Assqrment 3

Dnaw the n hamN10 potemtia enngy hon the vtnation in a diatomic

ndiaating the r bnatimal emngy leweis wnile dsn tte po temti al
imatin thatelo seiy nesom las the otenti emgy.

Potentia

Ye)
omhemrdD |De

Poten thal rmetion,

(2')

whene
oseinaton,
(he en n9H alues o the am hoîmonie
hc we Xe (2+4)t
E(0) = hewe ( + -

spacing enengy levels that

we is the wre nmser
The Guontity pstmial cuaye wene parato ae te is tha orn harmn
Waula oewI i4 the thon the ue - an étis aiays positve.
nssion on the mharmse oseinaton
quontized eneng
8 onite awn the ndamentl bonds g
lthe tenms ? uhat ane
(xptaming oseln atn.
guantized nA epmess i n hon onharmn e

(5t mhamNIe
Qomee tin

he lereg
Wave nme7
is parbola.
If the Potentiad ew ve md thwe
mhamanieity constmt <he vnhanmne geillatn

t'¡n deneosUS
eguidiston but-taein sepane
oe n0 t
hundam&ntal Bang nesult
is om innaned (1R) speatnvm that ibnates
2 un damental tnmsitiom, hhíah is Whm a moleeule
the v=0 ’=1 4 = 1 2 ed 422 tl)
between
Fuamen tal bomds ane intese a nake p m5t he peag
am2nbae
mid - IR spuctma The a) sonptim regueney oz atnddaold (ae
bama is the Some es the eency a e mo wenlan that
absooptin:

1 1 avotne
unâameom tal &on ds

Not an eavelent bnas dispay baonds nte IRpta rm ny po4n

the bana depens on the magn itnde o the dpote a4S geiated with
bnd.
Stng Polan bonds Such 95
bonls
medium potori y
mel ban ds.
’ weaxly polan bona ana
Obserab1e Bands.

medium weak

Amo lece is-nanea (LR) tn achre it des not hare a

in dipole mome mTment vitnaion. This
m_2ms that the alecue does not atsnb am oesret shw IR
 notn eafeuiate the enngy leyeig o ? knnen
lovel di a
Bands
notattonal stvatune o the 1haindual
2=V, + (h'-4") +(F-F )

J J

2 3

numbe7,
wave

(6-8) s+)2 em
(3+ ) t
> - (8+B4)
0, ,3

2 ’1

32

wave nwmben son R boun0h

(3i) em
D+(6'-B)("+)+(8'-g)
J/ , , 2 3
 neneqses
B decn 2ases ond I
ineneeases hen bomd tength
Jrand state to excited s tate )
8nI0
S0, g< B B- B =-Ve
· ie m -l,-2,-3

t (8'- 8) m
DR 2+ (B+ B) m
-ve
- ve

m-4 -3 -2

's8 with his nene9se oh

Value
Value hen deon las6,
loK8 like
Sa Rbomd

Bomd head

432 0,

+ B' Jn2

whene, J-l,23
bnamh

3
wnat s Brom-donson pninelple dem mstrate uít sailadie
tha fane fnank -Cndon onaí ple is slattd s e The

two pounts os a vitnatinal levet o ne eketnonie state lies

at app»emataiy the some in tennuellaj is tanee s ne o the two

yz0 evel fon hieh tae mid pon- Datien thon tie tunning pornt mus
be Siub stituted.

Khen the ntenn welean distanee does ngt enoage Ire'=ne ].

The tnansi tion ocens

-
InkxC6)

slete.
internujeaz sepanatian thon the gotuná
Smalleg on langer

sepanati n i3 coaun
Whe me )Pethe up per s/ute
state.
daraby aten tham thato loren
tu e state hene theercited
 a ma lka ule to sh ibnati na
what al the 'bgoe enltemia
speatne Bno tathnal spatnag
’
@rihatacl speetna
epenienee a Change in ib ple mmént
lne molecule m st
5 stmeChi
a vibmathonal mode.vitnatlsns suoh chage makng R-ein
in the nedis tni bu tion
Shanid nsult stneeth mde but t
bending acthre rn ibs qsy mmetnía
the dipole
Ex: co is IR - beoase doesnet
Syremetoi streeth mode
omnt.
t n s i s msf inoye diseneteeng Levels,
e he ntnetiona (4-4sD
byeieay in the mid -nqnoned state shuld
$pee tago7 ninatisnal
en2ace beteen
Ihe ene
vbnatioal selectisn nueg.
The tnamatons mnst satisth
tnonsitins slepond on Ploizuku
chonges but gypieay
ond the eeekd tates o mo 2edles cam be
4 The zund state itt quantized vibmetnal
oseinetin
nephuated hy hanmnil
moges.

(B) Rotatina spertrei

dipote moment
G The meleene mist have a pe7marnent
to intenaet with e1ectns mag netie wdic tia
’ Hel, co, tyb ete