Phase 1 - Cranfield - HyPER
Phase 1 - Cranfield - HyPER
Cranfield University
The Gas Technology Institute
Doosan Babcock
TRN 2039/09/2019
Executive Summary
Low carbon hydrogen (H2) will play an important role for decarbonising industry,
power, heat and transport. The Royal Society concluded that steam methane
reforming with some form of carbon capture and utilisation/storage (CCUS) was one
of the most likely technologies to be deployed at scale in the near to mid-term. We
propose to answer the call for technology development leading to a low carbon bulk
H2 supply through pilot scale demonstration of the sorption enhanced steam
reforming process, based on an existing GTI technology.
The Phase 1 feasibility study confirmed the opportunity for the GTI sorption
enhanced steam reforming process to offer bulk low carbon H2 production with over
50% CAPEX reduction and up to 98% carbon capture through integrated CO2
separation. With the potential to develop zero carbon H2 reforming as part of scale
up, this technology could significantly accelerate affordable decarbonisation of heat,
power and transport. For Phase 2, we propose a pilot scale demonstration using our
existing expertise to take this technology from TRL 4 to 6, demonstrating the process
as a full-chain integrated system for commercial industrial deployment.
7. References .................................................................................................................. 18
8. Appendices .................................................................................................................. 19
Steam Methane Reforming (SMR) technology is the predominate technology used in the
production of bulk H2, but it emits 8-12 kg of CO2 for every kg of H2 produced. Although
conventional SMR has been extensively studied for H2 production. Decarbonising it entails
installing a separate carbon capture unit downstream of the facility to comply with the next-
generation carbon emission targets.
This Phase 1 project explored the feasibility of producing bulk quantities of H2 from the
sorption enhanced steam methane reforming process integrated with an indirectly heated
calciner to facilitate the separation and removal of CO2 from the system in a solid phase.
This has been extensively developed in the US by the Gas Technology Institute (GTI). The
Compact H2 Generator (CHG) Technology patented by GTI can reduce the LCOH up to 20%
and CAPEX over 50% compared with SMR technology with 98% carbon capture.
H2 itself is a carbon-free fuel and will play a key role in the energy mix for countries with
established CO2 reduction schemes. For instance, western European countries have already
forecast an increase in H2 demand from vehicles of all sizes, rail networks, heating, fuel and
chemical production and power generation (see Figure 1 for an example of the H2
deployment and scale up pathways suggested by the Hydrogen Council 1). Many countries
continue to rely heavily on natural gas to secure their energy supply and account for
variations in electricity generation caused by weather, seasonality, and the intermittent
generation profile of renewables. This continued use of natural gas is often seen as
conflicting with greenhouse gas emission reduction goals and thus H2 is being explored as a
clean energy vector that can be stored, transported and used in similar manners to natural
The adoption of the proposed CHG H2 production technology does require functional and
available CO2 storage to be considered a low carbon option. Therefore, those countries
investigating and implementing CO2 capture with use, geo-storage or export are key target
markets. Some countries have identified market opportunities for H2 export and have put in
place financial incentives towards this goal and H2's overall use at different scales.
The growth of the CHG technology will be linked with the expanding H2 market, greenhouse
gas emissions legislation, and the development of key infrastructure (i.e. gas grid).
Therefore, near-term applications of the proposed CHG technology will be focussed on
industrial clusters where multiple potential uses of H2 exist. The CHG technology has the
capacity to scale up and expand into new markets as commitment to act on emissions
legislation increases. At the current market maturity level, the CHG technology represents a
prime candidate in the field of H2 production.
The counterfactual plant layout was simplified by excluding without thermal integration for
comparison at the pilot scale. Modelling of the CHG concept was performed to demonstrate
high pressure operation (4-30 bara) of the technology together with a closed sorbent loop.
This approach also facilitated flexible system control during the demonstration of the critical
components prior to whole plant testing.
A detailed description of the Pilot design is provided in section 2.4, but the overall CHG is
based on the sorption enhanced steam reforming process. This process is a second
generation hydrogen production process but offers a simpler process layout compared to the
Figure 2. Performance of 1.5 MWth pilot plant with different PSAOG recycle rate.
Optimised process modelling demonstrated that the CHG was able to achieve CO2 capture
of >93% by recycling the Pressure Swing Adsorption Off Gas (PSAOG) into the process. An
overall layout of the modelling is available to view in Appendix 8.1. The methane conversion
at equilibrium changed as a function of steam to carbon ratio, temperature, and reactor
pressure. The amount of steam used as an input influenced the overall thermal efficiency of
the system therefore different process models were developed for different PSAOG recycle
fraction (see Figure 2). A recycle fraction of 75% was considered for the full-scale and pilot
plant models but this could be further increased if higher CO2 capture rates are required.
The H2 in the PSAOG recycle stream negatively affects the methane conversion by shifting
the reactor equilibrium and therefore the equilibrium process models were developed with
and without an additional membrane unit to scrub out the H2 before it was recycled. The
In order to finalise the preliminary design of the pilot plant, the minimum turn-down of the
process has been modelled considering the minimum superficial velocity requirement inside
the fluidised bed reactors. The process turn-down potential was found to be around 60%
which can be further extended by controlling the operating pressure or steam-to-methane
ratio. A set of process scale-up models were also developed for 50 MWth and 150 MWth
systems to estimate the impact on the Levelised Cost of Hydrogen (LCOH). Unlike the pilot
scale model that excludes thermal integration, the scale-up models considered this to
increase the overall thermal efficiency. The results indicate that the thermal performance of
50 MWth and 150 MWth systems are similar to that of the 300 MWth system.
Despite the techno-economic benefits of operation at elevated pressure, the process has
thus far not been proven at the nominal design operating pressure of 24 bara. Therefore, the
lower-risk option of lower pressure operation was also considered.
The basis of the economic assessment of the CHG process was a bottom-up cost estimate
carried out for a 60 MSCFD (approximately 200 MWth) plant on the US Gulf Coast, delivering
99.99% H2 product purity and with the major equipment including materials, labour and
transport carried out in 2005.
All costs are presented on a Q1 2017 basis and for cost escalation from 2005 price indices
from the Bureau of Labour Statistics for US industrial gas production 3
were utilised. For
variable operating costs, an electrical import was costed as appropriate to reflect
compressor duties, whilst the cost for storage of CO2 was assumed constant.
The performance and cost metrics of the optimised CHG high- and low-pressure options
versus the counterfactual Steam Methane Reforming plus post-combustion capture and
State of the Art (SOTA) - deemed to be Auto Thermal Reforming (ATR) plus Gas Heated
Reformer (GHR) 4
- are presented in Table 1. The counterfactual and SOTA were updated
according to 20 years lifetime and a discount rate of 10%.
The CHG provides a clear advantage in carbon capture rate (up to 98%) and efficiency (up
to 73%) over the Counterfactual SMR+CCS and compares well with ATR+GHR. On a single
train basis, the economic analysis highlights that, for the high-pressure case, this advantage
is underwritten by a reduced capital expenditure (£105m vs £240m; a 56% reduction) and a
reduction in LCOH of 20% (£212/kNm3 to £170/kNm3). For the 4 bara scenario, the CAPEX
reduction is 53% and LCOH (£192/kNm3) is 10% lower than the Counterfactual.
The CAPEX and LCOH savings confirmed through Phase 1 activities highlight the dual
advantage of the CHG technology in terms of improved economics coupled with
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performance. At 38.1 kgCO2/kNm3 the carbon footprint for the high pressure CHG case is
just 42% that of the Counterfactual. Operation at low pressure further reduces carbon
footprint to just 28.6 kgCO2/kNm3. The process also has the potential to reach near-zero
carbon emissions with 100% recycle.
The proposed maximum output of 1.5 MWth represents an approximately 20x scale-up on
the existing 71 kWth facility in the US, achieved through a combination of increased physical
size and operating pressure. The 1.5 MWth pilot has been sized and a preliminary design of
the test article is shown in Figure 4.
The intent of the proposed pilot facility is to demonstrate the continuous operation of the
CHG process at high pressure, producing a high yield of H2 product and high capture rate of
CO2. However, it is recognised that there are a number of risks attendant to accomplishing
this objective. Operation at lower pressure has been shown to be both technically (for
optimal H2 yield) and economically feasible, and therefore the achievement of this operating
point would also be considered a success, should any issues with operation at elevated
pressure arise. In addition, the lack of process integration specified (e.g. thermal integration)
on the pilot is intentional in order for the facility to remain flexible for the controlled proving of
components prior to whole system testing.
The preliminary engineering design carried out in the feasibility study included preliminary
engineering including Process Design and Safety, Piping, Mechanical, Electrical, Control
and Instrumentation, Layout, Civils and Construction activities with several preliminary
deliverables as follows:
These deliverables allowed for a clearer understanding of the technical barriers to scale-up
and plant reliability. All the engineering activities will be carried out in more detail in the next
Phase giving further understanding of any residual technical barriers and potential
mitigations following pilot demonstration.
Full development of GTI’s CHG technology uses the ongoing small pilot-scale (0.071 MWth)
efforts at GTI in Chicago, US, in the Phase 2 demonstration (1.5 MWth) under the BEIS
Phase 2 Competition. The current work at GTI is funded with US-$6.5m (~£5.2m) by the
U.S. Department of Energy (DOE) with a further DOE feasibility study underway for a ~30
MWth H2-to-Power project. Figure 5 below shows the short-term development plan. The long-
term operation of the existing GTI small-scale pilot combined with the larger scale/ high-
pressure Phase 2 pilot operation will ensure that all major process risks will have been
reduced sufficiently to advance the technology to commercialisation.
In Phase 1, GTI, Doosan Babcock, and Cranfield University went through a structured
process to identify technical, environmental, economic, commercial, financial and project
management risks that need to be addressed. This provided a complementary assessment
to risks already identified and addressed under ongoing GTI activities. The primary technical
challenges relate to the operation of a steam methane reforming reaction in a fluidised bed
that includes a catalyst and a sorbent. The proposed pilot system will be able to operate at
higher pressure compared to the existing pilot at GTI.
For the short-term development, the key remaining commercial risks relate to 1. the total
equipment costs of the pilot, 2. the business arrangement between the parties and key
suppliers, 3. and identification of an early commercial opportunity.
1. Substantial efforts have been made to keep the cost of the pilot low while achieving
technical goals. e.g. rather than including a PSA for off gas recycle, that recycle
stream can be simulated through increased feed flow rate and dosing of impurities.
Lower cost construction materials will be used to account for the limited expected
operating life of the pilot and to accelerate the manufacture of the pilot.
2. The project partners have developed a teaming agreement that lays out their
business relationship.
3. For early market entry, small industrial applications (10 MWth) have been identified
with a number of possible first commercial projects at UK sites expected as part of
the BEIS grand challenge for Industrial Clusters.
The detailed design will rely on the work completed in Phase 1 and results from the cold flow
validation testing of the transport calciner and the fluidised bed/freeboard tests. The
transport calciner cold flow testing will validate the particle velocity relative to the gas velocity
and verify the operability of the configuration currently envisioned. The fluidised
bed/freeboard cold flow testing will ensure the freeboard height is greater than the terminal
disengagement height of the spouting bed of catalyst particles. A HAZOP will be convened
upon completion of the updated Phase 2 Process Flow Diagram (PFD), definition of
operating conditions, and the Piping & Instrumentation Diagram (P&ID). The results from the
HAZOP will allow the design to be finalised and released for fabrication.
The site preparation will utilise the requirements from the PFD and the results of the HAZOP
to begin upgrading the facility to meet the testing requirements and to operate in a safe and
reliable manner. Details from the design will also be used to ensure adequacy of the existing
structure for supporting the test equipment. Instrumentation and control equipment will be
procured in line with the P&ID and equipment specifications that are compatible with the
data acquisition and control system. The existing control logic from GTI’s US pilot will be
used as the basis for the control programming.
Construction will occur in parallel with the site preparation. Equipment will be inspected and
cleared for installation in line with an assembly planning. Operating procedures will again
rely on GTI’s existing procedures for their basis. A Facility Requirements Review will be held
to ensure the Pilot is ready for commissioning for the first test campaign. Upon
commissioning, the first test campaign will commence.
The 1.5 MWth Pilot testing is divided into four campaigns which incrementally gather data
and complete the integrated Pilot. Test campaign 1, shown in Figure 6 and bordered by the
smallest dashed line, will validate the operation of the transport calciner, with the key
objectives of determining the heat balance of the calciner firebox and operational limits of the
calciner. The specific operating limit parameters are calcining temperature, calcination rate
and effect of steam concentration.
Testing Campaign 2, shown in Figure 6 bordered by the medium dashed line, will
incorporate the pressurising lock hopper and H2 filter vessel into the system, with the key
purpose of validating operability of the pressurising lock hopper. The specific operability data
are the fill/drain cycle time, aeration rates, and stoppage resolution.
Testing campaign 3 (Figure 6, bordered by the solid line) will incorporate the bubbling
fluidised bed reactor and be the first campaign which generates H2. Figure 6 shows the
complete configuration, less the recycle simulant. This test series will incrementally grow the
output by starting at low pressure (4 bara) to demonstrate the functionality of the system.
The testing will incrementally increase the operating pressure once the performance data
and system reliability are achieved. The operating pressure will be increased to the following
pressures; 4 bara, 8 bara, 16 bara, and 24 bara. Other than overall proof of operation, this
campaign will enable refinement of the equilibrium models and fluidised bed reaction
kinetics- both of which are extremely valuable for future process modelling and system
optimisation.
Recycling the PSAOG is one of the novel features conceived during testing campaign 1 of
the overall project. To simulate the impact of the recycle the feed will be increased, and the
required contaminants will be injected from bottled storage. This test campaign (testing
campaign 4, shown on Figure 6 and boarded by the largest dashed line) will adequately
In conjunction with the HyPER 1.5 MWth Pilot testing, the commercialisation effort will
identify pathways for commercialisation and develop relationships with organisations
relevant to those pathways.
Based on the LCOH analysis, the cost of H2 production at a 10 TWh/yr scale has been
calculated and is 20% lower than the counterfactual. The results demonstrate the excellent
value for money that the CHG technology offers. If the CHG technology was deployed at a
scale of 10 TWh/yr by 2035, in line with UK Government intentions, then the HM
Government could expect to see a £140m Return on Investment (RoI) in the 24 bara
scenario or £67m RoI in the 4 bara scenario, relative to the Counterfactual (SMR + CCS).
These calculations assume 8000 operational hours per year and are based on the lower
heating value of H2. These projections display the significant economic benefits that could be
realised in the UK economy each year over the lifetime of operation, thus providing jobs,
clean growth, and cheap and sustainable bulk H2 supply.
The extent of deployment required to support a H2 pathway to net zero in the UK by 2050
even by a progressive blending strategy, would need similar scale and investment in the
counterfactual technology to the build rate of utility scale H2 production plant in the UK’s H21
Max Scenario 4. We have used this UK market demand to define the route to market and
drive the timeline for scale up. The £130Bn H2 production plant CAPEX costs (2023-2050)
for H21 Max UK Rollout are extrapolated for current state-of-the-art (ATR) from the H21
North of England 12.15 GWth bulk H2 production facility cost of £8.5Bn. With this scale of
ambition in mind for alternative lower cost H2 production technologies like the CHG, the 10
TWh/yr by 2035 (equivalent to deployment of up to four counterfactual scale plants) would
require earlier achievement of 300 MWth scale for the CHG technology.
The long-term development plan not only achieves this but also considers how to deliver a
net zero carbon H2 solution. At an anticipated CO2 capture performance post Phase 2
optimisation approaching 98%, the consortium is confident that a viable net zero carbon H2
production CHG solution is achievable in the long-term development plan (by 2023). This
would turn state of art reforming/carbon capture from a transition technology into one that
unlocks affordable zero carbon H2 from methane to complement green H2 from electrolysis.
Our technology development roadmap and product roadmaps are targeting notice to
proceed (NTP) on the 300 MWth unit scale by 2025, deployable in modules for a 1500 MWth
CHG plant. This would not only achieve 10 TWh/yr scale production before 2030 but also
provide a viable alternative for possible selection in a UK net zero carbon H2 build
programme. The proposed development programme would look to consolidate the techno-
economic advantages over the counterfactual through learning by doing at each product
scale up stage, to realise the significant CAPEX and LCOH benefits (56% and 20%
respectively). To achieve the route to market, the technology development roadmap focuses
on delivering three principal low carbon H2 product lines; a 10 MWth small Industrial scale
CHG; a 50 MWth small Utility scale CHG; and a 300 MWth large utility scale CHG with an
initial twin train concept for the first 300 MWth plant (150 MWth each).
HyPER Project Page | 17
7. References
1. Hydrogen Council, 2017. Hydrogen - scaling up, a sustainable pathway for the global
energy transition. Available at: http://hydrogencouncil.com/wp-
content/uploads/2017/11/Hydrogen-scaling-up-Hydrogen-Council.pdf
2. R Ray and S Ferguson, 2018. Benchmarking State-of-the-art and Next Generation
Technologies, Wood report 13333-8820-RP-001 Rev 3A.
3. BLS Data Viewer, Accessed October 2019. United States Department of Labor.
Available at: https://beta.bls.gov/dataViewer/view/timeseries/PCU32512-32512-
;jsessionid=50C623B2B45382D0D986BB2CA783805B
4. D Sadler and H S Anderson, 2018. H21 North of England, Rev 1.