The document outlines the historical development of atomic theory, starting from Ancient Greek concepts of atoms and elements, through the contributions of alchemists, to the modern atomic theory proposed by John Dalton in 1808. It details the structure of the atom, including the roles of protons, neutrons, and electrons, as well as significant experiments by scientists like Rutherford and Chadwick that shaped our understanding of atomic structure. Additionally, it highlights the importance of various laws and principles in chemistry, such as the law of conservation of mass and the law of definite proportions.
The document outlines the historical development of atomic theory, starting from Ancient Greek concepts of atoms and elements, through the contributions of alchemists, to the modern atomic theory proposed by John Dalton in 1808. It details the structure of the atom, including the roles of protons, neutrons, and electrons, as well as significant experiments by scientists like Rutherford and Chadwick that shaped our understanding of atomic structure. Additionally, it highlights the importance of various laws and principles in chemistry, such as the law of conservation of mass and the law of definite proportions.
Greeks on the atom and elements. • Describe the contributions of the alchemists to the science of chemistry. • Cite the contributions of some notable scientists to the understanding of the structure of the atom. Physical Science HUMSS Bill Reniel A. Ariaso, LPT LESSON OBJECTIVES: • Describe the nuclear model of the atom and the location of its major components (protons, neutrons, and electrons).
Physical Science HUMSS Bill Reniel A. Ariaso, LPT
Activity: Time Traveller’s Choice
If you were given a
chance to time travel, to what time and place will you go? Why?
Physical Science HUMSS Bill Reniel A. Ariaso, LPT
Atoms from the Eyes of Philosophers and Scientists
Imagine you were given the
chance to time travel to Greece in the fifth century BCE. Describe the events that happened during that time.
Physical Science HUMSS Bill Reniel A. Ariaso, LPT
Atoms from the Eyes of Philosophers and Scientists
Why is the Ancient Greeks’
concept of an atom important?
Physical Science HUMSS Bill Reniel A. Ariaso, LPT
Activity: Guess the Name of the Scientist
Physical Science HUMSS Bill Reniel A. Ariaso, LPT
Atoms from the Eyes of Philosophers and Scientists
Physical Science HUMSS Bill Reniel A. Ariaso, LPT
Atoms from the Eyes of Philosophers and Scientists • Empedocles asserted that the properties of materials are imparted by the different proportions of the “four elements” that comprise them. • For example, the hardness and dryness of a stone are attributed to its high composition of the element earth. • The softness and the life of animals come from their high water and fire compositions. Physical Science HUMSS Bill Reniel A. Ariaso, LPT Atoms from the Eyes of Philosophers and Scientists
Physical Science HUMSS Bill Reniel A. Ariaso, LPT
Atoms from the Eyes of Philosophers and Scientists • Aristotle supported this idea and added the fifth element which he called aether or ether. • His ideas greatly influenced the alchemists during 300 BC until the end of the 17th century. • The alchemist intertwined chemical questions with mythical and spiritual concepts to transmute base metals into gold, discover a universal cure for diseases, and discover a means of prolonging life. Physical Science HUMSS Bill Reniel A. Ariaso, LPT Atoms from the Eyes of Philosophers and Scientists • However, none of these efforts succeeded. • Nevertheless, alchemy had still contributed numerous techniques and concepts to chemistry such as the systematic logical approaches, the knowledge of medicinal chemistry, and the development of industrial chemistry. • Practical and simple small-scale processes, such as soap making, glass manufacturing, charcoal production, and pigment and dye manufacturing, have all originated during the period of alchemy. Physical Science HUMSS Bill Reniel A. Ariaso, LPT Activity: Word Umbrella
Physical Science HUMSS Bill Reniel A. Ariaso, LPT
Activity: Word Umbrella
Physical Science HUMSS Bill Reniel A. Ariaso, LPT
Atoms from the Eyes of Philosophers and Scientists
Physical Science HUMSS Bill Reniel A. Ariaso, LPT
Atoms from the Eyes of Philosophers and Scientists • As early as 400 BC, some Greek philosophers, including Democritus, supported the idea of matter based on the particle theory. • They believed that matter is composed of very small particles called atoms, which came from the Greek word atomos, meaning “indivisible” or “uncuttable.” Physical Science HUMSS Bill Reniel A. Ariaso, LPT Atoms from the Eyes of Philosophers and Scientists • Aristotle, however, did not believe in the existence of atoms. • He asserted that all matter was continuous, an idea that was accepted for almost 2000 years. • But both theories were not supported by experimental studies and therefore remained as speculations until the 1800s. Physical Science HUMSS Bill Reniel A. Ariaso, LPT Atoms from the Eyes of Philosophers and Scientists • Empedocles’ four-element theory and the practice of alchemy came to an end when The Sceptical Chymist by Robert Boyle was published in 1661. • It was then scientists came up with experimental results that led to what we know as the atomic theory of matter.
Physical Science HUMSS Bill Reniel A. Ariaso, LPT
Atoms from the Eyes of Philosophers and Scientists • In 1808, John Dalton came up with a theory that marked the beginning of the modern era of chemistry. • His postulates may be summed up by what is known as Dalton’s Atomic Theory.
Physical Science HUMSS Bill Reniel A. Ariaso, LPT
Dalton’s Atomic Theory 1. Elements are made up of tiny visible particles called atoms. 2. For any pure element, the mass and other properties of all its atoms are the same. However, atoms of different elements differ in mass and other properties.
Physical Science HUMSS Bill Reniel A. Ariaso, LPT
Dalton’s Atomic Theory 3. Compounds are composed of more than one element. Therefore, the constituent atoms in a given compound are present in a consistent or constant whole-number ratio. 4. In a chemical reaction, atoms are neither created nor destroyed. They simply combine, separate, or rearrange. Physical Science HUMSS Bill Reniel A. Ariaso, LPT Dalton’s Atomic Theory • Dalton’s concepts about matter and atoms are more detailed than those of Democritus. • Though he did not focus on describing the structure of atom, he realized the differing properties of elements, taking hydrogen and oxygen as examples. • According to Dalton, the atoms of H are different from those O2. Physical Science HUMSS Bill Reniel A. Ariaso, LPT Dalton’s Atomic Theory • The third postulate of Dalton supports the finding of Joseph Proust about the composition of matter. • In 1799, Proust proposed an important principle that became a fundamental concept in the quantitative analysis of chemical reactions.
Physical Science HUMSS Bill Reniel A. Ariaso, LPT
Dalton’s Atomic Theory • He suggested that when forming a compound, elements always combine in similar proportions by mass regardless of the size of the sample - a concept now known as the law of definite proportions.
Physical Science HUMSS Bill Reniel A. Ariaso, LPT
Dalton’s Atomic Theory • If one to examine samples of Carbon dioxide gas from a vehicle in Manila and carbon dioxide above the pine trees in Baguio, both samples of carbon dioxide will contain the same ratio of carbon to oxygen, which is 1:2.
Physical Science HUMSS Bill Reniel A. Ariaso, LPT
Dalton’s Atomic Theory • The third postulate also supports the law of multiple proportions. • This law illustrates that if the two or more different compounds are composed of the same two elements, then the ratio of the masses of the second element combined with a certain mass of the first element is always a ratio of small whole Physical Science HUMSS Bill Reniel A. Ariaso, LPT Dalton’s Atomic Theory • For example, carbon monoxide and carbon dioxide. • With a fixed mass of carbon, the ratio of oxygen masses in the two substances is 1:2. • Dalton’s last postulate points out that when a reaction is done in a closed container, the total mass before and after the reaction is the same. Physical Science HUMSS Bill Reniel A. Ariaso, LPT Dalton’s Atomic Theory • This principle is known as the law of conservation of mass, states that mass is neither created nor destroyed during a chemical reaction.
Physical Science HUMSS Bill Reniel A. Ariaso, LPT
Structure of An Atom • Atom is defined as the tiniest particle of an element that retains the chemical properties of that element. • All atoms are made up of the nucleus and electrons. • At the center of an atom is the nucleus, which is composed of protons and neutrons. Physical Science HUMSS Bill Reniel A. Ariaso, LPT Structure of An Atom • These two units are collectively called nucleons. • The nucleus is orbited by the atom’s electrons.
Physical Science HUMSS Bill Reniel A. Ariaso, LPT
Structure of An Atom • Establishing the structure of an atom took a long time and concerted efforts of many scientists. • After the postulation of Dalton’s atomic theory, experiments and scientific inferences allowed scientists to conceptualize the structure of the atom and the properties of its components particles. Physical Science HUMSS Bill Reniel A. Ariaso, LPT Structure of An Atom • One of his students, Marie Curie, proposed the term radioactivity to describe the ability of a material to undergo spontaneous emission of particles or radiation. • Later on, it was found out the three types of rays produced by the radioactive decay of a material - alpha, beta, and gamma rays. Physical Science HUMSS Bill Reniel A. Ariaso, LPT Structure of An Atom • After the discovery of X-rays in 1895 by Wilhelm Rontgen, Antoine Bequerel started studying the flourescent properties of some substances. • He accidentally learned that the darkening of thickly wrapped photographic plates occurs after exposing them to a U compound. Physical Science HUMSS Bill Reniel A. Ariaso, LPT Structure of An Atom • The alpha rays consist of positively charged particles, called alpha particles, and therefore deflected by a positively charged plate. • Beta rays consist of beta particles (high energy electrons) and are deflected by a negatively charged plate.
Physical Science HUMSS Bill Reniel A. Ariaso, LPT
Structure of An Atom • The gamma ray has high enery as well. • Similar to X-rays, gamma rays have no charge and are not affected by an external electric or magnetic field.
Physical Science HUMSS Bill Reniel A. Ariaso, LPT
Structure of An Atom • In 1897, Joseph John Thompson presented that electrons have a negative charge. • He proposed the “plum pudding” model of an atom, which illustrated how the negatively charged electrons (plums) are mixed with smeared out positive charges (pudding). Physical Science HUMSS Bill Reniel A. Ariaso, LPT Structure of An Atom • This model explained the neutrality of an atom. • However, it was short-lived and was immediately disproved as more information regarding the atom and its nature and composition were unearthed.
Physical Science HUMSS Bill Reniel A. Ariaso, LPT
Structure of An Atom • The result of Ernest Rutherford’s gold foil experiment in 1911 showed another view on the structure of the atom. • Rutherford used a gold foil in measuring the scattering of alpha particles.
Physical Science HUMSS Bill Reniel A. Ariaso, LPT
Structure of An Atom • He noticed that most of the alpha particles passed through the foil with little or no deflection; a few were deflected at wide angles. • The lesser number of deflected alpha particles suggested that relatively small positively charged particles in the gold foil repelled the positive alpha particles. Physical Science HUMSS Bill Reniel A. Ariaso, LPT Structure of An Atom • Moreover, Rutherford concluded that most of the atom is empty, which allowed most of the alpha particles to pass through the foil. • In summary, the gold foil experiment established that the nucleus is very dense, very small, and positively charged.
Physical Science HUMSS Bill Reniel A. Ariaso, LPT
Structure of An Atom • Rutherford also concluded that the electrons are located outside the nucleus.
Physical Science HUMSS Bill Reniel A. Ariaso, LPT
Protons and Neutrons • The positively charged in the nucleus is called the proton. • Experiments revealed that the magnitude of the charge of each proton is the same as that of an electron, which is 1.6022 x 10-19 Coulomb. • Each proton weighs 1.67262 x 10-24 gram. Physical Science HUMSS Bill Reniel A. Ariaso, LPT Protons and Neutrons • Rutherford and other scientists thought that there must be another type of subatomic particle in the nucleus. • In 1932, James Chadwick proved the presence of neutral subatomic particles, which he named neutrons.
Physical Science HUMSS Bill Reniel A. Ariaso, LPT
Protons and Neutrons • In his experiment, Chadwick bombarded a thin sheet of beryllium with alpha particles that led to the emission of a very high-enerygy radiation that did not deflect upon passing through a magnetic field and is thus electrically neutral.
Physical Science HUMSS Bill Reniel A. Ariaso, LPT
Protons and Neutrons • In his latter experiments, which were similar to those of Frederic and Irene Joliot-Curie, Chadwick found out that the radiation can knock off protons of a hydrogen atom from a paraffin target and recoil the protons with great velocity. • He believed that only particles that are greater in mass than the protons can recoil from the target. Physical Science HUMSS Bill Reniel A. Ariaso, LPT Protons and Neutrons • From his results, Chadwick then concluded that the radiation consisted of neutral particles that are slightly heavier than protons, and that these particles are found in the nucleus, together with the protons.
Physical Science HUMSS Bill Reniel A. Ariaso, LPT
Electrons • Sorrounding the nucleus are negatively charged particles called electron. • In a series of experiments by Robert Millikan in the early 1900s, he found that an electron has a charge equal to -1.6022 x 10-19 Coulomb. • From this result, the mass of an electron was calculated to be 9.10 x 10-28 gram.
Physical Science HUMSS Bill Reniel A. Ariaso, LPT
Electrons • Compared to the mass of a proton, each electron is considered 1840 times lighter than a proton. • Unlike the nucleus, electrons are considered elementary particles, meaning they cannot be broken down into smaller subunits. Physical Science HUMSS Bill Reniel A. Ariaso, LPT Electrons • The equal number of protons and electrons makes an atom electrically neutral and stable. • This stability was proven by Niels Bohr in 1913 using a new model in which electrons stay in particular orbits where they do not lose or gain energy. • This model served as the beginning of quantum mechanics/ Physical Science HUMSS Bill Reniel A. Ariaso, LPT Electrons • To easily picture an electron and nucleus relative to the size of an ato, think of the Araneta Coliseum as an atom. • Imagine the nucleus as a calamansi located at the center of the coliseum. • On the other hand, the electron can be smaller than a grain iodized salt moving around the farthest seats or the general admission seats. Physical Science HUMSS Bill Reniel A. Ariaso, LPT Electrons • The rest of the coliseum is simply empty space.