Explosive
Explosive
Primary Explosives
Low Explosives
High Explosives
CLASSIFICATION
EXPLOSIVES
PRIMARY SECONDARY
Primary Explosives
• Initiating explosive detonators
• Their highly sensitive explosives who is explode on receiving a slight
shock or by fire
Examples are:
• lead azide
• Mercury fulminate
• Tetracene
• Diazo dinitro phenol
• Silver Azide
Low Explosives
• They simply burn and do not explode suddenly
• The chemical reactions taking place in such explosives are comparatively
slow and their burning proceeds from the surface inward in layers at an
approximate rate of 20 cm per second.
• Potassium Nitrate (KNO3) +charcoal +sulfur(75:10:15)- Gun Powder
• Sodium nitrate + charcoal + sulfur
• Potassium Chlorate+ sulfur
• Potassium Chlorate +Arsenic sulphide +sulfur
• Potassium Chlorate + Sulphuric Acid
High explosives (HE)
• High explosives (HE, or high order explosives) are explosive materials
that detonate, meaning that the explosive shock front passes through
the material at a supersonic speed. High explosives detonate with
explosive velocity of about 3–9 kilometres per second For instance, TNT
has a detonation (burn) rate of approximately 6.9 km/s, detonating cord
of 6.7 km/s (22,000 feet per second), and C-4 about 8.0 km/s (26,000
feet per second). They are normally employed in mining, demolition,
and military applications. The term high explosive is in contrast with the
term low explosive, which explodes (deflagrates) at a lower rate.
• Countless high-explosive compounds are chemically possible, but
commercially and militarily important ones have included NG, TNT, TNP,
TNX, RDX, HMX, PETN, TATP, TATB, and HNS.
DIFFERENCE BETWEEN LOW AND HIGH EXPLOSIVE
LOW HIGH
1. LESS SHATTERING EFFECT 1. MORE SHATTERING EFFECT
2. WIDE DIAMETER CRATER 2. SMALL DIAMETER BUT DEEPER
3. GRADUAL SLOPING 3. SLOPE VERY STEEP
4. BIGGER FRAGMENTS 4. SMALLER FRAGMENTS
5. INTENSE HEAT EFFECT, LITTLE OR 5. SEVERE BLAST EFFECT
MODERATE BLAST EFFECT 6. INDEPENDENT OF CONFINEMENT
6. DEPENDENT ON CONFINEMENT 7. CUTTING EFFECT
7. BENDING EFFECT 8. Detonation
8. Deflagration
Industrial Explosives: Nitroglycerin and Dynamite
H2SO4
+ 3 HNO3 + 3H2O
Industrial Explosives: Nitroglycerin and Dynamite
❑Nitroglycerine is a poisonous heavy oil and is highly sensitive to shock.
It explodes very violently on detonation. to make nitro- glycerin easier
and safer to handle it is usually manufactured into dynamite.
❑Original dynamite was a mixture of 75% nitro glycerin and 25%
kieselguhr (a porous siliceous earth). Modern dynamites use wood flour,
Ammonium Nitrate or sodium nitrate as the absorbing agent for
nitroglycerine. An oxidizer is also added sometimes.
❑ Dynamite is easy to handle. it is high explosive used for rock blasting
and Gold mining. A jelly like mixture of 7 to 8% nitrocellulose and 92-93%
nitroglycerine is an exceptionally powerful high explosive commonly
known as gelatin dynamites or blasting gelatin. It can also be handled
safely.
Military explosives: TNT
2,4,6- trinitrotoluene in commonly known as TNT has become the principal
military explosive since 1920.
I. It is most widely used explosive because of its economic and safe
preparation process
II. Low sensitivity to impact
III. High explosive power,
IV. Comparatively low toxic effects and its low melting point (80.8℃).
It is manufactured by three stage Nitration of toluene with mixed acid.
Military explosives: TNT
Military explosives: Picric Acid
Explosive Emulsions
• Nipak: Amonnium nitrate + Sodium
nitrate+microballons+nitromethane+polyurethane+carbon
tetrachloride
Pyrotechnics
• Art of firework
• Signaling
• Illumination
• Smoke
• Incendiary effect
USE OF EXPLOSIVES
• MILITARY PURPOSE
• CIVIL ENGINEERING
• MINING
• AGRICULTURE
DETONATORS
• ELECTRICAL DETONATOR
• Explosive
• Detonators
• Power Sources
• Switches
Nitrocellulose