NO(g). 126. State the effect of temperature on

ΔH= +90Kj/mol. reaction 2SO2 (g) + O2 (g) 2SO3 (g).

Answer: increase in Temperature ΔH=-395.7Kj/mol.

will favour the product formation Answer: Increase in Temperature

while decrease in temperature will will favour the reactant formation

favour the backward formation. while decrease in Temperature will

121. What is the oxidation number of Mn favour the product formation.

in 2MnO4- 127. The oxidation number of oxygen in

(a) 7 (b) 6 (c) 5 (d) 4 Hydrogen peroxide is

Answer: (a) -1 (b) 1 (c) -2 (d) 2

122. MnO4- is a _________? Answer:

 PROF TUTORIALS
CHM 101 PDR TUTORIAL QUESTIONS.
128. The oxidation number of oxygen in (c) Negative (d) Positive
superoxide is ________? (a) −1/2 (b) Answer:
1/2 (c) 2 (d) -2 134. During Bond formation, Energy is
Answer: ________?
129. Oxidation of Hydrogen is said to be - (a) Released
1 in _________? (b) Absorbed
(a) Hydrides (b) Halides (c) Nitride (c) None
Answer: Answer:
130. Oxidation number of Mn changes 135. Electropositive element undergo
from _________ to _______ in the (a) Oxidation (b) Reduction
following reaction 2MnO4- + CO + Answer:
14H+ 2Mn² + CO2 + 7H2O (a) +7 to 136. The heat change when 500kg of
+2 (b) +2 to +7 (c) -7 to +2 (d) -2 to ammonia is produced according to the
+7 reaction N2 (g) + 3H2 (g)
Answer: 137. 2NH3 (g) ΔH=−91.8KJ is? (a) 1.35 x
131. The addition of higher 10⁶KJ (b) -1.35 x 10⁶KJ
electronegativity elements is Answer:
(a) Oxidation (b) Reduction 138. For the gas phase reaction H2 (g) + I2
(c) A and B (g) 2HI (g). Kc=50.3 at 731K. Equal
Answer: amounts (0.1M each) is introduced to
132. Which of the following is an a container and the temperature is
Oxidizing Agent in the equation raised to 731K. Calculate the
below MnO4- + Fe2+ Mn2+ + Fe3+ concentration of each when the
(a) MnO4- (b) Mn2+ system is at equilibrium.
(c) Fe3+ (d) Fe2+ Answer: [H2] = [I2] = 0.033M and
Answer: [HI] = 0.234M.
133. The oxidation of elements in its 139. Dynamic equilibrium occurs
neutral state is when________?
(a) 0 (b) varies
 PROF TUTORIALS
CHM 101 PDR TUTORIAL QUESTIONS.
Answer: When the rate of forward 147. CH4 (g) + O2 (g) CO2 (g) + O2 (g).
reaction equal the rate of backward ΔH=-890kj/mol. ΔH in this reaction
reaction. is ________?
140. In a closed system, which of the (a) Standard Enthalpy of Combustion
following is not conserved (b) Standard Enthalpy of
(a) Energy (b) Matter (c) None Neutralization
Answer: A (c) Standard Enthalpy of Solution
141. If Kc is larger, the reaction contains Answer:
mainly _________? 148. If the change in free energy of a
(a) Product (b) Reactants (c) A and B system is −899KJ-1 and the entropy
Answer: change is 10kj/mol/k at 25⁰C.
142. Which system does not interact with Calculate the enthalpy change.
the surrounding? (a) Isolated system (a) +2081kj/mol. (b) -2018kj/mol
(b) Closed system (c) Open system (c) +2018kj/mol (d) +2081kj/mol
Answer: Answer:
143. Which system freely exchange Matter 149. The valency of boron is?
and Energy? (a) Open (b) Closed (c) (a) 3 (b) 2 (a) 1
Isolated Answer:
Answer:
144. CuO + NH3 2Cu +H2O. Which of the
following is the reducing agent? 150. Equilibrium law can only take place

(a) NH3 (b) CuO (c) Cu (d) H2O in________ system.

Answer: (a) Free (b) Isolated (c) Closed

145. Find the oxidation number of Answer:

chromium in the oxidizing agent 151. 147. In the bombardment of the

K2Cr2O7 (a) +6 (b) -6 (c) +7 (d) -7 alpha particles, the positive ion are

Answer: trapped in________?

146. H3O+ represents _________? Answer: Ionization chamber

Answer: Hydrozonium or
Hydronium ion.
 PROF TUTORIALS
CHM 101 PDR TUTORIAL QUESTIONS.
152. Which of the following is an (b) Ca3P2(s) + 6H2O (l) 3Ca (OH)2
oxidising agent and reducing agent (aq) + 2PH3(g)
Fe2O3 +3CO 2Fe +3CO2 (c) P4(s) + 5O2(g) P4O10(g)
Answer: Fe2O3 is an oxidizing (d) None
Agent while 3CO is a reducing agent Answer: B
153. Mo₂₄O₃₇ + pMnO₄⁻ + qH+ rMoO₃ + 159. A ________ reaction is a reaction in
sMn²⁺ + tH₂O. What is p, q and r. which the same substance (on the
Answer: 14, 42, 12 reactant side) that is being oxidized is
154. What's the oxidation number of Cl in also being reduced.
ClF3 and CCl4 respectively? (a) Disproportionation reaction
(a) +3 and +4 (b) +3 and -4 (b) Cross-proportionation reaction
(c) -3 and +4 (d) -3 and -4 (c) Proportionation reaction
Answer: Answer:
155. What's the oxidation number of Al in 160. Reducing agent _________?
Al (OH) 4- Answer:
(a) +4 (b) -4 (c) -3 (d) +3 161. Oxidizing agent __________?
Answer: Answer:
156. What's the oxidation number of O in 162. A saturated aqueous solution of
KO2? compound XY contains 6 x 10-
(a) 1/2 (b) 2 (c) −1/2 (d) −2 3g/dm³ of X2+(aq) at 298K. What is
Answer: the solubility product of XY at 298K?
157. What's the oxidation number of Cr in (a) 3.6 x 10-3g²dm-6 (b) 3.7 x 10-
Cr2O72-? 3gdm-6
(a) +6 (b) -6 (c) +7 (d) -7 Answer:
Answer: 163. _________ named oxygen as acid
158. Which of the following is not a redox former?
reaction? Answer: Antoine Lavoisier
(a) Fe2O3(s) + 3CO (g) 2Fe(s) + 164. According to Bronzed Lowry, Acid is
3CO2 (g) _________ while Base is ________?
 PROF TUTORIALS
CHM 101 PDR TUTORIAL QUESTIONS.
(a) Proton Donor and Proton world are undergoing changes in pH.
Acceptor respectively The water in one lake was found to
(b) Proton acceptor and Proton Donor have [H+] = 3.2 x 10-5mol/L.
(c) None of the option Calculate the pH and pOH of the
Answer: lakes water and decide whether it is
165. Phosphoric acid is _________? acid or basic.
(a) Triprotic acid Answer: pH is 4.49 and pOH is 9.51
(b) Diprotic 171. What are the concentration of
(c) Monoprotic hydrogen ion and acetate ion in a
Answer: solution of 0.2M acetic acid,
166. If [𝐻+] > [𝑂𝐻−], then the solution is CH3COOH? What is the pH of the
_________? solution if Ka for CH3COOH is 1.7 x
(a) Acidic (b) Neutral (c) Basic 10-5M
Answer: Answer: 1.84 x 10-3M and 2.75.
167. If [𝐻+] < [𝑂𝐻−], then the solution is 172. What is the hydrogen ion
_________? concentration and pH of a 0.2M
(a) Neutral (b) Basic (c) Acidic solution of ammonia solution?
Answer: Answer: 5.26 x 10-10M and 9.28
168. If [𝐻+] = [𝑂𝐻−], then the solution is 173. A buffer solution consists of
__________? _________?
(a) Neutral (b) Acidic (c) Basic Answer: Acid species and Base
Answer: species in equilibrium
169. A water sample has [OH-] of 1.47 x 174. The best Indicator for the titration of
10-9mol/L. What is the pH of the strong acid against strong base is
water sample? _________?
(a) 5.17 (b) 6.12 (c) 3.45 (d) 4.35 (a) Methyl Orange
Answer: (b) Phenolphthalein
170. Because rain washes pollutant out of (c) Methyl Blue
the air, the lakes in many parts of the (d) Methyl Red
 PROF TUTORIALS
CHM 101 PDR TUTORIAL QUESTIONS.
Answer: (a) Exothermic and ΔH is
175. What will be the pH of a solution Positive
obtained by mixing 5g of acetic acid (b) Exothermic and ΔH will be
and 7.5g of sodium acetate, negative
CH3COONa and making the volume (c) Endothermic and ΔH is positive
to 500cm³, Ka for acetic acid is 1.8 x (d) Endothermic and ΔH is negative
10-5 Answer:
(a) 4.79 (b) 4.97 (c) 5.12 (d) 5.14 179. A 10.40g sample of silver was heated
Answer: to 100⁰C. It was then added to 28g of
176. Calculate the of 3.2 x 10-3M solution water in an insulated cup?
of Ba (OH)2 in water at 25⁰C. 180. The water temperature rose from 25
(a) 12 (b) 11.81 (c) 9.87 (d) 13 to 26.48⁰C. What is the specific heat
Answer: capacity of silver? S.H.C or water is
177. If the total energy of reactant Is 4.18 j/g/k.
greater than total energy of products, (a) 0.227j/g/k. (b) 0.372j/g/k (c) None
hence the reaction is _________? of the option
(a) Exothermic and ΔH is Answer:
Positive 181. 0.4g of methanol was burned raise the
(b) Exothermic and ΔH will be temperature of 100g to water by 10K.
negative If the specific heat capacity of water
(c) Endothermic and ΔH is is 4.2j/g/k. Calculate the heat if
positive combustion of methanol in Kj/mol.
(d) Endothermic and ΔH is [C=12, H=1, O=16]
negative (a) -336kj/mol. (b) 336kj/mol
Answer: (c) None
178. If the total energy of products is Answer:
greater than total energy of reactants. 182. Calculate the standard enthalpy of
Hence the reaction is ________? combustion of methane given that the
standard enthalpies of formation of
 PROF TUTORIALS
CHM 101 PDR TUTORIAL QUESTIONS.
methane, CO2 and water are -74.8, - +412, +612, +348, and +436Kjmol-¹
393.7 and -285.9Kj/mol respectively. (a) -124Kjmol-¹ (b) 124Kjmol-1
(a) -890.7kjmol1 (b) 890.7kj/mol Answer:
Answer: 188. If the molar heat of transition that
183. Calculate the standard enthalpy accompanied the transition below at
change when 50cm³ of 0.5moldm-3 60⁰C is 95.8Kjmol-1. CO (g) CO(s).
NaOH was mixed with 50cm³ of Calculate the standard entropy
184. 0.5moldm-3 HCl and the temperature change accompany the transition.
was raised by 3.2⁰C on stirring. If the (a) 95.8Kjmol-1 (b) 287.7J/K/mol.
specific heat capacity of the solution Answer:
is 4.2j/k/g. 189. The energy content of a chemical
(a) -53.8Kjmol-1 (b) 53.8Kjmol-1 Answer: substance is called ________?
185. If the heat of atomization of sodium is Answer: Enthalpy
+107kj, the dissociation of chlorine is 190. What is the rate of reaction of 0.5g of
+122kj, the heat of ionization of calcium trioxocarbonate (IV) in
sodium is +496kj, the electron excess dilute hydrochloric acid. Time
affinity of chlorine is -349Kj and the take for the reaction is 15 minutes?
heat of formation of sodium chloride Answer: 0.33g/min or 5.6 x 10-7
is -411Kj. What is the Lattice energy? Kgs-1 185.
(a) -787Kjmol-¹ (b) 787Kj/m 191. A positive Catalyst acts by
Answer: __________?
186. When ΔG is -ve, the reaction is Answer: Lowering the energy barrier
__________? (a) Spontaneous (b) of a chemical reaction
Non-Spontaneous 192. In the equation N2O4 2NO2. What is
Answer: the molecularity of the formed
187. Calculate the standard molar enthalpy reaction?
change for the hydrogenation of (a) 1(Unimolecular)
ethene if the bond enthalpies if C-H, (b) 2(Bimolecular)
H-H, C-C, C=C bonds at 298K are (c) 3(Trimolecular)
 PROF TUTORIALS
CHM 101 PDR TUTORIAL QUESTIONS.
Answer:
Use this information to Answer the
below questions;
193. In a chemical reaction, after 10s, 6
moles from the initial concentration
of 16 moles of the reactant
disappeared. Calculate the rate
constant
Answer: 0.0470s-1
194. Calculate the half-life
Answer: 14.74s
195. Calculate the rate of reaction
Answer: 6
196. Calculate the time for 10moles to
disappear
Answer: 20.87s