Impurities types and Treatment Methods
Impurities types and Treatment Methods
University of Arkansas,
United States Department
of Agriculture, and County
Governments Cooperating.
Improving
Home
Water Quality
Contents
Introduction 1
Water Testing 1
Bacteriological Testing 1
Mineral and pH Testing 2
Chemical Testing 2
Typical Problems 2
Hardness 2
Iron or Manganese 3
Acid Water (Low pH) 4
Total Dissolved Solids (TDS) 5
Nitrates 5
Sulphates and Sulfides 6
Pressure Filters 9
Manganese Greensand Oxidizing Filter 11
Taste and Odor Filter 12
Sand Filter to Remove Turbidity (Dirty Appearance) 12
Neutralizing Filter 12
Point-of-Use Filters 13
Chlorination 14
Chlorine Demand 15
Contact Time 15
Continuous Chlorination 17
Chlorine Calibration 18
Shock Chlorination 18
Feeding Soda Ash and Chlorine Together 19
Selected References 23
Figures
Figure 1. pH Scale
Acknowledgments
Water Testing
Three general types of water testing are applicable to residential
water: (1) bacteriological analysis to determine if the water supply is
contaminated by human or animal waste; (2) mineral and pH analysis to
determine the quality of the water and its desirability for a domestic
water supply; and (3) chemical analysis to check for contamination by
hazardous chemicals.
Bacteriological Testing
Bacteriological testing is done for a fee by the Arkansas Department
of Health (ADH). Contact your local health office for complete instruc
tions for sampling. The test is for a group of bacteria called coliform.
Coliform bacteria are found in the digestive system and pass through in
the waste of humans and warm-blooded animals. These fecal coliform
bacteria are not necessarily harmful, but they indicate that the water
supply is being contaminated by human or animal fecal matter which
can contain pathogenic organisms. The test report will state whether the
water is safe or unsafe to drink. It is not unusual for private water
supplies to have bacteriological contamination. Therefore, it is
important that all new wells and private water sources be tested
before being used and retested as necessary. Contact your
county health office for recommendations for testing.
Chemical Testing
The Water Quality Laboratory does not conduct tests for chemical
contamination. Testing for pesticides or other hazardous chemicals is
conducted by commercial laboratories. Fees are relatively expensive for
this type of analysis, particularly if the lab is asked to screen the water
sample for the presence of some unknown chemical. Fees are also high for
certain specific chemicals. Chemical testing is generally considered
unnecessary in Arkansas unless a known source is suspected.
Typical Problems
Hardness
Hardness is typically the most common problem in domestic water
samples. The cause is usually calcium or magnesium that dissolves in
rainwater as it passes through soil and rock formations. Bicarbonate,
sulfate or chloride compounds are formed in the process. Iron and
manganese can also contribute to hardness.
Hardness is a nuisance because it combines with soap to form an oily
curd. The harder the water, the more soap required to create suds or
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lather, and the more curd that will be formed. The curd creates the
common bathtub ring and forms a dull coating on hair, skin and clothing.
This coating is visible on glassware and dishes that have been washed in
hard water.
Hardness also forms scale in pipes that can eventually restrict the
flow of water. Heat accelerates the scaling process, so it builds up faster
in water heaters and hot water pipes.
Iron or Manganese
Iron and manganese are discussed together because they cause
similar problems, and removal techniques are similar. Very small concen
trations of the minerals cause problems – as little as 0.05 ppm
manganese or 0.3 ppm iron. Iron is usually present in much higher
concentrations than manganese with ten times as much being typical.
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Each of these processes are pH dependent. Iron can normally be
removed when the pH is about 7.5 or higher, but manganese is very
difficult to remove at pH values below 8.5. The equipment typically used
for iron and manganese treatment is as follows:
Two problems are caused by acid water. The first is corrosion that
destroys pumps, pipes and metallic plumbing fixtures. This is character
ized by blue or green stains on plumbing fixtures if the piping is copper.
Figure 1. pH scale. If the pH is low enough, the corrosion process can dissolve enough copper
from pipes to exceed the safe level of 1.3 ppm for drinking water. The
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second problem caused by acid water is that it interferes with water
treatment, particularly iron and manganese removal.
Two methods are typically used for treatment of acid water –
aeration to remove carbon dioxide (CO2) and the addition of alkalinity.
The addition of alkalinity is usually used for home treatment, because
aeration requires an open system and two pumps. Alkalinity can be
added by a neutralizing tank that is simply a pressure filter tank filled
with limestone or marble chips. The water dissolves calcium carbonate
from the chips as it passes through the tank, raising the pH and adding
to the hardness of the water. This works well if the flow rate through the
tank is slow, and the acidity is caused by CO2. If the acidity is caused by
a metallic mineral, pH adjustment will not be accomplished. The major
disadvantage is that hardness is increased by this treatment.
Alkalinity can also be added by injecting a soda ash solution with a
chemical feed pump. The advantages of this method are that it can be
more precisely calibrated for varying flow rates, there is no limit to the
pH adjustment that can be made and hardness is not added.
Nitrates
Nitrates (NO3) and nitrate-nitrogen (NO3-N) both occur naturally in
groundwater. They are normally low concentrations that are not a matter
of concern. However, if NO3 is higher than 45 ppm or if NO3-N is higher
than 10 ppm, the water can cause methemoglobinemia in infant babies.
Blue baby is the common name for this, and it can be fatal. Babies ingest
the NO3 by drinking water or water mixed with formula. It is also
possible for NO3 to pass through the milk of nursing mothers who drink
the water. There is no apparent detrimental health effect to adults.
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High NO3 can indicate contamination of the water supply by sewage,
livestock waste or agricultural fertilizers. This type of contamination
normally occurs because of surface water infiltration into shallow wells
and surface water supplies. High nitrate levels should be taken as a
warning to test for bacteriological contamination.
Certain ion exchange processes or reverse osmosis can remove NO3.
However, the equipment must be extremely reliable, particularly in house
holds with infants. Undetected equipment failure can be fatal. Because of
this possibility and the potential for pollution in high NO3 waters, NO3
removal for home consumption is not recommended. Instead, the cause of
the NO3 contamination should be found and eliminated.
Occasionally the foul odor is present only on the hot water side of
taps around the home. This can fool the homeowner into thinking he has
a sulphur problem. If the rotten egg odor is only noticeable in the hot
water, and particularly if the water heater is electric, the problem may
be a chemical reaction with the sacrificial element in the water heater.
The element is usually a magnesium rod that serves to retard corrosion
within the tank. It may be possible to remove and discard the rod if it is
contributing to the reaction that is causing the odor. You should refer to
the manufacturer’s recommendations or contact a plumber before
removing the rod. Some water heater manufacturers offer models that
have a rod made from materials other than magnesium.
Equipment Sulfur
6
Home Water
Treatment Equipment
Water Softeners
A softener is a tank filled with a zeolite resin that is designed to
remove calcium and magnesium hardness by ion exchange. Softeners
can also be used to remove iron and manganese that is in the soluble
form if the combined concentration of the two minerals does not exceed
the capacity of the softener. Manufacturers’ specifications generally
claim that their softeners will tolerate clear water iron up to about
5 ppm per cubic foot of zeolite bed volume. Oxidized iron or manganese
(the insoluble form) should be removed by filtration before it reaches the
softener, or it will accumulate on top of the zeolite and foul the softener.
The slimy material produced by iron bacteria will also foul a softener.
Table 1 lists the gallons of water that can be softened with various
sized softeners at different levels of water hardness.
An average family uses about 75 gallons of water per person per day.
Multiplying 75 times the number of occupants in the household yields an
estimate of the daily water use, Dividing the total water use into the
gallons of water between regenerations shown in Table 1 provides an
estimate of how often the softener has to be regenerated.
7
A two-tank softener with automatic controls can be programmed to
regenerate itself as needed (Figure 2). The regeneration cycle first back-
flushes the tank to remove dirt and oxidized iron or manganese that has
been filtered out on top of the resin material. Then a brine solution from
the salt tank flushes the zeolite tank to recharge the resin material with
salt ions and release the calcium and magnesium ions. The zeolite tank
is then rinsed with clear water to flush out the brine material. This
procedure is usually programmed to occur late at night, because the
softener is out of service during the regeneration cycle.
Water softeners can be leased from a commercial water service
company for a fee, or a homeowner can purchase his own equipment. The
advantage of a water service company is that they install and maintain
the equipment.
There is another method for treating water hardness that uses a
catalytic process rather than the salt ion exchange process. Anyone
interested in treatment alternatives to the salt ion exchange process
should contact a water treatment company or explore the internet for
more information.
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High-capacity RO equipment is expensive, but small-capacity units
that can treat about 5 gallons of water per day are available at reason
able prices from equipment dealers. These units are usually located near
the kitchen sink and have a two-gallon reservoir to hold treated water
for cooking and drinking (Figure 3).
Pressure Filters
These devices are used for a variety of water treatment processes
such as taste and odor improvement, iron and manganese removal and
removal of suspended matter (turbidity) in water that gives it a dirty
appearance. Pressure filters are fully enclosed tank type filters that
operate at the same pressure as the water delivery system (Figure 4).
They have two advantages over open filters – they are not open to
contamination, and they can operate with only one pump in the water
system. Since pressure filters are part of an enclosed system, the same
pump that lifts water from the well can push the water through the
filter tank and pressure tank to the house.
The design rate for water flow through pressure filters should be
about 3 to 4 gallons per minute (gpm) per square foot (ft2). This can be
more or less depending on the filter material in the tank, quality of
water being treated and the desired level of treatment. Higher rates of
10 to 12 gpm per ft2 can be forced through the tank for short periods of
demand if the pressure is high enough. However, consistently high
filtration rates give poor treatment and require frequent backwashing.
The correct flow rate through the media during service and the
proper backwashing rate during cleaning are the secrets to effective
water filtration. Adequate flow is required to clear the filter bed of
sediment before it becomes too dirty. Twelve to 15 gpm per ft2 is the
backwash rate required to keep most filters clean. Some filters are
backwashed daily, but most are backwashed once or twice per week
depending on the condition of the water and the amount used.
Backwashing can be done manually by turning valves on and off by
hand. However, backwashing is normally accomplished with electric Figure 4. Pressure filter with
valves that are set to automatically backwash the filter as scheduled automatic backwash control.
by a timer.
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Table 2. Approximate Flow and Backwash Rates for Pressure Filters
Table 2 above shows the approximate flow rates and backwash rates
for various diameter filters.
Check manufacturers’ data for more exact figures. Most home water
supply systems cannot supply over 10 to 15 gpm flow. Therefore, the size
filter that can be used is limited by the backwash water available. That
is why many of the home pressure filters are tall bottle-type units that
are only 8 to 10 inches in diameter. This size filter can be backwashed
with 8 to 10 gpm flow. However, the low surface area only provides treat
ment for a limited water flow of about 2 gpm average or about 5 gpm for
short peak flows.
10
Figure 6. Large-diameter pressure
filter.
11
Taste and Odor Filter
Activated carbon granules are used to absorb a variety of tastes and
odors that do not have an easily defined source. Activated carbon is also
used to remove chlorine taste and odors from water that has been chlori
nated. The carbon granules also provide mechanical filtration much the
same as sand. However, activated carbon is more expensive than sand
and is normally not used unless taste and odor removal or dechlorination
is desired. Carbon must be replaced once it has utilized all of its
absorption capacity.
Activated carbon will not control the following specific taste and odor
problems: the metallic taste caused by iron and manganese, the rotten
egg taste and odor associated with hydrogen sulfide, the salty taste
caused by high salt concentrations and the taste and odor associated
with some surface water algaes.
Neutralizing Filters
This is normally a pressure filter tank filled with limestone chips that
serves the purpose of adding alkalinity to the water. As the water passes
through the filter bed, calcium carbonate is dissolved into the water and
the pH of the water is increased. The calcium carbonate also increases the
hardness of the water, so the need for softening is increased.
Filter is not a good description of this equipment, because it is
actually a contact tank to expose the water to the limestone chips. It is a
very poor filter in terms of removing suspended particles, because the
chips are relatively large and provide little resistance to the flow of
water. However, enough filtration takes place that it is necessary to occa
sionally backwash the filter tank. And, if filtration is desirable, it is
possible to add layers of fine sand or activated carbon to the tank.
Neutralizing filters do a good job of increasing the pH if the flow rate
through the tank is low and the acid water problem is caused by carbon
dioxide. However, if the problem is due to mineral acids such as
hydrochloric or sulfuric, the limestone chips may be ineffective.
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High flow rates at times of peak water consumption offer very little
time for water to be in contact with the limestone chips as the water
passes through the tank. Less adjustment to pH will occur during those
times than periods of low flows.
Point-of-Use Filters
These filters are intended for treatment of limited quantities of
water. They are often installed at the kitchen sink to treat water for
cooking and drinking (Figure 7). Backwashing is not possible with these
filters, so they have replaceable elements that must be changed when
the filter becomes loaded with impurities.
The filter life depends on the quantity and quality of water used. Figure 7. Point-of-use filter.
Activated carbon filters for dechlorination and improvement of taste and
odor are very popular point-of-use filters. Elements for other types of
treatment are available. Small distillation units and reverse osmosis
units are available if you desire more treatment than is possible with
simple filtration.
13
About 3 pounds of soda ash to 4 or 5 gallons of water is the strongest
solution that should be attempted. Soda ash has a tendency to stop up
feeder lines and check valves associated with the chemical feed pump.
Problems can be minimized by keeping the solution mixture as weak as
possible to get the pH adjustment needed.
Several water treatment equipment companies make a plastic
solution tank designed to work with their chemical feed pump. A 12- to
15−gallon high-quality hard plastic trash can with a cover makes a good
solution container. The cheaper soft plastic containers will not work
because they will split when filled with water.
Chlorination
No other method of home water treatment has as many benefits
as chlorination.
Chlorine is an oxidizing agent that changes several problem
minerals like iron, manganese and hydrogen sulfide into insoluble
precipitates so they can be filtered from the water.
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Chlorine effectively improves taste and odor of drinking water by
oxidizing noxious substances and by preventing the growth of odor-causing
algaes. When surface water is used as the home water supply, chlorine also
prevents algaes from developing within pipes and tanks.
Chlorine Demand
When chlorine is added to water, it combines with organic and
inorganic materials and oxidizes some of the minerals that are present.
The amount required to satisfy these needs is called the chlorine demand.
Example:
Manganese (Mn) level is 0.35 ppm and iron (Fe) is 1.55 ppm.
Chlorine dosage for Mn: 1.3 x 0.35 ppm = 0.5 ppm
Chlorine dosage for Fe: 0.64 x 1.55 = 1.0 ppm
Total chlorine dosage: 0.5 + 1.0 = 1.5 ppm
Contact Time
It takes some time for chlorine to accomplish effective disinfection or
oxidation. The time required depends on the concentration of chlorine
in the water, temperature and pH of the water and what the desired
result is.
15
Disinfection for most water-borne disease-causing organisms occurs
after 10 minutes of contact time if pH is 6 to 8 and the free available
chlorine residual is between 0.2 to 0.4 ppm. However, some cysts can
tolerate 1 ppm chlorine for more than 1 hour, and some nematodes can
live for more than 2 hours in 3 ppm chlorine solutions.
16
Contact time can be reduced if the chlorine dosage
is increased in the water. The following shows the relation
ship between contact time and concentration of free
available chlorine.
Continuous Chlorination
This involves injecting low rates of chlorine into the water system to
continuously treat all water flowing through the system. Enough is
injected to meet the demand and leave a free residual of 0.2 to 0.4 ppm;
more if the contact time is short. Water usually requires the addition of
anywhere from 1 to 10 ppm total chlorine.
Household bleach
is approximately
5 percent chlorine, so it
is generally used as the
chlorine source for
home water systems. It
is injected into the
water with a chemical
feed pump. The feed Figure 9. Chlorination by chemical
pump is wired electri feed pump followed by filtration.
cally into the pressure
switch controlling the
well pump so the well
pump and feed pump
run at the same time.
This treats water as it
is pumped and allows a
very accurate calibra
tion of the chlorine
dosage regardless of
how much water is
pumped (Figure 9).
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Chlorine Calibration
Chlorine can be fed directly from a bleach jug if the chemical feed
pump injection rate can be set low enough to achieve the desired free
available chlorine residual. If this is not possible, then a diluted solution
can be prepared by adding water. Dilution is always necessary if chlorine
and soda ash are fed from the same solution tank.
Shock Chlorination
Shock chlorination is generally used as a flush or wash-down
treatment for disinfection. A chlorine concentration in excess of 50 ppm
is usually used for shock chlorination.
New water wells or wells where the pump has been pulled for service
should always be shock chlorinated. Wells that have been contaminated
by animals or rodents should be disinfected with this process. It should
also be used to wash open slow sand filter tanks or closed water treat
ment equipment that has been opened for servicing. Shock chlorination
is an excellent treatment for killing slime-producing bacteria that feed
on iron, manganese or sulfur.
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Table 5. Household Bleach Required Per 50 Feet of
Water Depth to Provide at Least 50 ppm Chlorine
Pour the chlorine solution into the well and pump it through the
treatment equipment and piping if they are to be disinfected. A good
practice is to let this solution stay in the well, equipment and piping
overnight. Then pump the well until all noticeable chlorine odor is gone
from the water. Do not use the water for any purpose with this
concentration of chlorine present.
Let the sample sit for 20 minutes and test for free available (residual)
chlorine. If the residual chlorine is too low, add another cup of bleach to
the solution and repeat the process. If it is too high, you will have to pour
the solution out and start over or wait until the solution is depleted and
then mix a new batch using less bleach. This process may take several
weeks before arriving at an acceptable calibration. The pH and residual
chlorine levels should be checked every few months. Recalibration may
become necessary if the quality of the well water changes significantly.
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Typical Problems
and Possible Treatments
Hardness
Symptoms
– Large quantities of soap required.
– Oily ring develops in bathtub and sink after each use.
– Scale forms inside pipes and water heaters.
– Glassware appears cloudy after dishwashing.
Remedy
– Water softener
Comments
– If iron is also a problem, select a softener that can tolerate the iron.
At concentrations above 2 ppm, it may be best to remove the iron
before softening.
– People on low-sodium diets should consult their physician before
drinking water softened by a sodium chloride exchange process.
– If sodium is a concern, consider using potassium chloride or
investigate the catalytic process for water softening.
Remedies
– Polyphosphate feeder 0 to 2 ppm
– Ion exchange filter (softener) 0 to 10 ppm
– Oxidizing filter (manganese greensand) 0 to 10 ppm
– Chlorination followed by filtration any amounts
Comments
– Polyphosphate feeders do not remove iron but tend to hold it in
solution; the iron taste will still be present.
– Many softeners will tolerate no more than 2 ppm iron; a high-
capacity unit is required to handle 10 ppm. Iron or manganese must
be in solution for the softener to work properly; softeners will not
tolerate suspended iron or manganese.
– Most manganese greensand filters are best suited for 5 ppm of iron
or less.
– Softeners or oxidizing filters will be rapidly fouled by the gelatinous
material associated with iron or manganese bacteria.
20
Iron or Manganese Bacteria
Symptoms
– Brownish-red to black slimy, gelatinous material collects inside water
storage tanks or toilet flush tanks.
– Brownish-red to black fuzzy flakes appear suspended in water.
– Pipes, fixtures, pump intakes or valves on water system become
clogged with gelatin-appearing material.
Remedy
– Clean all accessible areas of the water system; shock chlorinate the
well and water supply system; thoroughly pump the system.
Comment
– Shock chlorination requires the addition of at least 50 ppm chlorine.
– Thoroughly pump the system to discharge the high concentration of
chlorine before using the water, and don’t put the water through
charcoal filters.
Comments
– Neutralizing filters have limited capacity and usually need to be
followed by a softener because they increase hardness.
– Aeration is effective only if acidity is due to carbon dioxide; it opens
the system to contamination; two pumps are required to operate
the system.
Remedies
– Oxidizing filter (manganese greensand) 0 to 5 ppm
– Chlorination followed by filtration any amounts
Comment
– Rotten egg odor on the hot side only can mean water is reacting with
the sacrificial element in the water heater.
– Check with water heater manufacturer or plumber before removing
the element.
21
Turbid Water (cloudy)
Symptom
– Water has a dirty or cloudy appearance.
Remedies
– Filter
– Possible chlorination
Comment
– Turbidity can be an indication that surface water is contaminating
the well. It should be taken as a warning to have the water tested for
bacteriological contamination.
Nitrates
Symptoms
– None
Remedy
– Reverse osmosis unit, elimination of cause
Comments
– High nitrates can indicate surface water contamination of a well and
should be taken as a warning to test for bacteriological contamination.
Nitrates can be ingested in drinking water or passed through the milk
of breastfeeding mothers to cause “blue baby” (methemoglobinemia)
which can be fatal to infants. Because of the possibility of equipment
failure, treatment is not recommended in homes with babies unless
there is no other possible source of water.
Remedies
– Reverse osmosis
– Distillation
Comment
– Point-of-use equipment to treat small quantities of water at the
kitchen sink for cooking and drinking is all that is practical.
Symptoms
– Corrosion of metal pipes and fixtures.
– Green stains around water outlets serviced by copper pipes.
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Remedy
– Increase pH to 8.0 or 8.5 with neutralizing filter or by adding soda
ash. A phosphate feeder may also be added in severe cases.
Comment
– Water can be very corrosive even though the pH is neutral. This
occurs in water where there is no hardness or dissolved minerals to
coat piping and protect it from the natural corrosiveness of water.
Selected References
American Association for Vocational Instructional Materials, Planning
for an Individual Water System, pp. 57-72, 1973.
Clark, John W., Warren Viessman, Jr., and Mark J. Hammer, Water
Supply and Pollution Control, Harper and Row, New York, 1977.
Lehr, Jay H., Tyler E. Gass, Wayne A. Pettyjohn, and Jack DeMarre,
Domestic Water Treatment, McGraw Hill, New York, 1980.
Steel, Ernest W., Water Supply and Sewage, McGraw Hill, New York,
1960.
Tyson, Anthony, and Kerry Harrison, Water Quality for Private Water
Systems, Bulletin 939, University of Georgia Cooperative Extension
Service, Athens, Georgia, 1986.
23
University of Georgia
• http://aesl.ces.uga.edu/publications/watercirc/
Simple circulars on common domestic water quality concerns.
Cornell University
• http://waterquality.cce.cornell.edu
Information about drinking water quality, home water treatment,
wells, septic systems, bottled water, etc.
24
NSF – Public Health and Safety Company
• The EPA does NOT register or certify any devices for home water
treatment, but the NSF International does.
http://www.nsf.org/
• http://www.nsf.org/consumer/
NSF International, an independent, not-for-profit organization, has
been committed to making the world a safer place for consumers.
Explore our consumer web site to learn more about NSF, our
programs and services and the many ways we help consumers Live
SaferTM every day.
• http://www.nsf.org/consumer/drinking_water/
Questions and answers about drinking water
• http://www.nsf.org/certified/dwtu/
Here you can search for any products certified for bacteriostatic
effects.
25
• http://www.quackwatch.org/01QuackeryRelatedTopics/
waterindex.html
Links to stories and examples of “water-related frauds and quackery.”
26
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