0% found this document useful (0 votes)
60 views

class_12_coordination_compounds_Topper's_handwritten_Notes?

The document discusses coordination compounds, detailing their types, valency, and geometric arrangements. It explains the roles of ligands, including monodentate and polydentate ligands, and describes the characteristics of coordination entities. Additionally, it covers naming conventions and the importance of central atoms in coordination chemistry.
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF or read online on Scribd
0% found this document useful (0 votes)
60 views

class_12_coordination_compounds_Topper's_handwritten_Notes?

The document discusses coordination compounds, detailing their types, valency, and geometric arrangements. It explains the roles of ligands, including monodentate and polydentate ligands, and describes the characteristics of coordination entities. Additionally, it covers naming conventions and the importance of central atoms in coordination chemistry.
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF or read online on Scribd
You are on page 1/ 18
JEE, Neet & Boards Coordination Compounds | telegram:- litjeeneetnotess+ > |__ x Coordination Compounds. | chioxophyit - mg ul Hoemagiabin= Fe Vitamin Biz Co | Wernen's Theany- | 4 |l# Postuntes of wexnex theaxy |) metals have 2 types af valency |i} Pima varency | = Coxigaton no, ionizabe Satisfied by -ve Wand. | non-dixectional) > ola 3 I Cotlz 42 i Pdelz > 2 _1i) Secandaxy Valen ey 4 —_—_Change._heutral_dixectiona . gives definite geometxy — = Cocls: bits [CocNtisls] Cy —> Fmnl Agel Yellow _ cocts- Sina [Co (NHalsciicl: —> amo! Agel Piso Coca - YNH3 CCo (Nis) 4Cl2] Cl— > } mar Agel Giveen>— —Coci3: YNH3 CCOCNHs)yCh2) cl > 1 mot Agel _wisiess- vas yr | aes . 77 _ telegram:- iitjeeneetnotess = el _cocndination_polybedea ~ ion Gxovp bonded by Secondary — gg iokge lth cessor have_diffevent_Spatial _agsangement Called Coaadination_polyhedaa. ee “| fe finan TT octahetat oT ‘Gq: pionat 45 plana [fcoCwns)sJ*3 > octahedsal ny Ci (cobs > tetrahedxal is ] 0 | Ni * Pec t = sq: planoy hei “co a ey | ca teed i “pe } ! Paes Fa |coxdination entity Species inside sq bracket Couniey ion —> Outside she sq- braked | N +P iL inati ‘om 4 —__Dovble salt: when dissolved in tates - Completely breaks __- ! down into _jons 4 i KCl. MgCl2 = 6H20._kexnalite: I FesOu- (NHu2 SOu- 6H20 _Maby's_salb s k2S0y: Al2(SO4)3 +24 H20_ _ Potash Alum 4 K AL (Sou)2 +1220 4 4 —Cosdination comp tahich_do_n ot dissociate compicigy fois Be . Ku [Fe ccw)o) 2s 4 kt + ( Fe Cel" ___y :— See ee i / [co (WH3)3.Cl3 J | EN (co)4 J | IBS / (lewis acid) by cordingie hand in a definite geameay I Inside co%dination enbity CNI Cle (Hao)yy > wite | co tei) (NHa)s] > cots |'3) Ligand ion/ molecule banded ta Centsal atom throu: | Cemnis base) Caxdinate band Ip Coxdination entity. I 2 it ae I SM gone AH ge é _-bnidentate > Single donox_atom= Crs H20, NH fF", OK, 0% Vos*, Go. WHE NAP, NS) Nao || Pesoxido Soper Amice Imi Hivow @ldo 1 1 i 1 | Didentate- tino donox atom @ eh - etbuylenediammine Cethane_ ir? - diammtne) NH2~ ClHa= CHa = NH ® Pp - propylene diamine ___PdOpane 1,2- diammine a NHo= CHo ~ CH_=NH pS eee CHG | 6 _bn- botylenediarmine Bovlane .3- drammine Hon - CH ~ SH Mtl city Cas ii Lt Te i | pare! —'—) telegram:- iitjeeneetnotess ) Y | polydent Ode ‘Gevexal « donax_¢ atom. pee aa . eT (EDTA A)"4 ethylene diamminetetraacetate 4 wee . iio eae eee Be l “o-c- Che cHa-< 0" HI 5 i N- CH2- CH2-N y | O -c-Hee CHet= CU oF . | i § donax atom a * Hexaden 40+. 7 ~4 Charge | NH2- CH2~CHe ~NH ~CHa= Cle ~NHe fo tridentar \ tyien- NH2-CH2- CH2~ NH CH2- CH ~NH- CH2~ CH2- NH Chelate ligand did _membea iting afiex donation (stable) 7 l 7 z z cm [en Nh2-CH2- CHa-NH2 _dien- Nila CHa = CHa NACH Gp | L cae 16 | Me as M Me i \d-_ihich_can donate thxoigh_2_di¢t gy — | Soon | a 9s-cayi | 6 [co ten) 3] — 6 ig | Fe c¢20x)3] 6 Ci CNH) u) > if 1 digentate Je | Co%d ination_sphexe set (Fe¢on) 6 i l V. a ne Caxdi nation entity | (onizattan Sphexe cae 0% coxdinaton h Spheye Sphere eran 7 _ ; 5 { ed'stsith lone spade se [cocen) 4} -3-5 ieee [co (en)3]*3 <3 | CCo( Ws) c}t3 > (3)-C 6x0) = CFe (Eoray 7+ ca). Cet Cl (NH Jot > (9) cee | CFe Cc20u)s 173 > (=3)~ (4) = 33 i L _Homoaleptic- ony ane type Of Ligand » [co _(Wit)¢ ]5~ “Helene Mmoxe than _one type of Ligand ~ Ceo (NHa)y C12}t > —telegram:—jit}eeneetnotess __~ | uit_Achater {pare ih CL pee Effective MOmic. Dombe_ (EAN) nooks €~_ON__Cenxal_mMetal_qlar fox ming coxdinared bane with \igana i 1 ______| leans 2-OSt2xcnl Ls Cie Cane © DIG DS kes het te [ko Cfetais]—b2¢-942xesg5 0 a | ichs - N_Of meio} _Casbonyl_is equal | 49 Gtomic_no- of neaxest inext gas_then_thal_meta { Caxbanty fs" Staple { n(co)s] > 25-0 tars =35 L_Lmn Cco) 9)" > _25-(-1) 2x5 = 36 > Stabe t Mn (cols —> EAN > 25-04 2x6 = 379 @* “B85 | Cén (cole]t > FAND 25~1 + 2x6 = 36 > sfable i |Q@) vco)¢ > 23-0 +12 =35 te" = 3¢ (yCco)ed- > 23- (+1) +12. =36 » Sigble EAN > ajomoft 90: OF next gas > Redivcing agent “2 alinomentionme sdomu een. we eta Roles fox Uaiting Foxmule- > identify central_atom >write ti phabatical_Oxder : ~S abhievint2a_ligand »consider_tins-+_Letter_ For slehahgy ~~ tuxite fosmpta_in_sq bracket ————_———— ~~ no space bei ligand 4 Metal—————— — St: bs If counter ian_is_not_pxesent= charge is Indicated ons —_Toiommine frioque chroriy” “{uy)_chtorde tec onan Ts a Pp baba tts a ii fe ere —'— aa ia | CL} | . pee — . 7 a iin | tris ethane = 1:2 diaramine) cobalt WIE) _Sulehate_ Fas u pits Te Co Cen)3 ‘= i | Ceo tena? tan Sou- ~s fs | Ccacen)3)_ 27 “(S04)3 “= I! oI XU = 4 => Li i Q Teal_0: u then centyal_qtom is named « then axd® pois a Written in Raman’ | naming of ligand-_c\-~ chiovido ! ic_\@gang (owt > Qxalato ends in O- Oo > oxida | OH Hydroxide. _Nevtral_ligand- Nr3~ ammine M20 = 9404 NO > mitxasys eo = Casbonys => Prefix. di tei: tetra > denotes no- of ligand q > If Dame OF ligand _alyeady have (di tris tetra) thes —— q bis -2 Ba 1 tris - Bp tetxanis~ 4 JS Cricie (pPha)2 3 Es 1oyo_Cfxipheny\ phosphine) nicke Cm = AS Complies = ~fattonic > centyal_at |_atom has. Same pur? oples_—anionicss_Cenixql ator, add cate | fn! ‘a Clit) Platinom v Ce - z tat wis) 3 (1 20): 3]'? > taiammine tniaqua chyoriun “Uuentane , 3 +3 z ey ee 2rhylenedi.am pine) Cobalt sulph? (ethane 112: diamming (Cag Cvis)2)* CA3 (en)2]- a aml ick CE. H Tsomexis™ " Lk stroctusal_Isamenism I |) ionization ii) Salate — “Gcamp: bich_ gi = ne- of natel Make jes_insive | diff - ions 4 autside Caxdingtion sphere —— | [co (NHa)s Su] BY is _diftexen! | Ceo (wH3)5 B85 S04 Cex (W290) 61 C13 Cx (20)5 C1] C2 Hed iii) Linkage —___> ompidentate_ti iw)_coxdinatto | Cco (wH3)5 No2) Cle > Caton 4 anion both are Eco. tua) oe} Cla Camere ey ben . i : Co (wise) Cex endo I a oa eee —~___K Stereo 1somea_——————~ jet Li) Geometsion_isomes———— ee ee May_~ 0 >| Mah = 0 ane Mr [Mas ba = 2 9 at < Shin Mabed > 3 GT <3 Shans t NHS H3NK3 cl By NR3_H20 WH | Yee 7 Ere See] WS a t i TT T NHS Cr R20 CT o 8 i |_cis Tsans (abcd) Lac bd) ad be | I q aU mia) b a il | PE (weal C1 Be lec) ee | Mazbe - 9 @r< in Sa Scr | tw Ww M. “Tea Tsans Ct. Cis i [ore BS SV asano? | [et lela] Cot (aiyal TT (i _ {pa (AA) 2] 4% {mM (Ape) M(ap) cd 2 donor atom oF tA He | Q Go at = V ecametnisl {opie _isamer in octaheta_ Pee ' ae -Sieisis et [Mash Oo un ene a [ooh yn : a [Moube 4 2 25 | \ [mdabaitie Ms ii ! |Mogb.¢ j 3 + { MQgbed yp) Yo —5 [MozbxC2 1 5 + | == 6 IMazbede 1 6 +~— 2 sey Mabedes |! 9 —~ 6 [es | Mabedes | + 15 3s [fre (wHalucle] ov (co (way ci2]* Maub2 ale : 2 as i] b a 1 T sans os Ut (Waaly Clay? __Maube 0 + OS ft s | 20 5 or Tt aut | o : | Lean: Css a Mab ety 8 S| feo Cua) s Clg Fico tumastuorlsT | na nore ~~! = fag Jah [some meridona ts omex__- ij “| =OGt T= iota (ey! ee. | | aie t Didentate ligand bp ee | : A ee (M(AA)2b2) “ RO Ae t Tyans a { I cis io I China) molecule) rae i cahaws OT ag f i a 1 I ea 1B LM(aa)s a A (a ] | Saige tg a £ a foe RD a I ft ia i [ K wad = i Chixal £ 5 ! Shows G-I (hon Svpeximpasable mixxor ime i | ® ta) ;p——__| __dextroxotatany "'"leavoxatatoy uf | pp §(tve) Pei $ (ve) — Sotqtion Boiatlon — tee bndex influence Of ligand_, Centxal Atom Uses Hao tyes OF _O¥bite idizat i )_innes_oxbital > (n-))d, Ds, PP} vacant axbiat 7 _—ovler_onbita > 08 inpnq J Te alan, Ree a a LL ae {vacant oa bial bhdesgo_hybsidizatton_¢ oi ped? Baas te brahesdial— 459. _pianay /SMing al ks fos. = = ¢ Se ee ha Sq: planas SFL > Paining occurs — | cNe a? sp3 - oc hedsa) WE L3_Paising do nok Sp3d2- gctahedsal | Occurs. 2 ectrochemical Series [4 br 4 sen" crs SPL ET COW < C200" ¢ Had Me [) cEpta‘< Nia cen AN’ ligand oct 05 SFL with bd/ Sd metal ons > Fo act as Set with ni : > Hoo 4 C2047? act as SEL cot} ~ Nig > WEL > fet? 4 Mt > too > SEL + cot? (cN=4) ] Co- aa! ys? Ccocmale}?> cot? > gat (UAT Ts] y cwes rite Pee | patxing Vv (p-1) d Ns be | d2sp> ! Jou _spin/ spin_palaed + | diamagnelic o _Ccofg 1-3 cot3 39° - S51... loniie at LINC} . a L | 4 ah ha ; ws ee ee egos ae ic oabital complet Ligh spin? _, = mas ; spin Free comptes Pdixing x KC | “Euich]=2 Ni? aa® Tools I J Toy % BEL i he Pairing % _sp3 tetrahedral i Payamagnetic i LT Ni cco) ul wim 24% us? - eau ' Au foliv|4 TH COT Paixing VW ‘ 3d Us. ue 3 Tally CI It ~§p3 Tetiihedial ~ namdanets | Cwicenyy =>. wits ga [uftulnfil J Tr | sev dsp2 - Paising V7 Sq- planax r diamagnetic Cop Nadu |t>— Cols 943 ae SFL (av ja T 4 TY d d_e ~ excite: i SU [TT he yet OP dsp [ Sq: planay —_poxamasnt~ | Magnetic PROpesty gf Ce Pla 2 pe I case L Tat d* a3 ‘lI LIWEL 2 spi # “Inpey_axbitat > NBiDARS L CO) | \ Ee BAe eae [rfl T+ | se Hoh aliaays._ Sp3d 2 j | _ _______OWles_axbital (| el fuletv Wd] no poising com ley OCCOES. [uli fu ie Tye] q ae | Magnetic momen) | Moen) > > Mn'3— ad Gath L—> Pairing Ja Dnpaixed e == 2 wm = Jtnd2) By oxy = Je BM Cmnciet? > Mot? > ad4 gata. ——>. WEL ~ po paining Onpaised e-=4 1 H | = al oM [Fe ccnle] 3 > FetS > 388 = (4 Gr) * on TREE pal L»_ Parsing | Ye el Jil | (p2))_ Mus ig aM 14 CET > electrostatic Made} hey as e + : =ve_ Charge xQ1_OHIN__+ | © tone pais of ligand Se] d_anhital saiting act ! 80 Ligand = 4 ; ~ egeneacyof onal enss—ohen SET et lever I I | Bagy centes exe dxy dyz dex ibe re | Tetraheds dye d upe dal ary _dy2 dex oh | [LT fea 4 z3 bee + Sa orlamme 7) Ue | TIT 29 r dxryr 22 ih At= 4 bo f | (Ga Factors’ affe cléeng CFSE |_ Ao & charge on CMA | Ao & err of CA | Bi 4 Yde 5d> CFSE | 0 & Stsength Of ligand - Oclahedyal > totxaheaxas | I eoiox _e~ jump (tag -ea) 4 d-d_tyansiticn Lolo¥ (eg - tg) ( bt = 4 jo) ¥ fee Titan ES Removal of wates f l violet Colosless. ee 4 Fel igang ts tosh) | Cattraction {s_los4) a i (splitting is toss) | (no -dd_t¥ansittony | 00 colo ——[ensou: Ste 2-9 cysoy | Bive vitsto Gnbydsaus | unre Ligand caloaless | cordinale_ bond —T 20 > ¥ bond Eivitu2ore IF ¢ en —> [hai (aso)eten) J £89 Fi (ia0)2 fends Queen blvel Pose | en | bye. Ep > Set Chui ten)3)#? SFLt “crSe ft violet | Ept 2Y — —Gonding_in metal casbony! 6 iNi(co)4> _Sp3_~ Tetyahedsal Ni o4)) i | ] Co i ty | Fe (co)s — pid > TBP Oe based | CO D>_ocddshedyw ko . co 0 Wo = a eg Ot tin a(co)io I I H | | CCo2(ca) 8) co c co co ~Co~ co ¢° Ne Z% Co co i o. Synengic_band meio caahon_pood in ett canary] has hath © and mi bong ~ [ Tag} bo GT 1 |_ © bond in M=¢: M 2p Oxbital Co (TS nae ! gd. dong dp vacant axhiiet of mea (Rey ; | _ oo i Tr bond inti=c > Filled d oubiiet orm \ fo) a | | dana (il eat | Ir* Cantibonding! matecatss ja ‘el I Odhit af co: vt i! bi \ 71 | os | Mase tc zo po 4 I ua jee Synexgic bond oe Strong,

You might also like