ABHISHEK, VINAY & ARUN’S CHEMISTRY PVT- TUTORIALS

ABHISHEK SIR: 9833395472 VINAY SIR: 9867442504 ARUN SIR: 9870577035

“Where every student matters and every moment counts”
09-03-2025 PRELIM TEST – 11 Marks: 180
Standard: Time: 60 Min
XII – NEET TOPIC – FULL PORTION XI (HINTS AND SOLUTIONS)

Non-attempt Wrong question Total marks

/180

51) For single electron species the energy depends

upon principal quantum number ‘n’ only. α 2C 0.01
60) K= ,= <<<1
1-α 100
52) Based on n + l rule. For equal values of n + l,
 K =  2C
lower value of n has less energy. 2
 0.01
= ×1
53) The first ionization energies (as in NCERT) are  100 
as follows: = 1 × 10–8.
B: 801 kJ/mol Al: 577 kJ/mol
Ga: 579 kJ/mol Ga: [Ar]3d104s24p1 62) Moles of O2 used up = 25% of 4 = 1mol.
2SO2 + O2  2SO3
54) Neon has a very high electron gain enthalpy Initial moles 4 4 0
(almost zero). Moles at eqm. 4 – 2 4–1
Chlorine has a negative electron gain enthalpy but =2 =3 2
less negative than that of Fluorine. Therefore total number of moles of all gases at
eqm. = 2 + 3 + 2 = 7
56) Both are bent in shape. Bond angle of SO2 (sp2)
is greater than that of H2O (sp3) due to higher 64) – C = O is –R and –OH is +R
repulsion of multiple bonds.
PT
A
V
A

66) For statement (III), fluorination is too violent

to be controlled. For statement (IV), iodination is
very slow and reversible reaction. It can be carried
out in the presence of oxidizing agents
like HIO3 or HNO3.
57) (A) q + w = U  definite quantity CH4 + I2 CH3I + HI
(B) q → Path function 5HI + HIO3 → 3I2 + 3H2O.
(C) w → Path function
(D) H – TS = G → State function 67) (IV) Markovnikov’s rule is followed by
unsymmetrical alkenes.
58) U = q + w (V) Acetylene is more acidic, presence of
U = (–2kJ) + (+10kJ) sp C – H bond.
U = –2 + 10 = +8 kJ

59)

70) Since Ni is oxidized (from 0 to +2), it is the

reducing agent in this reaction.

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 ABHISHEK, VINAY & ARUN’S CHEMISTRY PVT- TUTORIALS
ABHISHEK SIR: 9833395472 VINAY SIR: 9867442504 ARUN SIR: 9870577035
“Where every student matters and every moment counts”
71) 81)

82) Sn2+ → Sn4+ + 2e–

83)
- +
72) A = HC  CNa
B = HC  C – CH3,
+-
C = Na c  C – CH3,
D = CH3 – CH2 – C  C – CH3 More s-character of orbital, orbital closer to
nucleus, higher electron affinity of half-filled
74) orbital, lesser stability.

84) 3o > 2o > 1o carbocation stability order (SN1)

III > II > I

88) Q > Kc  Concentration of products is more,

equilibrium shifts backward by Le-Chatelier’s
principle.

89) – CHO gets priority over –CO–

75) IV = + R effect of – OCH3 A

V
A
PT
92) The entropy change can be calculated by using
I = no destabilising effect the expression
III = –I effect of –Cl qrev
II = strong -I effect of –NO2 S =
T
When water freezes in a glass beaker, S (system)
77) SO2 + 2H2S → 2H2O + 3S decreases because molecules in solid ice are less
Here H2S is the limiting reactant random than in liquid water. However, when
2 mol of H2S give 3 mol of S water freezes to ice heat is released to the
 1 mol of H2S gives 3/2 mol of S. surrounding, entropy of the surrounding increases.
78) 4
93) 4g He = = 1 mol = NA atoms.
4
46
46g Na = = 2 mol = 2NA atoms.
23
0.40
0.40g Ca = = 0.01 mol = 10–2 NA atoms.
79) 40
12
12g He = = 3 mol = 3NA atoms.
4

95) The first element boron acts a non-metal and

hence the oxide formed from boron that is B2O3, or
boron trioxide will be acidic in a nature.
80) 0.05 M dibasic acid gives 0.1 M H+
PH = – log [H+]
= – log 10–1
PH = +1

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 ABHISHEK, VINAY & ARUN’S CHEMISTRY PVT- TUTORIALS
ABHISHEK SIR: 9833395472 VINAY SIR: 9867442504 ARUN SIR: 9870577035
“Where every student matters and every moment counts”

ANSWER KEY
51 – 1 52 – 2 53 – 4 54 – 2 55 – 3 56 – 1 57 – 3 58 – 1 59 – 3-4 60 – 1
61 – 2 62 – 2 63 – 1 64 – 2 65 – 4 66 – 2 67 – 4 68 – 3 69 – 1 70 – 2
71 – 4 72 – 3 73 – 1 74 – 1 75 – 2 76 – 1 77 – 3 78 – 4 79 – 4 80 – 1
81 – 2 82 – 1 83 – 4 84 – MTA 85 – 4 86 – 2 87 – 1 88 – 2 89 – 2 90 – 2
91 – 2 92 – 3 93 – 4 94 – 1 95 – 2

PT
A
V
A