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MgCO3

The document presents thermodynamic data for the reaction of magnesium oxide (MgO) with carbon (C) and oxygen (O2) to form magnesium carbonate (MgCO3) at various temperatures. It includes values for enthalpy change (Delta_H), Gibbs free energy change (Delta_G), volume change (Delta_Vol), and entropy change (Delta_S) for temperatures ranging from 700 K to 1410 K. Additionally, it provides equilibrium constants (Keq) and specific heat capacities (Delta_Cp) for the reaction.

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0% found this document useful (0 votes)
16 views4 pages

MgCO3

The document presents thermodynamic data for the reaction of magnesium oxide (MgO) with carbon (C) and oxygen (O2) to form magnesium carbonate (MgCO3) at various temperatures. It includes values for enthalpy change (Delta_H), Gibbs free energy change (Delta_G), volume change (Delta_Vol), and entropy change (Delta_S) for temperatures ranging from 700 K to 1410 K. Additionally, it provides equilibrium constants (Keq) and specific heat capacities (Delta_Cp) for the reaction.

Uploaded by

praful.bhalerao
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as TXT, PDF, TXT or read online on Scribd
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MgO + C + O2 = MgCO3

(T) (T) (T,g) (T)


___ _ ___ _ _____ _ _____

T(K) Delta_H�(J) Delta_G�(J) Delta_Vol(litre) Delta_S�(J/K)


Delta_Cp(J/K} Keq T
_____________ _____________ ____________ ________________ _______________
_____________ __________ _

------ MgO(s-FactPS) C(s1-FactPS) O2(g-FactPS) MgCO3(s-FactPS) ----

700.00 -506599.3 -391002.5 -5.7440E+01 -165.138


1.6062E+01 1.5005E+29
710.00 -506437.1 -389352.3 -5.8261E+01 -164.908
1.6385E+01 4.4044E+28
720.00 -506271.6 -387704.3 -5.9082E+01 -164.677
1.6704E+01 1.3382E+28
730.00 -506103.0 -386058.7 -5.9902E+01 -164.444
1.7020E+01 4.2021E+27
740.00 -505931.2 -384415.5 -6.0723E+01 -164.210
1.7332E+01 1.3620E+27
750.00 -505756.4 -382774.5 -6.1543E+01 -163.976
1.7641E+01 4.5511E+26
760.00 -505578.4 -381136.0 -6.2364E+01 -163.740
1.7946E+01 1.5658E+26
770.00 -505397.4 -379499.7 -6.3185E+01 -163.504
1.8248E+01 5.5405E+25
780.00 -505213.5 -377865.9 -6.4005E+01 -163.266
1.8546E+01 2.0141E+25
790.00 -505026.5 -376234.4 -6.4826E+01 -163.028
1.8841E+01 7.5148E+24
800.00 -504836.7 -374605.3 -6.5646E+01 -162.789
1.9131E+01 2.8748E+24
810.00 -504643.9 -372978.6 -6.6467E+01 -162.550
1.9419E+01 1.1265E+24
820.00 -504448.3 -371354.3 -6.7287E+01 -162.310
1.9703E+01 4.5182E+23
830.00 -504249.9 -369732.4 -6.8108E+01 -162.069
1.9983E+01 1.8531E+23
840.00 -504048.7 -368113.0 -6.8929E+01 -161.828
2.0260E+01 7.7659E+22
850.00 -503844.7 -366495.9 -6.9749E+01 -161.587
2.0533E+01 3.3230E+22
860.00 -503638.0 -364881.2 -7.0570E+01 -161.345
2.0802E+01 1.4507E+22
870.00 -503428.7 -363269.0 -7.1390E+01 -161.103
2.1068E+01 6.4573E+21
880.00 -503216.7 -361659.2 -7.2211E+01 -160.861
2.1331E+01 2.9286E+21
890.00 -503002.1 -360051.8 -7.3031E+01 -160.618
2.1590E+01 1.3525E+21
900.00 -502784.9 -358446.8 -7.3852E+01 -160.376
2.1846E+01 6.3560E+20
910.00 -502565.2 -356844.2 -7.4673E+01 -160.133
2.2098E+01 3.0380E+20
920.00 -502342.9 -355244.1 -7.5493E+01 -159.890
2.2347E+01 1.4761E+20
930.00 -502118.2 -353646.4 -7.6314E+01 -159.647
2.2592E+01 7.2863E+19
940.00 -501891.1 -352051.2 -7.7134E+01 -159.404
2.2835E+01 3.6522E+19
950.00 -501661.5 -350458.4 -7.7955E+01 -159.161
2.3074E+01 1.8581E+19
960.00 -501429.6 -348868.0 -7.8776E+01 -158.918
2.3309E+01 9.5897E+18
970.00 -501195.4 -347280.0 -7.9596E+01 -158.676
2.3542E+01 5.0189E+18
980.00 -500958.8 -345694.5 -8.0417E+01 -158.433
2.3771E+01 2.6624E+18
990.00 -500720.0 -344111.3 -8.1237E+01 -158.191
2.3997E+01 1.4310E+18
1000.00 -500478.9 -342530.6 -8.2058E+01 -157.948
2.4221E+01 7.7896E+17
1010.00 -500237.6 -340952.4 -8.2878E+01 -157.708
2.4037E+01 4.2929E+17 T
1020.00 -499998.1 -339376.5 -8.3699E+01 -157.472
2.3857E+01 2.3943E+17 T
1030.00 -499760.4 -337802.9 -8.4520E+01 -157.240
2.3682E+01 1.3510E+17 T
1040.00 -499524.5 -336231.6 -8.5340E+01 -157.012
2.3511E+01 7.7093E+16 T
1050.00 -499290.2 -334662.6 -8.6161E+01 -156.788
2.3344E+01 4.4477E+16 T
1060.00 -499057.6 -333095.9 -8.6981E+01 -156.568
2.3181E+01 2.5934E+16 T
1070.00 -498826.5 -331531.3 -8.7802E+01 -156.351
2.3021E+01 1.5279E+16 T
1080.00 -498597.1 -329968.8 -8.8622E+01 -156.137
2.2865E+01 9.0923E+15 T
1090.00 -498369.2 -328408.5 -8.9443E+01 -155.927
2.2712E+01 5.4638E+15 T
1100.00 -498142.9 -326850.3 -9.0264E+01 -155.721
2.2563E+01 3.3146E+15 T
1110.00 -497918.0 -325294.1 -9.1084E+01 -155.517
2.2416E+01 2.0295E+15 T
1120.00 -497694.5 -323739.9 -9.1905E+01 -155.317
2.2272E+01 1.2538E+15 T
1130.00 -497472.5 -322187.8 -9.2725E+01 -155.119
2.2131E+01 7.8138E+14 T
1140.00 -497251.9 -320637.5 -9.3546E+01 -154.925
2.1993E+01 4.9113E+14 T
1150.00 -497032.6 -319089.3 -9.4367E+01 -154.733
2.1857E+01 3.1126E+14 T
1160.00 -496814.7 -317542.9 -9.5187E+01 -154.545
2.1724E+01 1.9886E+14 T
1170.00 -496598.2 -315998.4 -9.6008E+01 -154.359
2.1593E+01 1.2805E+14 T
1180.00 -496382.9 -314455.7 -9.6828E+01 -154.176
2.1464E+01 8.3090E+13 T
1190.00 -496168.9 -312914.8 -9.7649E+01 -153.995
2.1338E+01 5.4318E+13 T
1200.00 -495956.1 -311375.8 -9.8469E+01 -153.817
2.1214E+01 3.5768E+13 T
1210.00 -495744.6 -309838.5 -9.9290E+01 -153.641
2.1091E+01 2.3720E+13 T
1220.00 -495534.3 -308302.9 -1.0011E+02 -153.468
2.0971E+01 1.5840E+13 T
1230.00 -495325.2 -306769.1 -1.0093E+02 -153.298
2.0853E+01 1.0649E+13 T
1240.00 -495117.2 -305237.0 -1.0175E+02 -153.129
2.0736E+01 7.2060E+12 T
1250.00 -494910.4 -303706.5 -1.0257E+02 -152.963
2.0621E+01 4.9077E+12 T
1260.00 -494704.8 -302177.7 -1.0339E+02 -152.799
2.0508E+01 3.3634E+12 T
1261.06 -494683.0 -302015.6 -1.0348E+02 -152.782
2.0496E+01 3.2324E+12 T
------ MgO(s-FactPS) C(s1-FactPS) O2(g-FactPS) MgCO3(l-FactPS) ----

MgCO3(1 mol): DH� = 60096.4 DG� = 0 ------ DS� = 47.655

1261.06 -434586.6 -302015.6 -1.0348E+02 -105.127


4.1806E+01 3.2324E+12
1270.00 -434235.0 -301077.1 -1.0421E+02 -104.849
3.8587E+01 2.4148E+12
1280.00 -433849.7 -300030.2 -1.0503E+02 -104.546
3.8478E+01 1.7515E+12
1290.00 -433465.4 -298986.2 -1.0585E+02 -104.247
3.8369E+01 1.2771E+12
1300.00 -433082.3 -297945.2 -1.0668E+02 -103.952
3.8262E+01 9.3602E+11
1310.00 -432700.2 -296907.2 -1.0750E+02 -103.659
3.8157E+01 6.8946E+11
1320.00 -432319.1 -295872.0 -1.0832E+02 -103.369
3.8053E+01 5.1034E+11
1330.00 -431939.1 -294839.8 -1.0914E+02 -103.082
3.7950E+01 3.7957E+11
1340.00 -431560.1 -293810.4 -1.0996E+02 -102.798
3.7849E+01 2.8363E+11
1350.00 -431182.2 -292783.8 -1.1078E+02 -102.517
3.7748E+01 2.1291E+11
1360.00 -430805.2 -291760.0 -1.1160E+02 -102.239
3.7649E+01 1.6054E+11
1370.00 -430429.2 -290739.0 -1.1242E+02 -101.964
3.7552E+01 1.2158E+11
1380.00 -430054.1 -289720.7 -1.1324E+02 -101.691
3.7455E+01 9.2469E+10
1390.00 -429680.1 -288705.2 -1.1406E+02 -101.421
3.7360E+01 7.0622E+10
1400.00 -429306.9 -287692.3 -1.1488E+02 -101.153
3.7265E+01 5.4158E+10
1410.00 -428934.8 -286682.1 -1.1570E+02 -100.888
3.7172E+01 4.1698E+10
1420.00 -428563.5 -285674.5 -1.1652E+02 -100.626
3.7079E+01 3.2230E+10
1430.00 -428193.2 -284669.6 -1.1734E+02 -100.366
3.6988E+01 2.5007E+10
1440.00 -427823.7 -283667.2 -1.1816E+02 -100.109
3.6897E+01 1.9476E+10
1450.00 -427455.2 -282667.4 -1.1898E+02 -99.854
3.6808E+01 1.5224E+10
1460.00 -427087.6 -281670.1 -1.1980E+02 -99.601
3.6719E+01 1.1943E+10
1470.00 -426720.8 -280675.4 -1.2063E+02 -99.351
3.6632E+01 9.4016E+09
1480.00 -426354.9 -279683.1 -1.2145E+02 -99.103
3.6545E+01 7.4267E+09
1490.00 -425989.9 -278693.3 -1.2227E+02 -98.857
3.6459E+01 5.8864E+09
1500.00 -425625.8 -277705.9 -1.2309E+02 -98.613
3.6373E+01 4.6810E+09
1510.00 -425262.5 -276721.0 -1.2391E+02 -98.372
3.6289E+01 3.7344E+09 T
1520.00 -424900.0 -275738.5 -1.2473E+02 -98.133
3.6205E+01 2.9887E+09 T
1530.00 -424538.3 -274758.4 -1.2555E+02 -97.895
3.6122E+01 2.3993E+09 T
1540.00 -424177.5 -273780.6 -1.2637E+02 -97.660
3.6040E+01 1.9321E+09 T
1550.00 -423817.5 -272805.2 -1.2719E+02 -97.427
3.5959E+01 1.5604E+09 T
1560.00 -423458.4 -271832.0 -1.2801E+02 -97.196
3.5878E+01 1.2639E+09 T
1570.00 -423100.0 -270861.2 -1.2883E+02 -96.967
3.5798E+01 1.0267E+09 T
1580.00 -422742.4 -269892.7 -1.2965E+02 -96.740
3.5718E+01 8.3637E+08 T
1590.00 -422385.6 -268926.4 -1.3047E+02 -96.515
3.5640E+01 6.8319E+08 T
1600.00 -422029.6 -267962.4 -1.3129E+02 -96.292
3.5562E+01 5.5957E+08 T
------ MgO(s-FactPS) C(s1-FactPS) O2(g-FactPS) MgCO3(s-FactPS) ----

298.00 -510189.2 -458970.3 -2.4453E+01 -171.876


1.1089E+00 2.8063E+80
_____________ _____________ ____________ ________________ _______________
_____________ __________ _

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