ilovepdf_merged (1)
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14. The magnitude of CFSE (crystal field splitting complex, ∆0) can be related to the configuration of d-
orbitals in a coordination entity is
a) if ∆0 < P, the configuration is t32ge1g b) if ∆0 > P, the configuration is t32ge1g
c) if ∆0 > P, the configuration is t22ge2g d) if ∆0 < P, the configuration is t42ge0g
NaNO 2 + HCl B
A
0-5oC
(3+2)
45. The rate of a reaction quadruples when the temperature changes from 293 K to 313 K. Calculate the
energy of activation of the reaction assuming that it does not change with temperature.
46. A reaction is first order in A and second order in B.
(i) Write the differential rate equation.
(ii) How is the rate affected on increasing the concentration of ‘B’ three times and decreasing the
concentration of ‘A’ by two times?
(iii) How is the rate affected when the concentrations of both ‘A’ and ‘B’ are tripled?
a) b)
c) d)
7. An ambidentate ligand is
a) Cl– b) CN–
c) OH– c) NO +2
8. The Eo of Fe2+/Fe, Zn2+/Zn and Sn2+/Sn are –0.44 V, –0.76 V and –0.14 V respectively. Which
metal/s is/are act as sacrificial electrode to protect iron from rusting?
a) Both Zn and Sn b) Zn only
c) Sn Only d) neither Zn nor Sn.
9. The chemical name of phosgene is
a) chromyl chloride b) triphenylphosphine
c) phosphorusoxychloride d) carbonyl chloride.
10. In a solution containing non-volatile solute, the mole fraction of solvent is 0.9. The relative lowering
of vapour pressure is
a) 1 b) 0.1
c) 0.9 d) 1.1
11. All natural and artificial radioactive decay of unstable nuclei take place by
a) zero order kinetics b) half order kinetics
c) first order kinetics d) second order kinetics
12. Match the following
List-I List-II
A) Glucocorticoids i) Responsible for development of secondary female characteristics.
B) Mineralocorticoids ii) Responsible for preparing the uterus for implantation of fertilised egg
C) Testosterone iii) Control carbohydrates metabolism
D) Estradiol iv) Responsible for development of secondary male characteristics.
v) Control level of excretion of water and salt by kidney.
a) A-(iv), B- (v), C-(ii), D-(i) b) A-(iii), B-(v), C-(iv), D-(i)
c) A-(ii), B-(i), C-(v), D-(iv) d) A-(iii), B-(ii), C-(iv), D-(i)
13. p-Aminoazobenzene is prepared from benzenediazonium chloride and aniline in
a) acidic medium b) basic medium
c) neutral medium d) both acidic and basic medium.
60
PE (KJ)
R
20
P
5
Time
By observing the above diagram, answer the following.
a) What is the value of activation energy of the reaction?
b) What is the value of ΔH of the reaction?
c) Draw potential energy diagram for the reaction P(g) → R(s).
33. State Faraday’s II law of electrolysis. Mention any two factors which determines the product of
electrolysis.
34. Name the two components present in binary solution. Which component determines the physical
state of binary solution?
PART-D
VI. Answer ANY FOUR of the following. Each question carries five marks. 4 × 5 = 20
35. a) How do you distinguish between primary, secondary and tertiary amines by using Hinsberg’s
reagent with chemical equations involved?
b) Give the preparation of p-hydroxyazobenzene. (3+2)
36. a) Between methanal and ethanal, which would undergo aldol condensation? Write the
chemical reaction involved in it.
b) Although phenoxide ion has more number of resonating structures than carboxylate ion,
carboxylic acid is a stronger acid than phenol. Why? (3+2)
37. a) What is peptide bond? Give an example for dipeptide.
b) What are oxidoreductase enzymes? Name the enzyme that catalyses hydrolysis of
maltose into glucose
c) Give any one main natural source of Vitamin K? (2+2+1)
38. a) Complete the following equation:
H CH3
i) HBr
H H
Na
ii) dry ether
Cl
44. Henry’s law constant for the molality of methane in benzene at 298 K is 4.27 × 105 mm Hg.
Calculate the mole fraction of methane in benzene at 298 K under 760 mm Hg.
45. Two electrolytic cells A and B containing solutions of AgNO3 and CuSO4 respectively are
connected in series. A steady current of 1.5 amperes was passed through them until 1.45 g of silver
is deposited at the cathode of cell A. How long did the current flow and What mass of copper was
deposited? [Atomic mass of copper = 63.5 and silver = 108].
(1.28 103 )K
46. The rate constant of a reaction is given by: log k = 13.25 − . Calculate the activation
T
energy and pre-exponential factor (A).
PART – F
(For visually challenged students only)
32. Give any three factors which affect a rate of reaction. 3
II. Fill in the blanks by choosing the appropriate word from those given in the brackets:
(SN2, instantaneous, phosphodiester, CHCl3, glycosidic, Yb2+,) 5 × 1 = 05
16. During Surgery, ____________ was used as anesthesia
17. The rate at a particular moment of time is expressed as ___________ rate of reaction.
i. CHCl3, NaOH
A
ii. H+
PART-C
IV. Answer ANY THREE of the following. Each question carries three marks. 3 × 3 = 09
26. Using abbreviations of following ligands, identify the number of donor sites and write the formula of
each ligand. a) en b) EDTA c) PPh3
27. Write the equations for the preparation of potassium permanganate from pyrolusite ore, what is the
colour of KMnO4 crystals?
28. Using Valence Bond Theory [VBT], explain geometry, hybridisation and magnetic property of [CoF6]3–
ion. [Atomic number of Cobalt is 27].
29. Give any three applications of coordination compounds.
30. Transition elements have higher enthalpy of atomization. Give two reasons. Among 3d and 4d series
of transition elements, which series has higher enthalpy of atomization?
V. Answer ANY TWO of the following. Each question carries three marks. 2 × 3 = 06
31. What does P and ZAB represent in the equation: Rate = PZABe− Ea /RT ? Name a factor on which Z depends.
32. Name the fuel cell used in Apollo space programme and write its anodic and cathodic reaction.
33. Give any three differences between ideal and non -ideal solutions.
34. Mention any three thermodynamic properties determined by using electrochemical cells.
PART-D
VI. Answer ANY FOUR of the following. Each question carries five marks. 4 × 5 = 20
35. a) Write the reactions involved in the conversion of toluene to m-nitrobenzoic acid.
b) The pKa values of acetic acid, benzoic acid and trifluoroacetic acid are 4.76, 4.19 and 0.23
respectively. Arrange them in the increasing order of acid strength. Justify the arrangement. (3+2)
36. a) Write the mechanism involved in the conversion of 2-bromo-2-methylpropane to
2-methylpropan-2-ol.
b)What are enantiomers? Name one physical property which differs enantiomers. (3+2)
37. a) Give the mechanism involved in the acid catalyzed hydration of C2H4 to C2H5OH. (3+2)
b) Name the enzyme involved in fermentation of glucose into ethanol and write its chemical equation.
b) Name any one biologically active amino compound used in the following:
(i) to increase blood pressure (containing secondary amino group)
(ii) as an anaesthetic in dentistry (a synthetic amino compound) (3+2)
40. An organic compound (X) with molecular formula C8H8O forms an orange-red precipitate with 2,4-
DNP reagent and gives yellow precipitate on heating with iodine in the presence of sodium
hydroxide. It neither reduces Tollens reagent nor does it decolourise bromine water. On oxidation
with chromic acid, ‘X’ gives a carboxylic acid (Y) having molecular formula C7H6O2. Identify the
compounds (X) and (Y) and write all the reactions involved. 5
PART–E
(NUMERICAL PROBLEMS)
VII. Answer ANY THREE of the following. Each question carries three marks. 3 × 3 = 09
41. Calculate the molality of 20%(w/v) aqueous solution of KI. Given density of aqueous solution of
KI = 1.2gcm–3. Molar mass of KI = 166gmol-1.
42. Vapour pressure of water at 293K is 17.535 mm Hg. Calculate the vapour pressure of water at 293K
when 25 g of glucose is dissolved in 450 g of water.
43. Calculate the emf of the following cell and state whether the cell is feasible or not?
Pt (s)| Br– (0.01M) | Br2 (l) || H+(0.03M) | H2 (g) (1bar) | Pt(s) Eo(½Br2|Br–) = 1.09V.
44. Calculate the limiting molar conductivity of Cl– by using the data Ʌo for
CaCl2 = 271.6 S cm2 mol–1 and λ0 for Ca2+ = 119.0 S cm2 mol–1.
45. The rate constant for a reaction is 60 s–1. How much time will it take to reduce the initial
concentration of the reactant to its 1/16thvalue?
46. In the given reaction A→B, the rate constant k is 2.0 x 10–2 lit mol-1s-1, find initial rate of reaction
when [A] = 0.5 M at 298K.
1. All PARTS (A to D) are compulsory. PART-E is only for visually challenged students.
2. For PART – A questions, first written-answer will be considered for awarding marks.
3. Answers without relevant diagram / figure / circuit wherever necessary will not carry any marks.
4. Direct answers to numerical problems without relevant formula and detailed solution will not carry
any marks.
PART – A
I. Pick the correct option among the four given options for ALL of the following questions: 15 × 1 = 15
1. The SI unit of surface charge density is __________ .
(A) C m–1 (B) C m–2 (C) C m–3 (D) kg m–3
2. The values of electric field (E) and electric potential (V) at any point on the equatorial plane of an electric
dipole are such that
(A) E = 0, V = 0 (B) E = 0, V ≠ 0 (C) E ≠ 0, V = 0 (D) E ≠ 0, V ≠ 0
3. If the potential difference across a capacitor is doubled, then the energy stored in it
(A) is doubled (B) is quadrupled (C) is halved (D) remains same
4. A wire has a non-uniform cross-sectional area as shown in the figure. A steady current I flows through
it. Which one of the following statements is correct?
(A) The drift speed of electron is constant.
(B) The drift speed of electron increases while moving from A to B.
(C) The drift speed of electron decreases while moving from A to B.
(D) The drift speed of electron varies randomly.
5. A charged particle of charge q is moving in a uniform magnetic field. The angle between the velocity(v)
of the charged particle and magnetic field(B) is . The trajectory of the charged particle varies with
angle . Match the following table by choosing the appropriate trajectory traced by the charged particle
for different possible values of angle .
Angle Trajectory
(i) = 0o
(a) circle
(ii) = 45o (b) straight line
(iii) = 90o (c) helix
(A) (i) – (a) , (ii) – (b), (iii) – (c) (B) (i) – (b) , (ii) – (c), (iii) – (a)
(C) (i) – (b) , (ii) – (a), (iii) – (c) (D) (i) – (c) , (ii) – (b), (iii) – (a)
PART – E
(FOR VISUALLY CHALLENGED STUDENTS ONLY)
4. A wire has a non-uniform cross-sectional area in which end A of the wire has smaller
area than that of end B. A steady current I flows through it. Which one of the following
statements is correct?
(A) The drift speed of electron is constant.
(B) The drift speed of electron increases while moving from A to B.
(C) The drift speed of electron decreases while moving from A to B.
(D) The drift speed of electron varies randomly.
***********
(A) (i) - (b), (ii) - (c), (iii) - (a) (B) (i) - (c), (ii) - (b), (iii) - (a)
(C) (i) - (a), (ii) - (b), (iii) - (c) (D) (i) - (c), (ii) - (a), (iii) - (b)
44. A series LCR circuit contains a pure inductor of inductance 5 H, a capacitor of capacitance 20 µF and
resistor of resistance 40 Ω. If the AC source of 200 V, 50 Hz is present in the circuit, find the
impedance. Also find the resonant frequency of the circuit.
45. An object is placed at a distance 0.3 m from a convex lens of focal length 0.2 m. Find the position and
nature of the image formed. Also find the distance through which the object should be moved to get an
image of linear magnification ‘-1’.
Column-I Column-II
(i) conductors (a) 𝐸 < 3 𝑒𝑉
(ii) insulators (b) 𝐸 = 0 𝑒𝑉
(iii) semiconductors (c) 𝐸 > 3 𝑒𝑉
(A) (i) - (a), (ii) - (b), (iii) - (c) (B) (i) - (b), (ii) - (a), (iii) - (c)
(C) (i) - (c), (ii) - (a), (iii) - (b) (D) (i) - (b), (ii) - (c), (iii) - (a)
PART – B
III. Answer any FIVE of the following questions: 5 × 2 = 10
21. State and explain Gauss’s law in electrostatics.
22. Define drift velocity and mobility of free electrons in conductors.
23. A long air-core solenoid of 1000 turns per unit length carries a current of 2 A. Calculate the magnetic
field at the mid-point on its axis.
24. Give the principle of AC generator. Why is a current induced in an AC generator called alternating
current?
25. Write any two uses of ultraviolet radiations.
26. Name the objective used in
a) refracting type telescope and
b) reflecting type telescope.
27. Write the two conditions for the total internal reflection to occur.
28. Name the majority and the minority charge carriers in n-type semiconductor.
PART – C
37. Derive the expression for the electric field at a point on the axis of an electric dipole.
38. Two cells of different emfs and different internal resistances are connected in series. Derive the
expression for effective emf and effective internal resistance of the combination.
39. Derive the expression for the magnetic field at a point on the axis of a circular current loop.
40. a) Two coherent waves of a constant phase difference undergo interference. Obtain the expression for
the resultant displacement. (3)
b) Write the conditions for constructive and destructive interference in terms of phase difference. (2)
41. What is a rectifier? Explain the working of a full-wave rectifier using a neat circuit diagram.
Draw its input-output waveforms.
VI. Answer any TWO of the following questions: 2 × 5 = 10
42. a) Calculate the potential at point P due to a charge of 400nC located 9 cm away.
b) Obtain the work done in moving a charge of 2nC from infinity to the point P. Does the answer
depend on the path along which the charge is moved?
43. In the following network, find the current I3.
44. An AC source of frequency 50Hz is connected in series with an inductor of 1H, a capacitor of 90µF and
a resistor of 100Ω. Does the current leads or lags the voltage? Calculate the phase difference between
the current and the voltage.
45. An equilateral prism is made of glass of unknown refractive index. A parallel beam of light is incident
on a face of the prism. The angle of minimum deviation is 40º. Find the refractive index of the material
of the prism. If the prism is placed in water of refractive index 1.33, find the new angle of minimum
deviation of a parallel beam of light.
*****