Modeling and Control of Fuel Cells Distributed Generation Applications IEEE Press Series on Power Engineering 1st Edition M. H. Nehrir - Download the full ebook now to never miss any detail
Modeling and Control of Fuel Cells Distributed Generation Applications IEEE Press Series on Power Engineering 1st Edition M. H. Nehrir - Download the full ebook now to never miss any detail
https://ebookfinal.com/download/micro-fuel-cells-principles-and-
applications-1st-edition-tim-zhao/
https://ebookfinal.com/download/cyber-physical-distributed-systems-
modeling-reliability-analysis-and-applications-1st-edition-huadong-mo/
https://ebookfinal.com/download/fuel-cells-problems-and-solutions-the-
ecs-series-of-texts-and-monographs-2nd-edition-vladimir-s-bagotsky/
https://ebookfinal.com/download/solid-oxide-fuel-cells-jeffrey-fergus/
Modeling and Control of Fuel Cells Distributed
Generation Applications IEEE Press Series on Power
Engineering 1st Edition M. H. Nehrir Digital Instant
Download
Author(s): M. H. Nehrir, C. Wang
ISBN(s): 9780470233283, 0470233281
Edition: 1
File Details: PDF, 12.81 MB
Year: 2009
Language: english
MODELING AND
CONTROL OF
FUEL CELLS
BOOKS IN THE IEEE PRESS SERIES ON POWER ENGINEERING
Electrical Insulation for Rotating Machines: Design, Evaluation, Aging, Testing, and
Repair
Greg Stone, Edward A. Boulter, Ian Culbert, and Hussein Dhirani
M. Hashem Nehrir
Caisheng Wang
IEEE
PRESS
SERIES
ON
POWER
ENGINEERING
+,IEEE
IEEE Press
�WILEY
A JOHN WILEY & SONS, INC., PUBLICATION
IEEE Press
445 Hoes Lane
Piscataway, NJ 08854
Technical Reviewers
Rama Ramakumar, Oklahoma State University
Kai Strunz, Technical University of Berlin
No part of this publication may be reproduced, stored in a retrieval system, or transmitted in any form or
by any means, electronic, mechanical, photocopying, recording, scanning, or otherwise, except as
permitted under Section 107 or 108 of the United States Copyright Act, without either the prior
written permission of the Publisher, or authorization through payment of the appropriate per copy fee to
the Copyright Clearance Center, Inc., 222 Rosewood Drive, Danvers,MA 01923, (978) 750 8400,
fax (978) 750 4470, or on the web at www.copyright.com. Requests to the Publisher for permission
should be addressed to the Pennissions Department, John Wiley & Sons, Inc., III River Street, Hoboken,
NJ 07030, (201) 748 6011, fax (201) 748 6008, or online at
Limit ofLiabilitylDisciaimer of Warranty: While the publisher and author have used their best efforts in
preparing this book, they make no representations or warranties with respect to the accuracy or
completeness of the contents of this book and specifically disclaim any implied warranties of
merchantability or fitness for a particular purpose. No warranty may be created or extended by sales
representatives or written sales materials. The advice and strategies contained herein may not be
suitable for your situation. You should consult with a professional where appropriate. Neither the
publisher nor author shall be liable for any loss of profit or any other commercial damages, including
but not limited to special, incidental, consequential, or other damages.
For general information on our other products and services or for technical support, please contact our
Customer Care Department within the United States at (800) 762 2974, outside the United States at
(317) 572 3993 or fax (317) 572 4002.
Wiley also publishes its books in a variety of electronic formats. Some content that appears in print may
not be available in electronic formats. For more information about Wiley products, visit our web site
at www.wiley.com.
Preface xiii
Acknowledgments xvii
1 Introduction 1
v
vi CONTENTS
2.1 Introduction 29
2.2 Chemical and Thermal Energy of an Element 30
2.3 Fundamentals of Thermodynamics 31
2.3.1 The First Law of Thermodynamics 31
2.3.2 The Second Law of Thermodynamics 32
2.4 Fundamentals of Electrochemical Processes 34
The Gibbs Free Energy 34
2.5 Energy Balance in Chemical Reactions 35
2.6 The Nernst Equation 37
2.7 Fuel Cell Basics 38
2.8 Types of Fuel Cells 40
2.9 Fuel Cell Equivalent Circuit 53
2.10 Capacitance of Double-Layer Charge Effect 54
2.11 Summary 55
References 56
4.1 Introduction 85
4.2 Nomenclature (SOFC) 86
4.3 SOFC Dynamic Model Development 88
4.3.1 Effective Partial Pressures 89
4.3.2 Material Conservation 92
4.3.3 SOFC Output Voltage 94
4.3.3.1 Activation Voltage Drop 95
4.3.4 Thermodynamic Energy Balance
for Tubular SOFC 98
4.3.4.1 The Fuel Cell Tube 99
4.3.4.2 Fuel 100
4.3.4.3 Air Between Cell and Air Supply
Tube (AST) 100
4.3.4.4 Air Supply Tube 101
4.3.4.5 Air in AST 101
4.4 SOFC Dynamic Model Structure 102
4.5 SOFC Model Response-Constant Fuel
Flow Operation 103
4.5.1 Steady-State Characteristics 103
4.5.2 Dynamic Response 106
4.5.2.1 Dynamics Due to the Double-Layer
Charge Effect 106
4.5.2.2 Dynamics Due to the Effect
of Pressure 108
4.5.2.3 Dynamics Due to the Effect of
Temperature 109
4.6 SOFC Model Response-Constant Fuel
Utilization Operation 111
4.6.1 Steady-State Characteristics 112
4.6.2 Dynamic Response 113
References 114
viii CONTENTS
Index 291
PREFACE
Fuel cells (FCs) have caught intensive attention in the last decade.
Following their successful development for the manned space program by
the U.S. National Aeronautical and Space Administration (NASA) in the
1960s, significant advances have been achieved in the fuel cell technology
and the applications of different types of fuel cells.
Environmental concerns and world-wide social and political pressure to
reduce carbon dioxide emission, and the desire to seek higher energy
conversion efficiencies in electrical power generation, have been the main
drivers for fuel cell technological advances and their applications,
including distributed power generation and fuel cell vehicle applications.
Electrical power producers are seeking ways to gain competitive position
in the deregulated power market by contributing to reduced environmental
emissions. In addition, as a part of the requirement to pursue technologies
to reduce carbon emissions, the automobile industry has started FC vehicle
development with the ultimate goal of reaching zero-emission car.
The operation of fuel cells, being based on electrochemical principles, is
normally better understood by scientists (i.e., chemists, physicists, and
material scientists) and chemical engineers working in this area. Since the
end product of fuel cells is electricity, their operation also needs to be
understood by electrical engineers working in the area to be able to design
interfacing electrical circuits and controllers to achieve their improved
performance. For this reason accurate and user-friendly dynamic fuel cell
models are needed to evaluate their steady-state and transient performance
xiii
xiv PREFACE
from electrical engineering. This book bridges the gap between the two
groups, namely scientists/chemical engineers and electrical engineers. It
explains the principle of operation of fuel cells in a simple language
understood by electrical engineers. It also explains the development of
physically-based dynamic models for PEM fuel cells (PEMFCs) and
tubular solid-oxide fuel cells (SOFCs), which have great potential for
distributed generation (DG) and mobile applications. The main focus of the
book, however, is on modeling, control and applications of the above two
types of fuel cells. PEMFCs are suitable for residential and backup power
as well as DG and FC vehicle applications. SOFCs are high-temperature
fuel cells suitable for DG and combined heat and power (CHP) operation to
achieve high system energy efficiency.
This book is the result of over 10 years of research on PEMFC and
SOFe. It combines the theory, modeling, interfacing, and control of FC
systems in one place. The book is intended to be a resource for all
engineers, in particular, electrical, chemical, and mechanical engineers,
and for all those interested in designing controllers and interfacing circuits
for FC energy systems and FC vehicles of the future. An overview of the
chapters covered in the book is given below:
Chapter 1 gives a brief history of U.S. electric utility formation and
background about the restructured utility that leads to increased interest in
DG. Then, an overview of DG and its different types, DG applications of
FCs, an introduction to hydrogen economy, and a need for a FC-powered
society are covered.
Chapter 2 gives a brief coverage of electrical and thermal energy,
fundamentals of thermodynamics, and electrochemical processes, which
have lead to the operation of FCs. The of operation of major
types of FCs and electrolyzer are also covered.
Chapters 3-5 cover the modeling of PEMFC, tubular SOFC, and
electrolyzer, respectively. The development of a physically-based dynamic
model and equivalent electrical circuit model for PEMFC and PEMFC model
validation are given in Chapter 3. Chapter 4 covers the development of a
physically-based dynamic model for tubular SOFC under different operating
conditions. The process of water electrolysis and electrolyzer modeling are
introduced in Chapter 5. The emphasis in these chapters is on the electrical
terminal characteristics of PEMFC, tubular SOFC, and electrolyzer.
An introduction to and modeling of power electronic switching devices
and circuits for FC energy systems is given in Chapter 6. Power electronic
(power conditioning) devices are important and integral part of FC systems
to obtain conditioned electricity output with desired power quality. The
PREFACE XV
M. HASHEM NEHRIR
CAISHENG
Bozeman, Montana
Detroit, Michigan
January 2009
ACKNOWLEDGMENTS
The authors would like to thank many people and organizations that helped
them in the preparation of this book; without their help and support this
book would not have been possible.
We are most grateful to Dr. Don Pierre, Professor Emeritus of Electrical
& Computer Engineering (ECE) Department at Montana State University
(MSU) for his invaluable suggestions and very careful editing and proof
reading of nearly the entire book. We also acknowledge the fruitful
discussions we had with Dr. Steven Shaw of MSU ECE Department during
the course of our research.
Dr. Paul Gannon of the MSU Chemical & Biological Engineering
(CBE) Department contributed in the writing of Chapter 10 (Present
Challenges and Future of Fuel Cells). His knowledge on fuel processing,
internal operation of fuel cells and the challenges involved in bringing fuel
cells into widespread use helped us bring this book to completion.
Mr. Chris Colson, currently a Ph.D. candidate in the MSU ECE
Department contributed to the hybrid operation and efficiency evaluation
of SOFC in combined heat and power mode. His previous work in this area
co-authored by the authors of this book, as well as Professor Emeritus Max
Diebert of MSU CBE and Professor Ruhul Amin of MSU Mechanical &
Industrial Engineering, is used as an example in Chapter 9. Mr. Colson also
helped in editing a portion of the book, for which we are thankful.
During the course of our research, we made many presentations at
technical conferences on the modeling and control of PEMFC and SOFC.
xvii
xviii ACKNOWLEDGMENTS
We are thankful to the many people who made constructive comments and
suggestions to us after attending our presentations. Their comments helped
us enrich the contents of this book.
We acknowledge the financial support provided by the following
agencies for work related to the contents of this book: Montana DOE
EPSCoR (1994-2001), Montana NSF-EPSCoR (1998-2000), U.S.
National Science Foundation (Grant 0135229, 2002-2006), and the High
Temperature Electrochemistry (HiTEC) Fuel Cell Project at MSU, funded
by the U.S. Department of Energy, as a subcontract from Battle Memorial
Institute and Pacific Northwest National Laboratory (Award DE-AC06-
76RL01830, 2002-2008).
Hashem Nehrir is thankful to MSU for providing him with the release
time (sabbatical leave) for the preparation of the first draft of the book. He
is also thankful to the MSU ECE Department for its institutional support
and encouragement.
We would like to thank the following fuel cell companies for providing
photos of their products for this book: Ballard Power Systems, FuelCell
Energy, ReliOn, Siemens, Versa Power Systems, and Hydrogenics Corp.
We are thankful to Drs. Rama Ramakumar of Oklahoma State
University, Oklahoma and Kai Strunz of University of Berlin,
Germany for their careful review of the book; their constructive comments
and suggestions made the book more comprehensive. We are also thankful
to the staff of IEEE Press-Wiley and Thomson Digital for their dedication
to this book project.
Last but not least, we are thankful to our families for their
and support during the course of development of this book.
M.H. N.
C. W.
CHAPTER 1
INTRODUCTION
Modeling and Control of Fuel Celis, By M. Hashem Nehrir and Caisheng Wang
Copyright © 2009 The Institute of Electrical and Electronics Engineers, Inc.
1
Discovering Diverse Content Through
Random Scribd Documents
SPEECHES AND PAPERS ON THE
ABOLITION OF PATENTS.
The following petition, which Mr. Macfie had the honour to present,
contains the motion which gave occasion for the speeches that form
the principal part of this compilation:—
So Tyndal—
Mark from the words of Justice Buller, on the same occasion, the
sentiment which was permitted to prevail and neutralise the statute:
—
We come to C. J. Eyre:—
“According to the letter of the statute, the words ... fall very
short ... but most certainly the exposition of the statute, so far
as usage will expound it, has gone very much beyond the
letter. ‘A deliberate surrender,’ comments Mr. Coryton, ‘of
judicial power in favour of an accumulation of popular
errors.’... Later judges, following in the same course, have
striven rather to regulate the inconsistencies they found, than
to address themselves to the cause and thus prevent the
possibility of their recurrence. Writers on this subject have on
this head followed in the course indicated by the Bench.”
In England
England. Scotland. Ireland. for the
Colonies.
In 1650—None.
1700 2
1750 7
1800 96 13 2 6
1825 250 62 33 87
1850 523 227 531 191
1866 2,121 2,121 2,121 none
1867 2,292 2,292 2,292 none
The House will observe that the complaint here is not that we were
hurt in British markets—for these the protective system of duties
closed—but that we lost our hold of foreign markets.
Sir Mark Isambard Brunel, the eminent engineer, told the
Committee of 1829:—
Again:—
Mr. J. S. Russell, who himself has taken out a good many Patents,
speaks more specifically:—
“There are a great many Patents of that kind taken out for
boilers of steam-engines, and boilers of steam-engines admit
of a very enormous variety of shape and proportion without
damaging their efficiency.... The consequence is, that I have
not defended any of my own. I have never made of mine
more than a mere registry of priority of invention. I have not
made mine a source of money, but I have suffered in this way
from Patents: I have gone on, in the course of my business,
doing my ordinary work, and I have found other people taking
out Patents for what I was doing without calling it an
invention, and then prosecuting me under the Patent they had
taken out for my own inventions, and it appears that there is
nothing to prohibit them from doing that.”
“If you were able to prove that you had been carrying on an
invention, whatever it might be, at the time when the person
claiming to hold a Patent for it took out his Patent, would not
that relieve you from all difficulty in the matter?—It would only
give me the pleasure of defending a law-suit.”
Our website is not just a platform for buying books, but a bridge
connecting readers to the timeless values of culture and wisdom. With
an elegant, user-friendly interface and an intelligent search system,
we are committed to providing a quick and convenient shopping
experience. Additionally, our special promotions and home delivery
services ensure that you save time and fully enjoy the joy of reading.
ebookfinal.com