Ace Science Academy

Subject : Che Paper Set : 1

Structure of Atom -
Standard : 11 Miscellaneous Date : 05-07-2024
Total Mark : 120 Time : 0H:0M

........................................... Chemistry - Section A (MCQ) ...........................................

(1) The minimum uncertainty in the speed of an electron in an one dimensional region of length 2ao
(Where a0 = Bohr radius 52.9pm ) is kms−1
(Given : Mass of electron = 9.1 × 10−31 kg, Planck’s constant h = 6.63 × 10−34 Js )
(A) 548 (B) 547 (C) 546 (D) 545
(2) Given below are two statements:
Statement I : Bohr’s theory accounts for the stability and line spectrum of Li+ ion.
Statement II : Bohr’s theory was unable to explain the splitting of spectral lines in the presence
of a magnetic field.
In the light of the above statements, choose the most appropriate answer from the options
given below:
(A) Both statement I and statement II are true.(B) Statement I is false but statement II is true.
(C) Both statement I and statement II are false.
(D) Statement I is true but statement II is false.
(3) Identify the incorrect statement from the following.
(A) A circular path around the nucleus in which an electron moves is proposed as Bohr’s orbit.
(B) An orbital is the one electron wave function (Ψ) in an atom.
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(C) The existence of Bohr’s orbits is supported by hydrogen spectrum.

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(D) Atomic orbital is characterised by the quantum numbers n and l only

( 2)
(4) Energy of an electron is given by E = −2.178 × 10−18 J Zn2 . Wavelength of light required to
excite an electron in an hydrogen atom from level n = 1 to n = 2 will be :
(h = 6.62 × 10−34 Js and c = 3.0 × 108 ms−1 )
(A) 1.214 × 10−7 m (B) 2.816 × 10−7 m (C) 6.500 × 10−7 m (D) 8.500 × 10−7 m
(5) Given below are the quantum numbers for 4 electrons.
A. n = 3, l = 2, m1 = 1, ms = +1/2
B. n = 4, l = 1, m1 = 0, ms = +1/2
C. n = 4, l = 2, m1 = −2, ms = −1/2
D. n = 3, l = 1, m1 = −1, ms = +1/2
The correct order of increasing energy is
(A) D < B < A < C (B) D < A < B < C (C) B < D < A < C (D) B < D < C < A
(6) The electron in the nth orbit of Li2+ is excited to (n + 1) orbit using the radiation of energy
1.47 × 10−17 J (as shown in the diagram). The value of n is .....Given RH = 2.18 × 10−18 J

(A) 2 (B) 3 (C) 1 (D) 4

(7) The minimum energy that must be possessed by photons in order to produce the photoelectric
effect with platinum metal is .... × 10−19 J
[Given: The threshold frequency of platinum is 1.3 ×1015 s−1 and h = 6.6 × 10−34 J s.]
(A) 32.1 (B) 0.624 (C) 8.58 (D) 976

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 (8) According to the wave-particle duality of matter by de-Broglie, which of the following graph plot
presents most appropriate relationship between wavelength of electron (λ) and momentum of
electron (p)?
(A) (B) (C) (D)

(9) Ejection of the photoelectron from metal in the photoelectric effect experiment can be stopped
by applying 0.5 V when the radiation of 250 nm is used. The work function of the metal is
................ eV
(A) 4 (B) 5.5 (C) 4.5 (D) 5
(10) The de Broglie wavelength of an electron in the 4th Bohr orbit is
(A) 8πa0 (B) 2πa0 (C) 4πa0 (D) 6πa0
(11) The quantum number of four electrons are given below
I.n = 4, l = 2, ml = −2, ms = −1/2
II.n = 3, l = 2, ml = 1, ms = +1/2
III.n = 4, l = 1, ml = 0, ms = +1/2
IV.n = 3, l = 1, ml = 1; ms = −1/2
The correct order of their increasing energies will be
(A) I < III < II < IV (B) I < II < III < IV (C) IV < II < III < I (D) IV < III < II < I
(12) The number of radial and angular nodes in 4d orbital are, respectively ........ .
(A) 1 and 2 (B) 3 and 2 (C) 1 and 0 (D) 2 and 1
(13) When light of wavelength 248 nm falls on a metal of threshold energy 3.0 eV , the de-Broglie
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wavelength of emitted electrons is ............. Å

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(Round√off to the Nearest Integer).

[Use : 3 = 1.73, h = 6.63 × 10−34 Js me = 9.1 × 10−31 kg; c = 3.0 × 108 ms−1 1eV = 1.6 × 10−19 J]
(A) 7 (B) 9 (C) 12 (D) 18
(14) If the principal quantam number n = 6, the correct sequence of filling of electron will be
(A) ns → (n − 2)f → np → (n − 1)d (B) ns → (n − 2)f → (n − 1)d → np
(C) ns → np → (n − 1)d → (n − 2)f (D) ns → (n − 1)d → (n − 2)f → np
(15) Compare the energies of following sets of quantum numbers for multielectron system.
(A) n = 4, 1 = 1 (B) n = 4, 1 = 2 (C) n = 3, 1 = 1 (D) n = 3, 1 = 2 (E) n = 4, 1 = 0
Choose the correct answer from the options given below:
(A) (B) > (A) > (C) > (E) > (D) (B) (E) > (C) < (D) < (A) < (B)
(C) (E) > (C) > (A) > (D) > (B) (D) (C) < (E) < (D) < (A) < (B)
(16) The number of s-electrons present in an ion with 55 protons in its unipositive state is
(A) 8 (B) 9 (C) 12 (D) 10
(17) The number of correct statements from the following
A. For 1 s orbital, the probability density is maximum at the nucleus.
B. For 2s orbital, the probability density first increases to maximum and then decreases sharply
to zero.
C. Boundary surface diagrams of the orbitals encloses a region of 100% probability of finding the
electron.
D. p and d-orbitals have 1 and 2 angular nodes respectively.
E. Probability density of p-orbital is zero at the nucleus.
(A) 3 (B) 4 (C) 2 (D) 5
(18) Total number of ions from the following with noble gas configuration is__________.
Sr2+ (Z = 38), Cs+ (Z = 55), La2+ (Z = 57)Pb2+

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 (Z = 82), Yb2+ (Z = 70) and Fe2+ (Z = 26)
(A) 2 (B) 7 (C) 9 (D) 11
(19) The number of radial node/s for 3p orbital is:
(A) 1 (B) 4 (C) 2 (D) 3
(20) Given below are two statements:
Statement-I: The orbitals having same energy are called as degenerate orbitals.
Statement-II: In hydrogen atom, 3p and 3 d orbitals are not degenerate orbitals.
In the light of the above statements, choose the most appropriate answer from the options given
(A) Statement-I is true but Statement-II is false(B) Both Statement-I and Statement-II are true.
(C) Both Statement-I and Statement-II are false
(D) Statement-I is false but Statement-II is true

........................................ Chemistry - Section B (NUMERIC) ........................................

(21) The energy of one mole of photons of radiation of wavelength 300nm is ...... kJ mol−1 .
(Given : h = 6.63 × 10−34 Js, NA = 6.02 × 1023 mol−1 , c = 3 × 108 ms−1 )
(22) The number of electrons present in all the completely filled subshells having n = 4 and s = + 12
is)______________. (Where n = principal quantum number and s = spin quantum number)
(23) Maximum number of electrons that can be accommodated in shell with n = 4 are:
(24) The number of following statement/s which is/are incorrect is
(A) Line emission spectra are used to study the electronic structure
(B) The emission spectra of atoms in the gas phase show a continuous spread of wavelength
from red to violet
(C) An absorption spectrum is like the photographic negative of an emission spectrum
(D) The element helium was discovered in the sun by spectroscopic method
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(25) The maximum number of orbitals which can be identified with n = 4 and ml = 0 is
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(26) Consider the following set of quantum numbers

n l ml
A 3 3 −3
B 3 2 −2
C 2 1 +1
D 2 2 +2
The number of correct sets of quantum numbers is ..... .
(27) The total number of isoelectronic species from the given set is .......
O2− , F − , Al, M g 2+ , N a+ , O+ , M g, Al3+ , F
(28) Electromagnetic radiation of wavelength 663 nm is just sufficient to ionise the atom of metal A.
The ionization energy of metal A in kJ mol−1 is ...... .
(Rounded-off to the nearest integer) [h = 6.63 × 10−34 Js, c = 3.00 × 108 ms−1 ,
NA = 6.02 × 1023 mol−1 ]
(29) For hydrogen atom, energy of an electron in first excited state is −3.4eV, KE. of the same
electron of hydrogen atom is xeV. Value of x is. . . . . . .×10−1 eV. (Nearest integer)
(30) The total number of orbitals associated with the principal quantum number 5 is

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 Ace Science Academy

Subject : Che Structure of Atom - Paper Set : 1

Standard : 11 Miscellaneous Date : 05-07-2024
Total Mark : 120 (Answer Key) Time : 0H:0M

Chemistry - Section A (MCQ)

1-A 2-B 3-D 4-A 5-B 6-C 7-C 8-A 9-C 10 - A

11 - C 12 - A 13 - B 14 - B 15 - D 16 - D 17 - A 18 - A 19 - A 20 - A

Chemistry - Section B (NUMERIC)

21 - 399 22 - 16 23 - 32 24 - 1 25 - 4 26 - 2 27 - 5 28 - 180 29 - 34 30 - 25

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