ee = Gooxdinarte, Gorpound a i pa 1b? @ we know thas in sKansition metal fox aula’ ge > f ee 1 “Pons hound +o a no. d_amions os newtsal atoms. @ } CY “SF tn modesn chemi Stay such compounds —@es nowt =< gs cooadinate compounds a > bxample ;_Unioxoghy!l , He rnoglobin and Vitamin B12 2 aa conscioate, tamaures of Pq. Fe, amd! Go xecpectively.. LS —4 nets Se —EEE = —_ siento. iby + 9 cnsdnte yan, —— a_contsd) atom ton banded toa fined mo. of fons __— ae ox molecules of Ligand 2 aS a iis i tht. cclna\t ton is snsxounded hy thee. _aimon’ gp bina; wolexsate IL) ton"—fn_a_coondtnadt entity the atom ax fants uth ich -gzorned ‘col, _axxamg men Omound f+ is called the cemtxal atom o fon fosegt LE witinost) , (olwuaea (feCow el? Houing centsdll atom o¢ to vst Co8* fe 3t dhese, centsal, atom, ion os.e, al. knownas desis cate é —Int_o-oxdination no. (ta/) of a_metal tom ox ton > Complex com be clined a nowof ligamde donor, Gtoms to which metal ig be, Coty bonded ~ a dln ay F r= D > anye PAGE NO: (WJ) y ome] | é Subject : Oxidatton-nuralber numbsa of _cemtxo), etal atom ofa . iT dne_oxidation nurnbex of the a ina complex i. defined as the choxoe $+ tdould Comey ( 4 a\\_ she, Ligamd: Aine xemoued angst te 3 sxections pais that one chae uth cemtaal atom _—__ vee a. = feu: (HOY «Lalla T* 7 Ee cgodgl =e [ooltmel —, Povtew sl a =a iB _g_Homole.ptic_amd Hertsolepive Completa, 2 thd eek ° {Gol wns), 12 ! \ a._metol xoleptic. complexes 5 Lorn plexes tn _utlhich —< 18 bound 0% moxe_tham one. typeof _Itgomadis. fx: [olJn,), 0 ie 4 % G pdxdina-to nS he, KE. SIN NS DOES- _ : —__@ Cental. atom amd the ltgamds| ame the. Ki ands... suasounding s——«~ Sersounding his. cemtsall aiom.| this _cuntad) dato given along —<¢g~ with _ nest_electeical, charge gr an | of the compound ——¢ —— thie _— oor — z= > Ihe_elecasical, chatege. of the. -Une_tiectsical_charageof the Coordination. compound is not -L008 din adion corm Pound is ene nsioned_. -|—mentionsd ta: Rta a - _ _ _ ft \ ——bo=0sd ination Pol ynedaon 3 Uhe spares (SET as ala yaLeaon =f —_axxamgment of the ligands atoms — which aue_disecty ng, i—___attash +0 she —tuntsal—metol_atorn.ox fon define ie Lo-08d ing 40 . 5 10-080 ina HN, Poly hedson., ral Host commonly eg at oy ooo —UWolaluadel” 6 cotahedaal Cy = ccc i vs\colu] iS 4¢¢sahedaall oe ae a am; S b De 89/4058 lam of, 4 EiPAGE NO. = Subject: pare , _ yates Eyam ples‘ = p > oc L 1 u L L IX he — ° > L L = Tsigpnal wip yxasnidal "sean. GynamatddD. @D.__Lesnests theasy of cooxdinodion compound * 2. p> silezed weants uios the fast to lomulode bre tdeo dont the stavctuse of co-oxdinasion compound. a ed a. te = 1A _arcd, died xt i i £ immentnd ae techniques —péimomy valemey amd seconds ae = Pstmary valemey | Seana alem 2» tis tonisable | non- to ntsab L- a = is _diseetona) in nat Sod wt 3 [It is_xecponsible ox_geomnetay So # comple —|~of comtexop rae) & 3 Subject : ee en {21st equal. to oxidayinn no. | Te 15 eqyual_to. couosdination 10. $+, = ! +> Ati. Astsenied by == === Asti Pa ented by Tris, : ayy (i) Ceo Gal aa)s 1) oyy PAGENO: CE —] DATE: Subject: wre TT) = Binainy Compoond such os Gels, Co, & P@Y haven >. ive! - Exoetsiment © _ = lost ith_—_ aromonia snld 7 $4 was Sound that some = pa@rkcinated ais Ag (2 on tig eattss {Ay lagi t oly kKoa _ | { | | tose) mol Coty Walia Maxeen) govt, mo age pA) mol. Cotly- tals (vioiet] gous mol agce 7 Ghase_abseantinns oye thee ith she conduoawlgy OPA Sux Ment KS Han ca be, exp! i — i ? Maint_ PAGE NO: (1 & owe | Subject: ie Za — Secondo Valen a Ee ee LAkane, PSaposed the tearm se: ondary valency tox thé a ee ee ee a Grtora 0% ton é at com Plexes. = amd ieee oe = o S.No. | Colow [ Soamula, Solvion Condachvit, e. aa ea a | settous (oolaaadel* 3cn- Li 3 tlectsol yte en Ht ; eo. 2. | Basalt (tolalwslst* 207 AnD. elecsol te = 5 7 Fas ¢ a. | en Luolalug ys Os) ALA electaalyte as | | violet {Colas Galen" 2A. electanlyde © & | Se = Compound no. 3 bY have identicd foxmala bie eS diflexent pxopexdies these atu known iSomexs ec = $e3G ti ndawy valency is cq,ual fn_the cooxdinavian 2 . |g GO _Dhe_ions Laggan ln ages SE — Gountex ion R Ba ane sptcies with in the squane banker inatio D ensses amd she tons outside the so,uane bxankers Ane collie Cou ntex ions ‘ [colwasds 0] a oA As Conadina tion entity Gountex tan SYS S's sss)5_e Gp i de Temas —paimang aind_timadany vlangy—— gr 8 conduactivity hy fotlousing —expeatirm ent __________———¢_ —_____Sonrnalg___Sal0gsmined_tm_exttsss enoles of Ag C2 WW é QO Fac, on a & Q_whitdy+ 6 4,0 2 & @ Collg- Yala L © @ 940) avn. ° ‘ 2 = Vv Sev Conductivity 2 @ _Ltalvwro, — 2 ce S A GL cols) co = 2 b wea © ee ~_@© (?ttun,), Os) — a u uo e uf a ( Diffentmes betosen Dortle salt amd os f ee a ee = 7 > Both double salt aes urell Comoalercs ase, ge Cy f | jx LS 0: . if PAGE NO, acl j s Subject : __ Seow ° oecr rT} . - dissociate into sirnle io 2 tanpleiy- hn se inate = But complex ion: ra So mab a do not dissociate ginko Fe®* amd C7 o = Dentoity Sf si cesta Meaaasinge amanda gla \gamd at atime centxal metal storm. 2 & alu, —> Dunticity — py 430 — Dendiot dy S—abe Gn? Denticity —> 9 | a a [tolenla lt, a Z t 1 1 = too ai Denticity On Bn = 2 2 coll of cobalt ~ 4 J. 2 DQ, a . o nbeess -B-Ligoms 1s am—astom_os_quoup_d_atams hich _hovingtamdén i i i ‘y — sto_conate._&= dia to centxal metal dors of complex compounol.— his moy be simple tons like vienna Ue oom > i a—Uassified of ig amd. Subject : peste: | eg are: } eS Vase =donos atom | % : © a On the basis of donox atom ligamoss aiue classi fied of ants Sette ing moannex — ae t le e —{t)_Unidentote Vigamd.s When \igamds fs bonded z F —A_métal atom ox ian by nale dona atom = known as unidemtate —ligame & § . 2 € f (a) wleutscl, ~ monodentate Lig.amd cf Seal foamul a. \igamd. Donor atom Charge, € In tts complex . « 5 yA No Aromine Nv oO t as ¥20 Agua 0 oO ey a ca rn Phaspnine oy NO. altos {| pt Co Losskony | & oe ¥ [pg | | -—————} & Pyidine j—_N | a ad p—2—_9& | —-@-——___| ‘ a =} "Tiono lap | i ee I; [> tO | Thio taxhonyl_| g | ~~~] - " pf 0S arcSubject : lame of tgand_tn_tks comples| Donatuatom| charge. Fluox ido | Flyoxo £ 4 Chloxida | Chioxo O = Bxomido | Bxomo 3x =. Lodide | Todo © =i Hydxoxo 0 ea Cy.anco, ¢ es, 1.so-cyano al = alikxito_ nl = Cynato oO = Tso cy nok Oo A ® Araido nl es ® foe kate oO 4 © Oxido/axo oO =) @ Su\pnida § =a @ Cosobonate 0 “a @ esoxido! Pex oxo ( 72 2 @ Sy\phito o =a 2 ©@ sot nighato o =A 2 @O aloe nistxa wl o\ 2 © sham Amido vl =1 Ze @® ost alistso nid al a “yg ©} stu,- tut “Yydanginym ol Ss 2 FF. PnGENO: (YG) | one | Subject: ew © a 4 a af SL Bidentote Vigamds t ‘The ligamds which foxms awn ~—" : i= n Fi 1@ 1. tok q ~ C—O | y Ce £ 02 EF} { if ‘ Oo & | Jareat,, Oxalato lox) 1 | ce fe 7 a0 —n eZ o 5 B Cra — iu, i — oe Sime Bion -\2-diamesn\tin) ‘Gono atom’ dakvonen thane ie eer P — |r Ee & sel a | a) a) fl ay me |PSENO: GE] DATE; Subject: Cory tu,—t == s—on \ GAa— 6 = N — 08 ! > Ex Diewhylent +x awn ine, 2 = = fe 2 alta —Cy— Cr — Nw — Orig ——, — ‘a o Donox atoms 3 lik fone. o _ Gnatag & O - o | (qv) Tetsadensta teVigandss c 2 fx —> ‘Txiethylent tetxo amine $7 Siu Cu, No CH, — CHs— Ne—u,~ Cu — iu, Donox atom? U slid agen Chas a SS SS S/S $ eX 8te eng nee] ee ~ seem Se af \V) Penta dentate, ligamd et = 2 - Ex —> Sthsiene diamins tai acctato LEDTAY ce pf Lr, Coc. Cr4z.c.00° 7 t WN — tris —C, — NA «ff & gf 4 Crycooe f ce 7 i ey eg Chatuqe, ¥o~ eZ i Gull Menadentats Ligands ms : ee fx > Etnylene diomoin! sh a oe + Ee 4 M4 too cucan® -—s qi =i | AN ——t4,—cu, — ec a | | 5 S CH,coo* Gueono® ]| z L Donox_ atom’) slid. gen bu eygen af Chasge t= Ml ee oo ol oF r ae x ooo = es — | im- Subject i ~ \vit) Ampbrdenta.te \igamds mg Sites _guesent’ in toes shsuchiwes but at @ time __ FZ nig ont donates tnt ont pie to_centeal mete adam 2 ho" Caal® (2 donot ade cyanal = ~~ ve° N= donass adorn yamo] ? sosyanido lnerv=c) Ove. example 5 Q__ Ac sn ne ales +hfocyanata =! thingy amata — al 180 Yifocyamato o Q ne Nos N00 akssite- Al Nits ito -O os Oe Nitxo Nitesito 2 : 2 _ slomenclaiust of Co-osdinat Compound ° - | 09 sexe, use, use of cule of TPAC —P Subject : Te l__tn_case of adbbzavinted lathes) Vigands, me fist o Actes ol _the abba ¥iodion ts used te detesmine the Te position tthe \igamd tn the alghabatically oxde z Ww) The formula fox the entat, co-oxdinaian entity .ulhatever = charged ox not enclosed in squoke beyocked eS ee \vi) When Moamds ane Falyatomic ineix foxmula £ ce Glosed in _arantheses | ECT BOS ) . & Wwitl_diqamds abbeiwicton ate also enclosed in Fa.scnthesi, 2 —< (yitt) Thexe should be ny Space hetweth the lieamds gmd — © Ye. metal ith in a. co-oadinatton Phe xe, eS (ix) “uhen the foxmula of a hasaped | ° F O=04d ination ¢ ast f_ Subject : = gg 0 Rota.ssium —stcjame a sgenta te (1) ~~ i _\ fa (calls J” — -Lex 3 xt {aglems —. k Ag len . La la x* Ltoltsouds 1° Le a ack: m x Loleode ls = KeltolCaduel @_Dtasstum te4sa cy amo mokelate lo) x Lato) O-4=% m4s xe Lvl) ta Larlewl,)PAGEN. a | € W ® Subject : = E fle 1O_tasaimmine 4xiaqoo chxomium IE) thiaxide re (ux ataads la Oy ue oto: Sa ' 32 a \Calaltils Utad)s 10, Pot fd bb be b at - = dian \y \colends O87 £ r od \Lalens a (Souls eo I -Q_dichtoxo bis Lethame -\.2 - diamine) tohalk TE jOn Gu \to Wa lends 1* = a-ass res (ee ta lene l [ea a Site eet ayo alee tense 4 [tol Caro) @l® —— i meas = i fos ——' yt ge SS [a tatatoulas ae 4 ee wemse 5 a. ne eS] SG asatyonatde sincate Ge) ay Loto. I aS Ho nH» Lanlowl eS - = Vo Lovaas © 1® Sa ie ve rE ana i> = a LeolwHals co P= il : Urn (wals 1003 ls i Hexaamnmine coal (str) chlos fd, i; ae a) I Bex J Lo Lales 1, 2 = E [Col wale 1s Yr ye Pp» [9 JoSubject — —Nlamning of Aonsanclean tps Nonpauoleai lense, fottousing xVles? eZ CT : ee —O dhe castbn fs__namned _fixast in ail cases Ee i = ~-@_tne_ligands aut named in_an alphabatical —oxcleut ~——belose the nome of the cemtaal atom of ton é 9) dame ol the amin io teend in‘Q’ Vike © ———_chioso bom © ‘ tox _HaQ__—4 — a aromine fox 3 4 C ssbonyt fox Co amd alttxosy! fox w/a * = Anite ame used to indicate the now of & iH -Uwhe nth _names of the Iigamd include a = numexical gaeffix ten ye_use— = brs fox di _ tis fox tei a } tetaalis fox jetag et. ~ - bx2 St 0, \%mala} a 4 dichloso bis 4st phenyl Phosphine ) nickel IL e = © _Oxidasion state of tne metal + pwinihy the ge | tomam_—numtex—paszninesis____9°*“¥——8= _@ fhe compe, ion ts cation ox neutxal. the metal ne named same ag the aren <= es =Subject : PAGENO, 7 meet | fox ex. Co tn a com@lta cation o neuteal, ss known as Cobalt. @_ Hare, cOm@lex fon iS am anion the name of the metals end latin usoxd. with the sulliy ‘aie’ usin ghete ’ -in_tase of Anionic Comaler Fe —— > _ fexxate, Sn ——> Stanna.ts Pb ——»> — Plumbare Ag — Ai genta Py ——> Ayxaste Gy ——> Cupexate, Gq ———> Cobe tote. “La Lincate, i_—> wliokelate, (x ——> xo mate, , ———> Platinate, 3 —— > Palladate Be __ fire . wee Ltol W902 CHa +x: hh (a) chi Ja )3 19 +\mr) sulphate _re x g r wane |e | ome Ld ee Subject : 6 er —Traitts tends | SS a iL Untosn bis Letname- a2= diamine) Cobalt (tr) so a Lait J F | Ee Xeaxacor®ooyt lol € € Tet aimals Lowol® 5 : i Vo Uvita)s (ola € i (Co CNHs) CH) OT g & ebsinmmineaqun chioso cobalt i\ chlouide e- h Ky 2nCou, bg Ka. = bs -u = oy f mM=2 eo Potassium ae yvozintal (ar) & S 1 Ks [AlCe04),_] ee i U-6=3 7 23 Genin fu a ee Ca | = ——= . PAGE NO. ae ) ae [PE (na), U (1o.) | ot Bo a me Be iannine chow gta = N= Elatinam fis ES Soni! Case = a coho® on Se G Hauge fi» ie gi . TS ie a 8. stan +4 a _ CN =4 CN= & Tl a > Crelen),u] [zou] i iz a3 ee : -tetsia Ch) oxozi I 2 a 2 > [rl[en),) [Pea] gs f \ a fuis/ ethane -4,2 —cliamine-) platinum |TV) C ivothuiailm plainanCle)Subject : Bonding tn (o-oxdination compounds 3 =? Wemnex as the fast to describe the: bonding Jeashate jn co-oxdination compound But bis theexy could nox —omsurex _hasis oueston We ke a mock padins Ane —punpessiy of forsrns gy —co-soxdlindte corn pound It Valinct bond {oxy i Accoxding to this theoxy tht, metal atom ax fon undex the influence (effect) “of ligands cain use, te. (n =o cay Q 0% by “43. Q Ns nnd ox bitals fox hybeidisotion tn ! suchas Octahed xal, seaahedadl .squaee plana. £ coon Yhok Gam Sonate _e7 Hai be ‘beading inad i3 ‘Subject —%- S800} oo = ie 24 4 ao Tetaahedaad. | = 3 4 det Squats Glamak md 3 S aid Aiqanal bipysam id _@ ». 4 b ped -|—Octahedacl a 2 5 b asp? Octahedadl, ~ BD. —2 - BA sexies Ld block slemenis ) i) > valene hell 2 ad Bd uss ug 7 \n-1) nh 2 LTE YY LT _% —» oleh fF S98d*# —> nd outex d oxhtial 2 4 _D. atspS — \n-a\d inner A oxbitales IP. P= iS invol : aon —). known as inn tx os bital_ Como lexSubject : =H ud is involved in hybxidisation then i util be Anous nas On os bistal._com plex Id Se i Vv sp5 —Tetxa hedxol 4 GN=4 dba silo ge, outex oxhitol, Square, plamor, +! amd innex oxbitol, complex ogi kuleelewd | Gat (fe be a aks - > +0 Fe. Bab wu ae Fe > dd ug use fee W ALi 4 Li \Y dd In the oxesence | y of stxong field Ngang C= ue Daixing t a MONA Nanare ea lLeEL lw hy av _\ l 117 “88593 hyo; % Cochitaly ge ny Jv [i beta + = 7 T oe OOSubject ;__ bare: RECESS O_Hybxidisotion ala inh te ~ + ; a _ @ Tanex oxbitall, | i in | wv cy a . sp Sh atohedadl, I Square bi gyacmmih ‘© © n (unpais ed e-) =0 ©. damon netic j @ Ww - tak fed igand i teh Ed 2» Vises > =A 253 —-~ 243 tp ti aalo— dd*-4st | W Cot aad Ug? o> Wwhbbhby TT Wit tity 3d us 4p ud wo > whbhbbhl LI Titty 1 adh ybsiclisction wh bivh | \whvhy fav TILT F Ships & y lo pai aaa take plac MS S'S'S'S 8 }9 18/9) 0) 5 5H 6= [Custis Subject: ey _¢~- -O__wybeidisotion ® spide a | C 0 eometxy * Ootahedsal ov eC 1, 0) Vet alas) ee ee -. eS Lal Ha) . n+ b=3. te med = Go > dd* ust ee at @ (or*—> gt us? i au ; a= Wwhhbht | Ol € $8 — 4p fe Ln tne presence of _steona Haid in. e_ Sield tea od (va) NA ___¢3- : _ nePAGE NO. Gry j Subject: bere; | Wh inh fav] Ve Nig Aa NH) NHy NF Ng @ (reoenectey 2 Octo hedaxal, @_ Color > Colour le QO by bsidisation s_d3s92 © tnoex oxbital com plex L Vous Spin complex ! piiln_paistd complex Livi th ia ) mous-2a ma aaNi—? ad® <2 posi —> ad® ys? = hhh Ot ad 48 up ud ae P.Oixin bh hh : a ni G7 sarion| eke woh woh - “1 : Q_tromedey + Jetsabedaal, «| ef} : @ Coloux * Colous4ull es fr [i . . = “ [ 3 v & i = a es - @_iv=9 n=2 ~ ‘ ams : a @ Twit =F aa Usbea 27 ef : o=4s-9 =| [ ona = L a@hi—> aq® use = Nit —> 3q8 Yee x ¢ yet —> Wwhwhh ¢ a FPAGE NO, Subject: bare (STS) Q_Hyber cisation de® _Q Genenest ’ XK > C> a> 0 E 2 aefl tT Eva 8s y L D 7 Gonation stating of lone pais : leds ligamd stxtngth decxeaser > e S » CsA} > % » staong fiers Ligamd ewok field tigamd4 , €ey ao ¢ I Subject: onre, TT} oi _ . of limitation of valence bond hear y of 6 q Je involves a numbex of a. um 9 tion A ao { . © YT Q 14 dots not otve og uomsiintive —xegule ol__magnetic dain e ¥ € J (i dosstoct_tnplain tnt, colona of cormlen compound x © doesnot give the, thexnendynamic 08 kinetic. © | Sabiliex of coo dinadign compound a | a © 34 does wot make crank Qxedictions the, tetxahedeol oH I ard gps glamak, stxuctyxe of = Grosd inate se | Cora glex ec ! &- | @ 3a does not di Hnquish betwoeeh urea amd “twang € field gama . | cs j Ques She spin only —radgnstiG rooms of (An Bx, Ee eae ae raglan © “S| = ids oe te Somo@lex ion is Wit any © euthes _terxahedxal, \sa2)_ 9 qwioké lamar, \dx 52) e Se esFAGENO: CHS] Subject: bare TI) —Hagnestic, Pxopensty of Gey > => inadi ain be _rogasuxed by neki ibiliy expesiments about the stsuctuae of Cee. > Box_metal, tons usith ete thxee e7 tn the d-oxbida! —- Vike et Us) S98) Ox*(08) be Vacomd ox bital. une _mnoxt thom hate, 3d electron ov, Patssend she xequized qaix of 3d oxbitals fox ontahedaad, this foe dh (cx an) aS Uandt, fee") B*U fee co) | o mane an G-oxbi orf il) +! by is 9, Sd @" hich eaves 2,4 £0 unPaiaed | Plectaon _aecpentively = However writin specie. Containing dY amd g* ions ahexe de, _com lication, irSubject : — (relew J has a magnetic _moment of single uapaized t= > Lf ed has a Magnedic mement of fi un paixed e>, > {eo Bo has magnetic memtnk at toux un paixed > : (ueleadu) diamagnetic in noduse, I PD > Danton l? rele oseitd, compler Corn Ple x: £ Vcottsoy lal” ase innex inuolving d&so* he, foxmex taso . g arnagnedtic gsnd the late diamay neds’ An—the_othes homd Lint | Efe ee)" amd [Oo F,42- e- Aus ortex asbital complexes involving P* ature. Pa posa.mdgnssic ca, ending 4 Brau tapaisecl electrons. |_Cy stab field thangs =| oe ee = —2 She GFT ts am electxnstatic rood), hich con ideX the & enttol.=Lisamd bond 4a be tonic | & | = tigamds ost txtoted ¢ Point _chotpes in cows of ‘S| Gnions—od dipole in case of neuteol —yrol ee ce i Ce Avital, —> 4 eye, chouge c amon = v6 chatige a Ligamd—§| ae + GENO: CEE] < : p38 el nl | rt | WO @ = _Vne Sd oxbttals tn $solated gaseous atom metal. ton ~ A 7 i o 89 . j ! eo —> 7 A i : Dd oxbital lefveot tomer eter) 24 xesults in splittin 2 f she d-oxbitell v a 1 ar n Bon entities | 4. L L L 2 a Gq) — a] YA a LIN = WA L he b a oe dxiey’ dat a Deuyoratil | [eg D Ione ; a ® 77 ® | 7 ey 9 | LTT TTY eangeeniee h | rary deonbrions 4 R78 eneroy eh i | 7 wystal held \ o Oy? dF dy da Oem Ao oe, oO] i 1 Salitting of d-oxbilals 7 e [ascinneeal gael aulPAGE NO: (SE_] | Subject: ome] flectronte anfia ic © 1 ef ef \ SFLIWFL . a) fag € 1 E € | gt seule 2 te tag + 7 | g® SLLWAL, 42. bg e | gg E SFL 4 . e. ~ tsa tg ee | (vet. 43 eo r fng_ts & | | ~~ i SFL, 45 pe — ne = E e F cee E WEL dag Ls = l Eb tah bgt e | at o = WEL, ta’ fd Ee i oo i SFL) tat ta! - 2 a) e SURE Sate e a e gf? SEL > gt be e WEL ted : 3 SEL ae - 3 WEE ag ‘s < ——¢ ge SFE > tal ie WwFL oO”: SEO | eee ore 4 = vas . USXOL ndina the metal, atorn ox ton 4 thexe will “be, Jcepulsion” _heruesn the elections gm metal d —oxdral, asd the, eleckons of the Ligands —Such_a_xtpulsinn {$8 moxé then the metal) d=oxbidal \ is_Aixected towards the ligamd then when itt LQ: ) yt from nes Vigan 3 > 5 2a a “ i ii x i d nil experignee, vaose _xepulsiOn amd incxe in fined athe crt dry .dy2 dx hich oe. dixected beiuveen 2 wile danse In egy —tesaqe.sentgy of the com g =7 fn tne octahedeal Comolex theee oxbital, of low 2 crtg 3 e+ amd tuo onbitalc of ight enexgy I ‘is _apliiting —fs_Itnousn tryst fl putin = tox _d* ton: jwo_Passibole paiitans are avai lable— BOP he iets lectus detec Gn one_of the ty 2 bitals. ‘ving the can finnsction. tnt te) ett fbx usmigh (NS <9) ame ke ns meal field a yyy \igame, amd fox na high pin_coralere Z MS) Hf de> tne fooato election enters in one_of the tig Pa “Pe _attvstat giving dhe confipugasion (taal tg’) z “RQ _Assamd fox uhich Ne? ane eee aie “Vigan amd form fot) spin CommlexePAGENO: (tg) € Subject: owe; TT | ee wn Sexige = LS ee em Ln guntddl, \igamd.s corn th Lawtomged in aseaies tno __oxdex hin casing Lita statnath . 7 Ba + UR | _[onexay LIV Aastaoge Cnosay\ r Zo ve, gh osbitdl, . 7 WY @heatcal Rye wae N deasnttals 0 a metal atomfbion 7 Hil beSubject = $n 4etsohedaal coordination entity doxmasion . the. d=pxbida\ F Ww iv Mi ——cctohedcall, field spitting fen ak At = 4 A 4 = Mexe. the ox a tok Sa: a fox fo ing paicing andthe xeloxe lon Qin cory Mgnsotions Wee, axel y seen Llectxonia to figs Kako in 4etsahed xa), comalexe : a Sie Ue a® srt, tt 4° WEL 6° SFL eu tas a? Seu eas WEL 7 WFL g° seu. ta i WEL : g® sku, ftt.® WEL ’ ab SEL en? i WAFL i do sFL es 42 wet ¢ wg? ore, et hat WRL pig FL gh tS : We- ~ “og neo] g Subject owe;CT TI | ei eg Aoloused in _Loosdinatinn compound oo ¢ fi “fan ual ans fr —soge—coaawss ts means Sat tome of tne uisibla © spectguen is semaued. for _uthite ight as {¢ Passes = ae tht, _soum ole 4 othe ight thas emenaes i, 00. Longe white = Ihe cous ol the complex is comglementexra) to i ix _appeans xed 4 Vv 7 a 3 > The coluux ol the com@ley com bee plained by C-e.T “tc {or Gos 12" gis complex folet in coloux => Dns _cosoplea is _thata hed ol_shexe the ¢1 As in thi \ in-%¢) = . > he, next highex €9 level i empty “te U t ws Hh ding 40_the_tnéain f bie yeillous ~ xegion iS @lsoxbec by the moplet i+ esould : 2 * \ ° baat ta? ——7 ban” fa!) Mena tas te » ® the complex appends. iole} in _coloux » 2 . 2. mun WI 2 —|-snexa u cps HY, . oy Aaa, tn'y te! 2 2 bite, 0 > {xsound tate, cited state i ° slote = T+ is impaxtam+ te note, that in absence md __caysta) field splitting dots not accu 2 amd__Rence the substomce i$ cdlopales ? y(t, —2 > cota t a > t »_@ Curso, . BHO B Cusoy + SHa9 . claws leas . ; |+ PAGE NO: (yy) | Subject : a | KAS KKHOE io Is n | 3 Ligand: only ast Sonnet by most of the. ¥xamsition metal I Winn conan hove. simple uiell defing stactoxes lke o— 7 Setea Cantons! ss 46) ts tetsabedeal Twi cala] } Go“we Subject ) O44 4G te | GG a@@¢ e \ he Fr L : Go. | oe 9 -@Q_ Mera cotbony\ enxomium lo) ts octahedsal Lox Ccalel foe ( 74 Co Co Co Catubonyl dimamgamese (0) 1s made ug of duto ayzannidal, Mn (Go) unit ined _b.